Chapter 1

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Chemistry 1151 Mid-Term Study Guide

Exam will have 100 points.

You will be allowed the entire class period to complete the exam.

The exam will be a mix of multiple-choice and show your work problems, following the format of the quizzes.

Review your quiz zes, homework problems, class notes, instructor’s homepage,

Chang’s web site and textbook.

Do not forget to bring a functioning calculator !!!

Chapter 1

 Know the basic steps in the “scientific method”

Distinguish between a hypothesis, a theory, and a law

Know the 3 states of matter and their general properties

Distinguish between homogeneous mixtures (solutions) and heterogeneous mixtures

Distinguish between physical and chemical means of separation and physical and chemical changes

Distinguish between atoms and molecules and elements and compounds

Know the difference between macroscopic and microscopic properties, and intensive and extensive properties

 Be able to express measurements in “scientific notation”

Know the basic metric units of mass, volume and length and be able to convert them into other units

Know the prefixes used with SI Units (Table 1.3 in text)

Be able to convert between Fahrenheit, Celsius and Kelvin temperature scales

Know the difference between accuracy and precision

Be able to express all answers with the correct number of significant figures

Be able to find density and use density to find volume and mass

Chapter 2

 Be familiar with Dalton’s Atomic Theory, the Law of Conservation of Mass, the

Law of Definite Proportions, and, the Law of Multiple Proportions

Know the subatomic particles, their approximate mass, charge, and location within the atom

Know the basic findings of the experiments of JJ Thompson (electron charge –

1.76 x 10 8 C/g), Millikan (charge of single electron

–1.6022 x 10 -19 C), and

Rutherford (small, dense nucleus) and Thompson’s ‘Plum-Pudding” Model of the

Atom

 Use “atomic notation” to find the number of electrons, protons and neutrons of an atom or ion number: protons + number of neutrons X or mass number X or Z X

number of protons atomic number A

Be able to define isotopes (same element, but different mass/number of neutrons)

 Know “family” names and general sections of the periodic chart (alkali metals, alkaline earth metals, transition metals, halogens, noble gases)

Know which elements are metals, metalloids and nonmetals

Know names and symbols of all elements in Figure 2.11 of text

Know the definition of a molecule, and which elements occur as diatomic molecules

Know the definition of ions, cations, and anions and be able to predict ion charge of an element from its location in the periodic chart (Table 2.2)

Be able to identify if a compound is an ionic compound

Know the definition of isoelectric and be able to recognize atoms and ions that are isoelectric

Be able to give the atomic composition of a compound from its formula

Know the definition of empirical formula and be able to recognize them

Be able to name binary and ternary compounds

Know the names of the common acids and ions (Table 2.3)

Know how to name oxoacids, oxoanions and bases

Be able to name compounds with waters of hydration

Chapter 3

 Know the definition of Mole, Avogadro’s Number and Molar Mass

Be able to calculate average atomic mass from an atom’s isotopic distribution and vice versa

Determine the number and types of atoms in a formula

Be able to find the Molar Mass of elements on the periodic chart and calculate the Molar Mass of compounds

Do conversions: mass moles

 Find % composition from a compound’s formula

individual particles

 Find a compound’s empirical formula from its % composition

 Find a compound’s (true) molecular formula from its empirical formula and molar mass

Write and balance chemical reactions

Use balanced equations to do stoichiometry problems (and calculate Theoretical yield)

Know how to identify and calculate limiting reagents and excess reagents

Be able to calculate % Yield (given actual yield) and vice versa

Chapter 4

Know the definitions of solution, solvent and solute

Be able to identify electrolytes and nonelectrolytes and which are strong electrolytes

Be able to describe the hydration of ions in aqueous solutions

Know the solubility rules (Table 4.2)

Be able to write molecular equations, ionic equations and net ionic equations for precipitation reactions

Know the Arrhenius and Brønsted theories of acids and bases

Know the definition of monoprotic, diprotic and triprotic acids

Know the difference between strong and weak acids an bases

Know whi ch acids are strong (“Big Six”) and which are weak

Know which bases are strong and which are weak

Define a neutralization reaction according to the

Brønsted theory (proton transfer)

Know how to identify Oxidation-Reduction Reactions (Redox reactions)

Be able to calculate oxidation numbers

Be able to identify which elements are oxidized, and reduced, and which reagents are oxidizing agents and which are reducing agents

Be able to write half reactions showing the transfer of electrons for an oxidation or reduction

Identify types of reactions: Combination, Decomposition, Metal Displacement,

Halogen Displacement, Hydrogen Displacement and Disproportionation

Reactions

Be able to find the concentration of a solution in units of Molarity (mol/L)

Be able to use Molarity as a conversion factor between moles and volume of a solution

Be able to calculate dilutions of solutions

Be able to stoichiometry problems that involve solutions of known Molarity

Know what an acid-base titration is, the definitions of equivalence point, titrant, standard solution and analyte

Be able to do stoichiometry problems that involve acid/base neutralizations

(titrations)

Be able to do stoichiometry problems that involve precipitation reactions

(gravimetric analysis).

Chapter 5

Know the properties of gases

Know which substances exists as gases and why

 For gases, be able to change pressure units from “atm” to “torr” and “mm of Hg”

Know what a barometer, closed end manometer and open-end manometer are and how to calculate the pressure of a gas

 Know how to use the gas laws (Boyles’, Charles’, Gay-Lussac’, Avogadro’s, and

Combined) to do calculations.

Potentially Useful Information:

1 atm = 760. mm Hg = 760. torr = 101.325 kPa = 29.92 in Hg

N

A

= 6.022 x 10 23 R = 0.082057 L atm / K mole

°C = (°F – 32°F)*(5°C/9°F) °F = (9°F/5°C)*°C + 32°F K = °C + 273.15

Happy studying !!

Good Luck !!

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