Physical Properties

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Physical Properties of Minerals

Physical Properties

• Color of Minerals

Idiochromatic color

– color caused by elements in chemical formula--Cu in malachite and azurite and Mn in rhodochrosite

Chromaphore color

– color caused by concentrations of elements not part of chemical formula-

-Cu and V in beryl (emerald), Fe in amethyst and V in zoisite (tanzanite )

• Electron and Molecular Transitions

• Colors caused by Idiochromatic and chromophore elements can be generated by

• 1. Crystal field transitions

– wavelengths of light are absorbed by “d” electrons in transition elements causing emissions of wavelengths of light quanta resulting in color of mineral---Cr +3 in emerald and ruby, Mn +2 in morganite and

Fe +2 in peridot

• 2.

Molecular Orbital Transitions

– ions undergo charge transitions or electron hopping--Fe +2 to Fe +3 in aquamarine or Fe +2 to Ti +4 in sapphire

• Inclusions of Other Minerals

• minerals dispersed or included in minerals can influence color

• chlorite dispersed in quartz (aventurine) can cause a green color

• black calcite can be caused by inclusions of

MnO

2

• red color in many minerals is caused by hematite inclusions

Mineral Properties Related to Light,

Heat, and Electricity

Play of Colors (Iridescence)

• defracted or reflected light off features on the mineral

– labradorite and opal

Chatoyancy

• silky or wavey appearance across the surface of the mineral as it is rotated--

Asterism

• a star like figure on surface of mineral caused by reflected or scattered light off included minerals aligned parallel to crystallographic axes

Luminescence

• caused by impurities (activators) in a mineral--some specimens of fluorite, scheelite, and calcite

Fluorescence

• emission of wavelengths of light caused by electron excitation in metals during bombardment by ultraviolet or X-rays

Phosphorescence

• continuous emission of wavelengths after excitation source is removed

• Thermoluminescence

• emissions of wavelengths when subjected to heat at less than “red hot” temperatures

Piezoelectricity

• a flow of electrons in minerals with exertion of a compression force between the “c” crystallographic axis of a mineral which has no center of symmetry---quartz and tourmaline

Pyroelectricity

• the same as above brought about by stimulation of mineral with heat--quartz and tourmaline

tourmaline

Hardness

• Moh’s hardness scale is a special list of minerals with increasing relative hardness

• 1. talc 6. feldspar

• 2. gypsum 7. quartz

3. calcite 8. topaz

• 4. fluorite 9. corundum

5. apatite 10. diamond

– glass and knife = 5.5 - 6

– steel file = 6 -7

– fingernail = 2.5

– penny = 3

– some minerals have more than 1 hardness depending on the direction of scratching-kyanite= 5-7 and calcite between 2 and 3

Tenacity

• cohesiveness of mineral or resistance to breaking, crushing, bending, etc.

1. brittle--if a mineral powders easily-quartz

2. malleable--if mineral can be hammered into sheets--native Cu, Au

• sectile--if mineral can be cut into thin shavings--talc

• ductile--if mineral can be drawn into wire--

Cu, Au

• flexable--if a mineral is bent and does not assume its’ original shape

• elastic--if a mineral is bent and resumes its’ original shape--mica

talc

Streak and Luster

• streak is the color of the powder of the mineral on a porcelain plate

• luster is metallic (dark or black prominent streak-dense and opaque to light) or nonmetallic ( translucent or transparent with a colorless or white streak) or somewhat inbetween called submetallic

• some specific nonmetallic lusters are:

1.vitreous--resembling glass--quartz crystals

– 2. resinous--resin like--sulfur and sphalerite

3. pearly--mother of pearl like--talc

talc--pearly

• greasy--like grease or oil--massive quartz

• silky--like silk--satin spar gyspum

• adamantine--brillant with a high index of refraction--diamond or clear quartz crystals

Cleavage

• ability of mineral to come apart in a consistent way

• breakage is along atomic planes--consistent with crystal symmetry--- there can be from one to multidirectional cleavage from mineral to mineral

Parting

• can resemble cleavage

• breakage of minerals along planes of weakness such as twinning planes--minerals which grow around each other, each one forming at a different time

• caused by minerals being subjected to special pressures during formation

Fracture

• inability of a mineral to break in a consistent way

• do not break along cleavage planes

Kinds of fracture are:

• concoidal--smooth, curved breakage--quartz

• fibrous or splintery

• hackly--jagged with sharp edges

• irregular--rough surfaces

Specific Gravity

• a number expressing a ratio between a mineral and the weight of an equal volume of water

• same number as density without units

S.G. depends on:

• kinds of atoms (atomic weight) comprising mineral

• packing of atoms(close or loosely packed)

S.G. can be determined with a Jolly Balance

Crystal Habits and Aggregates

• appearance of a single crystal or aggregate of a crystals of a mineral

• isolated individual crystals

– bladed--elongated flattened crystal like a knife blade

– acicular--thin needlelike crystal

– capillary--hair like or thinner

acicular-stibnite

• groups of distinct crystals

– dendritic--resembling a branching tree or veinlets on a tree leaf

– radiated--crystal appearing in a radial pattern

– drusy--a surface containing very small crystals radiated--wavellite

• groups of distinct crystals in parallel or spherical form

– columnar--column like crystals

– bladed--many flat knife like crystals

– fibrous--parallel fibers

– colloform--botryoidal (bunch of grapes, reniform (kidney shaped), mammillary fibrous--crysotile

(serpentine) colloform-hematite

• aggregate of scales or lamellae

– foliated--easily splits into thin sheets or leaves

– plumose--scaly-feather like

• granular aggregate

– equant crystal grains foliated (micaceous)- mica equant granular mass pyrite

• Other types pisolitic or oolitic-rounded masses of pea sized grains (pisolitic) or very small grains( oolitic)---this picture is bauxite (pisolitic) and some samples of hematite occur as oolitic stalactitic-resembling stalactites---this example is goethitelimonite

massive--massive with no form or distinguishing features geode--rock cavity filling with mineral crystals

banded--mineral showing narrow bands of different colors or textures

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