Saturday AM 0001 40th SOUSCC 2012 Saturday AM RozH 103 Conference Welcome 09:00 SOUSCC Opening Remarks B/OR RozH 103 09:40 0009 Radical-based Spin Ladders: An Example in Crystal Engineering Wong J. W. L. <University of Waterloo>, Lekin K., Oakley R. T. 10:00 0010 Synthesis and Reactivity of Low Valent Cationic Gallium Complexes Malbrecht B.J. <University of Western Ontario>, Dube J.W., Ragogna P.J. Bio-inspired Organic Chemistry 09:20 0001 Modifications on the C8 position of deoxyguanosine to develop pushpull probes for the detection of small molecule binding to DNA aptamers Humphries R. <University of Guelph, 50 Stone Road East, Guelph ON N1G 2W1>, Manderville R. A. 09:40 0002 Synthesis of Novel Symtriazine Compounds as Multi-target-directed ligands (MTDLs) for Alzheimer's disease Rahman S. <University of Toronto>, Co R. 10:00 0003 Synthesis of 1, 2dihydropyridazine-3, 6-dione Derivatives of 1, 3, 5-Triazine with potential bioactivity Zhang H. <Department of Physical and Environmental Science, University of Toronto Scarborough , 1265 Military Trail Toronto, ON, Canada, M1C 1A4, >, Mikhaylichenko S. 10:20 Coffee Break 10:40 0011 Synthesis and Magnetic Properties of Alkyl- and Acid-Modified DOTAM-Derived Lanthanide(III) Complexes Elmehriki AAH <Department of Chemistry, University of Western Ontario, London ON, N6A 5B7>, Suchy M, Milne M, Hudson RHE 11:00 0012 Nanorod Anion Exchange of Cadmium Selenide to Cadmium Sulfide Trang A.K. <University of Toronto, Department of Chemistry>, Mirkovic T., Scholes G.D. 11:20 0013 Investigations Towards the Isolation of Novel Phospheniums Kosnik S.C <University of Windsor>, Farrar G.J, Macdonald C.L.B 10:20 Coffee Break 10:40 0004 The Intramolecular AryneEne Reaction: Scope and Applications to Total Synthesis Candito D., Dobrovolsky D. <Davenport Chemical Laboratories , 80 St. George St. , University of Toronto , Toronto, Ontario , M5S 3H6, >, Lautens M. 11:00 0005 Determining the Reactivity at O-3 of N-Acetyl-Glucosamine with the Presence of Benzylidene at the Non-reducing End Bricker J. <University of Guelph, 50 Stone Road East, Guelph, ON N1G 2W1, > 11:20 0006 Synthesis of New Esters of Sym-triazine as Potential Inhibitors of Amyloid Beta-Peptides in Alzheimer's disease Luk T. <Supervisor: Dr. Lana Mikhaylichenko, Department of Physical and Environmental Sciences, University of Toronto Scarborough, 1265 Military Trail, Toronto, ON, M1C 1A4, Canada>, Dhar D., Co R., Levinta A. 11:40 0007 Synthesis of CA Anticodon for use in incorporating unnautural amino acids in proteins via tRNA McNelles S <UOIT>, Desaulniers J.-P. 12:00 Lunch at Brass Taps IN RozH 102 Inorganic Chemistry 09:20 0008 Synthesis of New imidazol-2- imine-thioureate Transition Metal Complexes and Use as Polymerization Catalysts Fan L. <Department of Chemistry, York University, 4700 Keele Street, Toronto ON>, Lavoie G.G. 11:40 0014 Novel Pincer Ligands Derived from 2-(2'-anilinyl)-4,4-dimethyl-2oxazoline Skeleton Herasymchuk K. <Ryerson University, 350 Victoria Street , Toronto, ON M5B 2K3>, Gossage R. A. 12:00 Lunch at Brass Taps BIOL RozH 105 Biological Chemistry 09:20 0015 Directed Evolution of Trypsin for the Mediated Sol-Gel Processing of TEOS Nash L.A. <>, Zelisko P.M. 0026 Saturday AM 11:00 0019 Ketoacids as antioxidants in human astrocytes exposed to oxidative and aluminum stress Thomas S <Department of Chemistry and Biochemistry, Laurentian University, 935 Ramsey Lake, Rd., Sudbury, ON, P3E 2C6>, Appanna V 11:20 0020 A Look at the Binding of Malachite Green Aptamer to Ligands by the Use of NMR Techniques Andreiev A.I. <Dieckmann Lab, University of Waterloo, 200 University Avenue West, Waterloo, ON, N2L 3G1> 11:40 0021 Synthesis of supramolecular vanadate receptor--structural mimics of vanadium haloperoxidase Notowibowo D <University of Toronto Scarborough, Department of Physical and Environmental Sciences, 1265 Military Trail, Toronto ON, M1C 1A4>, Co R, Patel D, Zhang X.A., Mikhaylichenko S. 12:00 Lunch at Brass Taps PHY RozH 107 Physical Chemistry 09:20 0022 Metal Extraction of Alkali Metals for the Reprocessing of Spent Nuclear Fuel Montgomery A. <Department of Chemistry, The University of Western Ontario, Chemistry Building, 1151 Richmond Street, London, Ontario, Canada N6A 5B7>, Stockmann T.J., Ding Z. 09:40 0023 Nonlinear Dynamical Behavior in the Bromate-2-Methyl-1,4hydroquinone Photoreaction Barbu R. <Department of Chemistry and Biochemistry, University of Windsor, ON, Canada , N9B 3P4>, Wang J. 10:00 0024 The Copper-Chlorine Cycle for Production of Hydrogen by Splitting of Water: Copper Complexation Reactions in Hydrochloric Acid and Decomposition of Copper Oxychloride Nixon A. <Faculty of Science, University of Ontario Institute of Technology, 2000 Simcoe St. N., Oshawa, ON>, Trevani L. 09:40 0016 Chemical synthesis and manipulation of hyaluronic acid hydrogel as a cell culture model for better representation of the natural extracellular matrix. Vo A. <University of Toronto , Toronto, Ontario; University of Ottawa, Ottawa, Ontario>, Owen S.C., Shoichet M.S. 10:20 Coffee Break 10:00 0017 Single-site mutations in the 10:40 0025 The routine construction of pVIII coat protein of M13KE bacteriophage: Potential applications in biomaterials research Koay N. <University of Waterloo, 200 University Ave W., Waterloo, ON N2L 3G1, >, Daub E., Honek J. vibronic models and their application to the simulation of photoelectron spectra Endicott J <Chemistry Department, University of Waterloo>, Nooijen M 11:00 0026 Low-Temperature Shpolskii 10:20 Coffee Break 10:40 0018 DNA Damage by UVC in Bacterial Spores Ibrahim H., Yan T. <Brock University> Fluorescence Spectroscopy of Polycyclic Aromatic Hydrocarbons: Probing Vibrational States at the Ground Electronic Energy Level Chen SB <Department of Chemistry, University of Toronto>, Dinshaw R, Ostroumov E, Scholes GD Saturday AM 0027 40th SOUSCC 2012 11:20 0027 Water mediated Nuclear Overhauser Effect: A new approach to the study of clay-xenobiotics interactions Soong R., Botana A., Wang J. <University of Toronto Scarborough, Toronto, ON, M1C 1A4>, Simpson A. 11:40 0028 Shedding Light on Photochromism: A Comprehensive Mechanistic Study with DFT and TD-DFT Methods Chen L. D. <Queen's University, 99 University Ave, Kingston, ON K7L 3N6; Stanford University, 450 Serra Mall, Stanford, CA 94305-2004>, Mosey* N. J. 12:00 Lunch at Brass Taps P/SS RozH 106 Physical Chemistry / Surface Science 09:20 0029 Fabricating and Characterizing New Light-Absorbing Materials for Solar Cells Tapley A <The University of Western Ontario, London On, N6A 3K7>, Vaccarello D, Ding Z 09:40 0030 Ru(II) Complexes for the development of new Dye-Sensitized Solar Cells (DSSCs) Bakhshaei B <York University> 10:00 0031 Non-precious Metal Catalysts Prepared by Electrochemical Polymerization Duffin L <Faculty of Science, Bachelor of Science, U.O.I.T> 10:20 Coffee Break 10:40 0032 Microcantilevers: Characterization and Applications to New Nanosensors Morrison A <Rowntree Research Group, University of Guelph, Guelph, ON, N1G 2W1> 11:00 0033 The Adsorption of Phosphorus on an Iron Oxide Surface Using Computational Quantum Chemistry Whyte S. <Department of Chemistry, Wilfrid Laurier University,75 University Ave. W, Waterloo, Ontario, N2L 3C5, Canada>, Hamilton I., Adamescu A. 11:20 0034 Development of scaffolded vesicles for drug and nutraceuticals delivery. Shodiev M. <Lipkowski Lab, University of Guelph, Guelph, ON> 11:40 0035 The Effects of Branched Chain Thiols on Carbon Deposition on Nickel Catalysts during the Dry Reforming of Methane Foran G <University of Guelph, 50 Stone Road, Guelph, Ontario> 09:20 0036 ATR-FTIR Microscopy of Human Embryonic Stem Cells Martino T. <Department of Chemistry, Western University , 1151 Richmond Street, , London, Ontario, Canada, N6A 5B7>, Dieters-Castator D., Tabatabaei M., Postovit L-M., LagugnéLabarthet* F. 09:40 0037 Method Validation of Detection of Guanidino Compounds using Liquid Chromatography Tandem Mass Spectrometry Zahid Hiba <University of Toronto>, Schulze Andreas, Mikhaylichenko Svetlana 10:00 0038 Using Capillary Electrophoresis and Magnetic Beads for Miniaturized Protein Sample Preparation Baillargeon A. L. <Western Univeristy, London, ON, N6A 3K7>, Booker C. J., Yeung K. K.-C. 10:20 Coffee Break 10:40 0039 Exploring the Protein Electrospray Process By Electrostatic Modeling Rodriguez A. <The University of Western Ontario, Department of Chemistry, London, Ontario>, Konermann L., Jiangjiang L. 11:00 0040 Investigation of Zn/Mn Containing Nanoclusters Using Electrospray Ionization Mass Spectrometry Comeau A. <The University of Western Ontario, London, Ontario, N6A 5B7>, Lui J., Corrigan J., Konermann L. 11:20 0041 Reconstruction and Resurrection of a Spectrofluorimeter: The Frankenstein Project. Bialy R.M. <Department of Chemical and Physical Sciences, University of Toronto Mississauga, 3359 Mississauga Road North, Mississauga, Ontario, L5L 1C6>, Piunno P.A.E. 11:40 End of Session 12:00 Lunch at Brass Taps POST RozH Foyer Posters From 12:00 until 17:20 0042 Manganese TetraphenylporphyrinBased Catalysts for the Dehydrogenation of Alkanes to Alkenes Kim D. <University of Toronto Scarborough, 1265 Military Trail, Toronto, ON M1C 1A4>, Sauer E.L.O. 12:00 Lunch at Brass Taps B/AN RozH 108 Bioanalytical / Analytical Chemistry 0043 Synthesis of pyrrolopyridazine derivatives as targets for HER receptors. Canzonieri GC <University of Toronto Scarborough>, Dalili SD 0054 Saturday AM 0044 Characterization of the enzymatic activities of voltage-dependent anion channel and Na+, K+-ATPase in the myelin membrane Rassam M. <Chemistry department, Wilfrid Laurier University, 75 University Ave W, Waterloo, ON, N2L 3C5>, DeBruin L. 0045 Computational Investigations of Carbonyl Sulfide Adsorption on Cationic Rhodium Clusters Chow W.C.T. <Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo, Ontario, Canada, N2L 3G1>, Lecours M.J., Hopkins W.S. 0046 A QM/MM Study on the Catalytic Ion B.F., Mechanism of Nicotinamidase Kazim E. <Department of Chemistry and Biochemistry, University of Windsor , Windsor, ON , N9B 3P4>, Gauld J.W. 0047 Synthesis of Small Molecules as Potential Histone Deacetylase Inhibitors Cordero K. <University of Toronto Scarborough, Department of Physical and Environmetal Sciences, 1265 Military Trail, Toronto, ON, M1C 1A4>, Dalili S. 0048 Design of a New Intsrument for Gasphase Nanocluster Research Lecours M.J. <Department of Chemistry, University of Waterloo, 200 University Ave. W, Waterloo, ON, Canada N2L 3G1>, Chow W.C.T, Hopkins W.S 0049 Chloride Transport of Human Uncoupling Protein-2 Matovic T <Chemistry Department, Wilfrid Laurier University, Waterloo, ON>, Hoang T, Smith MD, Jelokhani-Niaraki M 0050 Isoelectric fractionation using digital microfluidics Simoes T. <Department of Chemistry, University of Toronto, >, Choi K., Wheeler A.R. 0051 Structural analysis of human uncoupling protein-2 using selective tryptophan mutants Auld T. <Department of Chemistry, Wilfrid Laurier University, Waterloo ON>, Hoang T., Szabo A.G., Smith M.D., Jelokhani-Niaraki M. Identification of the Capsular 0052 Polysaccharide of Clostridium perfringens 1395 Valliani M <University of Guelph, 50 Stone Road East, Guelph, Ontario, N1G 2W1>, Monteiro M 0053 Candida antarctica Lipase B as a biocatalyst in the synthesis of silicone Burattini S. J. <Brock polyamides University, 500 Glenridge Avenue, St. Catharines, ON., L2S 3A1>, Zelisko P. M. 0054 The Synthesis of cyclopentadienylcobalt-cyclobutadiene Complexes for Functionalized Metallopolymer Production Middlemiss S <University of Western Ontario> Saturday PM Saturday PM 0055 OR/D 40th SOUSCC 2012 RozH 103 Organic Chemistry and Devices 13:40 0055 Capture and Release: A Diels-Alder Strategy for Robust and Switchable Hydrophobic Coatings Lui M. W. <Department of Chemistry and Centre for Advanced Materials and Biomaterials Reseaerch (CAMBR), Western University Canada, London, ON N6A 5B7>, Gobbo P., Workentin M. S., Ragogna P. J. 14:00 0056 Synthesis of Rotaxane containing Benzimidazolium axle and Cucurbit[7]uril wheel Youssouf A <University of Windsor, 401 Sunset Avenue, Windsor, Ontario , N9B 3P4> 14:20 0057 Useful Molecular Complexity Generated by a Gramine-type Fragmentation of a Meldrums Acid Moiety Armstrong E. L. <The Department of Chemistry,The University of Western Ontario, London, ON>, Kerr M. A. 14:40 0058 Synthesis and Characterization of New Discotic Liquid Crystals from Substituted Dibenzanthracenes Psutka K.M. <Department of Chemistry, Wilfrid Laurier University, 75 University Ave. W., Waterloo, Ontario, N2L 3C5, Canada>, Williams J., Paquette J., Maly K.E. Organic / Organometallic Chemistry 13:40 0064 Reversal of Ferrocenyl Imidazolone Planar Chirality Using an Epimeric Starting Material. Nelson Jonathan <Department of Chemistry, Brock University, St. Catharines, ON, L2S 3A1>, John Joshni, Dudding Travis, Metallinos* Costa 14:00 0065 The Reactivity of Digermenes Towards Isonitriles Cook E. E. <Department of Chemistry, Western University, London, Ontario, N6A 3K7>, Baines K. M. 14:20 0066 Towards the Synthesis of a New Pd-Phosphine Catalyst for the BuchwaldHartwig Reaction Chojnacka M.W. <Department of Chemistry & Biology, Ryerson University, 350 Victoria Street, Toronto, ON, Canada M5K 2B3>, Viirre R.D., Gossage R.A. 14:40 0067 Synthesis and Application of Manganese meso-Tetra(4-sulfonatophenyl)porphyrin as a Water-Soluble Catalyst for Aqueous-Phase Oxidation of Hydrocarbons Kim K. <University of Toronto Scarborough, 1265 Military Trail, Toronto, ON M4C 1A4>, Sauer E.L.O. Substrates for Organic Synthesis. Prack E. <University of Toronto>, DaCosta M. V., Bancerz M., Youn B., Georges M. K. 15:00 0068 Dancing Directed Metalation Groups: Regioselective Functionalization of Azaindoles Dalziel M. <Queen's University, Bader Lane, Kingston ON, K7L 2S8>, Kitching M., Schneider C., Snieckus V., Bailey A., Crudden C. 15:20 Coffee Break 15:20 Coffee Break 15:40 0060 15:40 0069 Amphtoric a-Boryl Aldehydes 15:00 0059 Verdazyl Radicals as The Synthesis and SelfAssembly of Novel Dibenzo[a,c]phenazines Flisar M.E. <Department of Chemistry,, Wilfrid Laurier University,, 75 University Ave. W, Waterloo, Ontario, N2L 3C5, Canada, kmaly@wlu.ca, >, Maly K.E. 16:00 0061 The Synthesis and Study of a Light-Switchable Hydrogen-Bond Motif Sawyer J. <The University of Western Ontario, London, ON, N6G 2J8>, Wisner J. 16:20 0062 Axially Substituted Boron Subphthalocyanine with Arylamines and Nitrogen-Based Heterocycles - Towards Application in Organic Electronics Weber O J <Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College St., Toronto, ON, M5S 3E5>, Morse G E, Paton A S, Bender T P 16:40 0063 The Synthesis of an Orexin Antagonist for the Purpose of Colorectal Cancer Detection through PET Imaging Park H <Department of Chemistry, The University of Western Ontario, London, ON, N6A 5B7>, Luyt L 17:00 End of Session OR/M and Derivatives He Z, Yudin A, Zajdlik A <University of Toronto, Department of Chemistry, 80 St. George Street, Toronto, Ontario, Canada, M5S 3H6> 16:00 0070 Study of High Pressure Diels Alder Reactions of Azodicarboxylate Compounds Landschoot B.K. <University of Western Ontario, Richmond St., London, ON, N6A 5B7>, Humenny W.J., Kerr M.A. 16:20 0071 Gamma Alkylation of Unsaturated Carbonyl Derivatives Functionalization of the Homobenzylic Position of Meldrum's Acid Alkylidenes Beaton E. <University of Waterloo,, Waterloo, ON, N2L 3G1>, Fillion E. 16:40 0072 Synthesis of Thymine and Uracil Nucleoside Analogues through a General Photochemical Reaction of Cyclobutanone Intermediates Jobst K. <York University, 4700 Keele St., Toronto, ON, M3J 1P3>, Lee-Ruff E. 17:00 End of Session BIOC RozH 102 Biochemistry RozH 105 0083 Saturday PM 13:40 0073 The Effect of Heme on Giardia lamblia Tseng W. <Biochemistry and Molecular Biology Program, Trent University, 1600 West Bank Drive, Peterborough, ON K9J7B8>, Yee J., Rafferty S. 14:00 0074 Familial amyotrophic lateral sclerosis and the stability of SOD1 mutant E100K Lockhart M.B. <University of Waterloo, Chemistry Department, 200 University Ave. W., Waterloo, ON, N2L 3G1> 14:20 0075 First Generation Backbone Modifications of siRNA That Displayed Potent RNAi Mediated Gene Silencing of Luciferase Efthymiou T., Desaulniers J.P., Peel B. <U.O.I.T> 14:40 0076 The challenges associated with purifying myristoylated hisactophilin, a co-translationally modified protein Go CD <University of Waterloo>, Meiering EM 15:00 0077 The Effects of Nitrosative Stress on Giardia lamblia Ninivirta L <Trent University, 1600 West Bank Drive, Peterborough, ON, K9J 7B8>, Yee J, Rafferty S 15:20 Coffee Break 15:40 0078 Peptide-based Inhibitors of Metallo-b-lactamases Rotondo C. <Department of Chemistry and Biochemistry,, Laurentian University, 935 Ramsey Lake Rd., Sudbury, ON, P3E 2C6, >, Siemann S. 16:00 0079 pH Studies on Immobilized Montpellier L. Anthrax Lethal Factor <Department of Chemistry and Biochemistry, Laurentian University, 935 Ramsey Lake Rd., Sudbury, ON, P3E 2C6>, Siemann S. 16:20 0080 Characterizing the Giardia lamblia Flavohemoglobin Almey J <Trent University, 1600 West bank Dr., Peterborough, ON., K9J 7B8> 16:40 0081 In vivo activity of a photo- switchable DNA-binding protein Kim YJB <Department of Chemistry, University of Toronto>, Mazumder M, Brechun KE, McMillen D, Woolley GA 17:00 End of Session T/CC RozH 107 Theoretical / Computational Chemistry 13:40 0082 Calculating Nuclear Quadrupolar Coupling Constants in HCl Kranz N <Department of Chemistry, University of Guelph, Guelph, ON, N1G2W1>, Penner G, Jamieson R 14:00 0083 A Computational Study of RNA Catalysis in the Hairpin Ribozyme Stankevicius J <University of Waterloo> Saturday PM 0084 40th SOUSCC 2012 14:20 0084 Density Functional Theory Calculations on the Complexation of pArsanilic Acid to Iron Oxide Clusters Lindner M. <Dept. of Chemistry, Wilfrid Laurier University, 75 University Ave>, Adamescu A., Hamilton I.P, Al-Abadleh H.A. 14:20 0093 Electrocatalytic CO2 Reduction using Ni(cyclam)2+ Covalently Adsorbed on a TiO2 Nanoparticle Electrode. McKim C <Faculty of Science, University of Ontario Institute of Technology, 2000 Simcoe St N, Oshawa ON, Canada, L1H 7K4>, Coulter K 14:40 0085 A Self-Interaction Correction 14:40 0094 Platinum-Manganese Alloy Catalysts for Ethanol Oxidation Reid O. <The University of Ontario Institute of Technology, 2000 Simcoe St. North, Oshawa, ON , L1H 7K4>, Easton E.B. 15:00 0086 A Mechanistic Study of C-H Bond Activation via Tin-Organo Compounds: A DFT Study Mroz N.M <University of Windsor>, Johnson S., Gauld J. W 15:00 0095 Fully Photodegradable Dendrimers Schon T <Department of Chemistry, The University of Western Ontario, London, Ontario,, N6A 5B7>, Nazemi A, Gillies E Scheme for Approximate Kohn-Sham Mizzi D. <The University of Potentials Western Ontario>, Staroverov V. N. 15:20 Coffee Break 15:20 Coffee Break 15:40 0087 A QM/MM Study of Initial Substrate Binding Models in Sribosylhomocysteinase (LuxS) Huang W-J., Gherib R. <Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Ave. Windsor, Ontario N9B 3P4, Canada>, Gauld J. W. 16:00 0088 A Study of Transition Metal Complexes Using 35Cl SSNMR and FirstPrinciples DFT Calculations O'Keefe C. A. <University of Windsor, Department of Chemistry and Biochemistry, Windsor, Ontario, N9B 3P4>, Schurko R. W. 16:20 0089 Spectroscopic & Theoretical Studies of Low Symmetry Porphyrins Jeffs K. <Stillman Bioinorganic Group,, The University of Western Ontario,, London, Ontario, 1151 Richmond St, N6A 5B8> 16:40 0090 Insights into the catalytic mechanism of Ovothiol A Fortowsky GB <Department of Chemistry and Biochemistry University of Windsor>, Bushnell EAC, Gauld JW 17:00 End of Session P/NS RozH 106 Physical Chemistry / Nanoscience 13:40 0091 Design And Evaluation Of Porous Carbon Materials For Chemical Protective Filter Canisters Barry A <Royal Military College of Canada, Chemical Protection Group, Kingston, Ont>, Cui Y, Evans M, Prior L, Gudgin Dickson EF 14:00 0092 Covalent Functionalization of Carbon Nanotubes with PEG Chains for Water Solubility MacIsaac C <Department of Chemistry and Chemical Biology, McMaster University>, Chadwick R, Adronov A 15:40 0096 The Influence of Electron Withdrawing Groups on the Supramolecular Functionalization of Carbon Nanotubes Using Conjugated Polymers Coleman B <McMaster University, Hamilton, Ontario> 16:00 0097 Modification of TiO2 matrix with CdO and its effect on overall cell performance in dye- and quantum dotsensitized solar cells Sisopha A. <York University>, Phung A., Sepehrifard A., Morin S. 16:20 0098 The Synthesis and Characterization of Gold Clusters and Nanoparticles Macoretta D. <Wilfrid Laurier University , Department of Chemistry , 75 University Ave West , Waterloo, ON, N2L 3C5>, Kitaev Dr. V, Cathcart N., Keunen R. 16:40 0099 The effectiveness of UVozone cleaning is tested using the atomizer (steam) test, and preliminary metastable helium de-excitation spectra are analyzed Moore M <Rowntree Group, University of Guelph, 50 Stone Road East> 17:00 End of Session 0099 Saturday PM