Asthram -1 ABCD……………… of CHEMISTRY Presented to: Bhavishya Phase: II Concept and material by Y.Vijay Aryan SIIT JEE 9948925181 Visit us @ www.siitjee.org 1 What is it ? Can you imagine anything after seeing it ? Can you fill these boxes ? Start your chemistry Game ! My friends………. Visit us @ www.siitjee.org 2 ABCD……. Of Chemistry: Most of the Universe consists of matter and energy. Energy is the capacity to do work. Matter has mass and occupies space. All matter is composed of basic elements that cannot be broken down to substances with different chemical or physical properties. Elements are substances consisting of one type of atom, for example Carbon atoms make up diamond, and also graphite. Pure (24K) gold is composed of only one type of atom, gold atoms. Atoms are the smallest particle into which an element can be divided. The ancient Greek philosophers developed the concept of the atom, although they considered it the fundamental particle that could not be broken down. Since the work of Enrico Fermi and his colleagues, we now know that the atom is divisible, often releasing tremendous energies as in nuclear explosions or (in a controlled fashion in) thermonuclear power plants. Symbols of the elements: Part of the language of chemistry are the names and symbols of the chemical elements. There are 91 naturally occurring elements found on Earth. Once you are familiar with the names and symbols of the more common elements, you will be able to learn to write chemical formulas and to do some simple chemical calculations. Definition of an element : A substance that cannot be broken down by any chemical means. Elements are defined by the number of protons they possess. Examples: gold, iron, silver 1. A BRIEF HISTORY OF ELEMENT SYMBOLS The modern symbols used to represent the chemical elements consist of one or two letters from the element's name. Historically, symbols were not always like this. Some of the earliest symbols were those used by the ancient Greeks to represent the four elements earth, air, fire, and water. These were adopted by Plato, using the Pathagorean geometric solids: Earth Air Fire Water cubic atoms octahedral atoms tetrahedral atoms icosahedral atoms As other chemical substances were defined, symbols of the planets were used. Ancient symbols: Gold The symbol for gold could also be used to represent the sun in astrology. Visit us @ www.siitjee.org Iron The symbol for iron could also be used to represent the planet Mars in astrology. 3 Lead The symbol for lead was also used to represent the planet Saturn in astrology. Mercury, called quicksilver The symbol for mercury could also be used to represent the planet of the same name in astrology. MagnesiumAlchemists used 'Magnesia alba' (literally "white magnesia") which was magnesium carbonate (MgCO3), also known as 'mild magnesian earth.' PhosphorusAlchemists often used light as a symbol of the spirit, therefore they were especially interested in light that seemed to be trapped in matter such as phosphorus. Platinum-chemists believed platinum to be an amalgamation of gold and silver. Potash carbonate) Silver : The symbol for silver is also associated wth the moon in astrology. Sulfur is one of the three heavenly substances (sulfur, mercury & salt). It was widely used in chemical pratice. Tin: The symbol for tin could also be used to represent the planet Jupiter in astrology. (potassium Zinc-Philosophers' wool, or nix alba (white snow) was zinc oxide made by burning zinc in air. John Dalton, in advocating his atomic theory recommended symbols composed of circles. Visit us @ www.siitjee.org 4 JOHN DALTON'S NOTATION symbols: of Before the early 1800s the symbols used to denote chemical elements and compounds were obscure. Alchemists wanted to keep their work secret and so devised symbols for the chemicals they used that would not reveal anything about them. This all changed with the work of Jöns Jakob Berzelius. Scientists of the day, however, viewed Dalton’s symbols as cumbersome and with little improvement, Finally, in 1813, Jon Jakob Berzelius devised a system using letters of the alphabet. He argued that letters should be used because they could be written more easily than other signs. The modernized version of Berzelius' system follows under the heading: Visit us @ www.siitjee.org 5 System for Determining Symbols of the Elements 1. The symbols of the most common elements, mainly nonmetals, use the first letter of their English name. Examples: H, B, C, N, O, F, P, S, I 2. If the name of the element has the same initial letter as another element, then the symbol uses the first and second letters of their English name. Examples: He, Li, Be, Ne, Al 3. If the first two letters of the element name are the same as another element, then the symbol consists of the first letter and the first consonant of the English name that they do not have in common. Examples: magnesium has the symbol Mg (first letter and first consonant) manganese has the symbol Mn chlorine has the symbol Cl(first letter and first consonant NOT in common) chromium has the symbol Cr 4. Some symbols are based on the old name or Latin name of the element. Na(Sodium) Natrium Sb(Antimony) Stibium Fe(Iron) Ferrum W(Tungsten) Wolfram Cu(Copper) Cuprum Au(Gold) Aurum Ag(Siver) Argentums Hg(Mercury) Hydrargyrum Sn(Tin) Stannum Pb(lead) Plumbum 5. New elements, or those with disputed claims for discovery/ synthesis are named using three letters based on the Latin for their atomic numbers: These symbols can be used for elements from atomic number 100 The names are derived by using root words for the three digits in the atomic number of the element and adding the suffix –ium Number 0 1 2 3 4 5 6 7 8 9 Rootword nil Un bi tri quad pent hex sept oct enn In certain cases the names are shortened. a. bi + ium = bium b. tri + ium = trium c. enn + nil = ennil Example: Write the IUPAC name of an element with atomic number 108 Answer: Un-nil-oct-ium = Unniloctium Symbol: Uno Visit us @ www.siitjee.org 6 2. MODERN CHEMICAL SYMBOLS Listed below are the atomic numbers, names, and symbols of the most common elements. The atomic number is used to determine the place of the element in the periodic table, it also has other meaning as you will find out later in the course. Become familiar with the names and symbols of these elements. Atomic Atomic Number Name Symbol 1 Hydrogen H 2 Helium He 3 Lithium Li 4 Beryllium Be 5 Boron B 6 Carbon C 7 Nitrogen N 8 Oxygen O 9 Fluorine F 10 Neon Ne In the beginning: Not until around 460 B.C., did a Greek philosopher, Democritus, develop the idea of atoms. He asked this question: If you break a piece of matter in half, and then break it in half again, how many breaks will you have to make before you can break it no further? Democritus thought that it ended at some point, a smallest possible bit of matter. He called these basic matter particles, atoms. For example consider an element carbon, start dividing it into fine particles and reach the stage where carbon particles cannot be further broken down. Moreover, if carbon has to undergo any chemical change, then the change must start from this particle.This smallest particle of carbon is called an atom of carbon. The word "atom" comes from the greek "a-tomos" and signifies "indivisible". This notion was invented by Leucippe of Milet in 420 B.C. Visit us @ www.siitjee.org 7 But advanced science confirmed that atom is also indivisible. What does an atom constitutes ? ATOMIC PARTICLES: Atoms consist of three subatomic particles: electrons are negatively charged particles and their properties are summarized in the following table protons are positively charged particles and their properties are summarized in the following table neutrons have no charge and their properties are summarized in the following table Particle Mass (kg) Mass (amu)# Charge* Electron 9.10939 x 10 -31 0.00055 -1 Proton 1.67262 x 10 -27 1.00728 +1 Neutron 1.67493 x 10 -27 1.00866 0 1 amu (atomic mass unit) = 1.66054 x 10 * unit charge = 1.602 x 10 -19 C (coulomb) # -27 kg ELECTRONS: J.J. Thomson determined mass of the electron, e-, in 1897 o the mass is 5.486 x 10 -4 amu or 9.10939 x 10 -31 kg Robert Millikan measured the charge of e-, -1.602 × 10-19 coulombs Thomson developed the "plum pudding" model of the atom. This model had all atomic particles distributed evenly throughout the volume of the atom Rutherford developed the "nuclear" model of the atom o based upon his experiment he showed that atoms contains regions of highly dense, positive material, called the nucleus o the nucleus is very dense, 99.95% (or more) of the mass of the atom is in the nucleus which has a diameter of approximately 10 -15 m o Rutherford discovered this through his famous experiment with gold foil in which he shot alpha particles (fairly massive particles with a positive charge) through thin gold foil and found that many particles were strongly deflected and some bounced back at him! This could only happen if the gold foil atoms contained massive centers that had a positive charge, as exhibited in the figure below. Visit us @ www.siitjee.org 8 PROTONS: small, positively charged particles (+1.602 × 10-19 coulombs reside in the nucleus along with the neutron, make up most of the mass of the atom the number of protons is what defines the type of a particular atom NEUTRONS: small particles with no charge reside in the nucleus along with the proton, make up most of the mass of the atom a differing number of neutrons is what defines an "isotope" of an atom ATOMIC NUMBER: The atomic number corresponds to the number of protons in the nucleus of an atom of that element. It also corresponds to the number of electrons in the neutral atom. the atomic number has the symbol, Z, and is shown as a subscript to the element symbol the atomic number gives the number of protons in the nucleus (and the number of electrons if the species is neutral) of a particular atom the atomic number defines a specific type of atom since each different type of atom (representing each element) will have a different number of protons in the nucleus MASS NUMBER: the mass number has the symbol, A, and is shown as a superscript to the element symbol the mass number gives the mass of atom in amu, atomic mass number, and is approximately equal to the number of protons plus the number of neutrons ELEMENTAL SYMBOLS: AXZ Elemental symbols are typically written as above where X is the element symbol with the mass number as a superscript and the atomic number as a subscript. Visit us @ www.siitjee.org 9 ISOTOPES: Almost all atoms have "Isotopes" Elements with the same number of protons (atomic number) but differing number of neutrons – isotopes are the same elements (atoms) with different masses isotopes will have slightly different chemical and physical properties due to the difference in mass, which can be very helpful in characterizing substances for example, below are three isotope of carbon, C: 12C6 13C6 14C6 #p 6 6 6 #e 6 6 6 #n 6 7 8 notice that the sum of # protons and # neutrons is equal to the mass number because nearly all elements have one or more isotopes, the mass of a naturally occurring element will be a "weighted average" of all the isotopes which occur naturally, for example: Carbon has two prominent isotopes which occur naturally (C-14 is present in very small quantities and is radioactive so does not stick around long and we won't count it here) shown below with their relative percent abundance C-12 12.0000 amu 98.9% abundant C-13 13.0000 amu 1.1 % abundant To determine the mass of naturally occurring carbon, we calculate the weighted average of the two isotopes by summing (fractional abundance)(mass of isotope) for each isotope: mass C = (0.989)(12.0000) + (0.011)(13.0000) = 12.011 amu Atomic weight: Atoms and molecules are material particles and they possess mass. The mass of one atom of an element is known as the atomic weight of the element. Atomic weight should not be confused with another concept called atomic number of an element. Atomic number A is the simple sum of the number of protons (Z) and neutrons (N) the element has. Thus A = Z + N and is an integral number as Z and N both are integer numbers. The atomic mass or weight is an actual measure of the weight of the atoms in grams or kilograms. The table below gives mass of some of the atoms. Element Mass in Kg Hydrogen 1.67 x 10-27 kg Oxygen 26.56 x 10-27 kg Chlorine 58.9 x 10-27 kg Uranium 395.0 x 10-27 kg We can see that when we deal with the masses, since they are very small, it is inconvenient to use such numbers in calculations. To make calculations less o Visit us @ www.siitjee.org 10 cumbersome, weight of the atom of an element is compared to the weight of standard atom and their ratio is taken. In 1962, it was decided by the international community, mass of the isotope of carbon, namely 12C, should be taken as 12. All the other atomic weights are compared to the weight of an atom of 12C. Average weight of one atom of the element Atomic weight of an atom of an element = 1/12 x weight of one atom of 12C Average weight of one atom of the element Atomic weight of an atom of an element = x 12 weight of one atom of 12C How to calculate the average weight of an element Elements exist in various isotopes. The average weight of an element is calculated from the proportion in which the isotopes occur (relative abundance). For example the atom chlorine has two isotopes : 35Cl and 37Cl. Their relative abundance is in the ratio of 3 : 1. 3 x 35 + 1 x 37 Thus the average weight of Cl atom = = 35.5 4 Please note that atomic weight is a ratio, hence does not have any units associated with it. If an element does not have an isotope, then its average weight is same as that of its atomic number. Gold (Au) and Platinum (Pt) fall in this category. The table below gives some of the atomic weights of elements accepted internationally. Element Symbol Atomic Weight Hydrogen H 1.008 Helium He 4.003 Lithium Li 6.939 Carbon C 12.011 Oxygen O 15.994 Sodium Na 22.990 Silicon Si 28.090 Chlorine Cl 35.452 Gram atomic weight or gram atomic mass : In chemical reactions, we deal with normal mass units such as grams (and kilograms). The quantity of element equivalent to its atomic weight taken in grams is called the gram atomic weight (GAW) or gram atomic mass (GAM). For example : 1 gram atomic mass of Visit us @ www.siitjee.org 11 sodium will be equal to 22.99 gm. Similarly 1 gram atomic mass of carbon will be equal to 12.011 gm. Atomic Number Name Symbol Standard atomic weight Group Period 1 Hydrogen H 1.00794 1 1 2 Helium He 4.002602 18 1 3 Lithium Li 6.941 1 2 4 Beryllium Be 9.012182 2 2 5 Boron B 10.811 13 2 6 Carbon C 12.0107 14 2 7 Nitrogen N 14.0067 15 2 8 Oxygen O 15.9994 16 2 9 Fluorine F 18.9984032 17 2 10 Neon Ne 20.1797 18 2 11 Sodium (Natrium) Na 22.98976928 1 3 12 Magnesium Mg 24.3050 2 3 13 Aluminium (Aluminum) Al 26.9815386 13 3 14 Silicon Si 28.0855 14 3 15 Phosphorus P 30.973762 15 3 16 Sulfur S 32.065 16 3 17 Chlorine Cl 35.453 17 3 18 Argon Ar 39.948 18 3 19 Potassium (Kalium) K 39.0983 1 4 20 Calcium Ca 40.078 2 4 21 Scandium Sc 44.955912 3 4 22 Titanium Ti 47.867 4 4 23 Vanadium V 50.9415 5 4 24 Chromium Cr 51.9961 6 4 25 Manganese Mn 54.938045 7 4 26 Iron (Ferrum) Fe 55.845 8 4 27 Cobalt Co 58.933195 9 4 28 Nickel Ni 58.6934 10 4 29 Copper (Cuprum) Cu 63.546 11 4 30 Zinc Zn 65.38 12 4 Visit us @ www.siitjee.org 12 Molecular weight: It is referred with respect to molecules. Average weight of one molecule of the substance Molecular weight of = x 12 a substance weight of one atom of 12C Types of ions: classification classification II I Based on charge Electro positive ions ex: k+, Ag+, Na+ Based on types of atoms involved Simple ions ex: k+, Ag+, Cl-,O2- Electro negative ions Compound ions ex: Cl-,O2-,SO42- ex: SO42- SO32- Ions and radicals: Atom is electrically neutral. But if it is stripped of electrons it gets a positive charge. This is because there is an imbalance of positive and negative charges. Similarly if an atom attracts extra electrons, it becomes negatively charged. The charged atoms are called ions. Na (neutral sodium atom) Cl (neutral chlorine atom) Na + (positive sodium ion) + e(electron) Visit us @ www.siitjee.org + e(electron) Cl(negative chlorine ion) 13 What is a Radical? Sometimes in a chemical reaction of compounds the constituent elements are not released, but there may be a group of atoms sticking together. These groups are called radicals. Thus a radical is a component of a compound consisting of groups of atoms. Radicals can be positively as well as negatively charged. To simplify the jargons, ions are called simple radicals and groups of atomic radicals are called compound radicals. For example (OH) is called a radical and is negatively charged. Hence it is written as (OH)-, Other common compound radicals are (SO4)2-, (NO3)-, etc. Some radicals and their chemical symbols are listed below: Valency Radical/ Ion Formulae Chloride, Bromide, Iodide Monovalent [1] Cl-, Br-,I- Hypochlorite ClO1- Chlorite ClO21- Chlorate ClO31- Perchlorate ClO41- Hypobromite BrO1- Bromite BrO21- Bromate BrO31- Perbromate BrO41- Hypoiodite IO1- Iodite IO21- Iodate IO31- Periodate IO41- Hydroxide OH1- Nitrite NO21- Nitrate NO31- Bicarbonate [Hydrogen carbonate] HCO31Bisulphite [Hydrogen sulphite] HSO31- Bisulphate [Hydrogen sulphate] HSO41- Dihydrogen phosphate H2PO41- Cyanide CN1- Cyanate CNO1- Thiocyanate SCN1- Permanganate Acetate Visit us @ www.siitjee.org MnO41CH3COO114 Divalent [2] Formate HCOO1- Hydride H1- Hydrogen H+ Lithium Li+ Sodium Na+ Potassium K+ Ammonium NH4+ Cuprous Cu+ Argentous Ag+ Mercurous Hg+ Aurous Au+ Oxide O2- Peroxide O22- Carbonate CO32- Sulphite SO32- Sulphate SO42- Thiosulphate S2O32- Biphosphate [Hydrogen phosphate] HPO42Chromate CrO42- Dichromate Cr2O72- Oxalate C2O42- Manganate MnO42- Beryllium Be2+ Magnesium Mg2+ Calcium Ca2+ Barium Ba2+ Nickel Ni2+ Zinc Zn2+ Cobalt Co2+ Cupric Cu2+ Argentic Ag2+ Mercuric Hg2+ Ferrous Fe2+ Plumbous Pb2+ Stannous Sn2+ Visit us @ www.siitjee.org 15 Trivalent [3] Tetravalent[4] Pentavalent[5] Mangannous Mn2+ Phosphite PO33- Phosphate PO43- Phosphide P3- Boride B3- Borate BO33- Nitride N3- Aluminate AlO33- Aluminium Al3+ Chromium Cr3+ Boron B3+ Ferric Fe3+ Auric Au3+ Antimonous Sb3+ Cobaltic Co3+ Carbide C4- Plumbic Pb4+ Stannic Sn4+ Platinic pt4+ Manganic Mn4+ Arsenic As5+ Antimonic Sb5+ How to write a Chemical formula ? Alphabets formed millions of words in English language, Just like that elements combine to form millions of compounds. The combinations of elements can be best understood by Criss cross method. The Criss Cross Method is used to find the general formula for ionic compounds. For monatomic ions, you simply take the absolute value of the ionic charge for the positively charge ion and make it the subscript for the negatively charged ion and vice versa. Example: Al +3 and Cl -1 The 3 becomes the subscript for the chloride ion and the 1 becomes understood for aluminum, to form aluminum chloride: AlCl3 Ionic compounds that form from polyatomic ions can also make use of the criss cross method. The only additional step is to include parenthesis around the polyatomic ion if it has a subscript other than one. Example: Mg+2 and OH-1 The 2 becomes the subscript for the hydroxide ion, but a set of parenthesis is needed to indicate 2 of each the O and the H. The 1 becomes the understood subscript for Mg. Magnesium Hydroxide: Mg(OH)2 Visit us @ www.siitjee.org 16 Writing formula from name: e.g. nickel (III) nitrate Step 1: Write the ionic symbol of the cation and anion. Ni3+ NO3(For cations with more than one charge, the charge will be given as a roman numeral.) Step 2: Use the “criss-cross” method to determine the subscripts of each of the ion in the formula. Ni (1) NO3 (3) (The criss-cross method helps one find the least common multiple of the charges. An ionic compound formula is the least whole number ratio of ions in which the total positive charge equals the total negative charge of the cations and anions respectively.) Step 3: Write the empirical formula (least whole number ratio of ions of the compound). Ni(NO3)3 (Parentheses are used around polyatomic ions when more than one of the ion is required in the formula. Write the formulas for the following ionic compounds: a) Silver sulphide b) Tin(IV) sulphate c)Potassium permanganate d)Titanium (IV) oxide e) Aluminum chloride f) Indium selenide Writing the name of a ionic compound from the formula: e.g. Fe2(CO3)3 Step 1: Name the cation. “iron (III)” (For cations with more than one charge, the charge needs to be included as a roman numeral. The charge is deduced from the subscripts of the ions in the empirical formula, i.e. the reverse “criss-cross” method.) Step 2: Name the anion. “carbonate” (Polyatomic ions have names that the student has memorized. Monoatomic anions end with the “-IDE” suffix.) Step 3: Put the two names together: “iron (III) carbonate” Name the following compounds: a) Ba(ClO)2 b) KBr c) ZnSO4 d) NH4Cl e) AuCl3 f) Hg2S g) Li3PO3 Covalent (or molecular) Compounds (binary only) Writing formulas from names: e.g. dinitrogen monoxide Step 1: Write the elemental symbols of the two elements: N O Step 2: Make the greek prefix the element’s subscript N2O (Subscripts of “1” are never written.) Write the formulas of the following molecular compound names: a) Phosphorus pentabromide b) Silicon tetrafluoride c) Dicarbon disulfide d) Nitrogen triiodide e)Sulfur hexafluoride f) Tetraarsenic decaoxide Writing names from molecular formulas: e.g. CS2 Step 1: Write the name of the first element as on the periodic table. “carbon” Step 2: Add a Greek prefix to this name if there is more than one of the element in the compound. Step 3: Write the name of the second element ending with the “-IDE” suffix. Always add a Greek prefix to indicate the number of the second element. Write the names of the following molecules: a)NO2 b)N2O4 c)P2S5 d)BF3 e)P4O10 Visit us @ www.siitjee.org 17 Chemical formulae of some important compounds: COMMON NAME King of chemicals Washing soda Baking soda Soda ash Aquafortis Bleaching powder Brine solution Rock salt Bone ash Caustic soda Lime stone Dry ice Grain alcohol Inorganic graphite Inorganic Benzene Laughing gas Tear gas Quick Lime Slaked Lime Urea Carbinol Plaster of paris Soda lime Quick silver Nitre Oleum Water gas Marsh gas Gypsum Aqua regia Nitration mixture Epsom salt Hematite or magnetite Blue vitriol CHEMICAL NAME Sulphuric acid Hydrated sodium carbonate sodium bicarbonate Anhydrous sodium carbonate Nitric acid Calcium oxychloride Sodium chloride(sol) Sodium chloride Calcium phosphate Sodium hydroxide Calcium carbonate Solid carbondioxide Ethanol Boron nitride Borozole Nitrous oxide Chloropicrin Calcium oxide Calcium hydroxide Amino methanamide Methanol Calcium sulphate hemi hydrate ---------Mercury Potasium Nitrate Fuming sulphuric acid Water gas Methane Calcium sulphate di hydrate ----------------------Magnesium hepta hydrate Ferroso ferric oxide Copper sulphate penta hydrate Visit us @ www.siitjee.org FORMULA H2SO4 Na2SO4.10H2O NaHCO3 Na2CO3 HNO3 CaOCl2 NaCl(sol) NaCl Ca3(PO4) 2 NaOH CaCO3 CO2 C2H5OH BN B3N3H3 N2O CCl 3NO2 CaO Ca(OH)2 NH2CONH2 CH3OH CaSO4.½ H 2O CaO + NaOH Hg KNO3 H2S2O7 CO + H2 CH4 CaSO4.2 H 2O HNO3 + HCl HNO3 + H2SO4 MgSO4.7H2O Fe3O4 CuSO4.5H2O 18 Assignment -I: 1. Identify the elements from the following words: a. ArGeNTiNa b. CoRn c. LiON d. CabbaGe 2. Find the number of protons, electrons and neutrons in a. Al b. Mg c. Zn 3. Find the number of protons, electrons and neutrons in a. Al3+ b. Na+ c. Cl4. An atom contains 8 protons & 8 neutrons in the nucleus there are 10 electrons. The atom is _____________ (a) Neutral & Metal (b) Neutral & An Ion (c) Neutral & Nonmetal (d) An Ion & Nonmetal (e) An Ion & Metal 5. A sodium atom has 1 electron in its outer shell which can hold 8 electrons. to achieve stability, the sodium atom _________ (a) Gives up 1 electron to another atom (b) Adds 7 electrons (c) Adds 4 electrons (d) Adds 2 electrons (e) Adds 3 electrons 6. Why an atomic number does not change, during a chemical reaction ? 7. Two neutrons are added to the nucleus of Carbon. Name the new particle that forms and also write its atomic number. 8. Find the neutron/ proton ratio of Zinc and carbon. 9. A neutral atom consists of 19 protons and 20 neutrons. Find the number of electrons in it. 10. Find the number of smallest units of masses that make 1 CGS unit of mass 11. Find the atomic weight of one Scandium atom. 12. Find the molecular weight of the following molecules: a. Sulphuric acid b. Nitric acid c. Epsom salt d. CO2 13. There is a compound containing C, H and O. The amount of ‘C’ present is 36 amu and the amount of ‘H’ present is 8 amu. Oxygen contributes a mass of 16 ×1.66 × 10-24 g. Find the molecular formula and the molecular weight of the compound. 14. Find the gram molecular weight of Calcium carbonate. 15. Find the weight of 50 Sulphuric acid molecules. 16. All radicals are ions, but all ions are not radicals. Explain it ? 17. Write the formulae and valencies of the following ions: a. Sulphate b. Sulphite c. Nitrate d. Carbonate e. Manganate f. ferric g. Stannous h. Chlorite 18. Write the formulae of the following compounds by criss cross method. a. Aluminium Sulphate b. Chromium Sulphate c. Silicon Carbide d. Boron nitride e. Magnesium bicarbonate 19. Nitration mixture is a mixture of _____________ and _____________ 20. Chemical formula of washing soda is _____________ Visit us @ www.siitjee.org 19 Assignment – II: 1. Among the following, select the symbols whose names are named after the scientists and write their names. C, No, Fm, K, Ag, Cm, Md, N, Es, Fe 2. Identify the names of the elements with which they are made : a. BeCaUSe b. SHOLaY c. CArBON d. SKY 3. Give two examples each for elements which have dependent and independent existence of atoms. 4. Calculate the number of protons, electrons, neutrons in the isotopes of hydrogen. 5. Calculate the number of protons, electrons, neutrons present in O2-,Cl-, K+ ions. 6. Why the atomic number of an element does not change during a reaction. 7. The mass number of a neutral element is 65, the number of negatively charged particles in it are 30.Then find the number of neutrally charged particles in it and write the name of the element. 8. The ratio of the number of neutrons present in Scandium and Chromium. 9. Find the number of the smallest units of masses that make 1 MKS unit of mass 10. There is a compound containing C, H, O. The amount of C present is 72 amu and the amount of H present is 12amu. Oxygen contributes a mass of 96 × 1.66 × 10-24 g. Find the molecular weight of the compound. 11. Find the molecular weight of 200 H2SO4 molecules. 12. A compound consists of Nitrogen and Oxygen. Nitrogen atom contributes 28 amu of mass, whereas Oxygen atom contributes 60 amu. Find the molecular formula and the molecular weight of the compound. 13. Write the formulae for the following compound using criss cross method. a. Sodium bicarbonate b. Ferric hydroxide c. limestone 14. Balance the equation in which Nitrogen dioxide, on treating with water, gives rise to Nitrous acid and Nitric acid 15. The 100th element, Fermium is based on a scientist’s name. Name the scientist , the symbol of element and write its IUPAC name. 16. Which elements exhibit highest valency in the periodic table ? Choose the correct answer 1. The weight of one calcium atom is a. 40 b. 20 c. 40 amu d. 40 gm 2. Size of the nucleus is ______ times the size of atom a. 105 b. 103 c. 10-5 d. 10-3 3. Homogeneous molecules are also called as __________ molecules. a. Compound b. Elementary c. Single d. double 4. Atomicity of Carbon in C60 is a. 6 b. 12 c. 60 d. 24 5. Molecular weight of Calcium carbonate is ________ Visit us @ www.siitjee.org 20 a. 59 b. 159 c. 100 d. 112 6. Molecular weight of Soda ash is a. 106 b. 108 c. 112 d. 116 7. Valency of N in N2O is a. 2 b. 1 c. 3 d. 4 8. Valency of Sulphur in SF2, SF6, SF4 is a. 2, 3, 5 b. 2, 4, 6 c. 2, 6, 4 d. 1, 2, 5 9. Identify the element that forms an electro negative ion. a. He b. H c. S d. CO3 10. Identify the element with highest valency among the following : a. Carbon b. Ruthenium c. Aluminium d. Arsenic 11. Identify the formula of Aluminium nitride. a. AlN b. Al2N c. Al3N d. Al3N2 12. Charge of Zincate radical is a. ZnO– b. Zn2O– c. ZnO22– d. ZnO3– 13. Identify the formula of Carbon tetra chloride. a. CCl b. CCl4 c. C4Cl d. CCl2 14. Identify the formula of Stannic chloride. a. SnCl b. SnCl2 c. SnCl3 d. SnCl4 15. Identify the formula of Potassium dichromate. a. K2CrO7 b. K2Cr2O7 c. K1Cr3O7 d. KCrO7 16. Charge of Manganate ion is a. MnO4– b. MnO2– c. Mn2O4– d. MnO42– 17. Identify the formula of Sodium thiosulphate. a. Na1S2O3 b. Na2S2O3 c. Na3S2O3 d. Na1S3O3 1. 2. 3. 4. 5. Chloride Hypo chlorite Chlorate Chlorite Per chlorate Matching ( ) ( ) ( ) ( ) ( ) Visit us @ www.siitjee.org a. ClO– b. ClO2– c. ClO3– d. Cl3– e. ClO4– f. Cl– 21