Lecture PowerPoint Physics: Principles with Applications, 6th edition Giancoli © 2005 Pearson Prentice Hall This work is protected by United States copyright laws and is provided solely for the use of instructors in teaching their courses and assessing student learning. Dissemination or sale of any part of this work (including on the World Wide Web) will destroy the integrity of the work and is not permitted. The work and materials from it should never be made available to students except by instructors using the accompanying text in their classes. All recipients of this work are expected to abide by these restrictions and to honor the intended pedagogical purposes and the needs of other instructors who rely on these materials. Modern Physics 26.9 The Ultimate Speed A basic result of special relativity is that nothing can equal or exceed the speed of light. This would require infinite momentum – not possible for anything with mass. 26.10 E = mc2; Mass and Energy At relativistic speeds, not only is the formula for momentum modified; that for energy is as well. The total energy can be written: (26-7b) Where the particle is at rest, (26-8) 26.10 E = mc2; Mass and Energy All the formulas presented here become the usual Newtonian kinematic formulas when the speeds are much smaller than the speed of light. There is no rule for when the speed is high enough that relativistic formulas must be used – it depends on the desired accuracy of the calculation. Chapter 27 Early Quantum Theory and Models of the Atom 27.1 Discovery and Properties of the Electron In the late 19th century, discharge tubes were made that emitted “cathode rays.” 27.1 Discovery and Properties of the Electron It was found that these rays could be deflected by electric or magnetic fields. 27.1 Discovery and Properties of the Electron By accelerating the rays through a known potential and then measuring the radius of their path in a known magnetic field, the charge to mass ratio could be measured: (27-1) The result is 27.1 Discovery and Properties of the Electron Cathode rays were soon called electrons. Millikan devised an experiment to measure the charge on the electron by measuring the electric field needed to suspend an oil droplet of known mass between parallel plates. 27.1 Discovery and Properties of the Electron The mass and charge of each droplet were measured; careful analysis of the data showed that the charge was always an integral multiple of a smallest charge, e. 27.1 Discovery and Properties of the Electron The currently accepted value of e is: Knowing e allows the electron mass to be calculated: 27.2 Planck’s Quantum Hypothesis; Blackbody Radiation All objects emit radiation whose total intensity is proportional to the fourth power of their temperature. This is called thermal radiation; a blackbody is one that emits thermal radiation only. 27.2 Planck’s Quantum Hypothesis; Blackbody Radiation The spectrum of blackbody radiation has been measured; it is found that the frequency of peak intensity increases linearly with temperature. 27.2 Planck’s Quantum Hypothesis; Blackbody Radiation This figure shows blackbody radiation curves for three different temperatures. Note that frequency increases to the left. 27.2 Planck’s Quantum Hypothesis; Blackbody Radiation This spectrum could not be reproduced using 19th-century physics. A solution was proposed by Max Planck in 1900: The energy of atomic oscillations within atoms cannot have an arbitrary value; it is related to the frequency: The constant h is now called Planck’s constant. 27.2 Planck’s Quantum Hypothesis; Blackbody Radiation Planck found the value of his constant by fitting blackbody curves: Planck’s proposal was that the energy of an oscillation had to be an integral multiple of hf. This is called the quantization of energy. 27.3 Photon Theory of Light and the Photoelectric Effect Einstein suggested that, given the success of Planck’s theory, light must be emitted in small energy packets: (27-4) These tiny packets, or particles, are called photons. 27.3 Photon Theory of Light and the Photoelectric Effect The photoelectric effect: If light strikes a metal, electrons are emitted. The effect does not occur if the frequency of the light is too low; the kinetic energy of the electrons increases with frequency. 27.3 Photon Theory of Light and the Photoelectric Effect If light is a wave, theory predicts: 1. Number of electrons and their energy should increase with intensity 2. Frequency would not matter 27.3 Photon Theory of Light and the Photoelectric Effect If light is particles, theory predicts: • Increasing intensity increases number of electrons but not energy • Above a minimum energy required to break atomic bond, kinetic energy will increase linearly with frequency • There is a cutoff frequency below which no electrons will be emitted, regardless of intensity 27.3 Photon Theory of Light and the Photoelectric Effect The particle theory assumes that an electron absorbs a single photon. Plotting the kinetic energy vs. frequency: This shows clear agreement with the photon theory, and not with wave theory. 27.3 Photon Theory of Light and the Photoelectric Effect The photoelectric effect is how “electric eye” detectors work. It is also used for movie film soundtracks. 27.4 Energy, Mass, and Momentum of a Photon Clearly, a photon must travel at the speed of light. Looking at the relativistic equation for momentum, it is clear that this can only happen if its rest mass is zero. We already know that the energy is hf; we can put this in the relativistic energy-momentum relation and find the momentum: (27-6) 27.4 Compton Effect Compton did experiments in which he scattered X-rays from different materials. He found that the scattered X-rays had a slightly longer wavelength (and less energy) than the incident ones, and that the wavelength depended on the scattering angle: (27-7) 27.4 Compton Effect This is another effect that is correctly predicted by the photon model and not by the wave model. 27.4 Photon Interactions; Pair Production Photons passing through matter can undergo the following interactions: 1. Photoelectric effect: photon is completely absorbed, electron is ejected 2. Photon may be totally absorbed by electron, but not have enough energy to eject it; the electron moves into an excited state 3. The photon can scatter from an atom and lose some energy 4. The photon can produce an electron-positron pair. 27.4 Photon Interactions; Pair Production In pair production, energy, electric charge, and momentum must all be conserved. Energy will be conserved through the mass and kinetic energy of the electron and positron; their opposite charges conserve charge; and the interaction must take place in the electromagnetic field of a nucleus, which can contribute momentum. 27.5 Wave-Particle Duality; the Principle of Complementarity We have phenomena such as diffraction and interference that show that light is a wave, and phenomena such as the photoelectric effect and the Compton effect that show that it is a particle. Which is it? This question has no answer; we must accept the dual wave-particle nature of light. 27.5 Wave-Particle Duality; the Principle of Complementarity The principle of complementarity states that both the wave and particle aspects of light are fundamental to its nature. Indeed, waves and particles are just our interpretations of how light behaves. 27.6 Wave Nature of Matter Just as light sometimes behaves as a particle, matter sometimes behaves like a wave. The wavelength of a particle of matter is: (27-8) (p=mv) This wavelength is called the deBroglie wavelength and is extraordinarily small. 27.6 Wave Nature of Matter The wave nature of matter becomes more important for very light particles such as the electron. 27.6 Wave Nature of Matter Electron wavelengths can easily be on the order of 10-10 m; electrons can be diffracted by crystals just as X-rays can. 27.8 Early Models of the Atom It was known that atoms were electrically neutral, but that they could become charged, implying that there were positive and negative charges and that some of them could be removed. One popular atomic model was the “plum-pudding” model: 27.8 Early Models of the Atom This model had the atom consisting of a bulk positive charge, with negative electrons buried throughout. 27.8 Early Models of the Atom Rutherford did an experiment that showed that the positively charged nucleus must be extremely small compared to the rest of the atom. He scattered alpha particles – helium nuclei – from gold foil and observed the scattering angle. He found that some of the angles were far larger than the plum-pudding model would allow. 27.8 Early Models of the Atom The only way to account for the large angles was to assume that all the positive charge was contained within a tiny volume – now we know that the radius of the nucleus is 1/10000 that of the atom. 27.8 Early Models of the Atom Therefore, Rutherford’s model of the atom is mostly empty space: 27.9 Atomic Spectra: Key to the Structure of the Atom A very thin gas heated in a discharge tube emits light only at characteristic frequencies. 27.9 Atomic Spectra: Key to the Structure of the Atom An atomic spectrum is a line spectrum – only certain frequencies appear. If white light passes through such a gas, it absorbs at those same frequencies. 27.9 Atomic Spectra: Key to the Structure of the Atom The wavelengths of electrons emitted from hydrogen have a regular pattern: (27-9) This is called the Balmer series. R is the Rydberg constant: 27.9 Atomic Spectra: Key to the Structure of the Atom Other series include the Lyman series: And the Paschen series: 27.9 Atomic Spectra: Key to the Structure of the Atom A portion of the complete spectrum of hydrogen is shown here. The lines cannot be explained by the Rutherford theory. 27.10 The Bohr Atom Bohr proposed that the possible energy states for atomic electrons were quantized – only certain values were possible. Then the spectrum could be explained as transitions from one level to another. 27.10 The Bohr Atom Bohr found that the angular momentum was quantized: (27-11) 27.10 The Bohr Atom An electron is held in orbit by the Coulomb force: 27.10 The Bohr Atom Using the Coulomb force, we can calculate the radii of the orbits: (27-13) (27-12) 27.10 The Bohr Atom The lowest energy level is called the ground state; the others are excited states. 27.11 de Broglie’s Hypothesis Applied to Atoms De Broglie’s hypothesis is the one associating a wavelength with the momentum of a particle. He proposed that only those orbits where the wave would be a circular standing wave will occur. This yields the same relation that Bohr had proposed. 27.11 de Broglie’s Hypothesis Applied to Atoms These are circular standing waves for n = 2, 3, and 5. Chapter 30 Nuclear Physics and Radioactivity 30.1 Structure and Properties of the Nucleus Nucleus is made of protons and neutrons Proton has positive charge: Neutron is electrically neutral: 30.1 Structure and Properties of the Nucleus Neutrons and protons are collectively called nucleons. The different nuclei are referred to as nuclides. Number of protons: atomic number, Z Number of nucleons: atomic mass number, A Neutron number: N = A - Z 30.1 Structure and Properties of the Nucleus A and Z are sufficient to specify a nuclide. Nuclides are symbolized as follows: X is the chemical symbol for the element; it contains the same information as Z but in a more easily recognizable form. 30.1 Structure and Properties of the Nucleus Nuclei with the same Z – so they are the same element – but different N are called isotopes. For many elements, several different isotopes exist in nature. Natural abundance is the percentage of a particular element that consists of a particular isotope in nature. 30.1 Structure and Properties of the Nucleus Because of wave-particle duality, the size of the nucleus is somewhat fuzzy. Measurements of high-energy electron scattering yield: (30-1) 30.1 Structure and Properties of the Nucleus Masses of atoms are measured with reference to the carbon-12 atom, which is assigned a mass of exactly 12u. A u is a unified atomic mass unit. 30.1 Structure and Properties of the Nucleus From the following table, you can see that the electron is considerably less massive than a nucleon. 30.2 Binding Energy and Nuclear Forces The total mass of a stable nucleus is always less than the sum of the masses of its separate protons and neutrons. Where has the mass gone? 30.2 Binding Energy and Nuclear Forces It has become energy, such as radiation or kinetic energy, released during the formation of the nucleus. This difference between the total mass of the constituents and the mass of the nucleus is called the total binding energy of the nucleus. 30.2 Binding Energy and Nuclear Forces To compare how tightly bound different nuclei are, we divide the binding energy by A to get the binding energy per nucleon. 30.2 Binding Energy and Nuclear Forces The higher the binding energy per nucleon, the more stable the nucleus. More massive nuclei require extra neutrons to overcome the Coulomb repulsion of the protons in order to be stable. 30.2 Binding Energy and Nuclear Forces The force that binds the nucleons together is called the strong nuclear force. It is a very strong, but short-range, force. It is essentially zero if the nucleons are more than about 10-15 m apart. The Coulomb force is long-range; this is why extra neutrons are needed for stability in high-Z nuclei. 30.2 Binding Energy and Nuclear Forces Nuclei that are unstable decay; many such decays are governed by another force called the weak nuclear force. 30.3 Radioactivity Towards the end of the 19th century, minerals were found that would darken a photographic plate even in the absence of light. This phenomenon is now called radioactivity. Marie and Pierre Curie isolated two new elements that were highly radioactive; they are now called polonium and radium. 30.3 Radioactivity Radioactive rays were observed to be of three types: 1. Alpha rays, which could barely penetrate a piece of paper 2. Beta rays, which could penetrate 3 mm of aluminum 3. Gamma rays, which could penetrate several centimeters of lead We now know that alpha rays are helium nuclei, beta rays are electrons, and gamma rays are electromagnetic radiation. 30.3 Radioactivity Alpha and beta rays are bent in opposite directions in a magnetic field, while gamma rays are not bent at all. 30.4 Alpha Decay Example of alpha decay: Radium-226 will alpha-decay to radon-22 30.4 Alpha Decay In general, alpha decay can be written: Alpha decay occurs when the strong nuclear force cannot hold a large nucleus together. The mass of the parent nucleus is greater than the sum of the masses of the daughter nucleus and the alpha particle; this difference is called the disintegration energy. 30.4 Alpha Decay Alpha decay is so much more likely than other forms of nuclear disintegration because the alpha particle itself is quite stable. 30.4 Alpha Decay One type of smoke detector uses alpha radiation – the presence of smoke is enough to absorb the alpha rays and keep them from striking the collector plate. 30.5 Beta Decay Beta decay occurs when a nucleus emits an electron. An example is the decay of carbon-14: The nucleus still has 14 nucleons, but it has one more proton and one fewer neutron. This decay is an example of an interaction that proceeds via the weak nuclear force. 30.5 Beta Decay The electron in beta decay is not an orbital electron; it is created in the decay. The fundamental process is a neutron decaying to a proton, electron, and neutrino: The need for a particle such as the neutrino was discovered through analysis of energy and momentum conservation in beta decay – it could not be a two-particle decay. 30.5 Beta Decay Neutrinos are notoriously difficult to detect, as they interact only weakly, and direct evidence for their existence was not available until more than 20 years had passed. The symbol for the neutrino is the Greek letter nu (ν); using this, we write the beta decay of carbon-14 as: 30.5 Beta Decay Beta decay can also occur where the nucleus emits a positron rather than an electron: And a nucleus can capture one of its inner electrons: 30.6 Gamma Decay Gamma rays are very high-energy photons. They are emitted when a nucleus decays from an excited state to a lower state, just as photons are emitted by electrons returning to a lower state. 30.7 Conservation of Nucleon Number and Other Conservation Laws A new law that is evident by studying radioactive decay is that the total number of nucleons cannot change. 30.8 Half-Life and Rate of Decay Nuclear decay is a random process; the decay of any nucleus is not influenced by the decay of any other. 30.8 Half-Life and Rate of Decay Therefore, the number of decays in a short time interval is proportional to the number of nuclei present and to the time: (30-3a) Here, λ is a constant characteristic of that particular nuclide, called the decay constant. 30.8 Half-Life and Rate of Decay This equation can be solved, using calculus, for N as a function of time: (30-4) 30.8 Half-Life and Rate of Decay The half-life is the time it takes for half the nuclei in a given sample to decay. It is related to the decay constant: (30-6) 30.10 Decay Series A decay series occurs when one radioactive isotope decays to another radioactive isotope, which decays to another, and so on. This allows the creation of nuclei that otherwise would not exist in nature. 30.10 Decay Series 30.11 Radioactive Dating Radioactive dating can be done by analyzing the fraction of carbon in organic material that is carbon-14. 30.11 Radioactive Dating The ratio of carbon-14 to carbon-12 in the atmosphere has been roughly constant over thousands of years. A living plant or tree will be constantly exchanging carbon with the atmosphere, and will have the same carbon ratio in its tissues. 30.11 Radioactive Dating When the plant dies, this exchange stops. Carbon-14 has a half-life of about 5730 years; it gradually decays away and becomes a smaller and smaller fraction of the total carbon in the plant tissue. This fraction can be measured, and the age of the tissue deduced. Objects older than about 60,000 years cannot be dated this way – there is too little carbon-14 left. 30.11 Radioactive Dating Other isotopes are useful for geologic time scale dating. Uranium-238 has a half-life of 4.5 x 109 years, and has been used to date the oldest rocks on Earth as about 4 billion years old. Chapter 31 Nuclear Energy; Effects and Uses of Radiation 31.1 Nuclear Reactions and the Transmutation of Elements A nuclear reaction takes place when a nucleus is struck by another nucleus or particle. If the original nucleus is transformed into another, this is called transmutation. An example: 31.1 Nuclear Reactions and the Transmutation of Elements Energy and momentum must be conserved in nuclear reactions. Generic reaction: The reaction energy, or Q-value, is the sum of the initial masses less the sum of the final masses, multiplied by c2: 31.1 Nuclear Reactions and the Transmutation of Elements If Q is positive, the reaction is exothermic, and will occur no matter how small the initial kinetic energy is. If Q is negative, there is a minimum initial kinetic energy that must be available before the reaction can take place. 31.1 Nuclear Reactions and the Transmutation of Elements Neutrons are very effective in nuclear reactions, as they nave no charge and therefore are not repelled by the nucleus. 31.2 Nuclear Fission; Nuclear Reactors After absorbing a neutron, a uranium-235 nucleus will split into two roughly equal parts. One way to visualize this is to view the nucleus as a kind of liquid drop. 31.2 Nuclear Fission; Nuclear Reactors The mass distribution of the fragments shows that the two pieces are large, but usually unequal. 31.2 Nuclear Fission; Nuclear Reactors The energy release in a fission reaction is quite large. Also, since smaller nuclei are stable with fewer neutrons, several neutrons emerge from each fission as well. These neutrons can be used to induce fission in other nuclei, causing a chain reaction. 31.2 Nuclear Fission; Nuclear Reactors In order to make a nuclear reactor, the chain reaction needs to be self-sustaining – it will continue indefinitely – but controlled. 31.2 Nuclear Fission; Nuclear Reactors A moderator is needed to slow the neutrons; otherwise their probability of interacting is too small. Common moderators are heavy water and graphite. Unless the moderator is heavy water, the fraction of fissionable nuclei in natural uranium is too small to sustain a chain reaction, about 0.7%. It needs to be enriched to about 2-3%. 31.2 Nuclear Fission; Nuclear Reactors Neutrons that escape from the uranium do not contribute to fission. There is a critical mass below which a chain reaction will not occur because too many neutrons escape. 31.2 Nuclear Fission; Nuclear Reactors Finally, there are control rods, usually cadmium or boron, that absorb neutrons and can be used for fine control of the reaction, to keep it critical but just barely. 31.2 Nuclear Fission; Nuclear Reactors Some problems associated with nuclear reactors include the disposal of radioactive waste and the possibility of accidental release of radiation. 31.2 Nuclear Fission; Nuclear Reactors An atomic bomb also uses fission, but the core is deliberately designed to undergo a massive uncontrolled chain reaction when the uranium is formed into a critical mass during the detonation process. 31.3 Nuclear Fusion The lightest nuclei can fuse to form heavier nuclei, releasing energy in the process. An example is the sequence of fusion processes that change hydrogen into helium in the Sun. They are listed here with the energy released in each: 31.3 Nuclear Fusion The net effect is to transform four protons into a helium nucleus plus two positrons, two neutrinos, and two gamma rays. (31-7) More massive stars can fuse heavier elements in their cores, all the way up to iron, the most stable nucleus. 31.3 Nuclear Fusion There are three fusion reactions that are being considered for power reactors: These reactions use very common fuels – deuterium or tritium – and release much more energy per nucleon than fission does. 31.3 Nuclear Fusion A successful fusion reactor has not yet been achieved, but fusion, or thermonuclear, bombs have been built. 31.3 Nuclear Fusion Several geometries for the containment of the incredibly hot plasma that must exist in a fusion reactor have been developed – the tokamak, which is a torus; or inertial confinement, which is tiny pellets of deuterium ignited by powerful lasers. 31.4 Passage of Radiation Through Matter; Radiation Damage Radiation includes alpha, beta, and gamma rays; X rays; and protons, neutrons, pions, and other particles. All these forms of radiation are called ionizing radiation, because they ionize material that they go through. This ionization can cause damage to materials, including biological tissue.