Calorimetry Practice Problems

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Objectives

Today I will be able to:

Calculate the heat absorbed and released in a chemical reaction

Informal assessment – monitoring student interactions and questions as they complete the practice problems

Formal assessment – analyzing student work from the practice problems and exit ticket

Common Core Connection

Make sense of problems and persevere in solving them

Reason abstractly and quantitatively

Evaluate: Warm Up

Formal assessment

Directed Practice Problems

Informal assessment

Individual Practice Problems

Informal/formal assessment

Evaluate: Exit Ticket

Formal assessment

Carbon exists in two natural forms: graphite and diamond. Each form can be combusted:

C

(graphite)

C

(diamond)

+ O

2(g)

+ O

2(g)

 CO

2(g)

 CO

2(g)

∆H = -393.5 kJ

∆H = -395.4 kJ

Calculate ∆H of the conversion of graphite to diamond: C

(graphite)

 C

(diamond)

HW: Finish Calorimetry Problems

Today I will be able to:

Calculate the heat absorbed and released in a chemical reaction

Study for Thermochemistry Quiz on

Wednesday, April 15

Warm Up

Directed Practice Problems

Individual Practice Problems

Exit Ticket

Calculate ∆H for the reaction 4 NH

3

O

2

(g)  4 NO (g) + 6 H following data.

2

(g) + 5

O (g), from the

N

2

(g) + O

2

(g)  2 NO (g) ∆H = -180.5 kJ

N

2

(g) + 3 H

2

(g)  2 NH

3

(g)∆H = -91.8 kJ

2 H

2

(g) + O

2

(g)  2 H

2

O (g) ∆H = -483.6 kJ

Example 1:

You put 103.0 g of aluminum in 100.0 grams of boiling water. The water temperature changes from 100.0ºC to 90.0ºC, while the aluminum temperature goes from 25.0ºC to 70.0ºC. What is the specific heat of aluminum?

Al H

2

O

-(103.0g)(c)(70.0-25.0

° C) (100.0g)(4.184J/g ° C)(90.0-100.0

° C)

-4640 g ° C(c) = -4180 J

c = 0.901 J/g ° C

What if something dissolves in the water?

What happens to the total mass???

You add them up! The whole solution increases (or decreases) in heat.

A chemistry student dissolves 4.51 grams of room temperature sodium hydroxide in

100.00 g of water at room temperature,

19.5

° C. As the sodium hydroxide dissolves, the temperature of the solution increases to

31.7

° C. Determine the heat of solution of the sodium hydroxide in J/mol.

47.3 kJ/mol

Calorimetry Problems

You may check Ms. Ose’s answer key as you work

Based on the calorimetry data presented below, is the reaction endothermic or exothermic? Explain.

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