AN EVALUATION OF THE ENVIRONMENTAL IMPACT OF THE INTERNAL COMBUSTION ENGINE VEHICLE VERSUS THE HYBRID-ELECTRIC VEHICLE by Sean A. Elliott An Engineering Project Submitted to the Graduate Faculty of Rensselaer Polytechnic Institute in Partial Fulfillment of the Requirements for the degree of MASTER OF MECHANICAL ENGINEERING Approved: _________________________________________ Dr. Sudhangshu Bose, Project Adviser Rensselaer Polytechnic Institute Hartford, Connecticut April, 2012 © Copyright 2012 by Sean A. Elliott All Rights Reserved ii Contents List of Tables ..................................................................................................................... v List of Figures .................................................................................................................. vii Abstract ........................................................................................................................... viii 1. Introduction.................................................................................................................. 1 1.1 Background ........................................................................................................ 1 1.2 Previous Studies ................................................................................................. 2 1.3 Project Scope ...................................................................................................... 5 2. Methodology ................................................................................................................ 6 2.1 Life Cycle Assessment Approach ...................................................................... 6 2.2 LCA Scope ......................................................................................................... 6 2.3 List of Key Assumptions.................................................................................... 7 3. Discussion .................................................................................................................. 10 3.1 Selection of Vehicles........................................................................................ 10 3.2 Material Procurement and Vehicle Production ................................................ 12 3.3 3.4 3.2.1 Procurement and Production of Materials............................................ 13 3.2.2 Vehicle Assembly Estimate ................................................................. 16 3.2.3 Batteries................................................................................................ 17 Use Cases ......................................................................................................... 19 3.3.1 Use Case Emissions Totals .................................................................. 19 3.3.2 Use Case Fuel Cost Totals ................................................................... 20 3.3.3 Replacement of Fluids.......................................................................... 21 3.3.4 Battery Replacement ............................................................................ 21 End of Life/Recycle ......................................................................................... 21 4. Results........................................................................................................................ 23 4.1 Energy Totals ................................................................................................... 23 iii 4.2 Emissions Totals .............................................................................................. 23 4.3 Cost Totals ....................................................................................................... 24 5. Conclusions................................................................................................................ 26 References........................................................................................................................ 28 iv List of Tables Table 1. Specifications of Vehicles Used for Study [11], [12] ........................................ 11 Table 2. Specifications of Vehicles Considered but not Chosen for Study [13], [14] .... 11 Table 3. Material Estimates by Weight [4] ...................................................................... 13 Table 4. Greenhouse Gas Emission Totals Per Vehicle due to Materials (kg/vehicle) [4] ......................................................................................................................................... 16 Table 5. Vehicle Assembly Information [15] .................................................................. 17 Table 6. Battery Material Compositions [4] .................................................................... 17 Table 7. Production Energies for Raw Battery Materials [4] .......................................... 18 Table 8. Battery Material Production Energies per Vehicle ............................................ 18 Table 9. Battery Assembly and Test Energies [4] ........................................................... 19 Table 10. Vehicle Scenario Parameters [11], [12] ........................................................... 19 Table 11. Emissions Values for Life of Vehicles Used [5] ............................................. 20 Table 12. Lifetime Vehicle Fuel Costs at $3.92/gal ........................................................ 20 Table 13. Lifetime Vehicle Fuel Costs at $5.50/gal ........................................................ 20 Table 14. Vehicle Fluid Weights (lb) [4]......................................................................... 21 Table 15. Material Recycling Estimates by Weight [10] ................................................ 22 Table 16. Energy Totals per Vehicle (in Million Btu)..................................................... 23 Table 17. Net Energy per Vehicle for Case Studies (in Million Btu).............................. 23 Table 18. Greenhouse Gas (GHG) Emission per Vehicle Totals (units of kg CO2e) ...... 24 v Table 19. Net GHG Emissions per Vehicle for Use Cases (units of kg CO2e) ............... 24 Table 20. Cost per Vehicle (in Dollars) ........................................................................... 25 Table 21. Net Cost per Vehicle (in Dollars) .................................................................... 25 vi List of Figures Figure 1. 2012 Toyota Prius Picture [11] ........................................................................ 12 Figure 2. 2012 Toyota Corolla S Picture [12] ................................................................. 12 Figure 3. Total Energy Use Per Vehicle during Production [4] ...................................... 14 Figure 4. Greenhouse Gas Emissions per Vehicle during Production [4] ....................... 15 vii Abstract Hybrid-electric vehicles (HEVs) have increased in popularity significantly in recent years. The principal advertised advantage of these types of vehicles is superior fuel economy when compared to a class-equivalent internal combustion engine vehicle (ICEV). Benefits of the superior fuel economy are twofold: 1) cost savings to the consumer, purchasing less fuel for a given distance traveled, and 2) less environmental impact due to lower vehicle emissions. Both of these benefits are well publicized by hybrid-electric vehicle manufacturers and advocates. Other factors must be considered, however, before an HEV can be proclaimed “better for the environment” or "cheaper to own" than an ICEV. Materials, manufacturing, reliability of technology, length of useful life and ease of recycling or disposal all must be considered in this argument. This study performs a comprehensive analysis focusing on the “cradle to grave” environmental impact of each of these types of vehicles. A supplementary total cost of ownership analysis is also included. Results indicate that, as expected, the HEV produces considerably less emissions than the ICEV. The results of the cost analysis do not show a clear winner, although the HEV proves to be the better choice if gasoline prices continue their upward trend. viii 1. Introduction 1.1 Background In recent years as the global population has continued to rise, so has the amount of pollution produced by humans. More than ever, individuals, businesses, and organizations have embraced the “go green” movement in hopes of preserving our planet’s natural resources. While air pollution and hazardous wastes produced by construction, manufacturing, mining, and agriculture industries are very large contributors to the overall world pollution, none of these are as tangible to the average individual as motor vehicle emissions, another leading cause of air pollution [1]. More stringent environmental regulations and individual's desires to do their part in the green movement have created a strong market for a new wave of green vehicles, motor vehicles that produce lower emissions. Many of the new-wave of green vehicles utilize alternative energies rather than gasoline but often are limited in range, speed, or power because these technologies are still in their infancy. One of the most popular green vehicles which utilizes reasonably mature technology is the hybrid-electric vehicle (HEV). This vehicle augments an internal combustion gasoline engine with an electric motor and large battery. By using the electric motor to store unused energy into the battery, this vehicle can operate without using the gasoline engine all the time. Many environmental advocates overstate the benefits of the hybrid car, however. The popular educational website “HowStuffWorks” contains an article on hybrid cars titled “Do Hybrid Cars Cause Pollution?” [2] To those familiar with the technology, of course the answer is yes since some amount of gasoline is still being combusted. A common misconception is that the hybrid car is “good” for the environment when the reality is that it is “less bad” than a vehicle which burns more fuel over the same distance traveled. Another aspect of the hybrid vehicle often overlooked is the energy during the manufacturing of a hybrid car, as this can be related to the amount of pollutants generated. Because of the advanced technologies and additional components used in a hybrid car, it often takes additional energy to manufacture when compared to the internal 1 combustion engine vehicle (ICEV). Hybrid car manufacturers claim that the additional energy required to manufacture the hybrid is easily outweighed by the energy saved during the vehicle’s lifetime of use. Studies have both disputed and confirmed this assertion depending on the assumptions made for the length and extent of use considered to make up the lifetime of the vehicle. Like the preconceived notion that a hybrid car is better for the environment than a comparable internal combustion engine vehicle, hybrid cars are marketed claiming that the lower amount of energy that they use will equate to a financial savings to the consumer. Again, the realization of this savings is dependent upon the number of miles driven over the life of the car because the initial capital investment of the more expensive hybrid vehicle must be offset by the savings in energy costs. 1.2 Previous Studies As stated in the previous section, various studies have been performed that make comparisons between the HEV and the ICEV. The scope of these studies differs and the results lead to a wide range of conclusions. These conclusions must be accepted with caution, however, as many people or organizations have agendas that lead to biased results. For example, possibly the most discussed report on this subject matter claims that a Hummer H2 (an ICEV) is more cost efficient per mile (and by extension, is more environmentally friendly) than the Toyota Prius (an HEV). This report, titled "Dust to Dust" [3] was published by a marketing firm and was not peer reviewed by subject matter experts in either academia or the automotive industry. Digging deeper reveals that the assumed life expectancy of the Hummer was over 300,000 miles compared to just 109,000 for the Prius. This report was widely publicized prior to the public being made aware of the questionable route to which the conclusions were made. The lesson here is that by taking liberties with the assumptions, the results can be skewed significantly in a given direction. So as not to fall into a similar trap of trusting distorted results, the literature review conducted for the findings reported for this project was limited to studies performed in academia or those supported by United States Government organizations. One study 2 relevant to this report was conducted by Argonne National Laboratory for the US Department of Energy [4]. This study developed a vehicle-cycle model for the greenhouse gases, regulated emissions, and energy use in transportation (the GREET model). This model evaluates energy and emission effects associated with vehicle material recovery and production, component fabrication, assembly and disposal/recycling. When the vehicle-cycle model is combined with the fuel-cycle model, the GREET model provides a comprehensive life cycle approach to compare energy use and emissions of conventional (i.e., ICEVs) and advanced vehicle technologies (i.e., HEVs). The GREET model was used to estimate total energy cycle results for six mid-size passenger vehicles, among them an internal combustion engine and an internal combustion engine with hybrid configuration. Among the relevant conclusions of the GREET model study to this report are that the lifetime energy use of the HEV is less than that of the conventional ICEV (an average of about 4200 BTU/mi versus 6400 BTU/mi). Most of the difference in these two figures is due to the vehicle operation (or use) phase. A 2001 study comparing the second generation Toyota Prius (an HEV) with a Toyota Corolla (an ICEV) determined that the Prius is not the most sensible choice from either an economic or environmental standpoint [5]. This study focused on the cost effectiveness of the fuel economy and the emissions of the two vehicles. It concluded that at the 2001 price of gasoline, the Corolla is more cost effective from a fuel economy standpoint than the Prius, even though the fuel economy of the Prius is superior. This conclusion is based on the fact that the Prius is more expensive than the Corolla and the difference in purchase price is not recovered by the fuel savings. In fact, according to the study, the price of gas would have to increase threefold to make the Prius the more economical decision. This study did not factor in the potential increase in repair costs for the more complicated Prius, including the possibility of replacing the expensive hybridelectric battery. In addition, the study also suggests that society may be better suited devoting resources to other environmental projects technology. 3 rather than hybrid vehicle From an environmental standpoint, the study conducted in [5] only takes into account the emissions from producing and burning the fuel. Even considering this limitation, one would question whether the conclusion is still valid ten years after its initial publication. The national average price for gasoline in 2001, the year the study was published, was $1.46 (Note: the study uses $1.50) [6]. In 2011, the cost per gallon was approximately $3.56. This is not the threefold increase called out by the survey but nonetheless there is more of a financial incentive to buy a car with better fuel economy now than in 2001. Additionally, the hybrid technology has improved in the last ten years, making hybrids both more efficient and reliable. The rated fuel economy of the 2012 Prius is more than 6 mpg better than that of the 2000 Prius quoted in the study [6],[7]. The improvement in fuel economy and the increase in gasoline prices make the Prius much more desirable than this study had forecast. However, the improvement in efficiency comes at the cost of a Prius that is more expensive to buy relative to the Corolla. Whether the increased initial cost can be offset by the savings in gasoline will be determined based on longevity and driving conditions presented later in this report. The utilization of resources to best help the environment is more difficult to quantify. However, if it can be shown that hybrid electric vehicles are economically beneficial, the fact that they produce less emissions than a comparable internal combustion engine vehicle means by default some amount of environmental benefit is realized. A Life Cycle Assessment (LCA) was conducted in 2000 that compared the energy consumed and the byproducts emitted during the use phase of the hybrid and internal combustion engine vehicle, as well as a diesel engine and an electric vehicle [8]. This simplified assessment was conducted under the assumption that all vehicle types had nearly similar production and end of life phases. For emissions, this study tabulated values for all four vehicle types for greenhouse gases (carbon dioxide, methane and nitrous oxide) as well as pollutants such as carbon monoxide, nitrogen oxide and others. Based on the use phase alone, the hybrid car emits about half as much greenhouse gases as the internal combustion engine vehicle and produces significantly lower amounts of pollutants. Using a weighted ranking system the emission data collected was compared for all four vehicles, which showed that the hybrid vehicle was found to have about half of the environmental impact of the internal combustion engine vehicle. The hybrid car 4 was matched only by the electric vehicle, though much of that vehicle's power was assumed to be generated by electric currents via nuclear power plants which do not produce greenhouse gases or pollutants in the same way as combustion-based power production. This study performs a similar analysis of the use phase and also includes production and end of life phases that were assumed to be similar and not included in [8]. 1.3 Project Scope The objective of this study is to conduct an independent analysis of the comprehensive environmental impact of both HEV and the ICEV. This study is intended to confirm or challenge the commonly held notion that HEVs are better for the environment than their ICEV counterparts. The expected outcome will be a quantifiable environmental impact for each of these vehicles. Multiple scenarios will be explored that attempt to predict the number of miles and type of driving (city, highway, etc.) for a couple of common types of drivers. Also included for each of these scenarios is a basic total ownership cost analysis. The environmental impact and total ownership cost together will allow an environmentally and economically conscious consumer to make an informed decision about which of these types of vehicle would best suit their needs and desires. 5 2. Methodology 2.1 Life Cycle Assessment Approach The Life Cycle Assessment approach can be summarized by four major steps [9]. The first step in the scope of the project is to determine which environmental concerns are to be taken into account for the study. The second step involves collecting an inventory of all environmental inputs (materials, energy, chemicals) and outputs (emissions, solid waste) of the product system. The data collected in the inventory are then used in the impact assessment to determine a representative effect of the system on the environment. The final step of the LCA is interpretation of the results. In this study, the results of the HEV and the ICEV are compared directly. 2.2 LCA Scope The goal of this study is to perform a cradle to grave comparison of the HEV and ICEV. Many prior studies narrow their focus to one portion of the life cycle, such as the use phase, and draw conclusions based on those results and overarching assumptions made for other phases. This study combines data extracted from prior works as well as original calculations to determine a result for the full life cycle. The scope is limited to two specific make and model vehicles, one hybrid electric and one containing a standard internal combustion engine. Minor assumptions are made as noted within each phase rather than leaving out entire phases by considering that the differences between the two vehicle types are negligible in that particular phase. This way, a reasonable total approximation of the environmental impact is achieved for each vehicle rather than a relative answer based solely on the phases analyzed. The scope of the material procurement and vehicle production phase tabulates the energy required to produce each major material used in the vehicle and estimates the energy required and emissions produced for each vehicle during assembly based on vehicle weight and location of assembly using published numbers. It is noted in [10] that the energy required for assembly of the vehicle is considered insignificant in relation to the energy required to produce all of the parts. This study still includes an estimate for this figure, however insignificant it may seem. The infrastructure of the production and 6 assembly facilities or the transportation of raw materials, parts, and assembled vehicles are not included as part of the assessment. The scope of the use phase of the vehicle includes three scenarios designed to simulate various types of driving conditions experienced over the life of the vehicle. These scenarios are a low mileage estimate where much of the driving is concentrated in urban areas, a moderate mileage estimate where city and highway driving are more balanced and a high mileage estimate where most of the driving is done on the highway. Using the EPA rated fuel economies for each vehicle, the amount of gas (and in turn the amount of emissions) consumed by each of the vehicles over their lifetime is determined. Also, use of fluids, tires, batteries, etc. are assumed for each vehicle and included in the total environmental impact analysis. The scenarios chosen are not meant to cover extreme cases but rather average representations of the life of a vehicle of this type. The end of life phase accounts for the disposal of materials at the end of the life of the vehicle. Since the energy and emissions associated with extracting and/or producing each material have already been accounted for, the main purpose of this phase is to give credit for the energy retrieved during recycling. The energy retrieved is determined by the energy savings that comes from secondary production using recycled materials versus primary production using virgin materials. Some energy is expended, however, in order to extract the materials to be recycled. This study will assume that the car is shredded (90% of all vehicles that are scrapped are shredded according to [10]). A nominal energy per unit weight is used to estimate the energy expended by the shredder. 2.3 List of Key Assumptions Energy and emissions for assembly and production scale with the numbers published in [15] are based on the location of manufacture and the mass of the vehicle in kg. These numbers do not differentiate between HEVs and ICEVs. All major metals used in batteries are considered recyclable. It is indicated in [4] that the metals from the Ni-MH battery can be recovered and used as alloying metals in the production of stainless steel. 7 The emissions values associated with the production and assembly of the lead acid batteries are assumed to be negligible as can be seen in Figure 4. The total parts and labor cost associated with a Prius Ni-MH battery replacement is assumed to be $3,000. This estimate was developed through online research although not one specific, citable source was found. For simplicity of calculations, the price of gasoline is assumed to be static over the life of the vehicle in each of the two gas price scenarios chosen ($3.92/gal and $5.50/gal). One hundred percent of shredded metals are assumed to be recycled. In reality, only the small amounts of metal that are not able to be separated from non-metal shredder residue are not recycled. The environmental impact of the disposal of non-metal shedder residue is not considered in this study but this impact is assumed to be small compared to the overall environmental impact of the vehicle including production and use phases. Emissions from the shredder are also assumed to be negligible. A net energy savings for nickel was not listed in [10] so the net energy savings is assumed to be the same as the energy required to produce nickel via the secondary production process. The energy expended by the shredder, 32 Btu/lb from [10], is assumed to be negligible since it is three orders of magnitude lower than the net energy savings of the metals being analyzed. Only greenhouse gases are compared in the emissions totals in Section 4. These are the only pollutants that can be compared using a common metric (CO2e). Other pollutants can be compared directly by looking at emissions results in Section 3. 8 Cost/energy associated with replacement parts are not included in the totals. These values will be variable depending on individual situations and are not likely to amount to a significant percentage of cost and energy. Any cost benefit or detriment associated with shredding a vehicle and recycling of materials is considered negligible. 9 3. Discussion 3.1 Selection of Vehicles The first step in performing any analysis relating to this project is to select two specific vehicles for comparison. These vehicles will be the basis of the subsequent research conducted involving materials, manufacturing, use and recycle. There are two key decision considerations used in the selection of vehicles. The first is that the vehicles chosen must be similar in a number of key parameters that allow for the best possible “apples to apples” comparison. To get an accurate picture of the difference between the hybrid-electric case and the internal combustion-only case, ideally the remainder of the vehicle should be the same. In addition, this study is targeting a consumer that is attempting to decide between two similar vehicles, one hybrid-electric and one internal combustion engine-only. Comparing a sedan with an SUV would not make for an appropriate scientific control. The second decision parameter is that the vehicles chosen must be appropriate for comparison using the information regarding materials and processes used in manufacturing so that as complete of an analysis as possible can be performed. The Toyota Prius hybrid vehicle was chosen as the starting point for this project since it has set the standard for HEVs since its introduction almost 15 years ago. The Prius is the most recognizable hybrid, both on the road and in name; so it was a logical decision for inclusion in this study. Three ICEVs were considered for comparison with the Prius: the Toyota Corolla, the Toyota Matrix and the Honda Civic. Table 1 and Table 2 provide key specifications that were used to determine the two vehicles that are used in the study. The specifications for the vehicles chosen as well as those not chosen for this study are presented for comparison purposes. The hybrid is unique from all of the other vehicles in a few particular areas. The first is that the additional components (namely the electric motor and nickel metal-hydride battery) give it some three hundred pounds of extra weight. The second is that the hybrid provides a nominal improvement of twenty miles per gallon in advertised fuel economy. The last major departure between the hybrid and the other three vehicles is the price, with the hybrid costing an average of over seven thousand dollars more than the three ICEVs. 10 Table 1. Specifications of Vehicles Used for Study [11], [12] Vehicle Make and Model Powertrain Transmission Net Horsepower Torque (ft-lb) Curb Weight (lb) Passenger Volume (cu. ft.) Cargo Volume (cu. ft.) Fuel Tank Capacity (gal) MPG City MPG Highway MPG Combined MSRP ($) Toyota Prius 2 (2012) Toyota Carolla L (2012) 1.8L 4-cylinder DOHC/Permanent Magnet AC Motor/Ni-MH battery 1.8L 4-cylinder DOHC Electronically controlled Continuously Variable Transmission 134 105 gasoline/153 electric 3042 93.7 21.6 11.9 51 48 50 24,000 5-speed manual 132 128 2734 92.1 12.3 13.2 27 34 -16,130 Table 2. Specifications of Vehicles Considered but not Chosen for Study [13], [14] Vehicle Make and Model Powertrain Transmission Net Horsepower Torque (ft-lb) Curb Weight (lb) Passenger Volume (cu. ft.) Cargo Volume (cu. ft.) Fuel Tank Capacity (gal) MPG City MPG Highway MPG Combined MSRP ($) Toyota Matrix L (2012) 1.8L 4-cylinder DOHC 5-speed manual 132 128 2844 94.2 19.8 13.2 26 32 -18,845 Honda Civic DX (2012) 1.8L 4-cylinder SOHC 5-speed manual 140 128 2608 94.6 12.5 13.2 28 36 31 15,805 The decision on which of the three internal combustion engine vehicles ultimately would be used in this study was made by choosing the best scientific control. If the internal combustion engine vehicle is considered the “control group” and the Prius is considered the “experimental group” (control group plus an electric motor and Ni-MH battery), which vehicle would be the closest match? As seen when comparing the metrics provided in Table 1 and Table 2, it is clear that the Toyota Corolla is the best match. 11 Both are compact sedans, both are made by the same manufacturer and many of the nonpower train-related components and metrics are identical. Comparing two vehicles this similar will mean that any differences in the results can very likely be attributed to the hybrid-electric system. Figure 1 shows a picture of the 2012 base Prius model. The 2012 Corolla is shown in Figure 2. Figure 1. 2012 Toyota Prius Picture [11] Figure 2. 2012 Toyota Corolla S Picture [12] 3.2 Material Procurement and Vehicle Production Information regarding the energy required to produce a vehicle and the emissions produced on a per vehicle basis based on manufacturing location is reported in [15]. The emissions discussed are greenhouse gases (GHGs) and are cumulatively expressed in kgCO2 equivalent. The study separately specifies the energy required and emissions 12 produced in the material production and vehicle assembly for a number of manufacturing locations around the world. This analysis will use a scaled version of the assembly energy but will independently tally the energy and emissions from the individual materials. A rough average of all data presented in [15] shows that 25 % of the energy required to produce a vehicle comes from the assembly portion and 75% comes from material production. This study will detail the production of materials and compare this with the assembly energy based on information published in [15]. 3.2.1 Procurement and Production of Materials The materials used to manufacture a vehicle reasonably overlap between the HEV and the ICEV, with the exception of the electric motor and the battery of the hybrid. Using the listed curb weights of each vehicle, the amount of each major material used in production is calculated in Table 3 using percent weight estimates for the HEV and ICEV from [4]. These materials cover all major components and subsystems for a new vehicle straight from the assembly line. Not listed in Table 3 are the batteries for each of the vehicles (lead acid for the Corolla, lead acid and nickel-metal hydride for the Prius) which will be discussed separately. Table 3. Material Estimates by Weight [4] Material Steel Cast Iron Wrought Al Cast Al Copper/brass Magnesium Glass Average Plastic Rubber Nickel Platinum Other Corolla Prius % Weight Weight (lb) % Weight Weight (lb) 61.7 1687 65.2 1983 11.1 303 6 183 2.2 60 1.8 55 4.7 128 5.1 155 1.9 52 4.3 131 0.02 1 0.02 1 2.9 79 2.9 88 11.2 306 10.6 322 2.4 66 1.9 58 0 0 0.1 3 0.0005 0 0.0003 0 1.9 52 2.2 67 Taking into account the fossil fuel energy required to produce the quantity of the materials listed above, Figure 3, taken from [4] shows an approximation of the energy 13 required to produce an HEV and an ICEV. Note that the values for fluids, batteries, and ADR (assembly, disposal and recycling) will be discussed later in this report. Figure 3. Total Energy Use Per Vehicle during Production [4] The greenhouse gas emissions per vehicle generated during the material production process are presented in Figure 4, from [4], in units of kg/vehicle. The following greenhouse gases were included in this tabulation: methane (CH4), nitrous oxide (N2O), carbon dioxide (CO2), particulate matter (PM10), sulfur oxide (SOx), volatile organic compounds (VOC), nitrogen oxide (NOx), and carbon monoxide (CO). 14 Figure 4. Greenhouse Gas Emissions per Vehicle during Production [4] Values of individual greenhouse gases are listed in table format in Table 4. Many of these greenhouses gases contribute significantly to global warming, most notably methane, nitrous oxide and carbon dioxide. Also listed in Table 4 are the CO2e values for the gases which contribute to global warming and the corresponding values of kg CO2e for each vehicle. In addition to the GHG effect on global warming, sulfur and nitrogen oxides are acidification gases that contribute to acid rain. Carbon monoxide, VOCs and particulate matter are all considered pollutants and have adverse effects on human health. 15 Table 4. Greenhouse Gas Emission Totals Per Vehicle due to Materials (kg/vehicle) [4] 3.2.2 Vehicle GHG CO2e Total CH4 21 ICEV kg kg CO2e 6300 10.3 216.3 HEV kg kg CO2e 5400 8.8 184.8 N2O CO2 0.075 6000 0.062 5100 310 1 23.25 6000 PM10 11.5 9.2 SOX VOC NOX CO 16 2 7.9 39 18 2 6.5 34 19.22 5100 Vehicle Assembly Estimate The top part of Table 5 presents values quoted in [15] for the energy in MJ and GHG emissions in kg CO2e for a given vehicle mass in kg, for vehicles produced in the United States and Japan. This study is being conducted from an American’s perspective so it will be assumed that the Corolla is assembled in the United States (Toyota has a Corolla production plant in Blue Springs, Mississippi) and that the Prius is assembled in Japan (as of 2012, all Prius’ are built and assembled in Japan). Presuming that the energy and emissions from vehicle assembly are directly proportional to the weight of the vehicle produced, the scaled values for energy and GHG emissions based on the listed curb weights of the Corolla and Prius are also presented in Table 5. It is noted that these values for vehicle assembly should be considered approximate since the specific vehicle type being assembled was not included with the original data from [15]. The purpose for using these approximate numbers, scaled by weight, was to try to account for the energy costs and associated emissions for vehicle assembly based on the location of the plant. For example, a vehicle produced in Europe might have fewer GHG emissions because of the use of nuclear power based electricity. 16 Table 5. Vehicle Assembly Information [15] Vehicle Assembly Values from Yan Country US Japan Vehicle Mass (kg) 1322 1214 Energy (MJ) 25,779 20,200 GHG Emissions (kg CO2-eq) 1793 1038 Scaled Vehicle Assembly Values Prius Mass (kg) -1380 Corolla Mass (kg) 1240 -Energy (MJ) 24,180 22,962 GHG Emissions (kg CO2-eq) 1682 1180 3.2.3 Batteries One of the most significant fundamental differences between an HEV and an ICEV are the batteries used to store energy. Both vehicles have the typical lead-acid (Pb-Ac) batteries that are used to start the vehicle’s engine. In the case of the Prius, the hybrid also has a larger nickel metal-hydride (Ni-MH) battery that, along with an electric motor, uses stored energy to supplement the gasoline powered engine. The material compositions of these two types of batteries are listed in Table 6, as reported in [4]. The material weights calculated for each vehicle are based on overall battery weights of 16 kg for the internal combustion engine lead acid battery, 10 kg for the hybrid lead acid battery and 38 kg for the hybrid Ni-MH battery. Table 6. Battery Material Compositions [4] Pb-Ac Ni-MH Material % Weight ICEV (kg) HEV (kg) Material % Weight HEV (kg) Lead 69 11.3 6.9 Nickel 28.2 10.8 Water 14.1 2.3 1.4 Steel 23.7 9.1 Sulfuric Acid 7.9 1.3 0.8 Plastic 22.5 8.6 Plastic 6.1 1.0 0.6 Iron 12 4.6 Fiberglass 2.1 0.3 0.2 Rare Earth Metals 6.3 2.4 Other 0.8 0.1 0.1 Copper 3.9 1.5 Cobalt 1.8 0.7 Magnesium 1 0.4 Wrought Al 0.5 0.2 Rubber 0.1 0.0 17 The battery materials that are most significant from an energy standpoint are lead, nickel and the combination of rare earth metals and other metals that make up the negative electrode of the Ni-MH battery. The consumption energies required for the production of each of these materials are presented in Table 7, as reported in [4]. The majority of lead is produced via secondary production (smelting scrap lead). Nickel is produced via the electrorefining process which dissolves a 70% nickel matte (smelted nickel ore) in sulfuric acid to separate the nickel from oxygen. The metal hydride electrode is produced by mining and processing an intermetallic compound. The original source of the metal-hydride consumption numbers has been questioned but these numbers are used due to the lack of substitute information. Table 8 presents the energy required per vehicle for producing major battery materials. Production energies of other components of the battery are not included because they are considered negligible compared to the production energy of the vehicle as a whole. Table 7. Production Energies for Raw Battery Materials [4] Material Production Energy (mmBtu/ton) Lead 9.5 Nickel 64 Metal Hydride 112.3 Table 8. Battery Material Production Energies per Vehicle Lead (kg) Energy (Btu) Nickel (kg) Energy (Btu) Metal-Hydride (kg) Energy (Btu) Total Energy (Btu) Corolla 11.3 118,357 ----118,357 Prius 6.9 72,271 10.8 762,073 13.5 1,671,499 2,505,843 The energy required for assembly and testing of the batteries is approximated in [4] as being 35.2 million Btu/ton of battery material for Ni-MH batteries and 27.5 million Btu/ton of battery material for Pb-Ac batteries. Based on these numbers and the weights of the batteries, Table 9 shows the total energy required for battery assembly and testing for each of the vehicles. 18 Table 9. Battery Assembly and Test Energies [4] Pb-Ac battery (kg) Energy (Btu) Ni-MH battery (kg) Energy (Btu) Total Energy (Btu) Corolla 16.4 497,244 --497,244 Prius 10 303,197 38.3 1,486,395 1,789,592 Figure 4 shows that the GHGs from battery production are negligible for the ICEV and 1500 kg per vehicle for the HEV. 3.3 Use Cases For the life of the vehicles during the use phase, Table 10 details the three test scenarios chosen for this study. These scenarios are not meant to represent any extremes of driving conditions but rather to approximate a diverse range of what the vehicles would experience in what is considered to be normal driving conditions. The first case assumes 100,000 miles over the life of the vehicle driven mainly in an urban environment. The second case assumes 150,000 miles split relatively equally between urban and highway. The third case assumes that the life of the vehicle is 200,000 miles driven mainly on the highway. The table lists the fuel efficiency (based on EPA estimates reported by the manufacturer) assumed for each vehicle in each case. These fuel efficiencies were calculated by summing the EPA City estimate times the percentage of urban driving with the EPA Highway estimate times the percentage of highway driving. Table 10. Vehicle Scenario Parameters [11], [12] Miles over Lifetime Urban Driving (%) Highway Driving (%) Estimated Prius MPG Case 1 Case 2 Case 3 100,000 150,000 200,000 75 55 20 25 45 80 50.3 49.7 48.6 Estimated Corolla MPG 3.3.1 28.8 30.2 32.6 Use Case Emissions Totals The emissions associated with the Prius and Corolla as reported in [5] in units of grams per mile are extrapolated out for each use case in Table 11 below. The emissions 19 reported are non-methane organic gases (NMOG, previously referred to as VOCs), carbon monoxide (CO), nitrogen oxides (NOx), and carbon dioxide (CO2). Table 11. Emissions Values for Life of Vehicles Used [5] Pollutant (g/mi) NMOG 0.003 CO 0.04 NOx 0.001 CO2 3.3.2 180 Prius Corolla Case 1 (kg) Case 2 (kg) Case 3 (kg) (g/mi) Case 1 (kg) Case 2 (kg) Case 3 (kg) 0.3 0.45 0.6 0.04 4 6 8 4 6 8 1.3 130 195 260 0.1 0.15 0.2 0.2 20 30 40 18,000 27,000 36,000 253 25,300 37,950 50,600 Use Case Fuel Cost Totals Using the mileage for each use case presented in Table 10, and assuming the current national average price of gasoline of $3.92 per gallon (taken from the week of 3/26/2012 from [16]), the total fuel costs for the lifetime of the vehicle are calculated and shown in Table 12. Assuming that the price of gas will increase as the car ages (due to inflation and other economic factors), an average estimate of $5.50 per gallon is used in the calculations shown in Table 13. Table 12. Lifetime Vehicle Fuel Costs at $3.92/gal Miles over Lifetime Estimated Prius MPG Total Prius Fuel Cost ($) Estimated Corolla MPG Total Corolla Fuel Cost ($) Case 1 Case 2 Case 3 100,000 150,000 200,000 50.3 49.7 48.6 $7,801 $11,843 $16,132 28.8 30.2 32.6 $13,635 $19,502 $24,049 Table 13. Lifetime Vehicle Fuel Costs at $5.50/gal Miles over Lifetime Estimated Prius MPG Total Prius Fuel Cost ($) Estimated Corolla MPG Total Corolla Fuel Cost ($) Case 1 Case 2 Case 3 100,000 150,000 200,000 50.3 49.7 48.6 $10,945 $16,616 $22,634 28.8 30.2 32.6 $19,130 $27,363 $33,742 20 3.3.3 Replacement of Fluids Table 14 below from [4] estimates the amount of fluids (excluding gasoline) that are used to support vehicle operation. These fluids are assumed to be replaced at various intervals over the course of the vehicle's life. Figure 3 and Figure 4 show the estimates for energy use and greenhouse gas emissions from the fluids for the life of each of the vehicles. The totals for the ICEV are approximately 13 million Btu/vehicle and 7,000 kg CO2e/vehicle. The totals for the HEV are approximately 12 million Btu/vehicle and 6,000 kg CO2e/vehicle. Table 14. Vehicle Fluid Weights (lb) [4] 3.3.4 Battery Replacement The Ni-MH battery is expected to last 150,000 miles based on Toyota laboratory bench testing [11]. The hybrid-electric battery is typically covered under warranty up to at least 100,000 miles. Battery replacement will be considered for Case 3 only and the parts and labor cost for this replacement will be assumed to be $3,000 ($2,400 parts, $600 labor). To account for the energy of the replacement battery, the energy values for the Ni-MH battery will simply be counted twice in Case 3. 3.4 End of Life/Recycle The end of life of these vehicles is considered to be the point where they are no longer road worthy, either because it is cost prohibitive to continue to drive the vehicle or it is no longer capable of passing a safety or emissions inspection. For the purposes of this study, the vehicle is assumed to be shredded since the vast majority of scrapped vehicles in the United States are shredded [10]. This study will assume that 100% of shredded metals are recycled and that all non-metals will be either incinerated or sent to a landfill. This assumption is reasonably accurate as the only metal that is wasted in the shedding 21 process is metal that cannot be separated from the automobile shredder residue (ASR). Table 15 provides values of net energy savings for the metals found in the Corolla and Prius. These values were obtained from [10] with the exception of the nickel value, which was assumed to be the same as the secondary production value of nickel discussed previously in this report. The remainder of these energy savings are estimated by the savings in energy from using recycled metals versus the energy required for mining and production of virgin metals. The estimated 32 Btu/lb of recycled metal required for the shedding process is assumed to be negligible. Table 15 calculates the estimated total energy savings based on the metal quantities present in the Corolla and Prius. These values include the metals used in the batteries for each of the vehicles. The total values compare favorably to the estimated 55 million Btu/vehicle energy savings for a vehicle that has been shredded quoted in [10]. Table 15. Material Recycling Estimates by Weight [10] Net Savings Corolla Prius (Btu/lb) Weight (lb) Savings (Btu) Weight (lb) Savings (Btu) Aluminum 120,200 188 22,597,600 238 28,607,600 Copper 37,000 52 1,924,000 137 5,069,000 Lead 14,200 25 355,000 15 213,000 Iron 10,700 303 3,242,100 193 2,065,100 Steel 10,700 1,687 18,050,900 2,003 21,432,100 Nickel* 32,000 0 0 24 768,000 Total 46,169,600 58,154,800 Material 22 4. Results 4.1 Energy Totals The energy figures presented in Section 3 for production, assembly, use and recycling, converted to the common unit of British thermal unit (Btu), are presented in Table 16 for the Corolla, the ICEV and the Prius, the HEV. These energy values are summed in Table 17 to determine the net energy usage per vehicle for each use case. Use case energy values are calculated as the product of the number of gallons of gasoline burned and the amount of energy that can be extracted from burning one gallon of gasoline (132 MJ) [17]. Table 16. Energy Totals per Vehicle (in Million Btu) Energy per Vehicle (mmBtu) Material Production Vehicle Assembly Battery Production Battery Assembly and Test Fluids Including Replacement Gasoline (Case 1) Gasoline (Case 2) Gasoline (Case 3) Battery Replacement (Case 3) Recycled Metal Savings Corolla (ICEV) Prius (HEV) 75 64 23 22 0.12 2.5 0.50 1.8 13 12 435 249 623 378 768 515 0 3.9 -46 -58 Table 17. Net Energy per Vehicle for Case Studies (in Million Btu) Net Energy per Vehicle (mm Btu) Corolla (ICEV) Prius (HEV) Case 1 500 293 Case 2 688 422 Case 3 833 563 4.2 Emissions Totals The greenhouse gas emissions from production, assembly, and use of each of the vehicles are presented in Table 18 in units of kilograms of CO2-equivalent. Only greenhouse gases are included in this total because the amounts of these gases can be compared across the various vehicle stages using a single common quantifier (CO2-e). Note that the production GHG emissions value for the HEV also includes 1,500 kg of 23 GHG from the Ni-MH battery. Information on other pollutants is presented in Section 3, where available. Table 19 presents the net greenhouse gas emissions per vehicle for each of the use cases. Note that the net GHG emissions for Case 3 include the production emissions from two Ni-MH batteries. Table 18. Greenhouse Gas (GHG) Emission per Vehicle Totals (units of kg CO2e) Emissions per Vehicle (kg CO2e) Corolla (ICEV) Prius (HEV) Production GHG Emissions 6,250 6,800 Assembly GHG Emissions 1,682 1,180 Use GHG Emissions (Case 1) 25,300 18,000 Use GHG Emissions (Case 2) 37,950 27,000 Use GHG Emissions (Case 3) 50,600 36,000 Table 19. Net GHG Emissions per Vehicle for Use Cases (units of kg CO 2e) Emissions per Vehicle (kg CO2e) Corolla (ICEV) Prius (HEV) Net GHG Emissions (Case 1) 33,232 25,980 Net GHG Emissions (Case 2) 45,882 34,980 Net GHG Emissions (Case 3) 58,532 45,480 4.3 Cost Totals The total costs per vehicle in units of dollars including the manufacturer's suggested retail price (MSRP) which encompasses production and assembly, the cost of gasoline for the use phase and the assumed cost of battery replacement for the hybrid Ni-MH battery (Case 3 only) are presented in Table 20. Costs such as maintenance, replacement parts and fluids are not included but can be assumed to be roughly similar between the ICEV and the HEV, on average. Also, no cost is included for vehicle shredding as the cost of the shredder is assumed to be offset by the sale of the recycled materials. Table 21 presents the net cost per vehicle for each use case ($3.92/gallon and $5.50/gallon assumptions are both included). 24 Table 20. Cost per Vehicle (in Dollars) Cost ($) Corolla (ICEV) Prius (HEV) Vehicle MSRP $16,130 $24,000 Gasoline (Case 1, $3.92/gal) $13,635 $7,801 Gasoline (Case 2, $3.92/gal) $19,502 $11,843 Gasoline (Case 3, $3.92/gal) $24,049 $16,132 Gasoline (Case 1, $5.50/gal) $19,130 $10,945 Gasoline (Case 2, $5.50/gal) $27,363 $16,616 Gasoline (Case 3, $5.50/gal) $33,742 $22,634 Battery Replacement (Case 3) $0 $3,000 Table 21. Net Cost per Vehicle (in Dollars) Net Cost ($) Gasoline (Case 1, $3.92/gal) Gasoline (Case 2, $3.92/gal) Gasoline (Case 3, $3.92/gal) Gasoline (Case 1, $5.50/gal) Gasoline (Case 2, $5.50/gal) Gasoline (Case 3, $5.50/gal) 25 Corolla (ICEV) Prius (HEV) $29,765 $31,801 $35,632 $35,843 $40,179 $43,132 $35,260 $34,945 $43,493 $40,616 $49,872 $49,634 5. Conclusions The net energy per vehicle values listed in Table 17 show that the Prius uses an average of about 60% of the energy that the Corolla uses over their respective lifetimes. This study was unable to replicate the scenario where the Prius required more energy to produce and assemble than the Corolla, likely because general manufacturing information based on overall vehicle mass was used instead of information specific to the Prius and Corolla. Although the energy to produce the Prius' battery was included, the energy intensive processes used to manufacture other components unique to the Prius were not accounted for. Another reason for the energy difference is that the energy totals from [15] for vehicle production and assembly were lower in Japan (where the Prius is manufactured) than in the US (where the Corolla is built) even after considering the fact that the Prius weighs more than the Corolla. The totals nonetheless show that the majority of the energy use does in fact occur during the use phase, where the Prius clearly has the advantage. The Prius also is of more value from a recycled metals perspective because it contains abundance of metals such as aluminum, copper and nickel. The greenhouse gas emissions per vehicle accumulated over a lifetime also favor the Prius as shown in Table 19. The Prius produces just under 80% of the greenhouse gas emissions of the Corolla over the vehicle lifetime. As stated in the previous paragraph, assembly values for the Prius were expected to be higher than the Corolla but this did not turn out to be the case. However, accounting for the GHG emissions from producing the battery, the Prius did produce more GHGs during production and assembly than the Corolla. This difference was more than compensated for during the use phase. Again the greenhouse gas emission totals from the use phase are 3-5 times those of the production totals, with the Prius being decidedly better in the use phase. Other pollutants are listed in Table 4 and Table 11 with the Prius having a large cumulative advantage regarding total pollution emitted. The amount of pollution and greenhouse gases emitted during the shredding process is assumed to be comparable for both vehicles and negligible relative to the production and use phases. 26 As indicated in Table 21, the Corolla is the more economical choice at today's gasoline price ($3.92/gal) but the Prius proves to be cheaper at a price of $5.50/gal. This result does not resoundingly support the hybrid manufacturer's claims but the lower gasoline price scenario agrees with the conclusions reported in [5]. Since some of the additional cost of the Prius can be attributed to the consideration that the Prius is slightly better equipped in terms of amenities than the Corolla, the fact that the overall costs between the two vehicles are close or in favor of the Prius may sway some buyers in the direction of the HEV. At high mileage and high gasoline prices, the Prius turns out to be less expensive than the Corolla even including the cost to replace the hybrid Ni-MH battery. The Prius proved to be considerably better for the environment because of a lower lifetime energy consumption and fewer emissions but the decision on which vehicle is less expensive when all costs are considered is not as clear. While these results are not a significant departure from what was expected based on prior research, it seems that the Prius is a better choice in a high gas price scenario while the Corolla makes financial sense only if one assumes that the price of gasoline will be stagnant. While hybrid and other alternative energy technologies will become a critical part of the future of transportation given government plans to increase fuel consumption regulations, a consumer wishing to make a decision based on the products of today could still see a financial benefit by purchasing a Corolla if they predict a low mileage and/or low gas price scenario, provided they were not morally opposed to the would-be negative environmental impact that comes along with such a savings. However, ultimately the environmental advantage of the Prius is without question and the bottom line cost favors the Prius if gasoline prices continue their upward trend, making it the most sensible choice for the majority of consumers. 27 References [1] Wikipedia.com: Pollution., n.d. 16 February 2012. <http://en.wikipedia.org/wiki/Pollution>. 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