name: _______________ date: _______ periodic trends - atomic radius and ionic radius atomic radius versus atomic number The radius of atoms is both measurable and predictable. It depends on both the number of occupied energy levels and the strength of attraction that the nucleus has for its electrons. Since electrons have a negative charge, they repel each other, but since protons have a positive charge, there is an attraction of the electrons toward the nucleus. Using this information, predict what will happen to the size (radius) of atoms as you: • move across a period from left to right? _____________________________ • move down a group? _____________________________ Using the data in the chart, make a line graph of the atomic radius vs. the atomic number. Then follow the directions below for annotating the graph. The unit for atomic radius is nanometers, or 1 x 10-9 meters. A. N. radius A. N. radius A. N. radius A. N. radius A. N. radius A. N. radius 1 0.030 10 0.093 19 0.152 28 0.111 37 0.088 46 0.077 2 0.070 11 0.066 20 0.064 29 0.112 38 0.186 47 0.160 3 0.143 12 0.117 21 0.110 30 0.104 39 0.099 48 154 4 0.231 13 0.197 22 0.160 31 0.146 40 0.131 49 0.125 5 0.129 14 0.126 23 0.125 32 0.124 41 0.128 50 0.133 6 0.122 15 0.122 24 0.121 33 0.117 42 0.114 51 0.169 7 0.244 16 0.215 25 0.180 34 0.157 43 0.143 52 0.136 8 0.137 17 0.133 26 0.134 35 0.138 44 0.144 53 0.149 9 0.162 18 0.140 27 0.141 36 0.137 45 0.133 54 0.190 ionization energy versus atomic number Ions are formed form by the loss or gain of electrons. Ionization energy is the energy required to remove the most loosely held valence electron from the atom to make the atom a +1 ion. The following table has the ionization energies of the first 54 elements. Using the data in the chart, make a line graph of the ionization energy vs. the atomic number. Ionization energy is measured in kilojoules, or kJ. A. N. IE A. N. IE A. N. IE A. N. IE A. N. IE A. N. IE 1 13.5 10 24.5 19 5.4 28 9.3 37 8.3 46 11.2 2 14.5 11 13.6 20 17.3 29 21.5 38 5.1 47 7.6 3 6.0 12 8.1 21 11.0 30 10.4 39 13.0 48 15.8 4 4.4 13 6.1 22 6.6 31 6.8 40 6.7 49 6.8 5 7.4 14 7.9 23 7.9 32 7.6 41 7.7 50 9.4 6 6.0 15 8.1 24 10.5 33 9.7 42 11.8 51 14.0 7 4.2 16 5.7 25 6.6 34 7.0 43 6.8 52 7.2 8 7.3 17 7.5 26 7.7 35 8.3 44 7.6 53 9.0 9 5.8 18 7.3 27 8.6 36 9.0 45 10.4 54 12.1 graph annotation: On the atomic radius versus atomic number graph, do the following: a. Label the points on the graph that represent an element with a valence configuration of ns1 (1 valence e-). b.Label the points on the graph that represent an element with a valence configuration of ns2np6 (8 valence e-) c. Circle the points on the graph that represent the 3d sublevel and the 4d sublevel. d. Draw a vertical line through the points on the graph that represent a filled valence shell. questions: 1. How many sections was the atomic radius graph divided into? _____ 2. On the periodic table, the first 54 elements are found in 5 horizontal rows known as __________. 3. Each section of the graph represents a __________ or horizontal row on the periodic table. 4. What is the trend in atomic radius within each section of the graph (how does atomic radius change with atomic number)? 5. As you move across a period on the periodic table, what happens to the atomic radius of the elements? 6. Are electrons being added to higher energy levels as you move from left to right across a period? Or, are they being added to the same energy level? What is responsible for the decrease in atomic radius across a period? 7. List the atomic numbers of the largest atom in each section of the graph. In what group on the periodic table are each of these elements located? 8. List the atomic numbers of the smallest atom in each section of the graph. In what group on the periodic table are each of these elements located? On the ionization energy versus atomic number graph, do the following: a. Label the points on the graph that represent an element with a valence configuration of ns1 (1 valence e-). b.Label the points on the graph that represent an element with a valence configuration of ns2np6 (8 valence e-) c. Circle the points on the graph that represent the 3d sublevel and the 4d sublevel. d. Draw a vertical line through the points on the graph that represent a filled valence shell. questions: 1. Define ionization energy. 2. Each section of the graph represents a __________ or horizontal row on the periodic table. 3. State the general trend in ionization energy moving across a period. 4. List the atomic number of the elements that have the lowest ionization energy in each section of the graph. 5. To what group of the periodic table do these elements belong? 6. List the atomic number of the elements that have the highest ionization energy in each section of the graph. 7. To what group of the periodic table do these elements belong? name: suggested answers date: _______ periodic trends - atomic radius and ionic radius atomic radius versus atomic number The radius of atoms is both measurable and predictable. It depends on both the number of occupied energy levels and the strength of attraction that the nucleus has for its electrons. Since electrons have a negative charge, they repel each other, but since protons have a positive charge, there is an attraction of the electrons toward the nucleus. Using this information, predict what will happen to the size (radius) of atoms as you: • move across a period from left to right? atomic radius decreases • move down a group? atomic radius increases Using the data in the chart, make a line graph of the atomic radius vs. the atomic number. Then follow the directions below for annotating the graph. The unit for atomic radius is nanometers, or 1 x 10-9 meters. A. N. radius A. N. radius A. N. radius A. N. radius A. N. radius A. N. radius 1 0.030 2 0.093 3 0.152 4 0.111 5 0.088 6 0.077 7 0.070 8 0.066 9 0.064 10 0.062 11 0.186 12 0.160 13 0.143 14 0.117 15 0.110 16 0.104 17 0.099 18 0.095 19 0.231 20 0.197 21 0.160 22 0.146 23 0.131 24 0.125 25 0.129 26 0.126 27 0.125 28 0.124 29 0.128 30 0.133 31 0.122 32 0.122 33 0.121 34 0.117 35 0.114 36 0.112 37 0.244 38 0.215 39 0.180 40 0.157 41 0.143 42 0.136 43 0.137 44 0.133 45 0.134 46 0.138 47 0.144 48 0.149 49 0.162 50 0.140 51 0.141 52 0.137 53 0.133 54 0.130 ionization energy versus atomic number Ions are formed form by the loss or gain of electrons. Ionization energy is the energy required to remove the most loosely held valence electron from the atom to make the atom a +1 ion. The following table has the ionization energies of the first 54 elements. Using the data in the chart, make a line graph of the ionization energy vs. the atomic number. Ionization energy is measured in kilojoules, or kJ. A. N. IE A. N. IE A. N. IE A. N. IE A. N. IE A. N. IE 1 13.5 2 24.5 3 5.4 4 9.3 5 8.3 6 11.2 7 14.5 8 13.6 9 17.3 10 21.5 11 5.1 12 7.6 13 6.0 14 8.1 15 11.0 16 10.4 17 13.0 18 15.8 19 4.4 20 6.1 21 6.6 22 6.8 23 6.7 24 6.8 25 7.4 26 7.9 27 7.9 28 7.6 29 7.7 30 9.4 31 6.0 32 8.1 33 10.5 34 9.7 35 11.8 36 14.0 37 4.2 38 5.7 39 6.6 40 7.0 41 6.8 42 7.2 43 7.3 44 7.5 45 7.7 46 8.3 47 7.6 48 9.0 49 5.8 50 7.3 51 8.6 52 9.0 53 10.4 54 12.1 graph annotation: On the atomic radius versus atomic number graph, do the following: a. Label the points on the graph that represent an element with a valence configuration of ns1 (1 valence e-). b.Label the points on the graph that represent an element with a valence configuration of ns2np6 (8 valence e-) c. Circle the points on the graph that represent the 3d sublevel and the 4d sublevel. 1st period d. Draw a vertical line through the points on the graph that represent a filled valence shell. 2nd period 3rd period 5th period 4th period Rb K Na 4d sublevel Li 3d sublevel Xe Kr Ar Ne questions: 1. How many sections was the atomic radius graph divided into? 5 sections 2. On the periodic table, the first 54 elements are found in 5 horizontal rows known as periods. 3. Each section of the graph represents a period or horizontal row on the periodic table. 4. What is the trend in atomic radius within each section of the graph (how does atomic radius change with atomic number)? atomic radius decreases 5. As you move across a period on the periodic table, what happens to the atomic radius of the elements? atomic radius decreases across a period, form left to right 6. Are electrons being added to higher energy levels as you move from left to right across a period? Or, are they being added to the same energy level? What is responsible for the decrease in atomic radius across a period? across a period, electrons are added to the same energy level; number of protons in the nucleus affects the radius 7. List the atomic numbers of the largest atom of each section of the graph. In what group on the periodic table are each of these elements located? 3, 11, 19, 37; located in group 1 (alkali metals) on the periodic table 8. List the atomic numbers of the smallest atom of each section of the graph. In what group on the periodic table are each of these elements located? 3, 11, 19, 37; located in group 1 (alkali metals) on the periodic table On the ionization energy versus atomic number graph, do the following: a. Label the points on the graph that represent an element with a valence configuration of ns1 (1 valence e-). b.Label the points on the graph that represent an element with a valence configuration of ns2np6 (8 valence e-) c. Circle the points on the graph that represent the 3d sublevel and the 4d sublevel. d. Draw a vertical line through the points on the graph that represent a filled valence shell. 2nd period 3rd period 4th period 5th period He Ne Ar Kr Xe 1st period H Li Na K Rb questions: 1. Define ionization energy. the energy needed to remove an electron from an atom to form a +1 ion 2. Each section of the graph represents a period or horizontal row on the periodic table. 3. State the general trend in ionization energy moving across a period. ionization energy increases across a period from left to right 4. List the atomic number of the elements that have the lowest ionization energy in each section of the graph. 3, 11, 19, 37 5. To what group of the periodic table do these elements belong? the alkali metals 6. List the atomic number of the elements that have the highest ionization energy in each section of the graph. 2, 10, 18, 36, 54 7. To what group of the periodic table do these elements belong? the noble gases