Physical Science Nuclear Physics Slides subject to change Atoms Each chemical element is composed of tiny, indivisible particles called atoms, which are identical for that element but different (masses and chemical properties) from atoms of other elements. Consists of negatively charged electrons and a small positively charged nucleus. Planetary Model Nucleus Nucleus consists of positively charged protons and, electrically neutral neutrons. Protons and neutrons are collectively called nucleons. Relative size - a marble in a football stadium. Atom diameter Nucleus diameter 1x10-10 m 1x10-14 m Labels Each element is assigned a chemical symbol. This symbol usually originates from its name or its Latin name. H = Hydrogen He = Helium C = Carbon Number of protons Z is the atomic number. All the atoms of an element have the same atomic number. Mass Number Number of protons is the atomic number, Z. Number of protons plus neutrons is the mass number, A. Mass Number A Z X Atomic Number, or number of protons In General 238 Element 92 U Uranium Details on a Uranium Nucleus How many protons? 92 How many neutrons? 238 – 92 = 146 Mass number? 238 238 92 U Uranium Background on Uranium Discovered in 1789, named after planet Uranus discovered 8 years earlier. Common element in Earth’s crust. One of the radioactive elements responsible for molten layer between Earth’s crust and core (more uranium in Earth’s crust than silver). First radioactive material discovered in 1896. Isotopes Forms of an element with different numbers of neutrons. Have same chemical properties, may have different physical properties. 238 92 U Uranium 238 plentiful in nature, 99.3% 235 92 U Uranium 235 rare in nature but needed for power/weapons, 0.7% Strong Nuclear Force Overcomes Coulomb repulsion force. Short range, only nearest neighbor nucleons involved. Large nucleus becomes very unstable. When over 83 protons, nucleus is subject to spontaneous disintegration. Nucleus of U-235: protons in red, neutrons in grey. Radioactivity Some nuclei spontaneously decay. Discovered in 1896 by Henri Becquerel studying fluorescence and phosphorescence, and working with uranium salts and photographic plates. The spontaneous process of nuclei undergoing a change by emitting particles or rays is called radioactive decay. An Alpha Decay Process Alpha particles: He nuclei (2 protons, 2 neutrons) Mass numbers and atomic numbers add up and match. Uranium decays to thorium. + 238 92 U 234 90 4 Th + He 2 + Beta Decay Beta particles: Electrons. A neutron decays in the nucleus to a proton and a neutron. Atomic mass and atomic numbers add up and match. Example is Cobalt-60. Decays to an unstable nickel atom. 60 27 60 0 28 -1 Co Ni* + e Gamma Decay Gamma rays consist of high energy photons with energies above about 100,000 eV (>1019 Hz). Due high energy content, gamma rays can cause serious damage when absorbed by living cells (photons strike DNA). 60 27 Ni* Ni + γ 60 27 Uranium Pitchblende ore contains uranium Lisbon Valley, UT Commercial Uranium : “Yellow Cake” Radium Discovered by Pierre and Marie Curie in 1898. Discovered mixed with uranium. Shared 1903 Nobel Prize with Henri Becquerel. Million times more radioactive than uranium. 226 Radium dust mixed with water and glue used to make radioluminescent paint during 1920’s: watch dials, instruments. 88 Ra Early Application When a radium atom decays, one of the particles it ejects (an alpha particle) hits a phosphor molecule in the surrounding paint that the manufacturer used to paint the watch dial's numbers. Then the phosphor glows a faint blue-green light. The radium, however, does not glow; only the phosphor glows. Radium Girls U.S. Radium Corporation Orange, NJ, ca.1920 Radium Girls The employees hired to paint the dials were mostly young women. Paint was applied with a small brush. The women "pointed" the brushes on their tongues between applications, and ingested a small quantity of radium each time. “But everyone knew the stuff was harmless. The women even painted their nails and their teeth to surprise their boyfriends when the lights went out. Danger to Radium Girls Radium is chemically similar to calcium, and is therefore a “bone seeker.” It emits alpha-particles. 226Ra that accumulated in the bone marrow irradiated nearby tissue, and produced bone cancer and other genetic damage. Curie herself died of radium poisoning in 1934. The right of individual workers to sue for damages from corporations due to labor abuse was established as a result of the Radium Girls case. See article. Products of Radioactivity Decay in three common ways: Emit alpha particles: Helium nuclei (2 protons, 2 neutrons). Emit beta particles: Electrons. Emit gamma rays: High energy photons. α β γ Half-Life Half-life is the time it takes for half of the nuclei of a sample to decay. Radioactive isotopes have characteristic half-lives. 50 g of other atoms 100 g of X First half life 75 g of other atoms Second half life 50 g of X 25 g of X Example Half-Lives Carbon-14 5,730 years Cobalt-60 5.26 years Strontium-90 29.12 years Radium-226 1600 years α decay to 222Rn (radon) Uranium-238 4.46 billion years Uranium-235 703 million years After cigarettes, radon is the second leading cause of lung cancer. − EPA Amount of substance, in % Quantity of Radioisotope 100 50 25 0 Years, in half-lives Lise Meitner Fission 1 0 Otto Hahn Large unstable nucleus splits into two intermediate-size nuclei, emits neutrons. Example: Uranium-235 fission. Bombard with one low-energy “thermal” neutron (Otto Hahn and Lise Meitner experiment). 235 142 92 56 n+ U 92 1 36 0 Ba + Kr +2 n - one of several U-235 decay processes U-235 Fission 142 Missing Mass Element or Particle Before After U-235 n Ba-142 Kr-92 2n Mass Difference Mass Total (in units of amu, 1.660x10-27 kg) 235.043924 1.008665 141.916453 91.926156 2.017330 236.052589 235.859939 –0.19265 amu ~3.2x10–28 kg How Masses Add Up Resulting masses are lighter. Where did the mass go? Lise Meitner proposed that it goes into energy from Einstein’s equation E = mc2. Mass Difference = mc2 = (0.19265)c2 = –3.2x10–28 kg –180 MeV Summary One neutron absorbed by U-235, momentarily becomes U-236, unstable, and splits into smaller atoms with tremendous kinetic energy (Coulomb repulsion) (~200 MeV) plus a few neutrons. Visualize with Niels Bohr water drop model. Fission Critical Mass When the process is self-sustaining, the sample has a critical mass. For every 2 or 3 neutrons released, at least one must strike another uranium nucleus. If less than 1, then the reaction will die out. Greater than one it will grow unless controlled (chain reaction). Controlled Reaction Slow Fission Down! A control rod (neutron-absorbing element boron or cadmium) absorbs a large number of neutrons in the reaction. Speed Fission Up! Fission works best with slow neutrons. Need a moderator (e.g., graphite, water) to slow down high-speed neutrons that are created. Warnings Aug 2, 1939 Einstein to FDR. Possibility that Nazis were developing an atomic bomb. First Controlled Fission December 2, 1942. Enrico Fermi, University of Chicago. Natural uranium, cadmium control rods. 315 tons of graphite used as a moderator to slow down the neutrons. Manhattan Project In an atomic bomb, a mass of fissile material greater than the critical mass must be assembled instantaneously. Held together for about a millionth of a second to permit the chain reaction to propagate before the bomb explodes Manhattan Project Hiroshima “Little Boy,” dropped on Hiroshima, Japan, August 8, 1945. Explodes 1,900 feet above city. 140,000 people die immediately. Equivalent to 13 kilotons of dynamite. Used 60 kg (132 lbs) of U-235. August 15, 1945, Japan announces surrender, ending WWII. (Germany had surrendered May 7, 1945) Hiroshima Nuclear Tests in Nevada Interview Controlled Nuclear Power Three-Mile Island, Middletown, PA Nuclear Power Plant Light and Heat Energy Mechanical Energy Nuclear Energy Thermal Energy Electrical Energy Nuclear Fuel Life Cycle Uranium enrichment centrifuges Enrichment Ore Processing Uranium Mine Cameco Corp.'s uranium mine in northern Saskatchewan Fuel Production Power Reactor Used Fuel Disposal Road transport of spent fuel in Japan Nuclear Waste Percent Radioactive Waste Percentofof Radioactive Worldwide Waste Worldwide High Level 3% Percent of Total Radioactivity Low Level 1% Intermediate Level 7% Low Level 90% High Level 95% Intermediate Level 4% High-Level Waste Thermally hot, highly radioactive, and potentially harmful used nuclear reactor fuel. Converted into granules and mixed with molten glass and stored. Licensees must safely store this fuel at their reactors. Disposal of high-level radioactive waste was defined by the Nuclear Waste Policy Act of 1982. High-Level Waste Nuclear Waste Policy Act of 1982: Dispose highlevel waste at Yucca Mountain, Nevada. 80 miles northwest of Las Vegas, NV. No official date for opening the $12 billion facility. 3/7/09 Obama proposed budget closed the facility. Satisfies Harry Reid (D-Nev). What to do with existing 57,000 tons of highly toxic waste at 121 above-ground sites? Existing plants create 2,000 tons each year. DOE study underway to find an alternative. Low-Level Waste Slightly radioactive. Includes things like protective clothing, laboratory equipment, paper towels, gloves, etc. Hospital, industry waste. Compacted using a high force compactor. Bury in shallow pits. WIPP Forbes, 2/13/12 p. 91. Waste Isolation Pilot Project (WIPP), Carlsbad, NM, is the nation’s only permanent, deep geologic repository for nuclear waste. Storage for radioactive drums with the plutoniumladen detritus of America’s nuclear weapons program. 3,000-ft salt layer. Clean Nuclear Process? Are there heavier elements that can be fused into a lighter element (so missing mass goes off as E=mc2 energy)? Fusion energy would be “clean.” No radioactive waste products. n Binding Energy per Nucleon Isotopes of Hydrogen Hydrogen 1 1 Deuterium “Heavy hydrogen D2O.” Abundant in oceans (1 in 6,500 molecules is “heavy water.” 2 1 H D Fusion n Candidate Fusion Equation Isotopes of Hydrogen Deuterium D 2 1 2 3 1 2 D+ D 1 He + n 0 Fusion Process Element or Particle Before After Deuterium Deuterium Helium-3 n Mass Difference Δmc2 Mass Total (in units of amu, 1.660539x10-27 kg) 2.014103 2.014103 3.016029 1.008665 4.028206 4.024694 -0.003512 amu -3.3 MeV Example Construction Lithium and Deuterium H-Bomb. Must overcome Coulomb repulsion, get close enough for strong nuclear force to take over. Fission bomb provides energy to bring them close to each other. Castle Bravo Test 15 Megatons (equivalent of dynamite). February 28, 1954, Bikini Atoll in South Pacific. “One of the atolls has been totally vaporized, disappearing into a gigantic mushroom cloud that spread at least 100 miles wide and dropping back to the sea in the form of radioactive fall-out.” 15 Megatons. February 28, 1954, Bikini Atoll in South Pacific. Big Ivan Tsar Bomba “Big Ivan,” the largest bomb ever tested, October 30, 1961 Commissioned by Nikita Kruschev. Exploded with 50-Megaton force. Burst at 13,000 feet, fireball reached the Earth. Designed so delivery aircraft could safely fly 25 miles away before detonation. Film Controlled Fusion Need kinetic energy to overcome Coulomb repulsion. National Ignition Facility Inertial confinement fusion experiments. Implode a microcapsule simultaneously irradiated by 192 giant lasers. Facility certified to operate March 27, 2009. NIF: Recipe for a Small Star Hollow, spherical plastic capsule about two millimeters in diameter (about the size of a small pea) Filled with 150 micrograms of a mixture of deuterium and tritium, the two heavy isotopes of hydrogen. Take a laser that for about 20 billionths of a second can generate 500 trillion watts – the equivalent of five million million 100-watt light bulbs. Focus all that laser power onto the surface of the capsule. Wait ten billionths of a second. Result: one miniature star. Controlled Fusion International approach under construction. International Thermonuclear Experimental Reactor (ITER), located in southern France. Magnetic confinement fusion experiments. Contain plasma in magnetic fields while energy is added. Impact on Humans Dosimeters – used to measure radiation. Radiation Impact on Humans Passage of an energetic charged nuclear particle through a cell produces a region of dense ionization along its track. Destroys or damages DNA. DNA Radiation Damage – artist concept Radiation Dosage Radiation dosage is the energy deposited per kilogram of living tissue. Traditional U.S. unit is rad (radiation absorbed dose), 0.01 J per kilogram of living tissue. Does not make a distinction between various types of radiation and the resulting damage. RBE Damage to Humans RBE (relative biological effectiveness). Photon (x-ray and γ-ray) radiation and β radiation are assigned the base value of 1. RBE for neutron radiation has the value of 10. RBE for alpha-particle radiation has the value of 20. Thus, 1 rad of alpha radiation is 20X more damaging than 1 rad of X-rays. Radiation Therapy Injure or destroy cells in the area being treated (the “target tissue”) – damage their genetic material, making it impossible for these cells to continue to grow and divide. Damages both cancer cells and normal cells –most normal cells can recover from the effects of radiation. Radiation therapy – damage as many cancer cells as possible, while limiting harm to nearby healthy tissue. Treatment Types External radiation therapy X-rays and gamma rays. Particle beams. LLUMC“Proton Treatment Center.” Proton treatment deposits energy in very small region, protecting organs in front of and behind the target. Treatment Types Radioactive implants are devices that are placed directly within cancerous tissue or tumors, in order to deliver radiation therapy intended to kill cancerous cells. With use of radioactive implants, tumor is subjected to radioactive activity over a longer period of time, as compared to external beam therapy. Permanent Brachytherapy Doctor implants radioactive (iodine125 or palladium-103) seeds into the prostate gland. Anywhere from 40 to 100 seeds are commonly implanted. The implants remain in place permanently, and become biologically inert (no longer useful) after a period of months. This technique allows a high dose of radiation to be delivered to the prostate with limited damage to surrounding tissues. Isotopes of Hydrogen Hydrogen (in “light water” H2O) Deuterium “Heavy hydrogen.” Stable isotope Tritium Radioactive isotope of hydrogen. Half-life = 4,500 days 1 1 2 1 H H 3 1 H Paper can block Use aluminum to block Use lead to block A Nuclear Decay Chain The natural decay chain of uranium-238 is as follows: decays, through alpha-emission, with a half-life of 4.5 billion years to thorium-234 which decays, through beta-emission, with a half-life of 24 days to protactinium-234 which decays, through beta-emission, with a half-life of 1.2 minutes to uranium-234 which decays, through alpha-emission, with a half-life of 240 thousand years to thorium-230 which decays, through alpha-emission, with a half-life of 77 thousand years to radium-226 which decays, through alpha-emission, with a half-life of 1.6 thousand years to radon-222 which decays, through alpha-emission, with a half-life of 3.8 days to polonium-218 which decays, through alpha-emission, with a half-life of 3.1 minutes to lead-214 which decays, through beta-emission, with a half-life of 27 minutes to bismuth-214 which decays, through beta-emission, with a half-life of 20 minutes to polonium-214 which decays, through alpha-emission, with a half-life of 160 microseconds to lead-210 which decays, through beta-emission, with a half-life of 22 years to bismuth-210 which decays, through beta-emission, with a half-life of 5 days to polonium-210 which decays, through alpha-emission, with a half-life of 140 days to lead-206, which is a stable nuclide. - Wikipedia Carbon Dating Carbon Dating Trace amounts of Carbon-14 are present in all organic materials. Created by the Sun in Earth’s upper atmosphere and mixed through atmosphere in CO2. Absorbed by all living things. When the living body dies, the amount in the body is “fixed.” Half-life of 14C is 5,730 years. Measure the ratio of 12C to 14C to estimate age. Example Bones were found in Texas that had only 25% of their carbon-14 left. Estimate their age. Half was lost in the first 5,730 years: down to 50% Half of what was left was lost in the next 5,730 years, down to 25%. Total elapsed time is approximately 11,460 years. Example Carbon−14 Carbon-14 5,730 years Cobalt-60 5.26 years Strontium-90 29.12 years Radium-226 1600 years Uranium-238 4.46 billion years Uranium-235 703 million years 14C Decay β decay to 14N