Oxidation and Reduction Oxidation The chemical process by which an element or compound gains oxygen. Example: 2Mg(s) + O2 2MgO Oxidation naturally happens to every metal except platinum and gold. Oxidation can also be applied to any element or compound which gives up electrons in order to form a covalent or ionic compounds. Example: Cu(s) Cu+2 + 2e- Fe + O2 Fe2O3 Ag + O2 Ag2O Oxygen cause food to spoil by oxidation! Reduction The chemical process by which an element or compound loses oxygen. This is how metal is refined. The oxygen is removed in order to “reduce” metals to their elemental form. Example: 2 ZnO 2 Zn + O2 Reduction is also applied to any element or compound which gains electrons in order to form a covalent or ionic compounds. Example: Fe+3 + 3e- Fe Redox This is the name given to any reaction that involves a gain of electrons by one compound and loss of electrons by another. An easy way to remember which is to think of LEO the Lion: LEO the lion says “GER” Lose Electrons— Oxidation Gain Electrons— Reduction You can recognize a redox reaction by assigning oxidation numbers to each element in each compound and look to see if they change from the reactant side to the product side. Example 1: Assign oxidation numbers first! +2 -1 0 +2 -1 0 CuCl2 + Zn ZnCl2 + Cu Zn Species oxidized? ______ – Loses electrons - Zn0 to Zn2+ Cu2+ Species reduced? ______ – Gains electrons - Cu2+ to Cu0 Example 2: +2 -2 0 0 +4 -2 2CuO + C Cu + CO2 C Species oxidized? ______ – Loses electrons - C0 to C+4 Cu2+ Species reduced? ______ – Gains electrons – Cu+2 to Cu0 Oxidizing Agent a substance that can cause another substance to be oxidized (lose electrons) Strong oxidizing agents are those that want to gain electrons the most, such as Fluorine, oxygen and Chlorine. (they are electron hungry!) They are the substance that gets reduced! Reducing Agent a substance that can cause another substance to be reduced (gain electrons) Strong reducing agents are those that easily give up electrons, such as Na, Li and K They are the substance that gets oxidized! Example 0 -1 -1 0 Cl2 + 2Br1-(aq) 2Cl1-(aq) + Br2 Species Oxidized = Loses electrons = Br1- Species Reduced = Gains electrons = Cl2 Oxidizing agent = Cl2 Reducing agent = Br1-