CH 3: The Metric System Renee Y. Becker CHM 1025 Valencia Community College 1 The Metric System • The English system was used primarily in the British Empire and wasn’t very standardized. • The French organized a committee to devise a universal measuring system. • After about 10 years, the committee designed and agreed on the metric system. • The metric system offers simplicity with a single base unit for each measurement. 2 Metric System Basic Units 3 SI unit • SI units – In 1960 International System of Units (SI) adopted – This system has 7 SI base units that all other units can be derived from – Metric system is a decimal system • We use SI prefixes • Indicates a power of 10 4 Measurement and Units SI Units Physical Quantity Mass Length Temperature Amount of substance Time Electric current Luminous intensity Name of Unit kilogram meter kelvin mole second ampere candela Abbreviation kg m K mol s A cd 5 Metric Prefixes Unit Symbol Value meter m 1 decimeter dm 10 = 1 x 101 centimeter cm 100 = 1 x 102 millimeter mm 1000= 1 x 103 micrometer m 1 x 106 nanometer nm 1 x 109 picometer pm 1 x 1012 1 kilometer = 1 x103 meter 1 km = 1000 m 6 Measurements and Units • Dimensional-Analysis method uses a conversion factor to express the relationship between units. Original quantity x conversion factor = equivalent quantity Example: express 2.50 kg lb. Conversion factor: 1.00 kg = 2.205 lb 2.50 kg x 2.205 lb = 6.00 lb 1.00 kg Then multiply by the conversion factor Always start with the original quantity 7 Measurements and Units • Remember that anything divided by itself =1 • This is how we can get rid of units!!! They cancel out!! • So remember when setting up dimensional analysis to always divide the units you are trying to get rid of. And multiply by the unit you want to keep! 8 Example 1 • What unit will the answer have for the following? 12 bird x 3 dog x 12 cat = 108 4 bird 1 dog 13 g CO2 x 1 mole CO2 44 g CO2 = .30 56 clowns x 2 doctors x 10 doctors = 3 x 101 12 clowns 3 cops 9 10 Example 2: Metric Conversion a) 1.267 km m cm b) .784 L mL c) 3.67 x 105 cm mm 11 Example 3: English Conversion a) 79 oz lb. b) 9.63 x 10-3 ft in 12 Example 4: Metric-English Conversion a) 1.34 x 1012 in cm b) 4.67 x 10-7 lb g c) 10.5 gal L 13 Example 5: Measurement with Compound Units I am traveling 32 mi/hr, how fast am I traveling in km/hr? 1 mi = 1.61 km 14 Volume by Calculations V=Lxwxh Length, width, and height have to be in the same unit Example: a box has L = 12 cm, w = 42 cm, h = 32 cm • What is the volume of the box? V = L x w x h = 12 cm x 42 cm x 32 cm = 1.6 x 104 cm3 – don’t forget to multiply the units as well as the #’s!!! – If the units are not the same you will have to convert so that they are!! 15 Volumes of Solids, Liquids, Gases 16 Volume by Displacement • How we can find density in the lab!! • If the jade has a mass of 21.3 g what is the density? 17 Gas Volume by Displacement You want to measure the volume of gas given off in a chemical reaction. The gas produced displaces the water in the flask into the beaker. The volume of water displaced is equal to the volume of gas. 18 Density • The density of an object is a measure of its concentration of mass. • Density is defined as the mass of an object divided by the volume of the object. • Density = Mass/Volume • M = DxV • V = M/D 19 Density • Density is expressed in different units. It is usually grams per milliliter (g/mL) for liquids, grams per cubic centimeter (g/cm3) for solids, and grams per liter (g/L) for gases. 20 Density 21 Density • We can estimate the density of a substance by comparing it to another object. • A solid object will float on top a liquid with a higher density. • Object S1 has a density less than that of water, but larger than that of L1. • Object S2 has a density less than that of L2, but larger than that of water. 22 Example 6: Density • What is the density(in g/mL) of unknown substance that has a volume of 20 mL and a mass of 10 g? 23 Example 7: Density • What is the density (in g/cm3) of a platinum nugget that has a mass of 224.50 g and a volume of 10.0 cm3 ? 24 Example 8: Volume • What is the volume (in mL) of an unknown substance if it’s mass is 0.125 g and it’s density is 1.873 g/mL? 25 Example 9: Mass • What is the mass (in g) of an unknown substance if it’s density is 2.578 g/mL and it’s volume is 4.23 mL? 26 Temperature • Temperature is a measure of the average kinetic energy of the individual particles in a sample. • There are three temperature scales: – Celsius – Fahrenheit – Kelvin • Kelvin is the absolute temperature scale. 27 Temperature Temperature Conversions: The Kelvin and Celsius degree are essentially the same because both are one hundredth of the interval between freezing and boiling points of water. 28 Temperature • Temperature Conversions: – Celsius (°C) — Kelvin temperature conversion: Kelvin (K) = °C + 273.15 – Fahrenheit (°F) — Celsius temperature conversions: C = 5/9 (F -32) F = (9/5 * C) + 32 29 Example 10: Temperature Carry out the indicated temperature conversions: (a) –78°C = ? K (b) 158°C = ? °F (c) 375 K = ? °C (d) 98.6°F = ? °C (e) 98.6°F = ? K 30 Temperature Scales • On the Fahrenheit scale, water freezes at 32 °F and boils at 212 °F. • On the Celsius scale, water freezes at 0 °C and boils at 100 °C. These are the reference points for the Celsius scale. • Water freezes at 273K and boils at 373K on the Kelvin scale. 31 Heat • Heat is the flow of energy from an object of higher temperature to an object of lower temperature. • Heat measures the total energy of a system. • Temperature measures the average energy of particles in a system. • Heat is often expressed in terms of joules (J) or calories (cal). 32 Heat vs. Temperature • Although both beakers below have the same temperature (100 ºC), the beaker on the right has twice the amount of heat, because it has twice the amount of water. 33