Name: Katelyn Leffel School/Grade Level/Course/Coop Teacher: Silver Bluff High School, 10th-11th Grade, Mr. McKenzie Topics of Your Lessons: Stoichiometric Conversions Lab Brief Description of Your Lessons: The objective of this lesson was to use mathematical and computational thinking to predict the amounts of reactants required and products produced in specific chemical reactions. Therefore the focus of assessment should be for students to construct, use and manipulate appropriate metric units, express relationships between variables for models and investigations, and use grade-level appropriate statistics to analyze data to calculate the limiting and excess reactants in chemical reaction. Standards: Content Standard 12: Students shall understand the relationship between balanced chemical equations and mole relationships. S12 C.4 - Calculate stoichiometric quantities and use these to determine theoretical yields. S13 C.1 - Apply the mole concept to calculate the number of particles and the amount of substance: Avogadro’s constant = 6.02×1023 S13 C.2 - Determine the empirical and molecular formulas using the molar concept: molar mass, average atomic mass, molecular mass, and formula mass What Worked: The students worked well together in their lab groups and displayed creativity and enthusiasm towards the activity. When the students found out that they would get to chew gum, and light a candle on fire they were all ecstatic. Each student participated throughout the whole lab activity, and asked plenty of questions. The activity was effective at students remembering the significance of atomic mass and identified mole ratios of reactants and products from balanced chemical equation. The students were be able to perform stoichiometric calculations related to chemical equations. What Would You Do Differently Next Time: Next time, I would review chemicals and chemical reactions that are used in commercial or industrial environments. Chemistry has changed from hit and miss calculations of a product to exact amounts being calculated for an industrial product. I would discuss with the students more background of the mole and its influence on chemistry with reference to commercial or industrial production. MOLE LAB 2 Candidate Name: Katelyn Leffel Honor Pledge: On my honor as a University of South Carolina Aiken student, I have completed my work according to the principle of Academic Integrity. I have neither given nor received any unauthorized aid on the assignment / examination. Signature Date ___________________ Subject Area: Chemistry CP Grade Level: 10th-11th Date Lesson to be Taught: March 12th, 2015 Time Frame/Duration: 55min Standards: S13 C.1 - Apply the mole concept to calculate the number of particles and the amount of substance: Avogadro’s constant = 6.02×1023 S13 C.2 - Determine the empirical and molecular formulas using the molar concept: molar mass, average atomic mass, molecular mass, and formula mass ● Common Core ● South Carolina Content ● other Learning Objective(s): Students shall understand the relationship between balanced chemical equations and mole relationships. Essential Question(s): How do I convert among the number of particles, moles, and the mass of a given substance? Number of Students: 20 Grouping: Students will be arranged in groups of 2 or 3. Accommodations for special needs: N/A Differentiation: N/A Materials/Resources Provide an itemized list of materials and the number required including... (Stimuli): Student materials/resources: ● Calculator ● Crayon ● Chalk ● Balance/Scale ● Aspirin ● Wood ● Aluminum Foil ● Educational Technology: A power point slide with warm up questions (see attachments). No technology is required for this lesson other than a calculator for use in calculations. Students should already have Previous Knowledge 7.P.2B.4 (Physical and Chemical Changes) 7.P.2B.5 – (Law of Conservation of Matter). Safety Issues/Concerns: No roughhousing in lab ever! Lesson Procedures: Time (min) 5 Lesson Phase Introduction Engage 5-10 Foundation 5-10 Engage Brain Activation Explore 5-10 Body of New Information 5-10 Explore Clarification Elaborate Teacher materials/resources: ● Mole Lab Worksheet ● PowerPoint Outline ● Alternate Individual Worksheet ● Assessments ● Chemistry and Matter Textbook ch. 11 ● (all copies of documents needed are attached) Details A power point slide should be up on the board when students enter class with bell ringer questions for students to answer (PowerPoint Slide 1). Allow students 5 minutes to completely answer questions. (Use this time to take attendance, and pass out Mole Lab worksheet. Review answers students wrote down for their bell ringer. (Slide 2) Ask Students Questions Review the Key terms and Steps of conversion. (Slide 3) Ask students to practice molar mass conversions (Slide 4). Introduce Mole Lab 2 Worksheet Review Procedures and Safety Concerns. (These can be found on the lab worksheet). Inform students that should any one of them at anytime are in violation of lab safety procedures and protocol they will not be allowed to participate in lab, and have an alternate worksheet to complete independently at their desks, that they will have to turn in by the end of class. If students have questions they should ask now, otherwise get into their groups and begin lab. 20-25 Mole Lab Evaluate 5-10 Summative Evaluate 5 Closure Evaluate As students begin to work on their lab float around the room to make sure everyone is following the correct procedures and safety precautions. 5-10 minutes before class is over ask students to return to seats to review PowerPoint summative questions. Discuss what answers each group got as a class. Students should have lab areas cleaned up. Lab worksheet with completed calculations and analysis are due tomorrow at the beginning of class. Once classroom is cleaned, and set up for the next class students may exit. Suggested Assessments: Diagnostic (Pre-) Assessment(s): Bell Ringer Assignment Formative Assessment(s): ): Independent Analysis of data/class discussion. Summative (Post-) Assessment(s): Lab Analysis Follow-up: If students are not able to comprehend the information learned in today’s lab, that’s okay. They should still try to answer the questions the best that they can. The lesson planned for the next day involves a review of information students have learned in chapter 11 so far at the beginning of class. Reference(s): Dingrando, L. (2002). Chemistry: Matter and change. New York, N.Y.: Glencoe/McGraw-Hill. Power Point Slide Outline Slide 2: Question 1 1. How many mole ratios can be written for the following reaction? 4H2(g) + O2(g) → 2H2O(l) 2. The mass in grams of 1 mol of any pure substance is equal to what? 3. Molar mass is used to convert what? Slide 3: Answer 1. 6 2. The Molar Mass 3. mass to moles Slide 4: Pre-Lab Practice Numbers we can use to do conversions with: 1mole = 6.022 x1023atoms = atomic mass(g) A. Convert 2.5mol K to mass. B. How many moles of Sn are in 800g? Slide 5: Pre-Lab Practice Using molar mass in conversions: For a compound 1mol = 6.022x1023 molecules = molar mass(g) Convert 4.5x1018 molecules to mass Name ___________________________________________ Date_________________ MOLE LAB Safety Preclusions: If students are seen rough housing, or not following correct lab safety, they will be excused from lab and will receive an alternate worksheet to work on individually at their desks. This worksheet should show all student work, and be turned in by the end of class. Procedure Part 1: Molecules in your name 1. Find the mass of a crayon. 2. Write your full name on a piece of paper. 3. Find the mass of the crayon again. Substance Mass (g) before Mass (g) after Mass(g) Used Crayon- C25H52 Chalk a. Find the molar mass of the crayon. (Made of wax-C25H52) Show your work. b. How many moles of wax were in your name? Show your work. c. How many molecules of wax were in your name? Show your work d. Find the molar mass of the chalk. (CaSO4) (Did you know chalk isn’t made from chalk anymore!!!) e. How many moles of chalk were in your name? Show your work f. How many molecules of chalk were in your name? Show your work g. You should have used approximately the same mass of crayon and chalk when writing your name. Why were there LESS molecules of chalk used than crayon? Procedure Part 2: Measure the items and fill in the chart below. Substance Mass (g) Molar Mass (g/mol) # of moles Aspirin (C9H8O4) Wood (CH2O) Al Foil (Al) 1. A substance has a mass of 90.1 grams and contains 3.0 x 1023 molecules. Which of the 3 substances in the chart above is it? (Solve for moles first using the molecules given, then set up a ratio to find g in 1 mole.) Show your work Stoichiometry Worksheet (Individual Work if excused from lab) Show all work 1. Given the following equation: 2 C4H10 + 13 O2 ---> 8 CO2 + 10 H2O, show what the following molar ratios should be. a. C4H10 / O2 b. O2 / CO2 c. O2 / H2O d. C4H10 / CO2 e. C4H10 / H2O 2. Given the following equation: 2 KClO3 ---> 2 KCl + 3 O2 How many moles of O2 letting 12.00 moles of KClO3 react can produce? 3. Given the following equation: 2 K + Cl2 ---> 2 KCl How many grams of KCl is produced from 2.50 g of K and excess Cl2. From 1.00 g of Cl2 and excess K? 4. Given the following equation: Na2O + H2O ---> 2 NaOH How many grams of NaOH is produced from 1.20 x 102 grams of Na2O? How many grams of Na2O are required to produce 1.60 x 102 grams of NaOH? 5. Given the following equation: 8 Fe + S8 ---> 8 FeS What mass of iron is needed to react with 16.0 grams of sulfur? How many grams of FeS are produced? 6. Given the following equation: 2 NaClO3 ---> 2 NaCl + 3 O2 12.00 moles of NaClO3 will produce how many grams of O2? How many grams of NaCl are produced when 80.0 grams of O2 are produced? 7. Given the following equation: Cu + 2 AgNO3 ---> Cu(NO3)2 + 2 Ag How many moles of Cu are needed to react with 3.50 moles of AgNO3? If 89.5 grams of Ag were produced, how many grams of Cu reacted? 8. Molten iron and carbon monoxide are produced in a blast furnace by the reaction of iron(III) oxide and coke (pure carbon). If 25.0 kilograms of pure Fe2O3 is used, how many kilograms of iron can be produced? The reaction is: Fe2O3 + 3 C ---> 2 Fe + 3 CO 9. The average human requires 120.0 grams of glucose (C6H12O6) per day. How many grams of CO2 (in the photosynthesis reaction) are required for this amount of glucose? The photosynthetic reaction is: 6 CO2 + 6 H2O ---> C6H12O6 + 6 O2 This problem is slightly different from those above. 10. Given the reaction: 4 NH3 (g) + 5 O2 (g) ---> 4 NO (g) + 6 H2O (l) When 1.20 mole of ammonia reacts, the total number of moles of products formed is: a. 1.20 b. 1.50 c. 1.80 d. 3.00 e. 12.0 Stoichiometry Worksheet (Individual Work if excused from lab) Answer Key 1.) a) b) c) d) e) 2 / 13 13 / 8 13 / 10 2 / 8 (or 1 / 4) 2 / 10 (or 1 / 5) 2) The KClO3 / O2 molar ratio is 2/3. a) 2 mol KClO3 / 3 mol. O2 = 12.00 mol KClO3 / x = 18.00 mol. b) x = 18.00 mol of O2 3.) Given the following equation: 2 K + Cl2 ---> 2 KCl How many grams of KCl is produced from 2.50 g of K and excess Cl2. From 1.00 g of Cl2 and excess K? 4. Given the following equation: Na2O + H2O ---> 2 NaOH How many grams of NaOH is produced from 1.20 x 102 grams of Na2O? How many grams of Na2O are required to produce 1.60 x 102 grams of NaOH? 5. Given the following equation: 8 Fe + S8 ---> 8 FeS What mass of iron is needed to react with 16.0 grams of sulfur? How many grams of FeS are produced? 6. Given the following equation: 2 NaClO3 ---> 2 NaCl + 3 O2 12.00 moles of NaClO3 will produce how many grams of O2? How many grams of NaCl are produced when 80.0 grams of O2 are produced? 7. Given the following equation: Cu + 2 AgNO3 ---> Cu(NO3)2 + 2 Ag How many moles of Cu are needed to react with 3.50 moles of AgNO3? If 89.5 grams of Ag were produced, how many grams of Cu reacted? 8. Molten iron and carbon monoxide are produced in a blast furnace by the reaction of iron(III) oxide and coke (pure carbon). If 25.0 kilograms of pure Fe2O3 is used, how many kilograms of iron can be produced? The reaction is: Fe2O3 + 3 C ---> 2 Fe + 3 CO 9. The average human requires 120.0 grams of glucose (C6H12O6) per day. How many grams of CO2 (in the photosynthesis reaction) are required for this amount of glucose? The photosynthetic reaction is: 6 CO2 + 6 H2O ---> C6H12O6 + 6 O2 This problem is slightly different from those above. 10. Given the reaction: 4 NH3 (g) + 5 O2 (g) ---> 4 NO (g) + 6 H2O (l) When 1.20 mole of ammonia reacts, the total number of moles of products formed is: a. 1.20 b. 1.50 c. 1.80 d. 3.00 e. 12.0 The correct answer is d. NH3 / (NO + H2O) = 4 / 10 4 / 10 = 1.20 / x x = 3.00 mol Post Mole Lab Quiz 1. Strychnine, C21H22N2O2, is a powerful poison and has been used to eradicate rats. If a can of rat poison contains 0.95 g of strychnine, what is the total number of atoms in the can? Correct Answer: MM = 334.45 g / mol 1 molecule= 47 atoms 0.95 g x 1 mol x 6.02x1023 molecules x 334.45g 1 mol 47 atoms = 8.0x1022 atoms 1 molecule 2. How many molecules are there in 4.00 moles of glucose, C6H12O6? Correct Answer: 4.00 mol C6H12O6 x 6.02x1023 molecules = 2.41 x 1024 molecules C6H12O6 1 mol 3. What is the mass of 5.00 moles of Fe2O3? Correct Answer 5.00 mol Fe2O3 x 159.70g = 799 g Fe2O3 1 mol 4. How many moles of argon atoms are present in 11.2 L of argon gas at STP? Correct Answer: 11.2 L Ar x 1 mol L = 0.500 moles Ar 22.4 L 5. How many moles are 1.20 x 1025 atoms of phosphorous? Correct Answer: 1.20 x 1025 atoms P x 1 mol 6.02x1023 atoms = 20.0 Moles P