AP CHEMISTRY- REVIEW Review1 UNCERTAINTIES REVIEW As part of your Lab Group. Analyze the following data. Mass of beaker: 7.15 g +/- 0.01 g Mass of beaker + metal: 12.12g +/- 0.01 g Height of cube: 2.12 cm +/- 0.01 cm Width of cube: 1.05 cm +/- 0.01 cm Length of cube: 0.75 cm +/- 0.01 cm Calculate the density of the cube with uncertainty. Given the theoretical density as 2.65 g/cm3 Find the % error and Discuss which type of error is more significant. CONVERSIONS A mole of anything is equal to 6.02 x1023 1 mole of an element is equal to its molar mass. So 1 mole of Carbon = 12g of C= 6.02x1023 atoms of C Convert 875 grams of C to atoms of carbon? Convert 3.156x1022 atoms of C to grams of C? MOLAR MASS Molar mass is the mass of one mole of an element or compound. If its an element we can find the molar mass by looking at the atomic mass of that element. Example, N-14 g If it’s a compound we must calculate it by multiplying the number of atoms times each atomic mass. Example. Find the molar mass of Ca3(PO4)2 3 (Ca) + 2(P) + 8 (O) 3 (40) + 2 (31) + 8 (16) 120 + 62 + 128 = 310 g COVALENT COMPOUNDS Covalent compounds exist as molecules. They are made up of nonmetals atoms. Water: H2O is made up of atoms of hydrogen and oxygen, both nonmetals. So it’s a covalent compound and exists as molecules. 1 mole of water = 6.02 x1023 molecules and each molecule contains 3 atoms. Two of hydrogen and one of oxygen. Calculate the number of molecules in 45 grams of C2H6 COVALENT NOMENCLATURE In naming covalent compounds , you must use prefixes to identify the number of each atom in the formula. You never reduce. First element keep its name, second ends in ide. Prefixes: 1= mono 6= hexa The prefix mono is not usually used for the first element. Carbon Dioxide= CO2 Dichlorine tetraoxide = ? 2= di 3= tri 4= tetra 5= penta 7= hepta 8= octa 9= nona 10= deca Disulfur Dichloride= S2Cl2 IONIC COMPOUNDS These are compounds formed when metal atoms combined with nonmetal atoms or polyatomic ions. What are polyatomic ions? 1 mole of an ionic compound is equal to 6.02 x1023 Formula units. ( fu’s) Sodium Chloride- NaCl- is an ionic compound and one mole of sodium chloride is equal to 6.02 x10 23 fu. Each fu is made up of two atoms, one of Na and one of Cl. Calculate how many atoms are found in 285 grams of CaCl2 POLYATOMIC IONS Nitrate Acetate Carbonate Ammonium Cyanide NO3-1 C2H3O2-1 CO3-2 NH4+1 CN-1 Phosphate Sulfate Chlorate Hydroxide Peroxide - ite ending = one oxygen less than ate Hypo---ite= one oxygen less than ite Per-----ate= one oxygen more than ate What’s the formula for: Hypochlorite Persulfate PO4-3 SO4-2 ClO3-1 OH-1 O2-1 IONIC FORMULAS Find the charges of each ion, cross them and reduce if possible Aluminum Nitride Al+3 N-3 Al3N3 AlN Sodium Phosphate Na+1 PO4-3 Na3PO4 Some metals like Copper have more than one charge, thus we use Roman numbers to identify them Copper I = Cu+1 Copper II= Cu+2 Lead II, Lead IV Iron II, Iron III Tin II, IV Many of the transitional metals have multiple charges. The ones above, you MUST know. Zinc is always +2, Silver is always +1 ASSIGNMENT 1. Convert the following: Show set up A) 1.15 grams of gold to atoms B) 2.85 grams of Aluminum oxide to atoms C) 0.88 grams of Carbon Dioxide to molecules D) 2.805 x1018 molecules of water to grams E) How many formula units of Calcium Sulfite in 888 grams. 2. Write the formulas for the following compounds A) Copper I acetate F) Disilicon trioxide B) Zinc Sulfide G) Lead IV Chromate C) Dinitrogen hexaoxide H) Magnesium peroxide D) Iron III Perphosphate I) Calcium Hypochlorite E) Silver nitrate J) Sulfur Dioxide