Everything Conversions - Key 1. What is the molecular formula of a substance with an empirical formula of C3H4O3 and a formula mass of 176? 3(12.0) + 4(1.01) + 3(16.0)= 88.0 176.0 = 2.0 88.0 Molecular formula = 2 * C3H4O3 or C6H8O6 2. Calculate the number of molecules of NBr3 in 37.5 g NBr3. 37.5g NBr3 1 x 1 mole x 254g NBr3 6.02 x 1023 molecules NBr3 = 8.89 x1022 molecules NBr3 1 mole 3. How many moles are in 14.0g of N2? 14.0g N2 x 1 mole = 0.500 moles N2 1 28.0g N2 4. What is the percent composition of each of the elements in CH3COOH? Carbon = 2 x 12.0 g = 24.0 g Hydrogen = 4 x 1.01 = 4.04 g Oxygen = 2 x 16.0 = 32. 0 g formula mass is 60.0 Carbon: (24.0 g / 60.0 g) x 100 = 40.0% Hydrogen: (4.04 g / 60.0 g) x 100 = 6.73 % Oxygen: (32.0 g / 60.0 g) x 100 = 53.3% 5. Benzoic acid contains 68.8% carbon, 4.95% hydrogen, 26.2% oxygen. What is the empirical formula for benzoic acid? 68.8g C 1 x 1 mole C 12.0 g = 5.73moles C 5.73/1.64 = 3.49 (Multiply by 2) = 7 4.95g H 1 x 1 mole H 1.01 g H = 4.90 moles H 4.90/1.64 = 2.99 (Multiply by 2) = 6 26.2g O 1 x 1 mole O 16. 0g O = 1.64 moles O 1.64/1.64 = 1(Multiply by 2) = 2 Empirical formula is: C7H6O2 6. Convert 0.877moles RbI to molecules. 0.877 moles RBI x 6.02 x 1023 molecules RbI = 5.28 x 1023 molecules RBI 1 1 mole 7. What is the molecular formula of a substance with an empirical formula of HgF and a formula mass of 4.40x102? (440 with zero being SD) 201 + 19.0 = (2.20 x102) or 220 (knowing zero is SD) 4.40 x102 = 2.00 2.20x102 Molecular formula = Hg2F2 8. How many grams of copper sulfide make up 3.71 x1025 atoms of copper sulfide? 3.71 x 1025 atoms CuS x 1 mole x 95.6g CuS = 5891.6 g CuF 5890g CuF 1 6.02 x 1023 atoms CuS 1 mole 9. A compound consists of 40.0% calcium, 12.0% carbon, and 48.0% oxygen by mass. What is the empirical formula? 40.1 Ca 1 x 12.0g C 1 x 1 mole C 12.0 g C 48.0 O 1 1 mole Ca 40.0 g Ca x 1 mole O 16.0 g O = 1.00 mole Ca = 1.00 moles C = 3.0 moles O 1.00/1.00 = 1 1.00/1.00 = 1 3.00/100 = 3 Empirical formula = Ca(CO3) 10. Convert 9.51 x1021 ions As to grams. 9.51 x 1021 ions As x 1 mole 1 6.02 x 1023 ions As x 74.9g As = 1.18g As 1 mole 11. Determine the empirical formula of a compound that is 78.5% Cs, 12.5% O. 78.5g Cs x 1 mole = 0.590 moles Cs 1 133 g Cs 0.590/0.590 = 1(*3) = 3 12.5g O x 1 mole = 0.781 moles O 1 16.0 g O Empirical formula = Cs3O4 0.781/0.590 = 1.23 (*3) =47 12. What is the molecular formula of the compound in #11 if it’s molecular mass is 926g? 926/ 463 = 2 Molecular formula is: Cs6O8 13. What is the percent composition of each of the elements in the compound Iron (III) Sulfide? Fe2S3 55.8 (2) = 53.8% 32.1 (3) = 46.3% 208 208 14. Convert 86.0g of H2S to molecules. 86.0 g H2S x 1 mole x 6.02 x 1023 molecules H2S = 1.52 x 1024 molecules H2S 34.1 g H2S 1 mole 15. What is the empirical formula of a compound if a sample contains 7.22g Nickel, 2.53 g Phosphorus and 5.25g of Oxygen? 7.22 g Ni x 1 moleNi = 0.123 mol Ni 1 58.7g Ni 0.123/0.0816 = 1.5 (*2)= 3 2.53g P x 1 mole P = 0.0816 mol P 1 31.0g P 0.0816/0.0816 = 1 (*2)= 2 5.25g O x 1 mole O = 0.328 mol O 1 16.0g O 0.328/0.0816 = 4(*2) = 8 Empirical formula = Ni3P2O8 or Ni3(PO4)2 16. How many molecules are in 5.62 moles of water? 5.62 moles H2O x 6.02 x 1023 molecules H2O = 3.38 x 1024 molecules H2O 1 1 mole H2O