Science Bridges China Research Profile Name: Position: Institute/division: Email: Tel: Liqun Zhang(张立群) Professor/Head of Key Lab Beijing University of Chemical Technology, Center of Advanced Elastomer Materials, Key Lab of Beijing City on Polymer zhanglq@mail.buct.edu.cn 0086-10-64423312 SUMMARY OF MY RELEVANT RESEARCH AREAS: Polymer Nanocomposites; Bioelastomer; Polymer Processing; Rubber Science and Technology 聚合物纳米复合材料;生物弹性体;聚合物加工;橡胶材料科学与工程 Primary Research interests: 1. With the goal of developing the biomaterials applications such as drug delivery matrix materials, tissue engineering scaffolds materials and organ-repairing materials, the research focuses on preparation of novel polymer materials with high elasticity and various biofunctionality. Main research fields are molecular design, synthesis method, structure and property of novel bioelastomer materials, nano-reinforcement and nano-modification of bioelastomer materials, the preparation methods of biodegradable porous scaffolds. Attention is also paid to the time-dependent and environment-dependent properties of the structure and biofunctionality on the bioelastomers as well as cooperation with the hospital on animal experiments and clinical application of bioelastomer materials, etc. 2. Based on the requirement of nation development strategy, such as resource, environment, energy, and so on, we study on the recycling science & technology of the cross-linked rubber, preparation science & technology of energy-saving/ environment friendly/recyclable thermoplastic elastomer, preparation science & technology of advanced material aiming at oil-saving tire. Among these, we emphasize on: science of rubber dynamic vulcanization, science of the crosslink and de-crosslink of rubber, and science of the viscoelasticity and hysteresis of rubber at broad vibration frequency range, and effect of interface on poly-phase, multi-component rubber compounds, and so on. 3. Study on filled elastomer matrix with both high-elastic performance and specific functions such as sound property, luminescence property, electrical conductivity, magnetic property. Focus on the design and development of filler structure and interface structure, the relationship of filler structure and functional response, the relationship of functions and stress, strain, temperature, and other outside fields, and its evolution with time. Develop functional elastomer composites with low-cost and high-performance, develop relevant whole set of product processing technology. 4. Focus on describing and characterizing multi-level and multi-scale structures of nano-dispersion reinforced rubber composites, developing methods of forming random or ordered nano-dispersed structures in rubber matrix, investigating thermodynamics and kinetics of nano dispersion and aggregation using statistical mechanics and molecular simulation methods, mechanism of nano-reinforcement (e.g. modulus, stress, strain, strength), relationship between the complex structure and performance of the nanocomposites, developing industrial low-cost and high- performance nano reinforcement technology and nano-composites. Topics in which you would like to develop collaborative research: Bioelastomer for drug delivery and tissue engineering; Delicate artificial device for medical application through polymer technology; Completely biobased polymer blends and composites for health care and environment. Relevant existing collaborations (academic/clinical/commercial) inside or outside China. 1. Project supported by Goodyear Rubber and Tire Company, USA 2. Project supported by High Performance Fiber Company, USA 3. Academic Collaboration with DIK, Germany 4. Academic Collaboration with Tokyo University of Technology, Sydney University and Bradford University. Relevant graphics, figures, pictures: 60 a a b c d e 50 Stress (MPa) 40 30 c d e 20 b 10 0 0 vol% 6.1 vol% 12.9 vol% 20.4 vol% 29.0 vol% 0 30 60 90 120 150 180 210 6 18 5 15 4 12 3 9 2 6 Tensile toughness Impact strength 1 0 0 5 10 15 20 25 Impact Strength (KJ/m2) Tensile toughness (GPa) Strain (%) 3 30 0 BE content (vol %) BEE highly toughened PLA blends--totally biobased The Concept and routine of Biobased Engineering Elastomer (BEE) Shape Tunable 5 stress/MPa Memory Degradable Biocompatible 4 P4S1 3 Starch/PVA/ HA system for GTR membrane 2 P1S1 1 0 0 50 100 150 200 250 300 350 400 450 strain/% Jaw bone Biobased Polyester SMP Materials 60 Melting temerature, oC 50 40 30 20 10 DC P co nten t, ph r 0.0 0.2 0.4 0.0 0.2 0.6 0.4 Molar fra 0.6 ction of 0.8 DEG 1.0 0.8 The concurrently increased electrical and thermal conductivity are observed and attributed to the well-dispersion of graphene in BE matrix Publications and other outputs relevant to your interest in this programme (up to 5) 1. Quanyong Liu, Liqun Zhang,* et al. Synthesis, preparation, in vitro degradation and application of novel degradable bioelastomers-A review, Progress in Polymer Science, In press. 2. B. C. Guo*, Y. W. Chen, Y. D. Lei, L. Q. Zhang*, et al. Shape Memory Biobased Polyester with Tunable Switching Temperature for Biomedical Applications. Biomacromolecules, 12 (2011) 1312-1321 3. T. Wei, L. Lei, H. Kang, B. Qiao, Z. Wang, L. Zhang*, Coates P D*, et al. Tough Bio-Based Elastomer Nanocomposites with High Performance for Engineering Applications, Adv Eng Mat, In press as cover story, DOI: 10.1002/adem.201100162 (Jan/Feb2012) . 4. Liu, Quanyong; Tan, Tianwei; Weng, Jingyi; Zhang, Liqun*. Study on the control of the compositions and properties of a biodegradable polyester elastomer. Biomedical Materials. 2009, 4 (2): Art. No. 025015 5. Liu, Quan-Yong; Wu, Si-Zhu; Tan, Tian-Wei; Weng, Jing-Yi; Zhang, Li-Qun*, et al. Preparation and Properties of a Novel Biodegradable Polyester Elastomer with Functional Groups. Journal of Biomaterials Science-Polymer Edition. 2009, 20 (11): 1567-1578.