Unit 12 Acids and Bases Chapter 19 Lesson 1 – Acids and Bases Arrhenius’ Definition Acids give _________________when dissolved in _______________________ Bases give _________________when dissolved in _______________________ Acid or Base? The measure of the __________________ of _________ ions in a solution is called _____________ The _________________ measures how _____________ or ______________ a solution is The scale ranges from _______ to ________. _______ = extremely strong acid Properties of Acids Affects the color of ____________________ _____________ with metals to produce ________________gas. Metal + Acid ____________________________ of bases to form water. Acid + Base Taste ____________ Strong and Weak Acids Strong acids will _________________ _______________________. (all of molecules become ions) HCl(aq) + H2O(l) H3O+(aq) + Cl-(aq) Weak acids do not ________________________________ easily. (only a few molecules become ions) HC2H3O2(aq) + H2O(l) H3O+ (aq) + C2H3O2 - H3O+ = _____________________ (same as ___________) Strong Acids (need to know!) Hydrochloric acid Hydrobromic acid Hydroiodic acid Nitric acid Sulfuric acid Chloric acid Perchloric acid ______ = extremely strong base Weak Acids Carbonic acid Acetic acid Citric acid Mono and Polyprotic Acids Monoprotic Acids Mono = _________________ These acids donate ________________ (per molecule) when they ______________________ HCl HNO3 Polyprotic acid Poly = ____________________ These acids donate ____________________ one H+ (per molecule) when they dissociate Polyprotic acids ionize in ______________________. H2S H3PO4 Properties of Bases Affects the color of _____________________ Neutralization of ______________________ to form water. Acid + Base Taste _____________________ Strong and Weak Bases Strong bases: Group 1a: Group 2a: yield ________________ in solution Feel _____________________ Weak bases _________ _____________ dissociate in solution, they just __________________ a H+ Examples: Bronsted-Lowry Definition Acids are any substance that can ______________________ an _________ Bases are any substance that can ____________________ accept an __________ Example Conjugate Pairs Reversible reactions have an _______________and _________________ on both sides Pairs that differ by only ________ ________________ (___________) are called conjugate pairs A ____________ acid will make a weak _____________________ base A ______________ acid will make a strong _____________________________ base. Same for ________________and __________________ bases. What about H2O? Acid or Base? Water is ___________________________ which means a substance can either ______________________ a proton (base) or _______________________ a proton (acid). Water will act as a _________________ when in solution with ______________________ Water will act as a _________________ when in solution with ______________________ Lesson 2 – pH and pOH pH Low pH = __________________ pH = _______________ of _______________________ Power is the ________________ power, as in 10 to the second power = _____________________ [H+] = _________________________of ______________ ion (molarity) The __________________ the concentration, the stronger the acid, the _____________________ the pH [H+] = Solving for pH: pH = pH examples What is the pH of a solution if the H+ concentration is 3.4 X 10-3 M? What is the H+ concentration of an acid with a pH of 3.0? pOH Low pOH =_____________________________ pOH =measure of ____________ ion concentration pOH is __________________________ from ____________ [OH-] = ______________________________of ____________ ion (molarity) The higher the concentration, the stronger ___________________, the lower the _______________ [OH-] = Solving for pOH: pOH = pOH Examples What is the pOH of a solution if the OH- concentration is 3.4 X 10-6 M? What is the OH- concentration of a base with a pOH of 2? pH and pOH pH is a measurement of the __________________ pOH is a measurement of the ________________ pH = __________________ pOH = ____________________ pH and pOH must equal _____________________________ pH + pOH = ___________ can be found when you know ____________and vise versa In _________________ water, pH and pOH are ____________ All aqueous solutions have a ___________and a ________________. Example If [H+] = 1.0 x 10-7 M, then what is the pH? Example If the [OH-] is 5.01 x 10-4 M, what is the pOH? Sample Problem In household bleach, the concentration of OH- ions is 5.0 x 10-2 M. What is the pH? Lesson 3 – Titration/Neutralization Neutralization _______________ + ___________________ __________ + ____________ Water is formed when the _____________ from the acid contacts the _________________ from the base. __________________is an ____________________ compound formed from the other parts of the acid and base. Terms ____________________ is a lab technique used to determine the ___________________________of an ___________ or ________________. _____________________ is when the number of moles of ____________________ _________ equals the number of moles of _______________________ ____________. This does ________necessarily mean pH is ______________, as the salt may _____________ the pH of the solution ________ ___________________is when the _____________________changes colors. (Meaning the solution has changed from ______________________ to _________________________) Indicators An indicator is a chemical that _______________ _______________ at a __________________ _______. Many indicators are a mixture of many chemicals. Some are found naturally Steps for Titrations 1. A measured volume of an ____________ or __________ solution of an ___________________ concentration is placed in a flask 2. Several drops of _______________________ are added to the flask 3. Measured volumes of a ___________________ (or acid, if a base is in the flask) of ______________ concentration (_____________ solution) are placed in a ______________ and slowly added into the acid until the indicator _____________________. Lab Example Phenolphthalein indicator is clear in _______________ and pink in ________________. The endpoint is when __________extra drop of _________________ is added after equivalence is reached, changing the indicator color. Titration The ________________ of an unknown solution can be determined _______________ (unknown solution) added from a ___________ ___________________are chemicals added to help determine when a reaction is complete The __________________ of the titration occurs when the reaction is complete This is also known as the __________________ ________________ – the point in the titration when the number of moles of _________ added _____________ the number of moles of ___________ originally in solution Plotting a Titration Curve Neutralization Calculations If the number of moles of __________ = moles of __________, you can use ___________________ to find the ______________ of the unknown Example - A 43.0 mL volume of NaOH was titrated with 32.0 mL of 0.100 M HCl. sodium hydroxide solution? Step 1: how many moles of HCl were needed? Step 2: How many moles of H are in each mole of the acid? Step 3: Moles H+ = Moles OH- What is the molarity of the Step 4: How many moles of OH are in each mole of base? Step 5: calculate Molarit Example A volume of 50.0 mL of 1.20 M H3PO4 neutralizes 45.5 mL of a Ca(OH)2 solution. Ca(OH)2 solution? What is the molarity of the Neutralization Calculations (quicker) The same formula as dilutions: ___________________ are for the ______________________solution _____________________ are for the _________________ solution ___________________are the coefficients from the ____________________________________. *You must have a ___________________________________________ for this to work! Example Solutions of sodium hydroxide (NaOH) are used to unclog drains. A 43.0 mL volume of NaOH was titrated with 32.0 mL of 0.100 M HCl. What is the molarity of the sodium hydroxide solution? Sample Problem A volume of 25. mL of 0.120 M H2SO4 neutralizes 40. mL of a NaOH solution. NaOH solution? What is the concentration of the Lesson 3 – Salt Hydrolysis A salt is an _________________ ___________________________ that: comes from the ____________________________ of an acid; comes from the ____________________________ of a base; is formed from a ________________________________reaction; some neutral; others ________________ or _____________________. “Salt hydrolysis” - a ____________________that reacts with water to produce an ______________ or ___________________. Salt Hydrolysis Hydrolyzing salts usually come from: a strong acid + a weak base = a weak acid + a strong base = A strong acid + a strong base = a weak acid + a weak base = “Strong” refers to the __________________ of ___________________________ Strong Acids Strong Bases Salt Hydrolysis To see if the resulting salt is ____________ or ____________, check the ________________ formed it. Practice on these: HCl + NaOH H2SO4 + NH4OH H2S+ KOH acid or base that