Unit 6a Question Packet Chemical Formulas & Equations Name …………………KEY……………………… Period …………. SKILLS 1. 2. 3. 4. counting ATOMS IN FORMULAS counting IONS IN IONIC FORMULAS identifying MOLECULAR & EMPIRICAL FORMULAS NAMES TO FORMULAS and FORMULAS TO NAMES SKILL #1: 5. BALANCING EQUATIONS 6. applying the LAW OF CONSERVATION OF MASS 7. identifying TYPES OF REACTIONS - refer to your notes & RB p. 73 & 87 COUNTING ATOMS IN FORMULAS 1. Fill in the table below. Put an “M” if the substance is molecular/covalent, an “I” if ionic, and an “H” if a hydrate. Total Total Formula Moles of each moles of Formula Moles of each moles of atom atoms atom atoms HClO3 CaCl2 1 mol H atoms 1 mol Ca atoms a. 5 f. 3 1 mol Cl atoms 2 mol Cl atoms I I 3 mol O atoms NH4C2H3O2 b. I Mg(OH)2 c. I LiCl4H2O d. e. SKILL #2: H CH3COOH I 1 mol N atoms 7 mol H atoms 2 mol C atoms 2 mol O atoms 1 mol Mg atoms 2 mol O atoms 2 mol H atoms 1 mol Li atoms 1 mol Cl atoms 8 mol H atoms 4 mol O atoms Mg3(PO4)2 12 5 g. h. I CH3CH2CH3 M Al(SCN)3 14 i. I NH4Cl5H2O 2 mol C atoms 4 mol H atoms 2 mol O atoms 8 j. counting IONS IN IONIC FORMULAS H 3 mol Mg atoms 2 mol P atoms 8 mol O atoms 13 3 mol C atoms 8 mol H atoms 11 1 mol Al atoms 3 mol S atoms 3 mol C atoms 3 mol N atoms 1 mol N atoms 1 mol Cl atoms 14 mol H atoms 5 mol O atoms 10 21 - refer to your notes, RB p. 73, and Table E! 2. Complete the table below. Use Table E!!! Ionic Compound Cation (+ ion) Anion (- ion) Total moles of ions Ionic Compound Cation (+ ion) Anion (- ion) Total moles of ions a. NH4C2H3O2 NH4+ C2H3O2– 2 e. CaF2 Ca2+ 2 F– 3 b. Ba(NO3)2 Ba2+ 2 NO3– 3 f. Al2O3 2 Al3+ 3 O2– 5 c. Li2CO3 2 Li+ CO32– 3 g. KMnO4 K+ MnO4– 2 d. NaHCO3 Na+ HCO3– 2 h. (NH4)3PO4 3 NH4+ PO43– 4 SKILL #3: – refer to your notes & RB p. 74 identifying MOLECULAR & EMPIRICAL FORMULAS 3. Below are a list of formulas. Write the empirical formula (if not already empirical). SKILL #4: a. C4H10 C2H5 b. C3H6 CH2 c. N2O4 e. C6H10 C3H5 i. K2S2O3 (ionic) f. Al2O3 (ionic) g. NH4NO3 (ionic) h. C11H22O11 CH2O j. S2O4 k. CH4 l. C6H12Cl2O2 C3H6ClO SO2 NO2 d. Na2SO4 (ionic) – refer to your notes & RB p. 75-78 NAMES TO FORMULAS and FORMULAS TO NAMES 4. Write formulas for the following ionic substances. Name sodium chloride aluminum oxide barium iodide gallium nitride Formula NaCl Al2O3 BaI2 GaN Name zinc sulfide potassium fluoride lithium bromide strontium chloride Formula ZnS KF LiBr SrCl2 5. What do the ionic compounds in #4 all have in common? How are they named? They all contain two elements only. Metal: always first (element name) Nonmetal: element root w/ -ide ending 6. Write formulas for the following ionic substances. Use Table E. Name sodium sulfate aluminum chromate magnesium hydrogen carbonate lithium permanganate rubidium oxalate Formula Na2SO4 Al2(CrO4)3 Mg(HCO3)2 LiMnO4 Rb2C2O4 Name barium phosphate calcium hydroxide potassium hydrogen sulfate ammonium chloride sodium acetate Formula Ba3(PO4)2 Ca(OH)2 KHSO4 NH4Cl NaC2H3O2 7. What do the ionic compounds in #6 all have in common? How are they named? They all contain polyatomic ions. + ion: always first (element name or ammonium) - ion: second (name on Table E) 8. Write formulas for the following ionic substances. Use Table E if needed. Name Formula lead(II) iodide copper(I) nitrate iron(III) sulfate chromium(V) chloride platinum(II) oxide Name Formula manganese(III) oxide copper(II) nitrate gold(III) oxide titanium(IV) phosphide iron(II) hydroxide PbI2 CuNO3 Fe2(SO4)3 CrCl5 PtO Mn2O3 Cu(NO3)2 Au2O3 Ti3P4 Fe(OH)2 9. What do the ionic compounds in #8 all have in common? How are they named? They all contain metals w/ more than 1 possible charge (oxidation state). + ion: always first (element name or ammonium Charge of metal ion goes as Roman numeral in ( ) - ion: second (name on Table E or root / ide ending) 10. Write IUPAC names the following ionic compounds. Name Formula Name Formula lithium bromide LiBr lead(II) sulfate PbSO4 silver oxide Ag2O sodium hydrogen carbonate NaHCO3 barium nitride Ba3N2 nickel(III) sulfate Ni2(SO4)3 tin(II) oxide SnO titanium(III) oxide Ti2O3 magnesium nitrate Mg(NO3)2 aluminum sulfite Al2(SO3)3 copper(I) phosphide Cu3P aluminum cyanide Al(CN)3 cobalt (III) oxide Co2O3 ammonium chloride NH4Cl silver bromide AgBr potassium nitrate KNO3 sodium nitrate NaNO3 calcium carbonate CaCO3 potassium iodide KI ammonium carbonate (NH4)2CO3 sodium hypochlorite NaClO sodium thiosulfate NaS2O3 iron(III) hydroxide Fe(OH)3 yttrium bromide YBr3 11. Write formulas for the following molecular substances. Name Formula dinitrogen trioxide diphosphorus pentoxide sulfur dioxide silicon dioxide xenon hexafluoride tetraphosphorus decoxide Name Formula silicon tetrafluoride carbon tetrachloride boron triiodide carbon disulfide phosphorus pentabromide boron trihydride N2O3 P2O5 SO2 SiO2 XeF6 P4O10 SiF4 CCl4 BI3 CS2 PBr5 BH3 12. Write IUPAC names for the following molecular substances. Name Formula Name Formula dinitrogen pentoxide N2O5 dihydrogen monosulfide H2S sulfur hexafluoride SF6 boron trifluoride BF3 phosphorus tribromide PBr3 phosphorus trihydride PH3 sulfur trioxide SO3 dihydrogen monoxide (water) H2O diboron tetrahydride B2H4 chlorine Cl2 SKILL #5: – refer to your notes & RB p. 79, 81 BALANCING EQUATIONS 13. Balance the following equations using the smallest, whole-number coefficients. a. __3__Mg *Start w/ O + ____Mn2O3 __3__MgO + __2__Mn b. _____C6H12O6 ___2__C2H5OH + ___2__CO2 *Start w/ H c. _____C3H8 + __5__ O2 __4__ H2O + __3__ CO2 *start w/ C or H d. __2__FeCl3 + ____Be3(PO4)2 *Start w/ Be, Cl, or (PO4) __3__BeCl2 + __2__FePO4 e. __4__NH3 + *Start w/ H __3__O2 __2__N2 + __6__H2O f. __3__ C2H4O2 + ____ PCl3 __3__ C2H3OCl + ____ H3PO3 *start w/ Cl *g. _____Fe2O3 + __3___CO __2__Fe + __3__CO2 * must start w/ O, want an EVEN # of O’s on both sides, so CO gets a 3 in front SKILL #6: – refer to your notes & RB p. 81 applying the LAW OF CONSERVATION OF MASS 14. Given the reaction: 2H2 + O2 2H2O What is the total mass of water formed when 8 grams of hydrogen reacts completely with 64 grams of oxygen? 8 g + 64 g = X 72 g = X 15. When glucose is fermented, it produces ethanol and carbon dioxide. If 60.0 grams of glucose is fermented and produces 16.5 grams of carbon dioxide gas, what mass of ethanol is produced? Glucose ethanol + CO2 60 g = X + 16.5 g 43.5 g = X 16. A 4.86-gram sample of calcium reacted completely with oxygen to form 6.80 grams of calcium oxide. This reaction is represented by the balanced equation below. 2Ca(s) + O2(g) 2CaO(s) Determine the total mass of oxygen that reacted. 4.86 g + X = 6.80 g X = 1.94 g 17. Given the following incomplete equations, write the formula of the molecule represented by X. a. X + Cl2 C2H5Cl + HCl C2H6 b. 4Fe + 3O2 2X Fe2O3 18. Which equation represents conservation of mass? (1) H2 + Cl2 HCl (2) H2 + Cl2 2HCl (3) H2 + O2 H2O SKILL # 7: (4) H2 + O2 2H2O – refer to your notes & RB p. 80 identifying TYPES OF REACTIONS 19. Complete the table below. Equation Reactant(s) Product(s) Type of Reaction a. Cl2 + 2NaI 2NaCl + I2 Cl2 + NaI NaCl + I2 Single replacement b. HNO3 + LiOH H2O + LiNO3 HNO3 + LiOH H2O + LiNO3 Double replacement c. 2NaN3 2Na + 3N2 NaN3 Na + N2 decomposition d. Ba(NO3)2 + K2SO4 2KNO3 + BaSO4 Ba(NO3)2 + K2SO4 KNO3 + BaSO4 Double replacement e. BaO + SO3 BaSO4 BaO + SO3 BaSO4 synthesis f. 2Al + Fe2O3 Al2O3 + 2Fe Al + Fe2O3 Al2O3 + Fe Single replacement g. P4 + 6Cl2 4PCl3 P4 + Cl2 PCl3 synthesis