AE447: Short Overview of Plastic Processing Material From Dr. Piyawit Khumphong (MTEC) Outline Extrusion Process Cast Film Blown Film Thermoforming Fiber Spinning Coextrusion Injection Molding Blow Molding Rotational Molding (Processing) (Performance) (Structure) (Property) Extrusion History: 1935 Extruder for thermoplastic was built by Paul Troester in Germany 1965 Entire extrusion process, from the feed hopper to the die, could be described quantitatively To extrude mean to push or force out (from Latin word: extrudere) ~ push out Solid State Extrusion Plasticating Extrusion Melt Fed Extrusion Types of Extruder Single screw extruder Plasticating, Multi stage, Rubber extruders Multi screw extruder Twin screw, Planetary roller extruders Screwless extruder Disk, Drum, Ram extruder Single screw extruder Dia 20-600 mm. (25-150 mm) L/D ratio Vented extruder Rubber extruder Transfermix Multi screw extruder Planetary gear Twin screw extruder Screwless extruder Drum extruder Disk extruder Ram extruder Why Screw ? Screw VS Plunger Ease of temperature control Better melt quality Uniform temperature No unmelt No overheated Energy efficiency Plunger: Conduction + Compression Screw: Conduction + Friction Materials used for extrusion process Practically all thermoplastics Relatively high MW high viscosity and melt strength i.e. PE, PP, PVC, etc. Highly viscous polymer: PTFE, UHMWPE screwless (ram) extrusion Geometry of Conventional Screw Extruder Pitch Flight Flight depth Channel depth Channel width Helix angle Diameters: ID, OD Geometry of Conventional Screw Extruder Flight depth, Channel depth, Channel width Feed Feed: Transition Metering Deep flight, mostly solid state Transition: Channel depth reduce in linear fashion /Compression Metering: Shallow flight, mostly molten state /Pumping Extruder Screw Rapid Compression Vented extruder Rubber extruder Feed: Gravity feed through hopper Screw channel: barrel, screw and screw flight Forward transport by frictional force:Solid state Frictional heat + Barrel heat (conduction) Plasticating (melting) Melt film: barrel surface Metering zone :simply pumped to die Polymer shape: cross-section of die Die head pressure: pressure required to force the material through the die Flow of Plastics Through Extruder barrel 1. drag flow : molten plastic is pushed forward (along screw edges) 2. pressure flow : reverse flow due to high end pressure 3. leak flow : reverse flow over screw edges Drag Flow (result of frictional force) Die Pressure Flow (high end P) Total flow = drag flow - pressure flow - (leak flow) Output as pressure at the end of screw factors: screw geometry, screw speed, barrel Temp, flow of plastics Twin Screw Extruder Profile extrusion of thermal sensitivematerials i.e. PVC Specialty polymer processing i.e compounding, devolatilization, chemical reaction, etc. Advantage over single screw extruder Better feeding and more positive conveying characteristic => can process hard-to-feed materials i.e. powder, slippery materials, etc. Short residence time and narrow RTD Better mixing, larger heat transfer area => good control of temperature. Twin Screw VS Single Screw Type of transport Positive displacement (closely intermeshing) Drag induced - Frictional drag (solid conveying zone) - Viscous drag (melt conveying zone) Velocity pattern Complex difficult to describe Well defined fairy easy to describe Complex Flow Pattern in Twin screw extruder Good mixing Good heat transfer Good devolatilization capacity Good control over stock temperature Large melting capacity Complex Flow Pattern in Twin screw extruder Not well developed theory Difficult to predict performance of a twin screw extruder based on extruder geometry, polymer properties and processing conditions Difficult to predict screw geometry when a certain performance is required in a particular application Modular Design Twin Screw Extruder Removable screw and barrel elements Changing sequence of screw elements along the shaft Co-Rotating and Counter Rotating Intermeshing Self wiping/ Kneading Extrusion Die: Basic Flow Pattern Which is an appropriate die design ? ________________ Why ?? Die Land Criteria in Die Design 1. Maintain laminar flow in the melt (Because change in the die creates ‘Dead Spots’ ---> Uneven Heat and Shear History) Parallel and Converging Flows Streamlines parallel Streamlines converge Shear Tensile + Shear How does Tensile Stress in converging flow affect the die profile design ? Melt Fracture Tensile stress exceeds the tensile strength of the melt ===> Irregular shaped extrudate ‘Melt Fracture’ Criteria in Die Design (cont’d) 2. Die entrance is tapered. 3. Long die land Eliminate dead spots Minimize tensile stress (melt fracture) Maintain steady melt Eliminate process memory (screw turning memory, elastic distortion of flow through the bend) Melt fracture and Process memory are DIE ENTRY phenomena Die Exit phenomena Most common defects 1. Sharkskin: surface rupture due to tensile stress built-up by accelerated velocity at the die wall as the extrudate leaves the die. (high modulus, low elasticity materials easily show sharkskin) Vmax . Vmin Same V 2. Orange peel 3. Bambooing sharkskin condition becomes more intense (excessive pressure, die T drops) Remedy: Extra heating the die thermally relaxing the stress lower viscosity Die Swell • Polymer swells as it leaves the die • This results from elastic recovery of the melt as leaving the die and before cooling. ID OD Die swell in (a) rod and (b) pipe Post-extrusion and products • Rod ----> Pelletization • Profile, Pipe and Tube • Sheets and Films • Filament • Wire and Cable • Coextrusion (Laminates) Pipe Extrusion To produce exact pipe dimension, a sizing mandrel is used. Internal sizing mandrel External sizing a) pressure sizing b) vacuum sizing Profile Extrusion Profile: extruded products other than films, sheet and filament Process optimization - Require equipment to support and shape the extrudate during ooling - 3 important effects: Die Swell Thinning effect of hual-off forces Shrinkage effect of cooling - Allowance must be made in the die design.