V. Energy Resources Consumption (10–15%) V. Energy Resources and Consumption A. Energy Concepts (Energy forms; power; units; conversions; Laws of Thermodynamics) B. Energy Consumption 1. History (Industrial Revolution; exponential growth; energy crisis) 2. Present global energy use 3. Future energy needs C. Fossil Fuel Resources and Use (Formation of coal, oil, and natural gas; extraction/purification methods; world reserves and global demand; synfuels; environmental advantages/disadvantages of sources) D. Nuclear Energy (Nuclear fission process; nuclear fuel; electricity production; nuclear reactor types; environmental advantages/disadvantages; safety issues; radiation and human health; radioactive wastes; nuclear fusion) E. Hydroelectric Power (Dams; flood control; salmon; silting; other impacts) F. Energy Conservation (Energy efficiency; CAFE standards; hybrid electric vehicles; mass transit) G. Renewable Energy (Solar energy; solar electricity; hydrogen fuel cells; biomass; wind energy; small-scale hydroelectric; ocean waves and tidal energy; geothermal; environmental advantages/disadvantages) Energy Concepts (Energy forms; power; units; conversions; Laws of Thermodynamics) • Potential Energy • Position – dam • Stored – chemical – Ex. Fossil fuels – Endothermic – stores energy (photosynthesis) – Exothermic – releases energy (fire) • Kinetic Energy • Movement • Heat – molecules in motion (thermo) – Ex. Heat water to steam, steam moves a turbine Energy Units and Conversions • • • • • BTU – measure of heat (1lb. Of water 1oF) Calorie – measure of heat (1 g of water 1oC) Kilocalorie – 1000g 1oC Horsepower – energy (ability to move) Joule – energy (1 Newton 1 meter) Metric Prefixes • • • • Tera (T) – 1012 (trillion); terabyte Giga (G) – 109 (billion); gigabytes Mega (M) – 106 (million); megawatts; mHz Kilo (K) – 103 (thousand); kilogram, kilometer, kilowatt; kHz Thermodynamics • 1st Law – energy can be transformed but cannot be created or destroyed (energy conservation) • 2nd Law – some energy is lost as heat. Entropy increases in a closed system – Entropy – the amount of disorder – Food chains, energy pyramids Energy Consumption • History – switch from biomass (wood) to coal during the Industrial Revolution (6,000 BTU/lb. vs 14,000 BTU/lb. • Coal replaced by oil in 1950’s • Coal and natural gas being used more in latter half of 20th century – (cost, depletion of stocks) • 1960’s US began to import oil – Larger homes – Shift from agriculture to industry – More/bigger appliances (TV, refrigerators, dishwashers) Energy Consumption • Industry – mining, refining, farming, construction, manufacturing; research/development of technology • Transportation – – Infrastructure – roads, rail, airports, docks, pipelines, warehouses • Residential – homes, apartments, schools, hospitals, parks • Commercial – stores • More people = more energy (cell phones, cars, etc.) Energy Consumption • Most energy is produced from non-renewable sources (FF, nuke) • Fossil fuels – Coal – Oil (petroleum) – Natural gas • Energy conversion – chemical to electrical, heat to mechanical (about 30% efficient) • Advantages – easy to use, currently abundant • Disadvantages – nonrenewable, produces pollutants (acid rain and the greenhouse effect) FF - Coal • Dirtiest, most abundant – Sulfur (acid rain) and C (CO2) • Coal reserves in the United States, Russia, and China could last hundreds to over a thousand years. – US has 27% of the world’s proven coal reserves – Russia (17%) – China (13%) – In 2005, China and the U.S. accounted for 53% of the global coal consumption. 50% US reserves 2% US reserves • Coal is formed in several stages as the buried remains of land plants that lived 300-400 million years ago. Cogeneration • Production of two useful forms of energy from the same fuel. Heat from burning the fuel can produce steam for electricity and to warm the building Coal • Advantages: – Abundant in the US (cheap) – May be able to ‘clean up’ • Scrubbers • Electrostatic precipitators • Disadvantages – Acid rain (SO2) – CO2 emissions (climate change) – Fly/coal ash – may contain As, Pb, Co, Hg Oil • Crude oil (petroleum) • Extracted from underground deposits • Separated into: gasoline, heating oil and asphalt – Only 35-50% can be recovered economically – As the price of oil increases it will become more economical to remove it – Increased to remove it, cost lowers the net energy yield • Transportation • U.S. uses 23 barrels per capita/year Oil • OPEC have 78% of the world’s proven oil reserves and most of the world’s unproven reserves. • Alternative fuels? Case Study: U.S. Oil Supplies • U.S. – the world’s largest oil user – has only 2.9% of the world’s proven oil reserves. • U.S oil production peaked in 1974 • About 60% of U.S oil imports goes through refineries in hurricane-prone regions of the Gulf Coast. Oils from Tar Sand and Oil Shale • Petroleum from tar sand – High sulfur – Extracting and processing produces: • Toxic sludge • Lots of contaminated water • Requires large inputs of natural gas which reduces net energy yield. • Oil shales - kerogen (solid combustible mixture of hydrocarbons) that can be processed Natural Gas • Mostly methane - often found above crude oil – Gases are tapped and liquefied, removed as liquefied petroleum gas (LPG). • Remains of tiny algae and animals decomposed in anaerobic conditions (pressure, heat + time) Natural Gas • Russia and Iran have almost half of the world’s reserves of conventional gas, and global reserves should last 62-125 years. • Natural gas is versatile and clean-burning fuel • It produces CO2 and CH4 (from leaks) into the troposphere (Greenhouse gases) Methane Hydrates • Methane pockets trapped in permafrost (tundra) or deep in the oceans • 350-3500 year supply (?) • Disadvantage – cost to remove, release of CH4 during removal Elements in the Earth • Oxygen - most abundant element in crust • Nitrogen - most abundant element in the atmosphere • Iron - most abundant element in the core • Aluminum - element extracted from bauxite • Nuclear fission (U, Pu) • Energy conversion – nuclear to heat to mechanical to electrical • Advantages: very efficient, no air pollution • Disadvantages: radiation, thermal pollution, not cheap to build/operate reactors, nonrenewable fuel Energy Produced • One gram of U235 delivers as much energy as 3.5 metric tons of coal!!! • 20% of homes in the U.S. is supplied with nuke • Reactors can run for years without refueling or being shut down and need little maintenance. Types of Reactors Thermal • Uses moderators to slow neutrons which increases probability of collisions • Can use more U238 in the fuel • Moderator is also coolant • Most reactors Fast reactors • No moderator, faster neutrons • U235 has to be more concentrated but other atoms are fissile • Less radioactive waste • More expensive to build and operate • Less common Thermal Reactors • Use different moderators and/or coolants – Pressurized – water (under pressure) cools the core; second system of water converted to steam to run the turbine – Boiling water – one system – Graphite – uses graphite as moderator (allows use of more U238); Chernobyl Disadvantages • Radioactive Waste - no permanent long-term disposal site for commercial nuclear waste. • Relatively short supply of U235 (only enough left for 100~200 years) • Nuclear Power Plants are expensive to build. • Minor maintenance problems can be very expensive to fix. Nuclear Waste • Fission products (cesium, strontium, I2) emit radiation (cancer, birth defects) • Radiation – radioactive elements are unstable and give off pieces (particles and waves) – Half-life – length of time it takes for half of the radioactive element to become stable Half-Life • Every radioactive element has a half-life • Fraction of a second to billions of years – 4.5 billion for U238 • The longer the half-life, the less intense the radiation. • Nuclear wastes are stored for 10 half-lives (harmless) Types of Waste • High-level waste • Most dangerous • Spent fuel • Liquid and solid waste from production of fuel (Pu) • Low-level waste – Hospitals, research institutions, and decommissioned power plants • After three or four years, spent fuel rods are stored/cooled in a steel-lined concrete container • After cooling they are temporarily stored on site • In the past • Stored in underground tanks that leaked into the soil, contaminating groundwater • Dumped at sea into deep water • Incinerated • How to store radioactive wastes long-term: – Bury it deep underground, or in the Antarctic or deep ocean. – Shoot it into space. – Change it into harmless or less harmful isotopes. Yucca Mountain • Federal Government • Located 100 miles from Las Vegas • Store radioactive sources at least 10,000 years; peak radiation after 400,000 years • Storage in one place (the middle of the desert) is safer than scattered around the country in temporary facilities. • Remote, sparse population • Hard rock formations • Yucca Mountain is the most studied geological formation ever Cons About Yucca Mountain • Peak radiation - after 10,000 years • Water corrode containers and leak radiation • Transportation to Yucca Mountain will take 24 years • Waste will travel through 45 states • Accidents, terrorists • Harry Reid (D Nv); Senate Majority Leader has blocked Yucca Mountain project, Obama stopped funding Accidents: • Chernobyl - former Soviet Union – worst in history – Hundreds died from radiation exposure. – Thousands contracted cancers from high levels of radiation exposure. • Fukushima, Japan – tsunami • Three Mile Island – Pa. – Small radioactive gas leak http://youtu.be/kLId9kso2oE - fukushima http://youtu.be/RXZ9MhSJfVU - chernobyl Case Study: Chernobyl • 1986, Ukraine • Poor reactor design and human error • 2005, 56 people had died from radiation – 4,000 more expected from cancer Fukushima - 2011 • • • • Earthquake created a tsunami Flooding caused pumps to fail Back-up pumps (battery) failed later Hydrogen gases built up inside the reactor buildings causing them to explode What Happened to Nuclear Power? • Multi billion-dollar construction costs. • Higher operation costs and more malfunctions than expected. • Public concerns – Safety – Terrorism • Nuclear power plants will not lessen dependence on imported oil and will not reduce CO2 emissions as much as other alternatives. • Wind turbines, solar cells, geothermal energy, and hydrogen contributes much less to CO2 emissions. Alternative Solutions • Today’s inefficient reactors burn only 3% of Uranium. The other 97% is waste. • A new “fast” reactor promises to burn 99.9% of fuel creating a residue that will be harmless in only 300 years • Solution will take at least 10 years and $2 billion dollars in federal funds Hydroelectric • 98% of usable rivers are already dammed • Hydroelectric power • Irrigation, flood control Water • Energy conversion – kinetic to electrical or heat • Benefits – already have the technology to do this, pollution free, dams are also useful as water sources and flood controls; world’s largest source of electrical power • Costs – there are environmental costs to building new dams, there are not rivers located everywhere Solar - Types • Photovoltaic cells - convert sunlight to electricity - 10% efficiency • Thermal systems - sun’s heat is used to heat bodies of water enough to produce steam for electricity • Energy conversion – radiant/heat to electrical, heat or mechanical • Benefits – pollution-free, unlimited source • Costs – not useful in cloudy areas or at night, we do not have the technology needed to use very efficiently Photovoltaic Cells Solar Energy • Renewable energy resources are hindered by a lack of government support compared to nonrenewable fossil fuels and nuclear power. – Direct solar – Moving water – Wind – Geothermal Solar • Advantages: • Free • Net energy is moderate (active) to high (passive) • No pollution • Relatively low cost to build/maintain • Disadvantages: • 60% sunlight • Remove blocks (buildings/trees) • Need storage • High costs to build/ maintain (active) • Unattractive Passive Solar Heating • Absorbs and stores heat without pumps to distribute the heat. Wind • Energy conversion – solar, mechanical, electric • Benefits – no pollution, source is free (after construction), maintenance is moderate and renewable • Costs – can only be used in places with lots of wind • Much of the world’s potential for wind power remains untapped • Capturing only 20% of the wind energy at the world’s best energy sites could meet all the world’s energy demands Geothermal • Only energy source that doesn’t come from the sun • Conversion – thermal to mechanical to electrical and heat • Benefits – pollution-free • Disadvantages – not available everywhere, we don’t have all the technology needed to use it, takes up a lot of room, initial costs are high, pumping costs are high Tidal Power • Energy conversion – kinetic to electrical • Advantages – no pollution, free, cheap renewable • Disadvantages – cost to build/maintain Renewable Energy • European Union - 22% of electricity from renewable by 2010. • China - 10% of its total energy from renewable by 2020. • California got about 12% of its electricity (2004) from wind; plans to increase this to 50% by 2030. • Denmark - 20% of electricity from wind and plans to increase this to 50% by 2030. • Brazil - 20% of its gasoline from sugarcane residue. • In 2004, the world’s renewable-energy industries provided 1.7 million jobs. Biomass • • • • • Any organic matter (wood, crop wastes, trash, etc.) Currently about 5% of U.S. energy Energy conversion – chemical to electrical or heat Benefits – cheap, less toxic pollutants, uses wastes Disadvantages – more technology needed to make it efficient, not useful in everywhere, some pollution Alternative Fuels • Biodiesel – vegetable oils and alcohols; expensive • Biogas – by-product of decaying vegetation; need technology • Hydrogen – free, renewable; expensive and more technology is needed Converting Plants and Plant Wastes to Liquid Biofuels • Motor vehicles can run on ethanol, biodiesel, and methanol produced from plants and plant wastes. • The major advantages of biofuels are: – Crops used for production can be grown almost anywhere. – There is no net increase in CO2 emissions. – Widely available and easy to store and transport. Ethanol/Methanol – not as efficient (Miles per gallon) needs more technology; uses grains (corn) • Propane – most usable form of alternative fuel; not as efficient (mpg) • Syngas – man-made gas made of hydrogen and carbon monoxide; needs more technology • Case Study: Producing Ethanol • Crops (sugarcane, corn, and switchgrass) and wastes (agricultural, forestry and municipal) can be converted to ethanol. • 10-23% pure ethanol makes gasohol which can be run in conventional motors. • 85% ethanol (E85) must be burned in flex-fuel cars. • Processing all corn grown in the U.S. into ethanol would cover only about 55 days of current driving. Case Study: Biodiesel and Methanol • Growing crops for biodiesel could cause deforestation. • Methanol is made mostly from natural gas but can also be produced at a higher cost from CO2 from the atmosphere which could help slow global warming. – Can also be converted to other hydrocarbons to produce chemicals that are now made from petroleum and natural gas. Improve Energy Efficiency • General features of a car powered by a hybrid-electric engine. • “Gas sipping” cars account for less than 1% of all new car sales in the U.S. Fuel-Cell Vehicles • Fuel-efficient vehicles powered by a fuel cell that runs on hydrogen gas are being developed. • Combines hydrogen gas (H2) and oxygen gas (O2) fuel to produce electricity and water vapor (2H2+O2 2H2O). • Emits no air pollution or CO2 if the hydrogen is produced from renewable-energy sources. Conservation • Passive solar heating/cooling in commercial buildings • Insulation, plugging leaks, and using energyefficient heating and cooling systems, appliances, and lighting. Reducing Waste • Four widely used devices waste large amounts of energy: – Incandescent light bulb: 95% is lost as heat. – Internal combustion engine: 94% of the energy in its fuel is wasted. – Nuclear power plant: 92% of energy is wasted through nuclear fuel and energy needed for waste management. – Coal-burning power plant: 66% of the energy released by burning coal is lost. Saving Energy in Existing Buildings • About one-third of the heated air in typical U.S. homes and buildings escapes through closed windows and holes and cracks. Resources & Their Uses • Limestone – abundant locally, formed from layers of seashells and corals under pressure as they were covered; concrete • Lead – batteries, radiation shielding • Clay – books, magazines, bricks, and linoleum • Gold – money and for jewelry, medicine (teeth, lasers, cauterizing agents) and in electronics Nonrenewable Resources • Sustainability - prediction of how long resources will last – Ex. Coal, oil • Conservation - using less of a resource or reusing a resource • Restoration – recycling resources – Ex. – aluminum, paper, plastic, glass • CAFÉ - Corporate Average Fuel Economy Act – 1975; mpg stickers required on cars/trucks • Public Utility Regulatory Policies Act (PURPA)– 1978; higher utility rates for increased electricity use National Appliance Energy Act – 1987; energy efficiency stickers on all appliances • Clean Air Act Amendments – 1990; cities and emissions • Energy Policy Act – 1992; find renewable energy resources •