WATER AND ITS EXTRAORDINARY PROPERTIES WATER JOKE!! If H2O is the formula for water, what is the formula for ice? Take a guess. How much of Earth’s surface do you guys think is covered with water? Water is almost everywhere! It is the most abundant compound in most living things. Chemical Structure of Water Water is made up of two elements: two hydrogens and one oxygen They are joined together by covalent bonds. Property #1: Water is polar Definition of polarity: An uneven distribution of electrons between the oxygen and hydrogen atoms So in water, there is an unequal sharing of electrons between the hydrogen and oxygen molecules. Still don’t get why water is polar? In the molecule, oxygen is greedy and takes more of its fair share of electrons. Because oxygen is an electron hog, it slightly pulls the electrons closer to itself. That is why the hydrogen end of a water molecule is positive and the oxygen end is negative. It has two opposite poles. However, water overall is neutral, meaning it has a zero net (total) charge. The Water Molecule •As a result, the oxygen end of the molecule has a slight negative charge and the hydrogen end has a slight positive charge. Copyright Pearson Prentice Hall Covalent Bonds vs. Hydrogen Bonds Although the hydrogen and oxygen in the water molecule itself is joined together by covalent bonds, the individual water molecules are hydrogen bonded to one another. Covalent bonds are much stronger than hydrogen bonds. That is why it is easier to break apart water molecules from one another than it is to break apart a single molecule into its individual parts. Property #2: Cohesion Definition of cohesion: An attraction between molecules of the same substance. Because of hydrogen bonding, water is extremely cohesive. Cohesion results in a high surface tension for water. This produces something called a surface film. This explains why some insects and spider can walk on a pond’s surface (surface film). Pepper Demo What happened to the pepper when the detergent was added to the water? Why did that happen? (Apply and explain the property of cohesion in your answer) Pepper Demo What happened to the pepper when the detergent was added to the water? The pepper moved away from each other when the detergent was added. Why did that happen? (Apply and explain the property of cohesion in your answer) Pepper Demo What happened to the pepper when the detergent was added to the water? The pepper moved away from each other when the detergent was added. Why did that happen? (Apply and explain the property of cohesion in your answer) The detergent broke the hydrogen bonds between the water molecules, causing the pepper to move away from the detergent when dropped. The water molecules were no longer attracted to each other because the hydrogen bonds were broken. http://www.youtube.com/watch?v=nIR759w Ijdg Property #3: Adhesion Definition of adhesion: a an attraction between molecules of different substances Explains how tops of trees get their water. Water goes through the roots of the trees and than “climbs” its way up to the top. We call this capillarity…. http://www.youtube.com/watch?v=mc9gUm1mMzc String Demo What did you see happening to he water when poured down the string? Why did that happen? (Apply and explain the property of adhesion in your answer) String Demo What did you see happening to he water when poured down the string? The water did not spill and ran down the string. Why did that happen? (Apply and explain the property of adhesion in your answer) String Demo What did you see happening to he water when poured down the string? The water did not spill and ran down the string. Why did that happen? (Apply and explain the property of adhesion in your answer) The water molecules were attracted to the molecules in the string, allowing for it to climb down the string. Cork Demo What happened to the cork when the cup was half full? Where did the cork reside? What happened to the cork when the cup was overfilled? Where did the cork reside? Which property of water explains which part of the demo? Cork Demo What happened to the cork when the cup was half full? Where did the cork reside? The cork resided near the sides of the inside of the cup. What happened to the cork when the cup was overfilled? Where did the cork reside? Which property of water explains which part of the demo? Cork Demo What happened to the cork when the cup was half full? Where did the cork reside? The cork resided near the sides of the inside of the cup. What happened to the cork when the cup was overfilled? Where did the cork reside? The cork resided in the middle of the cup. Which property of water explains which part of the demo? Cork Demo What happened to the cork when the cup was half full? Where did the cork reside? The cork resided near the sides of the inside of the cup. Adhesion What happened to the cork when the cup was overfilled? Where did the cork reside? The cork resided in the middle of the cup. Cohesion Which property of water explains which part of the demo? Property #4: Water is less dense as a solid Unlike most substance, water expands as it freezes. Thus, ice is less dense than liquid water, which explains why ice floats on the surface of lakes and rivers. Nemo, I have a question. If water was denser as a solid, what would happen to our marine life? Well Dory… we would die. If ice were to sink to the bottom of the ocean, we would not be able to survive the cold of the winter. It would be disastrous. Oh. Cool! But, Nemo, I have a question. If water was denser as a solid, what would happen to our marine life? Example: Putting can of coke in the freezer. What happens? Example: Putting can of coke in the freezer. What happens? It explodes Why? Example: Putting can of coke in the freezer. What happens? It explodes Why? Because the water in it expands. Example: Putting can of coke in the freezer. What happens? It explodes Why? Because the water in it expands. Property #5: Water is the only molecule that exists as all 3 states of matter naturally. Evaporation: Condensation Freezing Sublimation Precipitation What are those? Property #5: Water is the only molecule that exists as all 3 states of matter naturally. Evaporation: going from a liquid to a vapor Condensation: Freezing Sublimation Precipitation What are those? Property #5: Water is the only molecule that exists as all 3 states of matter naturally. Evaporation: going from a liquid to a gas Condensation: going from a gas to a liquid Freezing: Sublimation Precipitation What are those? Property #5: Water is the only molecule that exists as all 3 states of matter naturally. Evaporation: going from a liquid to a gas Condensation: going from a gas to a liquid Freezing: going from a liquid to a solid Sublimation: Precipitation What are those? Property #5: Water is the only molecule that exists as all 3 states of matter naturally. Evaporation: going from a liquid to a gas Condensation: going from a gas to a liquid Freezing: going from a liquid to a solid Sublimation: going from a solid to a gas Precipitation: What are those? Property #5: Water is the only molecule that exists as all 3 states of matter naturally. Evaporation: going from a liquid to a gas Condensation: going from a gas to a liquid Freezing: going from a liquid to a solid Sublimation: going from a solid to a gas Precipitation: When water falls from the sky Awesome! Why is this important for us? Because of this property, water can actually recycle itself which is important, because we pollute our water. If it didn’t do that naturally on its own, we would have polluted water. Property #5: Water is a powerful but NOT a universal solvent Definition of a solute: The substance that is dissolved Definition of a solvent: the substance in which the solute dissolves Example Water dissolves ionic compounds such as NaCl (Table Salt) This means that the solute NaCl is soluble in water. Example Water dissolves polar covalent compounds such as fructose (table sugar) This means that fructose is also soluble in water. Why did these substances dissolve in water? Because they are similar to water in that they are ionic (the NaCl) and polar (the fructose). As a general rule, “like dissolves like” Why don’t nonpolar solutes dissolve in polar solvents? Polar molecules are attracted to each other and form bonds with one another. Because nonpolar molecules are not attracted to polar molecules, they are excluded by the polar molecules and pushed away. Polar substances are the cool kids leaving out the nonpolar losers. Review Video http://www.youtube.com/watch?v=DAilC0sj vy0 Last water joke!! What kind of bears dissolve in water? POLAR bears!! THAT’S ALL! THANKS