Name: ____________________________ Northwest Vista College Chem 1311 - General Chemistry I Spring 2012 Practice- Chapter 4 (25 pts) Please write legibly. Show your work to get full credit, when appropriate! 1. (2 pts) Identify each of the following substances as a strong electrolyte, weak electrolyte, or nonelectrolyte: a) H2O b) KCl c) CH3COOH d) C12H22O11 2. (1 pts) Characterize the following compounds as soluble or insoluble in water: a) Ca3(PO4)2 b) Mn(OH)2 c) AgClO3 d) K2S 3. (3 pts) Write ionic & net ionic equations for the following reactions, include state labels: a) AgNO3 (aq) + Na2SO4 (aq) 1 b) BaCl2 (aq) + ZnSO4 (aq) c) (NH4)2CO3 (aq) + CaCl2 (aq) 4. (1 pts) Identify each of the following species as a Brønsted acid, base, or both: a) HI b) CH3COOc) H2PO4d) HSO4- 5. (3 pts) Balance the following equations and write the corresponding net ionic equations (if appropriate): (HBr is a strong acid) a) ____ HBr (aq) + ____ NH3 (aq) (Ba(OH)2 is a strong base) (H3PO4 is a weak acid) (Mg(ClO4)2 is soluble) b) ____ Ba(OH)2 (aq) + ____ H3PO4 (aq) c) ____ HClO4 (aq) + _____ Mg(OH)2 (s) 2 6. (4 pts) For the complete redox reactions given here, (i) break down each reaction into its half-reactions; (ii) identify the oxidizing agent; (iii) identify the reducing agent. a) 2Sr + O2 2SrO b) 2Li + H2 2LiH c) 2Cs + Br2 2CsBr d) 3Mg + N2 Mg3N2 7. (3 pts) Give the oxidation number of the underlined atoms in the following molecules & ions: a) ClF g) NaHCO3 b) IF7 h) Li2 c) CH4 i) NaIO3 d) K2CrO4 j) KO2 e) K2Cr2O7 k) PF6- f) KMnO4 l) KAuCl4 8. (1 pts) Calculate the mass of KI in grams required to prepare 5.00 x 10 2 mL of 2.80 M solution. 3 9. (1 pts) How many moles of MgCl2 are present in 60.0 mL of 0.100 M MgCl2 solution? 10. (2 pts) Calculate the molarity of each of the following solutions: a) 29.0 g of ethanol (C2H5OH) in 545 mL of solution b) 9.00 g of sodium chloride (NaCl) in 86.4 mL of solution 11. (1 pts) How would you prepare 60.0 mL of 0.200 M HNO3 from a stock solution of 4.00 M HNO3? 4 12. (1 pts) How many grams of NaCl are required to precipitate most of the Ag+ ions from 2.50 x 102 mL of 0.0113 M AgNO3 solution? Write the net ionic equation for the reaction. 13. (1 pts) A quantity of 18.68 mL of KOH solution is needed to neutralize 0.4218 g of KHP. What is the concentration (in molarity) of the KOH solution? (KHP - potassium hydrogen phthalate, KHC8H4O4) 14. (1 pts) Iron(II) can be oxidized by an acidic K2Cr2O7 solution according to the net ionic equation: Cr2O72- + 6Fe2+ + 14H+ 2Cr3+ + 6Fe3+ + 7H2O If it takes 26.0 mL o 0.0250 M K2Cr2O7 to titrate 25 mL of a solution containing Fe2+, what is the molar concentration of Fe2+? 5