Unit 6 Vocabulary Preview Prefixes/Suffixes/Roots SubSuperPolyAnBiPreMonoDi TriTetraPentaHexaHeptaOctaNonaDeca- Below Above Many Negative/Against Two Before One Two Three Four Five Six Seven Eight Nine Ten Key Vocab 1. Ionic Bond 2. Covalent Bond 3. Metallic Bond 4. Multivalent 5. Polyatomic Ion 6. Oxidation Number 7. Compound 8. Cation 9. Anion 10. Binary 11. Avogadro’s Number 12. Mole 13. Molecule 14. Molar Mass 15. Percent Composition 16. Empirical Formula 17. Molecular Formula CALCULATION OF PERCENT HYDRATION FROM THE CHEMICAL FORMULA The percent hydration (percent water) can be calculated from the formula of the hydrate by dividing the mass of water in one mole of the hydrate by the molar mass of the hydrate and multiplying this fraction by 100. EXAMPLE: What is the percent water in copper(II) sulfate pentahydrate, CuSO4 ·5 H2O? 1. Calculate the formula mass. When determining the formula mass for a hydrate, the waters of hydration must be included. 1 Cu @ 63.55 g = 63.55 g 1 S @ 32.07 g = 32.07 g 4 O @ 16.00 g = 64.00 g 159.62 g/mol 2 H @ 1.01 = 2.02 g 1 O @ 16.00 = 16.00 g 18.02 g/mol Formula Mass = 159.62 + 5(18.02) = 249.72 g/mol 2. Divide the mass of water in one mole of the hydrate (5 x 18.02 = 90.10) by the molar mass of the hydrate (249.72) and multiply this fraction by 100. Percent hydration = (90.10 g /249.72 g)(100) = 36.08% Worksheet 1 Review/Pre-assessment 1. How many elements make up the following compounds? a) C12H22O11 C__________ H___________ O___________ b) Ca(HCO3)2 Ca_______ H_________ C__________ O_________ c) C7H5(NO3)3 C______ H________ N__________ O__________ d) Al (OH)3 Al _________ O____________ H_____________ 2. Classify as ionic (I) or covalent (C): a) H2SO4 ___________________ e) BaI2 ____________________ b) MgCl2 ___________________ f) CuNO3 __________________ c) CO2 _____________________ g) H2O ____________________ d) KOH ___________________ h) LiBr2 ___________________ 3. Indicate the most likely charges (oxidation number) on the following elements when they become ions: a) O ______________ f) Cr_____________ b) H ______________ g) P ____________ c) Br ______________ h) S _____________ d) K ______________ I) Na ____________ e) Ba ______________ j ) C ____________ 4. For the multivalent elements below, indicate their possible charges: a) Fe ________________ b) Pb _______________ c) Sn _______________ d) Cu _______________ e) Ag _______________ f) Ni ________________ 5. Write formulas for the following polyatomic ions: a) phosphate _____________________ b) nitrate ________________________ c) carbonate _____________________ d) hydroxide ______________________ e) sulfate _________________________ f) ammonium ____________________ g) acetate ________________________ h) chromate ______________________ i) dichromate ____________________ j) permaganate __________________ k) oxalate ________________________ 6. Using table 9.2 on p. 255 of your textbook, write the names for each multivalent metal ion. a) Cu +1 __________________________ b) Fe+3 __________________________ c) Co+2 __________________________ d) Hg+2 __________________________ e) Pb+4 __________________________ f) Cr+3 ___________________________ g) Sn+2 ___________________________ Name: _____________________ Chamberlain Class: ________ Ionic Compound Puzzles Directions: With a partner, use the puzzle pieces in the baggie to make ten different compounds. To make a compound, the charges have to cancel (the puzzle has to make a rectangle). List the metal ion (+), the nonmetal ion (-) and then write the formula by adding subscripts to represent the number of that ion that there are in the compound. After the notes, you will be able to go back and name your compounds. You must do a minimum of 5 compounds in which the metal and nonmetal do not have the same charge. Metal Ion Nonmetal Ion Chemical Formula Compound Name Mrs. C O.K. Ba+2 P-3 Ba3P2 Barium phosphide Analysis & Results: 1. What do you think it means if a compound is binary? 2. What does the oxidation number tell you about the number of valence electrons the ion has? 3. Why can’t two negative ions or two positive ions bond together? 4. What is the sum of the charges each time you made a compound? 5. What do the subscripts tell you in the formula? 6. Reflect on the activity that you just did. In what ways did it help you? Compound 1. Magnesium fluoride 2. Copper (II) phosphate 3. Zinc acetate 4. Silver carbonate 5. Iron (III) sulfite 6. Aluminum hydroxide 7. Sodium sulfate 8. Calcium nitrate 9. Rubidium dichromate 10. Ammonium oxalate 11. Potassium peroxide 12. Chromium (III) sulfate 13. Tin (IV) oxide 14. Lead (II) cyanide 15. Aluminum hydrogen carbonate 16. Ammonium chlorate 17. Magnesium iodate 18. Sodium hydroxide 19. Phosphoric acid 20. Hydrochloric acid 21. Sodium chlorate 22. Lead (II) oxide 23. Calcium carbonate 24. Copper (I) chloride 25. Silver Nitrate Write positive ion with charge as superscript Write negative ion with charge as superscript Write formula with correct subscripts (no + or – signs!) Name These: 1. Rb2O 2. CoF2 3. NiCO3 4. K3PO4 5. H2SO4 6. Al(NO3)3 7. HgSO4 8. Zn(OH)2 9. Ba(ClO3)2 10.Mg(C2H3O2)2 11. AgCN 12. NaHCO3 13. HNO3 14. KOH 15. Cu2CrO4 16. Sr(NO2)2 17. HC2H3O2 18. LiMnO4 19. BaBr2 20. CaCl2 21. AgNO3 22. KI 23. LiOH 24. CuSO4 25. HCl Full Name Write Molecular Formulas for: 1. Carbon tetrachloride 2. Dihydrogen monoxide 3. Dinitrogen trioxide 4. Triphophorous tetrabromide 5. Dicarbon hexachloride 6. Carbon monoxide 7. Trinitrogen octasulfur pentachloride 8. Dihydrogen dioxide 9. Carbon dioxide 10. Tetracarbon octaoxide Try these ionic compounds & acids (WS#2) 11. Calcium oxide 12. Aluminum oxide 13. Lithium nitride 14. Sodium fluoride 15. Sodium phosphate 16. Nitric Acid 17. Acetic Acid 18. Silver Nitrate Mixed Review Compound 19. Copper (II) Sulfate 20. Tricarbon nonachloride 21. Ammonium carbonate 22. Carbon monoxide 23. Iron (III) oxide Ionic or Covalent Formula Write Molecular Names for: Remember to use prefixes to indicate how many of each type of atom there are. Do not use “mono” in front of the first element 1. NH3 2. P4O10 3. S2O3 4. CCl5 5. CO4 6. C3H6O3 7. PO3 8. CO 9. C7F9 Try these ionic compounds & acids (WS#2) 10. CuSO4 11. KMnO4 12. SnF2 13. (NH4)3PO4 14. HgCrO4 15. AgNO3 16. H3PO4 17. Pb(NO3)4 18. H2CO3 Mixed Review Compound 19. CO2 20. Co(CN)3 21. OF2 22. Zn(OH)2 23. Ni2CO3 Ionic or Covalent Name 1. Convert to moles: a. 32.9 g neon 1.63 moles b. 0.00823 g molybdenum 8.58 x 10-5 moles c. 6.16 g calcium nitrate 0.0376 moles d. 6.4 x 10-4 g aluminum phosphate 5.2 x 10-6 moles e. 7.12 x 1023 molecules silicon tetrafluoride 1.18 moles f. 4.87 x 1017 atoms arsenic 8.09 x 10-7 moles g. 0.98 L of N2O 0.044 moles 2. Convert to grams: a. 0.112 moles tungsten 20.6 g b. 2.48 x 10-3 moles carbon 0.0298 g c. 51.6 moles nickel (II) oxide 3.85 x 103 g d. 1.09 moles zinc hydroxide 108 g 3. Convert to molecules: a. 6.72 moles sodium chloride 4.05 x 1024 molecules b. 102 moles chromium (III) bromide 6.14 x 1025 molecules c. 47.9 g cobalt (II) oxalate 1.96 x 1022 molecules d. 16.2 g diphosphorus pentoxide 6.87 x 1022 molecules e. 4.61 L of H2O 1.24x 1023 molecules 4. Convert to grams: a. 1.06 x 1027 atoms copper 1.12 x 105 g b. 7.39 x 1023 molecules tin (II) chromate 288 g c. 8.27 x 1024 molecules potassium dichromate 4040 g d. 4.52 x 1021 molecules barium sulfate 1.75 g e. 5.78 L of N2 7.23 g N2 5. Convert to Liters: a. 6.54 moles H2 b. 3.98 g O2 146 Liters 2.79 Liters 1. Determine the percentage composition of each of the following compounds: a) sodium oxalate, Na2C2O4 (33% Na, 20% C, 47% O) b) ethanol, C2H5OH (52% C, 13% H, 35% O) c) aluminum oxide, Al2O3 (53% Al, 47% O) d) potassium sulfate, K2SO4 (44.87% K, 18.40% S, 36.72% O) 2. Calculate the mass of the given element in each of the following compounds: a) bromine in 50.0 g potassium bromine, KBr (33.5 g) b) chromium in 1.00 kg sodium dichromate, Na2Cr2O7 (0.397 kg) c) nitrogen in 85.0 mg of lysine, C6H14N2O2 (16.3 mg) d) cobalt in 2.84 g cobalt (II) acetate, Co(C2H3O2)2 (0.947 g Co) 3. A sample of Ag2S has a mass of 62.4g. What mass of each element could be obtained by decomposing this sample? (54.35 g Ag, 8.05 g S) 4. Calculate the mass of zinc in a 30.00 g sample of zinc nitrate, Zn(NO3)2 (10.36 g Zn) 5. Calculate the mass of oxygen in 4.00 g of manganese dioxide, MnO2. (1.47 g O) 6. Calculate the mass of gold in 0.780 g of Au2Se3. (0.487 g Au) 1. Complete the table by writing the molecular formula for each of the following substances: Compound Molecular Formula Water H2 O Hydrogen Peroxide H2O2 Glucose C6H12O6 Methane CH4 Ethane C2H6 Octane C8H18 Empirical Formula 2. Determine the molecular formula of each of the following unknown substances: empirical formula CH2 experimental molar mass 28 g/mol (C2H4) empirical formula C6H8O experimental molar mass 290 g/mol (C18H24O3) 3. Determine the empirical formula for compounds that have the following analyses: 57.6% strontium, 13.8% phosphorus, and 28.6% oxygen. (Sr3P2O8) 4. Determine the empirical formula for compounds that have the following analyses: a 0.858 g sample of an unknown substance is composed of 0.537 of copper and 0.321 g of fluorine. (CuF2) 5. A 10.64 g sample of a lead compound is analyzed and found to be made up of 9.65 g of lead and 0.99 g of oxygen. The molecular mass of the unknown compound is 1,370 grams/mole. Determine the molecular formula for this compound. (Pb6O8) 6. Determine the molecular formula for a compound that is 36.2% aluminum and 63.8% sulfur and has a molecular mass of 1,893 g/ mole. (Al6S9)