iGCSE Scheme of Work Year 9 Sept 2011 Crude Oil and Fuels Lesson Learning Objectives Activities Lesson 1 Fuels from Crude Oil Crude oil is a mixture of a very large number of compounds. Most of the compounds in crude oil are hydrocarbons, which are molecules made up of hydrogen and carbon atoms only. The many hydrocarbons in crude oil may be separated into fractions, each of which contains molecules with a similar number of carbon atoms, by evaporating the oil and allowing it to condense at a number of different temperatures. This process is called fractional distillation. Candidates should know and understand the main processes in continuous fractional distillation in a fractionating column. Knowledge of the names of specific fractions or fuels is not required. Starter Ask pupils what they know about Crude oil (5 mins) Discuss the make up of Crude oil as hydrocarbons. Define hydrocarbons Demo Distillation of crude oil, collect fractions, and show differences in colour viscosity, boiling point. From the results of the distillation expt get pupils to consider trends in boiling points viscosity and flammability. See diagram in e science C1a cude oil lesson 2 Explain these properties in terms of the number of carbon atoms present and the length of the carbon chain. Assessment Safety Other emphasis Artificial crude oil only, teacher demo V watching demo A Listening to explanation on distillation iGCSE Scheme of Work Year 9 Sept 2011 Crude Oil and Fuels Lesson Learning Objectives Lesson 2 The many hydrocarbons in crude oil may be separated into fractions, each of which contains molecules with a similar number of carbon atoms, by evaporating the oil and allowing it to condense at a number of different temperatures. This process is called fractional distillation. Fractional Distillation Candidates should know and understand the main processes in continuous fractional distillation in a fractionating column. Knowledge of the names of specific fractions or fuels is not required. Activities Assessment Safety Other emphasis Starter Review the process of separation of crude oil from last lesson. RSC video Fractional Distillation (10 mins) E science animation Get pupils to add information to a diagram of a fractionating column on uses, boiling point, chain length and viscosity Discuss the processes involved in fractional distillation and get pupils to write a paragraph describing the process, possible peer assessment activity. Plenary - get volunteers to talk about a key word for 30 seconds without saying ‘erm’ Suggested words Fractions, chain length, viscosity, volatility, hydrocarbon, HW sheet on fractionation V seeing animation A listening to explanation K iGCSE Scheme of Work Year 9 Module C1a Crude Oil Lesson Learning Objectives Lesson 3 Activities Starter – Most of the hydrocarbons in crude oil are saturated hydrocarbons called alkanes. Introduce Alkanes as simple The general formula for the hydrocarbons. Introduce the general homologous series of formula for alkanes and explain the alkanes is CnH2n+2. idea of saturated hydrocarbons. Hydro carbons Candidates should know that in saturated hydrocarbons all the carbon–carbon bonds are single covalent bonds. Alkane molecules can be represented in the following forms: C2H6 or Pupils use model molecules of methane, ethane, propane and butane and draw structures in books, using lines for covalent bonds. Label drawings with formulae and names. E science worksheet C3.1a 3.2 How do the properties of alkanes depend on the length of the carbon chain? Candidates should know that in displayed structures a — represents a covalent bond. Candidates should be able to recognise alkanes from their formulae in any of the forms, but only need to know the names of methane, ethane and propane. Plenary Show me board exercise, show pupils examples of structures and formula and ask them to provide either the structure or formula. Sept 2011 Assessment Safety Other emphasis iGCSE Scheme of Work Year 9 Sept 2011 Crude Oil and Fuels Lesson Learning Objectives Activities Assessment Lesson 4 Starter Ask pupils to list as many fuels as they can think of. (5 mins) Demo products of combustion experiment using apparatus shown on p.59. Demo Bunsen flame (10 mins) to show carbon formed on a gauze. Introduce complete and incomplete combustion. Burning fuels Most fuels, including coal, contain carbon and/or hydrogen and may also contain some sulfur. The gases released into the atmosphere when a fuel burns may include carbon dioxide, water (vapour), carbon monoxide, sulfur dioxide and oxides of nitrogen. Solid particles (particulates) may also be released. Candidates should be able to relate products of combustion to the elements present in compounds in the fuel and to the extent of combustion (whether complete or partial). No details of how the oxides of nitrogen are formed are required, other than the fact that they are formed at high temperatures. Solid particles may contain soot (carbon) and unburnt fuels. The combustion of hydrocarbon fuels releases energy. During combustion, the carbon and hydrogen in the fuels are oxidised. Discuss with pupils where these products have come from and what elements must be present in fuels. Ask pupils to work out word and balanced equations from observations. Make notes on elements found in fuels. Consider what is happening in the equations, introduce the idea that the elements have been oxidised during burning. Animation Burning propane animation on e-science (10 mins) Write balanced equations for incomplete combustion if not already done. Give notes on above. Safety Other emphasis iGCSE Scheme of Work Module C1a Crude Oil Lesson Learning Objectives Lesson 5 Cleaner Fuels Sulfur dioxide and oxides of nitrogen cause acid rain, an increase in carbon dioxide results in climate change, and solid particles cause global dimming. Candidates should know at least one effect of, but are not required to know details of any other causes of, acid rain or climate change. Sulfur can be removed from fuels before they are burned, eg in vehicles. Sulfur dioxide can be removed from the waste gases after combustion, eg in power stations. Knowledge of the methods of removing sulfur is not required. Year 9 Activities Starter Show the powerpoint slides of images of global warming then acid rain and ask pupils to link the images in each case. (5 mins) Demo Burn sulphur in O2. Add water and test pH with universal indicator. Could also burn a small piece of coal to see if sulphur is present in this. Ask pupils how it is related to burning fuels and what the environmental impact is. (5 mins) Write balanced eqn for this reaction. Main Pupils Split into three groups. Each group is given enough laptops so 1 between 2. The pupils research into one of three environmental impacts from pollution: global warming, dimming and acid rain. The groups in their pairs find as much info as possible. (15 mins) They then combine the information to prepare a report to the rest of the class.(10 mins) The reports are then given and should include: Causes, chemicals involved, effects, methods of reducing effect. The reports should be three minutes long and involve at least 4 people. (10 mins) Plenary : Cross-word Sept 2011 Assessment Homework: Summary questions on p61 Safety Burn sulfur in a fume cupboard Other emphasis iGCSE Scheme of Work Module C1a Year 9 July 2011 Crude Oil Lesson Learning Objectives Activities Assessment Safety Other emphasis Lesson 6 Alternative fuels Biofuels, including biodiesel and ethanol, are produced from plant material, and are possible alternatives to hydrocarbon fuels. Candidates should know and understand the benefits and disadvantages of biofuels in terms of: o use of renewable resources o their impacts on land use their carbon footprint. Candidates are not required to have a detailed knowledge of the methods of production of biofuels, but should be aware that ethanol is produced by fermentation. Starter Show pupils the Slide show(alternative fuels A and video (alternative fuels B) from e-science. (5 mins) Pupils should create a ‘Guide to Fuels’. This should be in alphabetical order, with the name of the fuel, what/how it is made and advantages and disadvantages. The students could then rate each fuel with a 0–5 star to represent how good a fuel they think it is. They should consider the three important factors in Column 2 in their Guide(15 mins). Concept map ‘ What makes a good fuel? Pg 101 ‘ Complete Chemistry’ Gallagher and Ingram Pupils should then complete a spider diagram in groups of 3 on A4 paper about fuels. Then, in turn, ask each student to write one point onto the class diagram on the board or projector (each point should be different). Then ask the students to consider all the points written and see if they agree or disagree and why. If students highlight any misconceptions, change any incorrect statements. (15-20 mins). Plenary - Pupils plan an advert to go into a magazine on one type of alternative fuels, to persuade people of industry to use it. (15 mins). Revise for test V seeing animation A listening to explanation K spider diagram. iGCSE Scheme of Work Year 9 Sept 2011 Crude Oil and Fuels Lesson Learning Objectives Activities Lesson 7 Hydrogen as a fuel Hydrogen can be burned as a fuel in combustion engines or can be used in fuel cells that produce electricity to power vehicles. Candidates should be able to compare the advantages and disadvantages of the combustion of hydrogen with the use of hydrogen fuel cells from information that is provided. o o Candidates should know and understand the benefits and disadvantages of hydrogen fuel in terms of: storage and use products of combustion. Knowledge of the details of the reactions in fuel cells is not required. Starter Hydrogen car video from BMW Laptop research lesson – in pairs students research hydrogen as a fuel in combustion engines and in fuel cells and make notes in their books. Students produce a table of Disadvantages and advantages of using hydrogen as a fuel. Plenary Assessment Safety Other emphasis Prepare for test next lesson. iGCSE Scheme of Work Year 9 Sept 2011 Crude Oil and Fuels Lesson Lesson 8 Learning Objectives Activities Test Assessment Safety Other emphasis