MP: BP: 0.00°C 100. °C cp (solid): 2.03 J/g°C cp (liquid): 4.184 J/g°C cp (gas): 2.01 J/g°C Hfusion: 6.01kJ/mol Hvaporization: 40.7 kJ/mol • The data above is for water. Determine the amount of heat (in kJ) needed to raise the temperature of 75.0g of water from 12.0°C to 115.0°C. Green – draw heating curve Blue – formula and substitution – first calculation black – formula and substitution – next two calculations Red - answer 199kJ MP: -39°C BP: 356 °C cp (solid): 0.12 J/g°C cp (liquid): 0.14 J/g°C cp (gas): Hfusion: 0.100 J/g°C 2.3 kJ/mol Hvaporization: 59.2 kJ/mol • The data above is for mercury. Use the data to determine the amount energy released when the temperature of 15.0g of mercury cools from 70.0°C to -45°C. Green – draw heating curve Blue – formula and substitution – first calculation black – formula and substitution – next two calculations Red - answer -412 J MP: -39°C BP: 356 °C cp (solid): 0.12 J/g°C cp (liquid): 0.14 J/g°C cp (gas): Hfusion: 0.100 J/g°C 2.3 kJ/mol Hvaporization: 59.2 kJ/mol • 0.50g of mercury spill in the classroom, where the temperature is 22°C. How much heat would be required to completely vaporize the mercury that spilled? Green – draw heating curve Blue – formula and substitution – first calculation black – formula and substitution – next two calculations Red - answer 171 J MP: -39°C BP: 356 °C cp (solid): 0.12 J/g°C cp (liquid): 0.14 J/g°C cp (gas): Hfusion: 0.100 J/g°C 2.3 kJ/mol Hvaporization: 59.2 kJ/mol • A 100.0g sample of mercury is at -69°C. Determine the final temperature and the state of the mercury if it absorbs 2.5kJ of heat. 32°C Calorimeter Problems A 15.0g sample of a metal is heated to 99.7°C and then placed in a calorimeter containing 35.0g of water at 24.6°C. The temperature is monitored until a final temperature of 28.2°C is reached. Determine the specific heat of the metal. 0.49 J/g°C Calorimeter Problems A 15.0g sample of a aluminum (specific heat = 0.900 J/g°C) is heated and then placed in a calorimeter containing 40.0g of water at 21.0°C. The temperature is monitored until a final temperature of 24.9°C is reached. Determine the initial temperature of the aluminum. 73°C