Unit 6 Thermal Conductivity Objectives To measure the thermal conductivity coefficients of several different materials by thermal conductivity apparatus. Apparatus Steam stove, thermal conductivity apparatus, measuring cup, electric scale, thermometer, polystyrene cover, samples, timer (stopwatch), clamps. Cover the ice with the can Clamp this tube Measuring cup B Fill to 60%~70%. Light D Measuring cup A Knob C Principles 1. In a stable and uniform heat conduction, the transmitted heat ∆Q within time ∆t is proportional to the temperature difference, cross sectional area A (perpendicular to the direction of heat flow), and the inverse of thickness 1/h. The proportion factor is the thermal conductivity. As shown in Eq. (1) kA∆T∆t ……………………(1) h where ∆Q is the total transmitted heat, ∆Q = ∆T is the temperature difference, ∆t is the time interval, A is the cross sectional area, h is the heat transmission distance (the thickness of the sample), and k is the Thermal Conductivity. 2. In this experiment, we keep one end of the sample at 100 ℃ and the other end at 0 ℃. i.e. ∆T = 100 ℃. ………….(2) Q1: How to maintain the temperature of the two ends at 100 ℃ and 0 ℃? 3. In this experiment, we measure the melt rate of ice to determine the rate of heat conduction. Latent heat of ice is 80 cal/g, and then in Eq. (1) ∆Q =mass of melting ice m (g) × 80 (cal/g) ……… (3). Substitute Eq. (2) and (3) to Eq. (1), we have 80 × m × h ⎛ Cal ⎞ ⎜ ⎟. A × 100 × ∆t ⎝ cm ⋅ °C ⋅ sec ⎠ ( h is in unit of cm ) k= Instructions 1. Set up your devices as Fig. 1, but do not connect the steam stove. 2. Measure the thickness h of the sample. 3. Connect the steam stove when the steam is ready, and use measuring cup B to 4. 5. collect the water from the steam chamber. Place your sample on the top of the steam chamber and tight the screw to fasten the sample, just as Fig.1. Aim the escape canal at the drain, and you can put on some petrolatum (Vaseline) to prevent leakage. Wait for a couple minutes for the system to become stable so that the temperature will stop rising. 6. Place the plastic can (with ice inside) under tap (faucet) and pour it with tap water ( just pour the external surface of the can, and DO NOT pour the water inside the can). Rotate the can when pouring tap water on it, hence the can will be heated uniformly ( DO NOT pry out the ice). Q2: Why don’t we pour the tap water directly on the ice but on the external surface of the can? 7. Put the ice ( with the plastic can) upside-down on the V-type escape canal of the sample. 8. Wait for a few minutes until the ice starts melting and the surface of ice totally contacts the sample. NOTE: The temperature of ice may be under 0 ℃ before the ice starts melting, so we have to wait and start our experiment after it starts melting. If the surface of ice is not smooth, you may have to grind it. 9. Measure the weight of measuring cup A. 10. Measure the diameter d1 of the ice. 11. Measure the mass of water collected in measuring cup A after a recommended time of 5 minutes, and record the time as t1. Then measure the diameter d2 of the 2 ice. d avg 1 ⎛1 ⎞ = (d 1 + d 2 ) , A = π ⎜ davg ⎟ . 2 ⎝2 ⎠ 12. Measure the total mass of measuring cup A. Then subtract the mass measured in step 9 from the total mass and record the value as m1. Then the heat absorbed by the ice is ∆Q1 = m1 × 80 . Then pour out the water from cup A. 13. Add a polystyrene under the ice. 14. When the ice is melting steadily, start colleting the water with measuring cup A. After a recommended time of 5 minutes, subtract the mass measured in step 9 from the total mass of the cup, and record it as m2. The heat absorbed by the ice is ∆Q 2 = m 2 × 80 . 15. If t1=t2, ∆Q1 − ∆Q 2 = kA∆T∆t h (m1 − m2 ) × 80 . , where ∆t = t1 . k = h 100 × A × ∆t NOTE: A reasonable error should be under 15%. Q3: Why do we have to measure ∆Q1 and ∆Q2 ? What will it be if we only do it once (without measuring ∆Q2 )? Q4: How to calculate for k when t1 ≠ t2 ? 16. Repeat step 9 to 14. 17. Change a sample and repeat step 9 to 15. Remark: 1. The steam stove and steam chamber are extremely hot, be careful when operating your experiment! 2. Fill the stove to up to 60% to 70% is enough. Too much water will decrease the 3. 4. 5. heating; on contrary, you may have to add some water during the experiment if the water is not enough. When all the devices are ready and you are going to start your experiment, you can turn the switch C to “MAX”. The glass sample may break if the heating is not uniform. Therefore, you can pour some cold water on the glass before placing it on the heat conductivity apparatus. Also, you can slide the ice on the glass sample to make the temperature uniform. Place the ice by the V-type escape canal after all. When D light blinks, you have to turn off the stove and add some water into it to prevent damage.