Requirements for the Establishment of Mercury Monitors in Mexico as a Pilot Project Identification of the Technical Design of the Monitoring Pilot Project for Wet Deposition of Mercury in Mexico ANNE M. HANSEN, MANFRED VAN AFFERDEN General Project Objective Identify the requirements for the establishment of mercury monitors in Mexico as a pilot project in collaboration with key agencies in Mexico and liaising with appropriate Canadian and US authorities as well as private sector contractors. What is the big idea? Extension of Mercury Deposition Network Integration of Mexican sampling stations into the existing network Intensification of future collaboration in prevention of exposure Installation of two wet-deposition monitors MDN requires two different instruments for the collection and measurement of precipitation: An electrically powered collector that automatically collects precipitation samples for mercury analysis A raingage that mechanically measures and records the amount of precipitation Collector Raingage Sample and data handling Weekly precipitation samples should be collected every Tuesday and mailed to the Mercury Analytical Laboratory at Frontier Geosciences (USA) for analysis by cold vapor atomic fluorescence spectrometry. The MDN provides data for total mercury, but will include methylmercury if desired by a site sponsor. Field bucket Event recorder trace Why install mercury monitors in Mexico? Deposition of Mercury General NADP Monitoring Objectives To characterize geographic patterns and temporal trends in biologically important chemical deposition. To support research activities related to: The productivity of managed and natural systems; The chemistry of surface and ground waters, including estuaries; The health of domestic animals, wildlife, and fish; Human health. (Dossett and Bowersox, 1999) General Mexican Objectives Assess mercury exposure rates to ecosystems and human populations through mercury wet deposition in Mexico; Evaluate the effects of emissions reduction and control on a long term basis; Identify main mercury transport routes; Fulfill international commitments; Increase Mexican capacity in the assessment of mercury deposition and effects. Who will be responsible? Responsibilities in Mexico Semarnat Subsecretaría de Planeación y Política Ambiental Subsecretaría de Gestión para la protección ambiental Subsecretaría de Fomento y Normatividad Ambiental Dirección General de Planeación y Evaluación Dirección General de Impacto y Riesgo Ambiental Dirección General de Estadística e Información Ambiental Dirección General de Manejo Integral de Contaminantes Dirección General de Política Ambiental e Integración Regional y Sectorial Dirección General de Zona Federal Marítimo Terrestre y Ambientes Costeros Dirección General de Vida Silvestre Dirección General de Federalización y Descentralización de Servicios Forestales y de Suelo Unidad Coordinadora de Participación Social y Transparencia Oficialía Mayor Dirección General del Sector Primario y Recursos Naturales Renovables Dirección General de la Industria Dirección General de Fomento Ambiental del Desarrollo Urbano, Transporte, Servicios y Turismo Dirección General de Energía y Actividades Extractivas Unidad Coordinadora de Asuntos Internacionales Dirección General de Recursos Humanos Coordinación General de Comunicación Social Dirección General de Programación, Organización y Presupuesto Contraloría Interna Coordinación General de Delegaciones Dirección General de Recursos Materiales, Inmuebles y Servicios Delegaciones Federales Dirección General de Informática y Telecomunicaciones Centro de Educación y Capacitación para el Desarrollo Sustentable Coordinación General Jurídica Órganos Desconcentrados Comisión Nacional del Agua Instituto Mexicano de Tecnología del Agua Instituto Nacional de Ecología Procuraduría Federal de Protección al Ambiente Comisión Nacional de Áreas Naturales Protegidas Órgano Descentralizado Comisión Nacional Forestal Comisión Intersecretarial Comisión Nacional para el Conocimiento y Uso de la Biodiversidad Responsibilities in Mexico The responsibilities of monitoring mercury in wet deposition is not clearly defined Potential future responsible institutions: Semarnat: Has the principal responsibility CNA: National Water Commission National Meteorological Service (SMN) INE: National Institute of Ecology CENICA Where to install the monitors? Strategy of site selection Far from Mercury point sources in order to measure background levels On or close to the site of already existing meteorological stations or observatories Automatic Hydrometeorological Stations (AHSs)(60) Meteorological Observatories (82) NADP/NTN site selection criteria (modified according to Bigelow et al. 2001) Regional Local On-site Specific Mexican Site selection criteria Accessibility and infrastructure (courier mail service, electricity, telephone, laboratory) An operator lives on or very close to the site Site selection procedure 1st step: Application of regional requirements (20 and 50 km) From the 142 sites (AHS, MO) 108 stations were excluded 2nd step: Application of Mexican requirements (operator) From the AHSs only 16 fulfill the condition of potential operators living close to the site 3rd step: Application of local and on-site requirements (telephone) From these 16 sites only 6 do not fulfill these requirements 4th step: Presence of chemical lab for major ions Among the final 10 stations, only 4 have a chemical laboratory close by 5th step: On-site verification and evaluation of 2 sites Location of the preselected sites Cd. Constitución Huejutla Tecamachalco Puerto Ángel On-site evaluation of Huejutla-site On-site evaluation of Puerto Ángel-site Who will participate? Project Coordination Steering Committee NADP, INE, NACEC (Mercury, M&A Task Forces) Technical Project Management IMTA Equipment and Analysis NADP, Frontier Geosciences among others On-site Institutions Huejutla: SMN-CNA, Instituto Tecnológico Agropecuario (operator Biol. Alejandra López Mancilla) Cd. Puerto Angel: SMN-CNA (operator Ing. Ulises López Rodríguez) Constitución: SMN-CNA (operator Javier Martínez Arreola) Tecamachalco: SMN-CNA, Universidad Tecnológica (operator M.C. Ofelia Araceli López Mejía) Capacity building US / Canadian Institutions Training courses: On-site: Installation, initial sampling phase, maintenance US/Canada: Wet deposition, sampling and maintenance, interpretation of results US/Canada: Clean - Lab analysis On-site supervision: Routine operation and quality control How much will it cost? Costs for an extended, subsidized pilot project (US$) Equipment 9,100 Installation 12,000 Operation 38,220 Capacity building 16,100 Balance, conductance meter and electrode, pH meter and electrodes, lab-material Site preparation and modification, platform, shipping, custom liberation Shipping, personnel, communication, office supply, maintenance and materials Training courses, on-site supervision Analysis 43,680 Mercury (free), methylmercury, major ions Technical project management Personnel, per diem, transportation, telephone Total 67,300 186,400 When may it start? Right now? Heavy rain Steering committee Ing. José Luis Razo Quvedo Ing. Orlando Quintero Martínez Ing. Gloria Herrera Ing. Ángel Barrera Morteo Biol. Alejandra López Mancilla Javier Martínez Arreola M.C. Ofelia Araceli López Mejía Ing. Ulises López Rodríguez