Color from Colorants Dr. Brij Mohal Managing Director and VP October 10, 2014 PNWSCT Where Art Meets Technology 1 Agenda o Pigments o o o o Paint Base Structures o o o Colorant Optimization Paint Performance Color Control o o o Colorants Pigment Durability Color Space Tint Strength Color Difference Dispensing Equipment o General Do’s and Don’ts 2 Pigments 3 Colorants 4 Converting pigments into color solutions Where Art Meets Technology 5 What is POS (Point of Sale) Where Art Meets Technology Spectrophotometer Colorants AXX B C D E F I KX L R T V Dispensers Fandeck P D M A Paint Bases What are Colorants? Chromaflo TechnologiesTM Highlights Where Art Meets Technology o Carefully controlled pigment dispersions o Color strength and color shade o Formulated to ensure o Optimal pigment strength development o Good performance (compatibility) in paints bases o Accurate reproducibility in dispensing equipment o Stability of colorants – shelf life o Pigment combinations selected for balanced cost performance and color space coverage What are Colorants? Where Art Meets Technology Chromaflo TechnologiesTM Highlights Pigment Surfactant Humectants Water Resins Biocides Additives Etc. Adjustments Liter Gallon Toning Pail Packaging / Labeling Milling Premix Page | 8 Dispersibility of Pigments o Wetting o o o o De-agglomeration o o Low energy requirement Dispersion o o Pigment Surface Chemistry Surfactants Solvents High energy requirement Stabilization o o Surfactants Ionic forces 9 Dispersibility of Pigments Wetting De-agglomeration Dispersion 10 Dispersibility of Pigments Physical Properties BET Surface area m2/g Oil Absorption ml/100 g Particle size, nm PR 101 25 900 WH 6 14 360 PR 170 25 69 215 PR122 77 65 90 PV 19 90 82 65 PY 83 27 87 40 PY 151 23 48 215 PO 36 14 64 395 11 Dispersibility of Pigments Physical Properties BET Surface area m2/g Oil Absorption ml/100 g Particle size, nm PB 15:1 72 52 55 PB 15:2 57 64 60 PB 15:3 44 61 75 PB 7 40 50 50 PG 36 61 46 35 12 Dispersibility of Pigments Surface Chemical Properties PB 15 PG 7 13 Pigment Durability 14 Standard Architectural Color System Where Art Meets Technology System Colorants AXX Organic Yellow B Black C Yellow Oxide D Phthalo Green E Phthalo Blue F Red Oxide I Brown Oxide KX White L Raw Umber R Organic Red T Medium Yellow V Magenta 15 Solar Radiation 16 Exposure to the Elements o Ultraviolet 295-400 nm 6.8% o Visible 400-700 nm 55.4% o Infra-red 700-2450 nm 37.8% o Data based on CIE Publication 85, Table 4 17 Exposure to the Elements Static Testing Picture from Atlas Material Testing Solutions 18 Accelerated Testing Q-Panel QUV XENON ARC DEVICES Pictures from Atlas Material Testing Solutions 19 Exposure to the Elements 3.000 Miami "Average" 45° S Daylight Irradiance (W/m2/nm) 2.500 2.000 1.500 1.000 0.500 0.000 250 290 330 370 410 450 490 530 570 Wavelength (nm) 610 650 690 730 770 Data from Atlas Material Testing Solutions 20 Exposure to the Elements - QUV 2.500 Irradiance (W/m2/nm) 2.000 1.500 Miami Peak Sun 26 S UVB-313 1.000 0.500 UVA-340 0.000 250 280 310 340 370 400 430 460 490 520 550 580 610 640 670 700 730 760 790 Wavelength (nm) Data from Atlas Material Testing Solutions Exposure to the Elements – Xenon Arc 3.50 Type S Borosilicate/Type S Borosilicate Irradiance (W/m2/nm) 3.00 Sunlight (norm @ 560) 2.50 2.00 1.50 1.00 0.50 0.00 250 300 350 400 450 500 550 600 650 700 750 800 Wavelength [nm] Data from Atlas Material Testing Solutions Accelerated Testing Desirable Characteristics: o o o o o Exact match to outdoor conditions Does not alter degradation mechanisms; i.e. “correlates” with outdoor exposures Repeatable and reproducible Independent control over stress factors Provides “acceleration” over real time 23 Fade Data for D, E, V Colorants 100.0 90.0 % Strength 80.0 70.0 V D E 60.0 50.0 40.0 30.0 20.0 10.0 0.0 0 500 1000 1500 2000 2500 Hours 24 Fade Data for AXX Colorants y = -25.555Ln(x) + 231.62 R2 = 0.993 AXX - Organic Yellow 100 90 % Strength 80 70 60 50 40 30 20 10 0 0 500 1000 1500 2000 2500 Hours 25 Xenon-Arc for Yellow colorant 26 Fade Data for R Colorant y = -11.659Ln(x) + 162.64 R2 = 0.9986 R - Organic Red 100.0 90.0 % Strength 80.0 70.0 60.0 50.0 40.0 30.0 20.0 10.0 0.0 0 500 1000 1500 2000 2500 Hours 27 Fade Data for R Colorant 28 Fade Data for AXX and AN Colorants Y(AXX) = -25.555Ln(x) + 231.62 Y(AN) = -13.191Ln(x) + 167.95 2 R = 0.993 R2 = 0.9674 100 90 % Strength 80 70 60 AXX 50 AN 40 30 20 10 0 0 500 1000 1500 2000 2500 Hours 29 Fade Data for R and RN Colorants Y(R) = -11.659Ln(x) + 162.64 Y(RN) = -8.3062Ln(x) + 139.86 2 2 R = 0.9986 R = 0.9943 100.0 90.0 80.0 % Strength 70.0 60.0 R 50.0 RN 40.0 30.0 20.0 10.0 0.0 0 500 1000 1500 2000 2500 Hours 30 Fade Data for AXX and AN in Florida Y(AXX) = -20.457Ln(x) + 108.79 Y(AN) = -12.16Ln(x) + 110.43 2 R = 0.9876 R2 = 0.8743 100 90 % Strength 80 70 60 AXX 50 AN 40 30 20 10 0 0 2 4 6 8 10 12 14 Months in Florida 31 Chemical Attack R112 on cement 32 Pigments in Industrial Systems - PV 19 33 Pigments in Industrial Systems PR 170 34 Pigments in Industrial Systems PR 122 35 Colortrend® 808 High Performance Colorants Where Art Meets Technology …beyond the standard 12 colorants • What makes them High Performance ? • Purpose of the various colorants • Matrix of properties 36 Colortrend® 808 High Performance Colorants Where Art Meets Technology What makes them High Performance ? • Lightfastness • Expanded Color Space • High Strength • Opacity - More opaque pigment - More pigment in the colorant 37 Fade Data for reds and yellows Where Art Meets Technology Colortrend® 808HP- REE Opacity of REE This photo shows the same paint containing the same amounts of the R and REE drawndown at the same film thickness on a black and white drawdown card. The REE is on the right and the black and white border can barely be seen. With the paint on the right containing R the substrate can clearly be seen showing through Colortrend® 808HP- REE Opacity DPP and BV The same paint containing the same amount of colorant at the same film thickness on a black and white drawdown card. The black and white border can barely be seen versus the control. PY74 PY184 PR188 PR254 Colortrend® 808HP- QME Hiding power of QME This photo shows the difference in strength of QME vs. V. The same amounts of V, on the left, and QME, on the right, were added to the white base. Conclusions o o o o Need both organic and inorganic pigments for a POS tinting system A number of inorganic and organic pigments do not fade upon exterior exposure Alternate reds and yellows may be utilized for higher performance Chemical attack on pigments needs to be considered 42 Color Space 43 Standard Architectural Color System Where Art Meets Technology System Colorants AXX Organic Yellow B Black C Yellow Oxide D Phthalo Green E Phthalo Blue F Red Oxide I Brown Oxide KX White L Raw Umber R Organic Red T Medium Yellow V Magenta 44 Colorants in Color Space Where Art Meets Technology +b* CIE L*a*b* Color Space 50 - a* +a* -50 50 -50 - b* Color Space Comparison Where Art Meets Technology Color Space Comparison Where Art Meets Technology Architectural Colorants Color Space Comparison Where Art Meets Technology Architectural Colorants Color Space Comparison Where Art Meets Technology Architectural Colorants Color Space Comparison Where Art Meets Technology Architectural Coatings – A Colorful Extension Where Art Meets Technology A color system that uses the traditional 12 colorants are represented by the green spheres. A color collection emphasizing the clean, bright and deep colors of the high performance and high strength colorants now available are represented by the blue spheres. Paint Base Structures 52 Why do color systems exist ? Where Art Meets Technology Consumers / End-users want: More color options Sheen choice Coatings producers want: Increased sales Higher customer satisfaction Why do color systems exist ? Where Art Meets Technology • FACT: Offering more color choice with ready-mixed paints while increasing profits is VERY difficult. Color systems are the answer Color System Rationale Where Art Meets Technology Ready-Mixed 40 color offerings (e.g.) 10 cans of each color for 4 paint lines = 1600 SKUs ........ ........ ........ ........ ........ ........ ........ ........ ........ Limited color choice High inventory ($$ tied up) Color System Has 4 bases + colorants Yields 800 to 2760 + colors (millions possible) 10 cans of each base in 4 paint lines = 160 SKUs P D M A Wide color choice Low inventory Why 4 Bases Where Art Meets Technology • Need different levels of TiO2 and can fill levels in 4 different bases to achieve wide color offering (from accents to pastels) Colorant Colorant Pastel Base Midtone Base Short Fill 128 oz Short Fill 124 oz ~1.5#/gal TiO2 ~2#/gal TiO2 Colorant Deep Base ~.7#/gal TiO2 Short Fill 120 oz Colorant Accent Base 0#/gal TiO2 Short Fill 116 oz Tint bases for Color Systems o o o o o o o Selection criteria SKU’s Hiding (Quality) Cost Economical use of TiO2 Economical use of colorant Total formula sold (close to full gallon) 57 Tint bases for Color Systems ADVANTAGES Colored Bases Improved Hiding Large Number of Colors Impressive Display Current Trend DISADVANTAGES Extra SKU’s. Used infrequently Expensive paint Expensive sales aids Large display requires more floor space Letdown Series in Color Better appearance and Sometimes limits Families flow of colors optimum colorant combination for cost, Interpolation possible lightfastness 58 Tint bases for Color Systems ADVANTAGES DISADVANTAGES All Quart Formulas More complete formula book Lightest possible colors not made Separate Formulas for Each Paint Type More accurate color reproduction Extra color matching required Confusion in store Balanced color palette Smoother appearance Increases number of colors Not limited to current trends Contains colors not sold 59 Tint bases for Color Systems ADVANTAGES Large Number of Colorants Greater flexibility in cost vs. performance Greater color space coverage High TiO2 Level in pastel Good Hiding base High quality system Large Number of White Bases Better opacity Less colorant use DISADVANTAGES More colorants to manufacture More SKU’s for user Larger number of canisters required Too expensive for some markets Extra manufaturing and SKU’s for paint company 60 Number of bases for a Colorant System Tint bases for Color Systems Lbs total pigment vs. colored pigment to total pigment ratio Lbs total pigment 2.5 2.0 1.5 1.0 0.5 0.0 0 20 40 60 80 100 % Colored pigment 62 Typical Colorant Loading TiO2 BASE Ounces (Y) No. of Colors 2.30 lbs Pastel 0.04 - 2.20 468 2.00 lbs Tint 3.00 – 5.6 240 0.70 lbs Deeptone 5.66 – 10.08 120 0.00 lbs Accent 9.00 – 12.66 112 63 Tint bases for Color Systems Lbs total pigment vs. colored pigment to total pigment ratio Lbs total pigment 2.5 2.0 1.5 1.0 0.5 0.0 0 20 40 60 80 100 % Colored pigment 64 Colorant Loading - 3 base system TiO2 BASE Ounces (Y) No. of Colors 2.30 lbs 2.00 lbs Pastel/Tint 0.04 – 5.6 708 0.70 lbs Deeptone 5.66 – 10.08 120 0.00 lbs Accent 9.0 – 12.66 112 65 Tint bases for Color Systems Lbs total pigment vs. colored pigment to total pigment ratio Lbs total pigment 2.5 2.0 1.5 1.0 0.5 0.0 0 20 40 60 80 100 % Colored pigment 66 Colorant Loading - 3 base system Color Frequency Gallons 468 1,000,000 240 500,000 120 200,000 112 50,000 940 Costs/Qt Base P Total T Total D Total A Total Grand Total Average cost $122,047.69 $0.122 $272,623.32 $0.545 $204,152.77 $1.021 $69,318.57 $1.386 $668,142.34 1,750,000 Color Frequency Cost of tinting 1.75 M gallons to 940 different colors $ 0.38 Gallons 468 1,000,000 240 500,000 120 200,000 112 50,000 940 1,750,000 Costs/Qt Base P Total T Total D Total A Total Grand Total Average cost $122,047.69 $0.122 $313,516.82 $0.627 $204,152.77 $1.021 $69,318.57 $1.386 Cost increase of 6% by tinting tint colors from a pastel base $709,035.84 $ 0.41 67 Colorant Loading - 3 base system Color Frequency Gallons 468 1,000,000 240 500,000 120 200,000 112 50,000 940 Costs/Qt Base P Total T Total D Total A Total Grand Total Average cost $122,047.69 $0.122 $272,623.32 $0.545 $204,152.77 $1.021 $69,318.57 $1.386 $668,142.34 1,750,000 Color Frequency $ 0.38 Gallons 468 1,000,000 240 500,000 120 200,000 112 50,000 940 1,750,000 Costs/Qt Base P Total T Total D Total A Total Grand Total Cost of tinting 1.75 M gallons to 940 different colors Average cost $122,047.69 $0.122 $272,623.32 $0.545 $377,119.56 $1.886 $69,318.57 $1.386 Cost increase of 25% by tinting deep colors using an accent base $841,109.14 $ 0.48 68 Colorant Loading - 2 base system Color Frequency Gallons 468 1,000,000 240 500,000 120 200,000 112 50,000 940 Costs/Qt Base P Total T Total D Total A Total Grand Total Average cost $122,047.69 $0.122 $272,623.32 $0.545 $204,152.77 $1.021 $69,318.57 $1.386 $668,142.34 1,750,000 Color Frequency $ 0.38 Gallons 468 1,000,000 240 500,000 120 200,000 112 50,000 940 1,750,000 Costs/Qt Base P Total T Total D Total A Total Grand Total Cost of tinting 1.75 M gallons to 940 different colors Average cost $122,047.69 $0.122 $313,516.82 $0.627 $377,119.56 $1.886 $69,318.57 $1.386 Cost increase of 32% by going to a 2 base system $882,002.64 $ 0.50 69 Selection criteria for number of bases o o o o Hiding (Quality) Economical use of TiO2 Economical use of colorant Colorant cost tends to increase anywhere from 6% - 20% for every reduction of a tinting base 70 Colortrend® and Chroma-Chem® Base recommendations: lbs/gal of TiO2 Where Art Meets Technology System CTA (Slightly toned) PCS CTF Industrial Pastel 2.3 2.0 2.2 2.25 Tint 2.0 1.45 2.0 - Deep 0.7 0.65 0.7 1.25 0 0 0 0 Base Accent 71 Color Control 72 Describing Differences between Colors o o o o o o Visually perceived - verbally relayed Instrumentally measured - numerically expressed Components of comparative description: Difference in color, shade or hue Difference in depth, intensity or strength Described as difference versus a reference, or a standard comparator 73 Color Difference (DE) o o o o o o o Describes if redder or greener, bluer or yellower, etc. Numerical degree assigned Combines red/green, blue/yellow, and light/dark Difference in readings of batch versus readings of standard A DE of 0 is the goal, exact color match A DE of 1-2 is perceptible by the human eye, but considered an acceptable ‘commercial color match’ A DE of 0.5 is considered a very close match 74 Strength o o o o o Describes if a sample is weaker or stronger in color intensity (between similar colors) A percentage reading where 100% is exactly the same strength as the comparator Readings of the batch are compared with readings of the standard 95% is weaker, 105% is stronger +/- 2% versus standard is a very close match 75 Samples of Color Difference 76 Color Difference DE • The Batch is similar in strength, but much redder than the Standard • Large DE • (DE of 6.77) Strength Difference • The Batch is a similar color, but much weaker that the Standard • Large strength difference • ( -10% strength) Colorant Testing o o o o Sample of Colorant Batch is put into control paint and compared against Colorant Standard in the same paint The two samples are drawn down on charts, dried, and measured instrumentally to determine strength and DE Specifications are 98-102% strength, and 0.5 max DE Other less critical properties are also measured on the colorant batch to ensure they are within specification 79 Dispensing Equipment 80 Anatomy of a dispenser o Canisters o Software and external devices o Piping and valves o Pumping group o Dispenser area/nozzle o Control unit and electronics o Shelf o Cabinet/frame 81 Types of Pumps (Corob) 82 Types of Pumps (Hero) Gear Pumps • Adversely affected by abrasivity • Elimination of Ethylene Glycol decreases • • • • lubrication properties and resistance to galvanic corrosion Gear pumps are manufactured using combinations of cast iron, brass, stainless steel and hardened steel. Dissimilar metal will create opportunity for galvanic corrosion Seals and flexible hoses will see faster deterioration which will be evidence by fluid leak Fluid leaks = electrical components failures Switch to LOW/ZERO VOC will result in increased calibration frequency and more frequent pump failure and replacement 83 Types of Pumps (Hero) Nutating Pump • Nutating pump is a reciprocating and oscillating piston • Nutating pump provides pulsating dispense, known to create splashing at faster dispense speeds • High operating speed exists between piston and bore • Requires the usage of a dynamic moving seal to retain fluid. This seal is prone to leakage and is not user serviceable • High levels of sheer and turbulence are imparted on the liquid as the motion requires 180 degree rotation of fluid along with passage through a small orifice • High piston speed increases possibilities for cavitation and loss of accuracy, especially as seal and bore wear occurs • High solids materials can restrict orifices and lead to reductions in flow and accuracy. • Decreased lubrication due to loss of glycol will accelerate wear 84 Types of Pumps (Hero) Bellow pumps • Technology is less scalable , sacrifice speed for accuracy • Retention of air in pleats result in performance drift • Requires backflow valve which is susceptible to clogging especially with heavier high solids colorants • Performance will be problematic whenever air is introduced into circuit(running circuit dry) 85 Pumps Types – Ups and downs (Corob) Optimal price-performance. Best configurable performances. Entry-medium market configurations available. SDP offer high tuning of performance. Need to refresh the convenience of the offer. Overall ownership costs are quite significant. Entry-medium market configurations available. Cost base remains high, impact on final price. Optimal performance- price Known technology with no leading innovative edge. TECH ARGUMENT Everlasting Teflon pump High productivity pump. Excellent with quality controlled colorants. Recent generation CRXs pumps working well over time. DOWNS Disadvantages Advantages Disadvantages Advantages SALES ARGUMENT Less effective with high sedimentation colorants if not with re-circulation. BELLOW Becoming affected by colorants with low VOC levels. Capable of dispensing poor quality colorants. Low cost of spare parts due to limited number of components Usually matched to slower turntable platforms. Check-ups needed over time. GEAR PISTON 86 The Technology: HERO’s Progressive Cavity Pump (“PCP”) Technology Core components: Canister and pump assembly Rotor & Stator Pump assembly Canister and pump assembly HERO’s patented Progressive Cavity Pump (“PCP”), technology developed in Europe for lowand zero-VOC colorants, allows HERO’s line to be ready for the entry of low- and zero-VOC colorants into the North American Market. In other words, there will be no added expense for any of HERO’s automatic dispensers in having to upgrade them to accommodate the new colorants. Colorant Do’s & Don’ts 88 Colorant Storage and Handling o o o o o o o o o o Store in a Manner to Ensure First in, First out Rotate Inventory Store in Ambient Conditions Keep Lids Closed Canisters, Pails, Drums, etc. Possible Problems - Drying, Change in Tint Strength, Seeding/Shocking, Etc. DON’T Reuse Transfer Containers Cross-Contamination, and Also Above DON’T Dilute, Rinse, etc. Colorant DON’T Use Suspect Material 89 Colorant Incorporation Into Canister o Shake Thoroughly (as recommended by the manufacturer) o o o Use Full Liters Do Not Store Partially Used Containers Keep Canisters Topped Off o Scrape Colorants From Can To Ensure Complete Usage o Dispose Of Empty Can In An Environmentally Acceptable Manner 90 Automatic Dispensing Machines o Use Agitation Cycles As Recommended By Manufacturer o Calibrate Regularly As Recommended By Manufacturer o Ensure Any Filters Etc. Are Cleaned Regularly o Keep Lids Closed o Use Nozzle Cover o Clean Nozzles Regularly 91 Manual Dispensing Machines o o o On Machines Without Automatic Stirring: Stir Once In The Morning (5 Minutes) Repeat After 6-8 Hours o o Having Dispensers With Nozzle Covers Is Highly Recommended Use Swab For Cleaning Nozzles o o o Be Sure To Keep Tinting Equipment Clean And Serviced Calibrate As Required Reinforce Training And Proper Use 92 Paint Mixing o o Use Recommended Mixing/Shake Times DO NOT OVERSHAKE o After Shaking, Open Can To Observe Full Incorporation Of Colorant In Paint 93 Colorant Best Practices o DO Use Inorganic Pigments Wherever Possible o o o o DON’T Paint over Fresh Stucco o o Cost Opacity Lightfastness Avoid Highly Alkaline Conditions - Fastness AVOID Using Complimentary Color Colorants o o Expensive Use Black or Umber 94 Colorant Combinations for Optimal Matching Colorant Combination Chart with Ratings B C F I L KX D E V R T AXX B Black 5 5 5 5 5 5 5 5 5 2 3 2 C Yellow Oxide 5 5 5 5 5 5 5 * 2 3 2 F Red Oxide 5 5 5 5 5 5 5 5 2 3 2 I Brown Oxide 5 5 5 5 5 5 5 5 5 2 3 2 L Raw Umber 5 5 5 5 5 5 5 5 5 2 3 2 KX White 5 5 5 5 5 5 5 5 5 2 3 2 D Green 5 5 5 5 5 5 5 3 2 E Blue 5 * 5 5 5 5 5 5 5 2 3 2 V Magenta 5 5 5 5 5 5 5 2 R Organic Red 2 2 2 2 2 2 2 2 2 2 2 T Med. Yellow 3 3 3 3 3 3 3 3 2 3 2 AXX Organic Yellow 2 2 2 2 2 2 2 2 2 2 2 Coloristically all right to mix. The lower number indicates a differential fading condition or a lower exterior durability combination. Avoid these colorant combinations unless absolutely necessary * Do not use these colorant combinations as they are poor coloristic choices and will increase cost of matches. * In addition to being a poor coloristic choice, there are known problems (chemically) with this combination. Ratings 5 - Excellent for all applications, 4 - Good for all applications, 3 - May have a differential fading problem in Southern exposures 2 - Not recommended for Southern exposures, 1 - Not recommended for Southern exposures A lower number may indicate differential fading problems. Alkaline conditions Organic pigments, especially AXX, T, R, and E are susceptible to alkali burn out on fresh or hot cementicious surfaces. The surface must be thoroughly cured and properly primed to obtain satisfactory results. If these precautions and proper preparation are not followed you may have premature failure of either the color or the coating itself. Notes: The deeper the color, the better organic pigments perform. Differential fading is the condition where one of the color components has a much better color retention on exterior exposure than the other component. An example would be a green made with AXX yellow and E Blue. The AXX component would fade quicker than the E component and the color would shift to the blue side. A low amount of AXX would allow the color to shift fairly rapidly. Remember a color is only as good as the least lightfast component. (For this reason: try, especially, to stay away from the AXX/E combination). The information contained herein is based on tests and reports considered reliable, but is presented without guarantee or responsibility as to the applicability or correctness or the suitability of our products whether used singly or in combination with other products. The products referred to above are sold without warranty express or implied. Before using any of our products, read the label and applicable Material Safety Data Sheet. 95 Thank You 96