I. Grade Level/Unit Number: 9-12 Unit 13 II: Unit Title: Acids & Bases III. Unit Length: 5 days (on a 90 min. per day block schedule) IV. Major Learning Outcomes: Students should be able to: V. Acids & Bases Distinguish between acids and bases based on formula and chemical properties. Distinguish between Arrhenius acids and bases and Bronsted-Lowry acids and bases. Compute concentration (molarity) of acids and bases in moles per liter. Calculate molarity given mass of solute and volume of solution. Calculate the mass of a solute needed to create a solution of a given molarity and volume. Solve dilution problems: M1V1=M2V2. Differentiate between concentration (molarity) and strength (degree of dissociation). No calculations involved. Use pH scale to identify acids and bases. Interpret pH scale in terms of the exponential nature of pH values in terms of concentration. Relate the color of an indicator to pH using pH ranges provided in a table. Range should involve various values of pH (for example: 3.3 or 10.8). Determine the concentration of an acid or base using titration. Interpret titration curve for strong acid/strong base. Compute pH, pOH, [H+], [OH-]. Calculations will involve only whole number values (for example: pH or pOH values such as 3,5,8 and[H+] and [OH-] values such as 1x10-4 or 1x10-10). Content Objectives Includes (with RBT Tags): Objective Objective Number 5.04 Assess the physical and chemical properties of acids and bases. General properties of acids and bases. Concentration and dilution of acids and bases. Ionization and the degree of dissociation (strengths) of acids and bases. Indicators. Acid-base titration. pH and pOH.VSEPR theory. Chemistry- Unit 13 DRAFT RBT Tag B4 1 3.02 Apply the mole concept, Avogadro’s number and conversion factors to chemical calculations: Molarity of solutions. VI. English Language Development Objectives (ELD) Included: NC English Language Proficiency (ELP) Standard 4 (2008) for Limited English Proficiency Students (LEP)- English Language learners communicate information, ideas, and concepts necessary for academic success in the content area of science. Suggestions for modified instruction and scaffolding for LEP students and/or students who need additional support are embedded in the unit plan and/or are added at the end of the corresponding section of the lessons. The amount of scaffolding needed will depend on the level of English proficiency of each LEP student. Therefore, novice level students will need more support with the language needed to understand and demonstrate the acquisition of concepts than intermediate or advanced students. VII. Materials/Equipment Needed Activity Household Acids * Bases Materials LabPro or CBL 2 interface TI Graphing Calculator DataMate program pH Sensor wash bottle distilled water ring stand utility clamp sensor soaking solution Household solutions Test tubes Test tube racks Red & blue litmus paper Stirring rods Red cabbage juice 250-mL beakers VIII. Detailed Content Description: Please see the detailed content description for each objective in the chemistry support document. The link to this downloadable document is in the Chemistry Standard Course of Study at: http://www.ncpublicschools.org/curriculum/science/scos/2004/24chemistry IX. Unit Notes: This unit is focused on the concept of the physical and chemical properties of acids and bases. Students should be able to identify Arrhenius acids and bases and Bronsted- Chemistry- Unit 13 DRAFT 2 Lowry acids and bases. They will be able to calculate the molarity of acids and bases and solve dilution problems. Students will be able to differentiate between concentration and strength of acids and bases. They will use the pH scale to identify acids and bases and be able to calculate pH, pOH, [H+], and [OH-] of acidic and basic solutions. Students will determine the concentration of acids and bases using titration and relate indicator color change to pH. This unit is focused on the concept of the physical and chemical properties of acids and bases. In each unit, Goal 1 objectives which relate to the process of scientific investigation are included. In each of the units, students will be practicing the processes of science: observing, hypothesizing, collecting data, analyzing, and concluding. The Goal 1 Objectives are as follows: COMPETENCY GOAL 1: The learner will develop abilities necessary to do and understand scientific inquiry. 1.01 Design, conduct and analyze investigations to answer questions related to chemistry. Identify questions and suggest hypotheses. Identify variables. Use a control when appropriate. Select and use appropriate measurement tools. Collect and organize data in tables, charts and graphs. Analyze and interpret data. Explain observations. Make inferences and predictions. Explain the relationship between evidence and explanation. Identify how scientists share findings. Chemistry- Unit 13 DRAFT This goal and these objectives are an integral part of each of the other goals. In order to measure and investigate scientific phenomena, students must be given the opportunity to design and conduct their own investigations in a safe laboratory. The students should use questions and models to formulate the relationship identified in their investigations and then report and share those finding with others Students will be able to: Identify questions and suggest hypotheses. Identify variables. Use a control when appropriate. Select and use appropriate measurement tools. Collect and organize data in tables, charts and graphs. Analyze and interpret data. Explain observations. Make inferences and predictions. Use questions and models to determine the relationships 3 between variables in investigations. Identify how scientists share findings. If a teacher follows this curriculum (s)he will have addressed the goals and objectives of the SCOS. However, teachers may want to substitute other activities that teach the same concept. The unit length has extra time built in for quizzes, going over homework, additional practice depending on the nature of the class, and assessment. Teachers should utilize the textbook as a resource by assigning homework each day and providing additional guided and independent practice. Reference Tables: The North Carolina Chemistry Reference Tables were developed to provide essential information that should be used on a regular basis by students, therefore eliminating the need for memorization. It is suggested that a copy be provided to each student on the first day of instruction. A copy of the reference tables can be downloaded at the following URL: http://www.ncpublicschools.org/docs/curriculum/science/scos/2004/chemistry/referencet ables.pdf Essential Questions: Essential questions for this unit are embedded within the unit. Essential questions are those questions that lead to student understanding. Students should be able to answer these questions at the end of an activity. Teachers are advised to put these questions up in a prominent place in the classroom. The questions can be answered in a journal format as a closure. Safety: Students should wear chemical splash goggles during any lab activity involving chemicals. This includes household substances. It is extremely important for the safety and success of your students that you do ALL activities and labs prior to assigning them to students. At the beginning of each lab, the teacher should address any specific safety concerns relating to the activity. Computer Based Activities: Several of the recommended activities are computer based and require students to visit various internet sites and view animations of various biological processes. These animations require various players and plug-ins which may or may not already be installed on your computers. Additionally some districts have firewalls that block Chemistry- Unit 13 DRAFT 4 downloading these types of files. Before assigning these activities to students it is essential for the teacher to try them on the computers that the students will use and to consult with the technology or media specialist if there are issues. These animations also have sound. Teachers may wish to provide headphones if possible. X. Global Content: Aligned with 21st Skills: One of the goals of the unit plans is to provide strategies that will enable educators to develop the 21st Century skills for their students. As much as students need to master the NCSOS goals and objectives, they need to master the skills that develop problem solving strategies, as well as the creativity and innovative thinking skills that have become critical in today’s increasingly interconnected workforce and society. The Partnership for 21st Century Skills website is provided below for more information about the skills and resources related to the 21st Century classroom. http://www.21stcenturyskills.org/index.php?option=com_content&task=view&id=27&Ite mid=120 NC SCS Chemistry 21st Century Skills Communication Skills 1.01, 5.04 & Conveying thought or opinions effectively 3.02 1.01, 5.04 & When presenting information, 3.02 distinguishing between relevant and irrelevant information Activity Household Acids * Bases Electronic Cereal Oil & Water Don’t Mix Lab Design a Molecule Project Polarity Review Electronic Cereal Oil & Water Don’t Mix Lab Design a Molecule Project Polarity Review Electronic Cereal Oil & Water Don’t 1.01, 5.04 & Explaining a concept to others 3.02 Interviewing others or being interviewed Computer Knowledge 1.01 Using word-processing and database programs 1.01 Developing visual aides for presentations 1.01 Using a computer for communication Learning new software programs Employability Skills 1.01, 5.04 & Assuming responsibility for own learning 3.02 Chemistry- Unit 13 DRAFT 5 1.01, 5.04 & Persisting until job is completed 3.02 1.01, 5.04 & Working independently 3.02 Developing career interest/goals 1.01 Responding to criticism or questions Information-retrieval Skills Searching for information via the computer Searching for print information Searching for information using community members Language Skills - Reading 5.04 & 3.02 Following written directions Identifying cause and effect relationships Summarizing main points after reading Locating and choosing appropriate reference materials Reading for personal learning Language Skill - Writing Using language accurately 1.01, 5.04 & Organizing and relating ideas when 3.02 writing Mix Lab Design a Molecule Project Polarity Review All activities WIZARD assessment questions Most of the activities can be presented as opportunities for students to follow written directions. The teacher will have to work with most students to develop this skill over time. The following activities are well suited to developing skills in following directions: Electronic Cereal Oil & Water Don’t Mix Lab Design a Molecule Project Polarity Review Chemistry- Unit 13 DRAFT Oil & Water Don’t Mix Lab Design a Molecule Project 6 1.01, 5.04 & Proofing and Editing 3.02 Synthesizing information from several sources Documenting sources Developing an outline Writing to persuade or justify a position Creating memos, letters, other forms of correspondence Teamwork 1.01 Taking initiative 1.01, 5.04 & Working on a team 3.02 All activities Thinking/Problem-Solving Skills Identifying key problems or questions 1.01, 5.04 & Evaluating results 3.02 5.04 & 3.02 Developing strategies to address problems 3.02 Developing an action plan or timeline Electronic Cereal Oil & Water Don’t Mix Lab Design a Molecule Project Polarity Review Electronic Cereal Oil & Water Don’t Mix Lab Design a Molecule Project Polarity Review Electronic Cereal Oil & Water Don’t Mix Lab Design a Molecule Project Design a Molecule Project EXPLORE: (60 minutes) Chemistry- Unit 13 DRAFT 7 Household Acids and Bases Lab Students will investigate various household acids and bases. They will use red and blue litmus paper to determine if the substance is an acid or base, followed by red cabbage juice to discover how indicators can show strengths. They will complete the lab by using Vernier pH probes to determine the pH value. Students will compare the various methods of experimentation. If pH probes are not available, the teacher may substitute pHydrion paper for the probeware. Essential Question: What is the relevance of common household acids and bases in regards to chemistry? Household Acids and Bases © 2008 Vernier Software & Technology Many common household solutions contain acids and bases. Acid-base indicators, such as litmus and red cabbage juice, turn different colors in acidic and basic solutions. They can, therefore, be used to show if a solution is acidic or basic. An acid turns blue litmus paper red, and a base turns red litmus paper blue. The acidity of a solution can be expressed using the pH scale. Acidic solutions have pH values less than 7, basic solutions have pH values greater than 7, and neutral solutions have a pH value equal to 7. In this experiment, you will use litmus and a pH Sensor to determine the pH values of household substances. After adding red cabbage juice to the same substances, you will determine the different red cabbage juice indicator colors over the entire pH range. Figure 1 Chemistry- Unit 13 DRAFT 8 MATERIALS LabPro or CBL 2 interface TI Graphing Calculator DataMate program pH Sensor wash bottle distilled water ring stand utility clamp sensor soaking solution household solutions 7 small test tubes test-tube rack red and blue litmus paper paper towel stirring rod red cabbage juice 250-mL beaker PROCEDURE 1. Obtain and wear goggles. CAUTION: Do not eat or drink in the laboratory. Part I Litmus Tests 2. Label 7 test tubes with the numbers 1-7 and place them in a test-tube rack. 3. Measure 3 mL of vinegar into test tube #1. Refer to the data table and fill each of the test tubes 2-7 to about the same level with its respective solution. CAUTION: Ammonia solution is toxic. Its liquid and vapor are extremely irritating, especially to eyes. Drain cleaner solution is corrosive. Handle these solutions with care. Do not allow the solutions to contact your skin or clothing. Wear goggles at all times. Notify your teacher immediately in the event of an accident. 4. Use a stirring rod to transfer one drop of vinegar to a small piece of blue litmus paper on a paper towel. Transfer one drop to a piece of red litmus paper on a paper towel. Record the results. Clean and dry the stirring rod each time. 5. Test solutions 2-7 using the same procedure. Be sure to clean and dry the stirring rod each time. Part II Red Cabbage Juice Indicator 6. After you have finished the Part I litmus tests, add 3 mL of red cabbage juice indicator to each of the 7 test tubes. Record your observations. Dispose of the testtube contents as directed by your teacher. Part III pH Tests 7. Prepare the pH Sensor for data collection. a. Plug the pH Sensor into Channel 1 of the LabPro or CBL 2 interface. Use the link cable to connect the TI Graphing Calculator to the interface. Firmly press in the cable ends. b. Remove the pH Sensor from the sensor storage solution bottle by unscrewing the lid. Carefully remove the bottle, leaving the 0-ring and cap on the sensor body. c. Rinse the tip of the sensor with distilled water and place the sensor tip into a beaker containing sensor soaking solution. Use a utility clamp to fasten the pH Sensor to a ring stand, as shown in Figure 1. Chemistry- Unit 13 DRAFT 9 8. Turn on the calculator and start the DATAMATE program. Press program. CLEAR to reset the 9. Set up the calculator and interface for the pH Sensor. a. If the calculator displays pH in CH 1, proceed directly to Step 10. If it does not, continue with this step to set up your sensor manually. b. Select SETUP from the main screen. c. Press ENTER to select CH 1. d. Select PH from the SELECT SENSOR menu. e. Select OK to return to the main screen. 10. Raise the pH Sensor from the sensor soaking solution and set the solution aside. Use a wash bottle filled with distilled water to thoroughly rinse the pH Sensor. Catch the rinse water in a 250-mL beaker. 11. Get one of the 7 solutions in the small container supplied by your teacher. Raise the solution to the pH Sensor and swirl the solution about the sensor. When the pH reading displayed on the main screen of the calculator stabilizes, record the pH value (round to the nearest 0.01 pH unit). 12. Prepare the pH Sensor for reuse. a. Rinse it with distilled water from a wash bottle. b. Place the sensor into the sensor soaking solution and swirl the solution about the sensor briefly. c. Rinse with distilled water again. 13. Determine the pH of the other solutions using the Step 11 procedure. You must clean the pH Sensor between tests, using the Step 12 procedure. 14. When you are done, rinse the sensor with distilled water and return it to the sensor soaking solution. Select QUIT and exit the DATAMATE program.. PROCESSING THE DATA 1. Which of the household solutions tested are acids? How can you tell? 2. Which of the solutions are bases? How can you tell? 3. What color(s) is red cabbage juice indicator in acids? In bases? 4. Can red cabbage juice indicator be used to determine the strength of acids and bases? Explain. 5. List advantages and disadvantages of litmus and red cabbage juice indicators. DATA TABLE Test Tube Solution Chemistry- Unit 13 Blue Litmus DRAFT Red Litmus Red Cabbage Juice 10 pH 1 vinegar 2 ammonia 3 lemon juice 4 soft drink 5 drain cleaner 6 detergent 7 baking soda EXPLAIN: Students will share their observations and answers to the Household Acids & Bases lab with the class. Instruct the students to provide reasons and explanations for their answers. ELABORATE: Acid and Base PowerPoint (45 minutes) The teacher should use the PowerPoint to introduce acid/base concepts including the theories, pH scale, and how to calculate pH, pOH, [H3O+], and [OH-]. Guided practice is provided. Essential Question: How are acids and bases identified according to their physical and chemical properties? Language (ELP) Objectives for LEP Students: Complete filling notes handout with Acid and Base PowerPoint (below). Unit 13 Acids and Bases- Notes 1. List the properties of acids ______ to taste React with some ________ to form _______ gas Turns litmus paper ______ Phenolphthalein ______ __________ Chemistry- Unit 13 DRAFT 11 Electrolytes _____________ Form ________: hydronium ions ___________ 2. List the properties of bases Bitter to __________ Slippery to __________ Turns litmus ___________ Phenolphalein turns ____________ Many form ______ (hydroxide ions) in ______ 3. What is the difference between acidic, basic, and neutral solutions? Acidic solutions: ____________________________ Basic solutions: _____________________________ Neutral solutions: ___________________________ 4. Definitions of acids and bases I. Arrhemius Acids ____________ and bases ______________. Ex. II. Bronsted-Lowery Acids are _________________ and bases are ___________ III. Conjugate acids and bases A conjugate acid is _______________ and a conjugate base is ______________. Ex. A conjugate acid-base pair is two _____________ related by the _______ or _______ of a single _______. Always _____________ with an __________ and an _________. Water is _________(a switch hitter?????) and can act as either _________ or ________ depending _______________________ . Monoprotic acids ________________________________________. Ex. Chemistry- Unit 13 DRAFT 12 Polyprotic acids _________________________________________ . Ex. 5. Types of acids and bases I. Strong _________ and _________: because electrolytes _________ 100% in water Ex. II. Weak _______ and _______: because _____________ only ___________ ionize in water. Ex. Slide 1 Unit 13: Acids and Bases Slide 2 Properties Acids: Sour to taste React with some metals to form H2 gas Turn litmus red Phenolphthalein stays colorless Electrolytes (conduct) Form H+ (H3O+): hydronium ions when attach to water molecule Chemistry- Unit 13 DRAFT 13 Slide 3 Bases: Bitter to taste Slippery to touch Turn litmus blue Phenolphthalein turns MAGENTA!!!!! Electrolytes Many form OH- (hydroxide ions) in water Slide 4 Slide 5 Acidic solutions: more H3O+ Basic solutions: more OHNeutral solutions: [H3O+] = [OH-] Definitions of acids and bases I. Arrhenius (traditional): Acids: produce H3O+ in water Bases: produce OH- in water Ex: HCl(g) H+(aq) + Cl-(aq) NaOH(s) Na+(aq) + OH-(aq) **** most common definition used in high school Chemistry!!!!!!!!!! Slide 6 II. Brǿnsted-Lowry: Acids: H+ donor (proton donor) Bases: H+ acceptor (proton acceptor) Chemistry- Unit 13 DRAFT 14 Slide 7 Conjugate acid: particle formed when a BASE gains a H+ (ex: NH3 NH4+) base conj acid Conjugate base: particle that remains after an acid has donated a H+ (ex: H2O OH-) acid conj base Slide 8 Conjugate acid-base pair: two substances related by the loss or gain of a single H+……. Always paired with acid and base…… Ex: NH3 + H2O NH4+ + OHwhich is which? Ex: HCl + H2O H3O+ + Clhow about here????? Slide 9 Water is AMPHOTERIC (a switch hitter?????) can act as either an acid or base depending on what it is coupled with Monoprotic acids: donate only one H+ (ex: HClO4, HCl, HBr, HNO3) Polyprotic acids: donate more than one H+ (ex: H2SO4, H2CO3) **these actually ionize in steps, with each H+ peeling away Slide 10 Types of Acids and bases I. Strong acids and bases: Strong electrolytes because they ionize 100% in water!!!!!!! Ex: strong acids: HCl, HNO3,H2SO4, HClO4, HI, HBr strong bases: (called ionic hydroxides) NaOH, KOH, Ca(OH)2…. Do you notice anything about the metals involved????? Chemistry- Unit 13 DRAFT 15 Slide 11 II. Weak acids and bases: weak electrolytes because they only SLIGHTLY ionize in water!!!!!!!!!!! ex: weak acids: H3PO4, HC2H3O2, H2CO3 weak bases: low [OH-] NH3 (NH4OH in water) Slide 12 What in the world is pH? Pouvoir hydrogene: “hydrogen power” pH=measure of [H3O+]……. Acidity + [H3O ] expressed in powers of 10 ex: 10-14 to 10-1 **Formula for calculation: -log [H3O+] = pH Slide 13 pH ranges from 0 to 14 pH <7 acids; 0 is strongest pH = 7 neutral pH >7 bases; 14 is strongest Slide 14 Calculations for pH Chemistry- Unit 13 if [H3O+] is: a. 1.00 x 10-3M b. 1.00 x 10-6M c. 1.00 x 10-7M DRAFT 16 Slide 15 Calculating pOH pOH = -log [OH-] pH + pOH = 14 So….. If pH is 2, then pOH is 12 If [OH-] is: a. 1.0 x 10-5 b. 1.0 x 10-12 Slide 16 Calculating [H3O+] or [OH-] If pH = 3, then [H3O+] is 1.0 x 10-3 If pOH = 5, then [OH-] is 1.0 x 10-5 Buffers: solutions that can absorb moderate amounts of acids and bases without a significant change in pH **provide ions that react with excess H3O+ or OH- EVALUATE: (30 minutes) Acid and Base Practice This activity will allow students to elaborate on their understanding of pH, pOH, [H3O+], and [OH-] calculations with guided and independent practice. After students have completed these questions, the teacher will evaluate students’ understanding by going over the questions with the students. ACID AND BASE PRACTICE 1. List 3 general properties of ACIDS. 2. List 3 general properties of BASES. 3. What are the two products of a neutralization reaction? 4. What are the proton-donor/proton-acceptor definitions of acids and bases? (i.e. which is which?) Chemistry- Unit 13 DRAFT 17 5. What ion is present in all acidic solutions? 6. How is pH related to the concentration of hydronium ions in solution? 7. What determines the degree to which an acid or base is weak or strong? 8. Are strong acids and bases good electrolytes? Explain why. 9. Explain how the concentration of an acid differs from the strength of an acid. 10. Of the five major types of reactions, which type is a neutralization reaction? 11. Circle the compound that is the proton donor: HNO3 + H2O H3O+ + NO3_ 12. Name the acid and base that react to form KCl. Acid: ________ Base: ________ 13. Apples contain several acids, including malic acid, ascorbic acid (vitamin C), and citric acid. What effect would apple juice have on phenolphthalein? 14. The desired pH range of chlorinated water in swimming pools is 7.2 to 7.8. How does the concentration of hydronium ions in this solution compare to that of lemon juice? 15. What is the pH of pure water? 16. To what subatomic particle is the hydrogen ion equivalent? 17. When a salt is formed, which forms the positive ion: the acid or base? ______________ the negative ion, the acid or base? _____________ 18. Water is formed from the reaction of an acid and a base. Why is it not classified as a salt? 19. What is the formula for calculating pH mathematically? 20.Compare the pH values of acids, bases, and salts. 21. If you add HCl to Mg metal, what will you observe? What products form from this reaction? Chemistry- Unit 13 DRAFT 18 22. Identify the following compounds as an acid, base, or salt. a. LiOH ________________ b. H2CO3 ___________ c. Ba(OH)2 ______________ d. MgCl2 ___________ 23. What happens when HNO3(aq) is added to KOH(aq)? What are the products? 24. Circle the following compounds that can react with H2SO4 to make a salt. Name the salt that would form where applicable. a. NaCl __________________ b. Ca(OH)2 ________________ c. HF ___________________ d. H2O __________________ e. Mg(OH)2 _______________ 25. A solution is an acid or a base and it doesn’t react with a metal. Is its pH more likely to be 4 or 9? Why? 26. Which of the following is a weak base? NaCl NH3 HCl HF KOH 27. Which of the following is a strong acid? NH3 HC2H3O2 HCl NaOH 28. An acid that only contains H and one other element is called a ____________ acid. 29. Any species that can react as either an acid or base is called _________________. 30. Name the following acids: a. HCl ________________ b. H2S _______________ c. HI ________________ d. HBr _______________ 31. A solution is neutral if its [H3O+] = __________________ 32. The pH scale range is ___________________________ 33. 34. In the space provided, identify each of the following substances as acidic, basic, or neutral. a. __________________ grapefruit b. __________________ pure water c. __________________ blood d. __________________ soap e. __________________ milk Calcium and magnesium hydroxides are strong bases, but they are used as antacids. Why won’t they harm human tissue? Chemistry- Unit 13 DRAFT 19 35. Write a balance equation for the neutralization reaction between KOH and H2SO4. 36. 37. What effect does an acid have on litmus? Base on litmus? How are binary acids named? 38. What acid is used in car batteries? 39. What acid is produced in the stomach? 40. What acid is found in vinegar? 41. Strong acids and strong bases are ______________ electrolytes. 42. Hydroxides from which metallic group all form strong bases? _________________ 43. How do industrial processes cause acid rain? ELABORATE: Molarity of Acid and Bases PowerPoint (30 minutes) Students need to understand the concept of concentration in solutions (molarity) and the strength of acids and bases. The PowerPoint can be used to introduce these concepts. Guided practice is also provided. Essential Question: How would you describe the difference between molarity and concentration in acids and bases? Slide 1 Molarity of acids and bases Chemistry- Unit 13 DRAFT 20 Slide 2 Molarity (M): number of moles of solute dissolved per liter of solution M= moles solute liters of solution **** higher concentration: higher molarity number *** most common concentration unit in high school chemistry Slide 3 Sample: Calculate the molarity if 1.35 mol H2SO4 is dissolved in 245mL of solution. (5.51M) Practice: What is the molarity if 92.4g of HCl is dissolved in 2.0L of solution. Practice: How many moles of solute are contained in 125mL of 0.0500M Ba(OH)2? (0.00625mol) Dilutions (preparing molar solutions) Slide 4 M1V1=M2V2 (M1V1: molarity and volume of stock solution) (M2V2: molarity of the dilute solution) Sample: How many milliliters of a 5.0M H2SO4 stock solution would you need to prepare 100.0mL of 0.25M H2SO4? (5.0mL) Slide 5 Practice: If you dilute 20.0mL of a 3.5M solution to make 100.0mL of solution, what is the molarity of the dilute solution? (0.70M) How many milliliters of 2.55M NaOH is needed to make 125mL of 0.75M solution? (37mL) Chemistry- Unit 13 DRAFT 21 Don’t confuse molarity and strength of acid or base!!! Slide 6 Molarity: concentration Strength: degree of dissociation Ex: strong acid with low concentration: 0.5M HCl weak acid with high concentration: 12.0M HC2H3O2 EVALUATE: (45 minutes) Molarity and Dilution Practice This activity will allow students to elaborate on their understanding of molarity and dilutions equations with guided and independent practice. After students have completed these questions, the teacher will evaluate students’ understanding by going over the questions with the students. The teacher should make sure that students understand where to find the equation in the reference tables. Essential Question: How would you describe concentration of solutions in chemistry? PRACTICE PROBLEMS: MOLARITY AND DILUTIONS (Show your work for all problems. Do not forget units and sig figs!!!!) Formulas: Molarity (M) = Moles of solute Liters of solution M1V1=M2V2 1. Molarity is one of many ways to express ______________ of a solution. ( volume/mass/concentration/color) 2. A 100.5mL intravenous (IV) solution contains 5.10g of glucose (C6H12H6). What is the molarity of this solution? Chemistry- Unit 13 DRAFT 22 3. What is the molarity of an aqueous solution containing 40.0g of glucose in 1.5L of solution? 4. What is the molarity of a bleach solution containing 9.6g of NaOCl per liter of bleach? 5. Calculate the molarity of 1.60L of a solution containing 1.55g of dissolved KBr. 6. What volume of a 3.00M HCl stock solution would you use to make 0.300L of a 1.25M HCl solution? 7. How many milliliters of a 6.0M H2SO4 stock solution would you need to prepare 100.0mL of 0.25M H2SO4? 8. If you dilute 20.0mL of a 3.5M solution to make 100.0mL of solution, what is the molarity of the dilute solution? 9. How many milliliters of 2.55M KOH is needed to make 125mL 1.25M KOH? 10. How many milliliters of 0.400M HBr solution can be made from 50.0mL of 8.00M HBr? ELABORATE: (45 minutes) Neutralization Reactions PowerPoint The teacher should use the PowerPoint to reintroduce equation writing relating it to neutralization reactions. The teacher will lead into titration and model the calculations. Guided practice is provided Essential Question: What are neutralization reactions? Chemistry- Unit 13 DRAFT 23 Slide 1 Slide 2 Acid + base salt + water Salt is made of cation from base and anion of acid Mg(OH)2 + 2HCl MgCl2 + H2O Slide 3 Analytical method in which a standard (known concentration) solution is used to determine concentration of another **use an acid-base indicator… *** can determine where neutralization occurs Slide 4 Titration: Chemistry- Unit 13 DRAFT 24 Slide 5 1. Buret is filled with standard solution and other buret is filled with unknown concentration solution. 2. Record initial volume of both burets (make sure solution is to tip!) 3. Run some of the known solution into a flask with indicator 4. Run unknown concentration sol’n until there is a SLIGHT color change ***Remember the formula for MOLARITY! Slide 6 1. 15.0cm3 of 0.5M NaOH and 25.0cm3 of vinegar of unknown concentration are titrated. What is the molarity of the vinegar solution? NaOH + HC2H3O2 NaC2H3O2 + H2O Is it balanced?????? 15.0cm3 x 1L/1000cm3 x 0.5mol/1L = 0.00750 mol vinegar Since all of the coefficients are 1, then moles NaOH = moles vinegar So….. 0.00750 mol NaOH = 0.00750 mol HC 2H3O2 0.00750 mol HC2H3O2 = 0.300M 0.025L Slide 7 Now you try this one: A 25mL solution of H2SO4 is completely neutralized by 18mL of 1.0M NaOH using phenolphthalein as the indicator. What is the concentration of sulfuric acid? (hint: write the balanced equation first and check out ratio of H+ an OH-) Slide 8 H2SO4 + 2NaOH Na2SO4 + 2H2O 0.018L NaOH x 1mol NaOH x 1mol H2SO4 =..0090mol H2SO4 1L 2mol NaOH 0.0090 mol H2SO4 = 0.36M H2SO4 0.025L Chemistry- Unit 13 DRAFT 25 Slide 9 Titration curve of a strong base titrating a strong acid EXPLORE: (60 minutes) Virtual Titration Lab This activity can be done as a whole class or students may complete individually in a computer lab. To access this activity, go to www.sasinschool.com. Log in, select Chemistry, then Solutions, then Acid-Base Chemistry. Essential Question: How can the concentration of a solution be determined through titration? Language (ELP) Objectives for LEP Students: In paragraph form, answer the above essential question and summarize observations from the Virtual Titration Lab. Share verbally observations from Virtual Titration Lab. EVALUATE: Sample Assessment Questions for Unit 13 Unit 13 Goal/ RBT Tag 5.04 C4 C4 Chemistry- Unit 13 Questions 1. What is the difference between solutions of a weak acid and a strong acid? a. the strong acid is more concentrated b. the weak acid does not turn litmus red c. the weak acid does not conduct electricity d. the strong acid has more hydronium ions per liter 2. An acid base titration involves a a. synthesis reaction b. neutralization reaction DRAFT 26 c. single replacement reaction d. decomposition reaction l 3.02 C4 1. What is the molarity of a solution that contains 125 g of NaCl in 4.00 L of solution? a. 0.535 M b. 2.14 M c. 8.56 M d. 31.3 M 2. How many milliliters of 18 M H2SO4 will be needed to make 500 mL of 1.5 M H2SO4? a. 20.8 mL b. 41.7 mL c. 54.0 mL d. 63.6 mL EVALUATE: (45 minutes) Below are sample test items obtained from the WIZARD test bank developed by eduware™ that can be used to allow students to assess their understanding and abilities and allow the teacher to evaluate the students understanding of key concepts and skill development for this unit. Chemistry- Unit 13 DRAFT 27 Chemistry- Unit 13 DRAFT 28 Chemistry- Unit 13 DRAFT 29 Chemistry- Unit 13 DRAFT 30