CHAPTER 6- FIBERS Fibers 1. ________________________________________________________ 2. ________________________________________________________ 3. ________________________________________________________ 4. Can be characterized based on comparison of both physical and chemical properties Fabric 1. ________________________________________________________ 2. ________________________________________________________ 3. Types of fibers and fabric: - Natural—____________________________________________ - Artificial—____________________________________________ Types of Fibers Synthetic __________________ __________________ __________________ __________________ __________________ __________________ Natural _____________________ _____________________ _____________________ _____________________ _____________________ Classification Natural fibers are classified according to their origin: 1. ________________________________________________________ 2. ________________________________________________________ 3. ________________________________________________________ Cellulose Fibers 1. Cotton—_________________________________________________ ________________________________________________________ 2. Rayon—_________________________________________________ ________________________________________________________ 3. Cellulose acetate—________________________________________ ________________________________________________________ Fiber Comparison Describe the difference(s) between the cotton on the left and the rayon on the right. ____________________________________________________________ ____________________________________________________________ ____________________________________________________________ Protein Fibers 1. Wool—__________________________________________________ ________________________________________________________ ________________________________________________________ 2. Silk—___________________________________________________ ________________________________________________________ Mineral Fibers 1. Asbestos—______________________________________________ ________________________________________________________ 2. Rock wool—_____________________________________________ 3. Fiberglass—_____________________________________________ Synthetic Fibers Made from derivatives of ________________________________________ 1. Nylon—_________________________________________________ 2. Polyester—______________________________________________ 3. Acrylic—________________________________________________ 4. Spandex—_______________________________________________ Man-made Fibers Fibers derived from ____________________________________________ – – SUMMARY QUESTIONS: Read p. 128-135 in the textbook 1) Why are fibers valuable at a crime scene? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 2) How do fibers have probative value? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 3) How are fabrics made? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 4) What are the different characteristics of a fiber, a filament & a fabric? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 5) Are inorganic fibers natural or synthetic? Name two. ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ Fabric Production 1. ________________________________________________________ ________________________________________________________ ________________________________________________________ 2. Most are either ______________ or ________________ 3. ________________________________________________________ ________________________________________________________ ________________________________________________________ Weave Terminology 1. Yarn—__________________________________________________ ________________________________________________________ 2. Warp—__________________________________________________ 3. Weft—__________________________________________________ 4. Blend—_________________________________________________ ________________________________________________________ Weave Patterns Plain Weave 1. ________________________________________________________ 2. ________________________________________________________ 3. Design resembles a _____________________ Twill Weave 1. ________________________________________________________ ________________________________________________________ 2. ________________________________________________________ 3. Design resembles ____________________ 4. _____________ is one of the most common examples. Satin Weave 1. ________________________________________________________ 2. ________________________________________________________ 3. ________________________________________________________ 4. ___________ is the most obvious example Knitted Fabric 1. ________________________________________________________ ________________________________________________________ 2. It may be one continuous thread or a combination. 3. ________________________________________________________ ________________________________________________________ ________________________________________________________ Polymers 1. Synthetic fibers are made of _________________________________ ________________________________________________________ 2. The word polymer means many (poly) units (mer). 3. ________________________________________________________ 4. By varying the ________________________________________ or by _____________________________________, polymers are created that have different properties. 5. As a result of these differences, they can be distinguished from one another forensically. Filament Cross Sections 1. ________________________________________________________ ________________________________________________________ 2. The holes of the nozzle are not necessarily round; therefore, the fiber filament may have a unique shape in cross section. Round 4-lobed Octalobal Trilobal Irregular Dogbone or Dumbbell Multi-lobed or Serrate Summary Questions: Read p. 136-143 in the textbook 1. What is the monomer of a polymer? ___________________________________________________________________ ___________________________________________________________________ 2. What is the monomer of wool? In silk? In cotton? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 3. List four synthetic fibers. ___________________________________________________________________ 4. What is the most common natural fiber used in textiles? The most common synthetic fiber? ___________________________________________________________________ ___________________________________________________________________ 5. Why does wool have a distinctive smell when it is burned? ___________________________________________________________________ ___________________________________________________________________ 6. How is silk produced? ___________________________________________________________________ ___________________________________________________________________ 7. Why is silk a simpler structure than wool? ___________________________________________________________________ ___________________________________________________________________ 8. What is rayon? ___________________________________________________________________ ___________________________________________________________________ 9. How are acetate fibers made? What products are formed from acetate fibers? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 10. Why was the discovery of Nylon 66 important? ___________________________________________________________________ ___________________________________________________________________ 11. Which of the fabrics found in Activity 6.3 would have the most probative value in an investigation? Which would have the least? Explain. ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 12. How are the properties of a linear polymer different from a cross-linked polymer? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 13. Identify the two types of acrylic fibers and their uses. ___________________________________________________________________ ___________________________________________________________________ 14. What is the structure of spandex (Lycra) What is the significance of fiber evidence? 1. Can prove _______________________________________________ 2. Can prove _______________________________________________ 3. Value is dependent on: • ________________________________________________ • ________________________________________________ • ________________________________________________ • ________________________________________________ Fiber as trace evidence Primary Transfer ____________________________ ____________________________ ____________________________ Secondary Transfer ____________________________ ____________________________ ____________________________ Using fibers to reconstruct crime scenes 1. ________________________________________________________ 2. The _________ & ___________________ of the fabric. 3. Mobility of victim ____________________________________________________ 4. The length of time between actual physical contact. __________________________________________________________ ______________________________________________ Testing for Identification 1. Microscopic observation 2. Burning — ______________________________________________ ________________________________________________________ 3. Thermal decomposition — _________________________________ ________________________________________________________ 4. Chemical tests — _________________________________________ 5. Density — the _____ of an object divided by the ______ of the object 6. Refractive index — _______________________________________ ________________________________________________________ 7. Fluorescence — __________________________________________ ________________________________________________________ Dyes 1. Components that make up dyes can be separated and matched to an unknown. 2. There are more than ______________________________________ 3. ________________________________________________________ 4. ________________________________________________________ ________________________________________________________ Collection of Fiber Evidence 1. ________________________________________________________ ________________________________________________________ ________________________________________________________ 2. ________________________________________________________ ________________________________________________________ 3. ________________________________________________________ ________________________________________________________ Fiber Evidence 1. ________________________________________________________ ________________________________________________________ 2. In the case of Wayne Williams, fibers weighed heavily on the outcome of the case. Williams was convicted in 1982 based on carpet fibers that were found in his home, in his car, and on several murder victims. Problems with Fiber Evidence 1. Class Characteristic ____________________________________________________ 2. The less common the fiber the more useful it is to identify a suspect. __________________________________________________________ ______________________________________________ Basic Comparison of Fiber Samples 1. ________________________________________________________ 2. ________________________________________________________ 3. ________________________________________________________ 4. ________________________________________________________ 5. ________________________________________________________ Summary Questions: Read p. 144-161 in the textbook 1) Can a fiber be individualized to a particular textile fabric? Why of how? ___________________________________________________________________ ___________________________________________________________________ 2) Can a piece of fabric be individualized to a particular garment? Why or how? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 3) If an unknown fiber is suspended in a solution with a density of 1.30, what might the fiber be? ___________________________________________________________________ 4) If the same fiber in question 3 is found to have a refractive index of 1.53, what might it be? ___________________________________________________________________ 5) How is the Becke line used to determine Refractive Index? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 6) Explain how an optical brightener may change how light reacts with fibers. ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 7) If a fiber disappears in castor oil, what might it be? ___________________________________________________________________ 8) How is chromatography used in identifying the make up of dyes? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 9) What is trace evidence? What is the common basis for analyzing trace evidence, that is, what are the goals? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 10) During a trial, what are the primary concerns in analyzing and using extremely small bits of trace evidence? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 11) How do forensic scientists use FTIR to analyze fibers? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 12) How does the FBI use a crook’s jeans to catch them? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ 13) How did Fibers & their analysis play a major role in the Amanda Davis case? ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________ ___________________________________________________________________