Ch 4 questions 38. Matter is anything that occupies space and has mass. Example: desk, chair 39. protons, neutrons; positive charge equal to the number ofprotons 40. evenly through a sphere 41. They would only be slightly deflected. 42. a. Electron cloud b. protons c. neutron 44. The number of protons equals the number of electrons. 45. 89+ 46. protons and neutrons 47. 1836 51. Rutherford aimed a beam of alpha particles at a thin foil of gold. He expected most of the alpha particles to pass through the gold atoms, confirming the plum pudding model. However, a few particles were deflected at very large angles, which led to the discovery of the positively charged nucleus. 52. The α particles were deflected by the positively charged gold nuclei. 53. The cathode ray was attracted to the positive end of the magnet implying that the cathode ray is negative. 54. attraction to the positively charged nucleus 58. differ: number of neutrons, masses; similar: chemical properties, number of protons and neutrons 59. They are all equal. 60. mass number = number of p + number of n 61. number of no = mass number – atomic number 62. superscript = mass number (40) and subscript = atomic number (19) 63. amu = 1/12 of the mass of a C-12 atom. It’s a relative standard that is closer in size to atomic and subatomic masses. 64. Yes; isotopes are atoms of the same element with different atomic mass but the same number of protons. 66. 44 protons, 44 electrons 67. 6 neutrons 68. mass number is 200 69. mass number is 131 70. 18 protons 71. S = (31.972amu)(0.9502) + (32.971amu)(0.0075) + (33.968 amu)(0.0421) + (35.967 amu)(0.0002) = 32.065 amu 72. Element Atomic Number Mass Number Protons Neutrons Electrons Cl 17 35 17 18 17 Cl 17 37 17 20 17 73. a. 55 electrons, 55 protons, 77 neutrons b. 27 electrons, 27 protons, 32 neutrons c. 69 electrons, 69 protons, 94 neutrons d. 30 electrons, 30 protons, 40 neutrons 74. a. 31 electrons, 31 protons, 38 neutrons b. 9 electrons, 9 protons, 14 neutrons c. 22 electrons, 22 protons, 26 neutrons d. 73 electrons, 73 protons, 108 neutrons 75. a. 23, 23 b. 25, 25 c. 77. 77 d. 16, 16 Zr 40 90 40 50 40 Zr 40 92 40 52 40 76. Ga-69 must be more abundant because the atomic mass of gallium is closer to the mass of Ga-69 then the mass of Ga-71. 77. 107.86 amu 78. 51.99 amu 79. Radioactive decay occurs when unstable nuclei spontaneously (without input of energy) lose energy by emitting radiation. 80. The stability of atoms depends on their neutrons-to-proton ratio. When this ratio is either too large or too small the nucleus of an atom becomes unstable causing an atom to be radioactive. 81. by emitting radiation or a particle 82. alpha particle: helium atom with a 2+ charge; beta particle: electron; gamma rays: high energy radiation 83. symbol Mass α: 24He 4 Charge β ϒ 1/1840 0 -1 0 +2 84. nuclear reaction 85. α, mass number decreases by 5; β, no change in mass number; ϒ no change in mass number 86. the neutron-to-proton ratio 87. Radioactivity results when unstable nuclei emit energy in order to gain stability. 88. stable, nonradioactive atom must be formed 89. 55 10 5 B → 36Li + 24He 137Cs → 56137Ba + -10e