Types of Reactions Purpose: The purpose of this lab is to observe some chemical reactions and identify the reactants and products of the reactions. Also, to classify each reaction and to write balanced equations. Purpose: Synthesis Experiment 1: 1. Examine a piece of copper and note its appearance 2. Using tongs, hold the copper in the hottest part of a burner flame for 1-2 minutes 3. Examine the copper and note any changes Experiment 2: 1. Place a watch glass near the base of the burner 2. Examine a piece of magnesium ribbon. Note its appearance 3. Using tongs, hold the magnesium in the flame until it starts to begin CAUTION: do not look directly at the flame, 4. Hold the magnesium away from you and over the watch glass until it stops burning. Put the remains in the evaporate dish. Make final observations. Decomposition Experiment 3: 1. Place a spatula full of potassium chlorate (KClO3) in a crucible. Make observations 2. Heat to melting 3. Light a wood splint. Blow out the flame and insert the glowing end into the crucible to test for oxygen gas. (CAUTION; do not allow your splint to fait into the liquid) Experiment 4: 1. Place two heaping spatulas full of copper (II) carbonate (CuCO3) into a clean, dry test tube. Make observations. 2. Using a test tube holder, heat the CuCO3 strongly in a burner flame for about 3 minutes. 3. Light a wood splint and then extinguish the Bunsen burner 4. Insert the burning splint into the test tube to test for the presence of carbon dioxide (CO2) gas- Note any change in the material in the test tube. Single Replacement Experiment 5: 1. Place a clean, dry test tube in a test tube rack 2. Add about 5 mL of 6m hydrochloric acid (HCl) to the test tube (CAUTION: handle the acid with care. It can cause painful burns 3. Make observations of HCl and Zinc 4. Carefully drop a small piece of zinc into the test tube. 5. Using a test tube holder, carefully invert another test tube over the top of the first one 6. Wait approximately 30 seconds to collect the gas 7. Remove the inverted tube and quickly insert a burning splint into the mouth of the tube to test for hydrogen gas. Make final observations Experiment 6: 1. Add about 5 mL of copper (II) sulfate (CuSO4) solution to a clean, dry test tube 2. Make initial observations of CuSO4 and Zinc 3. Place a small piece of zinc metal into the solution 4. Shake test tube occasionally 5. Wait at least 10-15 minutes. Make final observations Double Replacement Experiment 7: 1. Make initial observations of both chemicals 2. Add about 2 mL of potassium iodide (KI) to a clean, dry test tube 3. Add 2 drops of lead nitrate (Pb(NO2)3) to the same tube 4. Make final observations **Caution – do not put this reaction down the drain Experiment 8: 1. Make initial observations of both chemicals 2. In a clean test tube place 5 drops of iron (III) chloride (FeCl3) add 1 to 3 drops of potassium thiocayanate (KSCN) 3. Make final observations Observation Table: Sample Cu Mg KClO3 CuCO3 Before During After Balanced Equation Solid Thin Shiny Bronze Darker color, silver edges Gray solid darker 2Cu(s)+ O2(g)2CuO(s) Silver Thin strip shiny Bendable Bright white light white powder solid 2Mg(s)+O2(g)2MgO(s) white crystals solid Melting Clear liquid, bubbling Cracking noise Smoke Positive test for oxygen 2KClO3(s)3O2(g)+2KCl(s) Green powder Burning Turns black Dancing Positive test for carbon dioxide Black solid CuCo3(s) CO2(g)+ CuO(S) Type Synthesis Synthesis Decomposition Decomposition Zn & HCl Zinc- small gray, HCl- Clear aqueous solution Bubbling ,bubbles exploding on top Positive Test for hydrogen Zn(s)+2HCl(aq)ZnCl2(aq)+H2(g) Single Replacement Zn & CuSO4 Zinc- small gray CuSO4- Blue aqueous solution Solid chunks, zinc breaking up Bronze solid, blue liquid,black chunk Zn(s)+ CuSO4(aq)ZnSO4(aq) + Cu(s) Single Replacement Pb(NO3)2 & KI Lead nitrateclear liquid solution Liquid, solid particles forming, cloudy liquid, solid chunks Clear liquid, yellow solid chunks Pb(NO3)2+2KI2K(NO3)+Pb l2 DoubleReplacement Potassium iodine- clear liquid solution FeCl3 & KSCN Iron Chlorideorange liquid solution Black liquid, red outer trim Potassium thiocyanateclear liquid solution Red stain on test tube, Black thin liquid sticks to side, no chunks FeCl3+3KSCN 3KCl+Fe(SCN)3 DoubleReplacement Questions: 1. The test used to test for Carbon Dioxide gas was a wood splint test. A burning wood splint was entered into the test tube. If the splint was extinguished there is Carbon Dioxide present. 2. To test for hydrogen, a burning splint is placed in the test tube. If it makes a popping noise, hydrogen gas is present. Example: 2H2(g) + O2(g) 2H2O(l) 3a. AgNO3(aq)+Cu(s) CuNO3 + Ag Single Replacement b. BaCl2(aq) + Na2SO4(aq) NaCl + BaSO4 Double Replacement c. Cl2(g) + 2NaBr(aq) 2ClBr + 2Na Single Replacement d. 2KClO3(s) 3O2 + 2KCl Decomposition e. AlCl3(aq) + 3NH4OH(aq) 3NH4Cl + Al(OH)3 Double Replacement f. 2H2(g) + O2(g) 2H2O(l) Synthesis Conclusion: The purpose of this lab is to observe some chemical reactions and identify the reactants and products of the reactions. Also, to classify each reaction and to write balanced equations. A new lab technique used in this lab was the splint test which tested for Carbon Dioxide gas. A lite wood splint is entered into a test tube with the solution. If the flame was extinguished then the test is positive for the gas. A new technique used in this lab was predicting products. Predicting products is writing a balanced equation from the given solutions. Table F in the Chemistry Reference Table is needed when finding the state of matter that solutions are. When doing single replacement Table J is needed to see if some solutions can replace others. Synthesis is a reaction that is a combination of two solutions to form a new solution. A formula for synthesis is A + BAB. An example of synthesis is 2Cu(s)+ O2(g)2CuO(s). Copper and Oxygen combined to form a new solution. Decomposition is a reaction where a single solution separates to form two different solutions. A formula for decomposition is ABA+B. An example of decomposition is 2KClO3(s)3O2(g)+2KCl(s) where potassium chlorate forms oxygen and potassium chloride. Single replacement is a reaction when a single element replaces another that was in a compound. A formula for single replacement is AB + CAC + B. An example of single replacement is Zn(s) + CuSO4(aq)ZnSO4(aq). Reference table J is needed when doing single replacement. Double replacement is a reaction when an element in a compound replaces another element in a compound. A formula for double replacement is AB+CDAD+CB. An example of double replacement is Pb(NO3)2+2KI2K(NO3)+Pbl2.