What is a mineral? A homogenous, naturally occurring, solid inorganic substance with a definable chemical composition and an internal structure characterized by an orderly arrangement of atoms, ions, or molecules in a lattice. Mineral class : Groups of minerals distinguished from each other on the basis of chemical composition. crystal lattice: The orderly framework within which the atoms or ions of a mineral are fixed. Glass has no atomic order, so it is not a mineral. While the lower figure displays what an ordered atomic arrangement might look like. Crystals : A single, continuous piece of a mineral bounded by flat surfaces that formed naturally as the mineral grew. Crystal faces: flat surfaces that grew flat as the crystal grew. Stenos law: The angle between crystal faces of a given mineral will always be constant (see above figure). crystal form: the geometric shape of a crystal, defined by the arrangement of crystal faces. crystal habit : the general shape of a crystal or cluster of crystals that grew unimpeded. cube octahedron bipyramidal rhombohedron pyramid A crystal structure is defined by the arrangement of the packing of atoms. This is dependent upon the chemical composition of a mineral. For example, the figure above is for halite (NaCl), which has a cubic crystal structure. Polymorphs : Two minerals that have the same chemical composition but a different crystal lattice structure. A good example of polymorphs are diamonds and graphite, which are both made out of carbon (C). diamonds are hard because of the order of its crystal structure. graphite is very soft (it is what we write with in pencils) also because of its crystal structure. It too, just like diamonds, is made of carbon (C). Mineral growth: Minerals can form in one of five ways: • Solidification of a melt (freezing of a liquid like ice from water) • precipitation from a solution (ions, atoms or molecules dissolved in water come out of solution like salt or sugar out of water [rock candy]) • solid-state diffusion (movement of atoms through a solid to rearrange them into a new mineral) • biomineralization (biological organisms can “make” minerals such as shells that are made out of the mineral calcite. The shell is the mineral, not the organism, so it is inorganic) • fumerolic mineralization (mineral crystallize from a vapor, like the sulfur minerals that form around vents in Yellowstone national park.) M inerals grow outward from a central seed to fill the available space; their shape is controlled by the shape of their surroundings. After the animation is complete, click and drag each crystal to reveal its individual shape. 8PC version Minerals can be anhedral (no well developed crystal faces), sudhedral (poorly developed crystal faces, or euhedral (well developed crystal faces. euhedral crystal of olivine sudhedral crystal of olivine anhedral crystal of olivine This animation shows the progressive growth and interlocking of mineral crystals as they cool from a melt. It illustrates how some minerals interfere with the growth of other crystals. 8PC version Minerals have different physical properties that lead to their identification. 1) The color of a mineral can sometimes help in mineral identification, but commonly the same mineral can be many different colors. 2) The streak of a mineral (the color of the mineral in powered form) can be a very good tool in the process of mineral identification. 3) The luster of a mineral (the way a mineral surface scatters light) can be useful. 4) The hardness of a mineral (measure of a minerals bonds to resist breaking, the stronger the bonds in a crystal structure the harder the mineral) is very useful in mineral identification and lead to the development of Mohs hardness scale. 5) Specific gravity (a number representing the density of a mineral, as specified by the ratio between the weight of a volume of the mineral and the weight of an equal volume of water) is very helpful in mineral identification. 6) Crystal habit (the shape of a minerals crystal faces or lack there of) 7) Fracture (when a mineral breaks in an irregular pattern) and cleavage (the tendency of a mineral to break along preferred planes along atomic bonds) is very helpful in identifying a mineral. 8) Other properties of minerals such as reactions with acids or magnetism are good identification caricaturists. Quartz can be many different colors. Color is the poorest tool used in identifying minerals Streak This sample of pyrite has metallic luster These feldspar samples have a non-metallic luster. Mohs hardness scale. This kyanite sample shows a bladed crystal habit. The quartz crystal to the left is displaying a prismatic habit, while the sample to the right has a need-like habit. Mica has a good cleavage in one direction that helps in identifying it from other minerals. Halite (to the left) and calcite (to the right) also has distinctive cleavage that helps in the identification of these minerals. Cleavage of a mineral can be differentiated from mineral faces by cleavage planes being repeated while mineral faces tend to be a single surface. Magnetite is a naturally occurring magnetic mineral. Minerals are broken up into groups called mineral classes (groups of minerals distinguished from each other on the basis of chemical composition). The mineral classes are: Oxides: Metal cations bonded to oxygen anions (magnetite Fe3O4 is an example) Sulfides: Metal cation bonded to a sulfide anion (am example is pyrite AKA fools gold FeS2) Sulfates: Metal cation bonded to a SO4 anionic group (gypsum is an example CaSO2*2H2O) Halides: A cation bonded to a halogen ion like Cl or F (halite AKA salt is an example NaCl) Carbonates: a cation bonded to a CO3 anionic group (calcite CaCO3 is an example) Native elements : pure masses of a single element such as gold (Au). Silicates: a cation bonded to the SiO4 anionic group (Quartz SiO2 is an example) cation: an atom or complex of atoms with an overall positive charge due to the loss of an electron anion : an atom or complex of atoms with an overall negative charge due to the gain of an electron Magnetite oxide pyrite sulfide Gypsum sulfate Halite halide Calcite carbonate Gold native element Quartz silicate This is the silicon-oxygen tetrahedron which is the building block of all silicate minerals. The silicon-oxygen tetrahedron can be arranged in may different ways to form different silicate minerals. Above are (A) independent tetrahedra (olivine is an example) (B) single chains of tetrahedron (pyroxene is an example) (C) double chain tetrahedra (amphibole is an example) (D) sheets of tetrahedra (mica is an example). (E) displays how silicon-oxygen tetrahedrons can be linked in 3D by oxygen sharing. independent tetrahedra (olivine is an example) single chains of tetrahedron (pyroxene is an example) double chain tetrahedra (amphibole is an example sheets of tetrahedra (mica is an example)