Name: __________________________________ Date: __________________ Class/Period: _____________________________ A Little Review . . . Directions: Read each of the following questions carefully and answer in the space provided. If a question requires a calculation, SHOW ALL WORK! No work, no credit, no kidding! Remember to use units and significant figures where appropriate. Good luck! Chemical Reactions 1. Fill in the blanks below with the name of one of the five types of chemical reactions: synthesis, decomposition, single displacement, double displacement, and combustion. a) one reactant breaks down into two or more products ____________________________ b) element + compound → element + compound ____________________________ c) hydrocarbon + oxygen → carbon dioxide + water ____________________________ d) two ions trade places with each other in compounds ____________________________ e) two or more substances make one product ____________________________ 2. Identify the TYPE of chemical reaction below. a) 2 H2 + O2 → 2 H2O ____________________________ b) 2 KIO3 → 2 KI + 3 O2 ____________________________ c) Fe + CuSO4 → FeSO4 + Cu ____________________________ d) Li2SO4 + Pb(NO3)2 → 2 LiNO3 + PbSO4 ____________________________ e) C3H8 + 5 O2 → 3 CO2 + 4 H2O ____________________________ The Mole and Mole Conversions 3. The SI unit used to measure an amount is a(n) ____________________. 4. What is molar mass? ___________________________________________________________________ 5. Calculate the molar mass of: a) CuSO4 ________________ b) octane 6. a) ____________________ = 1 mole = ____________________ b) 6.02 x 1023 is called __________________________________. ________________ 7. How many moles are in 315 grams of magnesium chloride? ___________ 8. How many grams are in 7.6 moles of dinitrogen trioxide? ___________ 9. How many atoms are in 8.40 moles of aluminum (Al)? ___________ 10. How many molecules are in 88.0 grams of carbon dioxide? ___________ 11. How many moles are in 7.05 x 1024 atoms of carbon (C)? ___________ 12. How many grams are in 6.02 x 1023 formula units of LiCl? ___________ 13. a) What is an empirical formula? _________________________________________________________ b) What is a molecular formula? __________________________________________________________ 14. Compare the following formulas: C4O2H8 and C2OH4. a) Which is the empirical formula? _________________ Why? _________________________________ b) Which is the molecular formula? _________________ Why? ________________________________ 15. a) What is the empirical formula for C6H14? ____________________ b) What is the empirical formula for H2O2? ____________________ 16. Explain how to find an empirical formula when given the percent composition of each element in the compound. 17. a) Determine the empirical formula for a compound containing 1.203% of calcium and 2.128% of chlorine. b) A compound has the empirical formula CH2O. If its molar mass is 150 g/mol, what is the molecular formula of the compound? __________ Stoichiometry 18. a) What is stoichiometry? ______________________________________________________________ ________________________________________________________________________________ b) Upon what is stoichiometry based? ______________________________________________ 19. a) What is a mole ratio? _______________________________________________________________ b) Should a mole ratio ever be reduced? __________ Explain why or why not. ______________________ ________________________________________________________________________________ 20. Use the chemical reaction below to answer the following questions. 4 FeCl3 + 3 O2 → 2 Fe2O3 + 6 Cl2 a) What is the mole ratio between iron (III) chloride and chlorine in the equation below? _______________ b) What is the mole ratio between chlorine and oxygen? ______________________ 21. Balance the equation below, and then use it to answer the following questions. ___ LiOH + ___ PbSO4 → ___ Pb(OH)2 + ___ Li2SO4 a) How many moles of Pb(OH)2 will be produced from 3.0 moles of LiOH assuming you have an excess of PbSO4. ___________ b) If you need to make 750 g of Pb(OH)2, how many moles of LiOH would you need? ___________ c) What mass (in grams) of Li2SO4 will be produced with 72.0 grams of LiOH? ___________ d) What mass (in grams) of PbSO4 is required to make 4.00 moles of Li2SO4? ___________ Limiting and Excess Reactant Stoichiometry 22. a) What is a limiting reactant? __________________________________________________________ b) What is an excess reactant? __________________________________________________________ 23. You are making one ham sandwich at home for lunch. The recipe requires that you have 3 slices of ham, 2 pieces of bread, 2 pieces of Swiss cheese, and 1 tablespoon of mayonnaise. You find that you have 9 slices of ham, 4 slices of bread, 2 pieces of Swiss cheese, and 10 tablespoons of mayonnaise. Which ingredient would be the limiting reactant? ___________ 24. Examine the general chemical reaction below, and use it to answer the question that follows. 3A + B → C If you have 9 moles of A and 5 moles of B, which would be the limiting reactant? ___________ 25. Examine the general chemical reaction below, and use it to answer the question that follows. X2 + 2 Y → 2 XY If you have 7 moles of X2 and 8 moles of Y, which would be the limiting reactant? ___________ Solutions 26. What is a solution? ___________________________________________________________________ 27. a) What is a solute? __________________________________________________________________ b) What is a solvent? __________________________________________________________________ 28. You have a 25% aqueous solution of potassium bromide. Identify the solute and solvent. Solute: ___________________ Solvent: __________________ 29. a) What substance is nicknamed the “universal solvent”? _______________________ b) Why is this substance given this nickname? _______________________________________________ ________________________________________________________________________________ ________________________________________________________________________________ ________________________________________________________________________________ 30. a) Explain the phrase “like dissolves like” using the words polar and nonpolar. ________________________ ________________________________________________________________________________ ________________________________________________________________________________ b) Explain why oil and water do not mix to form a solution. ______________________________________ ________________________________________________________________________________ ________________________________________________________________________________ 31. a) Ionic solutes dissolve best in which type of solvent: ionic or covalent? _________________ b) Covalent solutes dissolve best in which type of solvent: ionic or covalent? _______________ c) Would sodium chloride dissolve best in water or hexane? __________________ d) Would carbon tetrachloride dissolve best in water or hexane? ______________ 32. The three main types of solutions are saturated, unsaturated, and supersaturated. Use the description below to identify the type of solution described. a) To which type of solution could you add more solute to it and have it dissolve simply by agitating it? _________________ b) Which type of solution will have some solute remaining unchanged at the bottom of the container? _________________ c) Which type of solution dissolves more than the maximum amount of solute by increasing temperature? _________________ 33. Use the graph below to answer the following questions. Solubility as a Function of Temperature a) How much KCl dissolves in 100 g of water at 80C? _______________ b) 90 g of NH4Cl dissolves at 90C in 100 g of water. Is this solution saturated, unsaturated, or supersaturated? _______________ c) Which of the solutes on the graph behave as gases? _______________ d) At 80C, a saturated solution of potassium chlorate is made. If the solution cools to 30C, how much solute will precipitate out? _______________ e) How much cerium sulfate will dissolve in 300. g of water at 20C? ________________ 34. What is the molarity of a solution containing 6.0 moles of solute dissolved in 2.00 L of solution? __________ 35. What volume of solution is needed to make a 3.0 M solution containing 109.5 g of HCl? ___________ 36. a) What is a colligative property? ________________________________________________________ ________________________________________________________________________________ b) Label whether the following increase or decrease when a solute is added to a pure solvent: i. Freezing point _____________________________ ii. Boiling point _____________________________ iii. Vapor pressure _____________________________ Acids and Bases 37. List three physical properties of an acid and one chemical property. physical property: _________________________________________________ physical property: _________________________________________________ physical property: _________________________________________________ chemical property: _________________________________________________ 38. List three physical properties of a base and one chemical property. physical property: _________________________________________________ physical property: _________________________________________________ physical property: _________________________________________________ chemical property: _________________________________________________ 39. a) Distinguish between a strong acid and a weak acid. b) Distinguish between a strong base and a weak base. 40. Compare and Contrast an Arrhenius acid and base and a Bronsted-Lowry acid and base by filling in the chart below. Acid Base Arrhenius Definition Bronsted-Lowry Definition 41. Read the reaction below from left to right. Identify the acid, base, and conjugate acid (CA) and conjugate base (CB). HCl _____ + NH3 _____ ↔ NH4+ _____ + Cl- _____ 42. Examine the description below and determine whether it describes a strong acid, weak acid, strong base, or weak base. a) dissociates completely (~100%) and turns blue litmus red ___________ b) partially dissociates, stays clear in phenolphthalein, orange on pH paper ___________ c) dissociates completely (~100%) into OH- ions ___________ d) dimly lights up conductivity apparatus (light bulb) and turns pink in phenolphthalein ___________ e) brightly lights up conductivity apparatus (light bulb) and has a pH of 2.1 ___________ f) dissociates completely (~100%) into H+ ions ___________ g) dimly lights up conductivity apparatus (light bulb) and turns red litmus blue ___________ h) dissociates completely (~100%), turns red litmus blue, and has a pH of 12.9 ___________ 43. a) What type of double displacement reaction occurs when an acid reacts with a base? _________________ b) What are ALWAYS the two products when an acid reacts with a base? ___________ and ____________ 44. If you spilled oven cleaner containing sodium hydroxide on the kitchen counter, what could be used to “counteract” this spill? ___________________________ 45. A flask contains 1 L of 5 M Mg(OH)2. Which of the following would completely “counteract” this solution? a) 1 L of 5 M HCl b) 1 L of 5 M Mg(OH)2 c) 0.5 L of 2.5 M HCl d) 0.5 L of 2.5 M Mg(OH)2 46. Draw the pH scale from 0 to 14 and label the acidic, basic, and neutral pH’s. 47. What is another word for a basic solution? ________________________