Tracer vs. Pressure Wave Velocities Through Unsaturated Saprolite Todd C. Rasmussen Associate Professor of Hydrology The University of Georgia, Athens www.hydrology.uga.edu Configuration for Intact Saprolite Column Saprolite surface TDR probe Tensiometer TDR probe Suction lysimeter TDR probe Tensiometer TDR probe Suction lysimeter TDR probe Tensiometer TDR probe Ceramic plate Depth (cm) 0 4 7 10 13 16 19 22 25 28 31 34 38 Representative Saprolite Properties Particle sizes sand = 0.66 g/g silt = 0.21 g/g clay = 0.13 g/g Bulk density 1.25 g/cm3 Porosity 0.5283 cm3/cm3 Field saturated K Lab saturated K 25.1 cm/day 27.3 cm/day Chloride Tracer Responses - Columns 1 and 2 - 1 2 z cm 13 25 13 25 38 days 2.17 7.99 3.50 9.89 18.64 v cm/d 6.00 3.13 3.72 2.53 2.04 ne % 3.8 7.3 5.9 8.7 10.8 Possible Explanations for Rapid Unsaturated Transport • • • • • • Preferential flow Bypass flow Macropore flow Fracture flow Boundary layer flow Mobile zone flow • • • • • Finger flow Funnel flow Media heterogeneities Ion exclusion Colloid transport Experimental Findings • A large saprolite core was used for an unsaturated flow and Cl- tracer experiment • The tracer traveled four times more quickly than homogeneous flow predicts • Unsaturated conditions were maintained using short irrigation pulses, 0.6 cm3/s • The pressure pulses traveled 1000 times more rapidly than expected. Irrigation Schedules ID Spray† Interval sec min # Duration Flux hours cm/day 1 A B 5 5 40 20 9 18 6 6 0.229 2 A B 5 5 40 20 18 29 12 9.67 0.221 † Spray rate = 0.6 cm3/s ID 3 A1 A2 A3 A4 A5 B1 B2 B3 B4 B5 C1 C2 C3 C4 Duration sec 2 2 2 2 2 1 1 1 1 1 3 3 3 3 Interval # min 10 20 30 60 120 10 20 30 60 120 20 40 60 120 6 3 2 1 1 6 3 2 1 1 3 3 1 1 Duration Flux hours cm/day 1 1 1 1 2 1 1 1 1 2 1 2 1 2 0.071 Types of Velocities • Darcian flux (velocity) – q = - K h • Fluid (transport) velocity –v=q/ • Kinematic (pressure wave) velocity – c = dq / d Unit Gradient Formulation h = [0, 0, -1] • Darcian flux: q=K • Fluid velocity: v=K/ • Kinematic velocity: c = dK / d • Kinematic ratio: k=c/v = d (ln K) / d (ln ) Moisture Characteristic Curves Brooks - Corey = 0.6465 6 van Genuchten = 0.6465 [ 1 - (1 - 7)0.1430]2 Broadbridge-White = 52 { 1 - 1/ - ln [ (10.3 - ) / (10.3 - 1) ] / 10.3 } where = ( - r ) / (s - r ) is the relative saturation Advection Dispersion Equation for Pressure Waves • • • • is the fluid pressure head c = dK / d is the kinematic wave velocity D = K / Cp is the hydraulic diffusivity Cp = d/d is the specific water capacity Pressure Response to Spike Input • Co is the magnitude of the input Peak Wave Velocity • w is the wave peak velocity • tp is the time of peak at depth z • = c z / D is the hydraulic Peclet Number Effect of Hydraulic Peclet Number • << 1 is dominated by diffusion • >> 1 is dominated by a kinematic wave Fluid Pressure Responses - Column 3 z cm p cm tp min w cm/d D cm2/d 7 17 24 34 15.28 9.91 5.94 2.35 5.08 6.75 9.42 18.17 1,983 3,627 3,670 2,695 2,314 10,276 14,680 15,272 Cp cm-1 30.7e-6 6.9e-6 4.8e-6 4.6e-6 Conclusions • The effective transport porosity of saprolite is less than the total porosity – This leads to at least a four-fold increase in the solute velocity relative to that predicted by homogeneous flow • The pressure wave velocity is even faster, about 1000 times greater than the darcian flux – A hydraulic advection-diffusion equation closely predicts observed pressure responses – The best fit occurs with a small specific water capacity, Cp = d / d Implications • Solute Transport: – Consistent with other studies, saprolite from the Georgia Piedmont shows preferential solute transport – Use of the total porosity to predict solute transport underestimates solute travel times • Fluid Pressure: – Rapid pressure waves are associated with surface perturbations – These have attributes of displacement (piston) flow – Use of pressure responses overestimates solute travel times Unsaturated Fractured Rock Hydraulic Properties Galileo Number • Dimensionless number, ratio of two forces: Hydraulic Conductivity • The unsaturated hydraulic conductivity is: • and the saturated hydraulic conductivity is: • which is just the Kozeny-Carman Equation