Prescriptive Activities: Facet Cluster 1.6: PF#64 Teacher Page Prescriptive #64: 64 The student doesn't know how many electrons are in a full shell (octet) for most atoms versus how many electrons are in a full shell for H, He, and Li1+, or Be2+ limiting their ability to predict bonding. Materials: Student handout Background: You have learned that electrons exist in different energy levels around the nucleus and that atoms that have a full outermost energy level are particularly stable. While it is true that most atoms require a full “octet” of 8 electrons in their outermost energy level to be stable, a few atoms are “full” with less than this. In particular, the four lightest elements, hydrogen (H), helium (He), lithium (Li) and beryllium (Be) tend to exist with only two electrons. Two electrons fills the first energy level .Thus, whereas we often refer to the “octet rule” for determining bonding, in the case of these four elements we can refer to the “duet rule” which simply means they are stable with two outermost electrons. For hydrogen, this means sharing one electron with another atom. This explains why hydrogen only forms covalent bonds with a single atom at a time, such as in HF or HCl. A helium atom consists of 2 protons, 2 neutrons and 2 electrons (illustrated at right). Since it already contains 2 electrons in its outermost shell it is stable and un-reactive and exists as individual atoms. Protons and neutrons are shown in red and blue and electrons are represented by the small grey circles which exist within the “electron cloud”. Note: at this scale the electrons would be much smaller and about ½ mile away from the nucleus. Helium atom Prescriptive Activities: Facet Cluster 1.6: PF#64 Teacher Page When lithium reacts it tends to lose one electron, to form a Li+ ion, with only two electrons in its outermost energy level. A beryllium atom contains 4 protons and 4 electrons. Two of these electrons fill the first energy level and the other two are in the 2nd energy level. When beryllium reacts with another element do you think that it would be “easier” for beryllium to gain six electrons to have eight in its outermost shell or to lose its two outer electrons, thereby having a full shell containing only two electrons? Lithium atom Beryllium does in fact lose two electrons when reacting with nonmetals and becomes stable with the remaining two electrons in its outermost shell. Questions: 1. How many electrons can exist within the first energy level of an atom? ______ 2. How many electrons can exist within the second energy level of an atom? ______ 3. How many valence electrons does lithium (Li) have? ______ 4. When lithium metal reacts with a nonmetal, does lithium obtain a full outer shell, by gaining or losing electrons? 5. How many electrons are gained or lost by lithium? 6. How many electrons are now in the outermost energy level of lithium? 7. Draw a representation showing hydrogen sharing electrons with carbon (C) in methane (CH4). Hydrogen has 1 electron and carbon has 6 (2 in its inner energy level and 4 in its valence energy level). 8. Why can hydrogen form only one bond? Teacher Notes: Students must already understand about energy levels of electrons, and that we cannot define exactly where electrons exist, but only a region in which they exist most of the time (usually defined as 90% of the time). Prescriptive Activities: Facet Cluster 1.6: PF#64 Teacher Page Beryllium does in fact lose two electrons when reacting with nonmetals and becomes stable with the remaining two electrons in its outermost shell. When reacting with nonmetals, the nonmetal does in fact remove two electrons from beryllium, which becomes stable with the remaining two electrons in its outermost shell.