CHEMISTRY 352 Spring 2006 Instructor: Dr. Gary Lampman E-mail address: lampman@chem.wwu.edu Lampman webpage for Chemistry 352: http://lightning.chem.wwu.edu/dept/facstaff/lampman/lamp352.html Office: CB 340. Phone: 650-3151, Office hours MTuWF 10. Feel free to come by for assistance or discussion at your convenience. I am also available at other times; catch me on the run or schedule an alternative time with me. Texts: Pavia, Lampman, and Kriz, Organic Chemistry, Volume 2 (2004 edition) and a set of molecular models. You will also need Volume 1. We will finish Chapter 8 in Volume 1 before starting in Volume 2. Organic chemistry is extremely cumulative and one must keep up with the readings. The best way to study is to read ahead in the text in advance of the lecture, come to lecture to fill in the pieces, and then work the problems. Chemistry 351 is definitely prerequisite to Chemistry 352. If you didn't do well in Chemistry 351 (less than a C grade), it is advisable to take this course over before starting Chemistry 352. Answers to the problems are included at the end of the book. Problem working is extremely important in organic chemistry. I suggest working the problems that I assign on paper, and then look at the answers in the book. You need practice drawing structures and mechanisms, rather than just looking at the answers. Some students make flash cards with the reactions that we study. Put reaction on the front and the answer on the back. Lectures: SL 140, 9 MTWF. The time will be used for lectures and working problems, according to the schedule given on that backside of this sheet. It is a good idea to read ahead in the text in advance of the lectures. PowerPoint slides are available from my website (see above). Computer Lab: Programs are available in CB 280 on the network: Organic Nomenclature for all chapters arranged by functional group ORM- full screen is great for mechanisms! Organic Reaction Drills (OGRE) is good for simple reactions Comprehensive Chemistry, Introduction to Organic Chemistry; simple. Exams: There will be three hour exams and a comprehensive final given during the quarter, according to the attached schedule. No make-up exams will be given. Copies of old exams will be available from my webpage. Students in the past have found the sample tests to be very helpful. In some cases, I may schedule a “help session” outside of class time, prior to an exam. Grading: 3 hour exams @ 100 pts each = Comprehensive final exam = A and AB-, B, B+ C-, C, C+ D F 300 points 200 500 points total 90 to 100% of total points 80 to 89% of total points 68 to 79% of total points 60 to 67% of total points Below about 60% of total points Schedule for Chemistry 352 DATES TOPICS and CHAPTER # Mar 28, 29, 31 Apr 3, 4, 5, 7 Finish Chap 8, starting with Sect. 8.7. Elimination Reactions: Alkenes and Alkynes (Chapter 9) Apr 10, 11 Nucleophilic Substitution: The SN1 and SN2 Mechanisms (start Chapter 10) Apr 12 (Wednesday) Exam 1 (Chap 8 and Chap 9) Apr 14, 17, 18, 19, 21, 24 Chapter 10, continued Apr 25 Spectroscopy I: start infrared spectroscopy Apr 26 (Wednesday) Exam 2 (Chap 10) Apr 28, May 1, 2 Spectroscopy I: Infrared Spectroscopy May 3, 5, 8, 9, 10, 12 Spectroscopy II: NMR May 15, 16 Start Chap 12 May 17 (Wednesday) Exam 3 (Chap 11,13) May 19, 22, 23 Nucleophilic Substitution: Reactions (Chapter 12) May 24, 26, 30, 31 Jun 2 May 29th Memorial Day Alkenes and Alkynes II: Oxidation and Reduction; Oxymercuration, Hydroboration and Simple Ring Formation (Chapter 14) Jun 7 (Wednesday) 8-10 AM EXAMS Final (comprehensive) and Chap 12 and 14)