Professor’s eyes only… You may be surprised to learn… …that over 25% of all undergraduate students do not utilize their required course material. …student retention is dropping nationwide and while the higher education community has done a remarkable job of opening the doors of college to more and more students, we have not seen equal strides in the number of students who actually complete four-year degrees. (Education Trust, 2004) See the next slide on what you can do… Professor: Course/Section: Professor’s eyes only… What you can do… • The top factors motivating a student to use their adopted books all involve whether the material is immediately used, referred to, or assessed from in the classroom. • Please take a few minutes the first day of class to explain and demonstrate why you adopted your book and accompanying technology. • The next few slides show the book, technology products, and messaging to students that indicates they will be responsible for the content. Feel free to customize the information or delete from your slide set. Professor: Course/Section: Solomon/Berg/Martin Biology, 8e This is your required course material You will need this material for: - tests and quizzes - homework and reading assignments Professor: Course/Section: Some of the reasons why you need to use the new edition… • Based on instructor and student feedback, text and illustrations throughout this edition have been extensively revised, honed, and reorganized. • Would you like to monitor your progress quickly and easily? Track your progress with ease using innovative resources like ThomsonNOW Foremost is a self-assessment diagnostic tool--ThomsonNOW for Biology-with automatic grading, which saves you time and helps you learn concepts more efficiently. Professor: Course/Section: ThomsonNow for Biology is a powerful online learning tool that helps you assess your unique study needs, and available with each new copy of Solomon/Berg/Martin’s Biology, 8e. • On-line assessments/exams • Animations/interactivities • Point-of-use eBook study less, learn more! Personalized Study How Do I Prepare? InfoTrac College Edition • Do your research 24/7! • Easy access to over 10 million full-text articles • Nearly 5000 academic journals, magazines, and periodicals. • Do your research from home, work, or your dorm room! • InfoTrac can be used for ALL of your courses! • Includes InfoWrite, a web-based training tool designed to help you develop your writing skills. Professor: Course/Section: HOW TO SEARCH THE DATABASE There are 3 ways to search: Subject Guide Keyword Search Advanced Search There is also a Limit Search function, which limits the search by date, journal, or keyword. IT’S EASY TO SEARCH BY SUBJECT OR KEYWORD! STEP 1 STEP 2 STEP 3 Type in a subject or keyword. Click on View to see search results, or click on Narrow to narrow down the search. Once the article is located, click on the title to view. INFOWRITE InfoTrac College Edition, your Online Research and Learning Center, includes InfoWrite, a web-based training tool designed to help you develop your writing skills. InfoWrite offers the following benefits: • Facilitates the writing process • Assists with the organization and presentation of ideas • Helps you articulate key concepts • Improves grammar, spelling and correct word usage • Aids your creativity Also included: • Critical Thinking with InfoTrac • APA vs. MLA documentation style • Essay Topics • Research and the Internet …and much more! • On-line live tutoring from biology experts! Professor: Course/Section: Essential Study Skills for Science Students Written specifically for science students, this book discusses how to develop good study habits, sharpen memory, learn more quickly, get the most out of lectures, prepare for tests, produce excellent term papers, and improve critical-thinking skills. Buy ISBN # 0534375952 • Your book may come with an access card for Biology’s e-resources. Access your e-Resources • Go to www.thomsonedu.com • Create or sign into your Thomsonedu account. • Enter the access code found in the card. Access your e-Resources • You should now have access to your e-resources for Biology. To access resources in ThomsonNOW, click on the ThomsonNOW link. Access your e-Resources • First-time users: Set up your ThomsonNOW account. It will link up to your Thomsonedu account. Enter Your School Name New ThomsonNOW Account Student Homepage Enter a Course Key Students Please Read… If your textbook doesn’t already come with the helpful study aids we’ve discussed, go to your local college bookstore or go on-line to the textbook URL … http://www.thomsonedu.com/biology Professor: Course/Section: Atoms and Molecules: The Chemical Basis of Life Chapter 2 Learning Objective 1 • What principal chemical elements are found in living things? • What are the most important functions of these elements? Element • A substance that cannot be decomposed into simpler substances by normal chemical reactions The Periodic Table KEY CONCEPTS • Carbon, hydrogen, oxygen, and nitrogen are the most abundant elements in living things (about 96% of mass) Element Functions • Carbon • • Hydrogen and oxygen • • backbone of organic molecules components of water Nitrogen • component of proteins and nucleic acids Learning Objective 2 • Compare the physical properties (mass and charge) and locations of electrons, protons, and neutrons • What is the difference between the atomic number and the mass number of an atom? Atom • Nucleus protons (positive) • neutrons (uncharged) • • Electrons encircle the nucleus • negative • Atomic Number and Mass • Each atom is a particular element • • identified by number of protons (atomic number) Atomic mass • sum of protons and neutrons AMU • Atomic Mass Unit • • Mass of a single proton or neutron Mass of an electron • about 1/1800 amu Isotopes Carbon-12 (126 C) (6p, 6n) Carbon-14 (146 C) (6p, 8n) Fig. 2-2, p. 28 Learning Objective 3 • What are orbitals and electron shells? • How are electron shells related to principal energy levels? KEY CONCEPTS • Chemical properties of an atom are determined by its highest-energy (valence) electrons Orbitals • Electrons move rapidly in electron orbitals • • Outside the nucleus Electron shell Electrons in orbitals at the same principal energy level • Electron in shell far from nucleus has more energy than electron in shell close to nucleus • Atomic Orbitals Nucleus (a) The first principal energy level contains a maximum of 2 electrons, occupying a single spherical orbital (designated 1s). The electrons depicted in the diagram could be present anywhere in the blue area. Fig. 2-4a, p. 30 (b) The second principal energy level includes four orbitals, each with a maximum of 2 electrons: one spherical (2s) and three dumbbell-shaped (2p) orbitals at right angles to one another. Fig. 2-4b, p. 30 (c) Orbitals of the first and second principal energy levels of a neon atom are shown superimposed. Note that the single 2s orbital plus three 2p orbitals make up neon's full valence shell of 8 electrons. Compare this more realistic view of the atomic orbitals with the Bohr model of a neon atom at right. Fig. 2-4c, p. 30 Learning Objective 4 • How does the number of valence electrons of an atom relate to its chemical properties? Valence Electrons • Electron in the outer shell • • most energetic electrons Number and arrangement of an atom’s valence electrons • determine its chemical properties Valence Electrons • An atom tends to lose, gain, or share electrons to fill its valence shell • Electrons needed to fill valence shell Most atoms: 8 electrons • Hydrogen or helium: 2 electrons • Learning Objective 5 • What is the difference between simplest, molecular, and structural chemical formulas? Compounds • Atoms are joined by chemical bonds to form compounds • A chemical formula gives the types and relative numbers of atoms in a substance Chemical Formulae • Simplest formula • • Molecular formula • • smallest whole-number ratio of component atoms actual numbers of each type of atom Structural formula • the arrangement of atoms in a molecule KEY CONCEPTS • A molecule consists of atoms joined by covalent bonds • Other important chemical bonds include ionic bonds and hydrogen bonds Learning Objective 6 • Why is the mole concept so useful to chemists? Avogadro’s Number • Avogadro’s number 6.02 x 1023 • One mole (atomic or molecular mass in grams) of any substance contains 6.02 x 1023 atoms, molecules, or ions • Enables scientists to “count” particles by weighing a sample Learning Objective 7 • What is the difference between covalent bonds, ionic bonds, hydrogen bonds, and van der Waals interactions? • How does each differ in the mechanisms by which they form and in relative strength? Covalent Bonds • • • • Strong, stable bonds Formed when atoms share valence electrons Form molecules May rearrange the orbitals of valence electrons (orbital hybridization) Covalent Bonds H H Hydrogen (H) Hydrogen (H) Molecular hydrogen (H2) or H H (a) Single covalent bond formation. Two hydrogen atoms achieve stability by sharing a pair of electrons, thereby forming a molecule of hydrogen. In the structural formula on the right, the straight line between the hydrogen atoms represents a single covalent bond. Oxygen (O) Oxygen (O) Molecular oxygen (O2) or (double bond is formed) O O O O (b) Double covalent bond formation. In molecular oxygen, two oxygen atoms share two pairs of electrons, forming a double covalent bond. The parallel straight lines in the structural formula represent a double covalent bond. Fig. 2-5, p. 32 Nonpolar and Polar Covalent Bonds • Covalent bonds are nonpolar if electrons are shared equally between the two atoms • polar if one atom is more electronegative (greater electron affinity) than the other • Ionic Bonds • Form between a positively charged cation and a negatively charged anion • Are strong in the absence of water but relatively weak in aqueous solution Ionic Bonds 11 protons 17 protons and 11 electrons Sodium (Na) 17 electrons Chlorine (Cl) + – 10 electrons 18 electrons Sodium ion (Na+) Chloride ion (Cl–) Sodium chloride (NaCl) Fig. 2-9a, p. 35 Hydrogen Bonds • • Relatively weak bonds Form when A hydrogen atom with a partial positive charge • Is attracted to an atom (usually O or N) with a partial negative charge • Already bonded to another molecule or part of the same molecule • Hydrogen Bonds Electronegative atoms – + O H H N H H Hydrogen bond H Fig. 2-11, p. 35 KEY CONCEPTS • Hydrogen bonds and van der Waals interactions are weak attractions van der Waals interactions • Weak forces • Based on fluctuating electric charges Learning Objective 8 • What are oxidation and reduction reactions? • How do oxidation and reduction reactions relate to the transfer of energy? Redox Reactions • Oxidation and reduction reactions • Electrons (energy) are transferred from a reducing agent to an oxidizing agent Oxidation and Reduction • Oxidation • • Atom, ion, or molecule loses electrons (energy) Reduction • Atom, ion, or molecule gains electrons (energy) KEY CONCEPTS • The energy of an electron is transferred in a redox reaction Learning Objective 9 • How do hydrogen bonds between adjacent water molecules govern the properties of water? Polar Molecules • Water is a polar molecule • One end has a partial positive charge and the other has a partial negative charge • Because it is polar, water is an excellent solvent for ionic or polar solutes Polar Molecules Oxygen part Partial negative charge at oxygen end of molecule Hydrogen (H) Oxygen (O) Hydrogen (H) Water molecule (H2O) Hydrogen parts Partial positive charge at hydrogen end of molecule Fig. 2-7, p. 34 Oxygen part Partial negative charge at oxygen end of molecule Hydrogen (H) Oxygen (O) Hydrogen (H) Water molecule (H2O) Hydrogen parts Partial positive charge at hydrogen end of molecule Stepped Art Fig. 2-7, p. 34 Cohesion and Adhesion • Water molecules exhibit cohesion because they form hydrogen bonds with one another • Water molecules exhibit adhesion by hydrogen bonding to substances with ionic or polar regions Hydrogen Bonds in Water Specific Heat • • • Water has high specific heat Hydrogen bonds must break to raise water temperature Specific heat of water helps organisms maintain relatively constant internal temperature • keep large bodies of water (ocean) at a constant temperature • Heat of Vaporization • Water has a high heat of vaporization • Hydrogen bonds must break for molecules to enter vapor phase • Molecules carry heat, causing evaporative cooling Ice • Hydrogen bonds between water molecules make ice less dense than liquid water • Because ice floats, the aquatic environment is less extreme Three Phases of Water KEY CONCEPTS • Water molecules are polar, with partial positive and negative charges • Form hydrogen bonds with one another and other charged substances Learning Objective 10 • What is the difference between an acid and a base? • What are the properties of acids and bases? Acids and Bases • Acids proton (hydrogen ion, H+ ) donors • dissociate in solution to yield H+ and an anion • • Bases proton acceptors • dissociate in solution to yield hydroxide ions (OH-) • KEY CONCEPTS • • • Acids are hydrogen ion donors Bases are hydrogen ion acceptors The pH scale measures the hydrogen ion concentration of a solution Learning Objective 11 • How does the hydrogen ion concentration (moles per liter) of a solution relate to its pH value? • How do buffers help minimize changes in pH? pH • The negative log of the hydrogen ion (H+) concentration of a solution (measured in moles per liter) pH of Solutions • Neutral solution equal concentrations of H+ and OH• (10 -7 mol/L), pH 7 • • Acidic solution • • pH less than 7 Basic solution • pH greater than 7 Buffers • Buffering system • • based on a weak acid or a weak base Buffer • resists changes in pH of a solution when acids or bases are added Learning Objective 12 • What is the composition of a salt? • Why are salts are important in organisms? Salts • Salt • • a compound in which the hydrogen atom of an acid is replaced by some other cation Salts provide many mineral ions essential for life functions How Atoms Bond CLICK TO PLAY Spheres of Hydration CLICK TO PLAY The pH Scale CLICK TO PLAY The Shell Model of Electron Distribution CLICK TO PLAY