Starter: Write some information about the atom The structure of the atom 11/03/2016 I did some experiments in 1808 that proved this and called these particles ATOMS. Most of an atom is empty space and the nucleus is actually very small so this diagram is wrong: Dalton NEUTRON – neutral, same mass as proton (“1”) PROTON – positive, same mass as neutron (“1”) ELECTRON – negative, mass nearly nothing What particles are atoms made of? For some time, people thought that atoms were the smallest particles and could not be broken into anything smaller. Scientists now know that atoms are actually made from even smaller particles. There are three types: proton neutron electron How are these particles arranged inside the atom? What is the structure of an atom? Protons, neutrons and electrons are not evenly distributed in an atom. The protons and neutrons exist in a dense core at the centre of the atom. This is called the nucleus. The electrons are spread out around the edge of the atom. They orbit the nucleus in layers called shells. Mass and atomic number 11/03/2016 Particle Relative Mass Relative Charge Proton 1 +1 Neutron 1 0 Electron Very small -1 MASS NUMBER = number of protons + number of neutrons SYMBOL PROTON NUMBER = number of protons (obviously) Atomic mass in more detail 11/03/2016 RELATIVE ATOMIC MASS, Ar (“Mass number”) = number of protons + number of neutrons SYMBOL PROTON NUMBER = number of protons (obviously) – this number is always the same for an element Mass and atomic number 11/03/2016 How many protons, neutrons and electrons? Atomic structure worksheet 11/03/2016 Proton Mass Number of Number of Number of Element Symbol number number protons neutrons electrons Use a periodic table to help you complete the table below. carbon C 12 aluminium 13 chlorine 18 33 caesium 133 36 titanium How are electrons arranged? Electrons are not evenly spread but exist in layers called shells. (The shells can also be called energy levels). The arrangement of electrons in these shells is often called the electron configuration. 1st shell 2nd shell 3rd shell Note that this diagram is not drawn to scale – the atom is mostly empty space. If the electrons are the size shown, the nucleus would be too small to see. How many electrons per shell? Each shell has a maximum number of electrons that it can hold. Electrons will fill the shells nearest the nucleus first. 1st shell holds a maximum of 2 electrons 2nd shell holds a maximum of 8 electrons 3rd shell holds a maximum of 8 electrons This electron arrangement is written as 2,8,8. Electron structure 11/03/2016 Consider an atom of Potassium: Potassium has 19 electrons. These electrons occupy specific energy levels “shells”… Nucleus The inner shell has __ electrons The next shell has __ electrons The next shell has __ electrons The next shell has the remaining __ electron Electron structure = 2,8,8,1 Electron structure 11/03/2016 Draw the electronic structure of the following atoms: Nucleus Nucleus Nucleus Electron structure Electron structure Electron structure = 2,5 = 2,8,2 = 2,8,8,2 Electron shells worksheet 11/03/2016 Isotopes 11/03/2016 11/03/2016 An isotope is an atom with a different number of neutrons: Notice that the mass number is different. How many neutrons does each isotope have? Each isotope has 8 protons – if it didn’t then it just wouldn’t be oxygen any more. Strange atomic masses 11/03/2016 When you look at a periodic table sometimes the atomic mass is not a whole number. Consider chlorine, for example: How can an atom have a decimal for its mass? This is because out of every four naturally occurring chlorine atoms, 3 have a mass of 35 and 1 has a mass of 37 so the average atomic mass is: (3 x 35 + 1 x 37) / 4 = 35.5 Q. Magnesium is often found as 24Mg or 26Mg. If 79% of magnesium is 24Mg what is the average atomic mass? (79 x 24 + 21 x 26) / 100 = 24.4 Calculating relative atomic mass Where are r.a.m. values found? The values of relative atomic mass (r.a.m.) are usually given in a data book or found in the periodic table, so you don’t have to work them out or remember them all! relative atomic mass symbol atomic number When looking up r.a.m in the periodic table, remember that it is always the larger of the two numbers given. Why isn’t r.a.m. always a whole number? Relative atomic mass (r.a.m.) is not always a whole number. For example, the r.a.m. of chlorine is 35.5. The standard r.a.m. value of each element is actually the average relative atomic mass, which takes all the isotopes of each element into account. Chlorine has two isotopes: chlorine-35 (75%) and chlorine-37 (25%). average r.a.m. of chlorine = (35 × 75%) + (37 × 25%) = (35 × 0.75) + (37 × 0.25) = 26.25 + 9.25 = 35.5 What 2 pieces of information do you need in order to calculate the r.a.m.? 1. The abundance of the isotopes (%) 2. The relative mass of the isotope. average r.a.m. of chlorine = (35 × 75%) + (37 × 25%) = (35 × 0.75) + (37 × 0.25) = 26.25 + 9.25 = 35.5 Calculating average r.a.m. from isotopes To calculate the average r.a.m. of a mixture of isotopes, multiply the percentage of each isotope by its relative atomic mass and then add these together. Naturally-occurring bromine is composed of two isotopes: bromine-79 (50.5%) and bromine-81 (49.5%). What is the average r.a.m. of naturally-occurring bromine? average r.a.m. = (79 × 50.5%) + (81 × 49.5%) = (79 × 0.505) + (81 × 0.495) = 39.895 + 40.095 = 79.99 This figure can be rounded up. Past paper questions… Plenary… 11/03/2016 • What are isotopes? • Tell me something you have learnt about electron shells