AP Audit - AP Chemistry - 2013 Curricular Requirements CR1 CR2 CR3a CR3b CR3c CR3d CR3e CR3f CR4 CR5a CR5b CR6 CR7 Students and teachers use a recently published (within the last ten years) college-level chemistry textbook The curse is structured around the enduring understandings within the big ideas as described in the AP Chemistry Curriculum Framework The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 1: Structure of Matter The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 2: Properties of matter-characteristics, states, and forces of attraction. The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 3: Chemical Reactions The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 4: Rates of Chemical Reactions The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 5: Thermodynamics The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 6: Equilibrium The course provides students with the opportunity to connect their knowledge of chemistry and science to major societal or technological components. (e.g., concerns, technological advances, innovations) to help them become scientifically literate citizens. Students are provided the opportunity to engage in investigative laboratory work integrated throughout the course for a minimum of 25 percent of instructional time. Students are provided the opportunity to engage in a minimum of 16 hands-on laboratory experiments integrated throughout the course while using basic laboratory equipment to support the learning objectives listed within the AP Chemistry Curriculum Framework. The laboratory investigations used throughout the course allow students to apply the seven science practices defined in the AP Chemistry Curriculum Framework. At minimum, six of the required 16 labs are conducted in a guided-inquiry format. The course provides opportunities for students to develop, record, and maintain evidence of their verbal, written, and graphic communication skills through laboratory reports, summaries of literature or scientific investigations, and oral written, and graphic presentations. 1 Syllabus Index (page #) 3 3,4,5,6,7, 8,9,10,11 4, 9,10 4, 9, 10, 11 4, 8 6 5 7, 8 2 2,4,5,6,7, 8,11,12 4,5,6,7,8, 9,11,12 4,5,6,7,8, 9,11,12 2 Course Overview Advanced Placement Chemistry is taught as a second year course to 11th and 12th grade students who have completed Chemistry 1-2 or Honors Chemistry 1-2. These first year courses provide a strong background in both content and hands-on laboratory experience (a minimum 25% of instructional time). All course requirements for AP Chemistry (listed below) are introduced during the first year of chemistry. A number of topics (stoichiometry, relationships in the periodic table, mole concept, electronic structure of atoms, molecular shapes, gases, and data acquisition, manipulation, and communication in written reports) as well as basic chemistry laboratory skills and safety are covered extensively during the first year of chemistry, providing a sound base for AP Chemistry. The summer assignment immediately preceding AP Chemistry provides focused review of these topics. AP Chemistry is designed to provide a first-year college chemistry experience, especially in terms of the application of chemical concepts to problem-solving and laboratory experiments. During class time chemical concepts are introduced, and practice problems presented, analyzed and solved. Laboratory exercises provide practical applications of the lecture material and practice problems and an opportunity to explore these concepts and applications through inquiry. Laboratory Laboratory exercises are generally performed during one of the two block periods available per week (a minimum 25% of total instructional time). The laboratory exercises are designed to allow students to apply the seven science practices defined in the AP Chemistry Course Description. Students are provided instructions, modeling and time to master basic laboratory techniques such as organizing their bench space, preparing solutions, conducting titrations and analyzing data. In the laboratory, students generally work in pairs. Students complete pre-laboratory questions and procedure development prior to entering the laboratory. Group discussion of data and error analysis is an integral part of the laboratory work. Laboratory reports are completed for every laboratory exercise in a college-type laboratory notebook. Students submit carbon copies of their laboratory reports and their analytical skills are additionally assessed by laboratory quizzes. Six of the sixteen laboratory exercises can be described as inquiry or guided inquiry. [CR5a,6,7; SP 1-7] Components of Laboratory Reports: Purpose Materials Pre laboratory preparation Procedures Results - Data Tables/Graphs/Written Descriptions Analysis Conclusions [CR7] Second Semester Project Students will select a Chemical & Engineering News article to present to the class, with a poster, PowerPoint and/or oral format. The articles include a wide variety of everyday products that involve innovations based on chemistry, environmental concerns and technological components including careers in chemistry. [CR4] 2 Assessments Assessments for AP Chemistry include quizzes, laboratory reports and laboratory quizzes, and written examinations. Most examination questions are reproduced from old AP exams both multiple choice and free response. Approximate weighting of types of assessments: Labs/Classwork/Project Tests HW/Quizzes Final/Practice Test 25% 35% 20% 20% Course Requirements – Big Ideas of AP Chemistry [CR2] Big Idea 1: The chemical elements are fundamental building materials of matter, and all matter can be understood in terms of arrangements of atoms. These atoms retain their identity in chemical reactions. Big Idea 2: Chemical and physical properties of materials can be explained by the structure and the arrangement of atoms, ions, or molecules and the forces between them. Big Idea 3: Changes in matter involve the rearrangement and/or reorganization of atoms and/or the transfer of electrons. Big Idea 4: Rates of chemical reactions are determined by details of their molecular collisions. Big Idea 5: The laws of thermodynamics describe the essential role of energy and explain and predict the direction of changes in matter. Big Idea 6: Any bond or intermolecular attraction that can be formed can be broken. These two processes are in a dynamic competition, sensitive to initial conditions and external perturbations. Class Prerequisites Completion of Chemistry 1-2 or Honors Chemistry 1-2 and Advanced Algebra 1-2 with grades of “C” or better. Bibliography Textbook: [CR1] Brown, T.L., LeMay Jr., H.E., Bursten, B.E. and Burdge, J.R. Chemistry: The Central Science, Prentice-Hall, 11th Edition, 2009. Brown, T.L. and Waterman, Edward. AP Exam Workbook for Chemistry: the Central Science – 11th ed., Prentice Hall. 2009. Laboratory manuals: Cesa, Irene (senior editor). Flinn Scientific ChemTopic Labs, Flinn Scientific Inc., 2002-2006. Morrison, Duncan and Scodellaro, Darrel, Essential Experiments for Chemistry, SMG Lab Books, 2005. Nelson, John H. and Kemp, Kenneth C. Laboratory Experiments, Chemistry: The Central Science, Prentice-Hall, 11th Edition, 2009. Randall, Jack. Advanced Chemistry with Vernier, Vernier Software and Technology, 2nd edition, 2007. The College Board. AP Chemistry Guided-Inquiry Experiments: Applying the Science Practices, 2013 Volz, Donald L. and Smola, Ray. Investigating Chemistry through Inquiry, Vernier Software and Technology, 2009. Other materials: Vernier Logger Pro graphing and analytical software, LabQuest and probe ware Chem Ed 2001, 2005, 2011, 2013 workshop and plenary session materials 3 Course Plan by Unit Unit 1 (Chapters 1-4): Review of Formulas, Reaction Type, Stoichiometry and Solution Stoichiometry Big Ideas: 1,2,3 Chemistry or Honors Chemistry, Summer Assignment and Fall Semester – 5 weeks Topics Laboratory Exercises 1. The Determination of the Percent LO1.1,1.2,1.3,1.4,1.17,1.18,1.19,1.20 Water in a Compound – Vernier #2 LO2.1,2.2 LO3.1,3.2,3.3,3.4,3.5,3.6,3.8,3.9,3.10,3.11 (SP2,3,5,6; LO1.2,1.3,3.5,3.6) Write/name ionic and covalent formulas, Students will use a prescribed including common acids procedure and series of calculations to determine the Calculate % composition percent of water and formula Calculate empirical formulas of a hydrate. Represent substances and chemical reactions using particulate drawings 2. What makes hard water hard Balance chemical equations (gravimetric analysis)? (CB Identify reaction types (synthesis, Investigation 3) INQUIRY decomposition, acid-base, precipitation, (SP1,2,4,5,6,7; LO 1.19, 2.10,3.2,3.3) oxidation-reduction), predict products of Students will perform and reactions and write chemical equations, perfect the separation including net ionic equations where appropriate technique of filtering a mixture Distinguish between chemical and physical to collect a precipitate, proper changes rinse and dry the precipitate Identify whether a reaction is exothermic or until a constant mass is endothermic and indicate this in a chemical reached. equation Students will design an Use stoichiometry to solve for theoretical yield, experiment that will limiting reactants, and percent yield and percent appropriately use equipment error for gravimetric analysis, Describe general properties of aqueous collect data and calculate the solutions – electrolytes, non-electrolytes, concentration of an analyte. solubility Calculate concentrations of solutions (molarity) 3. Reactions Lab: Brown, LeMay et al. Perform titration calculations #4 (SP3,6; LO3.2,3.9) Non-laboratory activities: Students are given practice problems which require them to calculate empirical and molecular formulas; solve for limiting reactants based on stoichiometry; determine the concentration of an analyte in a solution using titration data; identify oxidationreduction pairs in a chemical equation (LO1.2,1.4,1.20,3.4,3.8) [CR3a,c] Students will follow a prescribed procedure to perform a series of chemical reactions whereby the students will predict the results. 4. Classic titration of a strong acid with strong base, with appropriate indicator and no pH sensor (SP1,2,4,5; LO1.20) Students conduct and evaluate the results of an acid-base titration. [CR5b] 4 Unit 2 (Chapters 5 and 19): Thermochemistry and Thermodynamics Big Idea 5 Fall Semester – 6 weeks Topics LO5.1,5.2,5.3,5.4,5.5,5.6,5.7,5.8,5.12,5.13,5.14, 5.15,5.16,5.17,5.18 Use and create graphs that show the relationship between distance between atoms under difference circumstances which influence interaction strength Relate temperature to the motions of particles in graphical form and particulate drawings Define and use heat capacity to convert between temperature and heat Relate magnitude of energy changes in different situations Distinguish between heat and work Relate energy changes to heat capacity, enthalpy of fusion/vaporization, chemical reactions and work Use calorimetry to determine changes in enthalpy Define enthalpy and be able to calculate enthalpy during a temperature change and during a change of state Use bond energies to calculate enthalpy change in a chemical reaction State and use Hess’s Law to calculate enthalpy change in a process Use standard heats of formation to calculate the heats of reaction Define and apply the Second Law of Thermodynamics (entropy) Predict whether a process is thermodynamically favored (spontaneous) using the signs of Ho, So and/or Go Coupled reactions Non-laboratory activities: Students are given practice problems which require them to interpret graphs of energy diagrams and Maxwell-Bolton distributions; calculate energy changes from calorimetry data (LO5.1,5.2,5.7) [CR3e] 5 Laboratory Exercises 5. The hand warmer design challenge: where does the heat come from? (CB Investigation 12) INQUIRY (SP2,4,5,6; LO5.6,5.7) Students devise a plan for using calorimetry to determine the heat generated by different mixtures of solute and solvent combinations. Students do calculations to determine heat of reaction for dissolving processes. [CR5b] Unit 3 (Chapter 14): Chemical Kinetics Big Idea 4 Fall Semester – 3 weeks Topics Laboratory Exercises 6. What is the relationship LO1.16 between the concentration LO4.1,4.2,4.3,4.4,4.5,4.6,4.7,4.8,4.9 of a solution and the Identify the factors that affect reaction rates amount of transmitted light Measure and calculate reaction rates through the solution Apply stoichiometry to calculations of reaction rates (using Vernier technology) Analyze the effect of change in reactant concentrations (CB Investigation 1) on reaction rates INQUIRY Determine exponents in the rate law (SP2,4,5,6; LO 1.15,1.16) Determine rate orders – change in concentration over Students will design a time procedure/data Calculate half-life and relate it to the rate constant of a collection strategy to first-order reaction determine the Relate temperature to reaction rate concentration of dye in Describe and apply the collision model an unknown solution. Represent a reaction using an energy profile, Students will use particulate representation and chemical equations, Vernier technology and including activation energy and the differences Logger pro to plot and between catalyzed and non-catalyzed reactions analyze the linear Identify and evaluate reaction mechanisms relationship of Explain catalysis, including enzymes, acid-base and transmittance vs molar surface catalysts concentration. 7. Kinetics of dye fading of Non-laboratory activities: phenolphthalein – Flinn Students are given practice problems which require them to ChemTopic Lab, modified analyze concentration vs. time data to determine the rate law to use Vernier LabQuest for zero, first or second order reactions; calculate rate and colorimeters and constants; interpret energy profiles. incorporate techniques and (LO4.2,4.6,4.8) questions in CB [CR3d] Investigation 11 INQUIRY (SP1,2,4,5; LO4.1,4.2 Students will plan out the details of how to perform the Beer’s law calibration experiment and the reaction of phenolphthalein with NaOH in such a way to determine the rate law of the reaction. [CR5b] 6 Unit 4 (Chapters 15-17): Equilibrium Big Idea 6 Fall and Spring Semesters – 8 weeks Topics Laboratory Exercises 8. The Determination of an LO2.2; LO3.7; LO6.1,6.2,6.3,6.4,6.5,6.6,6.7,6.8,6.9,6.10, Equilibrium Constant – 6.11, Vernier #10 (SP2,4,5,6,7; 6.12,6.13,6.14,6.15,6.16,6.17,6.18,6.19,6.20,6.21,6.22,6.23, 6.24,6.25 LO6.1,6.6) Explain that equilibrium occurs when forward and Students will use a reverse rates are equal for a chemical reaction. prescribed procedure to perform a chemical Calculate an equilibrium constant (K) or reaction reaction and use a series quotient (Q) given component concentrations of calculations to Knowing K, calculate initial and equilibrium determine the equilibrium concentrations of reactants and products constant for a system at Apply equilibrium constants (K) and Q to predict the equilibrium. direction of the reaction. 9. Titration Labs – Apply LeChâtelier’s Principle, especially effects of Standardizing a Solution volume, pressure and temperature changes. of Sodium Hydroxide Interpret K in terms of relative concentrations of Vernier #6 and Acid-Base products vs. reactants. Titration - Vernier #7 Identify Brønsted-Lowry acids and bases and (SP2,4,5,6; LO6.12,6.13) conjugate acid-base pairs Students will use titration Draw and interpret particulate diagrams representing technique using Vernier strong, weak, polyprotic acids and strong bases technology, pH probes and Compare strong and weak acids and bases in terms Logger pro (data analysis) of relative pH, dissociation (ionization) and how 10. Titration: How Much they behave in titrations Acid is in Fruit Juice and Relate weak acids and bases to equilibrium Soft Drink? (CB Calculate Ka and Kb Investigation 4) Solve problems using Ka and Kb, including titrations INQUIRY of strong acids with strong bases, strong acids with (SP1,2,3,4,5,6,7; LO1.20, weak bases and weak acids with strong bases. 3.3,6.13) Identify acidic and basic salts Students will devise a plan Explain the common ion effect for collecting data from an Calculate the pH of buffered solutions, calculate acid-base titration in order required concentrations of all species to reach a to determine the acid in particular pH fruit juice and soft drinks. Explain how buffers work, especially with regard to Students will determine addition of a strong acid or a strong base the appropriate lab Relate Ksp to solubilities of salts equipment, tolls, and Solve problems using solubility equilibria - Ksp, indicator to use in including those for solubility performing a titration Relate Q to Ksp – solubilities of mixtures of salts including which measurements are needed Use particulate diagrams to help analyze the thermodynamic changes associated with dissolving and how to obtain them. 7 salts Describe the formation of complex ions Relate free energy (Go) with K Non-laboratory activities: Students are given practice problems (largely old AP Chemistry exam questions) which require them to find Ka, Kb, Ksp or initial or equilibrium concentrations of reactants and/or products or pH; calculate molarity of analytes at different points in a titration and represent the species present with particulate diagrams. (LO6.13,6.16,6.21,6.22) [CR3f] 11. The preparation and testing of an effective buffer: how do components influence a buffer’s pH and capacity? (Buffers – Vernier #19) (SP1,2,4,6,7; LO1.4,6.20) Students devise a procedure for identifying buffering activity for a solution. Students will determine which measurements are needed and how to obtain them. [CR5b] Unit 5 (Chapter 20): Electrochemistry Big Idea 3 Spring Semester – 4 weeks Laboratory Exercises Topics LO3.12,3.13 Define oxidation and reduction Identify oxidized and reduced species in a chemical equation and write half-reactions. Balance oxidation/reduction reactions. Diagram voltaic and electrolytic cells Understand and apply the relationships among Gibbs Free Energy, equilibrium constants, and the EMF of a cell. Calculate work done by a voltaic cell. Non-laboratory activities: Students are given practice problems which require them to identify oxidation-reduction pairs in a chemical equation and balance it using the halfreaction method; identify the components of galvanic and electrolytic cells on a diagram (LO3.12,3.13) [CR3c] 8 12. Electrochemistry: Voltaic Cells (Vernier #20) (SP1,2,3,4,5,6,7; LO3.12,3.13) Students will prepare a variety of semi-microscale voltaic cells in a 24-well test plate and measure the potential of different metals. Test two voltaic cells that use unknown metal electrodes and identify the metals. 13. Electrochemistry Inquiry Lab: Orange Juice Clocks (Talesnick, ChemEd) INQUIRY (SP1,2,3,4,5,6,7; LO3.12,3.13) Students will devise a procedure using different juices to illustrate oxidation-reduction reactions that drive a clock. Students will evaluate the effectiveness of the different juices. [CR5b] Unit 6 (Chapters 6 – 9): Atomic Structure, the Periodic Table, Basic Chemical Bonding and Molecular Geometries Big Ideas 1,2 Chemistry or Honors Chemistry, Summer Work and Spring Semester - 2 weeks Topics Laboratory Exercises 14. Molecular geometries – LO1.5,1.6,1.7,1.8,1.9,1.10,1.11,1.12,1.13,1.14,1.15,1.16 Brown, LeMay et al. #11 LO2.14,2.17,2.18,2.19,2.20,2.21,2.22,2.23,2.24,2.25,2.26, 2.27,2.28,2.29, 2.30,2.31,2.32 (SP1,5,6,7; LO2.21) Describe the quantum mechanical model of the Students will predict the atom and explain why it is better than the shell shapes of molecules by model of the atom (Bohr) building a model of the molecule with foam balls Use Coulomb’s Law as a basis to understand trends and sticks and applying in the periodic table, especially ionization energy Valence Shell Electron Pair Use photoelectron spectroscopy (PES) to deduce Repulsion theory. the structure of a particular element and to identify elements Identify core and valence electrons in multielectron atoms [CR5b] Apply electron configurations to explain the set-up of the periodic table and the properties of elements Write electron configurations for atoms and ions, using position on the periodic table Describe, predict and explain periodic trends in atomic and ionic radii, ionization energy, electronegativity, typical ionic charges and properties based on Coulomb’s Law, the concepts of core and valence electrons, and position on the periodic table Mass spectrometry and its application to the calculation of average atomic mass Use absorbed or emitted radiation to find the concentration of a solution (Beer-Lambert Law) or probe the electronic structure of a particular element or compound Distinguish among ionic, covalent and metallic bonding Predict the type of bonding based on position of the elements on the periodic table Apply the general trends for electronegativity in the periodic table to predictions of types of chemical bonding (bond polarity) Calculate and explain lattice-energies Justify the electron sea model of metallic bonding Draw Lewis Structures for compounds – octet rule 9 and exceptions, resonance structures Describe the shapes of molecules using VSEPR Theory Identify hybrid orbitals Sigma and pi bonds Predict polarity of molecules using bond polarities and VSEPR Associate type of bonding with properties of a given solid substance Draw and explain representations of ionic bonding Compare properties of metal alloys with their constituent elements Draw and explain representations of pure metals and alloys Draw and explain representations of molecular solids, including covalent networks Non-laboratory activities: Students are given practice problems which require them to identify particular elements using PES data; calculate average atomic mass from mass spectrometry data; draw Lewis structures (LO1.6,1.14) [CR3a,3b] 10 Unit 7 (Chapters 10, 11 and 13) Gases, Intermolecular Forces and Properties of Solutions Big Idea 2 Chemistry or Honors Chemistry, Summer Work and Spring Semester - 2 weeks Topics Laboratory Exercises 15. The Molar Volume of a LO2.3,2.4,2.5,2.6,2.7,2.8,2.9,2.10,2.11,2.12,2.13,2.14,2.15,2.16 Gas – Vernier #5 and LO5.9,5.10,5.11 The Molar Mass of a Compare the properties of gases, liquids and solids Volatile Liquid – using particulate models and the kinetic molecular Vernier #3 (SP2,3,4,5,7 theory LO2.6) Apply the Gas Laws – Boyle’s, Charles’, Avogadro’s, Students will use a Ideal Gas law, Dalton’s Law, Graham’s prescribed procedure Apply the Kinetic Molecular Theory to explain and series of properties of gases calculations to collect Describe and explain the behavior of ideal gases vs. real gas samples over water, gases (i.e. deviation from ideal at high pressure, low atmospheric pressure, temperatures, effects of intermolecular forces) and room temperature: Use IM forces to explain properties of solutions – Determine the molar viscosity, surface tension, volumes of mixing (liquids) volume of a gas under and hardness and macroscopic crystal structures (solids) these conditions. Calculate and explain enthalpy changes for phase Students will use a changes prescribed procedure Describe the properties of solutions and series of Methods to separate components of solutions calculations to (chromatography, distillation) determine the Explain energetics of solution formation using relative molecular mass of an strengths of intermolecular/interparticle interactions unknown liquid Explain solubilities in terms of particle structure and 16. Sticky question: How intermolecular forces do you separate Calculate molarity and prepare solutions of particular molecules that are molarities attracted to one another Represent different types of solutions using particle (chromatography)? (CB diagrams Investigation 5) Identify types and characteristics of different IMFs INQUIRY Compare properties of different substances based on (SP1,4,5,6; their structure and IMFs LO2.7,2.10,2.13) Non-laboratory activities: Students are given practice problems which require them to apply the gas laws, draw particulate models of gas behavior, interpret chromatography patterns Students are given short essay questions requiring them to compare properties of different substances based on their intermolecular forces (LO2.5,2.6,2.15,2.16) [CR3b] 11 Students will design an experiment that tests the solvents that they believe will provide the best separation of food dyes Students will evaluate the use of the solvent in terms of “greenness”. [CR5b] List of Laboratory Exercises The Determination of the Percent Water in a Compound – Vernier #2 What makes hard water hard (gravimetric analysis)? (CB Investigation 3) INQUIRY Reactions Lab: Brown, LeMay et al. #4 Classic titration of a strong acid with strong base, with appropriate indicator and no pH sensor The hand warmer design challenge: where does the heat come from? (CB Investigation 12) INQUIRY 6. What is the relationship between the concentration of a solution and the amount of transmitted light through the solution (spectrophotometry)? (using Vernier LabQuest instead of Spec 20) (CB Investigation 1) INQUIRY 7. Kinetics of dye fading of phenolphthalein – Flinn ChemTopic Lab, modified to use LabQuest and incorporate techniques and questions in CB Investigation 11 INQUIRY 8. The Determination of an Equilibrium Constant – Vernier #10 9. Titration Labs – Standardizing a Solution of Sodium Hydroxide -Vernier #6 and Acid-Base Titration - Vernier #7 10. Titration: How Much Acid is in Fruit Juice and Soft Drinks? (CB Investigation 4) INQUIRY 11. The preparation and testing of an effective buffer: how do components influence a buffer’s pH and capacity? (Buffers – Vernier #19) 12. Electrochemistry – Voltaic Cells (Vernier #20) 13. Electrochemistry Inquiry Lab: Orange Juice Clocks (Talesnick, ChemEd 2001) INQUIRY 14. Molecular geometries – Brown, LeMay et al. #11 15. The Molar Volume of a Gas – Vernier #5 and The Molar Mass of a Volatile Liquid – Vernier #3 16. Sticky question: How do you separate molecules that are attracted to one another (chromatography)? (CB Investigation 5) INQUIRY 1. 2. 3. 4. 5. 12