Dynamica en Residu’s van Pesticiden Drift van pesticiden 9. Drift van pesticiden 1. INTRODUCTION: AGRICULTURAL SPRAY APPLICATIONS .................................. 2 2. DEFINITION OF DRIFT........................................................................................ 5 3. FACTORS THAT AFFECT DRIFT.......................................................................... 7 3.1 DROPLET SIZE DISTRIBUTION ..................................................................... 7 3.1.1 Nozzle type and size ................................................................................ 7 3.1.2 Spray pressure ........................................................................................ 9 3.1.3 Physicochemical properties of the spray liquid ........................................ 9 3.2 WEATHER CONDITIONS ............................................................................. 12 3.2.1 Wind ..................................................................................................... 12 3.2.2 Temperature and Air Humidity .............................................................. 12 3.2.3 Atmospheric Stability ............................................................................ 13 3.3 SURROUNDING CHARACTERISTICS ........................................................... 15 3.3.1 Crop type .............................................................................................. 15 3.3.2 Neighbouring structures at the field borders ......................................... 15 4. MEASUREMENTS OF DRIFT ............................................................................. 16 4.1 WIND TUNNEL MEASUREMENTS ............................................................... 17 4.2 FIELD MEASUREMENTS ............................................................................. 18 5. TOWARDS DRIFT REDUCTION ...? ................................................................... 19 6. DRIFT RISK ASSESSMENT ............................................................................... 23 -1- Dynamica en Residu’s van Pesticiden Drift van pesticiden 1. INTRODUCTION: AGRICULTURAL SPRAY APPLICATIONS World-wide, most pesticides are applied through hydraulic sprayers of various size and complexity. From the smallest knapsack to aerial equipment, the main parts are a tank, a pump and a set of nozzles, interconnected by pipes/hoses and control valves. Aerial equipment (not further discussed here) is common in America. In Europe, spraying equipment at ground level is used. We can distinguish two kinds of ground spray applications: Spray application for orchards (e.g. fruit orchard, vineyard…) and spray applications for fields [e.g. grasslands and field crops (potatoes, wheat, sugar beets…)]. In orchards vertical spray equipments are used (figure 1), whereas in fields we encounter horizontal spray booms (figure 2). Figure 1. Examples of orchard spraying Figure 2. Example of field spraying Spray nozzles are mounted to the boom. Nozzles can be classified according to the type of energy that is used to atomize the liquid into a spray: hydraulic, rotary or air-blasted. Hydraulic nozzles are the most important in agricultural spraying: Liquid is atomized by being forced under pressure (hydraulic energy) through the nozzle tip forming droplets. In this way a spray is created. See figure 3. Rotary nozzle: The spray liquid is atomised into droplets by a spinning disc. The higher the rotation speed, the finer the droplets. -2- Dynamica en Residu’s van Pesticiden Drift van pesticiden Air-blast nozzle: An air stream at high velocity is used to blast the spray liquid into droplets. Figure 3. Example of a spray nozzle (left) and a nozzle spray (right) A very important characteristic of the spray is its droplet size. The finer the droplets, the better the coverage of the canopies and the pests. Figure 4 illustrates this. If the droplet diameter is reduced from 400 µm to 50 µm for a constant amount of sprayed liquid, then 512 (=28 where 8 = 400 µm/50 µm) droplets instead of one single droplet can be formed, and hence the coverage and biological efficiency of the insecticide strongly increase! Figure 4. Illustration of the relation between droplet size and coverage of an insect pest On the other hand, spraying with fine droplets (< 150 µm) leads to drift (figure 5). Drift is defined as the quantity of pesticide active ingredients (a.i.) that is deflected out of the treated area by air currents at the moment of spray application. The deposition of a.i. outside the target field can have negative effects on the health of humans and the environment (especially surface waters are known to be driftsensitive), it also leads to economical losses. -3- Dynamica en Residu’s van Pesticiden Drift van pesticiden Figure 5. Illustration of drift Note that the droplet size is an interaction between three factors: nozzle selection (size and type), spray pressure and physicochemical properties of the spray liquid (viscosity and surface tension). These parameters will be discussed later on. The droplet size is not one single value, but it is a uniform distribution of sizes, which shows a maximum. An example of a droplet size distribution spectrum is given in figure 6. Figure 6. Droplet size distribution spectrum of a spray with nozzle FF 110 03 at pressure 3 bar The left spectrum of figure 6 is only presented here to give an idea of the shape and the magnitude of a droplet size spectrum, but this kind of spectrum is not used in reality! The spectrum is commonly expressed on a logarithmic scale, as illustrated in the middle graph. The most important parameter derived of the spectrum is the Volume Median Diameter (VMD or Dv0.5), which is defined as the droplet size of which 50 % of the spray volume has a higher diameter than this value, and 50 % has a lower diameter than this value. Therefore droplet size distributions are often presented as cumulative logarithmic spectrum (right graph in figure 6), because in this way of presenting, the VMD value is easily derived out of the graph. -4- Dynamica en Residu’s van Pesticiden Drift van pesticiden The VMD values do not give an indication of how broad the range of the distribution is. As illustrated in figure 7 (left), two spectra can have the same VMD value, but the blue spectrum is broader than the orange one. Figure 7. Illustration of Dv0.1, VMD and Dv0.9 values For this reason, the Dv0.1 and the Dv0.9 values are defined respectively similarly as: - the diameter value for which 10 % of the spray volume has a lower diameter value, and 90 % has a higher value - the diameter value for which 90 % of the spray volume has a lower diameter value, and 10 % has a higher value The Dv0.1 and Dv0.9 values give indications on how large the ranges of the spectra are. Again it is better to present the cumulated spectrum (figure 7, right) because in this way of presenting, the Dv0.1 and Dv0.9 values are easily derived out of the graph. 2. DEFINITION OF DRIFT Spray drift is defined as the quantity of plant protection product that is deflected out of the treated area by air currents at the moment of, or after, spray application. The deposition of plant protection products outside the target field can have negative effects on the health of humans and the environment (De Schampheleire et al., 2006). Spray drift is also an undesired phenomenon because it causes great economical losses. -5- Dynamica en Residu’s van Pesticiden Drift van pesticiden Figure 8. Particle spray drift (left) versus evaporation drift (right) There are two forms of spray drift: particle spray drift and evaporation spray drift. Figure 8 illustrates the differences: Particle spray drift occurs immediately the moment of spraying, while evaporation spray drift happens afterwards spraying. Even days or weeks after spray application, evaporation drift can occur. Also see figure 5 for a realistic particle spray drift-scenario! This course deals with particle spray drift. For shortness in the text that follows, we will briefly talk about ‘drift’. Drift is expressed as percentage (%) of the application dose (l/ha or kg/ha) in function of the distance. For example if one says that there is 5 % percent drift for an application dose of 180 l/ha of a herbicide at 5 m from the field border, then this l means that at 5 m distance of the field border we will find 9 l/ha 5% * 180 of ha herbicide. Figure 9 gives an example of a typical drift curve in function of the distance at 15 °C temperature, 60 % relative air humidity and 2.3 m.s-1 wind speed. DRIFT IN GRASSLAND (t° = 15 °C, R.H. = 60 %, v = 2.3 m/s) 6 Drift (%) 5 4 3 2 1 0 0 5 10 15 Distance from field border (m) Figure 9. Example of a drift curve for grassland -6- 20 25 Dynamica en Residu’s van Pesticiden Drift van pesticiden 3. FACTORS THAT AFFECT DRIFT The main factors that affect drift are droplet size distribution of the spray, weather conditions and surrounding characteristics. 3.1 DROPLET SIZE DISTRIBUTION As already mentioned, spray droplet size distribution is an interaction between nozzle (type and size), spray pressure and physicochemical properties of the spray liquid. Good coverage is essential for insecticides and fungicides because of the small size of the target organism (see figure 4). Therefore, small- to medium-size droplets are desirable when applying insecticides and fungicides because they provide better penetration into the canopy and better coverage. However, small droplets can drift long distances. The smaller the droplets, the lighter they are and the more driftprone. It is stated that droplets smaller than 150 µm in diameter pose the most serious drift hazards, while some researcher take 100 µm as drift-prone limit. 3.1.1 Nozzle type and size There are a lot of nozzle designs available on the market. For agricultural sprayings the most important nozzles are the hydraulic nozzles. Some commonly used hydraulic nozzles are explained below. Flat Fan nozzle and Low-Drift nozzle The Flat Fan (FF) nozzle was already illustrated in figure 3. Figure 10 shows how a Low-Drift (LD) nozzle operates. An LD nozzle is an FF nozzle with an extra orifice. The pre-orifice creates an extra compartment (turbulence chamber) before the nozzle tip. When the spray liquid enters this compartment, the pressure of the liquid drops, and thus the liquid looses some of its energy and has less energy to break up in droplets. Coarser droplets will be formed at the nozzle tip. -7- Dynamica en Residu’s van Pesticiden Drift van pesticiden Figure 10. Construction of an FF nozzle and an LD nozzle Air Induction nozzle The air induction (AI) nozzle (figure 11) consists of a narrow channel that ends into the nozzle tip. At the beginning of the channel there is an air hole, through which air is sucked in a natural way (Venturi principle) when liquid is being forced through the channel under pressure. Inside the channel there is an intens mixing between the liquid and the air phases due to the high shear forces. At the nozzle tip, where the spray liquid is atomized into droplets, the air is incorporated inside the droplets as small air bubbles. In this way – due to the incorporation of air – coarser droplets are generated compared to the FF nozzle. Air hole Nozzle tip Figure 11. Construction of an AI nozzle Nozzle codes Nozzles are indicated with a code that consist of 3 parts: - A part that gives information on the nozzle type (FF, LD or AI) - A part that gives information on the nozzle spray angle (80°, 90°, 110° or 120°) -8- Dynamica en Residu’s van Pesticiden - Drift van pesticiden A part that gives information on the nozzle size (02, 03, 04 or 06) For example the code ‘FF 110 03’ means a Flat Fan nozzle with spray angle 110 ° (see figure 12 for an illustration of the spray angle) and nozzle tip opening 03. The code ‘LD 120 02’ means a Low-Drift nozzle with spray angle 120 ° and nozzle tip opening 02. 110° Figure 12. Spray angle of a hydraulic nozzle The nozzle tip opening is given as 02, 03, 04 or 06. This number indicates the numbers of gallons that are atomized through the nozzle tip when water is being atomised through the nozzle at a constant spray pressure of 3 bar. For example an FF 110 02 nozzle gives a volume rate of 2 gallons a minute at spray pressure 3 bar, while the FF 110 04 nozzle has a volume rate of 4 gallons a minute at spray pressure 3 bar. 3.1.2 Spray pressure Of course spray pressure is also a determining factor for the droplet size. Table 1 illustrates the effect of spray pressure on the VMD for an FF 110 03 nozzle. Table 1. VMD values for F 110 03 @ various spray pressures Spray VMD pressure 2 bar 270 µm 3 bar 175 µm 4 bar 150 µm 3.1.3 Physicochemical properties of the spray liquid The physical properties of the tank mix, atomized during a spray application, can affect the droplet size spectrum, and therefore the drift potential. -9- Dynamica en Residu’s van Pesticiden Drift van pesticiden Several researchers examined the drift-reducing (or -inducing) effect of additives or adjuvants, but they used a solution of the additive or the adjuvant in water, while it is generally known that not the physicochemical properties of the additive or the adjuvant itself, but the physicochemical characteristics of the complete spray mixture is the determining factor for droplet size, and hence drift. The major physicochemical properties affecting atomization are: - Extensional viscosity E - Surface tension γ - Density Extensional Viscosity E Fluids offer some degree of resistance to shearing motion. This resistance to shearing motion is a form of internal friction called viscosity. Viscosity tends to resist liquid stretching, thereby affecting atomization. An increase in extensional viscosity can produce coarser sprays. Viscosity is calculated out of the time a fluid needs to flow through a vertical, bulbed capillary between two marked points (upper mark and lower mark) under the influence of gravity. A schedule of a viscosity meter is given in figure 13. Figure 13. Equipment for the measurement of viscosity of agricultural spray liquids (ASTM E2408–04) The absolute viscosity of a fluid is calculated as η = α.t where t is the time the fluid needs to flow between the two marks and α is a constant that is characteristic for - 10 - Dynamica en Residu’s van Pesticiden Drift van pesticiden the viscosity meter (depending on diameter of the capillary, dimensions of the bulb…). The value for α can be calculated by measuring t for distilled water, since ηwater is a known value (ηwater = 1.10-3 N.s.m-2 at 20 °C). For spray liquids, absolute viscosities are rarely used. One rather defines the viscosity in a relative fashion, as the “extensional viscosity”. Extensional viscosity E is measured (equation 1) as the ratio of tf and tw where tf is the flow time of the spray liquid between the upper and the lower fixed mark of the viscosity meter, and tw is the flow time for water (not distilled water, but tap-water, which was used to formulate the spray liquid). E tf (Eq. 1) tw Surface Tension γ Molecules in liquid state experience strong intermolecular attractive forces, they are referred to as cohesive forces. The cohesive forces between liquid molecules are responsible for the phenomenon known as surface tension: The molecules in the centre of the liquid experience net force zero, while the molecules at the surface experience a net inwards force (figure 14). Figure 14. illustration of the attractive forces between molecules of a liquid To increase the surface of the liquid, energy is needed to overcome these inward forces. The energy dW (Work) needed to expand the liquid surface area with one unit dA (Area) is defined as the surface tension γ: dW dA (Eq. 2) - 11 - Dynamica en Residu’s van Pesticiden Drift van pesticiden Surface tension tends to resist atomization, so a decrease in surface tension tends to cause a decrease in droplet size. Density The density of a liquid may affect atomization, as with rotary atomizers, where higher density causes the rotation rate to decrease, with a resultant increase in droplet size. However, with hydraulic nozzles in agricultural sprays, where the density is similar for most spray liquids (equalling the density of water = 1 kg.l -1), density may not have a significant effect on atomization. 3.2 WEATHER CONDITIONS Wind is the main weather condition affecting drift. Temperature, air humidity and atmospheric stability also affect drift, but their effect is less pronounced than the effect of the wind. 3.2.1 Wind The higher the wind speed, the more doplets will be blown away and cause drift. According legislation, it is not allowed to apply field sprayings above a wind speed of 5 m.s-1. When sensitive areas are located in the neighbourhood of the sprayed field (surface waters, recreation area, parcel with sensitive crop…), then the wind direction also becomes an important parameter. 3.2.2 Temperature and Air Humidity Most days there is a correlation between temperature and air humidity (R.H. = Relative Humidity). High temperature correlates with low R.H., and vice versa. Figure 15 illustrates the effect of temperature and R.H. on drift. In the right case, the R.H. is low (20 %) and the temperature is high (30 °C). The water content of the droplets evaporates, the droplets refine, and they become drift-prone. In the left case, the R.H. is high (80 %) and the temperature is low (15 °C). The droplets behold their water content, no drift occurs. - 12 - Dynamica en Residu’s van Pesticiden Drift van pesticiden t° = 15 °C t° = 30 °C Figure 15. Influence of R.H. and temperature on drift 3.2.3 Atmospheric Stability Note that when one talks about wind, then the horizontal movement of air, caused by the local differences in air pressure, is meant. Atmospheric stability is defined as the vertical movements of air layers, caused by Height the differences in temperature between these layers. UNSTABLE CONDITION Temperature Height Dominating wind direction NEUTRAL CONDITION Height Temperature Dominating wind direction STABLE CONDITION Temperature Height INVERSION Dominating wind direction Temperature Figure 16. Influence of atmospheric stability on the movement of a smoke plume in the atmosphere - 13 - Dynamica en Residu’s van Pesticiden Drift van pesticiden Four regimes are distinguished. They are illustrated in figure 16 with the chimney – smoke plume story. Remember from your physics course that air expands when it is heated! Hot air therefore has a lower density than cold air, and thus has the tendency to rise… Depending on the temperature profile in function of the height above the earth surface, the air will move into a certain direction… - Unstable condition Temperature strongly decreases with height. Hot air is situated near the earth’s surface, and cold air in the upper layers. The smoke plume spreads out in an upwards direction. There is ‘vertical mixing’. The chance that drift damage occurs is low, because the pesticides are strongly diluted into the atmosphere. But because a main part of the sprayed pesticides is lost into the atmosphere, it is not advisable to perform spray applications under these circumstances! - Neutral condition Temperature slightly decreases with height. This condition occurs in the morning, after the inversion layer (see further), that has been built up during the night, breaks up. There is a slight, upwards spreading-out of the plume. This is a good condition to perform a spray application. - Stable condition Temperature increases with height. The heavy (cold) air is situated near to the earth surface, while the hotter air layers are located at higher heights. The smoke plume is ‘pushed’ towards the earth surface. Stable conditions are often accompanied with low wind speeds (it is often difficult to distinguish the effects of wind speed and stability in this condition). Sprayings are allowed. - Inversion We talk about an ‘inversion’ when a maximum in the temperature profile is found. Then there is an isolated layer of cold air near the earth surface. This phenomenon typically occurs when the night has been clear with little wind; the earth surface then looses more heat than it receives. The inversion slowly disappears in the morning. - 14 - Dynamica en Residu’s van Pesticiden Drift van pesticiden When a spraying is performed under these circumstances, the drift cloud will stay located at its constant height, between the two cold layers. When there is wind, the suspended pesticide particles are able to move horizontally towards distant places. In this way highly concentrated drift clouds can be transported far away from the field, and cause serious contamination problems elsewhere. Sprayings are not allowed when there is an inversion! 3.3 SURROUNDING CHARACTERISTICS Two types of surroundings considering drift are distinguished: The crop type that is being sprayed, and intercepting structures neighbouring the field. 3.3.1 Crop type In the Netherlands, drift experiments were performed in different crop types (bare ground, potatoes, sugar beets and cereals) and in fruit orchards (leafless trees and trees with leafs). Figure 17 illustrates the results for some of the measurements. They were performed under ‘typical’ Dutch weather conditions. 50 aardappelen Potatoes (conventioneel) 45 40 suikerbieten Sugar beets Drift (%) 35 30 granen Cereals 25 blote Baregrond soil 20 15 10 5 0 0 2 4 6 8 10 12 14 Distance (m) Figure 17. Drift results for field measurements in the Netherlands 3.3.2 Neighbouring structures at the field borders Sometimes field borders (1 m – 5 m) are left unsprayed to intercept drifting pesticide droplets. These ‘buffer zones’ can be bare, or a drift-intercepting vegetation can be - 15 - Dynamica en Residu’s van Pesticiden Drift van pesticiden grown on them, for example a grain border. In orchards, hedgerows are often used for this purpose. It is also possible to surround the field borders with artificial structures, like screens and shrouds. Little research has been done on the effect of these structures on drift. 4. MEASUREMENTS OF DRIFT Two tools are used to perform drift experiments: the wind tunnel and field experiments. A wind tunnel is an artificially constructed corridor in which a wind can be generated with the aid of a fan. Figure 18 gives a scheme of the wind tunnel of the International Centre for Eremology (I.C.E.), at Ghent University, Belgium. This closed-circuit blowing-type wind tunnel has a 12-m long, 1.2-m wide and 3.2-m high test section. Figure 18. Discription of the wind tunnel by Cornelis The advantages of the wind tunnel are that the experiments take place under conditioned circumstances: Wind speed can be controlled, so the experiments have a high repeatability. Field experiments on the other hand take place under unconditioned circumstances since we cannot control the weather conditions! Field - 16 - Dynamica en Residu’s van Pesticiden Drift van pesticiden experiments are also more laborious and time consuming than wind tunnel measurements. But the main disadvantage of wind tunnel experiments is that they are not realistic… The wind tunnel is an ideal screening tool to evaluate drift-influencing factors, e.g. a set of LD nozzles is compared to a set of FF nozzles. In a second phase, based on the wind tunnel outcome, field experiments are conducted with the nozzles that were found to be drift-reducing under wind tunnel circumstances. In this way a lot of time, labour and money can be saved! 4.1 WIND TUNNEL MEASUREMENTS The set – up for drift tests in the wind tunnel is given in figure 19. Figure 19. Set – up for drift measurements in the wind tunnel The spray nozzle is placed at a fixed height of 0.5 m at the beginning of the test section. At this height the wind speed has a constant value of 4.0 – 4.1 m.s-1. The relative humidity and the temperature are kept constant at values 42 – 44 % and 16 – 17 °C. Ground collectors (paper strips) are placed at distances 0.25 m, 0.35 m, 0.50 m, 0.75 m, 1 m, 1.25 m, 1.75 m, 2.25 m, 3.5 m, 4.65 m and 6 m in plastic drains incorporated in the false bottom of the tunnel. Each spraying is performed for 15 seconds at a constant spray pressure. Spray pressure can be chosen between 2 bar to 6 bar. As spray liquid, various liquids, containing a tracer, can be used: - To evaluate the influence of spray application technique on drift (nozzle type, nozzle size and spray pressure), a solution of 150mM NaCl is used. The - 17 - Dynamica en Residu’s van Pesticiden Drift van pesticiden paper strips are collected immediately after spraying and extracted into a known amount of distilled water (100 ml – 500 ml). The concentrations of Na+ in the extraction water are determined with Flame Atomic Absorption Spectroscopy (FAAS). - To evaluate the influence of the physicochemical properties of the spray liquid on drift (various commercial pesticide formulations), the active ingredients (a.i.) of the formulations are used as tracer. The paper strips are collected immediately after spraying and extracted into a known amount of hexane (100 ml – 500 ml). The concentrations of the a.i. in the hexane are determined with GC-MS, GC-ECD or HPLC. In the wind tunnel experiments, drift is expressed as a volume percentage of the sprayed volume. This sprayed volume is mathematically calculated out of the spraying time (15 sec), the spray pressure (2 – 4 bar) and the nozzle tip opening size (02 – 04). 4.2 FIELD MEASUREMENTS Field experiments are performed in a grassland (meadow) with a Hardi Commander Twin Force field sprayer with boom length 27 m (see figure 20 - left) at the agricultural research centre ILVO (http://www.ilvo.vlaanderen.be) at Merelbeke. Figure 20. Spraying equipment (left) and set – up (right) for drift measurements in grassland The test-site consists of a spraying and a sampling zone (figure 20 – right). The spraying zone has dimensions 100 m x 27 m. The drift is collected on filter paper ground collectors with dimensions 0.25 m x 0.25 m. Three parallel rows of these ground collectors (fig. 20 – ■) are placed in the sampling zone. In each row the collectors are placed at distances 0.5 m, 1 m, 2 m, 3 m, 5 m, 10 m, 15 m and 20 m. - 18 - Dynamica en Residu’s van Pesticiden Drift van pesticiden The sprayings are done perpendicular to the wind direction. The spray liquid consists of a solution of the fluorescent tracer Brilliant Sulfo Flavine (BSF) in water. The filter papers are collected immediately after spraying. The fluorescent dye BSF is extracted from the filter papers in a known volume of water. The concentration of BSF in the extraction water is determined with a fluorimeter. Out of these concentrations, the amounts of drift collected by the filter papers are calculated. Drift percentages are expressed as percentages of the applied dose. Fluorescent dyes such as BSF are sensitive to UV – light. Therefore three filter papers are also placed windward the test – site (fig. 20 - ●). A correction factor, to bring into account for the photochemical breakdown of BSF, and also for the extraction efficiency of the filter papers in water, is determined by grafting these 3 papers with a known amount of BSF. The correction factor is calculated as the amount of BSF recovered from these papers to the amount grafted on it. A weather station is used to monitor wind speed, wind direction, temperature and relative humidity (RH). 5. TOWARDS DRIFT REDUCTION ...? Based on what we have seen in this course, we can formulate following fist-rules to avoid drift: - Use LD and AI nozzles instead of FF nozzles. Since LD and AI nozzles generate coarser droplets, less drift will occur, this is especially the case with AI nozzles (90 % or more drift reduction, compared to LD nozzles which give medium reductions of 50 %). On the other hand… do AI nozzles offer a solution? Recently it is reported in literature that some AI nozzles have lower biological efficiencies since the droplets they produces are too coarse (see p. 3: we need small droplets for good coverage of the canopies and pests!). - Use the lower end of spray pressure range. Manufacturers of nozzles give a pressure range in which their nozzles should be applied. Enquiries have shown that farmers have the tendency to use the higher end of the pressure range, and a lot of farmers even spray at higher pressures than the highest end! - Increase nozzle size. - 19 - Dynamica en Residu’s van Pesticiden - Drift van pesticiden Spray at favourable weather conditions, such as low wind speed, low temperature and high RH. Avoid spraying during temperature inversions! - Do not spray when wind is directed towards sensitive areas and surface waters. - Drive not to fast with the spray equipment. Typical driving speeds for ground sprayers are 4 – 8 km.h-1. High driving speeds (> 8 km.h-1) will cause air flows (turbulences) around the boom, so small droplets will be captured by drift. - Take a low as possible boom height (in case of field spraying – see figure 2). The higher the boom height, the longer the distance that droplets need to travel towards the canopy/pest, so the more change there is that the droplets are captured by drift. Note: Driving speed of the tractor and boom height are not free to choose. For example driving speed is determining for the application dose (l.ha-1). Lowering driving speed increases the application dose. Figure 21 gives an illustration of the importance of the boom height. The profiles of the spray cones should be slightly overlapping at ground level. If boom height is lowered too much, the spray cones will not be sufficiently overlapping anymore. Figure 21. Boom with spray nozzles - The spray equipment can be provided with shields and shrouds as driftintercepting structures, figure 22 gives an example for field spraying (shielded boom) and orchard spraying (tunnel spraying) - 20 - Dynamica en Residu’s van Pesticiden Drift van pesticiden Figure 22. Shielding of a boom (left) and tunnel spraying in fruit orchards (right) - Drift-intercepting structures can also be introduced at the field borders. In orchards natural hedgerows (this can be the last row of the fruit trees) are commonly used. In field crops field margins of a certain width are left unsprayed. These ‘buffer zones’ can be provided with a natural vegetation (the crop itself or a grain border) or an artificial structure, such as a screen (figure 23). Figure 23. Artificial screen bordering the field - The spray equipment can be provided with air assistance along the boom (figure 24). In this system an air flow is generated to ‘blow’ the droplets straight towards the canopy. Note: air assistance ≠ air-blast nozzles (p.3)! - 21 - Dynamica en Residu’s van Pesticiden Drift van pesticiden Figure 24. Spray tractors equipped with air-assistance (= grey bags at the boom) - Electrostatic spraying is a topic of the future. In this system droplets are given an electrostatic charge, so an electric field is induced between the droplets and the canopy. In this way an additional attractive force, directed towards the canopy, is given to the droplets. - Drift-retardants can be added to the spray liquid. This practice is not yet in use in Europe, but it is popular in America. Drift-retardants are polymers, which increase viscosity of the spray liquid (p.10-11), so coarser droplets are generated. In the past polyacrylamide (PAM) was popular in America, but the last few years, concerns on the use of PAM have risen. It is believed that under certain conditions of sunlight (UV light) PAM unzips into its monomer acrylamide. Acrylamide is carcinogenic. On the other hand acrylamide is not very stable in nature, it is readily micro-biodegraded, but at places where the concentration of PAM is high, acrylamide can be formed more rapidly than it is broken down, so human exposure problems could occur. Polyacrylate [polyacryl acid (PAA)] is an alternative, but at pH = 5.514, PAA is negatively charged (carbonic acid!). In combination with some spray formulations, this can give rise to problems (e.g. interaction with other components of the spray liquid with the formation of insoluble particles). Polyethers, polyesters, polyvinyls… were found to be irreversibly destroyed by the high shear forces, during the (re)circulation of the spray mix in the pipes/hoses/nozzles… of the spraying equipment. Hot topic drift-retardants are the natural polymers. They are natural sugars, thus the toxicity is low and the biodegrability is high. Guar - 22 - Dynamica en Residu’s van Pesticiden Drift van pesticiden gum is already in use in America. In the future, more polymeric sugars will undoubtedly become important: xanthane gum, inuline… 6. DRIFT RISK ASSESSMENT For information on drift risk assessment it is referred to De Schampheleire et al. (2006): De Schampheleire M, Spanoghe P, Brusselman E & Sonck S. 2006. Risk assessment for pesticide spray drift damage in Belgium. Crop Protection – in press. - 23 -