Enthalpies of Vaporization of Organic and Organometallic Compounds,
1880–2002
James S. Chickosa…
Department of Chemistry, University of Missouri-St. Louis, St. Louis, Missouri 63121
William E. Acree, Jr.b…
Department of Chemistry, University of North Texas, Denton, Texas 76203
共Received 17 June 2002; accepted 17 October 2002; published 21 April 2003兲
A compendium of vaporization enthalpies published within the period 1910–2002 is
reported. A brief review of temperature adjustments of vaporization enthalpies from
temperature of measurement to the standard reference temperature, 298.15 K, is included
as are recently suggested reference materials. Vaporization enthalpies are included for
organic, organo-metallic, and a few inorganic compounds. This compendium is the third
in a series focusing on phase change enthalpies. Previous compendia focused on fusion
and sublimation enthalpies. Sufficient data are presently available for many compounds
that thermodynamic cycles can be constructed to evaluate the reliability of the measurements. A protocol for doing so is described. © 2003 American Institute of Physics.
关DOI: 10.1063/1.1529214兴
Key words: compendium; enthalpies of condensation; evaporation; organic compounds; vaporization enthalpy.
Contents
1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2. Reference Materials for Vaporization Enthalpy
Measurements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3. Heat Capacity Adjustments. . . . . . . . . . . . . . . . . . .
4. Group Additivity Values for C p l (298.15 K)
Estimations. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5. A Thermochemical Cycle: Sublimation,
Vaporization, and Fusion Enthalpies. . . . . . . . . . . .
6. Estimation of Vaporization Enthalpies. . . . . . . . . .
7. Vaporization Enthalpy Compendium. . . . . . . . . . . .
8. Acknowledgment. . . . . . . . . . . . . . . . . . . . . . . . . . .
9. References for Introductory Material. . . . . . . . . . .
List of Tables
1. Recommended reference standards for
vaporization enthalpy measurements. . . . . . . . . . . .
2. Group values ⌫ l and ⌫ c for estimating
C p l (298.15 K) and C p c (298.15 K). . . . . . . . . . . . .
3. Some estimations of C p l (298.15 K) and
C p c (298.15 K) using group values. . . . . . . . . . . . .
4. A comparison of experimental sublimation
enthalpies and those calculated using Eq. 共6兲. . . . .
5. A list of acronyms used in Tables 6 and 7. . . . . . .
6. Enthalpies of vaporization of organic compounds,
1880–2002. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
7. Enthalpies of vaporization of organometallic and
519
520
520
521
523
525
525
878
878
820
853
List of Figures
1. A thermodynamic cycle for adjusting vaporization
enthalpies to T⫽298.15 K.. . . . . . . . . . . . . . . . . . .
2. A hypothetical molecule illustrating the different
hydrocarbon groups in estimating C p .. . . . . . . . . .
521
523
1. Introduction
Vaporization enthalpies are important thermodynamic
properties of the condensed phase. Vaporization enthalpies
are used frequently in adjusting enthalpies of formation of
liquids to the standard state and in evaluating environmental
transport properties.1,2 To the chemical engineer, the magnitude of this property needs to be taken into consideration in
designing equipment for chemical processing and synthesis.
Thus vaporization enthalpy data are of interest at a variety of
temperatures. As a consequence, there is a wealth of information in the literature that covers measurements over a
broad range of temperatures. The data covered by this compendium include as much of the spectrum as was available to
us.
Our interest in vaporization enthalpies goes back nearly
two decades. Our primary focus in measuring vaporization
enthalpies was as a means of adjusting enthalpies of formation of liquids to the standard state and in conjunction with
fusion enthalpies to adjust solids in a similar fashion.3 Since
then we have focused our attention on their estimation,4 and
assessment.5 In parallel studies, compilations of available
sublimation and fusion enthalpies were also initiated.6,7 A
520
522
524
525
526
527
a兲
Author to whom correspondence should be addressed; electronic mail:
jsc@umsl.edu
b兲
Electronic mail: acree@unt.edu
© 2003 American Institute of Physics.
0047-2689Õ2003Õ32„2…Õ519Õ360Õ$37.50
inorganic compounds, 1880–2002. . . . . . . . . . . . . .
8. References to Tables 6 and 7. . . . . . . . . . . . . . . . . .
519
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
520
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 1. Recommended reference standards for vaporization enthalpy measurements
Substance
C3 H8 O
C5 H12
C6 F6
C6 H6
C6 H14
C7 H16
C8 H18
C9 H20
C10H8
C10H22
C11H24
C12H26
C13H28
C14H30
C16H32
C18H38
C20H42
H2 O
a,d
1-propanol
pentaneb,d
hexafluorobenzenea,d
benzenea,c,d
hexaneb,d
heptaneb,d
octaneb,d
nonaneb,d
naphthalened
decaneb,d
undecaneb,d
dodecaneb,d
tridecaneb,d
tetradecaneb,d
hexadecaneb,d
octadecaneb,d
eicosaneb,d
waterd
T/K range
333–378
269–315
290–377
286 –383
286 –343
299–372
326 – 400
344 – 425
353– 434
268 –348
294 –382
313– 403
323– 402
344 – 422
364 – 452
312–590
344 –380
273–373
Vapor pressure range/Pa
20 E⫹3–135
2.0 E⫹4 –1.2
7.5 E⫹3–2.1
7.0 E⫹3–2.3
1.2 E⫹4 –1.0
6.4 E⫹3–1.0
7.7 E⫹3–1.0
6.4 E⫹3–1.0
1.0 E⫹3–2.3
1.7 E⫹1–3.2
4.1 E⫹1– 6.4
5.8 E⫹1–7.3
4.7 E⫹1–3.7
7.6 E⫹1– 4.4
5.5 E⫹1– 4.7
1.0 E⫺1–1.0
4.1 E⫺1–9.1
6.1 E⫹1–1.0
E⫹3
E⫹5
E⫹5
E⫹5
E⫹5
E⫹5
E⫹5
E⫹5
E⫹4
E⫹3
E⫹3
E⫹3
E⫹3
E⫹3
E⫹3
E⫹5
E⫹0
E⫹5
⌬ vapH m 共298.15 K兲 kJ mol⫺1
Classification
47.45⫾0.1
26.42⫾0.1
35.71⫾0.07
33.83⫾0.07
31.52⫾0.13
36.57⫾0.15
41.56⫾0.17
46.55⫾0.19
55.65⫾2.8
51.42⫾0.21
56.58⫾0.57
61.52⫾0.62
66.68⫾0.67
71.73⫾0.72
81.35⫾0.81
91.44⫾1.83
101.81⫾2.0
43.99⫾0.07
Primary
Primary
Primary
Primary
Primary
Primary
Primary
Primary
Secondary
Primary
Primary
Primary
Primary
Primary
Primary
Primary
Primary
Primary
a
Reference 12.
Reference 13.
c
Cancer suspect agent.
d
Reference 5.
b
reasonably exhaustive version of these databases covering
the literature to the present has recently been published and
is also available on line at http://webbook.nist.gov/
chemistry/. Combined with fusion and sublimation enthalpies appropriately adjusted to T⫽298.15 K, vaporization enthalpies ⌬ vapH m (298.15 K), complete a thermochemical
cycle that can be used to assess the quality of the available
data. Application of this thermochemical cycle is illustrated
below. A goal of the present contribution has been to provide
an exhaustive coverage of the literature from about 1880 to
2002; regrettably however, this compilation is probably still
incomplete.
2. Reference Materials for Vaporization
Enthalpy Measurements
Calibration is a fundamental requirement in every thermochemical measurement of vaporization enthalpy. Regardless
of which technique is used, the measurement ultimately depends either directly or indirectly on vapor pressure. Vapor
pressures of liquids vary over many orders of magnitude. An
experimental technique calibrated with a standard in one
pressure or temperature regime does not in itself guarantee
the same accuracy in another. Substantial variations in vaporization enthalpy are revealed in the tables that follow. This
variance clearly establishes the importance of documenting
the accuracy of the measurements through the use of appropriate reference materials that approximate the temperature
and pressure regimes of the measurements of interest.
A series of compounds have been recently proposed as
reference materials for vaporization enthalpy.5 These have
been classified as primary, secondary, or tertiary reference
materials, on the basis of various criteria. The materials classified as primary and secondary reference materials are listed
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
in Table 1. The temperature range, the corresponding vapor
pressures, and the recommended molar vaporization enthalpies at T⫽298.15 K are also included in the table. Some of
these reference materials are solids at T⫽298.15 K and
therefore the vaporization enthalpies are hypothetical values.
The reader should consult the literature cited at the bottom of
the table to obtain the vaporization enthalpy at the temperature of interest.
3. Heat Capacity Adjustments
Vaporization enthalpies, like their sublimation counterparts, are measurements based on mass transport and as such
are directly or indirectly dependent upon vapor pressure. The
vapor pressure of different liquids at a given temperature can
vary many orders of magnitude. In order to obtain a reasonable amount of mass transport, it is frequently necessary to
conduct these measurements at temperatures that differ substantially from the standard reference temperature, 298.15 K.
The actual temperature of measurement depends on the sensitivity of the instrument or apparatus and the properties of
the substance of interest. Vaporization enthalpy measurements are often conducted as a function of temperature.
The magnitude of the vaporization enthalpy is dependent
on temperature. Figure 1 and Eqs. 共1兲 and 共2兲 illustrate the
origin of this temperature dependence in terms of a thermodynamic cycle. If the heat capacities of the liquid and gas
phase are known, C p l and C p g , respectively, then the vaporization enthalpy at T⫽298.15 K can be related to the experimental measurements by using Eq. 共1兲. This equation, generally referred to as Kirchhoff’s equation, can be used to
adjust sublimation enthalpy measurements to any reference
temperature. The term T m represents either the temperature
ENTHALPIES OF VAPORIZATION
521
temperature. In some cases experimental data have been used
for C p l and in other cases both C p l and C p g have been estimated. The reader is encouraged to refer to the original literature for details. In an effort to provide some assistance to
the reader in this regard, a brief discussion of one of the
group additivity methods that are available for estimating the
heat capacity of liquids is included below. This is followed
by an illustration of how this value can be used in conjunction with Eq. 共3兲 to provide temperature adjustments.
FIG. 1. A thermodynamic cycle for adjusting vaporization enthalpies to T
⫽298.15 K.
of measurement for calorimetric measurements or the mean
temperature of measurement for experiments conducted
⌬ vapH m 共 298.15 K兲 ⫽⌬ vapH m 共 T m 兲
⫹
冕
Tm
共 C p l ⫺C p g 兲 dT
共1兲
⫹ 共 C p l ⫺C p g 兲共 T m ⫺298.15兲
共2兲
298.15
⌬ vapH m 共 298.15 K兲 ⬇⌬ vapH m 共 T m 兲
over narrow ranges of temperature. Treating the heat capacities of the two phases as independent of temperature and
integrating Eq. 共1兲 results in Eq. 共2兲. Since the magnitude of
the heat capacity of the gas phase is usually smaller than that
of the liquid phase 共l兲, vaporization enthalpies increase with
decreasing temperature.
Experimental heat capacities for many liquids at T
⫽298.15 K are available.8 Experimental gas phase heat capacities for compounds that are liquids at T⫽298.15 K are
unavailable and generally need to be estimated. Gas phase
heat capacities can be calculated from statistical mechanics
or estimated by group additivity methods. A number of group
additivity methods have been developed to estimate gas
phase heat capacities.9,10 However, group values for some
functional groups are not available. Equation 共3兲 is an example of an attempt to circumvent the lack of sufficient
group values.11 The term C p l (298.15 K) refers to the heat
capacity of the liquid at T⫽298.15 K. This term may either
be estimated or experimental values may be used if available. The uncertainty associated with the term in brackets in
Eq. 共3兲 is ⫾30 J mol⫺1 共⫾2␴兲
共 C p l ⫺C p g 兲 兵 T m ⫺298.15其
⫽ 关 10.58⫹0.26C p l 共 298.15 K兲兴共 T m ⫺298.15兲 .
共3兲
The vaporization enthalpies reported in this compendium
have not been adjusted to T⫽298.15 K unless done so by the
authors reporting the measurements. The vaporization enthalpies are reported at the mean temperature of measurement wherever possible. This allows the reader to verify the
reported data and to adjust for temperature in a consistent
manner. Authors have applied different methods to adjust for
4. Group Additivity Values for
C p l „298.15 K… Estimations
Tables 2A and 2B lists a set of group values that can be
used in estimations of C p l (298.15 K). The groups and their
corresponding values are identified by italics. A hypothetical
molecule is given in Fig. 2 that identifies each hydrocarbon
group. The functional groups listed in Table 2B are self explanatory. The R terms in this table represent variable groups
and are not included in the value. Values in brackets should
be considered as tentative assignments. The use of these
group values is illustrated with the examples in Table 3. Estimations of C p c (298.15 K) for these compounds follow the
same protocol.
Groups are defined on the basis of their substitution and
hybridization patterns. These groups are further subdivided
into cyclic, acyclic and aromatic categories. The estimation
of C p l (298.15 K) for propionic acid illustrates how directly
C p values can be estimated. Identification of the appropriate
group is important. Although not shown in Table 3, the same
protocol is used for estimating C p c (298.15 K). Estimation of
the heat capacity of piperadine is similar. In this case it is
important to use the appropriate cyclic group. Once the
proper groups are identified, the estimation is direct. Di-tbutyl ether is estimated in a similar fashion. Benzothiazole
illustrates the estimation of an aromatic molecule containing
a heterocyclic ring. The aromatic ring carbons are selected
based on their substitution pattern; the sulfur and nitrogen
atoms of the thiazole ring are identified as cyclic atoms; the
nitrogen atom is identified on the basis of its hybridization
and substitution pattern. 2-Methylcyclohexanone is another
example of an estimation of a cyclic molecule. This estimation includes the contributions of a cyclic carbonyl, four cyclic methylene groups, a methyl, and a cyclic tertiary methine group. The estimation of limonene illustrate an
example of a molecule that contains both cyclic and acyclic
double bonds. Additional examples can be found in the
literature.4,11
Heat capacities calculated according to the protocol just
described have been used when necessary in conjunction
with Eqs. 共4兲–共6兲 to adjust vaporization, sublimation, and
fusion enthalpies to 298.15 K. These temperature adjustments are necessary in illustrating the thermochemical cycle
described below. Equations 共4兲–共6兲 have been used in those
cases where the measurements were referenced to some other
temperature
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
522
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 2. Group values ⌫ l and ⌫ c for estimating C p l (298.15 K) and C p c (298.15 K)
共A兲 Group values for estimating the C p l (298.15 K) and C p c (298.15 K) of hydrocarbons.a
Hydrocarbon groups
Aliphatic groups
Cyclic aliphatic and olefinic groups
J mol⫺1 K⫺1
Description of group
3
primary sp C
secondary sp 3 C
tertiary sp 3 C
quaternary sp 3 C
⌫l
Formula
–CH3
–CH2 –
–CHR–
–CR3
⌫c
34.9
31.9
22.4
14.0
36.6
26.9
9
⫺5
J mol⫺1 K⫺1
Description of group
Formula
⌫l
⌫c
3
–Cc H2 –
–Cc HR–
–Cc R2 –
–Cc HR–
–Cc R2 –
25.9
20.6
18.0
21.8
21.2
24.6
11.7
6.1
15.9
关4.7兴
cyclic
cyclic
cyclic
cyclic
cyclic
secondary sp C
tertiary sp 3 C
quaternary sp 3 C
tertiary sp 2 C
quaternary sp 2 C
Olefinic and acetylenic groups
Aromatic groups
⫺1
J mol
Description of group
⌫l
Formula
⫽CH2
⫽CH–
⫽C–
⬅C–H
⬅C–
2
secondary sp C
tertiary sp 2 C
quaternary sp 2 C
tertiary sp C
quaternary sp C
25.8
27.8
21.7
34.3
28.9
⫺1
J mol⫺1 K⫺1
K
⌫c
46
21.4
6.9
37.1
15.5
Description of group
Formula
⌫l
⌫c
2
⫽Ca H–
⫽Ca R–
⫽Ca R–
21.8
15.3
关16兴
17.5
8.5
关9.1兴
tertiary aromatic sp C
quaternary aromatic sp 2 C
internal quaternary aromatic C
共B兲 Group values ⌫ l and ⌫ c of various functional groups.b
Monodentate functional groups
Acyclic bidentate functional groups
J mol⫺1 K⫺1
Description of group
alcohols, phenols
fluorine
chlorine
bromine
iodines
nitrile
carboxylic acid
acid chloride
aldehyde
isocyanate
nitro group
secondary sp 3 nitrogen
primary amides
thiols
sulfonamide
substituted urea
Formula
⌫l
⌫c
–OH
–F
–Cl
–Br
–I
–CN
–CO2 H
–COCl
–共C⫽O兲H
–NCO
–NO2
–NH2
–CONH2
–SH
–SO2 NH2
–NHCONH2
53.1
16.2
30.8
34.6
39.1
47.7
87.4
关62.8兴
57.7
关58.2兴
58.6
51.0
54.4
49.0
104
82.8
23.5
关24.8兴
28.7
32.4
关27.9兴
42.3
53.1
关60.2兴
关84.5兴
关52.7兴
56.1
21.6
54.4
关51.9兴
104
82.8
Acyclic tridentate functional groups
J mol⫺1 K⫺1
Description of group
ketones
ester
ether
secondary sp 3 N
secondary amide
carbamates
sulfides
disulfides
sulfoxides
sulfones
Formula
⌫l
⌫c
–CO–
–CO2 R
–O–
–NH–
–CONH–
–OCONH–
–S–
–S–S–
–SO–
–SO2 –
51.5
63.2
29.8
关51兴
79.9
28
40.3
49.8
⫺0.3
44.4
76.1
关116兴
41
47.7
88.7
Acyclic tetradentate functional groups
J mol⫺1 K⫺1
Description of group
3
tertiary sp N
tertiary sp 2 N
phosphine oxide
Formula
⌫l
⌫c
–NR2
⫽N–
–共PO兲R–
22.0
关44.4兴
关31.5兴
10.7
28.5
Cyclic functional groups
J mol⫺1 K⫺1
Description of group
cyclic ketones
lactones
cyclic carbonates
cyclic anhydrides
cyclic ether
cyclic sec. sp 3 N
Formula
⌫l
⌫c
–(CO) c –
–CO2 –
–OCO2 –
–CO2 CO–
–Oc–
–Nc H–
关46.4兴
关67.4兴
关92兴
34.3
45.2
关68.2兴
80.3
9.7
23.9
24.6
46.0
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
40.3
关74.5兴
关83.7兴
J mol⫺1 K⫺1
Description of group
Formula
⌫l
⌫c
quaternary silicon
quaternary tin
quaternary germanium
–SiR2 –
–SnR2 –
Ge
30.9
关58.6兴
关48.1兴
32.4
关77.2兴
关18.9兴
ENTHALPIES OF VAPORIZATION
523
TABLE 2. Group values ⌫ 1 and ⌫ c for estimating C p l (298.15 K) and C p c (298.15 K)—Continued
Cyclic functional groups
J mol⫺1 K⫺1
Description of group
cyclic
cyclic
cyclic
cyclic
cyclic
cyclic
cyclic
a
3
tertiary sp N
tertiary sp 2 N
urea
sec. amide
tertiary amide
imide
sulfides
Formula
⌫l
⌫c
–Nc R–
⫽Nc –
–NHCONH–
–CONH–
–CONR–
–CONHCO–
–Sc –
28.6
20.7
1.2
13.9
63.6
46.4
52.7
74.1
20.3
关92兴
关170兴
33.8
See Ref. 19.
Values reported in brackets are tentative assignments.
b
⌬ vapH m 共 298.15 K兲 /J mol⫺1
⬇⌬ vapH m 共 T m 兲 ⫹ 关 10.58⫹0.26C p l 共 298.15 K兲兴
⫻ 共 T m ⫺298.15兲 ,
共4兲
⌬ subH m 共 298.15 K兲 /J mol⫺1
⬇⌬ subH m 共 T m 兲 ⫹ 关 0.75⫹0.15C p c 共 298.15 K兲兴
⫻ 共 T m ⫺298.15兲 ,
共5兲
⌬ fusH m 共 298.15 K兲 /J mol⫺1
The use of a thermochemical cycle is an extremely effective manner of evaluating the quality of enthalpy data associated with phase changes. It should be emphasized at the
start that internal consistency within a cycle does not guarantee that all the data are necessarily of high quality. Sublimation enthalpy is related to the sum of the fusion and vaporization enthalpies, Eq. 共7兲, provided all are referenced to
the same temperature. Vaporization enthalpy is the larger of
⌬ subH m 共 298.15 K兲 ⫽⌬ vapH m 共 298.15 K兲
⬇⌬ fusH m 共 T fus兲 ⫹ 兵 关 0.75⫹0.15C p c 共 298.15 K兲兴
⫹⌬ fusH m 共 298.15 K兲
⫻ 共 T m ⫺298.15兲 ⫺ 关 10.58⫹0.26C p l 共 298.15 K兲兴
⫻ 共 T m ⫺298.15兲 .
5. A Thermochemical Cycle: Sublimation,
Vaporization, and Fusion Enthalpies
共6兲
An uncertainty 共⫾2 ␴兲 of one third the temperature adjustment has been associated with the use of Eqs. 共5兲 and 共6兲 in
Table 4. The uncertainty has been assigned arbitrarily.
FIG. 2. A hypothetical molecule illustrating the different hydrocarbon groups
in estimating C p .
共7兲
the two enthalpies on the right hand side of the equation.
Since fusion enthalpies of solids usually decrease when adjusted to 298.15 K, the latter contributes a smaller amount to
the sublimation enthalpy, particularly if the melting point of
the material is high. Thus an accurate vaporization enthalpy
can tolerate a less accurately determined fusion enthalpy.
This is fortunate since as discussed below, there is a physical
basis for variance in fusion enthalpy.
Many solids exhibit polymorphism or undergo solid-solid
phase transitions. These may occur unnoticed. Solid-solid
phase transitions occurring below T⫽298.15 K generally do
not pose a problem if the vaporization and sublimation enthalpy measurements are conducted at temperatures above
the phase change. Enthalpic differences between polymorphic forms generally tend to be small in relation to solid-gas,
liquid-gas transitions. Since the smaller ⌬ fusH m (298.15 K)
term in Eq. 共7兲 is the one affected by polymorphism, this
phenomena should not have a large effect on the quality of
the thermochemical cycle, even if the sublimation and fusion
enthalpy measurements are conducted on different polymorphic forms. In many cases the sublimation enthalpy measured directly should compare favorably with the sum of the
fusion and vaporization enthalpy. Yet often this is not the
case.
The results given in Table 4 illustrate some of the situations that can arise when constructing a thermochemical
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
524
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 3. Some estimations of C p l (298.15 K) and C p c (298.15 K) using group values
a
See Ref. 8.
See Ref. 14.
b
cycle based on phase changes. The sublimation enthalpy of
p-nitroaniline has been measured frequently and reproducibly. The value of 共100.9⫾1.0兲 kJ mol⫺1 is the mean value of
nine measurements. Two measurements of the fusion and
vaporization enthalpy are also available. Both fusion enthalpies are in good agreement with each other; the mean value
is reported in Table 4. Comparison of the vaporization enthalpies at T⫽298.15 K results in values with a 12 kJ mol⫺1
discrepancy. In this instance the experimental sublimation
enthalpy falls halfway between the two values calculated by
Eq. 共7兲. The experimental data suggest a vaporization enthalpy of 85.5 kJ mol⫺1. This is an instance where the vaporization enthalpies are in disagreement; disagreement between
sublimation enthalpies is the more common occurrence.
Data for 1,6-hexanedioic acid represents results that are
more typical. The fusion and vaporization enthalpies have
been measured once while the sublimation enthalpy has been
reported three times. In this instance good agreement is obJ. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
served between three of the four sublimation values.
Acetanilide provides a different but similar example. The
sublimation enthalpies calculated using Eq. 共6兲 are slightly
larger than the two direct measurements. The data suggest a
vaporization enthalpy of 73.9 and a sublimation enthalpy of
90 kJ mol⫺1 at T⫽298.15 K.
The vaporization and sublimation enthalpies of
4-chlorobiphenyl have been reported a number of times. One
set of sublimation enthalpies cluster around 83 kJ mol⫺1 and
the other around 75 kJ mol⫺1. A distinction between these
two possibilities is possible by examining the vaporization
enthalpies of the isomeric 2- and 3-chlorobiphenyls 共see
Table 6兲. The vaporization enthalpies of these isomeric materials would be expected to be similar. On this basis, a vaporization of around 72 kJ mol⫺1 and a sublimation enthalpy
of approximately 83 kJ mol⫺1 for 4-chlorobiphenyl at T
⫽298.15 K is selected for 4-chlorobiphenyl.
Benzil is a case where all the available data appear to be
ENTHALPIES OF VAPORIZATION
525
TABLE 4. A comparison of experimental sublimation enthalpies and those calculated using Eq. 共6兲; enthalpies in kJ mol⫺1; C p in J mol⫺1 K⫺1 a
⌬ fusH m
(T fus)
⌬ vapH m
T fus /K (T m /K)
4-nitroaniline
21.1
420.7
C6 H10O4
1,6-hexanedioic acid
34.85
426.4
C8 H9 NO
acetanilide
21.65
387.5
C12H9 Cl
4-chlorobiphenyl
13.32
348.6
C14H10O2
C14H22O
benzil
2,6-di-t-butylphenol
23.1
16.57
368
310.7
fluoranthene
18.8
methylhexadecanoate
C6 H6 N2 O2
C16H10
C17H34O2
a
⌬ subH m
T m /K (T m )
77.9
70
92
488
430
447
64.8
66.3
71.6
66.8
59
65.9
69.2
60.4
488
402
298
368
384
466
416
401
383.3
62.3
86.2
77.4
518
495
398
68.16
307.2
69.6
82.4
82.6
71.4
302
426
393
437
55.35
305.2
T m /K
C pl
C pc
⌬ fusH m
共298 K兲
100.7
298
235.8 164.7 15.4⫾1.9
133.6
129.3
140
80.6
87.2
86
73.7
298
383
306.5
313.5
326.5
278
326
302.4 213.8
98.4
84.6
81.5
110.9
98.3
84.6
99.2
102.1
102.6
152.3
329
298
298
298
298
303
298
340
328
296
239.1 177.0
272.9 211.7
351.6 248.0
401.8 311.1
310.5 226.6
579.6 490.1
⌬ vapH m
共298 K兲
⌬ subH m
共298 K兲
关Eq. 共6兲兴
⌬ subH m
共298 K兲a
91.5⫾4.5 106.9⫾4.9 100.9
79.5⫾3.2 94.9⫾3.7
27.6⫾2.4 105.3⫾3.5 132.9⫾4.3 133.6
132.1⫾0.9
140.3⫾0.1
17.6⫾1.3 78.6⫾4.6 96.2⫾4.7 81.0⫾0.1
73.9⫾2.4 91.4⫾2.8 88.0⫾0.3
10.8⫾0.8 71.6
82.4⫾0.8 85.3⫾0.2
72.5⫾1.7 83.3⫾1.9 74.6⫾0.3
66.0⫾2.1 76.8⫾2.2
79.6⫾4.0 90.4⫾4.1
18.6⫾1.5 81.2⫾2.8 99.8⫾2.2 99.62.0
15.7⫾0.3 72.2⫾2.4 88.0⫾2.5 84.6
81.5
110.9
14.0⫾1.6 82.4⫾5.3 96.4⫾5.5 98.3
104.2⫾4.7 118.2⫾5.0 84.8⫾0.1
86.5⫾2.4 100.5⫾2.9 99.2
103.6⫾0.5
103.6⫾0.3
67.4⫾0.3 70.2⫾0.1 137.6⫾0.3 152.⫾0.1
54.7⫾0.2 103.0⫾3.1 170.6⫾3.1
97.9⫾2.3 165.3⫾2.3
93.8⫾3.3 161.2⫾3.3
125.0⫾0.2
157.8⫾3.1
152.6⫾2.3
148.5⫾3.3
See Ref. 7. ⌬ fusH m (T fus) and ⌬ vapH m (T m ) refer to the fusion and vaporization enthalpy at the melting point and mean temperaure of measurement; fusion
enthalpies are from Chickos et al.6 and Domalski and Hearing14; sublimation enthalpies from Chickos and Acree;7 vaporization enthalpies from Table 6;
uncertainties in fusion and vaporization enthalpies 共⫾2 ␴兲 are those associated with the temperature adjustment only.
internally consistent. The fusion enthalpy reported is the average of two literature values.14 Similarly with 2,6-di-tbutylphenol and fluoranthene. The sublimation enthalpies
measured directly and those calculated by Eq. 共7兲 agree
within ⫾4.0 kJ mol⫺1, which is the accuracy typical of many
experimental sublimation and vaporization enthalpy measurements.
The scatter of data obtained for methyl hexadecanoate illustrate another common situation that can arise when data
from the literature are examined. Two fusion enthalpies and
several vaporization enthalpies have been reported which are
not in particularly good agreement. Using the value of the
sublimation enthalpy as a guide, consistent results are obtained if the fusion enthalpy of 54.7 kJ mol⫺1 共298.15 K兲 is
combined with the mean of the last three vaporization enthalpies, 98.3⫾5.3 kJ mol⫺1, resulting in a sublimation enthalpy
of 152.9⫾5.4 kJ mol⫺1.
6. Estimation of Vaporization Enthalpies
Vaporization enthalpy is a property that is successfully
modeled by various computational methods. Many estimation methods in the chemical engineering literature have
been developed to provide vaporization enthalpies near or at
the boiling point and are accurate to a few %. Some require
critical constants and other parameters that may have to be
estimated themselves. A summary of some of the existing
methods and their applications can be found in the book
edited by Lyman et al.10 共see also Ref. 15兲. The estimation of
vaporization enthalpy at or near the boiling point continues
to be a topic of recurring interest.16 –23
A number of methods and equations for the estimation of
vaporization enthalpies at T⫽298.15 K have also been developed. Some model vaporization enthalpies on concepts of
group additivity while some are based on other thermodynamic principles.24 –35 Details on the application of some of
these methods in estimating vaporization enthalpies are
available.4,10,25
7. Vaporization Enthalpy Compendium
Vaporization enthalpies reported from the 1880s to 2002
are included in Tables 6 and 7. Table 5 contains a listing of
the acronyms and abbreviations that are used in both tables.
Table 6 contains vaporization enthalpy data for organic compounds; Table 7 contains similar information for a selected
number of organometallic and inorganic substances. Information in the tables is organized as described below.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
526
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 5. A list of acronyms and abbreviations used in Tables 6 and 7
A
B
BG
C
GC
GCC
CGC
DM
DSC
EB
EST
GS
HG
HSA
I
IPM
ME
MG
MM
NA
OM
RG
SG
STG
T
TE
UV
calculated from the vapor pressure data reported by the
method of least squares
calculated from the difference of the enthalpies of
sublimation at temperature T, and fusion at the melting
point
Bourdon gauge
calorimetric determination
gas chromatography
gas chromatography-calorimetry
correlation gas chromatography
diaphram manometer
differential scanning calorimeter
ebullometry
estimated value
gas saturation, transpiration
Heise gauge
head space analysis
isoteniscope
inclined piston manometry
mass effusion–Knudsen effusion
McLeod gauge
mercury manometer
not available at the time of publication
oil manometer
Rodebush gauge
spoon gauge
strain gauge
tensimeter
torsion effusion
ultraviolet absorption
Compounds are arranged according to molecular formula.
The compound’s name, occasionally a synonym, and the
CAS registry number are included on the first line. The range
of temperatures studied is the next entry in the table. For
measurements performed at a constant temperature or when
not specified, this entry is left blank. The vaporization enthalpy at the mean temperature of measurement,
⌬ vapH m (T m ), is the next entry followed by the mean temperature (T m /K), an acronym or abbreviation briefly describing the type of measurement and the reference to the
original work. In some cases the type of measurement was
not available, or recorded. In these instances this entry was
left blank. If the authors of the work have adjusted their
results to 298.15 K, then this information along with the
reference is entered on the third line. This information is
repeated for multiple measurements. The measurements are
arranged in reverse chronological order. Entries for compounds with deuterium substitution are listed after the unlabeled parent.
The authors have made an effort to present the data accurately and without error. Much of the earlier data have been
retrieved with the aid of existing compendia that have been
published over the years. Most of these compendia include
references to the original literature. A notable exception is
the very useful reference Handbook of the Thermodynamics
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
of Organic Compounds by Stephenson and Malanowski published in 1987 by Elsevier Science Publishing Co. Some of
the data included in this compendium, notably for the higher
n-alkanes and haloalkanes, appears to be data that have been
estimated.36,37 Estimated vaporization enthalpies are generally not included in Table 5 unless the data are reported in
the Stephenson and Malanowski compendium or the source
is identified. The reader should exercise some caution when
using data that are not referenced to the primary literature.
Additionally, some of the information has originated from
non-English language journals with translations occasionally
provided by the author’s students. These tables, having been
complied over a period of twenty years, have gone through
numerous revisions. Some errors have been corrected; however it is unlikely that all of them have been detected. The
reader is encouraged to consult the original literature when
using this data.
Several sources of data contains vapor pressure data represented in the form of the Antoine equation 关Eq. 共8兲兴, where
P represents the vapor pressure, T is the temperature in K,
and A, B, and C are the Antoine constants obtained from
treatment of the vapor pressure-temperature data
log10 P⫽A⫺B/ 共 C⫹T 兲 .
共8兲
Vaporization enthalpies were calculated from the Antoine
constants in one of two ways. A Lotus macro was written to
calculate vapor pressures using the Antoine constants over a
30 K temperature range; the resulting vapor pressure–
temperature data were reformulated in terms of the integrated
form of the Clausius–Clapeyron equation. A ln P versus 1/T
linear regression analysis provided ⌬ vapH m (T m )/R at the
mean temperature, T m , of the 30 K range. The 30 K temperature range was chosen closest to T⫽298.15 K but within
the temperature range specified. Alternatively, vaporization
enthalpy was calculated using the Antoine constants from the
following equation:
⌬ vapH m 共 T m 兲 ⫽2.303RB 关 T m / 共 T m ⫹C兲兴 2 .
共9兲
Temperatures were chosen to lie with the range of measurement, often at the mean temperature. In a number of instances, the authors only provide vapor pressure–
temperature data. In these instances, a vaporization enthalpy
was calculated from the data as described above.
An examination of data in Tables 6 and 7 reveals that
many compounds have been measured repeatedly. All the
data here are treated equally; there has been no attempt to
recommend or identify recommended values. A critical
evaluation of the data is beyond the scope of this compendium. However, the reader should be aware of a number of
critical reviews that are available. The IUPAC monograph,
‘‘Enthalpies of Vaporization of Organic Compounds by Majer and Svoboda12 is among the most extensive evaluations
available. Others are included in the references associated
with Tables 6 and 7. The reader is encouraged to consult
these references before deciding on the best value to use.
ENTHALPIES OF VAPORIZATION
527
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002
Molecular formula
CBrClF2
CBrCl3
CBrF3
CBrFO
CBrN
CBrN3 O6
CBr2 F2
CBr3 F
CBr4
CClFO
CClF2 NO
CClF3
CClF3 O
CClF3 O2
CClF3 O3 S
CClF3 S
CClF4 N
CClF4 NO2 S
CClF4 NO12S4
CClF7 S
CClN
CCl2 FNO
Compound
共Temperature range/K兲
bromochlorodifluoromethane
共268 –324兲
共194 –287兲
共321– 403兲
共403– 427兲
共178 –283兲
共178 –283兲
bromotrichloromethane
共273–387兲
共294 – 443兲
bromotrifluoromethane
共276 –340兲
共160–267兲
共165–216兲
carbonic bromide fluoride
共197–256兲
cyanogen bromide
共273–313兲
bromotrinitromethane
共318 –335兲
dibromodifluoromethane
共247–297兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
23.0
23.1
22.4
23.1
26.0
18.7
共283兲
共272兲
共336兲
共415兲
共193兲
共268兲
35.0
36.1
共288兲
共309兲
17.8
17.7
19.1
共291兲
共252兲
共180兲
A
A
22.9
共241兲
A
45.9
共288兲
47.8
共326兲
A
26.1
共282兲
A
共156 –218兲
18.6
共203兲
tribromofluoromethane
共315–380兲
34.4
共330兲
carbon tetrabromide
共375– 463兲
48.3
共390兲
共369– 463兲
48.2
共384兲
carbonic chloride fluoride
共165–211兲
22.7
共196兲
共157–227兲
22.0
共192兲
difluorocarbamoyl chloride
共189–234兲
25.8
共219兲
chlorotrifluoromethane
共268 –302兲
16.0
共283兲
共133–185兲
17.0
共170兲
共184 –246兲
15.7
共231兲
共243–271兲
15.7
共257兲
共145–192兲
16.8
共177兲
共124 –191兲
17.1
共177兲
共134 –298兲
NA
trifluoromethyl hypochlorite
共160–226兲
21.2
共211兲
共142–219兲
19.6
共204兲
peroxyhypochlorous acid, trifluoromethyl ester
共163–296兲
23.4
共281兲
fluorosulfuric acid, chlorodifluoromethyl ester
共227–309兲
32.1
共243兲
共228 –310兲
34.6
共243兲
trifluoromethanesulfenyl chloride
共247–272兲
24.5
共260兲
difluoro共difluorochloromethyl兲amine
共209–277兲
26.6
共262兲
chloro共trifluoromethyl兲 sulfamoyl fluoride
共253–288兲
28.8
共273兲
fluorosulfuric acid, bis关关共flurosulfȯnyl兲oxy兴amino兴chloromethylene ester
42.6
共424兲
chlorotetrafluoro 共trifluoromethyl兲 sulfur
共293–353兲
25.9
共323兲
cyanogen chloride
共196 –286兲
32.2
共271兲
dichlorocarbamic fluoride
40.7
Method
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
CAS registry number
Reference
关353-59-3兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关79/12兴
关60/16兴关84/9兴
关75-62-7兴
关79/12兴
关87/5兴关70/16兴
关75-63-8兴
关87/5兴
关87/5兴
关79/12兴
关753-56-0兴
关87/5兴
关506-68-3兴
关54/14兴关84/9兴
关560-95-2兴
关87/5兴关70/10兴
关75-61-6兴
关87/5兴关59/1兴
关79/12兴关70/16兴
关48/7兴
关353-54-8兴
关87/5兴关48/7兴
关558-13-4兴
关79/12兴
关87/5兴关47/5兴
关353-49-1兴
关87/5兴关64/3兴
关48/17兴
关16847-30-6兴
关87/5兴
关75-72-9兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴关79/12兴
关47/5兴
关41/13兴
关22082-78-6兴
关87/5兴
关87/5兴
关32755-26-3兴
关87/5兴
关6069-31-4兴
关99/16兴
关87/5兴关66/15兴
关421-17-0兴
关87/5兴关99/16兴
关13880-71-2兴
关87/5兴
关19419-95-5兴
关87/5兴关99/16兴
关53684-03-0兴
关75/21兴
关42179-04-4兴
关99/16兴
关506-77-4兴
关47/5兴
关32751-02-3兴
关72/40兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
528
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
CCl2 F2
CCl2 F3 N
CCl2 F3 N
CCl2 F3 N
CCl2 F3 NS
CCl2 F3 P
CCl2 F3 PS
CCl2 O
CCl3 F
CCl3 F2 N
CCl3 F2 N
CCl3 F2 P
CCl3 NO
CCl3 NO2
CCl4
CFIO
CFN
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
dichlorodifluoromethane
共282–345兲
20.0
共173–244兲
21.4
共173–240兲
21.6
共236 –285兲
20.4
共341–385兲
20.5
共172–279兲
22.9
共154 –243兲
21.5
N,N-difluoro-1,1-dichloro-1-fluoromethylamine
共209–277兲
27.0
N,N-dichloro-1,1,1-trifluoromethylamine
共226 –291兲
25.8
N,1-dichloro-N,1,1-trifluoromethylamine
共226 –291兲
26.4
共trifluoromethyl兲imidosulfurous dichloride
共284 –344兲
35.4
共283–362兲
33.7
共trifluoromethyl兲dichlorophosphine
共208 –276兲
29.2
dichloro共trifluoromethylthio兲phosphine
共293–363兲
31.7
Mean temperature
(T m /K)
Method
共297兲
共229兲
共225兲
共270兲
共356兲
共187兲
共228兲
A
A
A
A
A
共262兲
I
共276兲
A
共258兲
共298兲
共298兲
A
共260兲
共308兲
A
24.5
25.7
24.5
24.4
27.0
25.8
共295兲
共266兲
共353兲
共421兲
共233兲
共258兲
A
A
A
A
28.5
28.2
25.6
24.7
25.1
27.3
27.1
25.2
共244 –334兲
26.4
N,N-difluoro-1,1,1-trichloromethylamine
共252–325兲
33.4
N,1,1-trichloro-N,1-difluoromethylamine
共273–319兲
27.8
difluoro共trichloromethyl兲phosphine
共289–313兲
32.5
trichloronitrosomethane
共253–333兲
32.4
trichloronitromethane
共273–333兲
39.3
共301– 449兲
38.5
共247–385兲
40.0
carbon tetrachloride
共349– 416兲
30.4
共412– 497兲
29.2
共494 –555兲
30.6
32.4
共262–349兲
33.7
共293–351兲
32.3
共313–338兲
31.7
carbonyl fluoride iodide
共230–292兲
26.1
cyanogen fluoride
共201–227兲
22.4
共228兲
共234兲
共310兲
共372兲
共439兲
共251兲
共276兲
共290兲
共259兲
A
A
A
A
A
共267兲
I
phosgene
共280–341兲
共240–281兲
共338 – 410兲
共406 – 455兲
共215–248兲
共180–273兲
trichlorofluoromethane
共213–301兲
共213–249兲
共295–363兲
共357– 429兲
共424 – 468兲
共237–293兲
共237–293兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
共296兲
共301兲
A
共268兲
A
共288兲
共316兲
共262兲
A
A
共364兲
共427兲
共509兲
共298兲
共277兲
共308兲
共325兲
A
A
A
C
A, EB
共277兲
A
共214兲
A
CAS registry number
Reference
关75-71-8兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关79/12兴
关47/5兴
关70/15兴
关13880-73-4兴
关87/5兴
关71/17兴
关10564-47-3兴
关99/16兴
关87/5兴
关421-58-9兴
关64/4兴
关18799-78-5兴
关87/5兴关99/16兴
关60/25兴
关75-44-5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关48/2兴
关47/5兴
关75-69-4兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关79/12兴
关41/4兴
关41/4兴
关40/1兴
关87/5兴关70/15兴
关71/17兴
关1112-03-4兴
关87/5兴
关3711-49-7兴
关87/5兴
关76-06-2兴
关87/5兴
关87/5兴关70/16兴
关47/5兴
关56-23-5兴
关87/5兴
关87/5兴
关87/5兴
关80/1兴
关87/5兴关72/6兴
关59/2兴
关53/1兴
关87/5兴
关1495-50-7兴
关87/5兴关64/25兴
关70/16兴
ENTHALPIES OF VAPORIZATION
529
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
CFNO3 S
CFNO6 S2
CFN3 O6
CF2 N2 OS
CF2 N2 O4
CF2 N2 S
CF2 O
CF2 O4 S
CF2 S
CF3 I
CF3 NO
CF3 NO
CF3 NOS
CF3 NOS
CF3 NOS
CF3 NO2
CF3 NO4
CF3 NO6 S2
CF4
CF4 N2 O
CF4 N2 O3 S2
CF4 O
CF4 OS
CF4 O2
CF4 O2 S
CF4 O2 S
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
36.5
共309兲
A
40.9
共345兲
A
34.2
共289兲
A, T
37.2
共277兲
A
41.4
共296兲
A
44.1
共286兲
A
20.0
共174兲
A
27.3
共281兲
A
19.2
17.4
共196兲
共196兲
A
A
22.5
共281兲
A
sulfuryl fluoride isocyanate
共294 –335兲
pyrosulfuryl fluoride isocyanate
共330– 405兲
fluorotrinitromethane
共274 –358兲
cyanoimidosulfuryl
fluoride
共262–354兲
difluorodinitromethane
共283–310兲
N-cyano-S,S-difluorosulfilimine
共271–320兲
carbonyl fluoride
共159–189兲
fluoroformyl fluorosulfate
共250–296兲
thiocarbonyl fluoride
共133–211兲
共178 –211兲
iodotrifluoromethane
共188 –296兲
共difluoroamino兲 carbonyl fluoride
共143–217兲
21.6
共202兲
A, MM
trifluoronitrosomethane
共141–174兲
17.1
共159兲
A
S,S,-difluoro-N-共fluoroformyl兲-sulfimine
共220–323兲
37.3
共235兲
A
trifluoromethyl thionitrite
共196 –215兲
25.8
共205兲
T
共N-sulfinyl兲-trifluoromethylamine
共239–289兲
27.0
共274兲
A
trifluoronitromethane
共238 –243兲
21.6
共240兲
A
共trifluoromethyl兲 peroxynitrate
共193–247兲
24.8
共232兲
A
N-共fluoroformyl兲-N,O-bis共fluorosulfonyl兲 hydroxylamine
共325–392兲
36.3
共340兲
A
carbon tetrafluoride
共195–227兲
12.1
共212兲
A
共89–163兲
12.3
共148兲
A
共160–197兲
11.9
共182兲
A
共116 –146兲
12.4
共131兲
共93–146兲
12.8
共131兲
fluoro共trifluoromethyl兲 diimidoxide
共233–267兲
27.7
共252兲
A
carbonylbis共imidosulfuryl fluoride兲
共316 –331兲
41.3
共323兲
A
hypofluorous acid trifluoromethyl ester
共153–194兲
15.5
共179兲
A
关Note: The table in Ref. 关48/1兴 gives the temperatures in °C; however, all of the equations and
graphs in the article suggest that the temperature should be in Kelvin. We have assumed that the
tabulated temperatures are in Kelvin; the results closely correspond to the entry in Ref. 关87/5兴.兴
trifluoromethyl sulfinyl fluoride
共204 –271兲
22.7
共256兲
A, I
hydroperoxyfluoric acid trifluoromethyl
共156 –203兲
trifluoromethane sulfonyl fluoride
共226 –249兲
trifluoromethyl fluorosulfonate
共194 –269兲
ester
18.7
共188兲
A
23.4
共237兲
A
25.6
共231兲
CAS registry number
Reference
关1495-51-8兴
关87/5兴关99/16兴
关27931-74-4兴
关87/5兴关99/16兴
关1840-42-2兴
关87/5兴关66/13兴
关19073-57-5兴
关87/5兴关99/16兴
关1185-11-1兴
关87/5兴关73/25兴
关14453-41-9兴
关87/5兴关99/16兴
关353-50-4兴
关87/5兴
关7519-54-2兴
关87/5兴关99/16兴
关420-32-6兴
关87/5兴关70/16兴
关87/5兴关99/16兴
关62/33兴
关2314-97-8兴
关87/5兴关70/16兴
关48/7兴
关2368-32-3兴
关87/5兴关65/23兴
关334-99-6兴
关87/5兴
关3855-41-2兴
关87/5兴关99/16兴
关69/32兴
关10564-49-5兴
关87/5兴关99/16兴
关335-02-4兴
关87/5兴
关50311-48-3兴
关87/5兴
关19252-48-3兴
关87/5兴关99/16兴
关75-73-0兴
关87/5兴
关87/5兴
关87/5兴
关69/6兴
关33/1兴关87/5兴
关815-10-1兴
关87/5兴
关25523-80-2兴
关87/5兴关99/16兴
关373-91-1兴
关87/5兴关48/1兴
关812-12-4兴
关87/5兴关68/15兴
关70/16兴关99/16兴
关34511-13-2兴
关87/5兴
关335-05-7兴
关87/5兴关99/16兴
关60/15兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
530
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
CF4 O4 S
CF4 O5 S2
CF4 O6 S2
CF5 NO
CF5 OPS
CF5 OPS
CF5 O3 P
CF5 O3 P
CF5 PS
CF6 N2 O2 S2
CF6 N2 S2
CF6 PS
CF8 OS
CF8 S
CF9 NOS
CF10O5 S2
CIN
CN4 O8
Compound
共Temperature range/K兲
COS
CO2
CS2
Mean temperature
(T m /K)
trifluoromethylperoxyfluorosulfonate
共233–286兲
27.7
fluorosulfonic acid trifluoromethane sulfonic acid anhydride
共308 –338兲
32.9
trifluoromethyl fluorodisulfate
共292–351兲
34.4
pentafluoromethoxyamine
共167–210兲
18.5
phosphorothionic difluoride, S-trifluoromethyl ester
共293–353兲
23.1
trifluoromethylthiosphoryl difluoride
23.0
trifluoromethoxyphosphoryl difluoride
共225–264兲
27.4
difluoroperoxyphosphoric acid trifluoromethyl ester
共241–280兲
32.0
trifluoromethyl thiodifluorophosphine
24.3
N,N⬘-共difluoromethylene兲bisimidosulfuryl fluoride
共283–308兲
36.0
difluoromethane bis共S,S-difluorosulfilimine兲
共230–313兲
36.0
difluoro共trifluoromethylthio兲phosphine
共293–353兲
22.3
pentafluoro共trifluoromethoxy兲 sulfur
共217–262兲
24.4
trifluoro共pentafluorothio兲methane
共223–252兲
20.2
共205–262兲
23.8
tetrafluoro共difluoroamino兲共trifluoromethoxy兲 sulfur
共257–298兲
28.7
关␮-共carbonodiperoxato兲兴decafluoro disulfur
38.1
cyanogen iodide
共419– 426兲
40.0
共298 – 414兲
58.3
tetranitromethane
共286 –373兲
43.1
共313–373兲
42.9
共273–313兲
CO
⌬ vapH m
共kJ mol⫺1兲
carbon monoxide
共68 –108兲
共69– 83兲
carbonyl sulfide
共161–284兲
共284 –379兲
共140–224兲
共162–224兲
carbon dioxide
共273–304兲
共216 –273兲
共267–303兲
共179–198兲
carbon disulfide
共255–354兲
共354 –552兲
共260–353兲
共338 – 408兲
共388 – 497兲
共490–533兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
A
关60/15兴
关21595-44-8兴
关87/5兴关99/16兴
共259兲
共323兲
共321兲
共195兲
A
共323兲
关60/15兴
关4217-93-0兴
关87/5兴关65/19兴
关52752-66-6兴
关99/16兴
关74/38兴
共245兲
共265兲
A
共295兲
共245兲
A
共323兲
共247兲
A
共253兲
共247兲
I
A
共272兲
A
共423兲
共313兲
A
共301兲
共328兲
A
A
46.6
共288兲
6.0
6.0
6.0
共93兲
共81兲
共81兲
20.4
18.3
19.5
19.0⫾0.1
19.5
共176兲
共299兲
共209兲
共214兲
共209兲
16.7
16.4
16.5
25.9
共288兲
共258兲
共282兲
共188兲
28.7
27.1
28.5
27.4
27.0
28.7
共270兲
共369兲
共275兲
共353兲
共403兲
共505兲
A
C
A
A
A
A
A
A
A
关73/37兴
关39125-42-3兴
关87/5兴关73/37兴
关74/38兴
关20094-83-1兴
关68/21兴
关17686-45-2兴
关87/5兴关99/16兴
关52752-65-5兴
关99/16兴
关1873-23-0兴
关87/5兴关64/18兴
关373-80-8兴
关01/22兴
关87/5兴关99/16兴
关87/5兴关64/19兴
关60672-59-5兴
关76/31兴
关506-78-5兴
关87/5兴
关47/5兴
关509-14-8兴
关87/5兴
关87/5兴关84/9兴
关52/15兴
关87/5兴关84/9兴
关49/19兴
关630-08-0兴
关87/5兴
关32/3兴
关32/3兴
关463-58-1兴
关99/16兴
关99/16兴
关87/5兴
关39/5兴
关37/2兴
关124-38-9兴
关87/5兴
关87/5兴
关72/6兴
关56/1兴
关75-15-0兴
关99/16兴
关99/16兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
ENTHALPIES OF VAPORIZATION
531
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共255–318兲
共277–353兲
CHBrF2
CHBr3
CHClF2
CHCl2 F
CHCl2 FO3 S
CHCl3
CHFI2
CHFN2 O4
CHFO
CHF2 I
CHF3
CHF3 O2
CHF3 O3 S
CHF3 S
共303–358兲
bromodifluoromethane
共194 –259兲
共194 –288兲
tribromomethane
共320– 412兲
共303–373兲
chlorodifluoromethane
共275–327兲
共170–233兲
共230–275兲
共324 –366兲
共194 –310兲
共229–236兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
28.7
28.1
28.1⫾0.1
27.5⫾0.1
26.7⫾0.1
27.7
27.6
共270兲
共292兲
共282兲
共298兲
共319兲
共298兲
共318兲
EB
EB
C
C
C
24.0
24.7
共244兲
共209兲
A
46.1⫾0.1
42.3
44.0
共298兲
共335兲
共318兲
C
EB
20.0
21.3
20.4
20.1
21.8
21.0
20.2
共290兲
共218兲
共260兲
共339兲
共209兲
共232兲
共232兲
A
A
A
A
共267兲
共294兲
共356兲
共412兲
共233兲
共267兲
共259兲
A
A
A
A
共284兲
A
dichlorofluoromethane
共225–282兲
26.1
共279–344兲
25.3
共341–399兲
24.2
共397– 450兲
24.1
共229–236兲
U20.9
共181–282兲
26.2
共244 –317兲
36.7
fluorosulfuric acid, dichloromethyl ester
共275–293兲
36.2
chloroform
共306 – 427兲
30.8
共227–269兲
31.8
共333– 416兲
30.4
共410– 481兲
28.9
共479–523兲
30.1
31.1
共260–333兲
32.5
共215–334兲
35.0
共308 –333兲
30.9
diiodofluoromethane
共299–332兲
32.9
fluorodinitromethane
共298 –338兲
formyl fluoride
共178 –235兲
difluoroiodomethane
共227–287兲
trifluoromethane
共138 –190兲
共198 –298兲
共146 –192兲
trifluoromethyl hydroperoxide
共248 –285兲
trifluoromethylsulfonic
acid
共354 – 435兲
trifluoromethanethiol
共167–236兲
共321兲
共254兲
共348兲
共425兲
共494兲
共298兲
共275兲
共230兲
共320兲
Method
C
A
A
A
A
C
EB
共314兲
A
43.6
共313兲
A
24.4
共220兲
A
26.0
共272兲
A
18.1
16.8
18.0
共175兲
共213兲
共177兲
A
A
30.9
共270兲
A
47.7
共369兲
A
21.8
共183兲
CAS registry number
Reference
关72/6兴关87/5兴
关62/2兴
关62/2兴
关62/2兴
关62/2兴
关61/25兴
关46/4兴
关1511-62-2兴
关87/5兴
关79/12兴
关75-25-2兴
关72/41兴
关72/6兴关79/12兴
关41/7兴关84/9兴
关75-45-6兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关79/12兴
关64/2兴
关57/18兴
关75-43-4兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关64/2兴
关47/5兴
关40/1兴
关42016-50-2兴
关87/5兴关99/16兴
关67-66-3兴
关95/16兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关80/1兴
关72/6兴
关47/5兴
关38/5兴
关1493-01-2兴
关87/5兴关79/12兴
关70/16兴
关7182-87-8兴
关87/5兴
关1493-02-3兴
关87/5兴关64/3兴
关70/16兴
关1493-03-4兴
关87/5兴关79/12兴
关70/16兴
关75-46-7兴
关87/5兴
关87/5兴
关62/1兴
关16156-36-8兴
关87/5兴
关1493-13-6兴
关87/5兴关99/16兴
关1493-15-8兴
关99/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
532
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
CHF7 S
CHN
CDN
CHNO
CHNS
CHN3 O6
CH2 BrCl
CH2 Br2
Compound
共Temperature range/K兲
共167–236兲
共difluoromethyl兲 sulfur pentafluoride
共221–292兲
共221–293兲
hydrogen cyanide
共259–299兲
共298 – 457兲
共257–315兲
共259–294兲
共257–319兲
共265–300兲
共256 –319兲
deuterium cyanide
共182–282兲
共265–293兲
cyanic acid
共233–268兲
共197–267兲
thiocyanic acid
共278 –396兲
trinitromethane
共290–317兲
bromochloromethane
共226 –341兲
共289–341兲
dibromomethane
共273–373兲
共290– 409兲
CH2 ClF
CH2 Cl2
共238 –371兲
chlorofluoromethane
共140–264兲
dichloromethane
共311–383兲
共264 –311兲
共303–313兲
共233–313兲
CH2 F2
CH2 F3 NS
CH2 I2
CH2 O
CH2 O2
共186 –312兲
difluoromethane
共256 –321兲
共191–222兲
共191–258兲
共316 –351兲
共191–221兲
共191–242兲
1,1,1-trifluoromethanesulfenamide
共218 –291兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
21.0
共221兲
A
27.5
25.6
共237兲
共278兲
A
28.1
27.8
28.1
28.0
28.1
27.8
27.2
共274兲
共313兲
共272兲
共277兲
共272兲
共282兲
共303兲
26.2
27.6
共267兲
共279兲
30.7
NA
共253兲
A
28.0
共293兲
A
32.6
共303兲
A
42.0
33.5
共241兲
共304兲
A
37.0⫾0.1
36.5
37.2
共298兲
共288兲
共305兲
C
37.8
共253兲
23.3
共249兲
A
30.6⫾0.1
29.0
28.8
30.3
29.2
30.2
NA
29.4
共298兲
共326兲
共298兲
共279兲
共308兲
共248兲
C
A
C
EB
19.9
21.2
20.3
20.3
21.2
20.6
共271兲
共207兲
共243兲
共331兲
共206兲
共227兲
A
A
A
A
34.1
共276兲
A
45.6
49.0
48.8
45.4
共298兲
共298兲
共307兲
共371兲
GC
C
24.3
24.2
共236兲
共236兲
A
35.2
36.0
20.1⫾0.1
共315兲
共298兲
共298兲
EB
A
C
A
A
MM
A, EST
diiodomethane
共293– 455兲
共356 –505兲
formaldehyde
共184 –251兲
共173–251兲
formic acid
共300–392兲
共283–384兲
monomer
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
CAS registry number
Reference
关87/5兴关99/16兴
关420-67-7兴
关99/16兴
关87/5兴关99/16兴
关74-90-8兴
关87/5兴
关87/5兴
关75/10兴
关34/5兴
关26/1兴
关26/8兴
关26/9兴
关3017-23-0兴
关47/5兴
关34/5兴
关420-05-3兴
关87/5兴
关38/2兴
关463-56-9兴
关87/5兴
关517-25-9兴
关87/5兴关67/25兴
关74-95-7兴
关87/5兴
关59/1兴关79/12兴
关74-95-3兴
关72/41兴
关79/12兴
关87/5兴关56/16兴
关70/16兴
关47/5兴
关593-70-4兴
关87/5兴关70/16兴
关75-09-2兴
关89/10兴
关87/5兴
关80/1兴
关72/6兴
关60/3兴
关48/5兴
关46/17兴
关27/2兴
关75-10-5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关68/5兴
关68/5兴
关1512-33-0兴
关87/5兴关99/16兴
关60/24兴
关75-11-6兴
关94/19兴
关87/4兴
关79/12兴
关87/5兴关70/16兴
关50-00-0兴
关87/5兴
关35/1兴关87/5兴
关64-18-6兴
关87/9兴
关87/5兴
关70/8兴
ENTHALPIES OF VAPORIZATION
533
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共310–374兲
共273–373兲
共273–373兲
CH3 Br
CH3 Cl
CH3 Cl2 P
CH3 F
CH3 F2 N
CH3 F2 NS
CH3 F2 P
CH3 F2 OPS
CH3 F2 PS2
CH3 F4 NP2 S2
CH3 I
CH3 NO
CH3 NOS
CH3 NO2
共273–307兲
共295–374兲
methyl bromide
共223–278兲
共201–296兲
共203–277兲
共203–278兲
methyl chloride
共247–310兲
共368 – 416兲
共308 –373兲
共198 –278兲
共183–250兲
共191–249兲
共192–249兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
46.3⫾0.5
35.2
19.9
29.6
20.3
20.9
20.4
21.1
36.8
47.7
共298兲
共325兲
共298兲
共303兲
共315兲
共338兲
共315兲
共338兲
共288兲
共374兲
25.8
24.6
25.2
25.3
共238兲
共281兲
共262兲
共263兲
22.0
21.8
21.0
22.0
22.7
23.5
22.6
20.1
共262兲
共383兲
共323兲
共263兲
共235兲
共206兲
共234兲
共293兲
A
A
A
Method
C
C
C
A, EST
C
dichloromethyl phosphine
共229–297兲
methyl fluoride
共205–242兲
共240–288兲
共141–208兲
35.5
共282兲
A
16.9
16.9
17.1
共227兲
共273兲
共193兲
A
A
A, EST
共165–217兲
16.4
共202兲
共170–197兲
17.7
共183兲
A
23.5
22.9
共242兲
共257兲
A
N,N-difluoromethylamine
共203–257兲
methylimidosulfurous difluoride
共194 –258兲
28.7
共194 –258兲
28.6
difluoromethyl phosphine
共174 –236兲
23.4
difluorothiophosphoric, S-methyl ester
共236 –298兲
31.2
difluorodithiophosphoric acid, methyl ester
共253–298兲
39.0
N,N-bis共difluorothiophosphoryl兲 N-methylamine
共273–325兲
38.7
methyl iodide
共228 –337兲
30.4
共315–502兲
26.5
共208 –227兲
31.1
共259–314兲
29.2
共218 –315兲
30.4
共273–307兲
28.2
formamide
共293–377兲
70.8
共415– 466兲
61.2
60.2
共343– 483兲
64.0
N-sulfinyl methanamine
共252–277兲
31.8
methyl nitrite
共226兲
共243兲
A
共221兲
A
共251兲
A
共268兲
A
共288兲
A
共243兲
共330兲
共217兲
共274兲
共233兲
共288兲
A
A
EB
共308兲
共430兲
共298兲
共358兲
A
A
A
共264兲
A
CAS registry number
Reference
关70/8兴
关49/1兴
关41/10兴
关34/8兴
关30/8兴
关30/8兴
关30/8兴
关30/8兴
关1894/1兴
关1883/1兴
关74-83-9兴
关79/12兴
关87/5兴关61/13兴
关47/1兴
关38/3兴
关74-87-31兴
关87/5兴
关87/5兴
关87/5兴
关48/5兴
关47/1兴
关46/4兴
关40/2兴
关26/6兴
关676-83-5兴
关87/5兴关63/29兴
关593-53-3兴
关87/5兴
关87/5兴
关87/5兴关61/13兴
关70/16兴
关87/5兴关48/15兴
关84/9兴
关87/5兴关19/1兴
关84/9兴
关753-58-2兴
关87/5兴
关60/19兴
关758-20-3兴
关99/16兴
关87/5兴关99/16兴
关753-59-3兴
关87/5兴
关25237-37-0兴
关87/5兴关99/16兴
关21348-13-0兴
关87/5兴关99/16兴
关25741-62-2兴
关87/5兴关99/16兴
关74-88-4兴
关87/5兴
关87/5兴
关82/17兴
关72/6兴关79/12兴
关47/5兴
关36/2兴
关75-12-7兴
关87/5兴
关87/5兴
关85/7兴关85/6兴
关47/5兴
关4291-05-8兴
关87/5兴关99/16兴
关624-91-9兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
534
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共218 –273兲
共154 –225兲
CH3 NO2
CH3 NO3
CH4
CH4 F2 NPS
CH4 N2
CH4 N2
CH4 N2 O2
CH4 O
nitromethane
共313–353兲
共405– 476兲
共328 – 410兲
methyl nitrate
共273–303兲
methane
共90–120兲
共115–149兲
共148 –189兲
共91–127兲
共91–190兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
22.1
26.2
22.6⫾0.2
共258兲
共190兲
A
37.2
35.2
36.8
37.2⫾0.1
36.3⫾0.1
35.2⫾0.1
34.0⫾0.1
38.3⫾0.1
共298兲
共420兲
共343兲
共318兲
共335兲
共353兲
共374兲
共298兲
CGC
A
A
C
C
C
C
C
34.8
共288兲
A
共105兲
共134兲
共174兲
共112兲
共175兲
共137兲
共175兲
共112兲
共130兲
共160兲
共180兲
共149兲
共99兲
共101兲
A
A
A
共288兲
A
8.6
8.4
8.7
8.6
8.5
8.1
共100–190兲
8.6
8.2
7.5
5.9
4.0
共109–189兲
8.5
8.5⫾0.1
共92–110兲
8.6
difluorothiophosphoric acid, N-methylamide
共273–325兲
39.1
ammonium cyanide
共222–305兲
47.1
methyl diazene
共195–236兲
27.5
ammonium carbamate
共247–331兲
54.1
methanol
34.3
共175–273兲
39.2
共338 – 487兲
36.9
共188 –228兲
43.7
共224 –290兲
38.9
共285–345兲
38.3
共335–376兲
37.0
共373– 458兲
36.1
共453–513兲
35.1
32.7
28.1
20.6
7.4
共316 –336兲
37.5
共243–303兲
37.8
共288 –337兲
38.3
共337–383兲
37.0
37.4⫾0.1
36.7⫾0.1
36.2⫾0.1
35.6⫾0.1
35.3⫾0.1
34.7⫾0.1
35.2⫾0.1
35.6⫾0.1
36.2⫾0.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
C
C
C
C
共237兲
共221兲
A
共262兲
共258兲
共353兲
共213兲
共275兲
共300兲
共350兲
共388兲
共468兲
共373兲
共423兲
共473兲
共510兲
共331兲
共298兲
共303兲
共352兲
共298兲
共313兲
共323兲
共333兲
共338兲
共343兲
共338兲
共331兲
共321兲
A
A
A
A
A
A
A
A
C
C
C
C
EB
C
C
C
C
C
C
C
C
C
CAS registry number
Reference
关87/5兴
关82/2兴
关58/19兴
关75-52-2兴
关95/21兴
关87/5兴关67/12兴
关87/5兴关54/2兴
关54/2兴
关54/2兴
关54/2兴
关54/2兴
关47/11兴
关598-58-3兴
关87/5兴
关74-82-8兴
关87/5兴
关87/5兴
关87/5兴
关72/5兴关84/9兴
关72/5兴
关71/28兴
关70/4兴
关61/31兴
关61/31兴
关61/31兴
关61/31兴
关61/31兴
关39/5兴
关21/1兴关84/9兴
关31411-30-0兴
关87/5兴关99/16兴
关12211-52-8兴
关47/5兴
关26981-93-1兴
关87/5兴
关47/5兴
关67-56-1兴
关99/32兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关86/17兴
关86/17兴
关86/17兴
关86/17兴
关84/26兴
关83/14兴
关74/9兴关84/9兴
关73/26兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/3兴
关73/3兴
关73/3兴
ENTHALPIES OF VAPORIZATION
535
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共275–336兲
共288 –357兲
共353– 483兲
CH4 O2
CH4 O3 S
CH4 S
CH5 N
CH5 NO
CH5 NO
CH6 ClN
CH6 N2
C2 BrCl2 F3 O4
C2 BrCl3 O
C2 BrF3
C2 BrF5 O3 S
C2 BrF9 S
C2 Br2 ClF3
C2 Br2 F4
C2 ClFN2
共278 –323兲
methyl hydroperoxide
共253–313兲
methanesulfonic acid
共395– 440兲
methyl mercaptan
共208 –298兲
共267–359兲
共221–283兲
共345– 424兲
共414 – 470兲
共222–279兲
methylamine
共319–381兲
共373– 430兲
共263–329兲
共223–273兲
共190–267兲
N-methylhydroxylamine
共293–338兲
共313–338兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
37.0⫾0.1
38.7
37.43⫾0.02
38.3
36.3
37.3⫾0.1
37.7⫾0.1
38.4
共306兲
共290兲
共298兲
共303兲
共368兲
共298兲
共298兲
共293兲
C
EB
C
EB
37.7
共268兲
A
73.9
共410兲
A
27.2
25.2
25.7
23.7
24.2
23.8
25.8
共223兲
共359兲
共268兲
共360兲
共429兲
共298兲
共264兲
24.8
23.5
26.1
27.2
27.4
共334兲
共388兲
共278兲
共258兲
共252兲
A
A
A
A
49.7
49.3
共308兲
共325兲
A
A
共243兲
共225兲
A
共533兲
A
共286兲
A
共283兲
A
共280兲
A
共275兲
A
O-methylhydroxylamine
共228 –322兲
36.9
共210–321兲
38.0
methylamine hydrochloride
共518 –593兲
114.5
methylhydrazine
共274 –299兲
41.8
perchloric acid, 1,2,2-trifluoro-1-chloro-2-bromoethyl ester
共273–294兲
42.5
trichloroacetyl bromide
共265– 416兲
42.6
bromotrifluoroethylene
共260–340兲
25.0
2-bromotetrafluoroethyl fluorosulfate
共273–298兲
33.2
pentafluoro共1-bromo-1,2,2,2-tetrafluoroethyl兲 sulfur
共294 –330兲
30.7
2-chloro-1,2-dibromo-1,1,2-trifluoroethane
共343– 428兲
31.4
35.0⫾0.1
34.2⫾0.1
33.5⫾0.1
32.6⫾0.1
31.6⫾0.1
1,2-dibromotetrafluoroethane
共283–357兲
28.5
共354 – 443兲
26.9
共440– 488兲
27.1
28.4⫾0.1
27.5⫾0.1
26.5⫾0.1
共246 –295兲
30.0
cis chloro共fluoroimino兲acetonitrile
共254 –320兲
31.7
Method
C
C
A
A
A
A
共285兲
共309兲
A
共358兲
共298兲
共313兲
共328兲
共343兲
共358兲
A
C
C
C
C
C
共298兲
共369兲
共455兲
共298兲
共313兲
共328兲
共280兲
A
A
A
C
C
C
共269兲
A
CAS registry number
Reference
关73/3兴
关72/6兴关87/5兴
关71/27兴
关70/2兴
关67/38兴
关66/2兴
关63/2兴
关60/5兴
关3031-73-0兴
关87/5兴关51/10兴
关75-75-2兴
关87/5兴关99/16兴
关74-93-1兴
关99/16兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关87/5兴关42/1兴
关74-89-5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴关70/16兴
关37/10兴关84/9兴
关593-77-1兴
关87/5兴关70/16兴
关87/5兴关57/4兴
关84/9兴
关67-62-9兴
关87/5兴
关57/4兴关84/9兴
关593-51-1兴
关87/5兴
关60-33-4兴
关87/5兴关51/1兴
关38217-36-6兴
关87/5兴关73/19兴
关34069-94-8兴
关87/5兴关47/5兴
关598-73-2兴
关87/5兴
关63/17兴
关63011-81-4兴
关87/5兴关99/16兴
关354-51-8兴
关87/5兴
关81/13兴
关81/13兴
关81/13兴
关81/13兴
关81/13兴
关124-73-2兴
关87/5兴
关87/5兴
关87/5兴
关81/13兴
关81/13兴
关81/13兴
关87/5兴关70/16兴
关30915-40-3兴
关87/5兴关71/19兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
536
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 ClFN2
C2 ClF2 NO2
C2 ClF3
C2 ClF3 O2
C2 ClF3 O4 S
C2 ClF4 NO
C2 ClF4 NO4 S
C2 ClF5
C2 ClF5 O
C2 ClF5 OS
C2 ClF5 O3 S
C2 ClF5 O6 S2
C2 ClF6 NOS
C2 ClF6 P
C2 ClF6 PS2
C2 ClF9 NP
C2 ClF9 S
C2 Cl2 F2
C2 Cl2 F2 N2
C2 Cl2 F2 O
C2 Cl2 F3 NO
C2 Cl2 F3 NOS
C2 Cl2 F3 NO2 S
C2 Cl2 F4
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
trans chloro共fluoroimino兲acetonitrile
共257–320兲
32.7
chloro共fluorocarbonyl兲carbamic fluoride
36.8
chlorotrifluoroethylene
共206 –262兲
21.8
共298 –379兲
20.2
共206 –263兲
21.7
共195–250兲
21.9
chloroformic acid, trifluoromethyl ester
共195–273兲
24.1
difluorochloroacetic acid, fluorosulfuric acid anhydride
共265–352兲
39.8
Mean temperature
(T m /K)
Method
共272兲
A
共376兲
共247兲
共313兲
共248兲
共235兲
A
A
共258兲
A
共280兲
A
chloro共trifluoromethyl兲carbamic fluoride
28.9
共310兲
fluorosulfuric acid, chloro共trifluoromethyl兲carbamic acid anhydride
28.5
共398兲
chloropentafluoroethane
共262–317兲
19.7
共277兲
共234 –265兲
20.1
共250兲
共312–353兲
19.7
共327兲
共178 –234兲
20.9
共219兲
共176 –235兲
20.9
共220兲
19.4⫾0.1
共234兲
hypochlorous acid, pentafluoroethyl ester
共193–248兲
25.0
共233兲
pentafluoroethanesulfinyl chloride
共273–338兲
32.7
共288兲
2-chlorotetrafluoroethyl fluorosulfate
共248 –330兲
32.9
1,2,2-trifluoro-1-chloro-1,2-ethanediol bis共fluorosulfate兲
共308 – 406兲
53.2
共pentafluoroethyl兲imidosulfurous chloride fluoride
35.6
bis共trifluoromethyl兲 chlorophosphine
共193–273兲
27.8
chloro bis共trifluoromethylthio兲phosphine
共293–373兲
33.0
关bis共trifluoromethyl兲amino兴trifluorochlorophosphorous共V兲
共223–273兲
26.4
2-chlorotetrafluoroethylsulfur pentafluoride
28.3
1,2-dichloro-1,2-difluoroethylene
共191–294兲
27.9
共240–294兲
27.2
dichloro共difluoroamino兲acetonitrile
共238 –341兲
26.8
fluorodichloroacetyl fluoride
共208 –273兲
21.8
N,N⬘-dichloro-2,2,2-trifluoroacetamide
40.9
S,S-dichloro-N-共trifluoroacetyl兲 sulfilimine
共306 –333兲
44.2
共trifluoromethyl兲sulfonyl carbonimidic dichloride
共312– 405兲
44.1
1,1-dichloro-1,2,2,2-tetrafluoroethane
共231–373兲
23.5
23.2
22.5
20.8
17.7
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
A
A
C
A
A
共289兲
CAS registry number
Reference
关30915-39-0兴
关87/5兴关71/19兴
关42016-33-1兴
关73/21兴
关79-38-9兴
关87/5兴
关87/5兴
关51/2兴
关33/2兴
关23213-83-4兴
关87/5兴
关6069-32-5兴
关87/5兴关66/15兴
关99/16兴
关42016-31-9兴
关73/21兴
关42016-34-2兴
关73/21兴
关76-15-3兴
关87/5兴
关87/5兴
关87/5兴
关66/4兴
关87/5兴关55/1兴
关55/1兴
关22675-67-8兴
关87/5兴关73/22兴
关39937-08-1兴
关87/5兴关64/22兴
关99/16兴
共258兲
关63/17兴
关1957-17-1兴
关87/5兴关99/16兴
关74366-11-3兴
关80/10兴
关650-52-2兴
关64/4兴关84/9兴
共333兲
关60/25兴
共248兲
关66/23兴
关646-63-9兴
关61/21兴关99/16兴
关598-88-9兴
关87/5兴
关33/3兴
关30913-21-4兴
关87/5兴关71/19兴
关354-18-7兴
关87/5兴
关32751-03-4兴
关72/40兴
关24433-67-8兴
关87/5兴关69/22兴
关99/16兴
关51587-33-8兴
关87/5兴关99/16兴
关374-07-2兴
关87/5兴关70/16兴
关55/20兴
关55/20兴
关55/20兴
关55/20兴
共323兲
A
共326兲
I
共320兲
共279兲
共279兲
A
共253兲
A
共258兲
A
共319兲
A
共327兲
A
共246兲
共233兲
共273兲
共313兲
共353兲
A
BG
BG
BG
BG
ENTHALPIES OF VAPORIZATION
537
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 Cl2 F4
C2 Cl2 F4 O4
C2 Cl2 F5 NS
C2 Cl2 F8 NP
C2 Cl3 F3
C2 Cl3 F3
C2 Cl3 F3
C2 Cl3 F3 O4
C2 Cl3 N
C2 Cl4
C2 Cl4 F2
C2 Cl4 F2 O3 S
C2 Cl4 F2 O4
C2 Cl4 F4 N2
C2 Cl4 F6 OS
C2 Cl4 O
C2 Cl4 O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
1,2-dichloro-1,1,2,2-tetrafluoroethane
共277–391兲
24.3
共210–277兲
25.1
共178 –277兲
25.3
perchloric acid, 1,1,2,2-tetrafluoro-2-chloroethyl ester
共249–294兲
32.6
S,S-dichloro-N-共pentafluoroethyl兲 sulfilimine
共297–375兲
37.4
关bis共trifluoromethyl兲amino兴difluorodichlorophosphorous 共V兲
共262–305兲
32.9
1,1,1-trichloro-2,2,2-trifluoroethane
28.1⫾0.1
27.2⫾0.1
26.3⫾0.1
共297–319兲
28.9
共286 –310兲
29.2
1,1,2-trichloro-1,2,2-trifluoroethane
共273–319兲
28.3
共238 –364兲
30.9
共360– 473兲
26.9
共297–317兲
28.8
28.4⫾0.1
27.5⫾0.1
26.6⫾0.1
28.2⫾0.4
共273–318兲
28.2
共248 –356兲
30.8
共243–353兲
NA
trichlorotrifluoroethane
共248 –352兲
30.5
perchloric acid, 1,2,2-trifluoro-1,2-dichloroethyl ester
共273–296兲
26.9
trichloroacetonitrile
共289–357兲
35.1
共289–356兲
34.7
tetrachloroethylene
共307–393兲
38.4
共310–393兲
38.7
共300–380兲
38.9
共333–373兲
37.6
39.6⫾0.1
1,2-difluorotetrachloroethane
34.6⫾0.1
34.1⫾0.1
33.6⫾0.1
33.1⫾0.1
32.6⫾0.1
共301–365兲
36.6
共235–293兲
36.4
共312–362兲
34.0
共283–364兲
32.7
2-fluorotetrachloroethyl fluorosulfate
共311– 437兲
42.0
perchloric acid, 1,2-difluoro-1,2,2-trichloroethyl ester
共273–294兲
30.2
1,2-bis共dichloroamino兲tetrafluoroethane
43.1
pentafluoro共2-fluoro-1,1,2,2-tetrachloroethoxy兲sulfur
共314 – 418兲
42.8
tetrachloroethylene oxide
共308 –348兲
36.9
trichloroacetyl chloride
共305–393兲
38.3
Method
共292兲
共262兲
共261兲
A
A
共279兲
A
共312兲
A
共293兲
共298兲
共313兲
共328兲
共308兲
共298兲
C
C
C
共288兲
共253兲
共375兲
共307兲
共298兲
共313兲
共328兲
共298兲
共288兲
共263兲
A
A
A
A
C
C
C
A
共263兲
共284兲
A
共304兲
共304兲
A
共322兲
共325兲
共315兲
共348兲
共298兲
共308兲
共315兲
共323兲
共330兲
共338兲
共316兲
共278兲
共327兲
共298兲
A
C
C
C
C
C
C
A
A
A
共329兲
共283兲
A
共329兲
A
共323兲
A
共320兲
A
CAS registry number
Reference
关76-14-2兴
关87/5兴
关87/5兴
关47/5兴
关38126-28-2兴
关87/5兴关73/19兴
关10564-48-4兴
关87/5兴关99/16兴
关66/33兴
关354-58-5兴
关80/9兴
关80/9兴
关80/9兴
关80/9兴
关87/5兴关63/6兴
关76-13-1兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关80/9兴
关80/9兴
关80/9兴
关74/5兴
关63/6兴
关40/1兴
关39/7兴
关38/4兴
关38126-27-1兴
关87/5兴
关545-06-2兴
关87/5兴关70/16兴
关54/4兴
关127-18-4兴
关95/13兴
关87/5兴关72/6兴
关70/3兴关84/9兴
关67/30兴
关60/1兴
关76-12-0兴
关92/11兴
关92/11兴
关92/11兴
关92/11兴
关92/11兴
关87/5兴
关87/5兴
关87/5兴
关33/4兴
关63/17兴
关38126-29-3兴
关87/5兴关73/19兴
关72/40兴
关762-90-3兴
关87/5兴关62/19兴
关16650-10-5兴
关87/5兴
关76-02-8兴
关87/5兴关59/1兴
关70/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
538
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 Cl6
Compound
共Temperature range/K兲
C2 F2 N2 O
hexachloroethane
共460–513兲
共345– 460兲
共305– 458兲
ethylene oxide—d4 oxide
共230–273兲
fluorocarbonyl isocyanate
共228 –264兲
difluorocarboncyamidic amide
C2 F2 N2 O2
difluorocarbonisocyantidic amide
C2 F2 N4 O8
1,2-difluoro-1,1,2,2-tetranitroethane
共297–323兲
oxalyl fluoride
共264 –272兲
bis共fluorocarbonyl兲peroxide
共226 –266兲
trifluoroacetonitrile
共151–206兲
共141–203兲
共197–241兲
共282–336兲
共272–311兲
共142–206兲
trifluoromethyl isocyanate
共195–228兲
trifluoronitrosoethylene
共247–250兲
trifluoromethanesulfinyl cyanide
C2 D4 O
C2 FNO2
C2 F2 O2
C2 F2 O4
C2 F3 N
C2 F3 NO
C2 F3 NO
C2 F3 NOS
C2 F3 NOS
C2 F3 NO2 S
C2 F3 NO2 S2
C2 F3 NO3 S
C2 F3 NS
C2 F3 N3 O6
C2 F4
C2 F4 N2
C2 F4 N2 O3
C2 F4 N2 O4
C2 F4 N2 O6 S2
C2 F4 O
C2 F4 O2 S
C2 F4 O3
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
40.3
51.2
53.7
共475兲
共360兲
共320兲
27.6
共258兲
33.5
共249兲
29.7
共383兲
33.9
共327兲
62.8
共310兲
29.7
共268兲
30.6
共251兲
19.3
19.2
18.5
17.4
17.4
19.2
共191兲
共188兲
共226兲
共309兲
共287兲
共191兲
A
A
A
A
A
22.5
共213兲
A
25.7
共248兲
A
40.2
共352兲
I
27.9
共278兲
A
36.4
共282兲
A
41.0
共312兲
A
36.9
共290兲
A
32.6
共279兲
A
57.7
共328兲
A
16.8
16.6
18.6
共258兲
共288兲
共193兲
A
A
A
共223兲
A
共278兲
A
共323兲
共274兲
A, I
共284兲
A
共200兲
A
共285兲
A
trifluoromethylsulfenyl isocyanate
共231–293兲
2,2,2-trifluoro-N-sulfinylacetamide
共267–302兲
trifluoromethanesulfonyl isothiocyanate
共297–385兲
trifluoromethanesulfonyl isocyanate
共275–345兲
thiocyanic acid, trifluoromethyl ester
共226 –294兲
1,1,2-trifluoro-1,2,2-trinitroethane
共313–353兲
tetrafluoroethylene
共197–273兲
共273–306兲
共142–208兲
tetrafluoroaminoacetic, nitrile
共193–238兲
23.9
1,1,2,2-tetrafluoro-1-nitro-2-nitrosoethane
共233–293兲
28.8
1,1,2,2-tetrafluoro-1,2-dinitroethane
共303–343兲
67.8
共259–333兲
34.7
1,2-bis共fluoroformyl兲-1,2-bis共fluorosulfonyl兲hydrazine
共273–296兲
49.8
trifluoroacetyl fluoride
共161–215兲
20.9
trifluoroethylene sulfonyl fluoride
共270–313兲
27.0
fluoroperoxyformic acid, trifluoromethyl ester
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
A
A
A
CAS registry number
Reference
关67-12-11兴
关87/5兴
关87/5兴关70/16兴
关47/5兴
关6552-57-4兴
关52/2兴关84/9兴
关15435-14-0兴
关87/5兴关67/31兴
关32837-63-1兴
关73/23兴
关32837-64-2兴
关73/23兴
关20165-39-3兴
关87/5兴关73/25兴
关359-40-0兴
关87/5兴
关692-74-0兴
关62/3兴关84/9兴
关353-85-5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关61/2兴
关460-49-1兴
关87/5兴
关2713-04-4兴
关87/5兴
关61951-27-7兴
关77/17兴
关691-03-2兴
关87/5兴关99/16兴
关63/42兴
关26454-68-2兴
关87/5兴关99/16兴
关51587-30-5兴
关87/5兴关99/16兴
关30227-06-6兴
关87/5兴关99/16兴
关690-24-4兴
关87/5兴关99/16兴
关63/42兴
关20165-38-2兴
关87/5兴关73/25兴
关116-14-3兴
关87/5兴
关87/5兴
关87/5兴关53/2兴
关84/9兴
关5131-88-4兴
关87/5兴
关679-08-3兴
关87/5兴
关356-16-1兴
关73/25兴
关87/5兴关57/19兴
关19252-50-7兴
关87/5兴关99/16兴
关354-34-7兴
关87/5兴关72/2兴
关684-106兴
关87/5兴关99/16兴
关16118-40-4兴
ENTHALPIES OF VAPORIZATION
539
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 F4 O4 S
C2 F4 S2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共194 –249兲
trifluoroacetyl fluorosulfate
共262–321兲
共250–320兲
perfluoro-1-3-dithietane
27.3
共234兲
A
34.3
34.9
共277兲
共265兲
A
29.2
C2 F5 I
C2 F5 NO
C2 F5 NO
C2 F5 NOS
C2 F5 NOS
C2 F5 NOS
C2 F5 NOS
C2 F5 NO4 S
C2 F5 N3 O3
C2 F6
C2 F6 IN
C2 F6 IP
C2 F6 N2
C2 F6 N2 O
C2 F6 N2 O2
C2 F6 N2 O2
C2 F6 OS
C2 F6 OS
C2 F6 OS2
C2 F6 OS2
C2 F6 O2 S
C2 F6 O3
C2 F6 O3 S
C2 F6 O4 S
C2 F6 O5 S
C2 F6 O6 S2
C2 F6 O7 S2
pentafluoroiodoethane
共248 –283兲
pentafluoroacetamide
20.8
23.8
pentafluoronitrosoethane
共193–227兲
20.9
carbamothioic acid, difluoro-S-共trifluoromethyl兲 ester
23.0
S,S-difluoro-N-共trifluoroacetyl兲 sulfilimine
共240–282兲
34.4
1,1,1-trifluoro-N-共fluoroformyl兲methanesulfinimidyl fluoride
共276 –323兲
38.9
1,1,2,2,2-pentafluoro-N-sulfinyl ethylamine
共245–303兲
29.0
共fluorosulfonyl兲共trifluoromethoxy兲carbamoyl fluoride
共277–290兲
30.3
fluoro共1,1,2,2-tetrafluoro-2-nitroethyl兲-2-diimide oxide
共257–350兲
38.0
hexafluoroethane
共172–200兲
17.3
共180–196兲
17.1
N-iodo-bis共trifluoromethyl兲amine
共261–318兲
28.5
bis共trifluoromethyl兲phosphinous iodide
共273–320兲
33.2
hexafluoroazomethane
共205–242兲
22.9
hexafluoroazoxymethane
共274 –281兲
27.2
1,1,1-trifluoro-N-共nitrosooxy兲-N-共trifluoromethyl兲methanamine
共245–285兲
26.8
N-nitroso-O,N-bis共trifluoromethyl兲hydroxylamine
共272–283兲
25.4
bis共trifluoromethyl兲sulfoxide
共248 –303兲
27.9
pentafluoroethyl sulfinyl fluoride
共234 –293兲
28.5
S-trifluoromethyl-共trifluoromethyl兲thiosulfinate
共293–353兲
30.7
methanesulfonothioic acid, trifluoro-S-共trifluoromethyl兲 ester
27.8
perfluoroethyl fluorosulfate
共250–300兲
28.8
bis共trifluoromethyl兲 trioxide
共193–248兲
24.3
trifluoromethanesulfonic acid, trifluoromethyl ester
共238 –294兲
29.4
共238 –294兲
27.6
bis共trifluoromethyl兲sulfate
共219–304兲
28.7
peroxysulfuric acid, bis共trifluoromethyl兲 ester
共253–319兲
32.0
tetrafluoroethylene glycol, bis共fluorosulfate兲
共295–378兲
43.7
共268兲
A
共252兲
HG
共212兲
A
共315兲
共267兲
A
共291兲
A
共260兲
A
共283兲
共272兲
A
共186兲
共188兲
A
共276兲
A
共288兲
共227兲
A
共277兲
A
共270兲
A
共277兲
A
共263兲
A
共278兲
A, I
共323兲
共329兲
I
共275兲
共233兲
A
共252兲
共279兲
A
共262兲
共268兲
共310兲
A
CAS registry number
Reference
关87/5兴
关5762-53-8兴
关87/5兴关66/17兴
关66/4兴
关73/38兴
关354-64-3兴
关87/5兴
关32822-49-4兴
关71/18兴
关354-72-3兴
关87/5兴
关32837-66-4兴
关73/23兴
关24433-65-6兴
关87/5兴关69/22兴
关99/16兴
关28103-61-9兴
关87/5兴关99/16兴
关10564-50-8兴
关87/5兴关99/16兴
关19252-49-4兴
关99/16兴
关755-68-0兴
关87/5兴
关76-16-4兴
关87/5兴
关48/3兴
关5764-87-4兴
关87/5兴
关359-64-8兴
关64/4兴关84/9兴
关372-63-4兴
关87/5兴
关371-56-2兴
关87/5兴
关359-75-1兴
关87/5兴
关87/5兴
关30341-37-8兴
关87/5兴关99/16兴
关20621-31-2兴
关87/5兴关68/15兴
关99/16兴
关63548-94-7兴
关99/16兴
关76/18兴
关63/17兴
关17118-18-9兴
关87/5兴
关3582-05-6兴
关99/16兴
关87/5兴关65/18兴
关60/15兴
关41765-14-4兴
关99/16兴
关1479-53-4兴
关87/5兴关70/16兴
关99/16兴
bis共trifluoromethyl兲 disulfate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
540
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共328 –357兲
bis共trifluoromethyl兲 sulfide
38.3
共342兲
C2 F6 S
C2 F6 S2
bis共trifluoromethyl兲 disulfide
Molecular formula
Method
23.6
C2 F7 N
C2 F7 N
C2 F7 NOS
C2 F7 NO3 S
C2 F7 NO12S4
C2 F8 NOP
C2 F8 NOP
C2 F8 OS
C2 F8 OS
C2 F8 O3 S
C2 F8 S
C2 F8 S
C2 F10OS
C2 F10O2 S
C2 F10O3 S
C2 F10O3 S2
C2 F10S
C2 F11NS
C2 F12S2
C2 N2
C2 HBr
C2 HBrClF3
C2 HBrClF3
28.8
perfluorodimethylamine
共199–230兲
21.4
共215兲
共203–233兲
18.6
共218兲
perfluoroethylamine
共171–236兲
20.8
共221兲
共pentafluoroethyl兲imidosulfuryl fluoride
30.7
fluorosulfuric acid, 1,1,2,2-tetrafluoro-2-共difluoroamino兲ethyl ester
共276 –326兲
31.1
共291兲
fluorosulfuric acid, 1-关bis关共fluorosulfonyl兲oxo兴amino兴-2,2,2-trifluoro-ethylidene ester
43.4
共418兲
关bis共difluoromethyl兲amino兴 difluorophosphine oxide
共233–278兲
30.4
共255兲
phosphorous bis共trifluoromethyl兲nitroxide difluoride
28.0
共288兲
difluorooxo-bis-共trifluoromethyl兲 sulfur
共239–299兲
22.4
共254兲
28.4
pentafluoro共trifluoroacetyl兲 sulfur
共162–290兲
26.6
共177兲
pentafluoro 共trifluoroethaneperoxoato兲 sulfur
28.0
trifluorovinyl sulfur pentafluoride
25.1
共292兲
difluoro bis共trifluoromethyl兲 sulfur
28.8
pentafluoro共pentafluoroethoxy兲 sulfur
共245–287兲
27.6
共272兲
tetrafluorobis共trifluoromethoxy兲 sulfur
共246 –302兲
29.9
共261兲
共trifluoromethoxy兲关共trifluoromethyl兲dioxy兴 sulfur tetrafluoride
共255–317兲
32.5
共270兲
pentafluoro关1,2,2,2-tetrafluoro-1-关共fluorosulfonyl兲oxy兴ethyl兴 sulfur
34.8
trans tetrafluorobis共trifluoromethyl兲 sulfur
共233–293兲
23.3
共278兲
关bis共trifluoromethyl兲amino兴 sulfur pentafluoride
共233–306兲
29.3
共248兲
A
A
A
A
CAS registry number
Reference
关60/15兴
关371-78-8兴
关52/22兴
关372-64-5兴
关52/22兴
关359-62-6兴
关87/5兴
关87/5兴关49/27兴
关354-80-3兴
关87/5兴关70/16兴
关59617-28-6兴
关76/29兴
关4188-34-5兴
关87/5兴关99/16兴
关53684-02-9兴
关75/21兴
关66/33兴
A
A
A
A
A
关73/24兴
关33716-15-3兴
关87/5兴关99/16兴
关71/34兴
关82390-51-0兴
关99/16兴
关60672-61-9兴
关76/31兴
关1186-51-2兴
关61/21兴
关30341-38-9兴
关71/34兴
关87/5兴关62/19兴
关2004-38-8兴
关87/5兴关64/18兴
关41938-43-6兴
关99/16兴
关68010-32-2兴
关78/23兴
关42179-02-2兴
关87/5兴关99/16兴
关13888-13-6兴
关87/5兴关66/21兴
关99/16兴
perfluoro-1,3-dithietane octafluoride
35.6
cyanogen
共240–253兲
24.5
共246 –273兲
23.9
共246 –273兲
23.5
bromoacetylene
共214 –273兲
25.6
2-bromo-2-chloro-1,1,1-trifluoroethane
共298 –323兲
30.0
29.6⫾0.3
29.6⫾0.1
28.7⫾0.1
27.8⫾0.1
26.8⫾0.1
共227–318兲
34.3
共222–329兲
33.2
1-bromo-2-chloro-1,1,2-trifluoroethane
30.0⫾0.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共246兲
共257兲
共267兲
A
共273兲
A
共310兲
共298兲
共298兲
共313兲
共328兲
共343兲
共242兲
共237兲
A
共298兲
C
C
C
C
C
A
关73/38兴
关460-19-5兴
关87/5兴
关25/1兴
关25/1兴
关593-61-3兴
关87/5兴
关151-67-7兴
关87/5兴
关81/5兴
关80/9兴
关80/9兴
关80/9兴
关80/9兴
关65/6兴
关87/5兴关63/7兴
关70/16兴
关354-06-3兴
关81/13兴
ENTHALPIES OF VAPORIZATION
541
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 HBrF8 S
C2 HBr2 FO2
C2 HBr3 O
C2 HCl
C2 HClF2
C2 HClF6 OS
C2 HClF6 OS
C2 HClF8 OS
C2 HClF12O2 S
C2 HClF8 S
C2 HCl2 F3
C2 HCl2 F3
C2 HCl3
C2 HCl3 F2 O3 S
C2 HCl3 O
C2 HCl3 O2
C2 HCl4 FS
C2 HCl5
C2 HF3 O2
C2 HF5
C2 HF5 O
C2 HF6 NOS
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共313兲
共328兲
共343兲
C
C
C
共418兲
A
共306兲
A
共223兲
A
共233兲
共273兲
共313兲
共353兲
BG
BG
BG
BG
共294兲
A
共298兲
共258兲
MM
29.0⫾0.1
28.1⫾0.1
27.2⫾0.1
共1-bromo-2,2,2-trifluoroethyl兲sulfur pentafluoride
32.0
dibromofluoroacetic acid
共403– 468兲
60.2
tribromoacetaldehyde
共291– 447兲
47.8
chloroacetylene
共204 –238兲
21.8
1,1-difluoro-2-chloroethene
23.5
21.4
18.5
14.1
trans 关共2-chloro-2-fluorovinyl兲oxy兴 sulfur pentafluoride
36.8
cis 关共2-chloro-2-fluorovinyl兲oxy兴 sulfur pentafluoride
34.3
共2-chloro-1,2,2-trifluoroethoxy兲 sulfur pentafluoride
33.3
关共2-chloro-2,2-difluoroethylidiene兲dioxy兴bis共pentafluoro兲sulfur
39.0
共1,1,2-trifluoro-2-chloroethyl兲 sulfur pentafluoride
共279–323兲
30.2
1,1,1-trifluoro-2,2-dichloroethane
26.6⫾0.3
共243– 448兲
28.7
1,1,2-trifluoro-1,2-dichloroethane
26.8⫾0.3
trichloroethylene
共297–360兲
34.2
34.5⫾0.1
共280– 428兲
34.6
共290–359兲
36.2
共298 –360兲
35.6
fluorosulfuric acid, 2-fluoro-1,1,2-trichloroethyl ester
共317–353兲
36.6
trichloroacetaldehyde
共235–371兲
36.6
trichloroacetic acid
共326 – 473兲
65.0
共385– 470兲
57.2
共dichloromethyl兲共fluorodichloromethyl兲 sulfide
共322–352兲
46.5
pentachloroethane
共274 – 434兲
40.9
共298 – 435兲
45.5
trifluoroacetic acid
共285–345兲
35.9
共298兲
共313兲
共298兲
共295兲
共305兲
共313兲
C
共332兲
A
共250兲
A
共341兲
共400兲
A
共337兲
A
共289兲
共313兲
A
共300兲
A
22.8
21.9
20.9
20.3
共175兲
共190兲
共205兲
共215兲
C
C
C
C
22.3
19.3
17.6
15.6
20.4
共239兲
共260兲
共280兲
共300兲
共255兲
I
EB
EB
EB
A
pentafluoroethane
pentafluorodimethyl ether
共216 –238兲
共229–331兲
共229–331兲
共229–331兲
共240–313兲
S,S-bis共trifluoromethyl兲sulfoximine
CAS registry number
Reference
关81/13兴
关81/13兴
关81/13兴
关82390-50-9兴
关82/19兴
关353-99-1兴
关87/5兴
关115-17-3兴
关87/5兴关47/5兴
关593-63-5兴
关87/5兴
关359-10-4兴
关55/20兴
关55/20兴
关55/20兴
关55/20兴
关20407-78-7兴
关68/17兴
关20407-79-8兴
关68/17兴
关20334-47-8兴
关68/17兴
关20563-90-0兴
关68/17兴
关22756-13-4兴
关87/5兴关99/16兴
关306-83-2兴
关02/1兴
关92/19兴
关354-23-4兴
关02/1兴
关79-01-6兴
关95/14兴
关80/1兴
关87/5兴关70/16兴
关44/1兴
关12/1兴关84/9兴
关42087-88-7兴
关87/5兴关99/16兴
关75-87-6兴
关87/5兴关47/5兴
关76-03-9兴
关87/5兴关70/16兴
关59/1兴
关87/5兴关99/16兴
关76-01-7兴
关87/5兴
关30/1兴
关76-05-1兴
关87/5兴关62/4兴
关70/16兴关84/9兴
关354-33-6兴
关99/26兴
关99/26兴
关99/26兴
关99/26兴
关3822-68-2兴
关01/22兴
关96/6兴
关96/6兴
关96/6兴
关92/12兴
关34556-22-4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
542
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 HF6 NS2
C2 HF6 OPS
C2 HF6 PS
C2 HF6 PS2
C2 HF7 S
C2 HF9 S
C2 H2
C2 H2 Br2
C2 H2 Br2
C2 H2 Br2 Cl2
C2 H2 Br2 Cl2
C2 H2 Br4
C2 H2 Br4
C2 H2 ClFO
C2 H2 ClFO
C2 H2 ClF3 O2 S
C2 H2 ClF7 S
C2 H2 Cl2
C2 H2 Cl2
C2 H2 Cl2
C2 H2 Cl2 F2
C2 H2 Cl2 F6 OS
C2 H2 Cl2 F6 OS
C2 H2 Cl2 O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
35.1
bis共trifluoromethane兲 sulphenimide
共243–293兲
36.5
bis共trifluoromethyl兲 thiophospinic acid
共283–324兲
38.3
bis共trifluoromethyl兲共mercapto兲phosphine
共269–304兲
30.7
bis共trifluoromethyl兲 thiophosphinous acid
共217–280兲
32.9
共2,2-difluoroethenyl兲 pentafluoro sulfur
27.7
pentafluoro 共1,2,2,2-tetrafluoroethyl兲 sulfur
28.0
acetylene
共258 –308兲
16.3
共192–308兲
16.7
共192–225兲
16.7
17.0
共215–308兲
16.4
共193–207兲
16.8
cis 1,2-dibromoethylene
共299–351兲
40.6
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共346兲
I
关72/25兴
A
关60/24兴
关35814-49-4兴
关87/5兴
共268兲
共298兲
共286兲
共265兲
A
共273兲
共207兲
共210兲
共214兲
共230兲
共200兲
A
A
A
共314兲
A
35.2
42.9
共310兲
共292兲
A
45.9
共369兲
A
45.9
共335兲
A
61.5
共346兲
A
trans 1,2-dibromoethylene
共277–344兲
共277–343兲
1,2-dibromo-1,1-dichloroethane
共354 –519兲
1,2-dibromo-1,2-dichloroethane
共320–379兲
1,1,1,2-tetrabromoethane
共331– 473兲
1,1,2,2-tetrabromoethane
共413–573兲
chloroacetyl fluoride
共273–333兲
56.9
共428兲
A
38.0
共288兲
A, GS
fluoroacetyl chloride
共273–333兲
36.7
共288兲
A, GS
共260兲
A
共347兲
共288兲
共307兲
共288兲
A
A
共336兲
共288兲
共278兲
共250兲
A
共338兲
A
chlorosulfurous acid, 2,2,2-trifluoroethyl ester
36.0
共2-chloro-2,2-difluoroethyl兲pentafluoro sulfur
32.9
1,1-dichloroethylene
共245–305兲
28.4
cis 1,2-dichloroethylene
共332– 495兲
29.3
共273–334兲
31.5
共292–335兲
31.6
共273–356兲
31.8
trans 1,2-dichloroethylene
共321– 473兲
29.0
共273–319兲
30.1
共263–323兲
30.4
共235–358兲
31.4
1,2-dichloro-1,1-difluoroethane
共323– 493兲
27.8
共1,2-dichloro-2-fluoroethoxy兲pentafluoro sulfur
共temperature not given兲
38.8
共2,2-dichloro-2-fluoroethoxy兲pentafluoro sulfur
共temperature not given兲
38.5
chloroacetyl chloride
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
关64/31兴
关1486-19-7兴
关87/5兴关99/16兴
关58636-78-5兴
关78/23兴
关63011-80-3兴
关78/23兴
关74-86-2兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关64/15兴
关56/1兴关84/9兴
关590-11-4兴
关87/5兴关50/2兴
关70/16兴
关590-12-5兴
关87/5兴关70/16兴
关50/2兴关84/9兴
关75-81-0兴
关87/5兴关70/16兴
关683-68-1兴
关87/5兴
关630-16-0兴
关87/5兴关47/5兴
关79-27-6兴
关87/5兴关70/16兴
关359-14-8兴
关87/5兴关48/14兴
关70/16兴
关359-06-8兴
关87/5兴关48/14兴
关70/16兴
关57169-80-9兴
关75/41兴
关68010-35-5兴
关78/23兴
关75-35-4兴
关87/5兴关59/2兴
关70/16兴
关156-59-2兴
关87/5兴
关87/5兴关70/16兴
关51/3兴
关47/4兴
关156-60-5兴
关87/5兴
关83/2兴
关87/5兴关70/16兴
关47/4兴
关1649-08-7兴
关87/5兴
关20334-44-5兴
关68/17兴
关20334-45-6兴
关68/17兴
关79-04-9兴
ENTHALPIES OF VAPORIZATION
543
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 H2 Cl2 O2
C2 H2 Cl4
C2 H2 Cl4
C2 H2 Cl4 S
C2 H2 FN
C2 H2 F2
C2 H2 F4
C2 H2 F4 O2 S
C2 H2 F6 P2
C2 H2 F8 S
C2 H2 I2
C2 H2 I2
C2 H2 O
C2 H3 Br
C2 H3 BrO
C2 H3 BrO2
C2 H3 Br3
C2 H3 Cl
Compound
共Temperature range/K兲
共253–379兲
共301–380兲
共290–373兲
dichloroacetic acid
共317– 468兲
1,1,1,2-tetrachloroethane
共316 – 447兲
共332– 403兲
1,1,2,2-tetrachloroethane
共377– 419兲
共371– 419兲
共377– 418兲
共328 – 464兲
共298 – 403兲
共304 – 419兲
bis共dichloromethyl兲 sulfide
共355– 462兲
fluoroacetonitrile
共273–333兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
45.0
40.8
44.1
共268兲
共316兲
共305兲
A
55.7
共332兲
A
45.7⫾0.1
40.1
39.2
共298兲
共331兲
共347兲
C
A
40.4
40.8
40.1
39.0
45.8⫾0.2
41.9
47.7
45.7
共392兲
共394兲
共398兲
共415兲
共298兲
共343兲
共313兲
共319兲
A
47.6
共370兲
A
38.1
共288兲
A, GS
13.2
9.5
共233兲
共273兲
BG
BG
共249兲
共180兲
共200兲
共220兲
共240兲
共294兲
I
Method
C
A
1,1-difluoroethene
1,1,1,2-tetrafluoroethane
共221–246兲
23.7
26.4
25.0
23.8
22.7
共279–363兲
22.0
fluorosulfurous acid, 2,2,2-trifluoroethyl ester
33.6
1,2-bis-共trifluoromethyl兲 diphosphine
共233–292兲
33.8
pentafluoro 共2,2,2-trifluoroethyl兲 sulfur
29.3
cis 1,2-diiodoethylene
共302– 425兲
46.5
共302– 424兲
47.3
trans 1,2-diiodoethylene
共350– 403兲
42.3
共350– 403兲
43.8
ketene
共159–224兲
20.4⫾0.1
vinyl bromide
共224 –319兲
27.3
共186 –289兲
24.8
共207–285兲
26.9
acetyl bromide
共289–334兲
29.5
共275–333兲
31.4
bromoacetic acid
共327– 481兲
57.2
1,1,2-tribromoethane
共368 –511兲
50.5
共305– 461兲
52.9
vinyl chloride
共243–288兲
22.7
共213–273兲
22.9
共209–260兲
23.3
共277兲
A, SG
共317兲
共317兲
A
共365兲
共365兲
A
共209兲
A, MM
共239兲
共274兲
共270兲
A
共304兲
共290兲
A
共342兲
A
共383兲
共321兲
A
共265兲
共258兲
共245兲
A
CAS registry number
Reference
关87/5兴关70/16兴
关59/1兴
关35/5兴
关79-43-6兴
关87/5兴关47/5兴
关630-20-6兴
关80/1兴
关87/5兴关70/16兴
关49/1兴
关79-34-5兴
关87/5兴
关84/20兴
关78/21兴
关77/30兴
关72/41兴
关87/5兴关70/16兴
关50/1兴
关30/1兴
关51174-93-7兴
关87/5兴
关503-20-8兴
关87/5兴关48/14兴
关70/16兴
关75-38-7兴
关55/20兴
关55/20兴
关811-97-2兴
关01/22兴
关98/24兴
关98/24兴
关98/24兴
关98/24兴
关92/16兴
关75/41兴
关462-57-7兴
关87/5兴关58/10兴
关65227-29-4兴
关78/23兴
关590-26-1兴
关87/5兴关70/16兴
关50/2兴
关590-27-2兴
关87/5兴关70/16兴
关50/2兴
关463-51-4兴
关87/5兴关69/7兴
关593-60-2兴
关87/5兴关70/16兴
关37/4兴关84/9兴
关34/1兴关84/9兴
关506-96-7兴
关87/5兴
关69/3兴
关79-08-3兴
关87/5兴
关78-74-0兴
关87/5兴关70/16兴
关47/5兴
关75-01-4兴
关67/35兴
关67/11兴
关87/5兴关59/1兴
关70/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
544
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 H3 ClF2
C2 H3 ClF3 N
C2 H3 ClF3 P
C2 H3 ClO
C2 H3 ClO2
C2 H3 Cl2 F
C2 H3 Cl3
Compound
共Temperature range/K兲
C2 H3 F
C2 H3 FN2 O5
C2 H3 FO
C2 H3 F2 O
C2 H3 FO2
C2 H3 F3
Method
24.2
22.7
24.0
21.9
19.2
15.4
共240兲
共263兲
共233兲
共273兲
共313兲
共353兲
EB
A
BG
BG
BG
BG
30.8
共279兲
BG
N-chloro-N,1,1-trifluoroethanamine
共220–294兲
chloromethyl共trifluoromethyl兲phosphine
共236 –294兲
acetyl chloride
共273–323兲
共267–324兲
30.9
共279兲
24.5
31.5
共288兲
共282兲
A
A
chloroacetic acid
共336 – 463兲
共377– 463兲
61.1
56.8
共351兲
共392兲
A
A
55.7
共411兲
28.7
27.8
共265兲
共285兲
32.3
30.5
29.4
29.5
32.5⫾0.1
32.4
37.6
32.5⫾0.1
33.4
33.4⫾0.1
共310兲
共364兲
共414兲
共494兲
共298兲
共344兲
共211兲
共298兲
共279兲
共284兲
A
A
A
A
C
38.6
40.2⫾0.1
40.3⫾0.1
38.2
38.3
共331兲
共298兲
共298兲
共317兲
共338兲
A
C
C
38.4
49.6
51.5
共324兲
共340兲
共278兲
EB
A
16.6
共186兲
A
55.7
共343兲
14.3
共266兲
35.6⫾2.4
共231兲
52.3
53.6
共308兲
共308兲
A
T
18.1
17.5
16.7
15.9
18.9
16.4
13.8
8.7
共240兲
共250兲
共260兲
共270兲
共233兲
共273兲
共303兲
共333兲
EB
EB
EB
EB
BG
BG
BG
BG
共396 – 460兲
1,1-dichloro-1-fluoroethane
共250– 450兲
共270–312兲
1,1,1-trichloroethane
共295–372兲
共349– 408兲
共399– 487兲
共479–545兲
共268 –290兲
C2 H3 Cl3 O2
Mean temperature
(T m /K)
1-chloro-1,1-difluoroethane
共225–285兲
共248 –390兲
共196 –298兲
C2 H3 Cl3
⌬ vapH m
共kJ mol⫺1兲
1,1,2-trichloroethane
共316 –384兲
共302– 428兲
共323–386兲
chloral hydrate
共300–348兲
共325–370兲
共263–369兲
vinyl fluoride
共124 –201兲
2-fluoro-2,2-dinitroethanol
共313–373兲
acetyl fluoride
共195–281兲
acetyl hypofluorite
共209–253兲
fluoroacetic acid
共293– 443兲
共293– 443兲
1,1,1-trifluoroethane
共236 –280兲
共236 –280兲
共236 –280兲
共236 –280兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
EB
C
C
A
CAS registry number
Reference
关75-68-3兴
关93/6兴
关87/5兴关70/16兴
关55/20兴
关55/20兴
关55/20兴
关55/20兴
关16276-45-2兴
关87/5兴关67/28兴
关4669-76-5兴
关87/5兴
关75-36-5兴
关87/5兴
关87/5兴关59/1兴
关70/16兴
关79-11-8兴
关87/5兴
关87/5兴关59/1兴
关70/16兴
关49/1兴
关1717-00-6兴
关97/25兴
关92/17兴
关71-55-6兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关80/1兴
关77/30兴
关73/7兴
关72/41兴
关44/2兴
关44/2兴
关79-00-5兴
关87/5兴
关80/1兴
关72/41兴
关87/5兴关70/16兴
关49/1兴
关302-17-0兴
关94/16兴
关87/5兴
关47/5兴
关75-02-5兴
关87/5兴关47/5兴
关17003-75-7兴
关68/12兴
关557-99-3兴
关87/5兴
关78948-09-1兴
关85/16兴
关144-49-0兴
关87/5兴关70/16兴
关55/2兴
关420-46-2兴
关96/14兴
关96/14兴
关96/14兴
关96/14兴
关55/20兴
关55/20兴
关55/20兴
关55/20兴
ENTHALPIES OF VAPORIZATION
545
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共174 –226兲
C2 H3 F3 N2
C2 H3 F3 O
C2 H3 F3 O
C2 H3 F3 O2 S
C2 H3 F5 O3 S
C2 H3 F5 S
C2 H3 IO
C2 H3 N
C2 H3 NO
C2 H3 NO5
C2 H3 NS
C2 H3 NS
C2 H4
C2 H4 BrCl
C2 H4 BrCl
C2 H4 Br2
C2 H4 Br2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
20.5
19.2⫾0.1
共211兲
共224兲
C
共258兲
A
共248兲
A
共289兲
共313兲
共313兲
共285兲
A
A
MM
MM
1,1,1-trifluoroazomethane
共240–273兲
26.4
trifluoromethyl methyl ether
共233–313兲
22.5
2,2,2-trifluoroethanol
共276 –302兲
45.9
共298 –328兲
44.0
共298 –328兲
41.5
共273–298兲
44.5
methanesulfinic acid, trifluoromethyl ester
31.8
共ethaneperoxoato兲 pentafluoro sulfur
共217–377兲
36.2
vinylsulfur pentafluoride
28.5
acetyl iodide
共276 –302兲
37.1
acetonitrile
33.0
共288 –362兲
33.8
共314 –355兲
33.3
共299–343兲
34.8
共273–323兲
34.2
共280–300兲
33.9
methyl isocyanate
共265–308兲
29.9
共253–310兲
31.7
acetyl nitro peroxide
共277–330兲
34.6
methyl thiocyanate
共259– 406兲
40.7
methyl isothiocyanate
共309–392兲
共283–323兲
ethylene
共252–282兲
共170–273兲
共120–170兲
共169–211兲
共209–254兲
共120–182兲
共150–190兲
共148 –174兲
共124 –171兲
1-bromo-1-chloroethane
共290–356兲
共237–356兲
1-bromo-2-chloroethane
共244 –379兲
1,1-dibromoethane
共301– 421兲
共346兲
共297兲
共314兲
共289兲
A
共298兲
共303兲
共329兲
共315兲
共288兲
共290兲
A, EB
BG
共280兲
共268兲
A
A
共292兲
A
共274兲
A
37.4
37.3
共324兲
共298兲
A
14.0
13.7
14.4
13.7
13.6
14.1
14.0
14.3
14.4
共267兲
共258兲
共155兲
共196兲
共239兲
共167兲
共175兲
共161兲
共156兲
A
A
A
A
A
A
33.1
46.7
共305兲
共252兲
A
37.6⫾0.1
37.3⫾0.1
36.9⫾0.1
36.6⫾0.1
36.4⫾0.1
39.5
共308兲
共315兲
共323兲
共330兲
共338兲
共259兲
C
C
C
C
C
39.6
共316兲
EST
41.7⫾0.1
41.7⫾0.1
41.6⫾0.1
共308兲
共315兲
共323兲
C
C
C
1,2-dibromoethane
CAS registry number
Reference
关44/3兴
关44/3兴
关690-21-1兴
关87/5兴
关421-14-7兴
关92/12兴
关75-89-8兴
关87/5兴
关87/5兴关70/16兴
关73/5兴
关67/4兴
关30957-42-7兴
关71/20兴
关60672-60-8兴
关99/16兴关76/31兴
关61/22兴
关507-02-8兴
关87/5兴关69/3兴
关75-05-8兴
关83/5兴
关74/10兴
关87/5兴关71/4兴
关71/2兴
关68/24兴
关65/2兴
关624-83-9兴
关87/5兴
关87/5兴
关2278-22-0兴
关87/5兴
关556-64-9兴
关87/5兴关47/5兴
关99/16兴
关556-61-6兴
关87/5兴关99/16兴
关35/3兴关84/9兴
关74-85-1兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴关70/16兴
关50/3兴
关40/3兴
关37/5兴
关593-96-4兴
关87/5兴
关47/5兴
关107-04-0兴
关92/11兴
关92/11兴
关92/11兴
关92/11兴
关92/11兴
关47/5兴
关557-91-5兴
关87/5兴关56/16兴
关70/16兴
关106-93-4兴
关92/11兴
关92/11兴
关92/11兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
546
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 H4 ClF
C2 H4 ClN3
C2 H4 Cl2
Compound
共Temperature range/K兲
共283–317兲
共316 – 488兲
共404 –578兲
共285–298兲
共325– 404兲
共246 – 404兲
1-chloro-2-fluoroethane
共288 –327兲
1-chloro-2-azidoethane
共273–333兲
1,1-dichloroethane
共326 –345兲
共323–535兲
共363–535兲
共234 –290兲
共213–330兲
共258 –365兲
C2 H4 Cl2
共279– 434兲
C2 H4 FNO3
C2 H4 F2
C2 H4 F3 NS
C2 H4 F3 OP
C2 H4 F3 OP
C2 H4 F6 OS
Mean temperature
(T m /K)
41.5⫾0.1
41.4⫾0.1
41.8
40.0
37.4
49.6
39.6
31.1
共330兲
共338兲
共298兲
共331兲
共419兲
共291兲
共340兲
共261兲
C
C
A
A
A
MM, A
32.1
共303兲
A
43.8
共288兲
A
33.5
29.2
28.2
30.6⫾0.1
31.9
34.4
32.2
共336兲
共338兲
共378兲
共298兲
共275兲
共228兲
共273兲
34.4
35.1⫾0.1
31.1
34.8
31.1
40.8
34.7
35.2⫾0.1
34.8
34.7
37.5
共298兲
共298兲
共371兲
共294兲
共383兲
共538兲
共316兲
共298兲
共294兲
45.1
共335兲
A
38.3
共288兲
GS
22.7
22.1
23.3
21.8
22.1
共249兲
共318兲
共234兲
共265兲
共260兲
I
Method
A
A
C
EST
1,2-dichloroethane
共356 –558兲
共279–374兲
共368 –524兲
共523–561兲
共301–357兲
C2 H4 Cl2 S
⌬ vapH m
共kJ mol⫺1兲
共243–372兲
bis共chloromethyl兲sulfide
共320– 430兲
2-fluoroethyl nitrate
共273–333兲
1,1-difluoroethane
共218 –248兲
共303–333兲
共219–273兲
共250–386兲
共193–275兲
21.8
20.4
17.8
12.9
共161–247兲
23.8
1,1,1-trifluoro-N-methyl methanesulfenamide
共223–294兲
33.6
共trifluoromethyl兲phosphinous acid, methyl ester
共194 –291兲
29.4
methyl共trifluoromethyl兲phosphine oxide
共305–322兲
50.7
pentafluoro共2-fluoroethoxy兲 sulfur
共290–364兲
39.3
C2 H4 I2
1,2-diiodoethane
C2 H4 N2 O4
共371–526兲
1,1-dinitroethane
共303–363兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
GC
C
A
A
A
A
C
共258兲
EB
A
A, EST
共233兲
共273兲
共313兲
共353兲
共232兲
BG
BG
BG
BG
共279兲
A
共276兲
A
共313兲
共305兲
A
49.8
47.7
共298兲
共386兲
GC
A
51.0
共318兲
A
CAS registry number
Reference
关92/11兴
关92/11兴
关87/5兴
关87/5兴
关87/5兴
关57/1兴
关49/1兴
关47/5兴
关762-50-5兴
关87/5兴
关53422-48-3兴
关87/5兴
关75-34-3兴
关87/15兴
关87/5兴
关87/5兴
关72/41兴
关56/2兴
关47/5兴
关87/5兴关56/16兴
关70/16兴
关107-06-2兴
关94/19兴
关89/10兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关82/7兴
关80/1兴
关87/5兴关70/16兴
关56/25兴关38/12兴
关29/1兴
关3592-44-7兴
关87/5兴关99/16兴
关763-97-3兴
关87/5兴关48/14兴
关70/16兴
关75-37-6兴
关01/22兴
关99/29兴
关93/6兴
关87/5兴
关87/5兴关56/16兴
关70/16兴
关55/20兴
关55/20兴
关55/20兴
关55/20兴
关47/5兴
关62067-12-3兴
关87/5兴关60/24兴
关6395-71-7兴
关87/5兴
关26348-89-0兴
关70/26兴
关87/5兴关62/19兴
关99/16兴
关624-73-7兴
关94/19兴
关87/5兴关70/16兴
关600-40-8兴
关87/5兴
ENTHALPIES OF VAPORIZATION
547
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 H4 N2 O6
C2 H4 O
C2 H4 O
C2 D4 O
C2 H4 OS
C2 H4 O2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
70.5
55.3
68.3
62.3⫾0.4
68.6⫾0.4
共298兲
共358兲
共255兲
A
A
26.0
26.3
27.6
27.0
共308兲
共308兲
共283兲
共307兲
A
25.9
26.8
共298兲
共269兲
A
A
26.8
26.9
共269兲
共290兲
A
27.6
共258兲
35.2
共333兲
39.1
37.9
42.0
38.7
38.1
38.8
43.0
41.6
23.3⫾0.1
51.6⫾1.6
40.3
41.6
共360兲
共406兲
共305兲
共406兲
共452兲
共540兲
共308兲
共304兲
共298兲
共298兲
共340兲
共318兲
29.6
28.4
28.7⫾0.1
27.9⫾0.1
27.4⫾0.1
30.1
52.7
共292兲
共320兲
共293兲
共305兲
共313兲
共283兲
共299兲
A
A
C
C
C
BG
56.8
共348兲
A
34.8
共281兲
A
51.8
共362兲
A
44.2
共288兲
A
30.5
共306兲
A
30.3
共298兲
共225–333兲
26.9
26.6
31.0
27.6⫾0.1
27.0⫾0.1
26.2⫾0.1
30.6
共349兲
共341兲
共467兲
共305兲
共312兲
共323兲
共240兲
共301–348兲
27.9
共316兲
Compound
共Temperature range/K兲
ethylene glycol dinitrate
共283–535兲
共343– 465兲
共240–298兲
共278 –390兲
共293–323兲
acetaldehyde
共293–377兲
共293–345兲
共272–294兲
共273–307兲
ethylene oxide 共oxirane兲
共283–385兲
共239–284兲
共223–284兲
共268 –313兲
ethylene oxide-d4 oxide
共230–273兲
thioacetic acid
共307–360兲
acetic acid
共345–383兲
共391–550兲
共290–396兲
共391– 447兲
共437–535兲
共525–593兲
共289–392兲
monomer
C2 H4 O2
C2 H4 O2 S
C2 H4 O3
C2 H4 O3
C2 H4 O3
C2 H4 S
C2 H5 Br
共325–391兲
共303–399兲
methyl formate
共279–305兲
共305– 443兲
共261–305兲
共294 –304兲
mercaptoacetic acid
共333– 427兲
ethylene ozonide
共273–289兲
hydroxyacetic acid
共350–375兲
peroxyacetic acid
共273–383兲
ethylene sulfide
共291–361兲
ethyl bromide
共334 –504兲
共326 – 454兲
共452–503兲
Method
A
EB
A
A
A
A
A
A
C
C
MM
A
A
A
C
C
C
EST
CAS registry number
Reference
关628-96-6兴
关87/5兴
关87/5兴
关87/5兴关77/6兴
关41/1兴
关38/1兴
关75-07-0兴
关87/5兴
关77/24兴
关87/5兴关70/16兴
关50/4兴
关75-21-8兴
关87/5兴
关87/5兴关59/1兴
关70/16兴
关87/5兴关49/4兴
关37/7兴
关6552-57-4兴
关52/2兴关84/9兴
关507-09-5兴
关99/16兴
关64-19-7兴
关01/15兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关83/13兴
关87/5兴关70/16兴
关70/8兴
关70/8兴
关59/1兴
关54/3兴
关107-31-3兴
关87/5兴
关87/5兴
关76/14兴
关76/14兴
关76/14兴
关71/2兴
关28/1兴关84/9兴
关68-11-1兴
关87/5兴关99/16兴
关87/5兴关56/18兴
关79-14-1兴
关87/5兴
关79-21-0兴
关87/5兴关70/16兴
关420-12-2兴
关87/5兴关52/3兴
关99/16兴
关71/28兴
关74-96-4兴
关87/5兴
关87/5兴
关87/5兴
关77/8兴
关77/8兴
关77/8兴
关87/5兴关61/13兴
关70/16兴
关30/3兴关84/9兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
548
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 H5 Cl
Compound
共Temperature range/K兲
ethyl chloride
共285–344兲
共334 – 413兲
共403– 460兲
共207–305兲
共218 –285兲
C2 H5 ClO
C2 H5 ClO
C2 H5 ClO2 S
C2 H5 Cl2 P
C2 H5 Cl2 OP
2-chloroethanol
共328 – 401兲
共323–363兲
共363– 403兲
共269– 401兲
methyl共chloromethyl兲ether
共290–332兲
ethane sulfonyl chloride
共349– 449兲
共233–263兲
dichloroethyl phosphine
共313–385兲
ethylphosphonic dichloride
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
25.1
24.4
24.4
27.8
共300兲
共349兲
共418兲
共222兲
A
A
A
A, EST
25.9
24.8
共270兲
共294兲
C
43.3
46.9
39.1
45.7
共343兲
共338兲
共378兲
共284兲
A
32.2
共305兲
A
47.7
56.4
共364兲
共248兲
A
36.8
共328兲
A
42.7⫾4.2
C2 H5 F
C2 H5 FO
C2 H5 FO3 S
C2 H5 F2 N
C2 H5 F3 NP
C2 H5 I
C2 H5 N
C2 H5 NO
C2 H5 NO
C2 H5 NO
C2 H5 NO2
ethyl fluoride
共200–235兲
共275–353兲
共235–280兲
共343–375兲
共170–255兲
共173–251兲
20.7
20.2
20.5
20.7
4.2
20.8
共236兲
共290兲
共265兲
共358兲
共240兲
共236兲
I
A
A
A
EST
共156 –241兲
2-fluoroethanol
共273–333兲
22.0
共226兲
44.1
共288兲
GS
ethyl fluorosulfonate
共273–333兲
38.5
共288兲
GS
共250兲
共288兲
A
N,N-difluoroethylamine
共241–259兲
27.3
25.7
methyl共trifluoromethyl兲phosphinic acid amide
共238 –294兲
36.8
ethyl iodide
共313–353兲
31.7
31.9⫾0.1
共249–369兲
33.6
共219–345兲
34.7
共254 –293兲
32.0
共303–333兲
31.7
aziridine
共274 –303兲
34.9
acetaldehyde oxime
共288 –388兲
48.0
acetamide
共381– 492兲
63.8
共338 – 495兲
60.9
N-methylformamide
共340– 440兲
53.8
共340– 440兲
54.4⫾1.3
共310–391兲
54.5
56.2
共369– 472兲
53.4
ethyl nitrite
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共279兲
共298兲
共298兲
共264兲
共234兲
共278兲
共318兲
CGC
C
EST
共288兲
A
共303兲
A
共396兲
共353兲
A
共355兲
共298兲
共325兲
共298兲
共384兲
A
A
A
CAS registry number
Reference
关75-00-3兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴关61/13兴
关70/16兴
关48/6兴
关26/6兴
关107-07-3兴
关87/5兴
关73/9兴
关73/9兴
关47/5兴
关107-30-2兴
关87/5兴
关594-44-5兴
关99/16兴
关87/5兴关99/16兴
关1498-40-4兴
关87/5兴
关56/23兴关82/15兴
关353-36-6兴
关01/22兴
关87/5兴
关87/5兴
关87/5兴
关75/10兴
关87/5兴关61/13兴
关70/16兴
关47/5兴
关371-62-0兴
关87/5兴关48/14兴
关70/16兴
关371-69-7兴
关87/5兴关48/14兴
关70/16兴
关758-18-9兴
关87/5兴
关60/19兴
关4669-74-3兴
关87/5兴
关75-03-6兴
关95/21兴
关68/1兴
关87/5兴关61/13兴
关47/5兴
关44/4兴
关29/2兴
关151-56-4兴
关87/5兴
关107-29-9兴
关87/5兴
关60-35-5兴
关87/5兴
关47/5兴
关123-39-7兴
关96/28兴
关96/28兴
关87/5兴
关85/7兴关86/5兴
关87/5兴关61/3兴
关70/16兴
关109-95-5兴
ENTHALPIES OF VAPORIZATION
549
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共252–276兲
C2 H5 NO2
C2 H5 NO2
methyl carbamate
共333–388兲
nitroethane
共324 –388兲
共252–387兲
C2 H5 NO3
C2 H5 N3
ethyl nitrate
共273–361兲
共273–343兲
共273–333兲
azidoethane
共296 –320兲
共253–298兲
C2 H5 N3 O
2-azidoethanol
C2 H5 N3 O2
bis共nitrosomethyl兲amine
共276 – 426兲
ethane
共273–305兲
共154 –185兲
共95–129兲
共185–229兲
共228 –274兲
共91–144兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
25.7
27.8
共264兲
A
45.7
共348兲
A
38.6
共339兲
EB
41.3
38.0
共267兲
37.0
37.3
37.0
38.5
共288兲
共288兲
共288兲
A
31.5
28.9
共308兲
共268兲
A
A
33.9⫾1.3
C2 H6
C2 H6 BrF4 NS
C2 H6 ClF4 NS
C2 H6 ClP
C2 H6 Cl2 NP
C2 H6 FN
C2 H6 FO3 P
C2 H6 F2 NP
C2 H6 F3 NOS
C2 H6 F3 NS
C2 H6 F4 NP
C2 H6 N2
C2 H6 N2
C2 H6 N2 S
C2 H6 O
43.5
15.3
15.7
17.7
14.9
14.9
17.1
14.7
14.7
共136 –200兲
15.3
bromotetrafluoro共N-methylmethanaminato兲 sulfur
38.1
chlorotetrafluoro共N-methylmethanaminato兲 sulfur
36.0
chlorodimethyl phosphine
共273–306兲
32.9
共dimethylamino兲dichlorophosphine
40.8⫾0.7
fluorodimethylamine
共249–273兲
29.9
dimethylfluorophosphate
共273–333兲
44.4
共dimethylamino兲difluorophosphine
共263–313兲
29.3
共dimethylaminato兲trifluorooxo sulfur
共313–357兲
44.9
共dimethylamino兲 sulfur trifluoride
共296 –327兲
40.5
共dimethylamino兲 tetrafluorophosphorane
37.1
azomethane
共195–273兲
26.4
共209–236兲
25.3
methylammonium cyanide
共251–295兲
49.1
sulfur diimide, dimethyl
共248 –298兲
37.2
dimethyl ether
共183–265兲
22.6
共180–249兲
22.8
共293–360兲
21.2
共349– 400兲
21.1
共291兲
共288兲
共170兲
共114兲
共214兲
共259兲
共129兲
共210兲
共184兲
共185兲
A
A
A
A
A
共372兲
I
共359兲
I
共288兲
A
共298兲
STG
共261兲
A
共288兲
A, GS
共288兲
I
CAS registry number
Reference
关87/5兴关37/3兴
关34/6兴
关598-55-0兴
关87/5兴
关79-24-3兴
关87/5兴关56/15兴
关70/16兴
关47/5兴
关34/6兴
关625-58-1兴
关87/5兴关70/16兴
关57/2兴
关56/3兴
关34/6兴
关871-31-8兴
关87/5兴关70/16兴
关87/5兴关64/5兴
关84/9兴
关1517-05-1兴
关97/26兴
关87/5兴关47/5兴
关74-84-0兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关73/11兴
关71/28兴
关37/14兴
关26/2兴
关63324-17-4兴
关77/15兴
关63324-16-3兴
关77/15兴
关811-62-1兴
关87/5兴关58/11兴
关683-85-2兴
关95/2兴
关14722-43-1兴
关87/5兴
关5954-50-7兴
关87/5兴关48/14兴
A
关64/30兴
关22519-52-4兴
关68/22兴
关3880-03-3兴
关87/5兴关99/16兴
共258兲
共222兲
A
A
关66/31兴
关503-28-6兴
关87/5兴
关87/5兴
共280兲
A
共263兲
A
共250兲
共234兲
共308兲
共364兲
A
A
A
A
共335兲
共311兲
关87/5兴关73/10兴
关13849-02-0兴
关87/5兴关99/16兴
关115-10-6兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
550
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共241–303兲
共171–248兲
共171–248兲
共195–248兲
C2 H6 O
共320–359兲
共210–271兲
共193–223兲
共320–359兲
共349–374兲
共370– 464兲
共459–514兲
共292–353兲
共243–303兲
共271–373兲
共293–366兲
共288 –348兲
共298 –351兲
C2 H6 OS
Mean temperature
(T m /K)
22.2
18.5
21.4
22.7
21.5⫾0.1
共256兲
共298兲
共248兲
共233兲
共248兲
38.9
39.3
40.7
42.4
40.5
35.2
30.6
25.7
21.8
17.3
14.2
40.9
40.4
40.2
39.4
38.8
41.3
45.6
44.0
41.3
40.1
39.1
36.1
42.5
42.3
42.9
42.26⫾0.02
41.0⫾0.1
40.0⫾0.1
38.7⫾0.1
42.5
42.4
42.3⫾0.1
42.2⫾0.1
42.2
40.0
54.1
共338兲
共321兲
共298兲
共357兲
共393兲
共423兲
共453兲
共473兲
共493兲
共503兲
共320兲
共328兲
共335兲
共344兲
共351兲
共335兲
共256兲
共208兲
共335兲
共361兲
共385兲
共474兲
共307兲
共298兲
共286兲
共298兲
共320兲
共335兲
共351兲
共308兲
共303兲
共298兲
共298兲
共313兲
共351兲
共301兲
48.6
48.1
51.7
52.3
50.6
52.1
52.5
共392兲
共368兲
共320兲
共308兲
共340兲
共318兲
共308兲
54.1
共308兲
A
65.6⫾0.3
57.4
65.2
62.5
64.0
61.1
57.3
63.5
共298兲
共385兲
共338兲
共378兲
共338兲
共383兲
共436兲
共410兲
C
TGA
A
A
Method
A
C
ethanol
共323–357兲
共309–343兲
共309–343兲
共342–357兲
C2 H6 OS
⌬ vapH m
共kJ mol⫺1兲
共286 –351兲
dimethyl sulfoxide
共377– 483兲
共353–383兲
共305– 464兲
共298 –318兲
共325– 442兲
共303– 423兲
共293–323兲
2-mercaptoethanol
共293– 440兲
C2 H6 O2
ethylene glycol
C2 H6 O2
共363– 408兲
共323– 473兲
共363– 418兲
共323– 473兲
共363– 403兲
共403– 470兲
共395– 459兲
ethyl hydroperoxide
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
EB
EB
C
C
C
C
C
C
C
C
C
C
C
A
A
A
A
A
A
A
A
C
C
C
C
A, EB
C
C
TGA
A
MM
CAS registry number
Reference
关87/5兴
关76/2兴
关76/2兴
关41/3兴
关41/3兴
关64-17-5兴
关99/32兴
关99/30兴
关95/9兴
关95/9兴
关90/10兴
关89/15兴
关89/15兴
关89/15兴
关89/15兴
关89/15兴
关89/15兴
关88/19兴
关88/19兴
关88/19兴
关88/19兴
关88/19兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关83/14兴
关73/26兴
关71/27兴
关70/20兴
关70/20兴
关70/20兴
关87/5兴关70/2兴
关67/10兴
关66/2兴
关63/2兴
关49/5兴
关34/7兴
关1883/1兴
关67-68-5兴
关99/16兴
关87/18兴
关87/5兴
关74/36兴
关72/8兴关84/9兴
关72/35兴
关69/25兴
关60-24-2兴
关87/5兴关70/16兴
关99/16兴
关107-21-1兴
关88/14兴
关87/18兴
关87/5兴
关87/5兴
关52/5兴
关35/4兴
关35/4兴
关1901/1兴
关3031-74-1兴
ENTHALPIES OF VAPORIZATION
551
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 H6 O2 S
C2 H6 O4 S
C2 H6 S
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共253–363兲
64.0
共268兲
A
dimethyl sulfone
共387–523兲
56.0
共404兲
A
46.7
共355兲
A
28.5⫾0.1
27.9⫾0.6
28.9
27.7
26.6
26.7
27.5
27.7
28.8⫾0.1
27.9⫾0.1
27.0⫾0.1
28.2
28.9
28.9
共298兲
共283兲
共322兲
共387兲
共462兲
共298兲
共298兲
共276兲
共292兲
共310兲
共302兲
共278兲
共310兲
C
A
A
A
A
28.4
27.5
26.3
26.6
27.3
28.4
28.4
共288兲
共318兲
共380兲
共457兲
共298兲
共288兲
共288兲
28.7
共306兲
44.7
共298兲
38.5⫾0.6
37.8
37.8⫾0.1
37.8
38.4
36.0⫾0.1
34.9⫾0.1
33.7⫾0.1
36.7
36.2
38.2
共298兲
共312兲
共298兲
共298兲
共298兲
共341兲
共360兲
共383兲
共336兲
共349兲
共303兲
27.0
23.8
28.4
共292兲
共373兲
共264兲
A
A
A
Compound
共Temperature range/K兲
dimethyl sulfate
共340– 470兲
dimethyl sulfide
共268 –319兲
共307–379兲
共372– 453兲
共447–503兲
共287–318兲
共251–293兲
C2 H6 S
ethyl mercaptan 共ethanethiol兲
共273–313兲
共303–375兲
共265– 448兲
共442– 499兲
共273–339兲
共273–339兲
C2 H6 S2
1,2-ethanedithiol
C2 H6 S2
dimethyl disulfide
共297– 402兲
C2 H7 N
C2 H7 N
C2 H7 NO
C2 H7 NO
共321–388兲
共334 – 401兲
共288 –333兲
dimethylamine
共277–360兲
共358 – 438兲
共202–279兲
C
C
C
EB
A
A
A
A
A, EB
C
A
C
C
C
C
EB
ethyl amine
共213–297兲
共290– 449兲
共291–387兲
共377– 456兲
共275–288兲
共190–290兲
N,N-dimethylhydroxyl amine
共290–363兲
29.0
27.2
27.6
25.9
29.1
28.9
共282兲
共305兲
共306兲
共392兲
共281兲
共275兲
A
A
A
A
45.7
共305兲
A
N,O-dimethylhydroxyl amine
共228 –316兲
34.3
共243兲
A
CAS registry number
Reference
关87/5兴关51/10兴
关70/16兴
关67-71-0兴
关87/5兴关70/16兴
关99/16兴
关77-78-1兴
关87/5兴关99/16兴
关75-18-3兴
关97/30兴
关89/12兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关81/12兴
关71/28兴
关57/10兴
关57/10兴
关57/10兴
关52/9兴
关42/2兴
关35/2兴
关75-08-1兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关66/5兴
关87/5兴关52/6兴
关66/5兴
关35/2兴
关540-63-6兴
关62/11兴
关624-92-0兴
关89/12兴
关87/5兴
关85/2兴
关81/12兴
关71/28兴
关58/8兴
关58/8兴
关58/8兴
关52/9兴
关50/5兴
关50/5兴
关124-40-3兴
关87/5兴
关87/5兴
关87/5兴关39/1兴
关84/9兴
关75-04-7兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关62/5兴
关47/5兴
关5725-96-2兴
关87/5兴关57/4兴
关84/9兴
关1117-97-1兴
关87/5兴关57/4兴
关84/9兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
552
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C2 H7 NO
C2 H7 O3 P
C2 H8 ClN
C2 H8 ClN
C2 H8 N2
C2 H8 N2
C2 H8 N2
C3 BrClF6 O4
C3 BrF5 O
C3 BrF6 NO
C3 BrF9 N2
C3 BrF10NS
C3 Br2 F6 O
C3 Br3 F6 NO
C3 ClF4 NO2
C3 ClF5 O
C3 ClF5 O
C3 ClF6 NO2
C3 ClF6 NS
C3 ClF7 O
C3 ClF8 N
C3 ClF8 NOS
C3 ClF10NS
C3 Cl2 F5 N
C3 Cl2 F6
Compound
共Temperature range/K兲
2-aminoethanol
共310– 444兲
共379– 443兲
共273–301兲
共338 – 443兲
dimethyl phosphite
共346 – 456兲
dimethylammonium chloride
共429–533兲
共533–569兲
ethylammonium chloride
共382– 480兲
1,1-dimethylhydrazine
共267–303兲
共238 –292兲
1,2-dimethylhydrazine
共274 –297兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
61.7
54.7
U50.8
58.9
共325兲
共394兲
共287兲
共353兲
39.5
38.7
共361兲
A
95.6
143.9
共444兲
共548兲
A
A
34.3
共397兲
A
34.1
36.5
共284兲
共277兲
A
41.0
共286兲
A
共318兲
共299兲
共298兲
共298兲
共314兲
A
A, IPM
C
IPM
共283兲
A
共267兲
A
关141-43-5兴
关87/5兴
关59/1兴
关57/25兴
关50/1兴关84/9兴
关868-85-9兴
关93/20兴
关87/5兴关70/16兴
关506-59-2兴
关87/5兴
关87/5兴
关557-66-4兴
关87/5兴
关57-14-7兴
关00/18兴
关87/5兴关53/3兴
关84/9兴
关540-73-8兴
关87/5兴关51/15兴
关84/9兴
关107-15-3兴
关87/5兴
关87/5兴关75/4兴
关69/2兴
关65/8兴关70/11兴
关34/2兴关84/9兴
关38126-26-0兴
关87/5兴关73/19兴
关6129-62-0兴
关87/5兴
共278兲
A
关87/5兴
ethylenediamine
共303–391兲
共284 – 419兲
43.9
45.9
45.0⫾0.1
46.0⫾0.2
共299–390兲
45.6
perchloric acid, 1,1,2,3,3,3-hexafluoro-2-bromopropyl ester
共273–293兲
38.1
2-bromo-2,3,3,3-tetrafluoropropionyl fluoride
共224 –282兲
30.2
N,N-bis共trifluoromethyl兲 carbamoyl bromide
共233–293兲
30.7
N-bromo-tris共trifluoromethyl兲hydrazine
共283–333兲
36.8
bromotrifluoro关1,1,1,2,3,3,3-heptafluoro-2-propanaminoato共2-兲兴
35.1
共trifluoromethyl兲共1,2-dibromo-1,2,2-trifluoroethyl兲 ether
共299–335兲
34.6
1,1,1,1⬘,1⬘,1⬘-hexafluoro-N-共tribromomethoxy兲dimethylamine
共297–338兲
28.9
chloro共trifluoroacetyl兲carbamic fluoride
39.3
chloropentafluoroacetone
共232–303兲
27.3
2-chloro-2,3,3,3-tetrafluoropropionyl fluoride
共195–273兲
23.9
O-共chloroformyl兲-N,N-bis共trifluoromethyl兲hydroxylamine
共227–286兲
34.5
chloro共hexafluoroisopylidenimino兲 sulfur
37.7
heptafluoroisopropyl hypochorite
共196 –287兲
26.7
共194 –273兲
22.7
N-chloro-N-1,2,2,2-pentafluoro-1-共trifluoromethyl兲ethylamine
共240–311兲
28.8
共heptafluoropropyl兲imidosulfuryl chloride fluoride
26.7
chlorotrifluoro关1,1,1,2,3,3,3-heptafluoro-2-propanaminoato共2-兲兴
33.5
2,2-difluoro-1,2-dichloro-N-共trifluoromethyl兲ethylidenimine
共283–318兲
31.2
1,2-dichlorohexafluoropropane
共296 –307兲
28.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
A, GS
共308兲
sulfur
共394兲
I
共314兲
A
共312兲
A
共371兲
共247兲
A
共258兲
A
共271兲
A
共368兲
I
共272兲
共258兲
A
A
共255兲
A
共346兲
sulfur
共391兲
I
共298兲
A
共301兲
I
CAS registry number
Reference
关66/31兴
关62977-73-5兴
关77/15兴
关2356-57-2兴
关87/5兴
关29528-78-7兴
关87/5兴
关42016-32-0兴
关73/21兴
关79-53-8兴
关87/5兴关64/6兴
关84/9兴
关28627-00-1兴
关87/5兴
关15496-01-2兴
关87/5兴
关72/22兴
关22675-68-9兴
关87/5兴
关87/5兴
关33757-13-0兴
关87/5兴关71/17兴
关74366-14-6兴
关80/10兴
关62977-71-3兴
关77/15兴
关87/5兴
关661-97-2兴
关80/9兴
ENTHALPIES OF VAPORIZATION
553
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 Cl2 F6 N2
C3 Cl2 F6 O
C3 Cl2 F7 N
C3 Cl2 F7 NS
C3 Cl2 F7 NS
C3 Cl2 F7 P
C3 Cl3 F5 O
C3 Cl5 F3 O
C3 Cl6
C3 F3 N2 P
C3 F3 N3
C3 F4
C3 F4 O2 S2
C3 F5 N
C3 F5 N
C3 F6
C3 F9 N2 OS
C3 F6 O
C3 F6 O
C3 F6 O
C3 F6 O
C3 F6 O2
C3 F6 O4 S
C3 F6 O7 S2
C3 F7 I2 P
C3 F7 NO
C3 F7 NOS
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共298兲
共313兲
C
C
关80/9兴
关80/9兴
26.9⫾0.1
25.9⫾0.1
bis共trifluoromethyl兲aminocarbylamine chloride
共267–339兲
35.0
hypochlorous acid, 2-chloro-1,1,2,3,3,3-hexafluoropropyl ester
共273–293兲
29.6
N,N-dichloro-1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethylamine
共299–344兲
32.7
S,S-dichloro-N-关tetrafluoro-1-共trifluoromethyl兲ethyl兴sulfilimine
共313–347兲
39.3
C3 F7 N⫽SCl2
25.9
dichloro共heptafluoropropyl兲phosphine
共273–348兲
33.5
chlorodifluoromethyl 2,2-dichloro-1,1,2-trifluoroethyl ether
共302–350兲
33.4
33.8⫾0.5
trichloromethyl 2,2-dichloro-1,1,2-trifluoroethyl ether
共341– 423兲
42.2
45.7⫾0.7
hexachloropropylene
共366 –510兲
54.8⫾0.4
共382–540兲
49.3
dicyano共trifluoromethyl兲phosphine
共291–334兲
45.6
2,4,6-trifluoro-1,3,5-triazine
共277–344兲
38.8
tetrafluoropropyne
共179–218兲
18.8
ethane共dithioperoxoic兲acid, fluorooxo-trifluoromethyl ester
34.9
2,2-difluoro-3-共trifluoromethyl兲-2H-aziridine
共193–298兲
24.0
2,3-difluoro-2-共trifluoromethyl兲-2H-aziridine
共193–298兲
24.3
perfluoropropene
共233–293兲
21.9
N-cyano-S,S-bis共trifluoromethyl兲sulfoximine
30.8
hexafluorooxetane
共232–313兲
22.3
perfluoroacetone
共195–246兲
23.6
共303兲
共283兲
A
共314兲
A
共328兲
A
关66/32兴
关22675-69-0兴
关87/5兴
关32751-04-5兴
关87/5兴关71/17兴
关26454-66-0兴
关87/5兴关70/27兴
共361兲
I
关80/10兴
共310兲
共317兲
共298兲
A
EB
共356兲
共298兲
A
EB
共298兲
共397兲
EB
A
共306兲
A
共292兲
A
共203兲
A
共385兲
I
共283兲
A
共283兲
A
共278兲
A
共382兲
I
共247兲
A
共231兲
A
共240–357兲
22.3
共253兲
共213–245兲
23.1
共229兲
trifluoromethyl trifluorovinyl ether
共208 –241兲
22.9
共226兲
pentafluoropropionyl hypofluorite
共214 –248兲
25.8
共233兲
1,3-perfluorodioxolane
共234 –367兲
22.3
共249兲
pentafluoropropionic fluorosulfuric acid anhydride
共252–335兲
39.2
共267兲
hydroacrylic acid, tetrafluoroanhydride with fluorosulfuric acid, fluorosulfate
共308 – 403兲
49.4
共323兲
diiodo共heptafluoropropyl兲phosphine
共313–393兲
39.6
共353兲
heptafluoropropionamide
27.2
共279兲
1,1,1,2,3,3,3-heptafluoro-N-sulfinyl-2-propanamine
共252–280兲
34.1
共266兲
A
A
A
A
HG
A
关59/21兴
关37136-24-6兴
关87/5兴
关76/15兴
关428-73-9兴
关87/5兴
关76/15兴
关1888-71-7兴
关97/7兴
关87/5兴关70/16兴
关58310-46-6兴
关87/5兴
关675-14-9兴
关87/5兴
关20174-11-2兴
关87/5兴
关58936-60-0兴
关76/18兴
关3291-42-7兴
关87/5兴
关3291-41-6兴
关87/5兴
关116-15-4兴
关87/5兴关52/7兴
关70/16兴关84/9兴
关34556-28-0兴
关72/25兴
关425-82-1兴
关92/12兴
关116-16-5兴
关87/5兴关67/9兴
关84/9兴
关64/6兴关84/9兴
关55/21兴
关1187-93-5兴
关87/5兴
关5930-63-2兴
关87/5兴
关92/12兴
关51689-98-6兴
关87/5兴关66/15兴
关6378-48-9兴
关99/16兴
关59/21兴
关32822-50-7兴
关71/18兴
关26454-67-1兴
关87/5兴关99/16兴
关70/27兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
554
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 F7 NOS
C3 F7 NS
C3 F7 NO2
C3 F8
C3 F8 N2 O2
C3 F8 OS
C3 F8 S
C3 F9 N
C3 F9 NO
C3 F9 NOS
C3 F9 NOS2
C3 F9 NO2 S2
C3 F9 NO2 S3
C3 F9 N3 O
C3 F9 N3 O2
C3 F9 P
C3 F9 PS
C3 F9 PS
C3 F9 PS2
C3 F10OS
C3 F10O3 S
C3 F10S
C3 F10S
C3 F11NO3 S2
C3 F12O3 S2
C3 HClF6 O2 S
C3 HClF10S
C3 HCl7
C3 HF3
C3 HF6 N
C3 HF7
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
1,1,2,2,3,3,3-heptafluoro-N-sulfinyl-1-propanamine
26.3
共325兲
2,2,2-trifluoro-N-关共trifluoromethyl兲thio兴ethanimidoyl fluoride
28.0
共305兲
perfluoro-1-nitropropane
共247–296兲
28.5
共281兲
perfluoropropane
共193–237兲
21.6
共222兲
共213–259兲
20.9
共244兲
N-关关共difluoroamino兲carbonxyl兴oxy兴-1,1,1-trifluoro-N-共trifluoromethyl兲-methanamine
31.4
共310兲
pentafluoroethyl trifluoromethyl sulfur
32.5
pentafluoroethyl trifluoromethyl sulfide
28.8
perfluorotrimethylamine
共193–263兲
23.9
共248兲
1,1,1-trifluoro-N-共trifluoromethoxy兲-N-共trifluoromethyl兲methanamine
共226 –268兲
27.0
共253兲
关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴imidosulfuryl fluoride
28.7
S,S-bis共trifluoromethyl兲-N-关共trifluoromethyl兲thio兴sulfoximine
31.2
共360兲
S,S-bis共trifluoromethyl兲-N-关共trifluoromethyl兲sulfinyl兴sulfoximine
37.2
共388兲
1,1,1-trifluoro-N,N-bis共trifluoromethyl兲thio兴methanesulfonamide
共288 – 403兲
43.5
共303兲
nitrosotris共trifluoromethyl兲hydrazine
共279–300兲
29.5
共289兲
共233–294兲
33.5
共263兲
nitrotris共trifluoromethyl兲hydrazine
共293–321兲
31.6
共307兲
tris共trifluoromethyl兲phosphine
共248 –285兲
24.7
共270兲
bis共trifluoromethyl兲trifluoromethylthiophosphine
共242–293兲
32.5
共267兲
tris共trifluoromethyl兲phosphine sulfide
共282–308兲
29.1
共295兲
共trifluoromethyl兲dithiophosphite acid, bis共trifluoromethyl兲 ester
共273–296兲
37.9
共284兲
difluorooxo共trifluoromethyl兲共pentafluoroethyl兲 sulfur
共291–324兲
30.6
共306兲
pentafluoro 共pentafluoropropaneperoxoato兲 sulfur
34.4
关2,2-difluoro-共1-trifluoromethyl兲ethenyl兴 pentafluoro sulfur
30.0
difluoro共pentafluoroethyl兲共trifluoromethyl兲 sulfur
29.2
trifluoro共trifluorosulfato-O兲关1,1,1,2,3,3,3-heptafluoro-2-propanaminoato共2-兲兴 sulfur
33.5
共391兲
pentafluoro 关2,2,2-trifluoro-1-共fluorosulfonyl兲oxo兴-1-共trifluoromethyl兲-ethyl兴 sulfur
37.2
chlorosulfurous acid, 2,2,2-trifluoro-1-共trifluromethyl兲ethyl ester
36.7
关1-共chlorodifluoromethyl兲-2,2,2-trifluoroethyl兴 pentafluorosulfur
31.2
1,1,1,2,2,3,3-heptachloropropane
共413– 473兲
34.8
共428兲
3,3,3-trifluoropropyne
共138 –213兲
2,2,3-trifluoro-3-fluoromethylaziridine
共268 –298兲
1,1,1,2,3,3,3-heptafluoropropane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
I
A
A
A
A
I
I
A
A
A
A
CAS registry number
Reference
关74366-13-5兴
关80/10兴
关62067-06-5兴
关77/18兴
关423-33-6兴
关87/5兴
关76-19-7兴
关87/5兴关67/5兴
关63/4兴
关32837-67-5兴
关73/23兴
关33622-17-2兴
关71/34兴
关33547-10-3兴
关71/34兴
关432-03-1兴
关87/5兴
关671-63-6兴
关87/5兴
关59617-29-7兴
关76/29兴
关34556-26-8兴
关72/25兴
关34556-27-9兴
关72/25兴
关29749-02-8兴
关87/5兴关99/16兴
关10405-30-8兴
关87/5兴
关66/32兴
关10405-31-9兴
关87/5兴
关432-04-2兴
关87/5兴
关62/32兴
A
A
I
A
21.5
共198兲
A
30.2
共283兲
A
关64/32兴
关36121-49-0兴
关87/5兴关99/16兴
关33564-24-8兴
关87/5兴关99/16兴
关60672-62-0兴
关76/31兴
关68010-33-3兴
关78/23兴
关31222-06-7兴
关71/34兴
关65844-08-8兴
关77/15兴
关68010-30-0兴
关78/23兴
关57169-81-0兴
关75/21兴
关68010-36-6兴
关78/23兴
关594-89-8兴
关87/5兴关49/10兴
关70/16兴
关661-54-1兴
关87/5兴
关3291-64-3兴
关87/5兴
关431-89-0兴
ENTHALPIES OF VAPORIZATION
555
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 HF7 O
C3 HF7 O2 S
C3 HF8 NOS
C3 HF9 N2
C3 HF11S
C3 HN
C3 H2 ClF5 O
C3 H2 ClF5 O
C3 H2 Cl2 F4
C3 H2 Cl2 F4 O
C3 H2 Cl3 F3
C3 H2 Cl4
C3 H2 D5 N
C3 H2 FNOS
C3 H2 F6
C3 H2 F6 N2 S
C3 H2 F6 N2 S
C3 H2 F6 O
C3 H2 F6 O
C3 H2 F6 O2 S
C3 H2 F8 N2 S
C3 H2 O3
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共278 –308兲
22.7
共293兲
共293–353兲
22.6
共308兲
共237–370兲
22.3
共250兲
共237–370兲
14.5
共300兲
共237–370兲
12.5
共325兲
trifluoromethyl 1H-pentafluoroethyl ether
共232–313兲
27.3
共247兲
fluorosulfurous acid, 2,2,2-trifluoro-1-共trifluoromethyl兲ethyl ester
33.8
S-共pentafluoroethyl兲-S-共trifluoromethyl兲sulfoximine
36.3
共358兲
tris共trifluoromethyl兲hydrazine
共238 –307兲
29.9
共273兲
pentafluoro 关2,2,2-trifluoro-1-共1-trifluoromethyl兲ethyl兴 sulfur
30.1
cyanoacetylene
共279–315兲
28.1
共294兲
1-chloro-1,2,2-trifluoro-2-共difluoromethoxy兲ethane
共274 –351兲
33.8
共289兲
共290–329兲
32.9
共305兲
32.6⫾0.1
共298兲
31.3⫾0.1
共313兲
30.2⫾0.1
共328兲
29.1⫾0.1
共343兲
2-chloro-1,1,1-trifluoro-2-共difluoromethoxy兲ethane
共280–344兲
31.7
共295兲
共283–312兲
31.9
共297兲
3,3-dichloro-1,1,1,3-tetrafluoropropane
共297–333兲
31.7
共312兲
2-chloro-1,1,2-trifluoroethyl chlorofluoromethyl ether
37.5⫾0.1
共298兲
36.4⫾0.1
共313兲
35.3⫾0.1
共328兲
34.1⫾0.1
共343兲
32.9⫾0.1
共353兲
1,1,1-trichloro-3,3,3-trifluoropropane
共320–365兲
35.2
共335兲
1,1,2,3-tetrachloropropylene
共347– 416兲
42.9
共362兲
共ring-perdeuterocyclopropyl兲amine
共283–330兲
31.7
共298兲
fluoroacetyl isothiocyanate
共273–353兲
49.3
共288兲
1,1,1,3,3,3-hexafluoropropane
共283–323兲
24.5
amino 共hexafluoroisopropylidenimino兲 sulfur
37.7
2,2,2-trifluoro-N-关共trifluoromethyl兲thiol兴ethanimidamide
共322–390兲
39.8
46.9
A
I
A
A
C
C
C
C
A
A
C
C
C
C
C
A
A
共303兲
A
共388兲
I
共337兲
A, I
2-共difluoromethoxy兲-1,1,1,2-tetrafluoroethane
共274 –311兲
24.9
共293兲
1,1,1,3,3,3-hexafluoro-2-propanol
共294 –330兲
40.2
共309兲
共294 –330兲
41.6
共298兲
共273–296兲
47.3
共284兲
trifluoromethanesulfinic acid, 2,2,2-trifluoromethyl ester
36.8
共363兲
S,S-difluoro-N-关1-amino-2,2,2-trifluoro-1-共trifluoromethyl兲ethyl兴 sulfilimine
共295–313兲
38.7
共304兲
vinylene carbonate
共308 –350兲
Method
共323兲
I
A, MM
MM
A
A
CAS registry number
Reference
关02/24兴
关02/4兴
关92/12兴
关92/12兴
关92/12兴
关2356-61-8兴
关92/12兴
关52225-56-6兴
关75/41兴
关34556-23-5兴
关72/25兴
关66/32兴
关68010-34-4兴
关78/23兴
关1070-71-9兴
关87/5兴
关13838-16-9兴
关88/5兴
关87/5兴
关84/7兴
关84/7兴
关84/7兴
关84/7兴
关26675-46-7兴
关88/5兴
关87/5兴
关64712-27-2兴
关87/5兴
关37031-38-2兴
关84/2兴
关84/2兴
关84/2兴
关84/2兴
关84/2兴
关7125-84-0兴
关87/5兴
关60320-18-5兴
关87/5兴
关153557-95-0兴
关93/22兴
关459-71-2兴
关87/5兴关70/16兴
关99/16兴
关690-39-1兴
关00/23兴
关72/22兴
关62067-09-8兴
关87/5兴关77/18兴
关99/16兴
关57041-67-5兴
关96/16兴
关920-66-1兴
关87/5兴关73/5兴
关73/5兴
关67/10兴
关30957-44-9兴
关71/20兴
关2433-66-1兴
关87/5兴关69/22兴
关99/16兴
关872-36-6兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
556
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 H3 Cl
C3 H3 Cl2 F3
C3 H3 Cl2 F3 O
C3 H3 Cl3 O2
C3 H3 Cl5
C3 H3 F3
C3 H3 F4 I
C3 H3 F4 I
C3 H3 F4 NO2
C3 H3 F5
C3 H3 F5
C3 H3 F5 O
C3 H3 F5 O
C3 H3 F6 NOS
C3 H3 F6 NS
C3 H3 F6 O2 P
C3 H3 F6 PS
C3 H3 F6 PS2
C3 H3 N
C3 H3 NO
C3 H3 NO
C3 H3 NO2
C3 H3 NS
C3 H4
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共308 – 400兲
41.3
1-chloro-1-propyne
共200–289兲
28.3
1,1-dichloro-3,3,3-trifluoropropane
共301–342兲
33.7
2-chloro-1,1,2-trifluoroethyl chloromethyl ether
42.4⫾0.1
41.2⫾0.1
40.1⫾0.1
39.0⫾0.1
37.8⫾0.1
methyl trichloroacetate
48.3⫾0.1
1,1,2,2,3-pentachloropropane
共365– 447兲
46.3
3,3,3-trifluoro-1-propene
共283–363兲
22.0
1,1,1,2-tetrafluoro-3-iodopropane
共295–356兲
28.4
1,1,1,3-tetrafluoro-3-iodopropane
共301–356兲
31.2
methoxy 共trifluoromethyl兲carbamic fluoride
27.8
1,1,2,2,3-pentafluoropropane
共258 –353兲
30.2
1,1,1,2,2-pentafluoropropane
共232–283兲
22.9
共233–379兲
23.0
2,2,3,3,3-pentafluoro-1-propanol
共273–297兲
47.0
44.4
41.3
1,1,2,2-tetrafluoro-1-共fluoromethoxy兲ethane
共288 –317兲
33.5
N-methyl-S,S-bis共trifluoromethyl兲sulfoximine
30.7
N,N-bis共trifluoromethyl兲methanesulfenamide
共269–309兲
31.1
bis共trifluromethyl兲phosphinic acid, methyl ester
共258 –313兲
40.5
bis共trifluoromethyl兲 methylthiophosphine
共273–321兲
36.9
bis共trifluromethyl兲dithiophosphinic acid, methyl ester
共273–344兲
41.5
acrylonitrile
共257–352兲
33.6
共283–343兲
31.6
共222–351兲
35.5
共293–343兲
32.9
共273–353兲
32.6
oxazole
共293–344兲
34.6
32.5⫾0.1
isoxazole
共314 – 404兲
37.2⫾0.2
36.5⫾0.1
cyanoformic acid, methyl ester
共273–333兲
39.3
thiazole
共333–393兲
39.7
共336 –391兲
38.9
allene
共136 –274兲
22.6
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
MM
共274兲
A
共316兲
A
共298兲
共313兲
共328兲
共343兲
共358兲
C
C
C
C
C
共298兲
C
共380兲
A
共298兲
A
共310兲
A
共316兲
A
共273兲
A
共268兲
共248兲
A
共285兲
A, MM
共298兲
共298兲
MM
共303兲
I
共338兲
I
共284兲
A
共273兲
A
共297兲
T
共288兲
A
共272兲
共298兲
共237兲
共308兲
A
A
共308兲
共298兲
A
C
共298兲
共298兲
EB
C
共288兲
A
共348兲
共351兲
A
A
共259兲
A
CAS registry number
Reference
关71/1兴
关7747-84-4兴
关87/5兴
关460-69-5兴
关87/5兴
关428-92-2兴
关84/7兴
关84/7兴
关84/7兴
关84/7兴
关84/7兴
关72/41兴
关16714-68-4兴
关87/5兴关70/16兴
关677-21-4兴
关87/5兴
关1737-76-4兴
关87/5兴
关460-74-2兴
关87/5兴
关79/28兴
关679-86-7兴
关02/25兴
关1814-88-6兴
关87/5兴关70/16兴
关67/7兴
关422-05-9兴
关87/5兴关67/4兴
关84/9兴
关73/5兴关67/4兴
关67/3兴
关37031-31-5兴
关02/19兴
关34556-25-7兴
关72/25兴
关87/5兴
关25439-11-6兴
关87/5兴
关64/31兴
关18799-79-6兴
关87/5兴关99/16兴
关107-13-1兴
关87/5兴
关87/5兴
关64/9兴
关64/7兴
关45/6兴
关288-42-6兴
关87/5兴
关78/4兴
关288-14-2兴
关96/4兴
关78/4兴
关17640-15-2兴
关87/5兴关70/16兴
关288-47-1兴
关87/5兴
关87/5兴关69/4兴
关463-49-0兴
关87/5兴
ENTHALPIES OF VAPORIZATION
557
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 H4
C3 H4 Br2
C3 H4 Br4
C3 H4 ClFO3
C3 H4 ClF3
C3 H4 ClF3 O
C3 H4 ClF3 O2 S
C3 H4 Cl2 F2 O
C3 H4 Cl2 O
C3 H4 Cl2 O
C3 H4 Cl2 O2
C3 H4 Cl4
C3 H4 Cl4
C3 H4 Cl4
C3 H4 F2 O2
C3 H4 F4 O
C3 H4 F4 O
C3 H4 O
C3 H4 O
Compound
共Temperature range/K兲
共193–246兲
共153–238兲
共138 –189兲
共203–236兲
共200–260兲
1-propyne
共183–257兲
共257– 402兲
共303–361兲
共359– 402兲
共249–306兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
19.9
21.3
22.9
20.9
21.5
共231兲
共223兲
共174兲
共220兲
共245兲
23.0
20.8
21.2
21.9
23.2
22.1
23.9
21.6
23.4
21.4
共242兲
共272兲
共318兲
共374兲
共264兲
共275兲
共240兲
共338兲
共235兲
共230兲
A
A
A
A
A
共282兲
A
共433兲
A
共288兲
GS
共306兲
共316兲
A
共298兲
共313兲
共343兲
C
C
C
共335兲
I
共294兲
A
共307兲
A
共363兲
A
共298兲
共346兲
共291兲
C
A
共346兲
A
共315兲
A
共361兲
A
共288兲
GS
32.9
共303兲
I
47.9
50.3
53.6
共318兲
共313兲
共298兲
A
MM
MM
32.3
30.9
33.5
共265兲
共314兲
共223兲
A
42.0
共308兲
A
共162–255兲
共323– 400兲
共194 –250兲
共200–260兲
2,3-dibromopropylene
共267– 415兲
43.1
1,2,2,3-tetrabromopropane
共418 –580兲
57.7
carbonochloridic acid, 2-fluoroethyl ester
共273–333兲
46.6
1-chloro-3,3,3-trifluoropropane
共297–315兲
29.9
共301–341兲
33.7
2-chloro-1,1,2-trifluoroethyl methyl ether
34.4⫾0.1
33.4⫾0.1
31.1⫾0.1
trifluoromethanesulfinic acid, 2-chloroethyl ester
共320– 403兲
40.5
2,2-dichloro-1,1-difluoro-1-methoxyethane
共279–378兲
40.3
1,1-dichloroacetone
共292–382兲
35.8
1,3-dichloroacetone
共348 – 445兲
49.6
methyl dichloroacetate
47.7⫾0.1
共331– 481兲
44.9
共276 – 416兲
47.2
1,1,1,2-tetrachloropropane
共331– 469兲
42.3
1,1,1,3-tetrachloropropane
共300–377兲
57.8
1,2,2,3-tetrachloropropane
共346 – 415兲
42.8
methyl difluoroacetate
共273–333兲
41.9
2-difluoromethoxy-1,1-difluoroethane
共288 –328兲
2,2,3,3-tetrafluoro-1-propanol
共303–380兲
共298 –333兲
共298 –333兲
acrolein
共250–306兲
共304 –325兲
共208 –326兲
propargyl alcohol 共2-propyn-1-ol兲
共293–387兲
Method
A
MM
A
CAS registry number
Reference
关87/5兴
关47/5兴
关40/3兴关84/9兴
关30/5兴
关21/2兴关84/9兴
关74-99-7兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关67/13兴
关62/29兴
关33/8兴关84/9兴
关21/3兴
关513-31-5兴
关87/5兴关47/5兴
关54268-02-9兴
关87/5兴关70/16兴
关462-27-1兴
关87/5兴关48/14兴
关70/16兴
关460-35-5兴
关87/5兴
关72/7兴
关425-87-6兴
关84/2兴
关84/2兴
关84/2兴
关61915-99-9兴
关87/5兴关77/17兴
关99/16兴
关76-38-0兴
关87/5兴
关513-88-2兴
关87/5兴关70/5兴
关534-07-6兴
关87/5兴关70/5兴
关116-54-1兴
关72/41兴
关87/5兴关70/16兴
关47/5兴
关812-03-3兴
关87/5兴关70/16兴
关1070-78-6兴
关87/5兴
关13116-53-5兴
关87/5兴
关432-53-4兴
关87/5兴关48/14兴
关70/16兴
关32778-16-8兴
关02/19兴
关76-37-9兴
关87/5兴
关73/5兴
关73/5兴
关107-02-8兴
关87/5兴
关79/15兴
关87/5兴关47/5兴
关107-19-7兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
558
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 H4 O2
C3 H4 O2
C3 H4 O3
C3 H4 O3
C3 H4 S3
C3 H5 Br
C3 H5 Br
C3 H5 Br
C3 H5 Br3
C3 H5 Cl
C3 H5 Cl
C3 H5 Cl
C3 H5 Cl
C3 H5 Cl
C3 H5 ClO
C3 H5 ClO
C3 H5 ClO2
C3 H5 ClO2
C3 H5 Cl3
C3 H5 Cl3
C3 H5 Cl3
C3 H5 FO
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
53.1⫾4.2
45.3
32.7
共298兲
共356兲
共308兲
C
A
46.4
47.0⫾0.1
共339兲
共298兲
A
C
共396兲
共383兲
共423兲
共433兲
A
EB
EB
EB
共309兲
A
Method
acrylic acid
共341– 414兲
共293–343兲
␤-propiolactone 共2-oxetanone兲
共324 – 435兲
ethylene carbonate
共381– 437兲
59.6
共368 – 449兲
60.3
共368 – 449兲
56.3
共368 – 433兲
55.0
pyruvic acid
共294 – 438兲
51.4
trithiocarbonic acid, cyclic ethylene ester
共294 –303兲
82.9
allyl bromide
共297–338兲
32.2
31.7⫾0.1
31.0⫾0.1
30.4⫾0.1
cis 1-bromopropylene
共257–366兲
32.0
trans 1-bromopropylene
共262–372兲
32.5
1,2,3-tribromopropane
共390–595兲
50.8
共400– 478兲
50.2
allyl chloride
共203–318兲
33.1
共286 –317兲
30.0
1-chloropropene
共191–310兲
29.5
cis 1-chloropropene
共276 –332兲
27.9
共237–338兲
29.2
trans 1-chloropropene
共277–340兲
28.5
共241–343兲
29.7
2-chloropropene
共229–327兲
28.0
epichlorohydrin
共256 –391兲
42.9
chloroacetone
共316 –392兲
40.1
methyl chloroacetate
46.7⫾0.1
共318 – 402兲
45.5
共298 – 403兲
ethylchloroformate
共281–286兲
共281–286兲
1,1,1-trichloropropane
共244 –382兲
1,1,3-trichloropropane
共328 – 464兲
1,2,3-trichloropropane
共337– 477兲
共282– 431兲
1,2-epoxy-3-fluoropropane
共273–333兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共298兲
共312兲
共318兲
共330兲
共341兲
A, EB
C
C
C
共272兲
A
共277兲
A
共405兲
共415兲
A
共218兲
共301兲
A
共206兲
共291兲
共252兲
A
共292兲
共256兲
A
共244兲
A
共272兲
共331兲
A
共298兲
共333兲
C
A
46.7
共313兲
38.7⫾0.2
37.8⫾0.2
共283兲
共298兲
BG
BG
38.8
共259兲
A
41.8
共343兲
A
47.8⫾0.1
43.0
46.8
共298兲
共352兲
共297兲
C
A
39.9
共288兲
A, GS
CAS registry number
Reference
关79-10-7兴
关96/8兴
关87/5兴关73/14兴
关64/7兴
关127-17-3兴
关87/5兴
关66/19兴
关96-49-1兴
关87/5兴
关82/8兴
关82/8兴
关82/8兴
关127-17-3兴
关87/5兴关47/5兴
关822-38-8兴
关99/16兴
关106-95-6兴
关87/5兴关77/8兴
关77/8兴
关77/8兴
关77/8兴
关590-14-7兴
关87/5兴关70/16兴
关590-14-7兴
关87/5兴关70/16兴
关96-11-7兴
关87/5兴
关49/1兴关84/9兴
关107-05-1兴
关87/5兴
关44/5兴关84/9兴
关590-21-6兴
关47/5兴
关16136-84-8兴
关01/19兴
关87/5兴关70/16兴
关16136-85-9兴
关01/19兴
关87/5兴关70/16兴
关557-98-2兴
关87/5兴关70/16兴
关106-89-8兴
关47/5兴
关78-95-5兴
关87/5兴
关96-34-4兴
关72/41兴
关87/5兴关67/6兴
关84/9兴
关28/2兴关84/9兴
关541-41-3兴
关80/2兴
关80/2兴
关7789-89-1兴
关87/5兴关47/5兴
关20395-25-9兴
关87/5兴关70/16兴
关96-18-4兴
关89/10兴
关87/5兴关70/16兴
关47/5兴
关503-09-3兴
关87/5兴关48/14兴
关70/16兴
ENTHALPIES OF VAPORIZATION
559
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 H5 FO2
C3 H5 F3 O
C3 H5 F3 O
C3 H5 F3 O2 S
C3 H5 F3 S2
C3 H5 N
C3 H5 NO
C3 H5 NO
C3 H5 NO
C3 H5 NO
C3 H5 NO2
C3 H5 NO2
C3 H5 NS
C3 H5 NS
C3 H5 N3 O9
C3 H5 P
C3 H6
C3 H6
C3 H6 BrCl
C3 H6 BrNO
C3 H6 Br2
Compound
共Temperature range/K兲
methyl fluoroacetate
共273–333兲
1,1,2-trifluoro-1-methoxyethane
共276 –317兲
1,1,1-trifluoro-2-propanol
共292–333兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
42.7
共288兲
A, GS
31.1
共291兲
I
44.2
共307兲
A, MM
共298兲
MM
共294 –333兲
44.8
trifluoromethylsulfinic acid, trifluoromethyl ester
37.2
ethyl共trifluoromethyl兲 disulfide
共253–303兲
33.8
propionitrile
共288 –371兲
36.1
共308 –363兲
36.7
共189–295兲
36.5
共308 –370兲
35.9
acrylamide
共357– 413兲
61.5
共373– 413兲
76.5
methoxyacetonitrile
共285–316兲
41.7⫾0.6
2-cyanoethanol
共331– 494兲
53.4
2-propenal oxime
共303–381兲
42.2
1-nitropropylene
共301–373兲
37.1
共273–333兲
44.1
2-nitropropylene
共273–333兲
38.2
ethyl isothiocyanate
共283– 404兲
40.2
共283–323兲
39.8
ethyl thiocyanate
共358 – 422兲
44.2
glycerol trinitrate
共293–373兲
104.5
共400–524兲
58.6
2-propynylphosphine
共228 –273兲
36.8
cyclopropane
共195–225兲
21.8
共358 –398兲
20.4
共297–359兲
19.9
共188 –239兲
20.3
共239–298兲
19.9
共183–241兲
21.1
propylene
共297–363兲
18.7
共104 –161兲
22.2
共228 –271兲
18.7
共270–327兲
18.5
共325–363兲
18.8
共161–242兲
19.2
共298 – 423兲
18.7
共166 –226兲
19.6
共236 –283兲
19.3
1-bromo-3-chloropropane
共326 – 488兲
42.0
2-bromo-2-nitrosopropane
共239–356兲
41.0
1,1-dibromopropane
共370兲
共268兲
A
共303兲
共326兲
共280兲
共323兲
A
BG
共372兲
共388兲
A
A
共298兲
GS
共346兲
A
共318兲
A
共337兲
共288兲
A
共288兲
A
共298兲
共298兲
A
共373兲
A
共308兲
共415兲
A
共250兲
共210兲
共373兲
共312兲
共224兲
共254兲
共226兲
A
A
A
A
共312兲
共146兲
共256兲
共285兲
共340兲
共227兲
共360兲
共211兲
共268兲
A
A
A
A
A
A
共341兲
A
共254兲
A
CAS registry number
Reference
关453-18-9兴
关87/5兴关48/14兴
关70/16兴
关428-66-0兴
关02/19兴
关374-01-6兴
关87/5兴关73/5兴
关84/9兴
关73/5兴
关30957-43-8兴
关71/20兴
关691-05-4兴
关87/5兴关99/16兴
关107-12-0兴
关87/5兴
关71/2兴
关56/5兴关84/9兴
关49/1兴关84/9兴
关79-06-1兴
关87/5兴
关87/5兴
关1738-36-9兴
关95/11兴
关109-78-4兴
关87/5兴
关5314-33-0兴
关87/5兴
关3156-70-5兴
关84/22兴
关87/5兴关70/16兴
关4749-28-4兴
关87/5兴关70/16兴
关542-85-8兴
关87/5兴
关35/3兴关84/9兴
关542-90-5兴
关87/5兴关99/16兴
关55-63-0兴
关87/5兴
关47/5兴
关114596-02-0兴
关88/13兴
关75-19-4兴
关97/19兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关46/1兴关84/9兴
关115-07-1兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴关70/16兴
关53/17兴
关39/2兴
关21/2兴关84/9兴
关109-70-6兴
关87/5兴关70/16兴
关7119-91-7兴
关87/5兴关70/16兴
关598-17-4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
560
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共322– 449兲
C3 H6 Br2
C3 H6 Br2
C3 H6 Br2 O
C3 H6 Cl2
C3 H6 Cl2
C3 H6 Cl2
1,2-dibromopropane
共312– 403兲
共310– 400兲
共329– 456兲
共266 – 415兲
1,3-dibromopropane
共307– 437兲
共351– 487兲
共283– 440兲
2,3-dibromo-1-propanol
共330– 492兲
1,1-dichloropropane
共310–360兲
共282–399兲
1,2-dichloropropane
共294 – 406兲
共300–370兲
共239–373兲
共321–369兲
共288 –373兲
1,3-dichloropropane
共330– 400兲
C3 H6 Cl2
C3 H6 Cl2 O
C3 H6 Cl2 O
C3 H6 F2
C3 H6 F2
C3 H6 F2 O
C3 H6 F3 NS
C3 H6 F3 NS
C3 H6 F3 OP
C3 H6 F3 OP
C3 H6 F3 O2 P
C3 H6 F3 PS
C3 H6 F3 PS
共307– 435兲
2,2-dichloropropane
共295–340兲
共267–378兲
2,3-dichloro-1-propanol
共384-419兲
1,3-dichloro-2-propanol
共301– 448兲
1,1-difluoropropane
共219–311兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
42.5
共337兲
A, EST
41.4
42.2
42.3⫾0.7
44.6
42.8
共327兲
共298兲
共298兲
共344兲
共281兲
A
47.6
47.3⫾0.1
46.7⫾0.1
46.1⫾0.1
45.5⫾0.1
44.8⫾0.1
46.6
47.8
45.3
共298兲
共308兲
共315兲
共323兲
共330兲
共338兲
共322兲
共366兲
共298兲
GC
C
C
C
C
C
A
A
57.3
共345兲
A
35.2
35.5
共298兲
共297兲
A, EST
38.4⫾0.3
36.3
36.1⫾0.1
39.4
34.7
34.3
共298兲
共298兲
共298兲
共254兲
共336兲
共303兲
EB
41.0
41.0
40.6⫾0.1
39.0
共298兲
共298兲
共298兲
共322兲
GC
32.1
33.2
共298兲
共282兲
A
A
48.5
共399兲
A
50.4
共316兲
A
27.2
共234兲
A, EST
共226兲
A
共303兲
I
2,2-difluoropropane
共211–302兲
25.6
1,1-difluoro-2-methoxyethane
共288 –322兲
31.8
N,N-dimethyl-trifluoromethanesulfphenamide
共223–295兲
30.2
dimethyl共trifluoromethylthio兲amine
共273–329兲
31.1
methyl共trifluoromethyl兲phosphinous acid, methyl ester
共232–285兲
33.9
dimethyl共trifluoromethyl兲phosphine oxide
共347–360兲
52.4
共trifluoromethyl兲phosphonic acid, dimethyl ester
共237–318兲
37.4
methyl共trifluoromethyl兲phosphinothious acid, methyl ester
共273–313兲
38.4
dimethyl共trifluoromethyl兲phosphine sulfide
共323–357兲
47.2
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
EB
A
C
A
C
A
共259兲
共288兲
A
共258兲
共353兲
共252兲
共293兲
共340兲
A
CAS registry number
Reference
关87/5兴关56/16兴
关70/16兴
关78-75-1兴
关87/5兴
关91/2兴关75/16兴
关75/15兴
关87/5兴关70/16兴
关47/5兴
关109-64-8兴
关94/19兴
关92/11兴
关92/11兴
关92/11兴
关92/11兴
关92/11兴
关87/5兴
关87/5兴关70/16兴
关47/5兴
关96-13-9兴
关87/5兴关47/5兴
关78-99-9兴
关67/11兴关91/2兴
关87/5兴关56/16兴
关70/16兴
关78-87-5兴
关97/8兴
关91/2兴
关89/10兴
关87/5兴
关49/1兴
关33/5兴
关142-28-9兴
关94/19兴
关87/11兴关91/2兴
关89/10兴
关87/5兴关70/16兴
关594-20-7兴
关87/11兴关91/2兴
关87/5兴关70/16兴
关616-23-9兴
关87/5兴
关96-23-1兴
关87/5兴关47/5兴
关430-81-5兴
关87/5兴关56/16兴
关70/16兴
关420-45-1兴
关87/5兴关70/16兴
关461-57-4兴
关02/19兴
关60/24兴
关62067-13-4兴
关87/5兴关99/16兴
关26348-84-5兴
关70/26兴
关26348-91-4兴
关70/26兴
关684-56-0兴
关87/5兴关61/14兴
关26348-86-7兴
关70/26兴
关26348-92-5兴
关70/26兴
ENTHALPIES OF VAPORIZATION
561
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 H6 I2
C3 H6 N2 O4
C3 H6 N2 O4
C3 H6 N2 O6
C3 H6 N2 O6
C3 H6 N6 O6
C3 H6 O
C3 H6 O
C3 H6 O
C3 H6 O
C3 H6 O
C3 H6 O
C3 H6 O
C3 H6 O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
54.1
共298兲
GC
共338兲
A
共378兲
A
共303兲
A
共303兲
A, GS
共513兲
A
共298兲
CGC
共298兲
C
共344兲
共228兲
共254兲
共338兲
共389兲
共472兲
共373兲
共423兲
共473兲
共498兲
共300兲
共319兲
共274兲
A
A
A
A
A
A
C
C
C
C
EB
1,3-diiodopropane
1,1-dinitropropane
共323–383兲
57.9
2,2-dinitropropane
共363–553兲
46.3
1,2-propanediol dinitrate
共288 –328兲
63.8
1,3-propanediol dinitrate
共293–313兲
74.3⫾4.6
hexahydro-1,3,5-trinitro-1,3,5-triazine
共503–523兲
84.4
2-propen-1-ol
共323–373兲
47.3
oxetane
29.8
acetone
共329– 488兲
29.9
共178 –243兲
32.9
共203–269兲
33.8
共323–379兲
30.6
共374 – 464兲
29.5
共457–508兲
29.7
26.1
21.7
15.3
9.2
共285–329兲
31.9
共305–333兲
31.8
共259–351兲
32.8
共261–328兲
共278 –293兲
共310–329兲
共204 –339兲
共204 –339兲
共204 –339兲
allyl alcohol
共310–340兲
共253–370兲
共283–313兲
methyl vinyl ether
共278 – 412兲
propanal
共263–373兲
共286 –321兲
共290–322兲
共250–330兲
propylene oxide
共225–308兲
共292–345兲
共249–308兲
共285–322兲
共243–306兲
1,3-dioxolane
共305–347兲
共280–323兲
A
31.3
32.7
32.6
31.1
35.0
32.1
30.7
共298兲
共276兲
共285兲
共319兲
共253兲
共293兲
共313兲
44.6
46.7
NA
44.8
共325兲
共268兲
23.4
共293兲
A
31.5
NA
28.3
29.4
30.3
29.6
30.3
31.9
共278兲
共301兲
共321兲
共303兲
共286兲
共298兲
共305兲
共265兲
A
EB
31.6
28.5
27.9
30.1
28.2
32.9
共240兲
共307兲
共298兲
共264兲
共303兲
共273兲
34.6
35.8
共326兲
共295兲
A, EB
MG
MG
MG
A
共298兲
A
C
A
CAS registry number
Reference
关627-31-6兴
关94/19兴
关601-76-3兴
关87/5兴
关595-49-3兴
关87/5兴
关6423-43-4兴
关87/5兴关70/16兴
关3457-90-7兴
关87/5兴关57/5兴
关121-82-4兴
关87/5兴
关107-18-6兴
关95/21兴
关503-30-0兴
关81/8兴
关67-64-1兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关86/18兴
关86/18兴
关86/18兴
关86/18兴
关86/10兴
关84/23兴
关87/5兴关74/6兴
关75/8兴
关75/8兴
关87/5兴关72/6兴
关63/25兴
关57/3兴
关26/7兴
关26/7兴
关26/7兴
关107-18-6兴
关02/45兴
关87/5兴
关36/2兴
关35/3兴
关107-25-5兴
关87/5兴
关123-38-6兴
关77/24兴
关74/8兴
关72/4兴
关72/4兴
关72/4兴
关72/4兴
关87/5兴关70/16兴
关87/5兴关51/8兴
关75-56-9兴
关87/5兴关70/16兴
关66/3兴
关62/28兴
关59/1兴
关37/7兴
关35/5兴
关646-06-0兴
关89/3兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
562
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共321–357兲
共306 –346兲
共280–355兲
C3 H6 O2
C3 H6 O2
ethyl formate
共300–326兲
共327– 498兲
共213–336兲
methyl acetate
共260–351兲
共308 –338兲
共273–318兲
共274 –329兲
C3 H6 O2
propionic acid
共353–393兲
共343– 419兲
共414 –511兲
共345– 401兲
monomer
C3 H6 O3
C3 H6 O3
C3 H6 O3
C3 H6 O3
C3 H6 O3
C3 H6 O3
C3 H6 S
C3 H6 S
共328 – 437兲
2-methoxyacetic acid
共325– 477兲
methyl glycolate
共326 –381兲
共282– 425兲
dimethylcarbonate
共326 – 411兲
共311–397兲
peroxypropionic acid
共273–393兲
propylene ozonide
共261–296兲
1,3,5-trioxane
共329–386兲
2-methylthiirane
共272– 423兲
thiacyclobutane 共thietane兲
共275–393兲
共321– 404兲
C3 H7 Br
1-bromopropane
共301–344兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
33.7
33.7
34.1
35.6⫾0.4
共339兲
共326兲
共296兲
31.4
29.9
31.6⫾0.1
30.9⫾0.1
29.8⫾0.1
35.8
共313兲
共342兲
共304兲
共313兲
共328兲
共228兲
34.1
32.3⫾0.1
29.5⫾0.1
31.8
32.6⫾0.1
32.2⫾0.1
31.6⫾0.1
30.5⫾0.1
30.3⫾0.1
32.5
30.2
34.5
33.4
共275兲
共298兲
共343兲
共323兲
共298兲
共304兲
共313兲
共328兲
共331兲
共295兲
共330兲
共296兲
共289兲
A
C
C
DTA
C
C
C
C
C
54.9
47.0
60.6
46.4
56.0
31.1⫾0.1
55⫾2
48.3
共298兲
共358兲
共429兲
共360兲
共303兲
共298兲
共298兲
共343兲
CGC
A
A
A
54.5
共340兲
A
52.5⫾6.3
47.4
共298兲
共297兲
EB
A
36.4
37.7⫾0.2
共341兲
共298兲
EB
43.2
共288兲
A
36.9
共281兲
A
40.0
共344兲
A
34.6
共287兲
36.5
35.8
34.6
共290兲
共298兲
共336兲
A, EB
31.8
31.1⫾0.1
30.5⫾0.1
30.1⫾0.1
29.3⫾0.1
共316兲
共322兲
共332兲
共339兲
共352兲
A, EB
C
C
C
C
Method
A
C
C
C
A
BG
A
C
C
CAS registry number
Reference
关82/3兴
关80/18兴
关68/2兴关84/9兴
关59/23兴
关109-94-4兴
关93/8兴
关87/5兴
关76/14兴
关76/14兴
关76/14兴
关87/5兴关70/16兴
关79-20-9兴
关87/5兴
关80/13兴
关80/13兴
关80/8兴
关79/1兴
关77/12兴
关77/12兴
关77/12兴
关77/12兴
关76/8兴
关76/8兴
关71/2兴
关87/5兴关65/3兴
关70/16兴
关79-09-4兴
关95/21兴
关87/5兴
关87/5兴
关87/5兴
关83/13兴
关70/8兴
关70/8兴
关81/11兴
关625-45-6兴
关87/5兴关47/5兴
关96-35-5兴
关96/5兴
关87/5兴关47/4兴
关616-38-6兴
关02/23兴
关97/7兴关97/6兴
关4212-43-5兴
关87/5兴关51/10兴
关70/16兴
关87/5兴关56/18兴
关110-88-3兴
关87/5兴关65/4兴
关1072-43-1兴
关87/5兴关70/16兴
关99/16兴
关287-27-4兴
关99/16兴
关71/28兴
关87/5兴关53/8兴
关66/5兴
关106-94-5兴
关87/5兴关77/8兴
关77/8兴
关77/8兴
关77/8兴
关77/8兴
ENTHALPIES OF VAPORIZATION
563
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共250–368兲
C3 H7 Br
C3 H7 Cl
共220–344兲
共273–303兲
2-bromopropane
共323–363兲
共236 –328兲
共299–332兲
共211–333兲
共273–303兲
1-chloropropane
共250–320兲
共248 –320兲
C3 H7 Cl
C3 H7 ClO
C3 H7 ClO
C3 H7 ClO2
C3 H7 ClO2 S
C3 H7 ClS
C3 H7 F
C3 H7 F
C3 H7 I
共205–319兲
2-chloropropane
共239–310兲
共194 –309兲
共273–303兲
1-chloro-2-propanol
共308 –399兲
共308 –399兲
2-chloro-1-propanol
共316 –399兲
3-chloro-1,2-propanediol
共343– 409兲
1-propanesulfonyl chloride
共273–362兲
共362– 464兲
共243–273兲
methyl共2-chloroethyl兲 sulfide
共293–333兲
1-fluoropropane
共196 –289兲
2-fluoropropane
共190–264兲
1-iodopropane
共171–271兲
共271– 402兲
C3 H7 I
C3 H7 N
共237–375兲
2-iodopropane
共313–353兲
共173–262兲
共230–363兲
cyclopropylamine
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
31.9⫾0.1
34.1
共298兲
共265兲
C
A, EST
35.5
32.6
共235兲
共288兲
30.6
32.1
30.1
29.8⫾0.1
29.2⫾0.1
28.5⫾0.1
28.0⫾0.1
30.2⫾0.1
33.4
30.9
共298兲
共251兲
共314兲
共305兲
共318兲
共330兲
共338兲
共298兲
共226兲
共288兲
29.0
28.5⫾0.2
31.0
共298兲
共298兲
共263兲
33.1
共219兲
30.2
30.6
27.3
共254兲
共209兲
共288兲
A
45.0⫾2.2
42.2⫾1.9
共340兲
共380兲
EB
EB
45.0
共331兲
A
66.6
共358兲
52.3
49.9
60.1
共288兲
共377兲
共258兲
A
42.4
共308兲
A, GS
24.0
共274兲
A, EST
23.7
共249兲
A
37.8
36.3⫾0.1
36.8
共256兲
共298兲
共286兲
A
C
A, EST
37.0
共252兲
34.0
36.7
34.1⫾0.1
36.3
共298兲
共247兲
共298兲
共244兲
CGC
A
C
33.0
32.6
共288兲
共288兲
A
A
32.6
共288兲
A
CGC
A
EB
C
C
C
C
C
C
A
31.3⫾0.4
C3 H7 N
C3 H7 N
C3 H7 NO
allylamine
共273–303兲
共273–324兲
azetidine
共273–303兲
acetone oxime
CAS registry number
Reference
关66/2兴
关87/5兴关61/13兴
关70/16兴
关47/5兴
关06/1兴关84/9兴
关75-26-3兴
关95/21兴
关87/5兴
关87/5兴关77/8兴
关77/8兴
关77/8兴
关77/8兴
关77/8兴
关66/2兴
关47/5兴
关06/1兴关84/9兴
关540-54-5兴
关84/9兴关91/2兴
关77/1兴
关87/5兴关69/5兴
关70/16兴
关47/5兴
关75-29-6兴
关87/5兴
关47/5兴
关06/1兴关84/9兴
关127-00-4兴
关02/14兴
关02/14兴
关78-89-7兴
关87/5兴
关96-24-2兴
关96/13兴
关10147-36-1兴
关99/16兴
关99/16兴
关87/5兴关99/16兴
关87/5兴关48/9兴
关70/16兴
关460-13-9兴
关87/5兴关61/13兴
关70/16兴
关420-26-8兴
关87/5兴
关107-08-4兴
关87/5兴
关68/1兴
关87/5兴关61/13兴
关70/16兴
关47/5兴
关75-30-9兴
关95/21兴
关87/5兴
关68/1兴
关47/5兴
关765-30-0兴
关71/36兴
关107-11-9兴
关87/5兴
关87/5兴
关503-29-7兴
关87/5兴
关127-06-0兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
564
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 H7 NO
C3 H7 NO
C3 H7 NO
C3 H7 NO
C3 H7 NO
C3 H7 NO2
C3 H7 NO2
C3 H7 NO2
C3 H7 NO2
C3 H7 NO2
C3 H7 NO3
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
51.4
共345兲
A
60.3
共353兲
49.2
46.9
42.5
56.7
46.7
共316兲
共298兲
共370兲
共346兲
共318兲
A
A
58.4
共298兲
A
62.0
59.6
53.5
NA
共368兲
共348兲
共368兲
A
A
51.2
共326兲
A
56.6
共353兲
A
26.0
共260兲
A
43.9
42.6
共298兲
共308兲
CGC
A, EB
40.6
共346兲
43.9
40.9
共298兲
共299兲
CGC
A, EB
28.3
共260兲
A
35.3⫾0.1
39.7
共288兲
DSC
A
propyl nitrate
共273–343兲
41.7
共288兲
A
1-azidopropane
共253–298兲
31.1
共268兲
A
2-azidopropane
共253–298兲
33.2
共268兲
A
32.7
共241兲
18.8
19.5
22.1
19.0
19.2
18.9
18.77
20.0
共293兲
共233兲
共150兲
共266兲
共344兲
共327兲
共256兲
共216兲
49.0
共280兲
93⫾4.0
共359兲
ME, TE
30.1
37.0
共296兲
共231兲
A
A
Compound
共Temperature range/K兲
共338 –352兲
propionamide
共338 – 486兲
N,N-dimethyl formamide
共301– 426兲
共318 – 423兲
共331– 425兲
共303–363兲
N-ethylformamide
N-methylacetamide
共353– 428兲
共333– 443兲
共353– 479兲
propionaldehyde oxime
共313–339兲
ethyl carbamate
共338 – 457兲
isopropyl nitrite
共253–268兲
1-nitropropane
共313–353兲
共293– 405兲
共331– 404兲
2-nitropropane
共313–353兲
共284 –394兲
propyl nitrite
共253–268兲
isopropyl nitrate
共273–343兲
C3 H7 NO3
C3 H7 N3
C3 H7 N3
C3 H7 P
C3 H8
C3 H8 N2
C3 H8 N2 S
C3 H8 O
2-propenylphosphine
共210–273兲
propane
共278 –332兲
共165–248兲
共104 –165兲
共231–281兲
共329–369兲
共312–367兲
共166 –231兲
dimethyl ammonium cyanide
共251–295兲
1,3-dimethylthiourea
共342–375兲
methyl ethyl ether
共281– 433兲
共216 –299兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
A
A
A
CAS registry number
Reference
关87/5兴
关79-05-0兴
关47/5兴
关68-12-2兴
关87/5兴
关85/7兴关85/6兴
关79/21兴
关74/7兴关84/9兴
关68/3兴
关627-45-2兴
关85/7兴关85/6兴
关79-16-3兴
关93/2兴
关87/5兴
关87/5兴
关68/3兴
关627-39-4兴
关87/5兴
关51-79-6兴
关87/5兴关47/5兴
关541-42-4兴
关87/5兴关37/3兴
关108-03-2兴
关95/21兴
关87/5兴关56/15兴
关70/16兴
关49/1兴
关79-46-9兴
关75/21兴
关87/5兴关47/5兴
关56/15兴关70/16兴
关543-67-9兴
关87/5兴关37/3兴
关1712-64-7兴
关99/12兴
关87/5兴关57/2兴
关70/16兴
关627-13-4兴
关87/5兴关57/2兴
关70/16兴
关22293-25-0兴
关87/5兴关64/5兴
关84/9兴
关691-57-6兴
关87/5兴关64/5兴
关84/9兴
关81637-99-2兴
关88/13兴
关74-98-6兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关80/1兴
关71/28兴
关38/4兴
关87/5兴关73/10兴
关94/21兴
关540-67-0兴
关87/5兴
关87/5兴
ENTHALPIES OF VAPORIZATION
565
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C3 H8 O
Compound
共Temperature range/K兲
共281– 438兲
共278 –281兲
共182–280兲
1-propanol
共323–373兲
共303–370兲
共360–377兲
共200–228兲
共356 –376兲
共369– 407兲
共401– 482兲
共478 –507兲
共243–303兲
共275–373兲
共333–377兲
共292–370兲
共288 –348兲
共338 –378兲
共405–537兲
共343–385兲
共321–367兲
C3 H8 O
2-propanol
共322–355兲
共300–355兲
共195–228兲
共347–368兲
共350–383兲
共379– 461兲
共453–508兲
共273–374兲
共325–362兲
共288 –348兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
37.1
NA
26.3
共296兲
A
41.2
35.2
29.4
21.0
11.4
49.2
47.0
42.9
48.0
43.5
42.3
40.1
36.5
46.3
49.3
46.4⫾0.1
45.7⫾0.1
44.9⫾0.1
44.0⫾0.1
43.2⫾0.1
42.4⫾0.1
47.49⫾0.02
44.7
46.9
46.7
47.3⫾0.1
44.3
46.6
40.7
44.1
43.9⫾0.1
42.3⫾0.1
41.2⫾0.1
40.3⫾0.1
39.7⫾0.1
45.5
43.2
共371兲
共423兲
共453兲
共498兲
共528兲
共298兲
共318兲
共375兲
共214兲
共366兲
共384兲
共416兲
共492兲
共298兲
共290兲
共313兲
共323兲
共333兲
共343兲
共353兲
共363兲
共298兲
共348兲
共307兲
共303兲
共298兲
共353兲
共298兲
共420兲
共358兲
共343兲
共360兲
共370兲
共378兲
共384兲
共366兲
共354兲
43.2
39.8
29.7
23.7
16.5
10.5
40.4
44.8
50.3
42.0
41.3
39.2
35.3
45.7
43.1
45.34⫾0.02
45.5
45.2⫾0.1
42.7⫾0.1
41.0⫾0.1
39.8⫾0.1
38.9⫾0.1
共337兲
共355兲
共423兲
共453兲
共483兲
共503兲
共265兲
共315兲
共213兲
共355兲
共365兲
共394兲
共468兲
共288兲
共340兲
共298兲
共303兲
共298兲
共330兲
共346兲
共355兲
共363兲
CGC
A
A
A
A
A
C
C
C
C
C
C
C
EB
DTA
C
EB
C
C
C
C
C
C
A
A
A
A
A
A, EB
C
C
C
C
C
C
CAS registry number
Reference
关87/5兴
关67/7兴
关47/5兴
关71-23-8兴
关00/24兴
关00/24兴
关00/24兴
关00/24兴
关00/24兴
关95/21兴
关95/14兴
关90/10兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关83/14兴
关73/26兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关71/27兴
关70/2兴关87/5兴
关69/5兴
关67/10兴
关66/2兴
关63/8兴
关63/2兴
关63/20兴
关61/18兴
关61/18兴
关61/18兴
关61/18兴
关61/18兴
关61/18兴
关59/3兴
关57/21兴
关67-63-0兴
关02/26兴
关00/25兴
关00/25兴
关00/25兴
关00/25兴
关00/25兴
关99/32兴
关95/14兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关73/26兴
关87/5兴关70/2兴
关71/27兴
关67/10兴
关66/2兴
关64/23兴
关64/23兴
关64/23兴
关64/23兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
566
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共329–363兲
共395–508兲
C3 H8 OS2
C3 H8 O2
C3 H8 O2
C3 H8 O2
C3 H8 O2
C3 H8 O2
C3 H8 O3
共354 – 420兲
共273–363兲
2,3-dimercaptopropanol
共353– 413兲
2-methoxyethanol
共333– 423兲
共329–396兲
dimethoxymethane
共273–316兲
共273–318兲
共296 –314兲
共273–308兲
1,2-propanediol
共365– 496兲
共365– 496兲
共365– 496兲
共365– 496兲
共318 – 461兲
共353– 403兲
共403– 460兲
1,3-propanediol
共332– 448兲
共383– 433兲
共433– 488兲
propylene glycol
共373– 408兲
glycerol
共469–563兲
共291–341兲
共293–343兲
C3 H8 S
共456 –553兲
ethyl methyl sulfide
共253–363兲
共296 –373兲
C3 H8 S
1-propanethiol
共254 –364兲
共297–375兲
C3 H8 S
共284 –340兲
2-propanethiol
共242–348兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
42.8
44.0
39.1
43.2
41.7
39.8
41.1
44.4
共344兲
共298兲
共410兲
共324兲
共339兲
共355兲
共369兲
共298兲
61.2
共382兲
42.8
45.2⫾0.2
42.9
共348兲
共298兲
共344兲
A
C
31.2
29.8
30.3
30.1
共288兲
共288兲
共305兲
共288兲
A
A
60.0⫾0.3
56.2⫾0.2
52.0⫾0.3
47.5⫾0.6
58.6
58.2
56.0
共380兲
共420兲
共460兲
共500兲
共333兲
共378兲
共431兲
EB
EB
EB
EB
A
72.4⫾0.3
57.2
63.3
60.4
共298兲
共347兲
共408兲
共460兲
C
A
66.5
共413兲
TGA
91.7⫾0.9
78.5
86.8
67.5
66.8
66.2
65.5
64.8
85.8
共298兲
共484兲
共316兲
共343兲
共353兲
共363兲
共373兲
共383兲
共308兲
C
A
ME
GC
GC
GC
GC
GC
ME
86.0
共471兲
33.7
31.5
31.8
31.8
共268兲
共298兲
共311兲
共298兲
30.3
共338兲
33.7
31.9
31.8
共269兲
共298兲
共312兲
31.6⫾0.1
30.7⫾0.1
29.5⫾0.1
31.5
共303兲
共320兲
共341兲
共312兲
31.9
共257兲
Method
EB
C
C
C
C
A, EB
A, EB
C
C
C
CAS registry number
Reference
关63/8兴
关63/2兴
关63/20兴
关63/28兴
关63/28兴
关63/28兴
关55/4兴
关28/5兴
关59-52-9兴
关99/16兴关87/5兴
关109-86-4兴
关87/5兴
关71/5兴
关56/6兴
关109-87-5兴
关87/5兴
关87/5兴
关76/20兴
关49/2兴
关57-55-6兴
关02/17兴
关02/17兴
关02/17兴
关02/17兴
关87/5兴关47/5兴
关35/4兴
关35/4兴
关504-63-2兴
关88/14兴
关87/5兴关47/5兴
关35/4兴
关35/4兴
关87/18兴
关56-81-5兴
关88/10兴
关87/5兴
关77/11兴
关77/34兴
关77/34兴
关77/34兴
关77/34兴
关77/34兴
关87/5兴关62/18兴
关70/16兴
关1886/1兴
关624-89-5兴
关99/16兴
关81/12兴
关87/5兴关51/4兴
关71/28兴
关66/5兴关54/11兴
关35/2兴
关107-03-9兴
关99/16兴
关71/28兴
关87/5兴关56/7兴
关66/5兴关54/11兴
关56/7兴
关56/7兴
关56/7兴
关33/7兴
关75-33-2兴
关99/16兴
ENTHALPIES OF VAPORIZATION
567
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共283–358兲
C3 H8 S2
C3 H9 N
1,3-propanedithiol
共338 – 446兲
共377– 446兲
C3 H9 NO
C3 H9 NO
C3 H9 NO
C3 H9 NO
C3 H9 O3 P
C3 H9 O3 P
C3 H9 O4 P
C3 H9 P
C3 H10N2
C3 H10N2
C3 H10N2
C3 N2 O
C3 O2
C3 S2
C4 BrClF9 N
C4 BrF6 N
C4 BrF8 N
C4 BrF9 O3 S
Method
29.5
30.1
共298兲
共298兲
A, EB
50.9
41.6
49.7
共353兲
共398兲
共298兲
28.4
27.2
29.7
共298兲
共313兲
共292兲
A, EB, IPM
31.3
30.1
28.9
31.3
共298兲
共313兲
共328兲
共311兲
A, EB, IPM
23.0
24.1
24.6
24.5
共368兲
共288兲
共261兲
共250兲
A
C
A
propylamine
共296 –350兲
C3 H9 N
Mean temperature
(T m /K)
isopropylamine
共277–334兲
C3 H9 N
⌬ vapH m
共kJ mol⫺1兲
trimethylamine
共333– 403兲
共273–313兲
共193–276兲
2-共methylamino兲ethanol
共340– 461兲
57.0⫾0.5
共298兲
1-amino-2-propanol
共306 – 431兲
51.6
共321兲
N-methoxy dimethyl amine 共trimethylhydroxylamine兲
共194 –297兲
28.0
共282兲
2-methoxyethyl amine
共278 –318兲
38.8
共293兲
methylphosphonic acid, dimethyl ester
共336 – 408兲
64.0
共351兲
trimethyl phosphite
共302–342兲
42.5
共317兲
共422– 494兲
32.8
共437兲
trimethyl phosphate
共296 – 466兲
48.8
共311兲
trimethyl phosphine
共248 –310兲
28.9
共263兲
28.0⫾2.1
1,3-diaminopropane
50.2⫾0.1
共298兲
(dl) 1,2-propanediamine
共293–393兲
42.2
共308兲
共242–293兲
47.2
共278兲
共242–293兲
43.9⫾0.2
共298兲
44.2⫾0.2
共298兲
trimethylhydrazine
共257–287兲
34.6
共272兲
33.4⫾0.1
共292兲
carbonyl cyanide
共250–291兲
37.5
共276兲
carbon suboxide
共161–249兲
26.2
共234兲
carbon subsulfide
共287–383兲
45.1
共302兲
1,1,2-trifluoro-2-chloro-2-bromo-N,N-bis共trifluoromethyl兲ethylamine
共329–364兲
33.1
共344兲
2-bromo-N,N-bis共trifluoromethyl兲ethynylamine
共311–329兲
30.4
共320兲
N,N-bis共trifluoromethyl兲-2,2-difluoro-1-bromovinylamine
共293–320兲
31.2
共320兲
2-bromo-2-fluorosulfatooctafluorobutane
EB
A
A
A
A
EB
A
A
A
C
A
A, IPM
IPM
IPM
C
A
A
A
A
A
A
CAS registry number
Reference
关71/28兴
关87/5兴关54/2兴
关66/5兴关54/11兴
关109-80-8兴
关99/16兴
关87/5兴
关62/11兴
关75-31-0兴
关79/9兴
关79/9兴
关87/5兴关68/4兴
关70/16兴
关107-10-8兴
关79/9兴
关79/9兴
关79/9兴
关87/5兴关68/4兴
关70/16兴
关75-50-3兴
关50/9兴
关45/1兴
关87/5兴关44/6兴
关44/6兴
关109-83-1兴
关97/8兴
关78-96-6兴
关87/5兴
关5669-39-6兴
关87/5兴关57/4兴
关109-85-3兴
关87/5兴
关756-79-6兴
关87/5兴关55/5兴
关121-45-9兴
关90/9兴
关87/5兴
关512-56-1兴
关87/5兴关47/5兴
关594-09-2兴
关87/5兴
关57/23兴关62/15兴
关109-76-2兴
关69/2兴
关78-90-0兴
关87/5兴
关87/5兴关75/4兴
关75/4兴
关65/8兴关70/11兴
关1741-01-1兴
关55/6兴
关55/6兴
关1115-12-4兴
关87/5兴关48/16兴
关504-64-3兴
关87/5兴关65/5兴
关627-34-9兴
关87/5兴
关87/5兴
关22130-38-7兴
关87/5兴
关17727-57-4兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
568
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 BrF10N
C4 Br2 Cl2 F6
C4 Br2 F9 N
C4 ClF8 N
C4 ClF10N
C4 ClF10N
C4 ClF12NS
C4 Cl2 F6
C4 Cl2 F6
C4 Cl2 F6
C4 Cl2 F7 N
C4 Cl3 F7
C4 Cl4 F4
C4 Cl4 F6 O
C4 Cl6
C4 Cl6 O3
C4 F6 O3
C4 F6
C4 F7 NO
C4 F7 NO
C4 F7 NO3 S
C4 F8
C4 F8
C4 F8 N2 O2 S
C4 F8 N2 O3
C4 F8 OS
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共313–372兲
43.5
共342兲
1,1,2,2-tetrafluoro-2-bromo-N,N-bis共trifluoromethyl兲ethylamine
共289–329兲
30.4
共304兲
1,4-dibromo-2,3-dichloro-1,1,2,3,4,4-hexafluorobutane
47.7⫾0.1
共308兲
46.9⫾0.1
共315兲
1,2-dibromo-1,2,2-trifluoro-N,N-bis共trifluoromethyl兲ethylamine
共326 –366兲
34.3
共341兲
2-chloro-1,2-difluoro-N,N-bis共trifluoromethyl兲vinylamine
共273–312兲
29.1
共288兲
N-chloro-1,1,2,2,2-pentafluoro-N-共pentafluoroethyl兲ethanamine
27.2
共325兲
N-chloro-1,1,1,2,3,3,3-heptafluoro-N-共trifluoromethyl兲-2-propanamine
28.9
共325兲
chlorodifluoro关1,1,1,2,3,3,3-heptafluoro-2-propanaminoto共2-兲兴-共trifluoromethyl兲 sulfur
37.7
共402兲
1,4-dichloro-hexafluoro-2-butene
共279–330兲
34.0
共294兲
cis 2,3-dichloro-hexafluoro-2-butene
共298 –341兲
32.5
共313兲
trans 2,3-dichloro-hexafluoro-2-butene
共298 –340兲
32.2
共313兲
2,3,4,4-tetrafluoro-2,3-dichloro-共trifluoromethyl兲azetidine
共273–333兲
32.6
共288兲
2,3,3-trichloroheptafluorobutane
33.3
35.6
共298兲
共302– 446兲
36.4
共317兲
1,2,3,4-tetrachlorotetrafluoro-1-butene
共362– 414兲
39.4
共377兲
trichloromethyl 2-chloro-1,1,2,3,3,3-hexafluoropropyl ether
共325– 403兲
40.3
共340兲
42.8⫾0.7
共298兲
perchloro-1,3-butadiene
共343– 484兲
58.6
共358兲
共343– 473兲
60.4
共358兲
trichloroacetic anhydride
共329– 496兲
56.0
共344兲
trifluoroacetic anhydride
共271–312兲
34.7
共286兲
hexafluoro-1,3-butadiene
共273–343兲
25.9
共288兲
4,4-difluoro-3-共difluoromethylene兲-2-共trifluoromethyl兲-1,2-oxazetidine
共238 –283兲
31.1
共268兲
3,6-dihydro-2,2,3,3,5,6,6-heptafluoro-2H-1,4-oxazine
共249–293兲
27.3
共278兲
fluorosulfuric ester 3,3,3-trifluoro-2-共trifluoromethyl兲lactonitrile
共262–320兲
31.2
共277兲
perfluoro-1-butene
共203–279兲
28.9
共264兲
共250–293兲
U14.4
共265兲
perfluorocyclobutane
共289–348兲
23.5
共304兲
共343–388兲
23.2
共358兲
共233–388兲
25.0
共248兲
共234 –269兲
25.0
共254兲
共233–274兲
24.9
共259兲
N,N⬘-bis共trifluoroacetyl兲sulfur difluorodiimide
共328 –383兲
43.5
共355兲
perfluoro-2-共tetrafluoro-2-nitroethyl兲-1,2-oxazetidine
共273–343兲
31.0
共288兲
perfluorotetramethylene sulfoxide
37.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
关66/18兴
A
C
C
A
A
A
A
A
A
MM, A
A
A
EB
A
A
A
A
A
A
A
A
A
A
关87/5兴
关375-42-8兴
关92/11兴
关92/11兴
关17725-58-5兴
关87/5兴
关13747-22-3兴
关87/5兴
关54566-79-9兴
关75/19兴
关53684-04-1兴
关75/21兴
关62609-69-2兴
关77/15兴
关20972-44-5兴
关87/5兴
关2418-22-6兴
关87/5兴
关2418-21-5兴
关87/5兴
关87/5兴
关335-44-4兴
关59/28兴
关59/28兴
关87/5兴关56/12兴
关457-20-0兴
关87/5兴
关61136-57-0兴
关87/5兴
关76/15兴
关87-68-3兴
关87/5兴
关71/22兴关84/9兴
关4124-31-6兴
关87/5兴关47/5兴
关407-25-0兴
关87/5兴关62/4兴
关71/21兴
关685-63-2兴
关02/6兴
关87/5兴
关4777-13-3兴
关87/5兴
关26404-53-5兴
关87/5兴
关357-26-6兴
关87/5兴关71/21兴
关47/14兴关84/9兴
关115-25-3兴
关87/5兴
关87/5兴
关67/14兴
关62/22兴关84/9兴
关87/5兴关54/5兴
关78/22兴
A
关87/5兴
关42060-63-9兴
关73/38兴
ENTHALPIES OF VAPORIZATION
569
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 F8 O2 S
C4 F8 O4 S
C4 F8 S
C4 F8 S2
C4 F9 N
C4 F9 N
C4 F9 N
C4 F9 N
C4 F9 NO
C4 F9 NO
C4 F9 NO
C4 F9 NOS
C4 F9 NO2
C4 F9 NO2 S
C4 F9 NS
C4 F10
C4 F10OS
C4 F10OS
C4 F10O3 S
C4 F10O6 S2
C4 F10S
C4 F10S
C4 F11NOS
C4 F11NS
C4 F12N2 O
C4 F12N2 O
C4 F12N2 S
C4 F12OS
C4 F12O2 S
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
A
关42060-64-0兴
关73/38兴
关6069-35-8兴
关87/5兴关66/15兴
关706-76-3兴
关73/38兴
关710-65-6兴
关73/38兴
关453-22-5兴
关75/21兴
关13821-49-3兴
关87/5兴
A
关87/5兴
A
HG
关87/5兴
关32822-51-8兴
关71/18兴
A
关87/5兴
A
A, I
关87/5兴
关31340-35-9兴
关72/24兴
关15496-02-3兴
关87/5兴
关34556-29-1兴
关72/25兴
关31340-34-8兴
关72/24兴
关355-25-9兴
关87/5兴
关87/5兴
关87/5兴
关58/4兴
关58/4兴
关52/16兴关84/9兴
关33622-18-3兴
关71/34兴
关33622-19-4兴
关71/34兴
关5762-52-7兴
关87/5兴
关2261-44-1兴
关87/5兴关64/22兴
关87/5兴关64/22兴
关42069-60-6兴
关73/38兴
关33547-11-4兴
关71/34兴
关62609-62-5兴
关77/19兴
关37826-43-0兴
关87/5兴关72/21兴
A
关87/5兴关71/21兴
A
关87/5兴关71/21兴
关4101-59-1兴
关76/29兴
关33564-25-9兴
关99/16兴
关63465-11-2兴
关87/5兴关77/16兴
perfluorotetramethylene sulfone
31.1
heptafluorobutyric acid and fluorosulfuric acid anhydride
共268 –352兲
44.8
共283兲
perfluorotetramethylene sulfide
26.9
perfluoro-1,4-dithiane
33.0
1,1,1-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-methanamine
22.2
共288兲
perfluoro关N,N-dimethyl共vinylamine兲兴
共257–280兲
27.5
共268兲
perfluoro关N-methyl共propylidineamine兲兴
共245–280兲
26.6
共265兲
perfluoro关N-propyl共methylenenamine兲兴
共250–291兲
28.3
共276兲
nonafluorobutyramide
29.7
共306兲
2,2,4,4,5,5-hexafluoro-3-共trifluoromethyl兲oxazolidine
共253–293兲
27.4
共278兲
perfluoro关2,4-bis共trifluoromethyl兲-1,2-oxazetidine兴
共266 –289兲
25.9
共278兲
1,1,1-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-methanesulfinamide
36.4
共361兲
O-共trifluoroacetyl兲-N,N-bis共trifluoromethyl兲hydroxylamine
共234 –296兲
30.5
共281兲
N-共trifluoroacetyl兲-S,S-bis共trifluoromethyl兲sulfoximine
35.1
共363兲
1,1,1-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-methanesulfenamide
31.4
共324兲
perfluorobutane
共272–327兲
24.2
共287兲
共233–273兲
24.2
共258兲
共323–386兲
23.1
共338兲
共233–383兲
21.0
共293兲
共233–383兲
17.1
共333兲
共233–260兲
25.8
共247兲
heptafluoropropyl trifluoromethyl sulfoxide
33.6
bis共pentafluoroethyl兲 sulfoxide
35.1
fluorosulfuric acid, perfluoro共1-methylpropyl兲 ester
共294 –342兲
33.8
共309兲
1,1,1,2,3,4,4,4-octafluoro-2,3-bis共fluorosulfato兲butane
共316 –393兲
30.1
共331兲
共392– 411兲
27.1
共401兲
perfluoroetramethylene sulfur difluoride
41.5
heptafluoropropyl trifluoromethyl sulfide
27.7
difluoro共1,1,1,3,3,3-hexafluoro-2-propaniminato兲oxo共trifluoromethyl兲 sulfur
35.1
共396兲
fluoro共trifluoromethyl兲关2,2,2,1-tetrafluoro-1-共trifluoromethyl兲ethyl兴-imino sulfur
共300–333兲
32.4
共315兲
perfluoro共2,3-dimethyl兲-4-oxo-diazepentane
共276 –308兲
32.0
共291兲
perfluoro共2,4-dimethyl兲-4-oxo-diazepentane
共288 –318兲
30.1
共303兲
difluorobis关1,1,2,2,2-pentafluorothananaminato兴 sulfur
37.0
difluorooxobis共pentafluoroethyl兲 sulfur
共284 –341兲
33.8
共299兲
bis共trifluoromethyl兲bis共trifluoromethoxy兲 sulfur
共273–325兲
29.3
共288兲
CAS registry number
Reference
A
I
A
I
I
A
A
A
A
A
A
I
A, I
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
570
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 F12O3 S
C4 F12P2 S
C4 F12P4
C4 F12S
C4 F12S
C4 F13NOS
C4 F15N2 O2 P
C4 F16S2
C4 N4
C4 HBrF7 N
C4 HBrF9 N
C4 HBrF9 N
C4 HBr2 F6 N
C4 HCl2 F5 O2
C4 HF5
C4 HF6 N
C4 HF7 O2
C4 HF8 N
C4 HF8 N
C4 HF8 NO
C4 HF8 NOS
C4 HF9 N2 OS
C4 HF9 O2 S
C4 HF10N
C4 HF10N
C4 HF10NOS
C4 H2
C4 H2 BrF6 N
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
oxobis共trifluoromethyl兲bis共trifluoromethoxy兲 sulfur
共273–335兲
33.4
共288兲
di关bis共trifluoromethyl兲phosphino兴 sulfide
共273–335兲
42.2
共304兲
1,2,3,4-tetrakis共trifluoromethyl兲tetraphosphetane
共313–375兲
43.2
共328兲
difluorobis共pentafluoroethyl兲 sulfur
共284 –341兲
34.0
共299兲
32.2
difluoro共heptafluoropropyl兲 共trifluoromethyl兲 sulfur
32.8
trifluoro关1,1,1,2,3,3,3-heptafluoro-2-propanaminoato共2-兲兴-共trifluoromethanolato兲 sulfur
33.9
共389兲
phosphorous bis关bis共trifluoromethyl兲nitroxide兴 difluoride
共303–370兲
37.6
共336兲
hexadecafluoro-octahydro-1,4-dithiane
共323– 408兲
40.5
共365兲
dicyanoacetylene
共295–350兲
27.3
共310兲
1-bromo-2-fluoro-N,N-bis共trifluoromethyl兲vinylamine
共321–342兲
29.8
共331兲
2-bromo-1,1,2-trifluoro-N,N-bis共trifluoromethyl兲ethylamine
共308 –342兲
31.9
共323兲
2-bromo-1,2,2-trifluoro-N,N-bis共trifluoromethyl兲ethylamine
共301–332兲
33.8
共316兲
trans 1,2-dibromo-N,N-bis共trifluoromethyl兲vinylamine
共355–382兲
33.4
共369兲
3,4-dichloro-2,2,3,4,4-pentafluorobutyric acid
共373– 456兲
54.8
共388兲
3,3,4,4,4-pentafluoro-1-butyne
共203–261兲
23.6
共246兲
N,N-bis共trifluoromethyl兲ethynylamine
共229–271兲
26.0
共256兲
perfluorobutyric acid
共310– 426兲
50.1⫾0.2
共320兲
共310– 426兲
45.9⫾0.2
共360兲
共310– 426兲
41.0⫾0.5
共400兲
共329– 493兲
47.8
共344兲
共353–393兲
47.3
共368兲
N,N-bis共trifluoromethyl兲-1,2-difluorovinylamine
共276 –296兲
28.8
共286兲
N,N-bis共trifluoromethyl兲-2,2-difluorovinylamine
共274 –291兲
27.7
共282兲
2,2,3,3,5,5,6,6-octafluoromorpholine
共273–323兲
32.7
共288兲
2,2,3,3,4,4,5,5-octafluoro-1,1,2,3,4,5-hexahydro-1-iminothiophene-1-oxide
28.0
共397兲
1,1,1-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-methanesulfonimidamide
37.2
共388兲
trifluoromethanesulfinic acid, 2,2,2-trifluoro-1-共trifluoromethyl兲ethyl ester
39.3
共362兲
1,1,1,2,3,3,3-heptafluoro-N-共pentafluoroethyl兲ethanamine
26.4
共306兲
1,1,1,2,3,3,3-heptafluoro-N-共trifluoromethyl兲-2-propanamine
28.1
共309兲
S,S-bis共pentafluoroethyl兲sulfoximine
35.6
共366兲
1,3-butadiyne
共237–283兲
26.1
共268兲
共191–282兲
26.4
共267兲
共188 –234兲
33.4
共219兲
共195–273兲
25.4
共258兲
1-bromo-N,N-bis共trifluoromethyl兲vinylamine
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
A, I
关78/14兴
关66632-46-0兴
关87/5兴关78/14兴
T
A, SG
A
I
A
A
A
A
A
A
A
A
EB
EB
EB
A
A
A
A
A
I
HG
I
A
关64/31兴
关393-02-2兴
关87/5兴关58/10兴
关33622-15-0兴
关87/5兴
关71/34兴
关31206-31-2兴
关71/34兴
关65844-09-9兴
关78/14兴
关73/24兴
关4556-31-4兴
关99/16兴关73/38兴
关1071-98-3兴
关87/5兴
关25273-49-8兴
关87/5兴
关87/5兴
关4905-96-8兴
关87/5兴
关87/5兴
关375-07-5兴
关87/5兴关57/17兴
关7096-51-7兴
关87/5兴
关13747-21-2兴
关87/5兴
关375-22-4兴
关02/21兴
关02/21兴
关02/21兴
关87/5兴
关87/5兴
关13747-24-5兴
关87/5兴
关13747-23-4兴
关87/5兴
关375-17-7兴
关87/5兴
关77589-47-0兴
关81/15兴
关62609-65-8兴
关77/19兴
关52225-50-0兴
关74/25兴
关54566-81-3兴
关75/19兴
关53684-05-2兴
关75/21兴
关34556-24-6兴
关72/25兴
关460-12-8兴
关87/5兴关71/21兴
关47/5兴
关33/10兴关84/9兴
关26/3兴关84/9兴
关19451-87-7兴
ENTHALPIES OF VAPORIZATION
571
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H2 BrF6 N
C4 H2 BrF6 N
C4 H2 BrF8 N
C4 H2 BrF8 N
C4 H2 Br2 S
C4 H2 Cl2 O2
C4 H2 Cl2 S
C4 H2 F4
C4 H2 F8
C4 H2 F8 O
C4 H2 F6 OS
C4 H2 F6 O2
C4 H2 F7 S
C4 H2 F7 S
C4 H2 F8 O
C4 H2 N2 O4 S
C4 H2 N2 O4 S
C4 H2 O3
C4 H3 BrF7 N
C4 H3 BrS
C4 H3 BrS
C4 H3 ClF6 O2 S
C4 H3 ClS
C4 H3 Cl3 OS
C4 H3 F5 OS
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共303兲
A
共329兲
A
共327兲
A
共328兲
A
共328兲
A
共348兲
A, I
45.6
共303兲
A
49.9
36.2
40.7
33.7
共338兲
共338兲
共338兲
共348兲
A, I
共256兲
A
共269兲
EB
共298兲
I
共297兲
A
共330兲
HG
共300兲
A
共284兲
A
共298兲
I
共403兲
A
共288 –327兲
32.8
cis 2-bromo-N,N-bis共trifluoromethyl兲vinylamine
共314 –346兲
29.7
trans 2-bromo-N,N-bis共trifluoromethyl兲vinylamine
共314 –341兲
30.0
2-bromo-1,2-difluoro-N,N-bis共trifluoromethyl兲ethylamine
共323–348兲
32.4
2-bromo-2,2-difluoro-N,N-bis共trifluoromethyl兲ethylamine
共313–348兲
33.6
3,4-dibromothiophene
共333–374兲
32.1
trans fumaroyl chloride
共288 – 433兲
2,5-dichlorothiophene
共323– 425兲
共323– 425兲
共323– 425兲
共333–374兲
1,1,4,4-tetrafluoro-1,3-butadiene
共239–271兲
22.4
1,1,1,2,2,3,3,4-octafluorobutane
共260–278兲
28.9
2-difluoromethoxy-1,1,1,3,3,3-hexafluoropropane
共283–315兲
31.1
trifluorothioacetic acid S-共1,2,2-trifluoroethyl兲 ester
共282–322兲
34.3
trifluoroacetic acid, 2,2,2-trifluoroethyl ester
31.8
cis 2-fluoro-N,N-bis共trifluoromethyl兲vinylamine
共289–311兲
29.1
trans 2-fluoro-N,N-bis共trifluoromethyl兲vinylamine
共273–295兲
28.5
1,1,1,2,2,3,3-heptafluoro-3-共fluoromethoxy兲propane
共283–316兲
31.0
2,4-dinitrothiophene
共388 –523兲
59.7
2,5-dinitrothiophene
共388 –523兲
59.6
maleic anhydride
共336 – 475兲
49.1
共326 –350兲
54.8
共317– 475兲
56.7
2-bromo-2-fluoro-N,N-bis共trifluoromethyl兲ethylamine
共329–255兲
30.9
2-bromothiophene
共333–373兲
27.9
共342兲
A
共348兲
A, I
3-bromothiophene
共333–373兲
共348兲
A, I
28.9
共403兲
共351兲
共332兲
chlorosulfurous acid, 2,2,2-trifluoro-1-methyl-1-共trifluoromethyl兲ethyl ester
39.7
2-chlorothiophene
共313– 401兲
34.7
共328兲
共320– 401兲
36.9
共335兲
共333–374兲
34.4
共348兲
2,3,3-trichloro-2-propenethioic acid, O-methyl ester
共383– 423兲
64.8
trifluoroacetic acid, S-共2,2-difluoroethyl兲 ester
共282–322兲
39.3
A
A, I
GC
共297兲
A
CAS registry number
Reference
关87/5兴
关19483-21-7兴
关87/5兴
关19483-20-6兴
关87/5兴
关6857-63-2兴
关87/5兴
关6857-63-2兴
关87/5兴
关3141-26-2兴
关87/5兴关71/3兴
关99/16兴
关627-53-4兴
关87/5兴关47/5兴
关3172-52-9兴
关99/16兴
关99/16兴
关81/24兴
关87/5兴关71/3兴
关99/16兴
关407-70-5兴
关87/5兴
关662-35-1兴
关97/22兴
关26103-08-2兴
关02/19兴
关35709-12-7兴
关87/5兴关99/16兴
关407-38-5兴
关73/20兴
关25273-51-2兴
关87/5兴
关25211-47-6兴
关87/5兴
关184899-81-8兴
关02/19兴
关5347-12-6兴
关87/5兴关71/21兴
关99/16兴
关59434-05-8兴
关99/16兴
关108-31-6兴
关87/5兴
关49/28兴
关47/5兴
关25237-12-1兴
关87/5兴
关1003-09-4兴
关87/5兴关71/3兴
关99/16兴
关872-31-1兴
关87/5兴关71/3兴
关99/16兴
关57169-82-1兴
关75/41兴
关96-43-5兴
关99/16兴
关99/16兴关81/24兴
关87/5兴关71/3兴
关99/16兴
关76619-91-5兴
关80/24兴
关35709-11-6兴
关87/5兴关99/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
572
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H3 F6 NO2
C4 H3 F6 O2 P
C4 H3 F7 O
C4 H3 F7 O
C4 H3 F7 O
C4 H3 F7 O
C4 H3 F7 O
C4 H3 F7 O
C4 H3 F7 O2 S
C4 H3 IS
C4 H3 NO2 S
C4 H4
C4 H4 BrF6 N
C4 H4 Cl2
C4 H4 Cl2
C4 H4 Cl2 O2
C4 H4 Cl2 O3
C4 H4 Cl4 O2 S
C4 H4 F4 OS
C4 H4 F6 N2 S
C4 H4 F6 O
C4 H4 F6 O
C4 H4 F6 O
C4 H4 F6 O
C4 H4 F6 O
C4 H4 F6 O
C4 H4 F6 O
C4 H4 F6 O2 S
C4 H4 N2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
N,N-bis共trifluoromethyl兲acetamide-N-oxide
共268 –336兲
40.6
bis共trifluoromethyl兲acetoxyphosphine
共273–313兲
41.0
2,2,3,3,4,4,4-heptafluoro-1-butanol
共273–298兲
43.6
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共283兲
A
关22743-78-8兴
关87/5兴
共288兲
共286兲
1-共2,2-difluoroethoxy兲-1,1,2,2,2-pentafluoroethane
共288 –318兲
31.5
共303兲
1,1,2,2-tetrafluoro-1-共2,2,2-trifluoroethoxy兲ethane
共283–329兲
34.0
共298兲
1,1,2,2-tetrafluoro-3-共trifluoromethoxy兲propane
共288 –319兲
31.3
共303兲
1,1,1,3,3,3-hexafluoro-2-fluoromethoxypropane
共288 –331兲
34.1
共303兲
3-共difluoromethoxy兲-1,1,1,2,2-pentafluoropropane
共283–319兲
31.2
共298兲
fluorosulfurous acid, 2,2,2-trifluoro-1-methyl-1-共trifluoromethyl兲ethyl ester
36.4
2-iodothiophene
共333–374兲
29.0
共348兲
2-nitrothiophene
共378 – 443兲
48.6
共393兲
共321– 498兲
50.4
共336兲
1-butene-3-yne
共180–278兲
26.0
共236兲
2-bromo-N,N-bis共trifluoromethyl兲ethylamine
共323–356兲
31.0
共338兲
1,2-dichloro-1,3-butadiene
共260–308兲
33.3
共275兲
2,3-dichloro-1,3-butadiene
共299–368兲
33.8
共314兲
succinyl chloride
共312– 466兲
54.7
共327兲
chloroacetic acid anhydride
共340– 490兲
61.8
共355兲
3,3,4,4-tetrachlorotetrahydrothiophene-1,1-dioxide
共303–348兲
88.6
共318兲
trifluorothioacetic acid, S-共2-fluoroethyl兲 ester
共282–322兲
41.4
共297兲
2,2,2-trifluoro-N-methyl-N⬘-关共trifluoromethyl兲thio兴ethanimidamide
共339–387兲
34.9
共354兲
3-difluoromethoxy-1,1,2,2-tetrafluoropropane
共283–349兲
35.9
共298兲
1,1,1,3,3,3-hexafluoro-2-methoxypropane
共283–324兲
32.6
共298兲
1,1,1-trifluoro-2-共1,1,2-trifluoroethoxy兲ethane
共283–338兲
35.4
共298兲
1,1,1-trifluoro-2-共2,2,2-trifluoroethoxy兲ethane
共283–337兲
35.0
共298兲
1-共1,1-difluoroethoxy兲-1,1,2,2-tetrafluoroethane
共288 –352兲
38.1
共303兲
1,1,1,2,3,3-hexafluoro-3-methoxypropane
共288 –327兲
32.4
共303兲
1,1,2,2,3,3-hexafluoro-1-methoxypropane
共288 –341兲
34.5
共303兲
trifluoromethanesulfinic acid, 2,2,2-trifluoro-1-methylethyl ester
36.8
共375兲
pyrazine
共354 – 426兲
36.5⫾0.2
共380兲
共354 – 426兲
34.1⫾0.4
共420兲
共332–373兲
37.9
共352兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A, MM
I
I
I
I
I
A, I
A
A
A
A
A
A
A
A
A
A, I
I
I
I
I
I
I
I
HG
EB
EB
关64/4兴关84/9兴
关375-01-9兴
关87/5兴关71/21兴
关67/4兴
关171182-95-9兴
关02/19兴
关306-78-0兴
关02/19兴
关1683-81-4兴
关02/19兴
关28523-86-6兴
关02/19兴
关56860-81-2兴
关02/19兴
关57169-83-2兴
关75/41兴
关3437-95-4兴
关87/5兴关71/3兴
关99/16兴
关609-40-5兴
关99/16兴
关87/5兴
关689-97-4兴
关87/5兴关47/5兴
关1683-83-6兴
关87/5兴
关3574-40-1兴
关87/5兴
关1653-19-6兴
关87/5兴
关543-20-4兴
关87/5兴关47/5兴
关541-88-8兴
关87/5兴关47/5兴
关3737-41-5兴
关87/5兴关99/16兴
关35709-10-5兴
关87/5兴关99/16兴
关62067-10-1兴
关87/5兴关77/18兴
关99/16兴
关35042-99-0兴
关02/19兴
关13171-18-1兴
关02/19兴
关25449-61-0兴
关02/19兴
关333-36-8兴
关02/19兴
关50807-77-7兴
关02/19兴
关382-34-3兴
关02/19兴
关160620-20-2兴
关02/19兴
关52225-48-6兴
关74/25兴
关290-37-9兴
关02/17兴
关02/17兴
关95/4兴
ENTHALPIES OF VAPORIZATION
573
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H4 N2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
49.8⫾0.3
共298兲
C
53.5⫾0.4
共298兲
C
58.7
共414兲
A
64.3
共428兲
A
30.2
28.2
28.6
共253兲
共298兲
共290兲
A
42.9
42.9⫾0.1
共312兲
共298兲
A
C
57.3
共416兲
A
50.4
共391兲
A
35.8
34.8
34.6
34.1
33.7
33.6⫾0.1
32.7⫾0.1
31.5⫾0.1
32.6
共282兲
共348兲
共298兲
共315兲
共326兲
共319兲
共336兲
共357兲
共353兲
29.6
29.6
30.9
共253兲
共294兲
共308兲
A
A
36.1
共328兲
A
44.9
共283兲
49.0
51.0⫾0.1
47.5
共308兲
共298兲
共332兲
A
C
62.6
共383兲
A
40.6
共330兲
A
32.0
共305兲
A
42.0
共288兲
A
34.7
1,1,1,3,3-pentafluorobutane
共303–358兲
29.2
1,1,1,2,2-pentafluoro-3-methoxypropane
共283–321兲
31.6
1-共difluoromethoxy兲-1,1,2-trifluoroethane
共283–316兲
31.7
ethyl bis共trifluoromethyl兲phosphinite
共248 –328兲
33.2
3-butenenitrile
共293– 417兲
40.3
40.0
共254 –392兲
41.6
共335兲
HG
Compound
共Temperature range/K兲
pyrimidine
C4 H4 N2
pyridazine
C4 H4 N4 O7
furazandimethanol
dinitrate
共399– 433兲
furazandimethanol dinitrate, 2-oxide
共413– 453兲
furan
共238 –356兲
共227–323兲
共275–334兲
diketene
共297–388兲
C4 H4 N4 O8
C4 H4 O
C4 H4 O2
C4 H4 O3
C4 H4 O4
C4 H4 S
succinic anhydride
共401–534兲
1,4-dioxane-2,5-dione
共376 –513兲
thiophene
共267–381兲
共333–373兲
共300–366兲
共311–393兲
C4 H5 Cl
C4 H5 ClO
C4 H5 ClO3
C4 H5 Cl3 O2
C4 H5 Cl5
C4 H5 F2 I
C4 H5 F3 O
C4 H5 F3 OS
C4 H5 F3 O2
C4 H5 F5
C4 H5 F5 O
C4 H5 F5 O
C4 H5 F6 OP
C4 H5 N
共344 –363兲
2-chloro-1,3-butadiene
共243–263兲
共279–333兲
共293–333兲
methacryloyl chloride
共313–372兲
ethyl chloroglyoxylate
共268 – 408兲
ethyl trichloroacetate
共293– 440兲
共317–368兲
1,2,2,3,4-pentachlorobutane
共368 – 498兲
1,1-difluoro-4-iodo-1-butene
共318 –342兲
vinyl 2,2,2-trifluoroethyl ether
共293–317兲
trifluorothioacetic acid, S-ethyl ester
共273–313兲
trifluoroacetic acid, ethyl ester
I
EB
C
C
C
共318兲
共298兲
I
共298兲
I
共288兲
共308兲
共298兲
共268兲
A
CAS registry number
Reference
关289-95-2兴
关62/37兴
关289-80-5兴
关62/37兴
关57449-43-1兴
关87/5兴关75/18兴
关57449-44-2兴
关87/5兴关75/18兴
关110-00-9兴
关87/5兴
关70/36兴
关52/17兴关84/9兴
关674-82-8兴
关87/5兴
关68/19兴
关108-30-5兴
关87/5兴
关502-97-6兴
关87/5兴关47/5兴
关110-02-1兴
关99/16兴
关71/3兴
关71/28兴
关52/9兴
关49/7兴
关49/7兴
关49/7兴
关49/7兴
关45/8兴
关126-99-8兴
关87/5兴
关87/5兴关71/21兴
关64/7兴关84/9兴
关920-46-7兴
关87/5兴
关4755-77-5兴
关47/5兴
关515-84-4兴
关87/5兴
关72/41兴
关59/9兴关84/9兴
关2431-52-9兴
关87/5兴关68/29兴
关87/5兴
关406-90-6兴
关87/5兴
关383-64-2兴
关87/5兴
关383-63-1兴
关73/20兴
关406-58-6兴
关02/12兴
关378-16-5兴
关02/19兴
关69948-24-9兴
关02/19兴
关59/21兴
关109-75-1兴
关87/5兴
关69/14兴
关47/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
574
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H5 N
Compound
共Temperature range/K兲
共Z兲 2-butenenitrile
C4 H5 N
cis crotonitrile
共297– 405兲
共244 –381兲
trans crotonitrile
共292– 420兲
共254 –395兲
methacrylonitrile
共273–373兲
共229–363兲
cyclopropylcyanide
C4 H5 N
C4 H5 N
C4 H5 N
共310–391兲
共310–391兲
pyrrole
共285–329兲
共313–373兲
共338 – 440兲
C4 H5 NO
共333–373兲
N-deutero pyrrole
共285–329兲
3-methylisoxazole
C4 H5 NO
5-methylisoxazole
C4 H5 NO2
methyl cyanoacetate
共292–322兲
共385–573兲
succinimide
共416 –561兲
共388 –560兲
allyl isothiocyanate
共277–323兲
共370– 430兲
共283–323兲
C4 DH4 N
C4 H5 NO2
C4 H5 NS
C4 H5 NS
C4 H5 NS
C4 H5 N7 O12
C4 H6
C4 H6
Mean temperature
(T m /K)
40.0
共298兲
38.9
共298兲
37.1
39.0
共312兲
共259兲
A
39.7
40.5
共307兲
共268兲
A
36.5
35.4
共288兲
共243兲
A
41.9⫾0.1
39.4
39.8⫾0.4
共298兲
共325兲
共298兲
C
BG
BG
42.5
41.9
42.5
共300兲
共328兲
共353兲
I
A, EB, IPM
41.8
41.9
共348兲
42.9
共300兲
39.8⫾0.2
共298兲
C
39.7⫾0.2
共298兲
C
66.2⫾0.9
54.9
共298兲
共400兲
GS
A
66.9
73.5
共431兲
共403兲
A
47.6
56.8
42.1
共385兲
共298兲
39.4
40.0
共368兲
共357兲
A
共361兲
共298兲
A
C
共343兲
A
共276兲
共228兲
共298兲
共276兲
共273兲
A
A
共285兲
共203兲
共261兲
共330兲
共395兲
共298兲
共256兲
共235兲
A
A
A
A
A
共E兲 2-butenenitrile
C4 H5 N
C4 H5 N
⌬ vapH m
共kJ mol⫺1兲
2-methylthiazole
共353– 402兲
共342– 404兲
4-methylthiazole
共346 – 408兲
40.8
43.8⫾0.2
2,2,2-trinitro-N-共2,2,2-trinitroethyl兲ethanamine
共337–349兲
80.8
1,2-butadiene
共243–291兲
25.3
共204 –243兲
26.4
23.9
共184 –291兲
25.2
24.6⫾0.1
1,3-butadiene
共270–318兲
23.0
共193–213兲
25.7
共213–276兲
23.6
共315–382兲
22.4
共380– 425兲
22.9
21.1
共198 –271兲
23.7
共191–249兲
24.7
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
GC
A
C
CAS registry number
Reference
关627-26-9兴
关69/14兴
关1190-76-7兴
关69/14兴
关1190-76-7兴
关87/5兴
关47/5兴
关627-26-7兴
关87/5兴
关47/5兴
关126-98-7兴
关87/5兴
关47/5兴
关5500-21-0兴
关82/5兴
关71/2兴
关71/2兴
关109-97-7兴
关92/18兴
关71/3兴
关87/5兴关68/4兴
关67/10兴
关61/26兴
关47/5兴
关10162-82-0兴
关92/18兴
关30842-90-1兴
关78/9兴
关5765-44-6兴
关78/9兴
关105-34-0兴
关95/11兴
关87/5兴关71/21兴
关123-56-8兴
关87/5兴
关47/5兴
关57-06-7兴
关97/27兴
关87/5兴
关35/3兴关84/9兴
关99/16兴
关3581-87-1兴
关87/5兴关99/16兴
关87/5兴关69/29兴
关693-95-8兴
关87/5兴
关66/35兴
关34880-53-0兴
关87/5兴
关590-19-2兴
关87/5兴
关87/5兴
关71/28兴
关47/5兴
关47/13兴
关106-99-0兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关33/11兴关84/9兴
关32/1兴关84/9兴
ENTHALPIES OF VAPORIZATION
575
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H6
C4 H6
C4 H6
C4 H6 ClFO2
C4 H6 ClF3 O
C4 H6 Cl2
C4 H6 Cl2
C4 H6 Cl2
C4 H6 Cl2 O2
C4 H6 Cl2 O2
C4 H6 Cl4
C4 H6 FN
C4 H6 F2 O2
C4 H6 F3 I
C4 H6 F3 I
C4 H6 F3 NO3
C4 H6 F4 O
C4 H6 F4 O
C4 H6 F6 N2 O
C4 H6 F6 P2 S
C4 H6 N2 O
C4 H6 N2 O2
C4 H6 N4 O8
C4 H6 N4 O11
C4 H6 O
Compound
共Temperature range/K兲
1-butyne
共205–289兲
2-butyne
共240–308兲
cyclobutene
共206 –275兲
共196 –275兲
2-chloroethyl fluoroacetate
共273–333兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
26.0
23.7
25.8⫾0.1
24.5⫾0.1
共274兲
共298兲
共263兲
共281兲
A
29.0
26.7
26.9⫾0.1
共255兲
共298兲
共291兲
A
24.7
24.6
共260兲
共260兲
A
56.4
共288兲
A, GS
共298兲
共313兲
共328兲
共343兲
共358兲
C
C
C
C
C
共335兲
A
共321兲
A
共355兲
A
共334兲
A
共298兲
共298兲
C
A
Method
C
C
C
2-chloro-1,1,2-trifluoroethyl ethyl ether
37.5⫾0.1
36.5⫾0.1
35.3⫾0.1
34.2⫾0.1
32.9⫾0.1
3,4-dichloro-1-butene
共320–396兲
38.0
trans 1,3-dichloro-2-butene
共306 – 401兲
39.3
trans 1,4-dichloro-2-butene
共340–379兲
45.6
2-chloroethyl chloroacetate
共319– 478兲
53.3
ethyl dichloroacetate
50.6⫾0.1
共283– 430兲
46.2
1,2,3,3-tetrachlorobutane
共349– 464兲
54.2
4-fluorobutyronitrile
共273–333兲
45.2
共364兲
A
共288兲
A, GS
2-fluoroethyl fluoroacetate
共273–333兲
共288兲
A, GS
共312兲
A
共313兲
A
55.1
1,1,1-trifluoro-3-iodobutane
共304 –321兲
32.4
1,1,1-trifluoro-3-iodo-2-methylpropane
共298 –368兲
30.4
methyl N-trifluoromethyl-N-methoxyurethane
39.0
1-ethoxy-1,1,2,2-tetrafluoroethane
共283–330兲
33.0
1,1,2,2-tetrafluoro-3-methoxypropane
共293–347兲
35.2
1,1-dimethyl-2,2-bis共trifluoromethyl兲hydrazine-2-oxide
共287–356兲
36.4
methyl共trifluoromethyl兲phosphinothious acid, anhydrosulfide
共316 –342兲
46.7
dimethylfurazan
共353– 427兲
51.1
dimethylfurazan-2-oxide
共353– 493兲
57.0
1,1,1,3-tetranitro-2-methylpropane
共304 –327兲
75.7
2-nitro-2-hydroxmethyl-1,3-propanedioltrinitrate
共313–353兲
72.9
trans crotonaldehyde
共314 – 411兲
36.6⫾0.1
共298兲
I
共308兲
I
共302兲
A
共329兲
共368兲
A
共368兲
A
共316兲
A
共328兲
A
共320兲
EB
CAS registry number
Reference
关107-00-6兴
关87/5兴
关71/28兴
关50/10兴
关50/10兴
关503-17-3兴
关87/5兴
关71/28兴
关41/2兴
关822-35-2兴
关87/5兴
关41/8兴关84/9兴
关87/5兴关48/14兴
关71/21兴
关310-71-4兴
关84/7兴
关84/7兴
关84/7兴
关84/7兴
关84/7兴
关760-23-6兴
关87/5兴
关7415-31-8兴
关87/5兴
关110-57-6兴
关87/5兴
关3848-12-2兴
关87/5兴关47/5兴
关535-15-9兴
关72/41兴
关87/5兴关47/5兴
关13138-51-7兴
关87/5兴关68/29兴
关407-83-0兴
关87/5兴关48/14兴
关71/21兴
关87/5兴关48/14兴
关71/21兴
关540-87-4兴
关87/5兴
关26653-47-4兴
关87/5兴
关79/28兴
关512-51-6兴
关02/19兴
关60598-17-6兴
关02/19兴
关30295-33-1兴
关87/5兴
关26348-88-9兴
关70/26兴
关4975-21-7兴
关87/5兴关71/6兴
关2518-42-5兴
关87/5兴关71/6兴
关42216-58-0兴
关87/5兴
关20820-44-4兴
关87/5兴
关123-73-9兴
关02/15兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
576
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H6 O
Compound
共Temperature range/K兲
共314 – 411兲
共314 – 411兲
crotonaldehyde
共288 –376兲
共304 –377兲
共306 –376兲
C4 H6 O
C4 H6 O
C4 H6 O
C4 H6 O
C4 H6 OS
C4 H6 O2
C4 H6 O2
C4 H6 O2
C4 H6 O2
C4 H6 O2
C4 H6 O2
C4 H6 O2
C4 H6 O2
C4 H6 O2
C4 H6 O2 S
C4 H6 O2 S
cyclobutanone
共301–344兲
共283–313兲
共317–380兲
共249–298兲
divinyl ether
共253–323兲
共253–323兲
methyl vinyl ketone
共279–355兲
共300–355兲
2,3-dihydrofuran
共302–260兲
共302–360兲
divinyl sulfoxide
cyclopropane carboxylic acid
共357– 473兲
共357– 473兲
共357– 473兲
共357– 473兲
2,3-butanedione 共biacetyl兲
共273–348兲
共273–293兲
cis 2-butenoic acid
共306 – 445兲
trans 2-butenoic acid
共353– 458兲
2-butyne-1,4-diol
共418 –520兲
␥-butyrolactone
共378 – 406兲
共378 – 406兲
共345–370兲
共345–370兲
共392– 474兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
34.5⫾0.2
32.1⫾0.5
共360兲
共400兲
EB
EB
37.3⫾0.4
38.8
35.1⫾0.5
37.3
36.8
共298兲
共325兲
共332兲
共319兲
共321兲
C
EB
37.7
38.4
36.3
38.5
共322兲
共298兲
共332兲
共273兲
EB
A
A, EB
29.2
26.1
共268兲
共301兲
A
I
32.9
33.6
共294兲
共315兲
A
A
30.8⫾0.1
28.6⫾0.3
共300兲
共340兲
EB
EB
51.2⫾0.9
共298兲
C
58.9⫾0.3
55.7⫾0.2
52.4⫾0.2
48.8⫾0.4
共340兲
共380兲
共420兲
共460兲
EB
EB
EB
EB
38.5
39.6⫾0.2
共288兲
共283兲
A, I
55.8
共321兲
A
56.7
共368兲
A
69.0
共433兲
A
49.5⫾0.1
55.2⫾1.3
51.8⫾0.6
55.6⫾1.4
48.2
54.4⫾0.4
共392兲
共298兲
共357兲
共298兲
共407兲
共298兲
EB
EB
MM
MM
A
C
47.5⫾0.4
53.9
51.6
共298兲
共336兲
共313兲
C
A
A
34.2
28.8
38.0
共331兲
共314兲
共244兲
A
BG
34.4
共309兲
A
54.2
50.9
共340兲
共340兲
A
56.4⫾0.9
56.5⫾0.8
共298兲
共298兲
A
2-methyl-2-propenoic acid
共321– 435兲
共298 – 434兲
methyl acrylate
共316 –354兲
共299–337兲
共229–353兲
vinyl acetate
共294 –346兲
diacetyl sulfide
共325–355兲
共325–355兲
divinyl sulfone
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
CAS registry number
Reference
关02/15兴
关02/15兴
关4170-30-3兴
关96/8兴
关94/16兴
关88/4兴
关79/15兴
关87/5兴关73/23兴
关84/9兴
关1191-95-3兴
关94/16兴
关87/5兴
关87/5兴关76/10兴
关42/7兴关84/9兴
关109-93-3兴
关87/5兴
关33/13兴
关78-94-4兴
关87/5兴
关87/5兴
关1191-99-7兴
关02/21兴
关02/21兴
关1115-15-7兴
关89/12兴
关1759-53-1兴
关02/21兴
关02/21兴
关02/21兴
关02/21兴
关431-03-8兴
关87/5兴关72/12兴
关54/8兴
关503-64-0兴
关87/5兴关47/5兴
关107-93-7兴
关87/5兴关47/5兴
关110-65-6兴
关87/5兴关66/14兴
关71/21兴
关96-48-0兴
关91/7兴
关91/7兴
关91/7兴
关91/7兴
关87/5兴
关90/1兴
关79-41-4兴
关96/8兴
关87/5兴
关87/5兴关47/5兴
关96-33-3兴
关87/5兴
关71/2兴
关47/5兴
关108-05-4兴
关87/5兴关71/21兴
关63/21兴关84/9兴
关3232-39-1兴
关99/16兴
关87/5兴
关77-77-0兴
关89/12兴
关69/24兴
ENTHALPIES OF VAPORIZATION
577
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H6 O3
C4 H6 O3
C4 H6 O4
C4 H6 S
C4 H6 S
C4 H7 Br
C4 H7 Br
C4 H7 Br
C4 H7 Br
C4 H7 Br
C4 H7 BrO
C4 H7 BrO
C4 H7 BrO
C4 H7 Br3
C4 H7 Br3
C4 H7 Br3
C4 H7 Br3
C4 H7 Br3
C4 H7 Br3
C4 H7 Cl
C4 H7 Cl
C4 H7 ClO
C4 H7 ClO
C4 H7 ClO
C4 H7 ClO2
Compound
共Temperature range/K兲
acetic anhydride
共349– 429兲
共413–526兲
共320– 413兲
共336 – 412兲
propylene carbonate
共412– 466兲
共368 – 462兲
共368 – 462兲
共368 – 462兲
共293–353兲
共323–370兲
dimethyl oxalate
共347– 485兲
共293– 437兲
2-vinylthiirane
共273–335兲
divinyl sulfide
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
43.3
47.6
45.5
44.2
共364兲
共428兲
共335兲
共351兲
EB
A
A
54.4
57.8
55.2
53.0
55.2
33.8
共427兲
共383兲
共423兲
共443兲
共323兲
共338兲
A
EB
EB
EB
A, MM
44.7
48.8
共416兲
共308兲
HG, EB
A
38.7
共288兲
A
共298兲
C
共295兲
共244兲
A
共249兲
A
共291兲
共241兲
A
共249兲
A
共243兲
A
共337兲
共294兲
A
共321兲
A
共301兲
A
共490兲
A
共376兲
A
共371兲
共329兲
A
共409兲
共333兲
A
共405兲
A
共326兲
A
共300兲
A
共300兲
A
共322兲
A
共328兲
A
共360兲
A
38.3⫾0.7
cis 1-bromo-1-butene
共280–397兲
35.1
共229–359兲
36.5
trans 1-bromo-1-butene
共234 –368兲
36.1
2-bromo-1-butene
共276 –391兲
34.5
共226 –354兲
36.1
cis 2-bromo-2-butene
共234 –367兲
36.5
trans 2-bromo-2-butene
共228 –359兲
35.7
1-bromo-2-butanone
共322– 428兲
49.9
共279– 420兲
47.7
3-bromo-2-butanone
共306 – 409兲
46.4
isobutyryl bromide
共286 – 436兲
45.7
1,3-dibromo-2-共bromomethyl兲propane
共475– 660兲
66.1
1,1,2-tribromobutane
共361– 490兲
49.4
1,2,2-tribromobutane
共356 – 487兲
48.4
共314 – 486兲
50.7
1,2,3-tribromobutane
共394 –546兲
54.1
共318 – 489兲
51.3
1,2,4-tribromobutane
共390–541兲
53.5
2,2,3-tribromobutane
共311– 480兲
51.7
1-chloro-2-methyl-1-propene
共285–343兲
33.2
3-chloro-2-methyl-1-propene
共285–348兲
33.3
1-chloro-2-butanone
共307– 411兲
49.2
3-chloro-2-butanone
共313–389兲
38.8
3-chloro-2-butene-1-ol
共345– 437兲
50.0
propyl chloroformate
共293–303兲
40.7⫾0.4
共298兲
Method
CAS registry number
Reference
关108-24-7兴
关87/6兴
关87/5兴
关87/5兴关71/21兴
关59/1兴
关108-32-7兴
关87/5兴
关82/8兴
关82/8兴
关82/8兴
关72/37兴
关87/5兴关71/1兴
关553-90-2兴
关88/3兴
关87/5兴关47/5兴
关5954-75-6兴
关87/5兴关99/16兴
关627-51-0兴
关89/12兴
关31849-78-2兴
关87/5兴关71/21兴
关47/5兴
关32620-08-9兴
关87/5兴关47/5兴
关23074-36-4兴
关87/5兴关71/21兴
关47/5兴
关3017-71-8兴
关87/5兴关47/5兴
关3017-68-3兴
关87/5兴关47/5兴
关816-40-0兴
关87/5兴
关47/5兴
关814-75-5兴
关87/5兴
关2736-37-0兴
关87/5兴关47/5兴
关87/5兴
关3675-68-1兴
关87/5兴
关3675-69-2兴
关87/5兴
关47/5兴
关632-05-3兴
关87/5兴关71/21兴
关47/5兴
关38300-67-3兴
关87/5兴关71/21兴
关62127-47-3兴
关87/5兴关47/5兴
关513-37-1兴
关87/5兴
关563-47-3兴
关87/5兴
关616-27-3兴
关87/5兴关71/21兴
关4091-39-8兴
关87/5兴
关40605-42-3兴
关87/5兴
关109-61-5兴
关90/12兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
578
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H7 ClO2
C4 H7 ClS
C4 H7 Cl2 O4 P
C4 H7 Cl3
C4 H7 FOS
C4 H7 FO2
C4 H7 F3
C4 H7 IO2
C4 H7 N
C4 H7 N
Compound
共Temperature range/K兲
ethyl chloroacetate
共274 – 418兲
C4 H7 NO
C4 H7 NO
C4 H7 NO
C4 H7 NO
C4 H7 NO
C4 H7 NO
C4 H7 NO2
C4 H7 NO2
C4 H7 N3 O9
C4 H8
Mean temperature
(T m /K)
Method
40.7⫾0.4
共298兲
C
45.0
49.5⫾0.1
48.5
共289兲
共298兲
共313兲
A
C
共356兲
A
共298兲
A
共288兲
A
共288兲
A, GS
共288兲
A, GS
28.1
共241兲
A
52.1
共316兲
A
35.9
37.5
共339兲
共321兲
BG
39.2⫾0.1
38.8
37.7
共298兲
共318兲
共347兲
C
EB
A, EB
106.5
共370兲
A
57.9
共329兲
A
39.1⫾0.3
共298兲
C
86.3
共404兲
A
46.5⫾0.3
共298兲
GS
47.6
共343兲
A
73.6⫾1.3
41.7⫾0.6
69.1⫾0.5
60.0
共298兲
共298兲
共410兲
EB, BG
A
C
A
59.7
64.6
共383兲
共358兲
A
44.0
共288兲
A
60.0⫾11.3
共303兲
A, GS
23.3
28.3
22.8
22.0
22.5
20.1
25.3
24.5
23.3
21.9
23.2
共259兲
共177兲
共282兲
共357兲
共282兲
共298兲
共202兲
共219兲
共242兲
共267兲
共258兲
A
A
A
A
A
共298 – 418兲
2-butene-3-chloro-1-thiol
共341–397兲
48.2
dimethyl-共2,2-dichlorovinyl兲 phosphate
共283–387兲
68.0
1,2,3-trichlorobutane
共273– 442兲
41.3
2-fluoroethyl thioacetate
共273–333兲
44.7
ethyl fluoroacetate
共273–333兲
41.9
1,1,1-trifluorobutane
共226 –320兲
ethyl iodoacetate
共301–362兲
isobutyronitrile
共324 –354兲
共303–352兲
butyronitrile
共303– 493兲
共332– 401兲
C4 H7 NO
⌬ vapH m
共kJ mol⫺1兲
acetone cyanohydrin
共355–393兲
2-hydroxybutyronitrile
共314 – 452兲
2-methyl-2-oxazoline
methyacrylamide
共390– 418兲
ethoxyacetonitrile
共273–313兲
3-methoxypropionitrile
共328 – 438兲
2-pyrrolidone
共395–518兲
diacetamide
共368 – 496兲
共343– 496兲
2-nitro-1-butene
共273–333兲
1,2,4-butanetriol trinitrate
共293–313兲
1-butene
共200–274兲
共126 –192兲
共267–345兲
共342– 411兲
共267– 411兲
共216 –273兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关90/12兴
关105-39-5兴
关87/5兴
关72/41兴
关28/2兴关84/9兴
关87/5兴
关62-73-7兴
关87/5兴
关18338-40-4兴
关87/5兴关47/5兴
关462-31-7兴
关87/5兴关48/14兴
关459-72-3兴
关87/5兴关48/14兴
关71/21兴
关460-34-4兴
关87/5兴关71/21兴
关623-48-3兴
关87/5兴关47/3兴
关78-82-0兴
关79/18兴
关71/2兴
关109-74-0兴
关82/5兴
关71/4兴
关87/5兴关47/5兴
关73/12兴
关75-86-5兴
关87/5兴
关4476-02-2兴
关87/5兴关47/5兴
关1120-64-5兴
关76/27兴
关79-39-0兴
关87/5兴
关62957-60-2兴
关95/11兴
关33695-59-9兴
关87/5兴
关616-45-5兴
关98/14兴
关95/26兴
关90/1兴
关87/5兴
关625-77-4兴
关87/5兴
关47/5兴
关2783-12-2兴
关87/5兴关71/21兴
关6859-60-5兴
关87/5兴关57/11兴
关106-98-9兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关46/7兴
关46/7兴
关46/7兴
关46/7兴
关40/3兴关84/9兴
ENTHALPIES OF VAPORIZATION
579
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H8
C4 H8
C4 H8
C4 H8
C4 H8
C4 H8 BrClO
C4 H8 Br2
C4 H8 Br2
C4 H8 Br2
C4 H8 Br2
C4 H8 Br2
C4 H8 Br2
C4 H8 Br2
C4 H8 Br2
C4 H8 Br2 O
C4 H8 Cl2
C4 H8 Cl2
Compound
共Temperature range/K兲
cis 2-butene
共221–290兲
共276 –325兲
共324 –386兲
共383– 431兲
共195–267兲
trans 2-butene
共205–287兲
共273–315兲
共313–385兲
共382– 428兲
共203–274兲
共205–283兲
cyclobutane
共198 –287兲
共217–285兲
methylcyclopropane
共177–278兲
2-methylpropene
共212–279兲
共266 –313兲
共310–376兲
共371– 418兲
共303–398兲
共216 –273兲
2-bromoethyl 2-chloroethyl ether
共309– 469兲
1,1-dibromobutane
共342– 477兲
1,2-dibromobutane
共338 – 425兲
共330– 425兲
共281– 439兲
共273–333兲
1,3-dibromobutane
共351– 450兲
1,4-dibromobutane
共375–520兲
共305– 470兲
meso 2,3-dibromobutane
共274 – 431兲
threo 2,3-dibromobutane
共278 – 434兲
1,2-dibromo-2-methylpropane
共244 – 422兲
1,3-dibromo-2-methylpropane
共287– 448兲
bis 共2-bromoethyl兲 ether
共320– 486兲
1,1-dichlorobutane
共310–390兲
共304 –386兲
共303– 428兲
1,2-dichlorobutane
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
24.4
24.0
23.6
23.6
22.1
25.3
共275兲
共291兲
共339兲
共398兲
共298兲
共252兲
A
A
A
A
23.9
23.6
23.3
23.2
21.3
22.8⫾0.1
24.2
23.9
共272兲
共288兲
共328兲
共397兲
共298兲
共274兲
共259兲
共268兲
A
A
A
A
25.2
25.2
共272兲
共270兲
A
24.8
共263兲
A
23.1
22.7
22.2
22.3
20.6
22.2
22.8
共264兲
共281兲
共325兲
共386兲
共298兲
共350兲
共258兲
A
A
A
A
53.3
共324兲
A
45.8
共357兲
A, EST
43.5
45.9
45.6⫾0.7
42.8
45.1
共353兲
共298兲
共298兲
共296兲
共300兲
A
44.7
共366兲
A
52.6
51.4
49.4
共298兲
共390兲
共320兲
GC
A
41.7
共289兲
A
40.9
共293兲
A
43.3⫾0.1
33.3
共259兲
C
A
45.1
共302兲
A
55.1
共335兲
A
39.5
38.7
39.4⫾0.6
38.8
共298兲
共319兲
共298兲
共318兲
A
EB
EST
40.1⫾0.1
共298兲
C
Method
C
EB
A
CAS registry number
Reference
关590-18-1兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关42/8兴关84/9兴
关624-64-6兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关45/3兴
关45/3兴关84/9兴
关40/3兴关84/9兴
关287-23-0兴
关87/5兴
关53/12兴关84/9兴
关594-11-6兴
关87/5兴关47/5兴
关115-11-7兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关42/6兴
关40/3兴关84/9兴
关51070-66-7兴
关87/5兴关47/5兴
关62168-25-6兴
关87/5兴关56/16兴
关71/21兴
关533-98-2兴
关87/5兴
关75/16兴关75/15兴
关75/15兴
关87/5兴关47/5兴
关41/6兴
关107-80-2兴
关87/5兴
关110-52-1兴
关94/19兴
关87/5兴关71/21兴
关47/5兴
关5780-13-2兴
关87/5兴关47/5兴
关598-71-0兴
关87/5兴
关594-34-3兴
关74/2兴
关87/5兴关47/5兴
关28148-04-1兴
关87/5兴关47/5兴
关5414-19-7兴
关87/5兴关47/5兴
关541-33-3兴
关91/2兴
关87/5兴
关77/14兴
关87/5兴关56/16兴
关616-21-7兴
关92/7兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
580
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共312–394兲
共310–390兲
C4 H8 Cl2
共249–397兲
1,3-dichlorobutane
共320– 400兲
C4 H8 Cl2
共318 – 407兲
1,4-dichlorobutane
共325– 425兲
C4 H8 Cl2
共336 – 425兲
2,2-dichlorobutane
共300–370兲
共293–376兲
C4 H8 Cl2
meso 2,3-dichlorobutane
C4 H8 Cl2
(dl) 2,3-dichlorobutane
C4 H8 Cl2
2,3-dichlorobutane
共247–389兲
1,1-dichloro-2-methylpropane
共242–379兲
1,2-dichloro-2-methylpropane
共247–381兲
1,3-dichloro-2-methylpropane
共270– 408兲
bis共2-chloroethyl兲 ether
共297– 452兲
bis共2-chloroethyl兲 sulfide
共288 –358兲
C4 H8 Cl2
C4 H8 Cl2
C4 H8 Cl2
C4 H8 Cl2 O
C4 H8 Cl2 S
C4 H8 Cl2 S3
C4 H8 F2
C4 H8 F2
C4 H8 F2 O4 S
共353–393兲
bis共2-chloroethyl兲 trisulfide
共293–333兲
1,1-difluorobutane
共246 –347兲
2,2-difluorobutane
共238 –336兲
bis共2-fluoroethyl兲 sulfate
共273–333兲
C4 H8 I2
1,4-diiodobutane
C4 H8 N2
共dimethylamino兲acetonitrile
共277–307兲
1,4,5,6-tetrahydropyrimidine
共330–395兲
1,3-butanediol dinitrate
共293–313兲
1,4-butanediol dinitrate
共293–313兲
diethyleneglycol dinitrate
共293–333兲
2-butanone
C4 H8 N2
C4 H8 N2 O6
C4 H8 N2 O6
C4 H8 N2 O7
C4 H8 O
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
40.2⫾0.1
39.0
40.4
40.1⫾0.6
38.1
共298兲
共327兲
共298兲
共298兲
共264兲
42.2⫾0.1
42.3
42.3⫾1.8
40.5
共298兲
共298兲
共298兲
共333兲
C
46.7
46.5⫾0.1
46.4
46.4⫾0.1
46.4⫾0.1
43.4
共298兲
共298兲
共298兲
共298兲
共298兲
共351兲
GC
C
36.3⫾0.1
36.7
36.4
33.7⫾0.6
共298兲
共298兲
共308兲
共298兲
C
A
EB
关89/10兴
关87/5兴
关82/2兴关91/2兴
关75/16兴
关87/5兴关47/5兴
关1190-22-3兴
关92/7兴
关91/2兴
关90/11兴
关87/5兴
关110-56-2兴
关94/19兴
关92/7兴
关91/2兴
关90/11兴
关89/10兴
关87/5兴关71/21兴
关4279-22-5兴
关92/7兴
关91/2兴
关87/5兴
关77/14兴
38.4
共298兲
C
关92/7兴关93/18兴
39.7
共298兲
C
39.6
共262兲
A
38.7
共257兲
A
40.4
共262兲
A
45.1
共285兲
A
49.8
共312兲
A
59.6
共303兲
A, MM
50.3
共373兲
68.2
共308兲
A, GS
31.0
共261兲
A, EST
30.0
共253兲
A
63.9
共288兲
A, GS
59.0
共298兲
GC
关93/18兴
关7581-97-7兴
关87/5兴
关598-76-5兴
关87/5兴
关594-37-6兴
关87/5兴关47/5兴
关616-19-3兴
关87/5兴关47/5兴
关111-44-4兴
关87/5兴关47/5兴
关505-60-2兴
关87/5兴关47/6兴
关84/9兴
关43/8兴
关19149-77-0兴
关87/5兴关48/9兴
关99/16兴
关353-81-1兴
关87/5兴关56/16兴
关71/21兴
关353-81-1兴
关87/5兴关71/21兴
关381-46-4兴
关87/5兴关48/14兴
关99/16兴
关628-21-7兴
关94/19兴
关926-64-7兴
关97/10兴
关1606-49-1兴
关96/4兴
关6423-44-5兴
关87/5兴关57/5兴
关3457-91-8兴
关87/5兴关57/5兴
关693-21-0兴
关87/5兴
关78-93-3兴
45.4⫾0.6
Method
C
A
EB
A
C
A
C
C
A
GS
75.6⫾2.0
共298兲
IPM
71.4⫾7.1
共303兲
A, GS
57.4⫾0.8
共303兲
A, GS
94.3
共308兲
A
CAS registry number
Reference
ENTHALPIES OF VAPORIZATION
581
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共294 –342兲
共353– 403兲
共397– 479兲
共473–537兲
共258 –362兲
共315–363兲
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 O
C4 H8 OS
C4 H8 OS
共314 –370兲
2-methyl-2-propen-1-ol
共323–373兲
3-buten-1-ol
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
34.6
32.5
31.6
31.1
34.8⫾0.1
34.5⫾0.1
35.6
34.7
33.9
共309兲
共368兲
共412兲
共488兲
共298兲
共298兲
共273兲
共298兲
共330兲
33.8⫾0.1
32.3⫾0.1
31.3⫾0.1
30.5⫾0.1
30.0⫾0.1
33.9
共314兲
共338兲
共352兲
共363兲
共370兲
共329兲
C
C
C
C
C
51.9
共298兲
CGC
50.9⫾0.1
48.8⫾0.1
46.7⫾0.1
共313兲
共328兲
共343兲
C
C
C
共319兲
A
共298兲
共308兲
共339兲
共319兲
共306兲
CGC
A
EB
共269兲
A
共219兲
A
共238兲
A
共298兲
共318兲
共324兲
共340兲
共298兲
CGC
(dl) 3-buten-2-ol
共304 –370兲
39.2
butyraldehyde
共313–353兲
33.2
共293–349兲
34.2
共330–348兲
32.9
共304 –347兲
33.3
共258 –353兲
33.9
(dl) 1,2-epoxybutane
共254 –347兲
24.7
1,2-epoxy-2-methylpropane 共2,2-dimethyloxirane兲
共204 –329兲
30.6
ethyl vinyl ether
共223–309兲
29.5
isobutyraldehyde
共313–353兲
32.3
共313–324兲
31.4
共309–337兲
31.8
共333–347兲
33.4
共283–337兲
32.8
2-methoxy-1-propene
共281–309兲
cis methyl propenyl ether
共293–318兲
trans methyl propenyl ether
共293–322兲
tetrahydrofuran
共273–339兲
共399– 479兲
共467–541兲
共235–340兲
共302–339兲
共273–308兲
共296 –373兲
共224 –360兲
1,4-oxathiane
共342– 411兲
共342– 411兲
S-ethyl thiolacetate
Method
A
A
A
A
C
C
A, EB, GS
EB
A
28.3⫾0.1
共295兲
30.6
共305兲
A
29.5
共307兲
A
33.1
29.0
29.6
32.0
32.5⫾0.2
30.8
32.8
31.9
32.9
共288兲
共414兲
共482兲
共298兲
共288兲
共320兲
共288兲
共311兲
共298兲
A
A
A
C
42.1
44.8
共378兲
共357兲
A
40.0⫾0.2
共298兲
C
CAS registry number
Reference
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关83/3兴
关79/1兴
关78/20兴
关75/8兴
关87/5兴关75/8兴
关65/7兴
关61/17兴
关61/17兴
关61/17兴
关61/17兴
关61/17兴
关47/5兴
关513-42-8兴
关95/21兴
关627-27-0兴
关96/9兴
关96/9兴
关96/9兴
关6118-14-5兴
关87/5兴
关123-72-8兴
关95/21兴
关87/5兴
关63/15兴
关59/5兴关84/9兴
关38/7兴
关106-88-7兴
关87/5兴
关558-30-5兴
关87/5兴关47/5兴
关109-92-2兴
关87/5兴
关78-84-2兴
关95/21兴
关84/30兴
关76/20兴
关63/15兴
关87/5兴关59/5兴
关64/21兴
关116-11-0兴
关88/4兴
关4188-68-5兴
关87/5兴
关4188-69-6兴
关87/5兴
关109-99-9兴
关87/5兴
关87/5兴
关87/5兴
关81/8兴
关76/16兴
关75/33兴
关70/22兴关84/9兴
关70/23兴关84/9兴
关70/36兴
关15980-15-1兴
关99/16兴
关87/5兴
关625-60-5兴
关66/2兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
582
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H8 O2
C4 H8 O2
C4 H8 O2
C4 H8 O2
Compound
共Temperature range/K兲
2-methyl-1,3-dioxolane
共270–308兲
cis 2-butene-1,4-diol
共373–508兲
1,1-dimethoxyethene
共303–362兲
butanoic acid
共391– 429兲
共278 –308兲
共278 –308兲
共353–393兲
共437–592兲
共301–358兲
共355– 453兲
monomer
C4 H8 O2
C4 H8 O2
C4 H8 O2
共363– 436兲
1,3-dioxane
1,4-dioxane
共285–375兲
共329–372兲
共293–398兲
共283–353兲
ethyl acetate
共300–390兲
共313–353兲
共271–373兲
共288 –351兲
C4 H8 O2
C4 H8 O2
3-hydroxy-2-butanone
共273– 418兲
2-methylpropanoic acid
共278 –308兲
共278 –308兲
共344 – 445兲
共288 – 428兲
共428 –562兲
共228 –243兲
monomer
C4 H8 O2
C4 H8 O2
isopropyl formate
共221–342兲
methyl propionate
共313–363兲
共231–353兲
共353– 486兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
43.0⫾0.6
Method
GS
74.7
共388兲
39.6
共333兲
50.3
58.5⫾0.3
58.2⫾0.3
60.7
47.7
51.1
53.2
40.5⫾0.1
58⫾4
52.0
共406兲
共293兲
共298兲
共298兲
共452兲
共316兲
共370兲
共298兲
共298兲
共378兲
EB
GS
GS
CGC
A
A
A
C
C
39.1⫾0.1
35.6⫾0.4
共298兲
C
38.0
36.5
38.6⫾0.1
37.3
37.0
共300兲
共350兲
共298兲
共308兲
共318兲
A
34.1
35.0
36.7
35.6⫾0.1
34.6⫾0.1
31.4⫾0.1
33.8⫾0.1
33.4⫾0.1
32.4⫾0.1
31.9⫾0.1
31.0⫾0.1
34.0
31.9
35.1⫾0.2
35.7
共315兲
共298兲
共286兲
共298兲
共313兲
共343兲
共326兲
共331兲
共344兲
共351兲
共363兲
共320兲
共350兲
共298兲
共303兲
38.4
共288兲
A
55.8⫾0.3
55.5⫾0.3
51.6
50.9
45.4
53.4⫾3
35.5⫾0.1
53⫾4
共293兲
共298兲
共359兲
共303兲
共443兲
共398兲
共298兲
共298兲
GS
GS
EB
A
A
TE
C
C
34.5
共236兲
A
28.9
35.6⫾0.4
39.1
32.8
35.9⫾0.1
34.9⫾0.1
36.3⫾0.3
共298兲
共298兲
共246兲
共368兲
共298兲
共313兲
共298兲
CGC
GC
A
A
C
C
GCC
A
C
CGC
C
C
C
C
C
C
C
C
C
A
CAS registry number
Reference
关497-26-7兴
关98/21兴关02/32兴
关6117-80-2兴
关87/5兴
关95/29兴
关107-92-6兴
关01/15兴
关00/6兴
关00/6兴
关95/21兴
关87/5兴
关87/5兴
关87/5兴关71/21兴
关70/8兴
关70/8兴
关49/1兴关84/9兴
关505-22-6兴
关82/9兴
关59/23兴
关123-91-1兴
关87/5兴
关84/20兴
关82/9兴
关63/22兴关84/9兴
关36/6兴
关141-78-6兴
关97/11兴
关95/21兴
关81/11兴关84/9兴
关80/13兴
关80/13兴
关80/13兴
关77/12兴
关77/12兴
关77/12兴
关77/12兴
关77/12兴
关76/8兴
关76/8兴
关66/2兴
关87/5兴关65/3兴
关71/21兴
关513-86-0兴
关87/5兴
关79-31-2兴
关00/6兴
关00/6兴
关87/9兴
关87/5兴
关87/5兴
关79/4兴
关70/8兴
关70/8兴
关625-55-8兴
关87/5兴关47/5兴
关922-67-8兴
关95/21兴
关87/17兴
关87/5兴
关87/5兴
关80/13兴
关80/13兴
关80/5兴
ENTHALPIES OF VAPORIZATION
583
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H8 O2
C4 H8 O2 S
C4 H8 O2 S
C4 H8 O3
C4 H8 O3
C4 H8 O3
C4 H8 O3
C4 H8 O3
C4 H8 O3
C4 H8 O3
C4 H8 O3
C4 H8 S
C4 H8 S
C4 H8 S
Compound
共Temperature range/K兲
共293–353兲
propyl formate
共302–353兲
共354 –518兲
共230–355兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
35.8⫾0.1
34.2⫾0.1
33.8⫾0.1
32.8⫾0.1
32.1⫾0.1
31.5⫾0.1
35.9
共298兲
共326兲
共331兲
共344兲
共355兲
共363兲
共308兲
C
C
C
C
C
C
A
35.3
32.7
36.8
37.5⫾0.1
36.5⫾0.1
35.8⫾0.1
35.4⫾0.1
34.4⫾0.1
33.8⫾0.1
33.5⫾0.1
32.9⫾0.1
35.6
共317兲
共369兲
共245兲
共298兲
共313兲
共326兲
共331兲
共344兲
共351兲
共355兲
共363兲
共314兲
A
A
C
C
C
C
C
C
C
C
共420兲
A
共299–355兲
allyl methyl sulfone
共405– 450兲
68.2
tetrahydrothiophene-1,1-dioxide 共sulfolane兲
共423–529兲
59.0
共364 –529兲
53.7
共424 –542兲
67.8⫾0.8
共373– 453兲
58.2
共303–328兲
31.0
共413–558兲
58.7
共360– 400兲
54.5
ethoxyacetic acid
共280–310兲
69.1
2-methoxy-1,3-dioxolane
共278 –308兲
46.4⫾0.8
共278 –308兲
46.8⫾0.8
ethyl glycolate
共287– 432兲
47.1
2-hydroxyisobutyric acid
共371– 485兲
67.5
methyl 3-hydroxypropionate
共330–343兲
60.0
methoxyacetic acid, methyl ester
共285–310兲
39.3
(dl) methyl lactate
共313– 418兲
44.7
peroxybutyric acid
共273–393兲
45.5
2,2-dimethylthiirane
共273– 473兲
37.0
2-ethylthiirane
共298 – 450兲
tetrahydrothiophene
共331– 401兲
共343– 434兲
C4 H8 S2
1,3-dithiane
C4 H8 S2
1,4-dithiane
共389– 437兲
共438兲
共379兲
共298兲
共413兲
共315兲
共428兲
共380兲
共295兲
A
共298兲
GS
GS
共302兲
A
共386兲
A
共336兲
A
共297兲
A
共328兲
A
共288兲
A
共288兲
A
39.7
共313兲
A
38.8
37.7
37.1
共298兲
共346兲
共358兲
EB
A, EB
66.9⫾0.4
C4 H9 Br
共388 – 437兲
1-bromobutane
EB
TGA
A
A
48.7
68.9⫾0.5
47.9
GC
共404兲
共403兲
GC
A
CAS registry number
Reference
关79/1兴
关77/12兴
关77/12兴
关77/12兴
关77/12兴
关77/12兴
关87/5兴关65/3兴
关110-74-7兴
关93/8兴
关87/5兴
关87/5兴
关80/13兴
关80/13兴
关76/14兴
关76/14兴
关76/14兴
关76/14兴
关76/14兴
关76/14兴
关28/1兴关84/9兴
关16215-14-8兴
关87/5兴关99/16兴
关126-33-0兴
关99/16兴
关99/16兴
关97/8兴
关87/18兴
关87/5兴
关87/5兴
关84/18兴
关627-03-2兴
关87/5兴
关19693-75-5兴
关02/32兴
关95/7兴
关623-50-7兴
关87/5兴关47/5兴
关594-61-6兴
关87/5兴
关6149-41-3兴
关87/5兴
关6290-49-9兴
关87/5兴
关547-64-8兴
关87/5兴
关13122-71-9兴
关87/5兴关71/21兴
关3772-13-2兴
关87/5兴关71/21兴
关99/16兴
关3195-86-6兴
关87/5兴关71/21兴
关110-01-0兴
关71/28兴
关52/9兴
关87/5兴关52/10兴
关66/5兴
关505-23-7兴
关89/16兴
关505-29-3兴
关99/16兴
关89/16兴
关87/5兴
关109-65-9兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
584
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共323–363兲
共340–370兲
共338 –373兲
共273– 400兲
C4 H9 Br
C4 H9 Br
共293–343兲
2-bromobutane
共281– 403兲
1-bromo-2-methylpropane
共305–363兲
共281– 404兲
C4 H9 Br
C4 H9 BrO
C4 H9 Cl
2-bromo-2-methylpropane
共248 –346兲
共270–345兲
共298 –323兲
共273–346兲
1-bromo-2-butanol
共296 – 418兲
1-chlorobutane
共260–350兲
共256 –352兲
共257–389兲
C4 H9 Cl
C4 H9 Cl
C4 H9 Cl
共293–343兲
2-chlorobutane
共315–341兲
共266 –377兲
共273–312兲
1-chloro-2-methylpropane
共219–342兲
2-chloro-2-methylpropane
共313–353兲
共253–358兲
共295–323兲
共295–323兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
36.4
36.4
34.6
35.6⫾0.1
34.9⫾0.1
34.5⫾0.1
33.7⫾0.1
33.0⫾0.1
36.6⫾0.1
36.7⫾0.1
37.5
共298兲
共298兲
共353兲
共322兲
共332兲
共339兲
共352兲
共366兲
共298兲
共298兲
共288兲
33.5
共308兲
33.9
34.5⫾0.1
34.8⫾0.1
共296兲
共298兲
共298兲
A
C
C
34.1
33.1⫾0.1
32.6⫾0.1
32.0⫾0.1
31.4⫾0.1
34.0
34.9⫾0.1
共320兲
共330兲
共341兲
共353兲
共366兲
共296兲
共298兲
A, EB
C
C
C
C
A
C
31.4
31.0
31.5
31.8⫾0.1
31.2
共263兲
共298兲
共313兲
共298兲
共288兲
A
58.4
共311兲
A
33.5
33.5⫾0.1
32.7⫾0.1
31.8⫾0.1
30.9⫾0.1
30.0⫾0.1
29.4⫾0.1
35.6
33.5⫾0.1
35.0
共298兲
共298兲
共313兲
共328兲
共343兲
共358兲
共358兲
共271兲
共298兲
共272兲
C
C
C
C
C
C
DTA
C
A, EST
37.2
共308兲
30.9
33.1
31.5⫾0.1
30.7⫾0.1
29.9⫾0.1
29.1⫾0.1
28.2⫾0.1
31.6⫾0.1
31.8
共328兲
共281兲
共298兲
共313兲
共328兲
共343兲
共358兲
共298兲
共288兲
EB
A
C
C
C
C
C
C
36.1
31.7⫾0.1
共234兲
共298兲
A
C
28.6
32.3
27.8
27.0
共298兲
共268兲
共309兲
共310兲
CGC
A
A
Method
CGC
A, EB
C
C
C
C
C
C
C
A, EST
C
CAS registry number
Reference
关95/21兴
关91/2兴
关87/5兴关77/8兴
关77/8兴
关77/8兴
关77/8兴
关77/8兴
关77/8兴
关68/1兴
关66/2兴
关87/5兴关61/13兴
关71/21兴
关29/2兴关84/9兴
关78-76-2兴
关87/5兴关71/21兴
关68/1兴
关66/2兴
关78-77-3兴
关87/5兴关77/8兴
关77/8兴
关77/8兴
关77/8兴
关77/8兴
关87/5兴关71/21兴
关68/1兴
关507-19-7兴
关87/5兴
关87/9兴关91/2兴
关69/10兴
关68/1兴
关51/5兴关84/9兴
关2482-57-7兴
关87/5兴关47/5兴
关109-69-3兴
关84/9兴关91/2兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关69/5兴
关68/1兴
关87/5兴关61/13兴
关71/21兴
关29/2兴关84/9兴
关78-86-4兴
关96/27兴
关87/5兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关68/1兴
关28/3兴关84/9兴
关513-36-0兴
关87/5兴关47/5兴
关68/1兴
关507-20-0兴
关95/21兴
关87/5兴关71/21兴
关87/5兴关69/10兴
关69/10兴关84/9兴
ENTHALPIES OF VAPORIZATION
585
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H9 ClO2
C4 H9 ClO2 S
C4 H9 ClS
C4 H9 F
C4 H9 F
C4 H9 F
C4 H9 FO
C4 H9 I
Compound
共Temperature range/K兲
共254 –324兲
2-共2-chloroethoxy兲ethanol
共326 – 469兲
butyl sulfonyl chloride
共283–373兲
共373– 474兲
共253–283兲
ethyl 共2-chloroethyl兲 sulfide
共293–333兲
1-fluorobutane
共222–326兲
2-fluorobutane
共233–329兲
2-fluoro-2-methylpropane
共222–315兲
4-fluoro-1-butanol
共323–343兲
1-iodobutane
共313–353兲
共313–353兲
共292– 431兲
C4 H9 I
C4 H9 I
C4 H9 I
C4 H9 N
C4 H9 NO
C4 H9 NO
C4 H9 NO
C4 H9 NO
C4 H9 NO
C4 H9 NO
C4 H9 NO
2-iodobutane
共313–353兲
共313–353兲
1-iodo-2-methylpropane
共256 –393兲
2-iodo-2-methylpropane
共313–353兲
共236 –294兲
pyrrolidine
共273–313兲
共316 –394兲
共294 –360兲
2-butanone oxime
共308 – 425兲
共318 –343兲
N-ethylacetamide
buyraldehyde oxime
共313–343兲
butyramide
共397–504兲
N,N-dimethylacetamide
共371– 423兲
共297– 438兲
共303–363兲
N-methylpropionamide
共303–363兲
morpholine
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
29.0⫾0.1
29.1
共298兲
共269兲
C
59.8
共341兲
A
55.7
52.9
60.2
共298兲
共388兲
共268兲
A
44.4
共308兲
A, GS
30.1
共237兲
A, EST
29.2
共248兲
A
27.6
共237兲
A
64.0
共333兲
A
40.3
39.7
40.6⫾0.1
39.9
共298兲
共298兲
共298兲
共307兲
CGC
CGC
C
A, EST
37.9
38.8
38.5⫾0.1
共298兲
共298兲
共298兲
CGC
CGC
C
41.1
38.8⫾0.1
共271兲
共298兲
A
C
37.0
34.8
35.4⫾0.1
共298兲
共279兲
共298兲
CGC
A
C
38.4
35.8
共288兲
共331兲
A
EB, IPM
35.8⫾0.1
34.5⫾0.1
33.0⫾0.1
37.3
共322兲
共340兲
共360兲
共309兲
C
C
C
53.7
55.5
共323兲
共330兲
A
A
64.9⫾0.2
共298兲
C
55.8
共328兲
A
64.0
共412兲
A
45.1
50.2
67.9
45.2
共386兲
共298兲
共312兲
共318兲
A
A
66.9⫾1.3
64.9⫾0.3
54.4
共298兲
共298兲
共318兲
EB, BG
C
A
Method
A
CAS registry number
Reference
关68/1兴
关47/5兴
关628-89-7兴
关87/5兴关47/5兴
关2386-60-9兴
关99/16兴
关99/16兴
关87/5兴关99/16兴
关693-07-2兴
关87/5兴关48/9兴
关71/21兴
关2366-52-1兴
关87/5兴关61/13兴
关71/21兴
关359-01-3兴
关87/5兴关71/21兴
关353-61-7兴
关87/5兴关71/21兴
关372-93-0兴
关87/5兴
关542-69-8兴
关95/21兴
关95/21兴
关68/1兴
关87/5兴关61/13兴
关71/21兴
关513-48-4兴
关95/21兴
关95/21兴
关68/1兴
关513-38-2兴
关87/5兴关47/5兴
关68/1兴
关558-17-8兴
关95/21兴
关87/5兴关71/21兴
关68/1兴
关123-75-1兴
关87/5兴
关87/5兴关59/4兴
关68/4兴
关59/4兴
关59/4兴
关59/4兴
关59/10兴关84/9兴
关96-29-7兴
关87/5兴
关87/5兴
关625-50-3兴
关84/6兴
关110-69-0兴
关87/5兴
关541-35-5兴
关87/5兴
关127-19-5兴
关87/5兴
关85/7兴关85/6兴
关74/7兴关84/9兴
关87/5兴关68/3兴
关1187-58-2兴
关98/14兴
关84/6兴
关87/5兴关68/3兴
关110-91-8兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
586
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO2
C4 H9 NO3
C4 H9 NO3
C4 H9 N3 O2
C4 H9 P
C4 H9 P
C4 H9 P
C4 H10
C4 H10
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共274 –303兲
45.6⫾0.4
共274 –303兲
45.0⫾0.4
共313–343兲
44.3
共273–318兲
45.3
共317– 443兲
42.3
(dl) 2-aminobutyric acid
共400– 418兲
132.0
S 2-aminobutyric acid
共449– 462兲
162.5
sec-butyl nitrite
共267–287兲
29.6
tert-butyl nitrite
共267–337兲
30.8
lactic acid N-methyl amide
共359– 415兲
72.7
N-methyl carbamic acid, ethyl ester
共299– 443兲
51.7
2-methyl-1-nitropropane
共347– 415兲
41.1
Mean temperature
(T m /K)
Method
共288兲
共298兲
共328兲
共288兲
共332兲
GS
GS
TGA
A
A
共409兲
A
共455兲
A
共277兲
A
共282兲
A
共374兲
A
共314兲
A
共362兲
A, EB
2-methyl-2-nitropropane
共334 – 401兲
39.1
共349兲
EB
1-nitrobutane
共313–353兲
共357– 426兲
47.0
42.7
共298兲
共372兲
CGC
A, EB
(dl) 2-nitrobutane
共345– 413兲
40.3
共360兲
A, EB
propyl carbamate
共325– 468兲
butyl nitrate
共273–343兲
61.6
共340兲
A
44.1
共288兲
A
isobutyl nitrate
共273–343兲
42.8
共288兲
A
46.4
共306兲
A
34.4
共276兲
A
34.5
共273兲
37.4
共272兲
22.9
23.4
23.2
22.6
22.8
27.0
22.4
23.1
23.9
共308兲
共277兲
共288兲
共331兲
共390兲
共198兲
共298兲
共264兲
共258兲
21.5
22.4
26.9
21.9
21.4
21.6
21.6
共318兲
共265兲
共172兲
共278兲
共316兲
共376兲
共292兲
bis共nitrosoethyl兲amine
共291– 450兲
allymethylphosphine
共242–291兲
3-butenylphosphine
共252–295兲
phospholane
共257–347兲
butane
共300–315兲
共195–292兲
共273–321兲
共316 –383兲
共375– 425兲
共135–213兲
共206 –279兲
共195–273兲
2-methylpropene 共isobutene兲
共303–333兲
共186 –280兲
共121–187兲
共263–306兲
共301–366兲
共361– 408兲
共277–344兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
A
A
A
A
A
A
A
A
A
CAS registry number
Reference
关98/13兴
关98/13兴
关87/18兴
关87/5兴
关87/5兴
关2835-81-6兴
关87/5兴
关1492-24-6兴
关87/5兴
关924-43-6兴
关87/5兴关37/3兴
关540-80-7兴
关87/5兴关37/3兴
关87/5兴
关105-40-8兴
关87/5兴关47/5兴
关625-74-1兴
关87/5兴关56/15兴
关71/21兴
关594-70-7兴
关87/5兴关56/15兴
关71/21兴
关627-05-4兴
关95/21兴
关87/5兴关56/15兴
关71/21兴
关600-24-8兴
关87/5兴关56/15兴
关71/21兴
关627-12-3兴
关87/5兴关47/5兴
关928-45-0兴
关87/5兴关71/21兴
关57/2兴
关543-29-3兴
关87/5兴关71/21兴
关57/2兴
关87/5兴
关62778-93-2兴
关87/5兴
关114596-01-9兴
关88/13兴
关3466-00-0兴
关87/5兴
关106-97-8兴
关97/16兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴关73/11兴
关71/28兴
关45/4兴关84/9兴
关40/10兴关84/9兴
关75-28-5兴
关99/29兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关76/19兴关84/9兴
ENTHALPIES OF VAPORIZATION
587
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H10F3 NOS
C4 H10F3 NS
C4 H10N2
C4 H10N2 O2
C4 H10O
C4 H10O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
21.3
共188 –262兲
22.6
共diethylaminato兲trifluorooxo sulfur
共329–354兲
49.5
共N-ethylethaneaminato兲trifluoro sulfur
共318 –340兲
45.2
piperazine
共417– 460兲
50.1⫾1.9
diethylnitramine
共338 –378兲
49.7
1-butanol
共357–389兲
46.0
38.2
29.6
20.8
44.1
共323–373兲
52.5
共315–390兲
49.9
共364 – 403兲
45.3
共283–323兲
55.2
共376 –399兲
45.3
共323– 413兲
50.1
共413–550兲
41.9
共209–251兲
51.6
共376 –397兲
45.4
共391– 429兲
43.8
共415–501兲
41.9
共497–563兲
37.4
共243–303兲
51.7
共329–391兲
49.0
52.1
共288 – 404兲
55.0
49.5⫾0.1
48.6⫾0.1
47.5⫾0.1
46.4⫾0.1
52.34⫾0.02
共351–397兲
47.2
共295–391兲
53.0
52.3⫾0.1
47.2⫾0.1
45.4⫾0.1
43.1⫾0.1
共419–563兲
42.1
共362–398兲
46.6
51.0⫾0.1
共337–390兲
48.3
共314 –390兲
48.3
2-butanol
共306 –373兲
47.7
共303– 403兲
49.3
共359–381兲
43.2
共372–524兲
47.9
共210–303兲
57.5
共359–380兲
43.2
共368 – 404兲
42.0
共395– 485兲
39.6
共476 –536兲
35.0
共307–373兲
47.8
共293–380兲
53.2
共319–372兲
44.1
共280–314兲
50.2
共298 –393兲
48.1
49.74⫾0.02
Mean temperature
(T m /K)
Method
共286兲
共247兲
共341兲
A
共329兲
A
共298兲
EB
共358兲
共372兲
共423兲
共473兲
共523兲
EB
共298兲
共330兲
共379兲
共298兲
共387兲
共338兲
共428兲
共236兲
共386兲
共406兲
共430兲
共512兲
共298兲
共344兲
共298兲
共303兲
共333兲
共343兲
共353兲
共363兲
共298兲
共366兲
共310兲
共298兲
共356兲
共381兲
共391兲
共434兲
共377兲
共298兲
共352兲
共352兲
CGC
共321兲
共318兲
共370兲
共387兲
共225兲
共369兲
共383兲
共410兲
共491兲
共322兲
共308兲
共334兲
共295兲
共313兲
共298兲
A
A
A
A
A
A
A
A
C
C
C
C
C
C
EB
DTA
C
C
C
C
EB
C
A
A
A
A
A
A
A
A
C
CAS registry number
Reference
关71/28兴
关40/11兴关84/9兴
关26458-94-6兴
关87/5兴关99/16兴
关38078-09-0兴
关87/5兴关99/16兴
关275-02-5兴
关97/7兴
关7119-92-8兴
关58/22兴
关71-36-3兴
关01/15兴
关00/20兴
关00/20兴
关00/20兴
关99/32兴
关95/21兴
关95/13兴
关93/7兴
关92/9兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关83/14兴
关82/13兴
关82/6兴
关73/26兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关71/27兴
关87/5兴关70/2兴
关69/5兴
关66/2兴
关65/16兴
关65/16兴
关65/16兴
关63/20兴
关63/8兴
关63/2兴
关59/11兴关84/9兴
关1898兴关84/9兴
关78-92-2兴
关95/13兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关82/13兴
关78/20兴
关75/23兴
关75/1兴
关73/26兴
关71/27兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
588
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共323–373兲
共422–538兲
共345–381兲
共340–379兲
C4 H10O
2-methyl-1-propanol
共350– 400兲
共313– 411兲
共381–524兲
共202–243兲
共369–389兲
共383– 416兲
共401– 493兲
共483–548兲
共320–382兲
共293–388兲
共342–389兲
共333–381兲
共423–548兲
共353–388兲
C4 H10O
2-methyl-2-propanol
共321–359兲
共323–373兲
共299–375兲
共347–363兲
共356 – 480兲
共347–363兲
共357– 461兲
共453–506兲
共306 –357兲
共293–376兲
共313–355兲
共333–363兲
共329–363兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
46.3
49.7⫾0.1
38.4
44.1
48.5
44.7
共338兲
共298兲
共437兲
共360兲
共298兲
共355兲
EB
C
EB
45.3⫾0.1
43.3⫾0.1
41.9⫾0.1
40.8⫾0.1
共340兲
共355兲
共365兲
共372兲
C
C
C
C
45.4
49.5
46.0
55.0
44.2
42.6
41.1
36.2
50.8⫾0.1
49.7⫾0.1
48.3⫾0.1
45.0⫾0.1
48.1
52.6
50.79⫾0.02
46.2⫾0.1
44.2⫾0.1
41.9⫾0.1
46.2
47.0
50.8⫾0.1
40.1
45.2
49.8
共365兲
共328兲
共396兲
共228兲
共379兲
共398兲
共416兲
共498兲
共298兲
共313兲
共328兲
共358兲
共335兲
共308兲
共298兲
共347兲
共363兲
共381兲
共357兲
共348兲
共298兲
共438兲
共368兲
共298兲
EB
A
A
A
A
A
A
A
C
C
C
C
43.4
45.4
46.2
41.4
43.2
41.4
39.8
33.6
46.2⫾0.1
44.9⫾0.1
43.0⫾0.1
41.0⫾0.1
37.2⫾0.1
44.7
46.5
46.94⫾0.02
44.2
46.6⫾0.1
42.1
42.5⫾0.1
41.3⫾0.1
40.4⫾0.1
40.0⫾0.1
39.0⫾0.1
42.6
共336兲
共298兲
共314兲
共355兲
共371兲
共355兲
共372兲
共468兲
共303兲
共313兲
共328兲
共343兲
共368兲
共321兲
共308兲
共298兲
共328兲
共298兲
共348兲
共330兲
共340兲
共346兲
共349兲
共356兲
共344兲
44.9
共298兲
Method
C
C
C
C
C
A, EB
C
EB
C
CGC
A
A
A
A
A
A
C
C
C
C
C
C
C
EB
C
C
C
C
C
EB
C
CAS registry number
Reference
关69/19兴关84/9兴
关66/2兴
关63/20兴
关63/8兴
关63/2兴
关87/5兴关62/15兴
关70/2兴
关62/15兴
关62/15兴
关62/15兴
关62/15兴
关78-83-1兴
关93/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关84/5兴
关84/5兴
关84/5兴
关84/5兴
关82/13兴
关73/26兴
关71/27兴
关70/20兴
关70/20兴
关70/20兴
关87/5兴关70/2兴
关69/19兴关84/9兴
关66/2兴
关63/20兴
关63/8兴
关63/2兴
关75-65-0兴
关99/30兴
关95/21兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关84/5兴
关84/5兴
关84/5兴
关84/5兴
关84/5兴
关82/13兴
关73/26兴
关71/27兴
关69/19兴关84/9兴
关66/2兴
关63/18兴
关63/18兴
关63/18兴
关63/18兴
关63/18兴
关63/18兴
关87/5兴关70/2兴
关63/18兴
关63/2兴
ENTHALPIES OF VAPORIZATION
589
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H10O
Compound
共Temperature range/K兲
共373–506兲
共293–363兲
diethyl ether
共286 –329兲
共307– 457兲
共305–360兲
共351– 420兲
共417– 467兲
共250–329兲
共250–329兲
C4 H10O
共213–293兲
isopropyl methyl ether
共250–325兲
共260–325兲
C4 H10O
methyl propyl ether
共325– 407兲
共401– 476兲
共273–321兲
共253–328兲
C4 H10O2
C4 H10O2
C4 H10O2
C4 H10O2
C4 H10O2
C4 H10O2
C4 H10O2
C4 H10O2
共273–312兲
共⫾兲 1,2-butanediol
共372–506兲
共⫾兲 1,3-butanediol
共365–518兲
共362– 483兲
共373– 423兲
共423– 480兲
1,4-butanediol
共380–510兲
(dl) 2,3-butanediol
共348 – 457兲
共317– 455兲
共353– 403兲
共303– 456兲
meso 2,3-butanediol
共413– 453兲
共l兲 2,3-butanediol
共413– 453兲
diethylperoxide
共253–333兲
C4 H10O2
C4 H10O2 S
Mean temperature
(T m /K)
38.7
44.7
共388兲
共323兲
28.1
26.9
27.5
26.6
26.7
27.1⫾0.1
27.2
29.5
共301兲
共322兲
共320兲
共366兲
共432兲
共298兲
共298兲
共265兲
28.4
共278兲
28.8
26.4⫾0.1
28.4
26.4
共265兲
共298兲
共275兲
共298兲
A
C
A
27.2
26.7
30.7
27.6⫾0.1
29.7
27.5
27.9⫾0.2
29.7
共340兲
共416兲
共288兲
共298兲
共268兲
共298兲
共298兲
共288兲
A
A
A
C
A
71.6⫾0.8
共298兲
EB
74.5⫾1.0
67.6
59.7
58.1
共298兲
共377兲
共398兲
共451兲
EB
A
79.3⫾0.5
72.0
共298兲
共395兲
C
A
62.5
58.4
57.9
55.7
共363兲
共332兲
共378兲
共380兲
A
54.6
共433兲
关46/12兴
52.6
共433兲
29.0
共268兲
A
36.4⫾0.1
33.4
共298兲
共288兲
C
A
36.8⫾0.2
39.4
39.1
33.9
共298兲
共253兲
共253兲
共240兲
EB
A
A
47.4
45.9
48.2⫾0.1
44.7
共325兲
共338兲
共298兲
共351兲
EB
TGA
C
A
关46/12兴
关628-37-5兴
关87/5兴关51/10兴
关71/21兴
关534-15-6兴
关70/17兴
关87/5兴关49/2兴
关71/21兴
关110-71-4兴
关96/5兴
关87/5兴
关87/5兴
关47/5兴
关110-80-5兴
关01/17兴
关87/18兴
关71/5兴
关87/5兴关56/6兴
关111-48-8兴
Method
A
A
A
A
A
C
A
C
1,1-dimethoxyethane
共273–333兲
C4 H10O2
⌬ vapH m
共kJ mol⫺1兲
1,2-dimethoxyethane
共305–392兲
共238 –298兲
共238 –363兲
共225–366兲
2-ethoxyethanol
共310–385兲
共323–353兲
共336 – 408兲
bis 共2-hydroxyethyl兲 sulfide
CAS registry number
Reference
关63/20兴
关28/5兴
关60-29-7兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关80/3兴
关76/2兴
关87/5兴关72/9兴
关76/2兴
关22/2兴
关598-53-8兴
关87/5兴
关80/3兴
关87/5兴关76/2兴
关76/2兴
关557-17-5兴
关87/5兴
关87/5兴
关87/5兴
关80/3兴
关87/5兴关76/2兴
关76/2兴
关75/3兴
关10/1兴关84/9兴
关26171-83-5兴
关96/3兴
关107-88-0兴
关96/3兴
关87/5兴
关35/4兴
关35/4兴
关110-63-4兴
关88/14兴
关87/5兴
关513-85-9兴
关87/5兴
关47/5兴
关35/4兴
关35/4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
590
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H10O3
C4 H10O3
C4 H10O3
C4 H10O3 S
Compound
共Temperature range/K兲
共368 – 483兲
共315–558兲
diethylene glycol
共410–539兲
共410–539兲
共410–539兲
共410–539兲
共373– 453兲
共364 –518兲
共412–513兲
共403–513兲
1,2,3-butanetriol
共375–537兲
orthoformic acid trimethyl ester
共273–358兲
C4 H10O4 S
C4 H10S
meso erythritol
共397– 428兲
共394 – 401兲
diethyl sulfate
共413– 484兲
共320– 482兲
1-butanethiol
共323– 409兲
C4 H10S
tert-butyl mercaptan
共275–293兲
共293–373兲
C4 H10S
A
66.9⫾0.3
63.1⫾0.3
59.2⫾0.3
55.1⫾0.5
66.5
59.8
66.8
69.2
共420兲
共460兲
共500兲
共540兲
共413兲
共379兲
共427兲
共418兲
EB
EB
EB
EB
TGA
A
68.1
共390兲
39.0
38.1⫾0.8
共288兲
共298兲
A
44.7
44.5
共298兲
A
113.6⫾1.1
93.3
共412兲
共397兲
TE
A
50.1
54.9
共428兲
共335兲
A
36.5
35.0
共298兲
共338兲
A, EB
34.7⫾0.1
33.6⫾0.1
32.2⫾0.1
共330兲
共350兲
共371兲
C
C
C
34.1
33.2
共298兲
共325兲
A, EB
32.9⫾0.1
32.3⫾0.1
31.8⫾0.1
30.6⫾0.1
共318兲
共329兲
共337兲
共358兲
C
C
C
C
34.6
33.6
共298兲
共329兲
A, EB
33.3⫾0.1
32.3⫾0.1
31.0⫾0.1
共321兲
共340兲
共361兲
C
C
C
30.1
30.8
30.9
共284兲
共298兲
共308兲
A, EB
35.8⫾0.7
35.5
35.8
34.4
共298兲
共298兲
共298兲
共333兲
34.8
37.5
33.5
共324兲
共248兲
共364兲
34.1
共298兲
diethyl sulfide
共318 –396兲
共309–371兲
共233–361兲
C4 H10S
共383兲
共330兲
2-methyl-1-propanethiol
共314 –399兲
C4 H10S
27.1
28.3
Method
(dl) 2-butanethiol
共310–395兲
C4 H10S
Mean temperature
(T m /K)
diethyl sulfite
共283– 431兲
C4 H10O4
⌬ vapH m
共kJ mol⫺1兲
methyl isopropyl sulfide
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
A, EB
EB
CAS registry number
Reference
关87/5兴
关47/5兴
关111-46-6兴
关02/15兴
关02/15兴
关02/15兴
关02/15兴
关87/18兴
关87/5兴
关81/17兴关84/9兴
关27/1兴关84/9兴
关4435-50-1兴
关47/5兴
关149-73-5兴
关87/5兴
关71/26兴
关623-81-4兴
关75/43兴
关87/5兴关47/5兴
关99/16兴
关149-32-6兴
关90/16兴
关87/5兴
关64-67-5兴
关87/5兴
关47/5兴关99/16兴
关109-75-5兴
关71/28兴
关87/5兴关57/7兴
关66/5兴
关57/7兴
关57/7兴
关57/7兴
关513-53-1兴
关71/28兴
关87/5兴关58/7兴
关66/5兴
关58/7兴
关58/7兴
关58/7兴
关58/7兴
关513-44-0兴
关71/28兴
关87/5兴关58/6兴
关66/5兴
关58/6兴
关58/6兴
关58/6兴
关75-66-1兴
关98/25兴
关71/28兴
关87/5兴关53/7兴
关66/5兴
关352-93-2兴
关89/12兴
关81/12兴
关71/28兴
关87/5兴关52/11兴
关66/5兴
关52/9兴
关47/5兴
关35/2兴
关1551-21-9兴
关71/28兴
ENTHALPIES OF VAPORIZATION
591
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H10S
Compound
共Temperature range/K兲
共298 –368兲
methyl propyl sulfide
共308 –374兲
C4 H10S2
C4 H10S2
1,4-butanedithiol
共347– 469兲
diethyl disulfide
共383– 423兲
共287– 434兲
共373– 431兲
C4 H11N
共359– 433兲
butyl amine
共323–373兲
共313–350兲
共296 –349兲
C4 H11N
C4 H11N
C4 H11N
(dl) 2-aminobutane
共264 –371兲
sec-butylamine
共300–335兲
isobutylamine
共248 –347兲
共297–340兲
C4 H11N
C4 H11N
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
33.0⫾0.1
32.0⫾0.1
30.7⫾0.1
33.8
共318兲
共336兲
共358兲
共313兲
C
C
C
A, EB
36.2
35.3
34.5⫾0.1
33.4⫾0.1
32.1⫾0.1
共298兲
共323兲
共328兲
共347兲
共369兲
A, EB
C
C
C
50.9
55.3
54.9
共362兲
共298兲
共298兲
A
44.8
45.4⫾0.8
45.7
45.2⫾0.1
45.2
45.6
40.9
共298兲
共298兲
共302兲
共298兲
共298兲
共298兲
共388兲
CGC
C
A
C
41.5
共374兲
EB
35.6
34.7
35.7⫾0.2
35.5
35.7⫾0.1
34.7⫾0.1
33.5⫾0.1
32.4⫾0.1
31.1⫾0.1
35.7⫾0.1
共298兲
共328兲
共298兲
共311兲
共298兲
共313兲
共323兲
共343兲
共358兲
共298兲
CGC
A
C
EB
C
C
C
C
C
C
34.1
共279兲
A
32.4
32.7⫾0.1
31.6⫾0.1
30.5⫾0.1
29.4⫾0.1
32.6⫾0.1
共315兲
共298兲
共313兲
共328兲
共343兲
共298兲
EB
C
C
C
C
C
37.6
33.9⫾0.1
32.7⫾0.1
31.6⫾0.1
33.5
33.8⫾0.1
33.9⫾0.2
共263兲
共298兲
共313兲
共328兲
共313兲
共298兲
共298兲
C
C
C
EB
C
IPM
29.6⫾0.1
30.1
共298兲
共307兲
C
A, EB, IPM
31.2
30.4
28.4
31.3⫾0.1
30.2⫾0.1
29.1⫾0.1
28.0⫾0.1
31.2⫾0.1
共315兲
共340兲
共446兲
共298兲
共313兲
共328兲
共343兲
共298兲
A
A
A
C
C
C
C
C
EB
tert-butylamine
共292–349兲
diethylamine
共302–328兲
共325– 437兲
共431– 496兲
CAS registry number
Reference
关55/12兴
关55/12兴
关55/12兴
关87/5兴关52/9兴
关3877-15-4兴
关71/28兴
关87/5兴关52/9兴
关57/7兴
关57/7兴
关57/7兴
关1191-08-8兴
关87/5兴关99/16兴
关62/11兴
关62/11兴
关110-81-6兴
关95/21兴
关89/12兴
关87/5兴
关85/2兴
关81/12兴
关71/28兴
关87/5兴关66/5兴
关52/12兴
关52/9兴
关109-73-9兴
关95/21兴
关87/5兴
关85/2兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关69/2兴
关13952-84-6兴
关87/5兴关71/21兴
关13952-84-6兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关69/2兴
关78-81-9兴
关87/5兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关69/2兴
关65/8兴关70/11兴
关75-64-9兴
关69/2兴
关87/5兴关68/4兴
关109-89-7兴
关87/5兴
关87/5兴
关87/5兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关69/2兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
592
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C4 H11N
C4 H11NO
C4 H11NO
C4 H11NO2
C4 H11NO2
C4 H11NO2 S
C4 H11O3 P
C4 H11O3 P
C4 H12ClN
C4 H12ClN
C4 H12ClN2 P
C4 H12FN2 OP
C4 H12NP
C4 H12N2
C4 H12N2
C4 H12N2
C4 H12N2 O
C4 H12N2 OS
C4 H12N2 OS
C4 H12N2 S
C4 H13N3
C4 H13N3
C5 BrF12N
C5 ClF5
C5 ClF5
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共273–333兲
共292–313兲
共304 –323兲
N-methyl isopropyl amine
32.7⫾0.2
31.8
31.5
共298兲
共307兲
共319兲
I
30.7⫾0.1
29.5⫾0.1
27.1⫾0.1
30.9
共298兲
共313兲
共343兲
共306兲
C
C
C
EB
43.2
42.7
共365兲
共338兲
A
A
44.5
共293兲
A
69.0
共478兲
74.4
77.0
70.6
共438兲
共391兲
共481兲
A
54.3
共399兲
A
38.1
共353兲
A
70.1
共348兲
62.1
共498兲
177.6
共528兲
45.9⫾1.2
共298兲
STG
50.4
共327兲
A
36.8
共279兲
A
50.2
46.9
46.3⫾0.2
共278兲
共298兲
共298兲
IPM
IPM
47.2
43.5⫾0.2
43.6⫾0.2
共278兲
共298兲
共298兲
IPM
IPM
IPM
共293–319兲
2-共dimethylamino兲ethanol
共350–387兲
共323– 408兲
3-methoxypropylamine
共278 –390兲
2,2⬘-iminodiethanol
共463–582兲
diethanolamine
共423–542兲
共376 – 454兲
共466 –514兲
N,N-dimethylethanesulfonamide
共384 –517兲
diethylphosphite
共338 – 471兲
dimethyl ethylphosphonate
共333– 410兲
butylammonium chloride
共489–508兲
diethylamine hydrochloride
共513–558兲
bis共dimethylamino兲chlorophosphine
bis共dimethylamido兲fluorophosphate
共312–350兲
dimethyl共dimethylamino兲phosphine
共264 –372兲
(dl) 1,2-butanediamine
共251–293兲
共251–293兲
2-methyl-1,2-propanediamine
共256 –293兲
共256 –293兲
tetramethylhydrazine
共290–346兲
32.9
共305兲
N-共2-hydroxyethyl兲ethylenediamine
共383–517兲
62.8
共398兲
tetramethyl sulfurous diamide
共320–351兲
41.9
共335兲
N,N,N⬘,N⬘-tetramethylsulfamide
共358 – 495兲
53.2
共373兲
tetramethylsulfoxylic diamide
共301–326兲
40.4
共313兲
2,2⬘-diaminodiethylamine
共371–521兲
63.4⫾0.7
共298兲
dimethylene triamine
共371– 441兲
54.8
共386兲
1,1,2,3,3,3-hexafluoro-2-bromo-N,N-bis共trifluoromethyl兲-propylamine
共324 –351兲
30.2
共337兲
1-chloro-2,3,4,5,5-pentafluoro-1,3-cyclopentadiene
共273–303兲
31.0
共288兲
5-chloro-1,2,3,4,5-pentafluoro-1,3-cyclopentadiene
共283–323兲
28.7
共298兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
T
A
A
A
A
EB
A
A
A
A
CAS registry number
Reference
关69/16兴
关65/24兴关84/9兴
关62/23兴关84/9兴
关4747-21-1兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关108-01-0兴
关87/5兴
关87/5兴
关5332-73-0兴
关87/5兴
关111-42-2兴
关59/1兴
关111-42-2兴
关87/5兴
关69/20兴关84/9兴
关59/1兴关84/9兴
关6338-68-7兴
关87/5兴
关762-04-9兴
关87/5兴
关87/5兴关55/5兴
关84/9兴
关3858-78-4兴
关87/5兴
关660-68-4兴
关87/5兴
关95/2兴
关115-26-4兴
关87/5兴
关683-84-1兴
关87/5兴
关4426-48-6兴
关87/5兴关75/4兴
关75/4兴
关65/8兴关70/11兴
关811-93-8兴
关87/5兴关75/4兴
关75/4兴
关65/8兴关70/11兴
关6415-12-9兴
关87/5兴关57/20兴
关111-41-1兴
关87/5兴
关3768-60-3兴
关87/5兴关99/16兴
关3768-63-6兴
关87/5兴关99/16兴
关2129-20-6兴
关87/5兴
关111-40-0兴
关99/7兴
关111-40-0兴
关87/5兴
关87/5兴
关30221-57-9兴
关87/5兴
关30221-56-8兴
关87/5兴
ENTHALPIES OF VAPORIZATION
593
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 ClF10N
C5 ClF12N
C5 Cl2 F6
C5 Cl2 F9 N
C5 Cl5 F7 O
C5 Cl6
C5 Cl8
C5 F5 N
C5 F8
C5 F9 N
C5 F9 N
C5 F9 NO
C5 F9 NO
C5 F9 NO3 S
C5 F10
C5 F10N2 O2
C5 F10N2 O2
C5 F10O2
C5 F10O3 S
C5 F10O6 S2
C5 F11N
C5 F11N
C5 F11NO
C5 F12
C5 F12
C5 F12N2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
2,2,2-trifluoro-N-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethylidene兴-ethanimidoyl chloride
28.6
共361兲
N-chloro-1,1,2,3,3,3-heptafluoro-N-共pentafluoroethyl兲-2-propanamine
28.6
共346兲
1,2-dichlorohexafluorocyclopentene
33.0
36.5
共298兲
1,1-dichloro-2,2,2-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲-ethylidene兴ethanamine
31.2
共361兲
共1,1,2-trifluoro-2,2-dichloroethyl兲共2,2,3,3-tetrafluoro-1,1,3-trichloropropyl兲 ether
共362– 449兲
45.3
共377兲
50.7⫾0.8
共298兲
hexachlorocyclopentadiene
共335–512兲
53.7
共350兲
67.4
octachlorocyclopentene
83.4
perfluoropyridine
共273–363兲
36.3
共288兲
perfluoro-1,2-pentadiene
共262–276兲
26.1
共269兲
3,3,3-trifluoro-N,N-bis共trifluoromethyl兲-1-propylamine
共277–293兲
24.9
共285兲
2,3,4,5-tetrahydrononafluoropyridine
共249–310兲
29.3
共264兲
2,2,2-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-acetamide
32.1
共319兲
3,3,4,5,6,6-hexafluoro-3,6-dihydro-2-trifluoromethyl-2H-1,2-oxazine
共263–323兲
31.4
共278兲
nonafluoro-1-butanesulfonyl isocyanate
共309– 401兲
48.2
共324兲
perfluorocyclopentane
共285–297兲
27.0
共291兲
共290–330兲
25.6
共298兲
共290–329兲
26.3
共298兲
decafluoroglutaramide
35.6
共368兲
1-nitrodecafluoropiperadine
共283–343兲
29.6
共298兲
carbonofluoridic acid, 2,2,2-trifluoro-1,1-bis共trifluoromethyl兲ethyl ester
共275–305兲
32.2
共290兲
perfluorocyclopentyl fluorosulfate
共255–360兲
36.6
共307兲
octafluorocyclopentanediol bis共fluorosulfate兲
共334 – 423兲
49.5
共349兲
perfluoropiperidine
共302–355兲
30.0
A
EB
A
A
A
A
A
A
A
A
HG
A
A
共317兲
A
octafluoro-1-共trifluoromethyl兲pyrrolidine
共249–306兲
29.4
共264兲
N,2,2,2-tetrafluoro-N-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-acetamide
32.6
共332兲
perfluoro-2-methylbutane
共290–340兲
26.3
共298兲
共228 –308兲
31.0
共243兲
共290–337兲
27.4
共298兲
perfluoropentane
共280–340兲
26.6
共298兲
共221–303兲
31.1
共236兲
共288 –338兲
27.5
共298兲
关2,2,2-trifluoro-1,1-bis共trifluoromethyl兲ethyl兴共trifluoromethyl兲diazene
23.7
共309兲
A
A
A
CAS registry number
Reference
关54120-14-8兴
关75/19兴
关54566-78-8兴
关75/19兴
关706-79-6兴
关59/28兴
关59/28兴
关54566-77-7兴
关75/19兴
关61196-11-0兴
关87/5兴
关76/15兴
关77-47-4兴
关87/5兴
关77/26兴
关706-78-5兴
关77/26兴
关700-16-3兴
关87/5兴关61/9兴
关72/20兴
关21972-01-1兴
关87/5兴
关19451-91-3兴
关87/5兴
关714-37-4兴
关87/5兴
关52225-57-7兴
关74/24兴
关4827-67-2兴
关87/5兴
关34805-64-6兴
关87/5兴
关376-77-2兴
关87/5兴
关84/9兴关91/2兴
关56/10兴
关32822-52-9兴
关71/18兴
关1840-07-9兴
关87/5兴
关55064-79-4兴
关87/5兴关75/22兴
关63/17兴
关741-20-8兴
关72/20兴关87/5兴
关99/16兴
关836-77-1兴
关87/5兴关63/19兴
关72/20兴
关2344-10-7兴
关87/5兴
关52225-65-7兴
关74/24兴
关594-21-2兴
关84/9兴关91/2兴
关87/5兴关67/15兴
关56/10兴
关678-26-2兴
关84/9兴关91/2兴
关87/5兴关67/15兴
关56/10兴
关53684-06-3兴
关75/21兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
594
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 F12O2
C5 F12O2 S
C5 F12O4 S
C5 F13N
C5 F13NS
C5 F14N2 O
C5 F14N2 O
C5 F14OS
C5 F15N
C5 F15NS
C5 F15P5
C5 O2
C5 HClF8 O2
C5 HF10NO
C5 HF9
C5 HF9 IN
C5 HF9 IN
C5 HF9 O2
C5 HF10N
C5 HF12N
C5 HN3
C5 H2 BrF8 N
C5 H2 F6 O2
C5 H2 F9 N
C5 H2 F9 NOS
C5 H2 F9 NS
C5 H2 F10O
C5 H2 F10O
C5 H2 F10O
C5 H3 BrF9 N
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
bis共pentafluoroethoxy兲difluoromethane
共246 –299兲
32.7
共261兲
trifluoromethanesulfinic acid, 2,2,2-trifluoro-1,1-bis共trifluoromethyl兲
ethyl ester
37.7
共355兲
pentafluoro共2,2,3,3,4,4,5-heptafluoro-5-oxopentaneperoxoato兲 sulfur
39.2
N-共trifluoromethyl兲bis共pentafluoroethyl兲amine
共298 –319兲
30.2
共308兲
29.4⫾0.4
共298兲
N-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-S,S-bis共trifluoro-methyl兲sulfilimine
共314 –360兲
31.3
共329兲
1-关difluoro共trifluoromethoxy兲methyl兴-1,2,2-tris共trifluoromethyl兲-hydrazine
共302–311兲
34.7
共306兲
1,1-difluoro-N-共trifluoromethoxy兲-N,N⬘,N⬘-tris共trifluoromethyl兲-methanediamine
共282–323兲
33.7
共297兲
pentafluoro关共nonafluorocyclopentyl兲oxyl兴 sulfur
共300–361兲
36.1
共315兲
N-共trifluoromethyl兲bis共pentafluoroethyl兲amine
29.4⫾0.4
共298兲
difluoro关1,1,1,2,3,3,3-heptafluoro-2-propanaminoto共2-兲兴-bis共trifluoromethyl兲 sulfur
32.2
共375兲
1,2,3,4,5-pentakis共trifluoromethyl兲pentaphospholane
共319– 435兲
51.8
共334兲
pentacarbon dioxide
共186 –273兲
4.6
共258兲
trifluoroacetic acid, 1-共chlorodifluoromethyl兲-2,2,2-trifluoroethyl ester
37.2
共338兲
2,2,2-trifluoro-N-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-acetamide
42.3
共367兲
nonafluorocyclopentane
共289–348兲
29.6
共304兲
共289–348兲
29.4
共298兲
cis 3,3,3-trifluoro-1-iodo-N,N-bis共trifluoromethyl兲propenylamine
共343–366兲
31.3
共354兲
trans 3,3,3-trifluoro-1-iodo-N,N-bis共trifluoromethyl兲propenylamine
共345–368兲
35.0
共356兲
trifluoroacetic acid, 2,2,2-1-共trifluoromethyl兲ethyl ester
28.5
共321兲
2,2,3,3,4,4,5,5,6,6-decafluoropiperidine
共273–313兲
32.7
共288兲
1,1,1,2,3,3,3-heptafluoro-N-共pentafluoroethyl兲-2-propanamine
29.8
共325兲
ethylenetricarbonitrile
共313–343兲
66.0
共328兲
2-bromo-3,3-difluoro-N,N-bis共trifluoromethyl兲allylamine
共336 –367兲
33.8
共351兲
1,1,1,5,5,5-hexafluoropentan-2,4-dione
共273–330兲
33.1
共301兲
30.6⫾0.1
共298兲
trans 3,3,3-trifluoro-N,N-bis共trifluoromethyl兲propenylamine
共287–319兲
28.2
共302兲
2,2,2-trifluoro-N-关共trifluoromethyl兲thio兴ethanimidic acid, 2,2,2-trifluoroethyl ester
35.8
共373兲
2,2,2-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethyl兴ethane-thioamide
36.9
1,1,1,2,2,3,3-heptafluoro-3-共2,2,2-trifluoroethoxy兲propane
共288 –325兲
31.5
共303兲
1,1,1,2,4,4,4-heptafluoro-2-共trifluoromethoxy兲butane
共288 –323兲
31.8
共303兲
1,1,1,2,2-pentafluoro-3-共pentafluoroethoxy兲propane
共288 –320兲
31.2
共303兲
2-bromo-3,3,3-trifluoro-N,N-bis共trifluoromethyl兲propylamine
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
HG
A
A
A
A
A
I
A, SG
A
HG
A
A
A
HG
A
A, MG
A
GS
A
I
I
I
I
CAS registry number
Reference
关20822-11-1兴
关87/5兴
关52225-54-4兴
关74/25兴
关60672-63-1兴
关76/31兴
关1481-55-6兴
关87/5兴
关77/13兴
关37826-44-1兴
关87/5兴关99/16兴
关17636-89-4兴
关87/5兴
关17636-88-3兴
关87/5兴
关736-59-4兴
关87/5兴关99/16兴
关758-48-5兴
关77/20兴
关65844-10-2兴
关78/14兴
关745-23-3兴
关87/5兴关58/10兴
关51799-36-1兴
关87/5兴关37/1兴
关52225-55-5兴
关74/25兴
关74/24兴
关376-65-8兴
关87/5兴关56/10兴
关56/10兴
关20257-34-5兴
关87/5兴
关20257-35-6兴
关87/5兴
关42031-15-2兴
关73/20兴
关559-31-9兴
关87/5兴
关54566-80-2兴
关75/19兴
关997-76-2兴
关87/5兴关63/1兴
关19451-93-5兴
关87/5兴
关1522-22-1兴
关98/5兴
关97/2兴关75/2兴
关78/18兴
关25273-42-1兴
关87/5兴
关62067-07-6兴
关77/18兴
关57682-29-8兴
关75/42兴
关142469-08-7兴
关02/19兴
关347148-74-7兴
关02/19兴
关155653-44-4兴
关02/19兴
关19451-92-4兴
ENTHALPIES OF VAPORIZATION
595
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H3 F6 N
C5 H3 F7 O2
C5 H3 F8 NOS
C5 H3 F9 N2 OS
C5 H3 F9 O
C5 H3 F9 O
C5 H3 F9 O
C5 H3 F9 O
C5 H3 F9 O
C5 H3 F9 O
C5 H3 F9 O
C5 H3 F9 O2 S
C5 H3 N3
C5 H4 BrF6 N
C5 H4 BrF6 N
C5 H4 BrN
C5 H4 BrN
C5 H4 ClN
C5 H4 ClN
C5 H4 F4 N4 O10
C5 H4 F7 I
C5 H4 F8 O
C5 H4 F8 O
C5 H4 F9 N
C5 H4 N2
C5 H4 N2
C5 H4 N4
C5 H4 O2
C5 H4 O2 S
C5 H4 O3
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共342–365兲
34.2
共353兲
A
N,N-bis共trifluoromethyl兲-1-propynylamine
共295–312兲
31.1
共303兲
A
methyl perfluorobutyrate
34.5
2,2,3,3,4,4,5,5-octafluoro-1,1,2,3,4,5-hexahydro-1-共methylimino兲-thiophene-1-oxide
33.9
共330兲
1,1,1-trifluoro-N⬘-methyl-N-关2,2,2-trifluoro-1-共trifluoromethyl兲-ethylidene兴methanesulfonimidamide
32.6
共417兲
I
1,1,2,2-tetrafluoro-3-共pentafluoroethoxy兲propane
共288 –336兲
34.0
共303兲
I
1-共2,2-difluoroethoxy兲-1,1,2,2,3,3,3-heptafluoropropane
共288 –340兲
34.8
共303兲
I
1,1,1,2,2-pentafluoro-3-共1,1,2,2-tetrafluoroethoxy兲propane
共293–343兲
35.6
共308兲
I
1,1,1,2,4,4-hexafluoro-2-共trifluoromethoxy兲butane
共283–332兲
33.8
共298兲
I
1,1,1,3,3,3-hexafluoro-2-methoxy-2-共trifluoromethyl兲propane
共288 –326兲
31.3
共303兲
I
1,1,1,2,3,3-hexafluoro-3-共2,2,2-trifluoroethoxy兲propane
共293–346兲
36.1
共308兲
I
1,1,1,2,3,3-hexafluoro-4-共trifluoromethoxy兲butane
共288 –338兲
34.0
共303兲
I
trifluoromethanesulfinic acid, 2,2,2-trifluoro-1-methyl-1-共trifluoromethyl兲ethyl ester
34.3
共385兲
HG
2,2-dicyanopropionitrile
共293–333兲
55.2
B
cis 2-bromo-N,N-bis共trifluoromethyl兲propenylamine
共346 –367兲
35.3
共356兲
A
trans 2-bromo-N,N-bis共trifluoromethyl兲propenylamine
共336 –360兲
33.3
共348兲
A
2-bromopyridine
54.4⫾1.3
共298兲
C
3-bromopyridine
52.1⫾1.3
共298兲
C
共289– 447兲
47.4
共304兲
A
2-chloropyridine
51.0⫾1.2
共298兲
C
共286 – 444兲
53.0
共301兲
A
3-chloropyridine
47.9⫾1.1
共298兲
C
bis共2-fluoro-2,2-dinitroethyl兲difluoroformal
共323–357兲
72.7
共340兲
1,1,1,2,2,3,3-heptafluoro-5-iodopentane
共317–386兲
38.7
共332兲
A
1,1,2,2-tetrafluoro-3-共1,1,2,2-tetrafluoroethoxy兲propane
共293–366兲
40.2
共308兲
I
1,1,1,3,3-pentafluoro-3-methoxy-2-trifluoromethylpropane
共288 –343兲
34.5
共303兲
I
3,3,3-trifluoro-N,N-bis共trifluoromethyl兲propylamine
共290–333兲
31.0
共305兲
A
cis 2-methyl-2-butenedinitrile
共395– 467兲
58.5
共410兲
A
trans 2-methyl-2-butenedinitrile
共339– 411兲
47.9
共354兲
A
1,2,4-triazolo关1,5-a兴pyrimidine
共370–523兲
82.5⫾13.1
共298兲
EB
2-furfuraldehyde
共357– 435兲
44.7
共372兲
A
共329– 433兲
48.2
共344兲
共365– 443兲
47.6
共380兲
2-thiophene carboxylic acid
共314 –323兲
96.9 共sub兲
共319兲
citraconic anhydride
CAS registry number
Reference
关87/5兴
关25237-11-0兴
关87/5兴
关77/28兴关78/19兴
关77589-48-1兴
关81/15兴
关62609-63-6兴
关77/19兴
关176310-27-3兴
关02/19兴
关176310-28-4兴
关02/19兴
关50807-74-4兴
关02/19兴
关02/19兴
关66670-22-2兴
关02/19兴
关993-95-3兴
关02/19兴
关69948-43-2兴
关02/19兴
关52225-51-1兴
关74/25兴
关10359-20-3兴
关94/5兴
关25273-47-6兴
关87/5兴
关25273-48-7兴
关87/5兴
关109-04-6兴
关97/3兴
关626-55-1兴
关97/3兴
关87/5兴关47/5兴
关109-09-1兴
关97/4兴
关87/5兴关47/5兴
关626-60-8兴
关97/4兴
关97/12兴
关1513-88-8兴
关87/5兴
关16627-68-2兴
关02/19兴
关382-26-3兴
关02/19兴
关19451-89-9兴
关87/5兴
关37580-43-1兴
关87/5兴关72/20兴
关37580-44-2兴
关87/5兴关72/20兴
关275-02-5兴
关97/7兴
关98-01-1兴
关87/5兴
关50/1兴关84/9兴
关26/4兴关84/9兴
关527-72-0兴
关99/16兴
关616-02-4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
596
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H5 Cl3 OS
C5 H5 F3 O2
C5 H5 F6 NO
C5 H5 F6 NO
C5 H5 F6 NO
C5 H5 F6 NO2
C5 H5 F7 O
C5 H5 F7 O
C5 H5 F7 O
C5 H5 N
C5 H5 N
C5 H5 N
C5 H5 N
C5 H5 NO2
C5 H6
C5 H6
C5 H6
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共320– 487兲
53.3
2,3,3-trichloro-2-propenethioic acid, O-ethyl ester
共383– 423兲
66.9
1,1,1-trifluoropentane-2,4-dione
37.2⫾0.2
N,N-bis共trifluoromethyl兲allylamine-N-oxide
共254 –328兲
33.1
1-methoxy-N,N-bis共trifluoromethyl兲vinylamine
共321–343兲
32.4
cis 2-methoxy-N,N-bis共trifluoromethyl兲vinylamine
共341–362兲
32.5
N,N-bis共trifluoromethyl兲propionamide-N-oxide
共278 –361兲
42.1
1,1,1,2-tetrafluoro-2-共trifluoromethoxy兲butane
共283–319兲
30.3
1-ethoxy-1,1,2,2,3,3,3-heptafluoropropane
共288 –323兲
31.0
1,1,1,2,2,3,3-heptafluoro-4-methoxybutane
共293–344兲
34.6
cis 1-cyano-1,3-butadiene
40.7
38.3
cis 2,4-pentadienenitrile
共318 –383兲
41.4
bicyclo关1.1.0兴butane-1-carbonitrile
共307–349兲
48.0
pyridine
40.16⫾0.06
共323–373兲
40.4
共295–388兲
39.9
共296 –353兲
39.7
共348 – 434兲
37.3
共431–558兲
35.0
共552– 620兲
34.0
共298 –333兲
39.6
40.2
39.4
38.5
37.7
36.3
共340– 426兲
37.6
37.5⫾0.1
36.4⫾0.1
35.1⫾0.1
共320–388兲
38.4
2-cyanoacrylic acid, methyl ester
共258 –283兲
57.8
1,3-cyclopentadiene
共271–314兲
共291–314兲
共291–314兲
共273–287兲
ethynylcyclopropane
共290–320兲
isopropenylacetylene
Mean temperature
(T m /K)
Method
共335兲
A
GC
共298兲
共269兲
A
共332兲
A
共351兲
A
共293兲
A
共298兲
I
共303兲
I
共308兲
I
共348兲
共408兲
共333兲
A
共319兲
BG
共298兲
共298兲
共310兲
共311兲
共363兲
共446兲
共567兲
共313兲
共298兲
共313兲
共328兲
共343兲
共368兲
共355兲
共346兲
共366兲
共388兲
共335兲
CGC
EB
A
A
A
A
C
C
C
C
C
EB
C
C
C
MG
共270兲
A
28.2
28.1
28.4⫾0.3
29.7
共286兲
共302兲
共298兲
共298兲
A, MM
MM
31.1
共305兲
A
63.9
共364兲
A
55.9
共344兲
A
85.1
共344兲
27.2
C5 H6 ClN
C5 H6 Cl2 O2
C5 H6 F2 N4 O10
4-chloro-3-pentenenitrile
共349– 433兲
glutaryl chloride
共329– 490兲
bis共2-fluoro-2,2-dinitroethyl兲formal
共323–365兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关87/5兴关47/5兴
关76619-92-6兴
关80/24兴
关367-57-7兴
关97/2兴关75/2兴
关78/18兴
关22743-77-7兴
关87/5兴
关22130-39-8兴
关87/5兴
关22298-35-7兴
关87/5兴
关22743-66-4兴
关87/5兴
关200501-98-0兴
关02/19兴
关22052-86-4兴
关02/19兴
关376-98-7兴
关02/19兴
关54/17兴
关54/17兴
关2180-69-0兴
关87/5兴关72/20兴
关16955-35-4兴
关71/2兴
关110-86-1兴
关96/25兴
关95/21兴
关90/6兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关86/9兴
关84/4兴
关84/4兴
关84/4兴
关84/4兴
关84/4兴
关87/5兴关57/11兴
关57/11兴
关57/11兴
关57/11兴
关53/4兴
关137-05-3兴
关87/5兴关69/11兴
关72/20兴
关542-92-7兴
关67/27兴关84/9兴
关87/5兴关65/28兴
关65/28兴
关65/28兴关33/12兴
关6746-94-7兴
关87/5兴
关78-80-8兴
关77/25兴
关32366-08-8兴
关87/5兴
关2873-74-7兴
关87/5兴关47/5兴
关97/12兴
ENTHALPIES OF VAPORIZATION
597
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H6 F6 N2 S
C5 H6 F6 O
C5 H6 F6 N2 S
C5 H6 F6 O2 S
C5 H6 F6 O5 S2
C5 H6 N2
C5 H6 N2
C5 H6 N2
C5 H6 O
C5 H6 O2
C5 H6 O2
C5 H6 O2
C5 H6 O2
C5 H6 O3
C5 H6 O3
C5 H6 S
Compound
共Temperature range/K兲
C5 H7 ClO3
C5 H7 FO2
C5 H7 N
dimethylmalononitrile
共322– 413兲
2-methylpyrazine
共288 –392兲
glutaronitrile
共364 –560兲
共277–303兲
2-methylfuran
共289–337兲
共251–338兲
共288 –303兲
共333–373兲
共215–360兲
5-methyl-2(3H)-furanone
共324 – 442兲
共dl兲 5-methyl-2共5H兲-furanone
共356 – 481兲
furfuryl alcohol
共304 – 443兲
5-hydroxy-3-pentyn-2-one
共273–333兲
glutaric anhydride
共373–560兲
(dl) monomethylsuccinic anhydride
共342–521兲
2-methylthiophene
共333–373兲
3-methylthiophene
共326 –398兲
共333–373兲
共327–399兲
acetic acid, chlorooxo, propyl ester
共282–396兲
allyl fluoroacetate
共273–333兲
C5 H7 N
C5 H7 N
C5 H7 N
Method
I
I
I
HG
A, I
47.5
共337兲
42.4
共340兲
60.1
66.8
共379兲
共290兲
32.4
34.4
32.5
30.9
32.2
共304兲
共266兲
共295兲
共348兲
共298兲
40.3
共339兲
A
48.2
共371兲
A
53.6
共319兲
A
64.4
共288兲
A
60.9
共388兲
A
59.3
共357兲
A
36.8
38.7
37.2
共348兲
共298兲
共339兲
I
36.8
37.4
39.5
37.5
共357兲
共348兲
共298兲
共342兲
A, EB
52.7
共297兲
A
48.9
共288兲
A, GS
44.3
39.6
40.0⫾0.4
共298兲
共347兲
共298兲
C
BG
BG
37.1
共259兲
42.8
共280兲
A
38.0
39.0
共343兲
共336兲
I
A, EB, IPM
A
A
A
A
A, EB
I
cyclobutanecarbonitrile
共328 – 402兲
C5 H7 N
Mean temperature
(T m /K)
2,2,2-trifluoro-N,N-dimethyl-N⬘-关共trifluoromethyl兲thio兴-ethanimidamide
40.4
共400兲
1,1,1,2,3,3-hexafluoro-4-methoxybutane
共293–360兲
37.0
共308兲
dimethylamino共hexafluoroisoproplidenimino兲 sulfur
39.7
共383兲
trifluoromethanesulfinic acid, 2,2,2-trifluoro-1,1-dimethylethyl ester
35.6
共388兲
3,3-bis关共trifluoromethyl兲sulfonyl兴-1-propanol
共333– 418兲
32.8
共348兲
共324 –391兲
C5 H6 S
⌬ vapH m
共kJ mol⫺1兲
2-ethylacrylonitrile
共244 –387兲
angelic acid, nitrile
共265– 413兲
1-methylpyrrole
共333–373兲
共321– 423兲
共Z兲 2-pentenenitrile
CAS registry number
Reference
关62067-11-2兴
关77/18兴
关58705-93-4兴
关02/19兴
关72/22兴
关52225-49-7兴
关74/25兴
关61915-97-7兴
关87/5兴关77/17兴
关99/16兴
关7321-55-3兴
关87/5兴关67/20兴
关109-08-0兴
关95/4兴
关544-13-8兴
关87/5兴
关87/5兴关72/20兴
关534-22-5兴
关02/30兴
关87/5兴
关72/20兴
关71/3兴关84/9兴
关70/36兴
关591-12-8兴
关87/5兴
关591-11-7兴
关87/5兴
关98-00-0兴
关87/5兴关47/4兴
关15441-65-3兴
关87/5兴关72/20兴
关108-55-4兴
关87/5兴关47/5兴
关4100-80-5兴
关87/5兴关47/5兴
关554-14-3兴
关71/3兴关84/9兴
关71/28兴
关87/5兴关52/9兴
关99/16兴
关616-44-4兴
关99/16兴
关71/3兴关84/9兴
关71/28兴
关87/5兴关52/9兴
关54166-91-5兴
关87/5兴关47/5兴
关87/5兴关48/14兴
关72/20兴
关4426-11-3兴
关83/6兴
关71/2兴
关71/2兴
关87/5兴关47/5兴
关20068-02-4兴
关87/5兴关47/5兴
关96-54-8兴
关71/3兴
关87/5兴关68/4兴
关72/20兴
关25899-50-7兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
598
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C5 H7 N
共E兲 3-pentenenitrile
C5 H7 N
共E兲 2-pentenenitrile
C5 H7 N
tiglic acid, nitrile
共247–395兲
4-oxo-pentanenitrile
共293– 473兲
ethyl cyanoacetate
共340– 479兲
isothiocyanic acid, 3-butenyl ester
共342– 443兲
2,4-dimethylthiazole
共357– 421兲
bicyclo关2.1.0兴pentane
C5 H7 NO
C5 H7 NO2
C5 H7 NS
C5 H7 NS
C5 H8
C5 H8
C5 H8
C5 H8
C5 H8
C5 H8
C5 H8
C5 H8
C5 H8
C5 H8
C5 H8
共296 –315兲
spiropentane
共276 –344兲
vinylcyclopropane
共289–310兲
cyclopentene
共249–318兲
共289–318兲
共230–293兲
methylenecyclobutane
共290–316兲
共292–306兲
3-methyl-1,2-butadiene
共227–253兲
共252–323兲
共213–242兲
共274 –319兲
2-methyl-1,3-butadiene
共221–254兲
共254 –316兲
共216 –235兲
共290–308兲
共258 –318兲
3-methyl-1-butyne
共218 –320兲
1,2-pentadiene
共231–249兲
共249–331兲
共213–245兲
共285–319兲
cis 1,3-pentadiene
共255–326兲
共230–255兲
共213–242兲
共289–318兲
trans 1,3-pentadiene
共228 –256兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
43.2
共298兲
44.8
共298兲
44.9
共298兲
37.4
共262兲
A
52.3
共308兲
A
66.9
共355兲
A
45.2
共357兲
A
42.0
共372兲
A
28.0⫾0.5
28.6
共298兲
共305兲
EB
A
28.6
28.3⫾0.1
27.5⫾0.1
26.7⫾0.1
共291兲
共283兲
共298兲
共312兲
A
C
C
C
28.9
共299兲
A
29.9
24.8
28.4
共264兲
共299兲
共300兲
A
MM
26.1
29.1
共303兲
共299兲
A
A
27.7⫾0.4
共298兲
EB
31.0
29.9
28.0
31.6
29.0
共240兲
共267兲
共298兲
共230兲
共291兲
A
A
29.4
28.3
26.4
31.5
27.3
27.4
共239兲
共269兲
共298兲
共225兲
共299兲
共288兲
30.2
25.8
共233兲
共298兲
A
31.6
30.6
28.7
32.2
29.1
共240兲
共264兲
共298兲
共231兲
共300兲
A
A
30.1
31.2
28.3
31.9
28.8
共270兲
共242兲
共298兲
共230兲
共304兲
IPM
MM
30.7
共242兲
A
Method
IPM
EB
A
A
IPM
MM
IPM
MM
A
A
CAS registry number
Reference
关69/14兴
关16529-66-1兴
关69/14兴
关26294-98-4兴
关69/14兴
关30574-97-1兴
关87/5兴关47/5兴
关927-56-0兴
关87/5兴
关105-56-6兴
关87/5兴关47/5兴
关3386-97-8兴
关87/5兴关99/16兴
关541-58-2兴
关87/5兴
关185-94-4兴
关98/17兴关96/18兴
关87/5兴
关157-40-4兴
关87/5兴关50/7兴
关50/7兴
关50/7兴
关50/7兴
关693-86-7兴
关87/5兴
关142-29-0兴
关87/5兴
关50/6兴
关41/6兴
关1120-56-5兴
关87/5兴
关87/5兴关78/5兴
关78/17兴
关74/3兴
关598-25-4兴
关87/5兴
关87/5兴
关71/28兴
关69/12兴
关69/12兴
关78-79-5兴
关87/5兴
关87/5兴
关71/28兴
关69/12兴
关50/6兴
关38/7兴
关598-23-2兴
关87/5兴
关71/28兴
关591-95-7兴
关87/5兴
关87/5兴
关71/28兴
关69/12兴
关50/6兴
关1574-41-0兴
关87/5兴
关87/5兴
关71/28兴
关69/12兴
关50/6兴
关2004-41-0兴
关87/5兴
ENTHALPIES OF VAPORIZATION
599
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共256 –324兲
C5 H8
C5 H8
C5 H8
C5 H8
C5 H8 Br2
C5 H8 Br4
C5 H8 ClFO2
C5 H8 ClF3 O
C5 H8 ClF3 O
C5 H8 Cl2 O
C5 H8 Cl4
C5 H8 F2 O3
C5 H8 N2
共213–242兲
共292–316兲
1,4-pentadiene
共216 –236兲
共236 –307兲
共213–230兲
共288 –300兲
共194 –255兲
2,3-pentadiene
共234 –258兲
共258 –330兲
共213–247兲
共298 –322兲
1-pentyne
共229–315兲
2-pentyne
共240–329兲
Mean temperature
(T m /K)
29.5
27.8
31.3
28.3
共271兲
共298兲
共230兲
共304兲
29.1
28.1
25.2
29.3
26.5
28.4
共226兲
共251兲
共298兲
共221兲
共293兲
共240兲
32.3
31.1
29.5
33.2
29.6
共246兲
共273兲
共298兲
共232兲
共310兲
31.8
28.4
共244兲
共298兲
A
33.1
30.8
共255兲
共298兲
A
共288兲
A
共452兲
A
共288兲
GS
关87/5兴关48/14兴
关72/20兴
共298兲
共313兲
共324兲
C
C
C
关84/2兴
关84/2兴
关84/2兴
共298兲
共313兲
共328兲
共343兲
共358兲
C
C
C
C
C
共298兲
C
共355兲
A
关84/7兴
关84/7兴
关84/7兴
关84/7兴
关84/7兴
关78-71-7兴
关71/25兴
关2467-10-9兴
关87/5兴
共288兲
GS
54.3
48.5
共375兲
共450兲
EB
EB
66.0⫾3.9
共298兲
C
53.3⫾2.4
共298兲
C
42.1⫾0.2
43.2⫾0.3
40.6
42.6
39.6
42.7⫾0.1
43.6
共298兲
共332兲
共308兲
共353兲
共298兲
共286兲
A
A, EB
C
36.8⫾0.4
共298兲
C
trans 1,2-dibromocyclopentane
共273–332兲
47.9
pentarythritol tetrabromide
共439– 466兲
61.0
3-chloro-4-fluorobutyric acid, methyl ester
共273–333兲
54.5
2-chloro-1,1,2-trifluoroethyl isopropyl ether
39.2
38.1
37.0
2-chloro-1,1,1-trifluoroethyl propyl ether
41.0
39.9
38.7
37.5
36.2
3,3-bis共chloromethyl兲oxetane
56.0⫾0.4
1,1,1,5-tetrachloropentane
共340– 432兲
61.7
bis共2-fluoroethyl兲carbonate
共273–333兲
61.5
C5 H8 N2
1,3-dimethyl-2-imidazolidinone
共355– 498兲
共355– 498兲
1-ethylimidazole
C5 H8 N2
1-ethylpyrazole
C5 H8 O
cyclopentanone
共317– 427兲
共293– 404兲
共338 – 416兲
C5 H8 O
⌬ vapH m
共kJ mol⫺1兲
共273–299兲
2-ethylacrolein
Method
A
IPM
MM
A
A
IPM
MM
A
A
IPM
MM
GC
CAS registry number
Reference
关87/5兴
关71/28兴
关69/12兴
关50/6兴
关591-93-5兴
关87/5兴
关87/5兴
关71/28兴
关69/12兴
关50/6兴
关40/3兴
关591-96-8兴
关87/5兴
关87/5兴
关71/28兴
关69/12兴
关50/6兴
关627-19-0兴
关87/5兴
关71/28兴
关627-21-4兴
关87/5兴
关71/28兴
关10230-26-9兴
关87/5兴关41/6兴
关3229-00-3兴
关87/5兴
关87/5兴关48/14兴
关72/20兴
关80-73-9兴
关87/2兴
关87/2兴
关7098-07-9兴
关99/1兴
关2817-71-2兴
关99/1兴
关120-93-2兴
关91/17兴
关89/16兴
关87/7兴
关87/5兴
关87/5兴关76/10兴
关68/17兴
关42/7兴
关922-63-4兴
关96/8兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
600
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H8 O
C5 H8 O
C5 H8 O
C5 H8 O
C5 H8 O
C5 H8 O
C5 H8 O2
C5 H8 O2
C5 H8 O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
37.6
39.4
39.4⫾0.1
共374兲
A
共298兲
C
32.2
共280兲
A
39.2
共263兲
A
26.2
共328兲
A
41.0
43.9
49.5
共353兲
共337兲
共309兲
A
A
36.7
共318兲
A
51.4
56.2
共362兲
共342兲
42.6⫾0.4
41.3⫾0.1
共298兲
39.2
35.2
42.7
41.8⫾0.2
43.2
39.4
共322兲
共393兲
共303兲
共298兲
共298兲
共347兲
EB
A, I, EB
A, EB
C
C
61.8
共376兲
A
52.1⫾0.4
共298兲
C
62.2
共335兲
A
48.8
共316兲
A
57.7
共378兲
A
41.4
共258兲
cyclopropyl methyl ketone
共361–387兲
dihydro-2H-pyran
共273–288兲
trans 2-methyl-2-butenal
共248 –390兲
3-methyl-3-buten-2-one
共313–371兲
2-methyl-3-butyn-2-ol
共333–377兲
共294 –380兲
共294 –380兲
1-penten-3-one
共303–376兲
glutaraldehyde
共347–382兲
共327– 436兲
methyl cyclopropanecarboxylate
共273–313兲
acetylacetone
共307– 414兲
共378 – 411兲
共288 –378兲
84% enol
100% enol
C5 H8 O2
C5 H8 O2
C5 H8 O2
C5 H8 O2
C5 H8 O2
C5 H8 O2
C5 H8 O2
共297–398兲
cis 2-methyl-2-butenoic acid
共361– 458兲
2-ethylpropenoic acid
2-ethylacrylic acid
共320– 453兲
4-oxovaleraldehyde 共levulinaldehyde兲
共301– 460兲
3-methylcrotonic acid
共363– 473兲
2-ethyl acrylate
共243–372兲
2-propenoic acid, ethyl ester
GS
C
39.2
C5 H8 O2
C5 H8 O2
C5 H8 O2
C5 H8 O2
C5 H8 O3
methyl methacrylate
共295–386兲
共295–386兲
共295–386兲
共293–373兲
共318 –348兲
共305–373兲
38.8⫾0.1
36.3⫾0.2
33.3⫾0.4
37.9
37.7
38.0
40.1
39.0
共312–362兲
trans 2-methyl-2-butenoic acid
共350– 453兲
61.2
tetrahydro-2H-pyran-2-one 共␦-valerolactone兲
共393– 428兲
52.4⫾0.2
共393– 428兲
60.2⫾1.3
58.0⫾0.4
共342– 433兲
48.6
(dl) ␥-valerolactone
54.8⫾0.4
共310– 480兲
53.5
4-oxopentanoic acid
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共300兲
共340兲
共380兲
共308兲
共333兲
共320兲
EB
EB
EB
A
共327兲
共365兲
A
共410兲
共298兲
共298兲
共387兲
EB
EB
C
共298兲
共325兲
C
A
CAS registry number
Reference
关765-43-5兴
关87/5兴
关84/17兴
关83/6兴
关25512-65-6兴
关87/5兴关72/20兴
关58/23兴
关497-03-0兴
关87/5兴关47/5兴
关814-78-8兴
关87/5兴关72/20兴
关115-19-5兴
关99/33兴
关87/5兴关72/20兴
关84/9兴关50/11兴
关1629-58-9兴
关87/5兴
关111-30-8兴
关98/15兴
关98/15兴
关2868-37-3兴
关98/22兴
关83/6兴
关123-54-6兴
关85/4兴
关87/5兴关72/38兴
关87/5兴
关70/9兴
关70/9兴
关69/31兴
关565-63-9兴
关87/5兴
关3586-58-1兴
关96/8兴
关3586-58-1兴
关87/5兴关47/5兴
关626-96-0兴
关87/5兴关47/5兴
关541-47-9兴
关87/5兴
关140-88-5兴
关47/5兴
关140-88-5兴
关75/39兴
关80-62-6兴
关02/16兴
关02/16兴
关02/16兴
关87/5兴
关84/31兴
关84/9兴
关75/39兴
关56/8兴
关80-59-1兴
关87/5兴
关542-28-9兴
关91/7兴
关91/7兴
关90/1兴
关30/6兴
关108-29-2兴
关90/1兴
关87/5兴关47/5兴
关123-76-2兴
ENTHALPIES OF VAPORIZATION
601
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H8 O3
C5 H8 O4
C5 H8 O4
C5 H8 O4
C5 H9 BrO
C5 H9 Cl
C5 H9 ClO2
C5 H9 ClO2
C5 H9 ClO2
C5 H9 ClS
C5 H9 Cl3 O
C5 H9 FOS
C5 H9 FO2
C5 H9 FO2
C5 H9 FO3
C5 H9 N
C5 H9 N
C5 H9 N
C5 H9 NO
C5 H9 NO
C5 H9 NO
C5 H9 NO
C5 H9 NO
Compound
共Temperature range/K兲
共375–519兲
methyl acetoacetate
共289– 446兲
dimethyl malonate
共351– 460兲
共351– 460兲
共351– 460兲
共278 –308兲
共374 – 620兲
共308 – 454兲
glutaric acid
共428 –576兲
diacetoxymethane
共334 – 443兲
3-bromo-2-pentanone
共273–333兲
cyclopentyl chloride
共322–387兲
isopropyl chloroacetate
共308 – 425兲
2-chloropropionic acid, ethyl ester
共279– 420兲
3-chloropropionic acid, ethyl ester
共316 –358兲
共2-chloroethyl兲 allyl sulfide
共293–333兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
74.4
共390兲
A
45.4
共304兲
A
52.9⫾0.2
49.5⫾0.2
46.1⫾0.3
61.8⫾0.8
50.0
53.7
共360兲
共400兲
共440兲
共293兲
共497兲
共323兲
EB
EB
EB
GS
EB, HG
A
98.1
共443兲
A
50.6
共349兲
A
45.2
共288兲
A
38.8⫾0.4
37.4
共298兲
共337兲
C
A, EB
44.3
共323兲
46.5
共294兲
A
56.0
共331兲
A
50.2
共308兲
A, GS
3-chloro-2,2-bis共chloromethyl兲-1-propanol
共404 – 450兲
79.6
4-fluorothiobutyric acid, methyl ester
共273–333兲
52.4
共419兲
A
共288兲
A, GS
4-fluorobutyric acid, methyl ester
共273–333兲
共288兲
A, GS
共288兲
A, GS
共288兲
GS
共318兲
共328兲
共298兲
BG
A, I
I
47.3
isopropyl fluoroacetate
共273–333兲
44.3
3-fluoro-2-hydroxybutryic acid, methyl ester
共273–333兲
62.3
pivalonitrile
共299–365兲
共313–371兲
共313–371兲
2-methylbutyronitrile
共274 –313兲
valeronitrile
共313– 418兲
N-methyl-2-pyrrolidone
共330–373兲
共340– 476兲
共340– 476兲
共333– 473兲
butyl isocyanate
共273–389兲
isobutyl isocyanate
共273–376兲
N-methyl methacrylamide
共355– 489兲
1-methyl-2-pyrrolidinone
共361– 477兲
共291–299兲
37.0
36.5
37.8
42.5⫾0.3
GS
42.3
44.3
共328兲
共298兲
A
53.1
53.4
47.7
49.3
共345兲
共350兲
共425兲
共403兲
GS
EB
EB
46.8
共288兲
A
44.2
共288兲
A
60.9
共370兲
A
49.2
55.3
共376兲
共295兲
A
A
CAS registry number
Reference
关87/5兴关47/5兴
关105-45-3兴
关87/5兴
关108-59-8兴
关02/20兴
关02/20兴
关02/20兴
关92/13兴
关88/3兴
关87/5兴
关110-94-1兴
关87/5兴关47/5兴
关628-51-3兴
关87/5兴
关815-48-5兴
关87/5兴关72/20兴
关930-28-9兴
关93/17兴
关87/5兴关70/7兴
关105-48-6兴
关28/2兴关84/9兴
关535-13-7兴
关87/5兴关47/5兴
关623-71-2兴
关87/5兴
关19155-35-2兴
关87/5兴关49/8兴
关72/20兴关99/16兴
关813-99-0兴
关87/5兴
关63732-24-1兴
关87/5兴关48/14兴
关72/20兴关99/16兴
关87/5兴关48/14兴
关72/20兴
关406-06-4兴
关87/5兴关48/14兴
关87/5兴关48/14兴
关72/20兴
关630-18-2兴
关71/2兴
关87/5兴关67/16兴
关67/16兴
关18936-17-9兴
关94/5兴
关110-59-8兴
关87/5兴
关69/14兴
关872-50-4兴
关96/12兴
关87/2兴
关87/2兴
关79/21兴
关111-36-4兴
关87/5兴
关1873-29-6兴
关87/5兴
关3887-02-3兴
关87/5兴
关872-50-4兴
关87/5兴关72/20兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
602
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H9 NO
Compound
共Temperature range/K兲
C5 H9 NO
cis 2-pentenoic acid amide
共343–384兲
␣-methoxyisobutyronitrile
共261–285兲
2-ethoxypropanenitrile
共348 – 445兲
2-piperidone
共293–312兲
2-ethyl-2-oxazoline
C5 H9 NO2
N-formylmorpholine
C5 H9 NO
C5 H9 NO
C5 H9 NO
C5 H9 N3 O7
C5 H9 N3 O9
C5 H9 N3 O9
C5 H10
C5 H10
C5 H10
C5 H10
C5 H10
C5 H10
C5 H10
C5 H10
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
74.8
共358兲
A
37.4⫾0.8
共298兲
GS
46.7
共363兲
A, EB
74.5
共302兲
A
44.2⫾0.4
共298兲
C
共416兲
共399兲
TGA
共301兲
A
共314兲
A
共303兲
A, GS
共298兲
EB
共295兲
共337兲
共396兲
共467兲
共298兲
共298兲
共310兲
共322兲
共323兲
共304兲
共298兲
A
A
A
A
56.9
共375– 423兲
52.7
2-ethoxy-1,1,1-trinitropropane
共293–310兲
57.7
2-hydroxymethyl-2-methyl-1,3-propanediol trinitrate
共299–345兲
88.1
1,2,5-pentanetriol trinitrate
共293–313兲
41.7⫾2.1
1,1-dimethylcyclopropane
25.1⫾0.8
cyclopentane
共280–331兲
29.2
共322–384兲
28.0
共381– 455兲
27.2
共452–511兲
27.5
28.5
28.5⫾0.1
27.9⫾0.1
27.3⫾0.1
27.4
共289–323兲
29.0
29.2
1-pentene
共218 –311兲
29.1
共286 –304兲
26.7
25.5
共273–334兲
26.9
26.2⫾0.1
25.5⫾0.1
25.2⫾0.1
cis 2-pentene
共234 –318兲
29.8
26.8
共274 –341兲
28.1
trans 2-pentene
共251–341兲
28.8
26.7
共274 –341兲
28.0
2-methyl-1-butene
共240–336兲
28.5
25.9
共274 –336兲
27.3
25.9⫾0.1
25.5⫾0.1
3-methyl-1-butene
共237–324兲
26.3
23.9
共273–324兲
25.4
2-methyl-2-butene
共271–343兲
28.4
27.1
共276 –344兲
28.3
27.5⫾0.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
C
C
MM
C
共233兲
共295兲
共298兲
共288兲
共284兲
共298兲
共303兲
A
MM
共249兲
共298兲
共289兲
A
共266兲
共298兲
共289兲
C
C
C
EB
A
EB
共255兲
共298兲
共289兲
共298兲
共304兲
A
共252兲
共298兲
共288兲
A
共286兲
共298兲
共291兲
共290兲
C
C
EB
A
C
CAS registry number
Reference
关15856-96-9兴
关87/5兴
关76474-09-4兴
关95/11兴
关14631-45-9兴
关87/5兴关76/12兴
关675-20-7兴
关87/5兴
关10431-98-8兴
关76/27兴
关4394-85-8兴
关89/7兴
关87/18兴
关26459-85-8兴
关87/5兴
关3032-55-1兴
关87/5兴
关98071-55-7兴
关87/5兴关57/5兴
关1630-94-0兴
关74/3兴
关287-92-3兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关71/28兴
关59/8兴
关59/8兴
关59/8兴
关46/11兴
关45/2兴
关43/4兴
关109-67-1兴
关87/5兴
关50/6兴
关71/28兴
关49/12兴
关49/12兴
关49/12兴
关49/12兴
关627-20-3兴
关87/5兴
关71/28兴
关50/8兴
关646-04-8兴
关87/5兴
关71/28兴
关50/8兴
关563-46-2兴
关87/5兴
关71/28兴
关49/12兴
关49/12兴
关49/12兴
关563-45-1兴
关87/5兴
关71/28兴
关50/8兴
关515-35-9兴
关87/5兴
关71/28兴
关49/12兴
关49/12兴
ENTHALPIES OF VAPORIZATION
603
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H10Br2
C5 H10Br2
C5 H10Br2
C5 H10Br2
C5 H10Cl2
C5 H10Cl2
C5 H10Cl2
C5 H10Cl2
C5 H10Cl2 O
C5 H10Cl2 O
C5 H10Cl2 O2
C5 H10F2
C5 H10F2
C5 H10F2
C5 H10F2 O2
C5 H10N2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
27.1⫾0.1
26.3⫾0.1
共298兲
共312兲
C
C
48.8
共375兲
A, EST
46.5
49.0
49.2⫾0.8
48.8
共363兲
共298兲
共298兲
共307兲
A
EB
A
51.8
共392兲
A
54.4
共411兲
A
44.3
42.0
共298兲
共340兲
A
A, EST
44.4
41.9
43.8⫾0.7
共298兲
共347兲
共298兲
A
EB
48.9
45.0
48.1⫾0.8
共298兲
共363兲
共298兲
A
EB
52.2
47.2
51.3⫾0.8
共2-chloroethyl兲 共2-chloroisopropyl兲 ether
共297– 453兲
49.7
共2-chloroethyl兲 共2-chloropropyl兲 ether
共302– 467兲
49.3
bis共2-chloroethoxy兲 methane
共326 – 488兲
54.2
1,1-difluoropentane
共268 –378兲
34.4
共298兲
共377兲
共298兲
A
EB
共312兲
A
共317兲
A
共341兲
A
共283兲
A, EST
33.7
共277兲
A
33.8
共277兲
A
52.3
共288兲
A, GS
共345兲
共346兲
A
A
Compound
共Temperature range/K兲
1,1-dibromopentane
共360–501兲
1,2-dibromopentane
共348 – 465兲
共350– 450兲
共292– 448兲
1,4-dibromopentane
共377–524兲
1,5-dibromopentane
共396 –549兲
1,1-dichloropentane
共340– 410兲
共325– 457兲
1,2-dichloropentane
共330– 420兲
共332– 418兲
1,4-dichloropentane
共350– 440兲
共348 – 443兲
1,5-dichloropentane
共360– 450兲
共362– 453兲
2,2-difluoropentane
共262–367兲
3,3-difluoropentane
共262–368兲
bis共2-fluoroethoxy兲 methane
共273–333兲
3-共dimethylamino兲propionitrile
共330– 445兲
共331– 407兲
共290–317兲
C5 H10N2 O
C5 H10N2 O6
C5 H10N2 O6
C5 H10N2 O6
C5 H10O
42.2⫾0.1
45.9
52.4
44.1⫾0.2
47.3
1-nitrosopiperidine
共333–383兲
1,5-pentanediol dinitrate
共293–313兲
47.7
共348兲
A
78.9⫾5.9
共303兲
A, GS
2,4-pentanediol dinitrate
共293–313兲
60.6⫾5.9
共303兲
A, GS
共308兲
A
共259兲
A
1-共methoxymethoxy兲-2,2-dinitropropane
共293–333兲
71.3
allyl ethyl ether
共244 – 401兲
34.6
CAS registry number
Reference
关49/12兴
关49/12兴
关13320-56-4兴
关87/5兴关56/16兴
关72/20兴
关3234-49-9兴
关87/5兴
关75/15兴关91/2兴
关75/15兴
关87/5兴关47/5兴
关626-87-9兴
关87/5兴关72/20兴
关111-24-0兴
关87/5兴关72/20兴
关820-55-3兴
关87/12兴关91/2兴
关87/5兴关56/16兴
关72/20兴
关1674-33-5兴
关91/2兴
关87/5兴
关75/16兴
关626-92-6兴
关91/2兴
关87/5兴
关75/16兴
关628-76-2兴
关91/2兴
关87/5兴
关75/16兴
关52250-75-6兴
关87/5兴关47/5兴
关42434-29-7兴
关87/5兴关47/5兴
关111-91-1兴
关87/5兴关47/5兴
关62127-40-6兴
关87/5兴关56/16兴
关72/20兴
关371-65-3兴
关87/5兴关72/20兴
关358-03-2兴
关87/5兴关72/20兴
关373-40-0兴
关87/5兴关48/14兴
关72/20兴
关1738-25-6兴
关92/20兴
关87/5兴
关87/5兴
关84/28兴
关77/29兴
关100-75-4兴
关87/5兴
关3457-92-9兴
关87/5兴关57/5兴
关72/20兴
关25385-63-1兴
关87/5兴关57/5兴
关72/20兴
关67727-92-8兴
关87/5兴
关557-31-3兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
604
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H10O
C5 H10O
C5 H10O
C5 H10O
C5 H10O
C5 H10O
C5 H10O
C5 H10O
C5 H10O
Compound
共Temperature range/K兲
3,3-dimethyl-2-propen-1-ol
共348 –372兲
2-methyl-3-buten-2-ol
共290–372兲
3-buten-3-methyl-1-ol
共338 – 409兲
(dl) 3-buten-3-methyl-2-ol
共358 –379兲
cyclopentanol
共323–373兲
共346 – 437兲
共283–321兲
共283–323兲
共279–314兲
tetrahydropyran
共335– 412兲
共273–362兲
共273–288兲
2-methyltetrahydrofuran
共283–353兲
3-methyl-2-butanone
共311–369兲
共363– 415兲
共405–500兲
2-pentanone
共336 – 422兲
共416 –501兲
共487–561兲
共268 –373兲
共329–385兲
C5 H10O
Mean temperature
(T m /K)
Method
CAS registry number
Reference
49.9⫾0.1
48.4⫾0.1
46.8⫾0.1
共313兲
共328兲
共343兲
C
C
C
关616-25-1兴
关96/9兴
关96/9兴
关96/9兴
48.7
共360兲
43.1⫾0.1
共331兲
55.6
共353兲
A
关89/8兴
关115-18-4兴
关88/4兴
关763-32-6兴
关87/5兴
41.0
共368兲
A
57.1
52.7
56.1
56.4
57.1
57.5⫾0.2
57.5⫾0.3
共298兲
共361兲
共298兲
共298兲
共294兲
共298兲
共298兲
CGC
A, EB
A
A
33.2
35.0
35.0
共350兲
共288兲
共281兲
34.0
33.7
共298兲
共298兲
A
35.5
33.8
32.6
36.8
35.0
36.9
35.0⫾0.1
33.8⫾0.1
32.3⫾0.1
共326兲
共378兲
共420兲
共298兲
共343兲
共298兲
共327兲
共346兲
共367兲
A
A
A
C
36.1
33.7
33.3
38.4
38.3⫾0.3
38.4
39.5
36.5
共351兲
共431兲
共502兲
共298兲
共298兲
共298兲
共283兲
共344兲
A
A
A
C
GCC
EB
A, GS, EB
36.1⫾0.1
34.4⫾0.1
33.4⫾0.1
32.8⫾0.1
32.2⫾0.1
共335兲
共360兲
共375兲
共386兲
共394兲
C
C
C
C
C
35.9⫾0.2
36.6
33.7
33.3
38.5
38.7⫾0.3
38.6
36.1⫾0.1
34.9⫾0.1
33.5⫾0.1
36.6
共332兲
共344兲
共436兲
共509兲
共298兲
共298兲
共298兲
共335兲
共354兲
共375兲
共344兲
1-penten-3-ol
共328 –377兲
C5 H10O
⌬ vapH m
共kJ mol⫺1兲
3-pentanone
共290–375兲
共329– 426兲
共421–502兲
共494 –561兲
共329–384兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
C
A
C
C
C
A
A
A
C
GCC
C
C
C
A, GS, EB
关87/5兴
关96-41-3兴
关95/21兴
关87/7兴
关87/5兴
关87/5兴
关75/1兴
关68/17兴
关66/2兴
关142-68-7兴
关00/12兴
关87/5兴
关72/20兴关58/23兴
关96-47-9兴
关87/5兴
关70/36兴
关563-80-4兴
关87/5兴
关87/5兴
关87/5兴
关83/3兴
关87/5兴关75/8兴
关75/8兴
关67/39兴
关67/39兴
关67/39兴
关107-87-9兴
关87/5兴
关87/5兴
关87/5兴
关83/3兴
关79/7兴
关75/8兴
关66/12兴
关87/5兴关75/8兴
关65/7兴关72/20兴
关61/17兴
关61/17兴
关61/17兴
关61/17兴
关61/17兴
关96-22-0兴
关88/4兴
关87/5兴
关87/5兴
关87/5兴
关83/3兴
关79/7兴
关75/8兴
关67/39兴
关67/39兴
关67/39兴
关87/5兴关75/8兴
ENTHALPIES OF VAPORIZATION
605
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H10O
Compound
共Temperature range/K兲
共283–323兲
pentanal
共313–353兲
共290–385兲
C5 H10O
共305–377兲
pivaldehyde
共308 –336兲
3,3-dimethyloxetane
C5 H10OS
S-propyl thiolacetate
C5 H10OS
S-isopropyl thiolacetate
C5 H10OS
1-共methylthio兲-2-共vinyloxy兲ethane
共316 –347兲
tetrahydrofurfuryl alcohol
共393– 453兲
共333– 443兲
2,2-dimethyl-1,3-dioxolane
共278 –318兲
4-methyl-1,3-dioxane
共273–313兲
1-methoxy-2-butanone
共297– 408兲
C5 H10O
C5 H10O2
C5 H10O2
C5 H10O2
C5 H10O2
C5 H10O2
C5 H10O2
C5 H10O2
C5 H10O2
C5 H10O2
3-hydroxy-3-methyl-2-butanone
共317– 419兲
4-hydroxy-3-methyl-2-butanone
共375–528兲
共317– 458兲
butyl formate
共295–380兲
sec butyl formate
共238 –367兲
ethyl propionate
共315– 420兲
共372–538兲
共306 –372兲
C5 H10O2
C5 H10O2
C5 H10O2
isobutyl formate
共371–507兲
共240–372兲
isopropyl acetate
共313–353兲
共235–362兲
共273–363兲
methyl butyrate
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
36.9
共303兲
38.3
U50.0
38.1⫾0.1
37.3
共298兲
共305兲
共298兲
共320兲
34.2
共322兲
33.9⫾0.3
共298兲
C
44.1⫾0.2
共298兲
C
42.3⫾0.2
共298兲
C
47.5
共331兲
A
46.2
46.5
共408兲
共388兲
A
Method
CGC
A
41.1⫾0.2
GS
43.7⫾0.3
GS
44.9
共312兲
A
41.1
共332兲
A
58.3
59.0
共390兲
共332兲
A
37.9
41.3⫾0.1
40.1⫾0.1
39.0⫾0.1
38.7⫾0.1
38.1⫾0.1
37.3⫾0.1
共310兲
共298兲
共313兲
共328兲
共346兲
共355兲
共363兲
A
C
C
C
C
C
C
37.7
共253兲
A
36.7
34.4
39.3⫾0.1
38.2⫾0.1
36.6⫾0.1
36.0⫾0.1
35.5⫾0.1
34.5⫾0.1
39.1⫾0.1
38.2
共330兲
共387兲
共298兲
共313兲
共336兲
共344兲
共351兲
共363兲
共298兲
共321兲
A
C
C
C
C
C
C
C
A
36.6
38.6
共386兲
共255兲
A
A
37.0
37.2⫾0.2
38.8
36.3
共298兲
共298兲
共250兲
共288兲
CGC
C
A
A
CAS registry number
Reference
关65/7兴关72/20兴
关37/9兴
关110-62-3兴
关95/21兴
关87/5兴
关81/18兴
关79/15兴
关630-19-3兴
关89/2兴
关6921-35-3兴
关71/25兴
关2307-10-0兴
关66/2兴
关926-73-8兴
关66/2兴
关6607-53-0兴
关87/5兴关99/16兴
关97-99-4兴
关87/5兴
关79/21兴
关2916-31-6兴
关98/21兴关02/32兴
关1120-97-4兴
关98/21兴关02/32兴
关50741-70-3兴
关87/5兴关34/3兴
关72/20兴
关115-22-0兴
关87/5兴关72/20兴
关50/11兴
关3393-64-4兴
关87/5兴关72/20兴
关47/5兴
关592-84-7兴
关87/5兴
关80/13兴
关80/13兴
关80/13兴
关76/14兴
关76/14兴
关76/14兴
关589-40-2兴
关87/5兴
关105-37-3兴
关97/11兴
关87/5兴
关80/13兴
关80/13兴
关77/12兴
关77/12兴
关77/12兴
关77/12兴
关72/3兴
关87/5兴关65/3兴
关72/20兴
关542-55-2兴
关87/5兴
关87/5兴关47/5兴
关108-21-4兴
关95/21兴
关66/2兴
关87/5兴关47/5兴
关29/5兴
关623-42-7兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
606
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共349–384兲
共375–545兲
C5 H10O2
C5 H10O2
共246 –375兲
methyl isobutyrate
共366 –533兲
共239–366兲
propyl acetate
共313–363兲
共333–372兲
共374 –542兲
共322–383兲
共312–374兲
C5 H10O2
C5 H10O2
C5 H10O2
monomer
C5 H10O3
C5 H10O3
C5 H10O3
C5 H10O3
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
36.9
41.1⫾0.2
40.6⫾0.2
36.4
39.0⫾0.4
34.2
39.8⫾0.3
39.3⫾0.2
42.8
共350兲
共284兲
共298兲
共364兲
共298兲
共390兲
共298兲
共298兲
共261兲
33.7
37.3
40.1
共381兲
共298兲
共254兲
A
37.7
37.0
34.8
38.1
39.8⫾0.1
38.6⫾0.1
35.3⫾0.1
36.9⫾0.1
36.4⫾0.1
35.8⫾0.1
34.8⫾0.1
36.9
33.9
39.1⫾0.2
38.2
共298兲
共348兲
共389兲
共327兲
共298兲
共313兲
共343兲
共336兲
共344兲
共351兲
共363兲
共335兲
共375兲
共298兲
共327兲
CGC
共320兲
共360兲
共400兲
共440兲
EB
EB
EB
EB
共298兲
共298兲
共388兲
共390兲
共298兲
GS
CGC
EB
A
TE
共308兲
共298兲
共379兲
共322兲
共298兲
共298兲
共375兲
GS
GS
A, EB
A
TE
C
trimethylacetic acid 共pivalic acid兲
共344 – 472兲
57.6⫾0.2
共344 – 472兲
54.4⫾0.2
共344 – 472兲
50.9⫾0.2
共344 – 472兲
47.0⫾0.4
valeric acid 共pentanoic acid兲
共283–313兲
63.0⫾9.5
共353–393兲
65.9
共373– 465兲
57.9
共375–523兲
58.0
共243–266兲
62.4⫾3
3-methylbutanoic acid 共isovaleric acid兲
共293–323兲
60.7⫾0.3
共293–323兲
61.2⫾0.3
共364 – 464兲
55.8
共307– 448兲
56.6
共243–259兲
57.5⫾3
46.9⫾0.2
共360–377兲
45.9
diethyl carbonate
共352– 403兲
39.7
共308 – 400兲
40.9
43.6⫾0.2
共308 –368兲
39.1
共263–399兲
44.3
ethylene glycol methyl ethyl acetate
50.3⫾0.1
共343– 417兲
44.3
(dl) ethyl lactate
共308 – 426兲
共324 – 427兲
3-hydroxypropionic acid, ethyl ester
共338 –356兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共367兲
共323兲
共298兲
Method
GC
A
GCC
C
A
A
DTA
C
C
C
C
C
C
C
C
A
A
C
MM
共278兲
共298兲
共358兲
C
A
49.2
51.3
共323兲
共339兲
A
A
62.2
共347兲
A
CAS registry number
Reference
关02/27兴
关02/27兴
关02/27兴
关90/10兴
关87/17兴
关87/5兴
关80/5兴
关79/1兴
关87/5兴关47/5兴
关547-63-7兴
关87/5兴
关U/1兴关85/6兴
关87/5兴关47/5兴
关109-60-4兴
关95/21兴
关93/8兴
关87/5兴
关80/8兴
关80/13兴
关80/13兴
关80/13兴
关77/12兴
关77/12兴
关77/12兴
关77/12兴
关76/8兴
关76/8兴
关66/2兴
关87/5兴关65/3兴
关72/20兴
关75-98-9兴
关02/16兴
关02/16兴
关02/16兴
关02/16兴
关109-52-4兴
关00/6兴
关95/21兴
关87/9兴
关87/5兴
关79/4兴
关503-74-2兴
关00/6兴
关00/6兴
关87/9兴
关87/5兴
关79/4兴
关70/8兴
关1894/1兴
关105-58-8兴
关02/31兴
关87/5兴
关73/3兴
关71/1兴
关47/5兴
关110-49-6兴
关70/17兴
关87/5兴关57/6兴
关72/20兴
关97-64-3兴
关87/5兴
关87/5兴
关623-72-3兴
关87/5兴
ENTHALPIES OF VAPORIZATION
607
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H10O3
C5 H10O3
C5 H10O4
C5 H10S
C5 H10S
C5 H10S
C5 H10S
C5 H10S
C5 H11Br
Compound
共Temperature range/K兲
3-methoxypropionic acid, methyl ester
共350– 438兲
43.4
1,3,6-trioxacyclooctane
48.8⫾0.2
glycerol, 1-monoacetate
共385– 458兲
74.0
allyl ethyl sulfide
共300–327兲
38.9
共300–327兲
cyclopentanethiol
共354 – 446兲
共348 – 446兲
2-methyltetrahydrothiophene
共303– 433兲
共335– 447兲
共341– 411兲
3-methyltetrahydrothiophene
共307– 439兲
共340– 453兲
共346 – 422兲
pentamethylene sulfide
共310– 443兲
共347– 423兲
1-bromopentane
共323–363兲
共293– 443兲
C5 H11Br
C5 H11Br
C5 H11Br
C5 H11Br
C5 H11Br
C5 H11Br
C5 H11Br
C5 H11Br
C5 H11Cl
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共370兲
A
共298兲
C
共400兲
A
共313兲
A, EB
39.3
共298兲
38.2
38.4
共369兲
共363兲
A, EB
37.9⫾0.1
36.7⫾0.1
35.3⫾0.1
共361兲
共381兲
共405兲
C
C
C
40.6
41.8
41.3⫾0.1
39.0
38.7
共318兲
共298兲
共298兲
共350兲
共356兲
41.3
42.7
42.1⫾0.1
39.6
39.3
共322兲
共298兲
共298兲
共355兲
共361兲
41.4
42.8
39.5
共325兲
共298兲
共362兲
A, EB
40.9
41.4⫾0.1
41.1⫾0.1
41.0
共298兲
共298兲
共298兲
共308兲
CGC
C
C
A, EST
共318兲
A
共298兲
CGC
共319兲
A
共308兲
A
共321兲
A
共321兲
共268兲
A
共310兲
A
共316兲
A
共298兲
共298兲
共313兲
共328兲
共343兲
共358兲
共363兲
CGC
C
C
C
C
C
C
(dl) sec-pentylbromide, 2-bromopentane
共303– 432兲
37.5
2-bromopentane
共323–363兲
38.5
3-bromopentane
共304 – 434兲
37.7
1-bromo-2,2-dimethylpropane
共293– 420兲
35.6
1-bromo-2-methylbutane
共306 – 436兲
37.9
1-bromo-3-methylbutane
共306 – 436兲
37.9
共253–393兲
41.0
2-bromo-2-methylbutane
共295– 422兲
36.4
2-bromo-3-methylbutane
共301– 430兲
37.2
1-chloropentane
共313–353兲
38.8
38.2
37.3
36.5
35.6
34.6
34.0
A, EB
A, EB
CAS registry number
Reference
关3852-09-3兴
关87/5兴
关1779-19-7兴
关82/9兴
关106-61-6兴
关87/5兴关72/20兴
关5296-62-8兴
关87/5兴关62/16兴
关99/16兴
关62/16兴
关1679-07-8兴
关99/16兴
关87/5兴关61/7兴
关66/5兴
关61/7兴
关61/7兴
关61/7兴
关1795-09-1兴
关99/16兴
关71/28兴
关72/11兴关66/5兴
关87/5兴关66/5兴
关52/9兴
关4740-00-5兴
关99/16兴
关71/28兴
关72/11兴关66/5兴
关87/5兴关66/5兴
关52/9兴
关1613-51-0兴
关99/16兴
关71/28兴
关87/5兴关52/9兴
关110-53-2兴
关95/21兴
关68/1兴
关66/2兴
关87/5兴关61/13兴
关72/20兴
关107-81-3兴
关87/5兴关72/20兴
关107-81-3兴
关95/21兴
关1809-10-5兴
关87/5兴关72/20兴
关630-17-1兴
关87/5兴关72/20兴
关10422-35-2兴
关87/5兴关72/20兴
关107-82-4兴
关87/5兴关72/20兴
关47/5兴
关507-36-8兴
关87/5兴关72/20兴
关18295-25-5兴
关87/5兴关72/20兴
关543-59-9兴
关95/21兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
608
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共277– 421兲
C5 H11Cl
C5 H11Cl
C5 H11Cl
C5 H11Cl
C5 H11Cl
C5 H11Cl
C5 H11Cl
C5 H11ClO2 S
C5 H11Cl2 N
C5 H11F
C5 H11F
C5 H11F
C5 H11I
共283–323兲
2-chloropentane
共289– 409兲
3-chloropentane
共289– 410兲
1-chloro-2,2-dimethylpropane
共279–395兲
(dl) 1-chloro-2-methylbutane
共300–374兲
2-chloro-2-methylbutane
共280–396兲
2-chloro-3-methylbutane
共285– 405兲
1-chloro-3-methylbutane
共313–353兲
1-pentanesulfonyl chloride
共293–387兲
共387– 492兲
共263–293兲
N-methyl-bis共2-chloroethyl兲amine
共273–333兲
1-fluoropentane
共245–373兲
1-fluoro-2-methylbutane
共287–329兲
2-fluoro-2-methylbutane
共249–341兲
1-iodopentane
共313–353兲
共312– 473兲
C5 H11I
C5 H11I
C5 H11I
C5 H11N
C5 H11N
C5 H11N
1-iodo-2-methylbutane
共339– 406兲
1-iodo-3-methylbutane
共313–353兲
共270– 422兲
2-iodo-2-methylbutane
共308 –398兲
cyclopentylamine
共317– 419兲
共317– 419兲
1-methylpyrrolidine
共270–298兲
共270–298兲
共273–315兲
piperidine
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
38.2⫾0.1
38.7
共298兲
共292兲
C
A, EST
36.2
共303兲
36.0
35.2
34.4
33.5
31.9
36.2
共298兲
共313兲
共328兲
共358兲
共368兲
共304兲
C
C
C
C
C
A
36.5
共304兲
A
34.9
共294兲
A
35.4
共315兲
A
35.0
共295兲
A
35.9
共300兲
A
38.1
36.2
35.4
34.6
33.7
32.8
32.3
共298兲
共298兲
共313兲
共328兲
共343兲
共358兲
共368兲
CGC
C
C
C
C
C
C
58.5
55.1
60.5
共308兲
共402兲
共278兲
A
54.6
共288兲
A
33.7
共260兲
EST
30.7
共302兲
A
31.8
共264兲
A
44.4
45.3⫾0.1
43.1
共298兲
共298兲
共327兲
CGC
C
A, EST
39.8
共354兲
A
42.2
43.5
共298兲
共285兲
CGC
A
40.4
共323兲
A
38.3
40.2⫾0.4
共332兲
共298兲
EB
EB
35.0⫾0.7
34.2⫾0.7
33.7
共284兲
共298兲
共288兲
GS
GS
A
36.6
35.3
共338兲
共357兲
CAS registry number
Reference
关68/1兴
关87/5兴关61/13兴
关72/20兴
关37/9兴
关625-29-6兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关87/5兴关72/20兴
关616-20-6兴
关87/5兴关72/20兴
关753-89-9兴
关87/5兴关72/20兴
关616-13-7兴
关87/5兴关72/20兴
关594-36-5兴
关87/5兴关72/20兴
关631-65-2兴
关87/5兴关72/20兴
关107-84-6兴
关95/21兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关6303-18-0兴
关99/16兴
关99/16兴
关87/5兴关99/16兴
关51-75-2兴
关87/5兴
关592-50-7兴
关87/5兴关61/13兴
关72/20兴
关10086-64-3兴
关87/5兴关72/20兴
关661-53-0兴
关87/5兴关72/20兴
关628-17-1兴
关95/21兴
关68/1兴
关87/5兴关61/13兴
关72/20兴
关616-14-8兴
关87/5兴关72/20兴
关541-28-6兴
关95/21兴
关87/5兴关47/5兴
关594-38-7兴
关87/5兴关72/20兴
关1003-03-8兴
关87/5兴关75/5兴
关75/7兴
关120-94-5兴
关98/12兴
关98/12兴
关87/5兴
关110-89-4兴
关88/7兴
关88/7兴
ENTHALPIES OF VAPORIZATION
609
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C5 H11NO
共315– 417兲
N,N-diethylformamide
C5 H11NO
共303–363兲
N-isopropylacetamide
C5 H11NO
N-propylacetamide
C5 H11NO
N,N-dimethylpropionamide
共326 – 424兲
C5 H11NO
C5 H11NO
C5 H11NO
C5 H11NO
C5 H11NO2
C5 H11NO2
C5 H11NO2
C5 H11NO2
C5 H11NO3
C5 H11P
C5 H12
C5 DH11
C5 DH11
C5 D12
C5 H12
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
37.6
共330兲
A, EB, IPM
50.3
48.9
共298兲
共318兲
A
66.4⫾0.3
共298兲
C
69.8⫾0.2
共298兲
C
53.5
52.9
共341兲
A
共298兲
C
共288兲
共298兲
共343兲
共312兲
共291兲
GS
GS
TGA
A
A
共298兲
GS
共333兲
A
共293兲
GS
共298兲
GS
共371兲
A
共366兲
A
共293兲
A
共309兲
A, T
CAS registry number
Reference
关87/5兴关68/4兴
关617-84-5兴
关85/7兴关85/6兴
关87/5兴关68/3兴
关1118-69-0兴
关84/6兴
关5331-48-6兴
关84/6兴
关758-96-3兴
关87/5兴
关77/29兴
N-methyl-2-methylpropionamide
67.1⫾0.2
N-methylmorpholine
共274 –304兲
40.2⫾0.3
共274 –304兲
39.6⫾0.3
共323–363兲
33.6
共297–389兲
38.4
共276 –390兲
40.0
1-共dimethylamino兲-2-propanone
共298 –338兲
43.6⫾0.3
3-pentanone oxime
共318 – 425兲
55.8
methyl 2-共N,N-dimethylamino兲ethanoate
共278 –308兲
43.9⫾0.4
1-nitropentane
共278 –318兲
50.3⫾0.2
isobutyl carbamate
共356 – 479兲
58.8
N,N-dimethyl lactamide
共351– 417兲
73.7
isopentyl nitrate
共278 – 421兲
47.0
phosphorinane
共294 –345兲
39.9
pentane
共308 – 423兲
26.7
26.4
共223–352兲
29.8
共143–223兲
32.3
共350– 422兲
26.1
共418 – 470兲
26.2
26.6⫾0.1
26.4
25.5
23.0
19.7
15.1
8.5
共216 –296兲
26.2
共269–341兲
27.9
26.4
26.4
共286 –310兲
27.4
26.2
1-deuteropentane
共223–303兲
26.2
3-deuteropentane
共213–294兲
26.3
pentane—d12
共205–298兲
26.0
2,2-dimethylpropane 共neopentane兲
共268 –313兲
24.0
共312–385兲
23.1
共323兲
共298兲
共238兲
共208兲
共365兲
共433兲
共298兲
共298兲
共310兲
共350兲
共390兲
共430兲
共460兲
共298兲
共284兲
共298兲
共298兲
共298兲
共298兲
A
A
A
A
C
C
EB
C
MM
关84/6兴
关109-02-4兴
关98/13兴
关98/13兴
关87/18兴
关87/5兴
关87/5兴
关15364-56-4兴
关94/3兴
关1188-11-0兴
关87/5兴
关92/13兴
关628-05-7兴
关97/5兴
关543-28-2兴
关87/5兴关47/5兴
关31502-31-5兴
关87/5兴
关543-87-3兴
关87/5兴关47/5兴
关4743-40-2兴
关87/5兴关66/9兴
关109-66-0兴
关02/34兴
关94/12兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关82/6兴
关81/9兴
关77/31兴
关77/31兴
关77/31兴
关77/31兴
关77/31兴
关75/32兴
关87/5兴关74/11兴
关71/28兴
关47/7兴
关45/2兴
关40/15兴
共298兲
关75/32兴
共298兲
关75/32兴
关2031-90-5兴
关75/32兴
关463-82-1兴
关87/5兴
关87/5兴
共298兲
共283兲
共327兲
A
A
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
610
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共382– 433兲
共257–293兲
共343– 433兲
C5 H12
C5 H12ClF3 N2 S
C5 H12ClF3 N2 OS
C5 H12NO3 PS2
C5 H12N2
C5 H12N2
C5 H12N2 O
C5 H12N2 S
C5 H12O
C5 H12O
C5 H12O
C5 H12O
2-methylbutane 共isopentane兲
共255–323兲
共216 –323兲
共300– 460兲
共320–391兲
共385– 416兲
共412– 460兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
23.1
21.8
22.2
19.5
16.2
11.1
24.3
22.8
21.85
22.8⫾0.1
共397兲
共298兲
共290兲
共330兲
共370兲
共410兲
共272兲
共358兲
共298兲
共283兲
26.9
共270兲
28.5
共231兲
25.2
共315兲
25.2
共335兲
24.8
共400兲
25.3
共427兲
24.4
共310兲
21.5
共350兲
18.0
共390兲
12.9
共430兲
24.8
共298兲
共190–300兲
30.2
共205兲
共289–301兲
26.2
共295兲
25.0
共298兲
chlorobis共N-methylmethanaminato兲共trifluoromethyl兲 sulfur
38.1
共368兲
chlorobis共N-methylmethanaminato兲oxo共trifluoromethyl兲 sulfur
40.2
共477兲
phosphorodithioic acid, O,O-dimethyl-S-关2-共methylamino兲-2-oxoethyl兴 ester
共283–390兲
95.0
共298兲
methyl butyldiazene
36.4⫾0.2
共298兲
N-methylpiperazine
共274 –319兲
46.7
共289兲
1,1,3,3-tetramethylurea
共320– 450兲
41.7
共450兲
共320– 450兲
52.2
共325兲
1,3-diethylthiourea
共351–384兲
101⫾3.0
共368兲
1-methoxybutane
共293–367兲
32.5
共308兲
32.4
共398兲
共265–367兲
32.4
共298兲
共265–367兲
29.6
共343兲
32.5⫾0.1
共298兲
共296 –342兲
32.4
共311兲
1-ethoxypropane
共264 –359兲
33.0
共279兲
31.4
共298兲
共264 –359兲
31.4
共298兲
共264 –359兲
29.0
共336兲
31.4⫾0.1
共298兲
共293–335兲
31.6
共308兲
ethyl isopropyl ether
30.0
共298兲
methyl tert-butyl ether
共300–328兲
29.9
共314兲
共315–365兲
29.6
共330兲
共300– 411兲
31.2
共315兲
共287–326兲
30.4
共302兲
29.8
共298兲
共287–351兲
30.2
共302兲
29.6
共298兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
C
A
A
A
A
A
MM
C
I
I
A
C
A
A, EB
A, EB
ME, TE
A
C
C
EB
A
C
C
C
EB
C
A
CAS registry number
Reference
关87/5兴
关81/9兴
关77/32兴
关77/32兴
关77/32兴
关77/32兴
关75/26兴关84/9兴
关73/28兴关84/9兴
关71/28兴
关36/8兴
关78-78-4兴
关91/15兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关77/33兴
关77/33兴
关77/33兴
关77/33兴
关71/28兴
关47/5兴
关45/2兴
关42/5兴
关63265-71-4兴
关77/15兴
关63265-73-6兴
关77/15兴
关60-51-5兴
关87/5兴
关4426-46-4兴
关78/3兴
关109-01-3兴
关87/5兴
关632-22-4兴
关87/2兴
关87/2兴
关105-55-5兴
关94/21兴
关628-28-4兴
关87/5兴
关80/3兴
关76/2兴
关76/2兴
关75/3兴
关69/15兴
关628-32-0兴
关87/5兴关76/2兴
关80/3兴
关76/2兴
关76/2兴
关75/3兴
关69/15兴
关625-54-7兴
关80/3兴
关1634-04-4兴
关02/26兴
关98/9兴
关94/10兴
关91/3兴
关80/3兴
关87/5兴关76/2兴
关76/2兴
ENTHALPIES OF VAPORIZATION
611
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H12O
Compound
共Temperature range/K兲
共343–303兲
共310– 411兲
共347– 429兲
共307– 411兲
2-pentanol
共323–373兲
共274 –393兲
共322–393兲
共298 –393兲
C5 H12O
C5 H12O
C5 H12O
Mean temperature
(T m /K)
Method
27.9
30.4⫾0.1
共328兲
共298兲
C
44.4
40.1
36.1
31.7
26.4
22.0
14.1
7.1
43.5
57.8
57.4
51.5
47.2
54.3
45.4
55.7⫾0.2
54.4⫾0.2
53.0⫾0.2
51.2⫾0.2
55.4
55.0
50.5⫾0.1
49.2⫾0.1
47.0⫾0.1
44.4⫾0.1
51.6
56.2
56.9⫾0.2
共411兲
共448兲
共473兲
共498兲
共523兲
共548兲
共573兲
共586兲
共298兲
共298兲
共350兲
共403兲
共341兲
共423兲
共313兲
共328兲
共343兲
共358兲
共298兲
共325兲
共362兲
共374兲
共392兲
共411兲
共362兲
共322兲
共298兲
CGC
CGC
53.6
58.9
54.2⫾0.2
52.7⫾0.2
50.9⫾0.2
49.0⫾0.2
46.9⫾0.1
45.4⫾0.1
50.3
54.0
53.0
53.7
共298兲
共289兲
共298兲
共313兲
共328兲
共343兲
共358兲
共368兲
共337兲
共313兲
共298兲
共313兲
CGC
A
C
C
C
C
C
C
59.9
49.6
53.6
50.2
52.9
共260兲
共332兲
共294兲
共319兲
共298兲
A
51.2
49.8
53.9
58.5
56.1
54.1
43.4
56.7
共345兲
共353兲
共332兲
共264兲
共322兲
共298兲
共317兲
共313兲
51.5⫾0.3
50.5
47.3
49.0
共298兲
共298兲
共323兲
共295兲
1-pentanol
共323–373兲
共323–373兲
共335– 410兲
共388 – 420兲
共326 – 411兲
共408 – 441兲
C5 H12O
⌬ vapH m
共kJ mol⫺1兲
共298 –383兲
3-pentanol
共245–390兲
共317–389兲
共279–318兲
共294 –389兲
2-methyl-1-butanol
共330– 405兲
共338 – 402兲
共317– 403兲
共249–319兲
共307– 403兲
共302– 410兲
共298 –393兲
2-methyl-2-butanol
共274 –306兲
共323–373兲
共308 –375兲
共280–375兲
A
A
A
C
C
C
C
C
C
C
C
EB
DTA
C
C
C
A
A
A
C
GS
CGC
A
CAS registry number
Reference
关76/2兴
关75/3兴
关71-41-0兴
关00/26兴
关00/26兴
关00/26兴
关00/26兴
关00/26兴
关00/26兴
关00/26兴
关00/26兴
关99/32兴
关95/21兴
关95/21兴
关94/7兴
关87/5兴
关87/5兴
关87/5兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关83/14兴
关73/26兴
关70/20兴
关70/20兴
关70/20兴
关70/20兴
关87/5兴关70/2兴
关69/5兴
关66/2兴
关6032-29-7兴
关95/21兴
关87/5兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关84/10兴
关73/26兴
关63/2兴
关35/6兴关84/9兴
关584-02-1兴
关87/5兴
关84/10兴
关75/1兴
关73/26兴
关63/2兴
关137-32-6兴
关94/7兴
关87/5兴
关87/5兴
关87/5兴关79/16兴
关73/26兴
关63/2兴
关57/13兴关84/9兴
关84/9兴关35/6兴
关75-85-4兴
关01/7兴
关95/21兴
关94/7兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
612
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共323–376兲
共298 –375兲
C5 H12O
共298 –364兲
3-methyl-1-butanol
共323–373兲
共325–385兲
共303– 412兲
共298 – 426兲
C5 H12O
C5 H12O
C5 H12O
C5 H12O2
C5 H12O2
C5 H12O2
3-methyl-2-butanol
共280–301兲
共280–375兲
共298 –384兲
(dl) 3-methyl-2-butanol
共293–385兲
2,2-dimethyl-1-propanol
共274 –312兲
共330–387兲
1-ethoxy-2-methoxyethane
2,2-dimethoxypropane
共272–301兲
共272–301兲
共299–348兲
共292–357兲
2-isopropoxyethanol
共341– 413兲
C5 H12O2
C5 H12O2
C5 H12O2
C5 H12O2
C5 H12O2
C5 H12O3
C5 H12O3
C5 H12O3
Mean temperature
(T m /K)
45.8
50.1⫾0.2
48.4⫾0.2
46.4⫾0.2
44.2⫾0.1
42.0⫾0.1
40.3⫾0.1
52.8
49.2
48.5
共338兲
共298兲
共313兲
共328兲
共343兲
共358兲
共368兲
共313兲
共298兲
共313兲
A
C
C
C
C
C
C
55.3
47.2
57.1
55.2⫾0.2
54.2⫾0.2
52.9⫾0.2
51.4⫾0.2
49.7⫾0.2
56.5
54.3
共298兲
共340兲
共318兲
共303兲
共313兲
共328兲
共343兲
共358兲
共313兲
共298兲
CGC
51.6⫾0.3
49.0
52.7
51.7
共298兲
共295兲
共313兲
共298兲
GS
A
46.4
共308兲
A
51.8⫾0.3
47.5
共298兲
共345兲
GS,B
A
39.8⫾0.1
共298兲
C
37.6⫾0.4
38.2⫾0.4
35.3
33.4⫾0.2
共298兲
共324兲
共325兲
GS
GS
EB
50.1⫾0.1
45.1
共298兲
共356兲
C
A
52.1⫾0.1
46.3
共298兲
共365兲
C
A
共288兲
共298兲
A
C
共414兲
A
共361兲
A
共415兲
A
共298兲
共406兲
C
A
共400兲
A
Method
C
C
C
C
C
C
C
C
2-propoxyethanol
共350– 422兲
C5 H12O2
⌬ vapH m
共kJ mol⫺1兲
formaldehyde diethyl acetal 共diethoxymethane兲
共273–361兲
36.1
35.7⫾0.2
2-methyl-1,3-butanediol
共399–561兲
62.4
3-methyl-1,3-butanediol
共346 – 475兲
60.3
2,2-dimethyl-1,3-propanediol
共400– 480兲
79.4
1,5-pentanediol
86.8⫾0.5
共391– 479兲
78.6
tert-butyldioxymethanol
59.6⫾2.4
diethylene glycol, methyl ether
共385– 466兲
51.9
2,3,4-pentanetriol
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关87/5兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关73/26兴
关63/2兴
关35/6兴
关123-51-3兴
关95/21兴
关94/7兴
关87/5兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关73/26兴
关63/2兴
关598-75-4兴
关01/7兴
关87/5兴
关73/26兴
关63/2兴
关598-75-4兴
关87/5兴
关75-84-3兴
关01/7兴
关87/5兴
关5137-45-1兴
关70/17兴
关77-76-9兴
关02/32兴
关98/21兴
关94/16兴
关88/4兴
关109-59-1兴
关71/7兴
关87/5兴关57/6兴
关72/20兴
关2807-30-9兴
关71/5兴
关87/5兴关57/6兴
关72/20兴
关462-95-3兴
关87/5兴
关69/18兴
关684-84-4兴
关87/5兴
关2568-33-4兴
关87/5兴
关126-30-7兴
关87/5兴
关111-29-5兴
关88/14兴
关87/5兴
关17742-78-8兴
关83/11兴
关111-77-3兴
关87/5兴关57/6兴
关72/20兴
ENTHALPIES OF VAPORIZATION
613
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C5 H12O4
C5 H12O5
C5 H12O5
C5 H12O5
C5 H12S
C5 H12S
C5 H12S
Compound
共Temperature range/K兲
共428 – 600兲
tetramethoxymethane
共304 –387兲
adonitol
共418 – 465兲
D-arabinitol
共414 – 461兲
xylitol
共406 – 460兲
3-methyl-2-thiapentane
共288 – 418兲
4-methyl-2-thiapentane
共288 – 411兲
butyl methyl sulfide
共297– 423兲
共301–330兲
共296 –325兲
共343– 436兲
C5 H12S
methyl tert-butyl sulfide
共276 –397兲
共305– 411兲
C5 H12S
C5 H12S
C5 H12S
ethyl isopropyl sulfide
共284 – 406兲
共296 –325兲
共319–391兲
ethyl propyl sulfide
共293– 418兲
共331–398兲
1-pentanethiol
共300– 426兲
共347– 440兲
C5 H12S
C5 H12S
C5 H12S
C5 H12S
C5 H12S
2-pentanethiol
共287– 412兲
共347– 435兲
3-pentanethiol
共288 – 413兲
2-methyl-1-butanethiol
共293– 418兲
共324 – 432兲
3-methyl-1-butanethiol
共292– 418兲
共323– 431兲
2-methyl-2-butanethiol
共276 –398兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
78.9
共443兲
41.2
共319兲
111.1⫾1.5
Method
CAS registry number
Reference
共443兲
TE
关47/5兴
关1850-14-2兴
关80/15兴
关488-81-3兴
关90/16兴
110.1⫾1.5
共440兲
TE
111.1⫾0.8
共433兲
TE
38.5
共303兲
36.9
共303兲
40.4
35.3
40.5
41.0
40.9⫾0.8
38.1
38.0
共312兲
共315兲
共298兲
共298兲
共298兲
共313兲
共358兲
GC
EB
A, EB
36.5
35.9
35.1
共291兲
共298兲
共320兲
A, EB
38.1
37.8
38.5
37.9⫾0.8
38.1
36.3
共299兲
共298兲
共298兲
共298兲
共313兲
共334兲
GC
EB
A, EB
39.8
40.0
39.5
37.8
共308兲
共298兲
共298兲
共346兲
C
A, EB
40.6
41.1
37.1⫾0.1
36.4⫾0.1
34.9⫾0.1
38.1
共315兲
共298兲
共356兲
共376兲
共400兲
共362兲
C
C
C
A, EB
38.4
37.8
共302兲
共361兲
A
38.3
共303兲
39.2
39.9⫾0.1
39.7
37.6
共308兲
共298兲
共298兲
共339兲
A, EB
39.3
39.7
39.9⫾0.1
37.7
共307兲
共298兲
共298兲
共338兲
A, EB
36.3
共291兲
A
关90/16兴
关87-99-0兴
关90/16兴
关10359-64-5兴
关99/16兴
关5008-69-5兴
关99/16兴
关628-29-5兴
关99/16兴
关87/5兴
关81/12兴
关71/28兴
关64/7兴
关62/17兴
关87/5兴关61/8兴
关66/5兴
关6163-64-0兴
关99/16兴
关71/28兴
关87/5兴关62/9兴
关66/5兴
关5145-99-3兴
关99/16兴
关81/12兴
关71/28兴
关64/17兴
关62/17兴
关87/5兴关52/9兴
关4110-50-3兴
关99/16兴
关81/12兴
关81/8兴
关87/5兴关52/9兴
关110-66-7兴
关99/16兴
关71/28兴
关65/14兴
关65/14兴
关65/14兴
关87/5兴关52/11兴
关66/5兴
关2084-19-7兴
关99/16兴
关87/5兴
关616-31-9兴
关99/16兴
关1878-18-8兴
关99/16兴
关72/11兴关66/5兴
关71/28兴
关87/5兴关66/5兴
关541-31-1兴
关99/16兴
关71/28兴
关72/11兴关66/5兴
关87/5兴关66/5兴
关1679-09-0兴
关99/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
614
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共320– 411兲
C5 H12S
C5 H12S
C5 H12S2
C5 H12S2
C5 H12S2
C5 H13N
C5 H13N
C5 H13N
C5 H13N
C5 H13N
C5 H13NO2
C5 H13NO2 S
C5 H13NS
C5 H13N3
3-methyl-2-butanethiol
共285– 409兲
共315– 422兲
2,2-dimethyl-1-propanethiol
共280– 403兲
共292– 416兲
共213– 415兲
1,5-pentanedithiol
共363– 491兲
ethyl isopropyl disulfide
共369– 426兲
共363– 427兲
ethyl propyl disulfide
共373– 414兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
35.6
34.3
33.8⫾0.1
32.7⫾0.1
31.4⫾0.1
共298兲
共335兲
共330兲
共350兲
共372兲
A, EB
C
C
C
37.7
37.5⫾0.1
37.7
36.2
共300兲
共298兲
共298兲
共330兲
A, EB
36.9
36.4⫾0.1
36.8
36.2
42.1
共295兲
共298兲
共298兲
共307兲
共230兲
A, EB
EB, IPM
51.6
59.3
共378兲
共298兲
42.5
42.9
共384兲
共378兲
A, EB
44.0
共388兲
A, EB
33.1⫾0.1
32.1⫾0.1
31.0⫾0.1
28.8⫾0.1
33.4
共298兲
共313兲
共328兲
共358兲
共318兲
C
C
C
C
EB
31.8
共298兲
A
38.1
共298兲
A
32.3⫾1.4
共297兲
39.0
40.1⫾0.1
共313兲
共298兲
A
C
73.0
共405兲
A
52.1
共399兲
A
41.9
共364兲
A
N-ethylisopropylamine
共303–342兲
N,N-diethylmethylamine
共283–339兲
N-methylbutylamine
共283–313兲
tert-butylmethylamine
共270–288兲
pentylamine
共298 – 417兲
methyl diethanolamine
共390–520兲
N,N-diethyl methanesulfonamide
共384 –528兲
N-methyl-tert-butylsulfenamide
共329–397兲
1,1,3,3-tetramethylguanidine
46.9
C5 H13O3 P
diethyl methylphosphonate
共343– 402兲
C5 H14NP
trimethylphosphine-N-ethylimine
C5 H14N2
N,N-dimethyl-1,3-propanediamine
共303–366兲
共303– 408兲
51.8
56.5⫾4.2
共358兲
A
61.5⫾4.2
C5 H14N2
C6 BrF5
C6BrF15N2S
45.7
42.0
52.7
共318兲
共318兲
bis共dimethylamino兲methane
共273–348兲
32.3
共310兲
bromopentafluorobenzene
共400-522兲
38.2
共415兲
共414-522兲
38.0
共429兲
bis关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴diimidosulfuryl bromide fluoride
41.0
共476兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
A
EB
I
CAS registry number
Reference
关71/28兴
关87/5兴关62/10兴
关62/10兴
关62/10兴
关62/10兴
关2084-18-6兴
关99/16兴
关72/11兴关66/5兴
关71/28兴
关87/5兴关66/5兴
关1679-08-9兴
关99/16兴
关72/11兴关66/5兴
关71/28兴
关87/5兴关66/5兴
关66/5兴
关928-98-3兴
关87/5兴关99/16兴
关62/11兴
关53966-36-2兴
关99/16兴
关87/5兴关52/9兴
关30453-31-7兴
关87/5兴关52/9兴
关99/16兴
关19961-27-4兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关616-39-7兴
关87/5兴
关110-68-9兴
关87/5兴
关14610-37-8兴
关97/21兴
关110-58-7兴
关87/5兴关72/20兴
关69/2兴
关105-59-9兴
关87/5兴
关2374-61-0兴
关87/5兴
关99/16兴
关80-70-6兴
关67/29兴
关683-08-9兴
关87/5兴关72/20兴
关56/23兴关82/15兴
关60/23兴关82/15兴
关111-33-1兴
关87/5兴
关87/5兴
关77/29兴
关51-80-9兴
关65/29兴
关344-04-7兴
关87/5兴关72/20兴
关69/11兴
关62977-74-6兴
关77/15兴
ENTHALPIES OF VAPORIZATION
615
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6ClF15N2S
C6ClF5
C6ClF13N2
C6ClF14P
C6Cl2F12N2S
C6Cl3F3
C6Cl3F14P
C6Cl3N3O6
C6Cl4O2
C6Cl6
C6F6
C6F7NOS
C6F7OP
C6F7O2P
C6F8
C6F11NO
C6F11NO2S
C6F12
C6F12
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
bis关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴diimidosulfuryl chloride fluoride
37.2
共458兲
I
chloropentafluorobenzene
共290-550兲
41.3
共298兲
共348-402兲
37.7
共363兲
A
共307-417兲
40.0
共322兲
37.7⫾0.1
共349兲
36.4⫾0.1
共369兲
34.8⫾0.1
共391兲
共403-547兲
35.2
共418兲
EB
1-chloro-1’,2,2,2,2’,2’,2-heptafluoro-1,1’-bis共trifluoromethyl兲-azoethane
共297-355兲
33.3
共312兲
A
bis共heptafluoropropyl兲 chlorophosphine
共283-373兲
37.5
共328兲
bis共2-chlorohexafluoroisopropylimino兲 sulfur
43.5
共404兲
I
1,3,5-trichloro-2,4,6-trifluorobenzene
共364-496兲
49.2
共379兲
A
共364-550兲
53.8
共298兲
trichloro bis共heptafluoropropyl兲phosphorane
共323-393兲
40.1
共358兲
1,3,5-trichloro-2,4,6-trinitrobenzene
共503-543兲
68.9
共518兲
A
共503-543兲
43.2
共518兲
2,3,5,6-tetrachloro-1,4-benzoquinone 共chloranil兲
共343-435兲
88.5
共358兲
hexachlorobenzene
74.4⫾0.7
共298兲
GS
共413-453兲
76.8
共298兲
GC
共258-313兲
81.3
GC
共343-453兲
68.6
共398兲
GC
共502-589兲
68.7
共517兲
A
共387-582兲
60.5
共402兲
hexafluorobenzene
共318-376兲
34.4
共333兲
EB
共403-516兲
31.8
共425兲
共278-354兲
36.5
共293兲
A
共348-389兲
33.2
共363兲
A
共384-462兲
32.2
共399兲
A
共458-517兲
31.8
共473兲
A
共290-510兲
35.6
共298兲
35.7
共298兲
C
共293-323兲
35.7
共308兲
共278-321兲
36.2
共292兲
MM
共363-516兲
32.2
共378兲
EB
共275-387兲
36.5
共293兲
共293-356兲
35.1
共308兲
共293-358兲
35.5
共308兲
N-共pentafluorophenyl兲imidosulfuryl fluoride
共309-355兲
45.3
共332兲
pentafluorophenoxydifluorophosphine
共310-363兲
42.4
共325兲
pentafluorophenoxyphosphoryl difluoride
共323-367兲
46.4
共338兲
perfluoro共2-methyl-3-methylenecyclobutene兲
共243-306兲
31.0
共258兲
A
2,2,3,3,3-pentafluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲-ethylidene兴propanamide
32.7
共338兲
2,2,3,3,4,4,5,5-octafluoro-1,1,2,3,4,5-hexahydro-1-关共trifluoroacetyl兲-imino兴thiophene-1-oxide
33.9
共383兲
perfluoromethylcyclopentane
30.68
共298兲
EB
perfluorocyclohexane
共373-457兲
28.0
共388兲
CAS registry number
Reference
关62977-72-4兴
关77/15兴
关344-07-0兴
关91/2兴
关87/5兴
关87/5兴关68/10兴
关68/26兴
关68/26兴
关68/26兴
关66/11兴
关33757-14-1兴
关87/5兴关71/17兴
关59/21兴
关72/22兴
关319-88-0兴
关87/5兴
关84/9兴关91/2兴
关59/21兴
关2631-68-7兴
关87/5兴关68/14兴
关72/20兴
关118-75-2兴
关47/5兴
关118-74-1兴
关01/1兴
关94/22兴
关94/23兴
关90/2兴
关87/5兴
关47/5兴
关392-56-3兴
关90/7兴
关88/20兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关82/11兴关91/2兴
关81/8兴
关80/23兴
关69/9兴
关66/11兴
关65/8兴
关64/16兴
关46/5兴关84/9兴
关20094-84-2兴
关68/21兴
关76/28兴
关76/28兴
关87/5兴
关52225-58-8兴
关74/24兴
关77589-41-4兴
关81/16兴
关98/18兴
关355-68-0兴
关88/20兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
616
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6F12
C6F12N2
C6F12N2OS
C6F12N2O2S
C6F12N2S
C6F12N2S2
C6F12O
C6F12O2
C6F12O4
C6F13NS
C6F14
C6F14
C6F14
C6F14
C6F14IP
C6F14N2S
C6F14O
C6F15N
C6F15NO
C6F15O4S2
C6F16N2S
C6F16S
C6F20N3O3P
C6N2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共350-451兲
28.1
共365兲
A
共336-394兲
29.6
共351兲
perfluoro共1,2-dimethylcyclobutane兲
共242-318兲
32.1
共257兲
A
N,N,N,N-tetrakis共trifluoromethyl兲-1,2-ethynylenediamine
共305-328兲
32.1
共316兲
A
1,1,1,3,3,3-hexafluoro-2-isocyanato-N-关2,2,2-trifluoro-1-共trifluoro-methyl兲ethylidene兴-2-propanamine
39.3
共375兲
I
1,1,1-trifluoro-N’-共trifluoroacetyl兲-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴methanesulfonimidamide
32.6
共404兲
I
bis关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴sulfoxylic diamide
40.6
共391兲
I
bis共hexafluoroisopropylidenimino兲 disulfide
46.0
共417兲
I
perfluoro共methoxycyclopentane兲
共246-330兲
38.6
共261兲
A
trifluoroacetic acid, 2,2,2-trifluoro-1,1-bis共trifluoromethyl兲ethyl ester
共264-298兲
34.3
共279兲
A
33.1
共329兲
HG
carbonoperoxoic acid, O-关2,2,2-trifluoro-1,1-bis共trifluoromethyl兲ethyl兴-O,O共trifluoromethyl兲 ester ester
共273-315兲
33.5
共288兲
A
2,2,2-trifluoro-N-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-ethanimidothioic acid,
trifluoromethyl ester
35.3
共360兲
perfluorohexane
共261-334兲
34.4
共276兲
A
共285-340兲
31.4
共298兲
共433-449兲
33.4
共441兲
A
共303-330兲
31.5
共316兲
共284-342兲
32.4
共298兲
perfluoro-2-methylpentane
共280-340兲
31.4
共298兲
共253-329兲
34.5
共268兲
A
共277-341兲
32.5
共292兲
perfluoro-3-methylpentane
共282-333兲
30.8
共297兲
perfluoro-2,3-dimethylbutane
共260-340兲
31.6
共298兲
共262-333兲
33.0
共277兲
bis共heptafluoropropyl兲 iodophosphine
共273-353兲
41.6
共313兲
bis关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴 sulfur diimide
共325-378兲
38.5
共340兲
perfluorodipropyl ether
共306-327兲
31.2⫾0.4
共298兲
perfluorotriethylamine
共297-343兲
34.0⫾0.4
共298兲
34.2⫾0.1
共298兲
共320-334兲
32.8
共327兲
共317-349兲
32.9
共332兲
1,1,1,2,3,3,3,-heptafluoro-N-共pentafluoroethyl兲-N-共trifluoromethyl兲-2-propanamine
27.1
共338兲
2,2,4,4-tetrafluoro-1,1,3,3-tetrahydro-1,1,3,3-tetrakis共trifluoromethoxy兲-1,3-dithietane
37.2
共404兲
bis关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴diimidosulfuryl fluoride
35.8
difluorobis关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴 sulfur
共273-383兲
36.6
共328兲
phosphorous tris关bis共trifluoromethyl兲nitroxide兴 difluoride
39.3
共421兲
dicyanobutadiyne
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
A
EB
EB
C
A
A
I
A
CAS registry number
Reference
关87/5兴
关57/11兴关84/9兴
关2994-71-0兴
关87/5兴
关19451-96-8兴
关87/5兴
关34619-84-6兴
关72/24兴
关62609-66-9兴
关77/19兴
关31340-33-7兴
关72/24兴
关72/22兴
关788-40-9兴
关87/5兴关72/20兴
关24165-10-4兴
关87/5兴关75/22兴
关73/20兴
关55100-93-1兴
关87/5兴关75/22兴
关53120-07-9兴
关75/20兴
关355-42-0兴
关87/5兴
关84/9兴关91/2兴
关87/5兴关78/8兴
关58/12兴关84/9兴
关52/1兴
关335-04-4兴
关84/9兴关91/2兴
关87/5兴关67/15兴
关84/9兴
关52/1兴关84/9兴
关865-71-4兴
关87/5兴
关354-96-1兴
关84/9兴关91/2兴
关87/5兴关67/15兴
关84/9兴
关59/21兴
关34451-12-2兴
关87/5兴关72/21兴
关356-62-7兴
关89/13兴
关359-70-6兴
关95/20兴
关95/20兴
关87/5兴
关87/5兴
关54566-82-4兴
关75/19兴
关63441-15-6兴
关77/16兴
关59617-31-1兴
关76/29兴
关1423-18-3兴
关87/5兴关99/16兴
关73/24兴
关16419-78-6兴
ENTHALPIES OF VAPORIZATION
617
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6HBrF12N2
C6HClF11NO
C6HCl2N3O6
C6HCl3F8O2
C6HCl5
C6HCl5O
C6HF5
C6HF5O
C6HF12NO
C6HF12NOS
C6H2BrCl3O
C6H2ClN3O6
C6H2Cl3F
C6H2Cl3NO2
C6H2Cl4
C6H2Cl4
C6H2Cl4
C6H2Cl4O
C6H2Cl4O2
C6H2F4
C6H2F4
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共341-369兲
30.2
共355兲
1-bromo-N,N,N’,N’-tetrakis共trifluoromethyl兲vinylenediamine
共348-371兲
32.3
共359兲
N-关1-chloro-2,2,2-trifluoro-1-共trifluoromethyl兲ethyl兴-2,2,3,3,3-pentafluoropropanamide
40.8
共381兲
1,3-dichloro-2,4,6-trinitrobenzene
共504-563兲
46.9
共519兲
共504-533兲
80.4
octafluoro-3,5,6-trichlorohexanoic acid
共373-505兲
64.2
共388兲
Method
A
A
A
A
pentachlorobenzene
66.0
共357兲
共413-453兲
67.7
共298兲
共371-549兲
62.1
共386兲
pentachlorophenol
共463-507兲
69.0
共478兲
pentafluorobenzene
共358-397兲
33.5
共373兲
共393-479兲
32.6
共408兲
共473-531兲
32.2
共488兲
共290-510兲
36.2
共298兲
共322-368兲
34.8
共337兲
共373-530兲
32.0
共388兲
共298-356兲
35.7
共313兲
共298-358兲
35.7
共313兲
pentafluorophenol
共323-455兲
52.2⫾0.4
共298兲
共378-428兲
44.2
共393兲
2,2,3,3,3-pentafluoro-N-关1,2,2,-tetrafluoro-1-共trifluoromethyl兲ethyl兴-propanamide
41.3
共368兲
2,2,2-trifluoro-N-关共trifluoromethyl兲thio兴ethanimidic acid, 2,2,2-trifluoro-1共trifluoromethyl兲ethyl ether
33.6
共364兲
3-bromo-2,4,6-trichlorophenol
共385-579兲
67.1
共400兲
1-chloro-2,4,6-trinitrobenzene
共473-543兲
63.1
共488兲
1-fluoro-2,4,6-trichlorobenzene
共344-489兲
41.1
共359兲
2,4,5-trichloro-1-nitrobenzene
共427-560兲
56.7
共442兲
1,2,3,4-tetrachlorobenzene
共413-453兲
60.1
共298兲
共341-527兲
56.7
共356兲
1,2,3,5-tetrachlorobenzene
共413-453兲
60.7
共298兲
共331-519兲
51.1
共346兲
1,2,4,5-tetrachlorobenzene
共413-453兲
60.7
共298兲
共419-518兲
52.0
共434兲
2,3,4,6-tetrachlorophenol
共373-548兲
64.8
共388兲
3,4,5,6-tetrachloro-1,2-benzenediol
共293-323兲
77.9
共308兲
1,2,3,4-tetrafluorobenzene
共300-390兲
37.5
共298兲
共300-392兲
36.8
共315兲
共279-323兲
1,2,3,5-tetrafluorobenzene
共385-416兲
共290-380兲
GC
A
A
A
A
A
A
EB
EB
A
CAS registry number
Reference
关87/5兴
关19451-95-7兴
关87/5兴
关52225-62-4兴
关74/24兴
关1630-09-7兴
关87/5兴关72/20兴
关68/14兴
关2106-54-9兴
关87/5兴关72/20兴
关57/17兴
关608-93-5兴
关99/20兴
关94/22兴
关87/5兴关47/5兴
关87-86-5兴
关87/5兴关72/20兴
关363-72-4兴
关87/5兴
关87/5兴
关87/5兴
关82/11兴关91/2兴
关87/5兴关68/10兴
关66/11兴
关64/16兴
关46/5兴关84/9兴
关771-61-9兴
关97/6兴
关87/5兴关68/10兴
关52225-64-6兴
关74/24兴
关62067-08-7兴
I
关77/18兴
A
关87/5兴关47/5兴
关88-88-0兴
关87/5兴关68/14兴
关36556-33-9兴
关87/5兴
关89-69-0兴
关87/5兴
关634-66-2兴
关94/22兴
关87/5兴关47/5兴
关634-90-2兴
关94/22兴
关87/5兴关47/5兴
关95-94-3兴
关94/22兴
关87/5兴关47/5兴
关58-90-2兴
关87/5兴关47/5兴
关1198-55-6兴
关99/13兴
关551-62-2兴
关84/9兴关91/2兴
关87/5兴关75/27兴
关84/9兴
关87/5兴关69/9兴
关2367-82-0兴
关87/5兴
关84/9兴关91/2兴
A
A
A
GC
A
GC
A
GC
A
A
CGC
A
37.0
共294兲
MM
32.4
36.0
共400兲
共298兲
A
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
618
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6H2F4
C6H2F12O
C6H2F12O3S
C6H2F14NP
C6H3BrCl2O
C6H3ClN2O4
C6H3Cl2NO2
C6H3Cl3
C6H3Cl3
C6H3Cl3
C6H3Cl3O
C6H3Cl3O
C6H3Cl3O2
C6H3F3
C6H3F9O2
C6H3F9O2
C6H3F10NS
C6 H3 F11O
C6 H3 F11O
C6 H3 F11O
C6 H3 F11O
C6 H3 N3 O6
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共287-382兲
36.0
共302兲
A
共279-323兲
1,2,4,5-tetrafluorobenzene
共290-390兲
共390-488兲
共488-543兲
共293-390兲
36.0
共294兲
MM
37.2
33.1
32.6
36.8
共298兲
共405兲
共503兲
共308兲
A
A
A
Compound
共Temperature range/K兲
1,1,1,2,2,3,3,-heptafluoro-3-共2,2,3,3,3-pentafluoropropoxy兲-propane
共288-344兲
34.8
共303兲
bis共1,1,1,3,3,3-hexafluoro-2-propanol兲 sulfite
42.4
amino bis共heptafluropropyl兲phosphine
共293-393兲
38.7
共343兲
2-bromo-4,6-dichlorophenol
共357-541兲
58.6
共372兲
1-chloro-2,4-dinitrobenzene
共430-590兲
80.5
共445兲
3,4-dichloro-1-nitrobenzene
共417-515兲
55.5
共432兲
1,2,4-trichlorobenzene
55.8
共290兲
共391-490兲
49.5
共406兲
共413-453兲
57.6
共298兲
55.5⫾0.1
共298兲
共279-298兲
47.0
共288兲
共311-486兲
49.3
共326兲
1,2,3-trichlorobenzene
54.5
共325兲
共413-453兲
57.2
共298兲
共258-313兲
54.3
共293-383兲
53.5
共308兲
共313-492兲
47.4
共328兲
1,3,5-trichlorobenzene
共338-415兲
50.3⫾0.1
共375兲
51.7
共337兲
共413-453兲
59.0
共298兲
共336-482兲
48.8
共351兲
2,4,5-trichlorophenol
共345-525兲
54.5
共360兲
2,4,6-trichlorophenol
共349-519兲
58.8
共364兲
3,4,5-trichloro-1,2-benzenediol
共293-323兲
79.3
共308兲
1,3,5-trifluorobenzene
共280-320兲
33.9
共298兲
共279-350兲
34.5
共294兲
I
A
A
A
EB
GC
C
RG
GC
GC
A
A
DM
GC
A
A
A
CGC
A, MM
trifluoroacetic acid, 2,2,2-trifluoro-1-methyl-1-共trifluoromethyl兲ethyl ester
33.5
共338兲
HG
acetic acid, 2,2,2-trifluoro-1,1-bis共trifluoromethyl兲ethyl ester
共273-328兲
40.1
共288兲
A
2,2,2-trifluoro-N-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-ethanimidothioic acid, methyl ester
31.6
共383兲
1,1,1,2,2,3,3-heptafluoro-3-共2,2,3,3-tetrafluoropropoxy兲propane
共288 –357兲
37.2
共303兲
I
1,1,1,2,2,3,3,4,4,5,5-undecafluoro-5-methoxypentane
共288 –358兲
36.6
共303兲
I
1,1,1,2,3,3,4,4-octafluoro-4-methoxy-2-共trifluoromethyl兲butane
共288 –357兲
36.0
共303兲
I
1,1,1,2,3,3-hexafluoro-3-共2,2,3,3,3-pentafluoropropoxy兲propane
共293–360兲
38.4
共308兲
I
1,2,3-trinitrobenzene
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关87/5兴关75/27兴
关84/9兴
关87/5兴关69/9兴
关327-54-8兴
关84/9兴关91/2兴
关87/5兴
关87/5兴
关87/5兴关75/27兴
关89/4兴
关176310-30-8兴
关02/19兴
关53517-89-9兴
关75/43兴
关59/21兴
关45524-77-0兴
关87/5兴关47/5兴
关97-00-7兴
关87/5兴
关99-54-7兴
关87/5兴
关120-82-1兴
关99/20兴
关98/8兴
关94/22兴
关87/13兴
关49/11兴
关47/5兴
关87-61-6兴
关99/20兴
关94/22兴
关94/23兴
关87/5兴
关87/5兴关47/5兴
关108-70-3兴
关01/8兴
关99/20兴
关94/22兴
关87/5兴关47/5兴
关95-95-4兴
关87/5兴关47/5兴
关88-06-2兴
关87/5兴关47/5兴
关56961-20-7兴
关99/13兴
关372-38-3兴
关84/9兴关91/2兴
关87/5兴关69/9兴
关72/20兴
关42031-16-3兴
关73/20兴
关24165-09-1兴
关87/5兴关75/22兴
关54120-08-0兴
关75/20兴
关176310-29-5兴
关02/19兴
关181214-74-4兴
关02/19兴
关203783-56-6兴
关02/19兴
关290-28-8兴
关02/19兴
关603-13-4兴
ENTHALPIES OF VAPORIZATION
619
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H3 N3 O6
C6 H3 N3 O6
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共523–573兲
60.3
共538兲
A
1,2,4-trinitrobenzene
共523–573兲
82.6
共538兲
A
1,3,5-trinitrobenzene
共475–585兲
70.3
共490兲
A
106.4
共483兲
A
52.2
共267兲
A
49.1
49.7
共348兲
共320兲
A
50.1
共403兲
A
48.3
共432兲
A
49.9
共388兲
A
37.4
共288兲
A
56.5
共348兲
A
52.1
共435兲
EB
51.5
共429兲
EB
51.3
共400兲
A
51.2
44.5
50.8
50.9
51.2
44.0
49.9
50.0
共256兲
共376兲
共271兲
共298兲
50.4
44.1
50.0
53.9
47.0
44.7
共248兲
共372兲
共262兲
共298兲
共298兲
共363兲
46.4
44.2
54.8
U35.0
45.0
47.8
共326兲
共373兲
共298兲
60.8
共341兲
A
57.9
共348兲
A
70.5
共308兲
CGC
63.9
共288兲
A
Compound
共Temperature range/K兲
C6 H4 Cl2
2,4,6-trinitrophenol 共picric acid兲
共468 –598兲
1-bromo-3-chlorobenzene
共252– 469兲
1-bromo-4-chlorobenzene
共333– 470兲
共305– 470兲
1,2-dibromobenzene
共388 –568兲
1,3-dibromobenzene
共417–500兲
1,4-dibromobenzene
共373– 493兲
1-chloro-3-fluorobenzene
共273– 403兲
1-chloro-4-iodobenzene
共333–500兲
1-chloro-2-nitrobenzene
共420–516兲
1-chloro-3-nitrobenzene
共414 –506兲
1-chloro-4-nitrobenzene
共385–515兲
1,2-dichlorobenzene
C6 H4 Cl2
共363– 454兲
共256 –287兲
共413– 453兲
共258 –313兲
共373– 453兲
共360– 450兲
共301–343兲
1,3-dichlorobenzene
C6 H4 Cl2
共357– 448兲
共250–274兲
共413– 453兲
共360– 450兲
共348 –513兲
1,4-dichlorobenzene
C6 H3 N3 O7
C6 H4 BrCl
C6 H4 BrCl
C6 H4 Br2
C6 H4 Br2
C6 H4 Br2
C6 H4 ClF
C6 H4 ClI
C6 H4 ClNO2
C6 H4 ClNO2
C6 H4 ClNO2
C6 H4 Cl2 O
C6 H4 Cl2 O
C6 H4 Cl2 O2
C6 H4 Cl2 O3
C6 H4 Cl3 N
共358 – 448兲
共413– 453兲
共258 –313兲
共341– 448兲
共370– 450兲
2,4-dichlorophenol
共326 – 483兲
2,6-dichlorophenol
共333– 493兲
4,5-dichloro-1,2-benzenediol
共293–323兲
vinyl mucochlorate
共273–333兲
2,4,6-trichloroaniline
共388兲
共298兲
共322兲
共356兲
共298兲
EB
GC
GC
A
GS
EB
GC
EB
GC
GC
A
CAS registry number
Reference
关87/5兴关68/14兴
关72/20兴
关610-31-1兴
关87/5兴关68/14兴
关72/20兴
关99-35-4兴
关87/5兴关68/14兴
关72/20兴
关88-89-1兴
关87/5兴
关108-37-2兴
关87/5兴关72/20兴
关106-39-8兴
关87/5兴
关47/5兴
关583-53-9兴
关87/5兴关72/20兴
关108-36-1兴
关87/5兴
关106-37-6兴
关87/5兴关72/20兴
关625-98-9兴
关87/5兴
关352-33-0兴
关87/5兴
关88-73-3兴
关84/21兴
关121-73-3兴
关84/21兴
关100-00-5兴
关87/5兴
关95-50-1兴
关99/20兴
关98/8兴
关96/19兴
关94/22兴
关94/23兴
关87/5兴
关84/9兴关91/2兴
关82/1兴
关541-73-1兴
关99/20兴
关98/8兴
关96/19兴
关94/22兴
关84/9兴关91/2兴
关87/5兴关72/20兴
关106-46-7兴
关99/20兴
关98/8兴
关94/22兴
关94/23兴
关87/5兴
关84/9兴关91/2兴
关128-83-2兴
关87/5兴关47/5兴
关75/17兴
关87-65-0兴
关87/5兴关47/5兴
关3428-24-8兴
关99/13兴
关87/5兴
关634-93-5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
620
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H4 F2
C6 H4 F2
C6 H4 F2
C6 H4 F10O
C6 H4 INO2
C6 H4 I2
C6 H4 N2
C6 H4 N2 O4
C6 H4 N2 O4
C6 H4 N2 O4
C6 H4 O2
C6 H4 S4
C6 H5 Br
C6 H5 BrO
C6 H5 BrO
C6 H5 BrO
C6 H5 BrS
C6 H5 BrS
C6 H5 BrS
C6 H5 Cl
C6 H5 ClO
Compound
共Temperature range/K兲
共407–535兲
1,2-difluorobenzene
共300– 400兲
共304 – 403兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
92.9
共422兲
A
36.2
35.5
34.6⫾0.1
33.5⫾0.1
32.2⫾0.1
共298兲
共319兲
共327兲
共345兲
共367兲
EB
C
C
C
1,3-difluorobenzene
共310– 400兲
34.6
1,4-difluorobenzene
共300– 400兲
35.8
1,1,1,2,3,3-hexafluoro-3-共2,2,3,3-tetrafluoropropoxy兲propane
共293–379兲
42.3
2-iodo-1-nitrobenzene
共433–563兲
59.9
1,4-diiodobenzene
共402–560兲
52.6
nicotinic acid nitrile
共453– 479兲
45.0
1,2-dinitrobenzene
共454 –593兲
60.0
1,3-dinitrobenzene
共336 –379兲
96.7
1,4-dinitrobenzene
共445–572兲
60.3
1,4-benzoquinone
共388 – 402兲
47.8
tetrathiafulvene
共331–355兲
95.3
bromobenzene
共330– 430兲
44.8
44.0
共333– 463兲
42.3
44.5⫾0.1
共329– 427兲
42.4
2-bromophenol
50.2
3-bromophenol
共410–510兲
73.5
55.2
4-bromophenol
共390–511兲
58.8
58.6
2-bromobenzenethiol
50.6
3-bromobenzenethiol
51.1
4-bromobenzenethiol
52.3
chlorobenzene
共313–353兲
40.3
共413– 453兲
43.9
共258 –313兲
48.1
40.6⫾0.3
共405–597兲
35.4
共335– 405兲
41.0
41.0⫾0.1
共333– 405兲
38.8
共253–303兲
2-chlorophenol
共337– 447兲
共354 – 448兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共298兲
共298兲
共308兲
I
共448兲
A
A
共417兲
共466兲
A
共469兲
A
共351兲
A
共460兲
A
共395兲
A
共343兲
共298兲
共293兲
共348兲
共298兲
共344兲
C
A
C
共425兲
A
共405兲
A
共298兲
共298兲
共420兲
共298兲
共298兲
共348兲
37.3
共278兲
47.0
45.2
47.2
共352兲
共369兲
CGC
GC
GC
GC
A
C
ME
CAS registry number
Reference
关87/5兴关47/5兴
关367-11-3兴
关84/9兴关91/2兴
关63/23兴关84/9兴
关63/23兴
关63/23兴
关63/23兴
关372-18-9兴
关80/11兴关91/2兴
关540-36-3兴
关80/11兴关91/2兴
关65064-78-0兴
关02/19兴
关609-73-4兴
关87/5兴
关624-38-4兴
关87/5兴
关100-54-9兴
关87/5兴关72/20兴
关528-29-0兴
关87/5兴关72/20兴
关99-65-0兴
关87/5兴
关100-25-4兴
关87/5兴关72/20兴
关106-51-4兴
关87/5兴
关31366-25-3兴
关99/16兴
关108-86-1兴
关84/9兴关91/2兴
关75/37兴
关87/5兴关72/20兴
关68/1兴
关55/22兴
关95-56-7兴
关86/10兴
关591-20-8兴
关87/5兴
关86/10兴
关106-41-2兴
关87/5兴
关86/10兴
关6320-02-1兴
关86/10兴
关86/10兴
关106-53-6兴
关86/10兴
关108-90-7兴
关95/21兴
关94/22兴
关94/23兴
关89/16兴
关87/5兴
关84/9兴关91/2兴
关68/1兴
关87/5兴关52/18兴
关84/9兴
关40/12兴
关95-57-8兴
关95/12兴
关66/10兴
关87/5兴
ENTHALPIES OF VAPORIZATION
621
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H5 ClO
C6 H5 ClO
Compound
共Temperature range/K兲
共333– 449兲
共285– 447兲
3-chlorophenol
共317– 487兲
4-chlorophenol
共373– 493兲
C6 H5 ClS
共323– 493兲
2-chlorobenzenethiol
C6 H5 ClS
3-chlorobenzenethiol
C6 H5 ClS
4-chlorobenzenethiol
C6 H5 ClO2
4-chloro-1,2-benzenediol
共293–323兲
benzenesulfonyl chloride
共339–524兲
共338 –525兲
3,4-dichloroaniline
共420–545兲
phenyl dichlorophosphate
共339–513兲
fluorobenzene
共358 –530兲
共373– 419兲
共414 –501兲
共497–561兲
共255–360兲
共312–394兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
50.1
45.2
共348兲
共300兲
A
52.3
53.1
共332兲
A
共388兲
A
60.6
54.0
52.8
Method
共338兲
47.7
48.5
48.5
C6 H5 ClO2 S
C6 H5 Cl2 N
C6 H5 Cl2 O2 P
C6 H5 F
C6 H5 FO
C6 H5 FO
C6 H5 F8 NOS
C6 H5 F9 O
C6 H5 I
C6 H5 NO2
C6 H5 NO3
C6 H5 N3
C6 H6
70.2
共308兲
CGC
54.4
57.2
共354兲
共353兲
A
58.6
共435兲
A
63.6
共354兲
A
31.9
31.8
31.0
30.9
34.5
33.6
33.5⫾0.1
32.4⫾0.1
31.2⫾0.1
29.7⫾0.1
共373兲
共388兲
共429兲
共512兲
共298兲
共327兲
共318兲
共337兲
共358兲
共382兲
A
A
A
A
EB
C
C
C
C
3-fluorophenol
共373– 451兲
50.3
共388兲
4-fluorophenol
共360– 460兲
48.8
共375兲
1-共ethylimino兲-2,2,3,3,4,4,5,5-octafluoro-1,1,2,3,4,5-hexahydro-thiophene-1-oxide
31.4
共333兲
1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane
共293–350兲
34.2
共308兲
iodobenzene
共313–353兲
47.4
共298兲
共462– 679兲
41.1
共477兲
共320– 460兲
48.9
共298兲
共273–358兲
51.4
共288兲
共358 –543兲
46.0
共373兲
nitrobenzene
共313–353兲
54.5
共298兲
共291–305兲
56.1⫾1.7
共298兲
55.0
共298兲
共279–296兲
54.7
共287兲
共407– 483兲
共369– 481兲
2-nitrophenol
共366 – 490兲
共322–357兲
phenyl azide
共348 –368兲
benzene
共305–345兲
A
A
I
CGC
A
A
A
CGC
ME
A
48.5
48.9
共422兲
共425兲
55.9
54.4
共381兲
共337兲
A
A
45.2
共358兲
A
33.2
共320兲
CAS registry number
Reference
关87/5兴关74/15兴
关47/5兴
关108-43-0兴
关86/10兴
关87/5兴关47/5兴
关106-48-9兴
关87/5兴
关86/10兴
关47/5兴
关6320-03-2兴
关86/10兴
关2037-31-2兴
关86/10兴
关106-54-7兴
关86/10兴
关2138-22-9兴
关99/13兴
关98-09-9兴
关99/16兴
关87/5兴关47/5兴
关95-76-1兴
关87/5兴
关770-12-7兴
关87/5兴关47/5兴
关462-06-6兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关84/9兴关91/2兴
关87/5兴关56/19兴
关56/19兴
关56/19兴
关56/19兴
关56/19兴
关372-20-3兴
关87/5兴
关371-41-5兴
关87/5兴
关77984-30-6兴
关81/15兴
关163702-05-4兴
关02/19兴
关591-50-4兴
关95/21兴
关87/5兴
关84/9兴关91/2兴
关87/5兴关72/20兴
关87/5兴关72/20兴
关98-95-3兴
关95/21兴
关71/10兴
关71/9兴
关87/5兴关72/20兴
关60/18兴
关52/19兴关84/9兴
关33/15兴
关88-75-5兴
关87/5兴
关47/5兴
关622-37-3兴
关87/5兴关72/20兴
关71-43-2兴
关02/45兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
622
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共258 –313兲
共296 –377兲
共279–377兲
共353– 422兲
共420–502兲
共501–562兲
共313–373兲
共284 –354兲
共282–354兲
共288 –354兲
共298 –373兲
共273–348兲
C6 D6
C6 H6
C6 H6
C6 H6
C6 H6 ClN
C6 H6 ClN
C6 H6 ClN
C6 H6 Cl4
C6 H6 Cl6
C6 H6 Cl6
C6 H6 F8 O
C6 H6 F9 N3 S
⌬ vapH m
共kJ mol⫺1兲
35.6
33.5
33.9⫾0.2
33.4
33.1
32.4
31.9
31.4
30.6
34.4
31.5
30.2
30.3
30.8
30.5
30.2
35.3
31.0
33.8⫾0.1
33.0⫾0.1
32.2⫾0.1
31.8⫾0.1
31.4⫾0.1
30.9⫾0.1
32.6⫾0.4
32.5⫾0.5
33.9
31.6⫾0.4
34.1
34.1
33.8
34.1
31.2
34.1
33.4
34.5
34.0
Mean temperature
(T m /K)
共311兲
共307兲
共314兲
共324兲
共332兲
共344兲
共353兲
共294兲
共368兲
共435兲
共516兲
共352兲
共361兲
共366兲
共343兲
共350兲
共298兲
共313兲
共328兲
共333兲
共343兲
共353兲
共313兲
共328兲
共298兲
共345兲
共293兲
共299兲
共298兲
共297兲
共294兲
共303兲
共313兲
共288兲
共298兲
Method
GC
EB
GC
C
C
C
C
C
C
A
A
A
A
C
C
C
C
C
C
DSC
DSC
DSC
C
MM
EB
benzene—d6
共283–352兲
34.2
共298兲
1,5-hexadien-3-yne
共223–357兲
40.4
共238兲
A
1,3-hexadien-5-yne
共223–303兲
44.0
共238兲
A
2,4-hexadiyne
共364 – 408兲
42.5
共298兲
EB
2-chloroaniline
共397– 482兲
50.7
共412兲
A
共287–336兲
58.2⫾1.4
共311兲
TE, ME
共294 –330兲
57.1⫾1.0
共312兲
TE, ME
3-chloroaniline
共398 –573兲
53.6
共413兲
A
共292–346兲
60.3⫾0.6
共319兲
TE, ME
共304 –342兲
61.0⫾0.8
共323兲
TE, ME
4-chloroaniline
共363–505兲
52.2
共378兲
A
␣-3,4,5,6-tetrachlorocyclohexene
共353–399兲
58.0
共368兲
A
␣-hexachlorocyclohexane
共343– 453兲
68.5
共398兲
GC
␤-hexachlorocyclohexane
共343– 453兲
70.5
共398兲
GC
1,1,2,2,3,3,4,4-octafluoro-5-methoxypentane
共293–396兲
44.8
共308兲
I
N-关N,N⬘-dimethyl-S-共trifluoromethyl兲sulfonodiimidoyl兴-1,1,1,3,3,3-hexafluoro-2-propanimine
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关94/23兴
关90/7兴
关89/16兴
关88/19兴
关88/19兴
关88/19兴
关88/19兴
关88/19兴
关88/19兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关83/12兴
关83/12兴
关83/12兴
关83/8兴
关77/30兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关71/23兴
关71/23兴
关71/28兴
关71/23兴
关49/20兴
关49/6兴
关47/7兴
关46/4兴
关46/8兴
关45/2兴
关41/9兴
关40/5兴
关27/3兴
关1076-43-3兴
关53/10兴
关821-08-9兴
关87/5兴
关10420-90-3兴
关87/5兴
关2809-69-0兴
关86/1兴
关95-51-2兴
关87/5兴
关85/11兴
关85/11兴
关108-42-9兴
关87/5兴关72/20兴
关85/11兴
关85/11兴
关106-47-8兴
关87/5兴
关41992-55-6兴
关87/5兴
关319-84-6兴
关90/2兴
关58-69-9兴
关90/2兴
关77527-96-9兴
关02/19兴
关63265-76-9兴
ENTHALPIES OF VAPORIZATION
623
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H6 N2
C6 H6 N2 O2
C6 H6 N2 O2
C6 H6 N2 O2
C6 H6 O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
32.6
共426兲
I
49.4
共368兲
A
59.3
64.8
共438兲
共392兲
A
64.9
共458兲
A
77.9
70.0
共488兲
共430兲
A
53.2
58.8
49.5
57.4
50.9
46.8
43.8
51.1
51.3
共378兲
共298兲
共470兲
共329兲
共402兲
共464兲
共535兲
EB
CGC
A
A
A
A
A
共398兲
EB, GS
51.4
48.1
共395兲
共434兲
63.1
61.2
共410兲
共393兲
A
GC
74.3
74.3
共434兲
共407兲
A
GC
70.5
共463兲
A
69.5
共440兲
A
56.3
共288兲
A
45.9
43.5
43.1
共348兲
3-hexenedinitrile
共353– 448兲
2-nitroaniline
共423–553兲
共377–558兲
3-nitroaniline
共443–578兲
4-nitroaniline
共473–538兲
共415– 609兲
phenol
共363–391兲
共393– 433兲
共455– 655兲
共314 –395兲
共387– 456兲
共449–526兲
共520– 625兲
共383– 473兲
C6 H6 O2
C6 H6 O2
C6 H6 O2
C6 H6 O3
C6 H6 O4
C6 H6 S
共380– 455兲
共414 – 454兲
1,2-dihydroxybenzene 共catechol兲
共395–519兲
共378 – 439兲
1,3-dihydroxybenzene 共resorcinol兲
共419–550兲
共392– 463兲
1,4-dihydroxybenzene 共hydroquinone兲
共448 –559兲
1,2,3-trihydroxybenzene
共425–582兲
butynedioic acid, dimethyl ester
共273– 460兲
benzenethiol 共thiophenol兲
共333– 471兲
共385– 486兲
C6 H7 Cl3 OS
C6 H7 N
C6 H7 N
C6 H7 N
43.8⫾0.1
42.6⫾0.1
41.8⫾0.1
41.3⫾0.1
共324 – 440兲
44.3
2,3,3-trichloro-2-propenethioic acid, O-propyl ester
共383– 433兲
69.4
3-methylenecyclobutanecarbonitrile
共348 – 435兲
45.9
bicyclo关2.1.0兴pentane-1-carbonitrile
共332–390兲
41.8
aniline
共350– 499兲
51.0⫾0.2
共350– 499兲
48.0⫾0.2
共350– 499兲
45.2⫾0.2
共350– 499兲
42.2⫾0.4
共421–591兲
45.8
共273–338兲
52.2
共304 – 485兲
53.6
共373– 458兲
48.6
共455–523兲
46.3
共313–386兲
51.4
共304 – 457兲
54.0
共400兲
A, EB
共375兲
共395兲
共407兲
共417兲
共339兲
C
C
C
C
GC
共366兲
BG
共343兲
BG
共360兲
共400兲
共440兲
共480兲
共444兲
共288兲
共319兲
共388兲
共470兲
共350兲
共319兲
EB
EB
EB
EB
A
A
A
A
CAS registry number
Reference
关77/15兴
关1119-85-3兴
关87/5兴
关88-74-4兴
关87/5兴
关47/5兴
关99-09-2兴
关87/5兴
关100-01-6兴
关87/5兴
关47/5兴
关108-95-2兴
关01/17兴
关95/21兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关86/10兴
关87/5兴关60/4兴
关72/20兴
关49/1兴关84/9兴
关39/4兴
关120-80-9兴
关87/5兴
关75/24兴
关108-46-3兴
关87/5兴
关87/5兴关75/24兴
关123-31-9兴
关87/5兴
关87-66-1兴
关87/5兴关55/9兴
关87/5兴关72/20兴
关108-98-5兴
关99/16兴
关86/10兴
关87/5兴关66/5兴
关56/13兴
关56/13兴
关56/13兴
关56/13兴
关56/13兴
关55/9兴关84/9兴
关76619-93-7兴
关80/24兴
关15760-35-7兴
关71/2兴
关31357-71-8兴
关71/2兴
关62-53-3兴
关02/14兴
关02/14兴
关02/14兴
关02/14兴
关92/1兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关79/23兴
关62/7兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
624
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H7 N
Compound
共Temperature range/K兲
2-methylpyridine
共308 – 441兲
共308 – 441兲
共308 – 441兲
共308 – 441兲
共323–373兲
共292– 403兲
共209–245兲
共429–537兲
共521– 621兲
共352– 445兲
共352– 442兲
C6 H7 N
共337– 403兲
3-methylpyridine
共314 – 457兲
共314 – 457兲
共314 – 457兲
共314 – 457兲
共374 – 458兲
共450–570兲
共561– 645兲
共347– 458兲
共347– 458兲
C6 H7 N
C6 H7 N
C6 H7 NO
C6 H7 NO
共354 – 418兲
4-methylpyridine
共328 – 459兲
共328 – 459兲
共328 – 459兲
共328 – 459兲
共323–373兲
共348 – 460兲
共348 –347兲
共381– 460兲
共452–573兲
共564 – 646兲
共348 – 459兲
共350– 418兲
2-cyclopentene-1-carbonitrile
2-methoxypyridine
共304 –338兲
1-methyl-2(1H)-pyridone
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
53.0
共333兲
C
41.2⫾0.1
38.8⫾0.1
36.4⫾0.1
33.7⫾0.3
43.6
42.0
46.9
36.5
35.4
42.5⫾0.1
41.6⫾0.1
40.7⫾0.1
39.8⫾0.1
38.3⫾0.1
39.1
39.1
38.8⫾0.1
37.7⫾0.1
36.2⫾0.1
39.8
共320兲
共360兲
共400兲
共440兲
共298兲
共307兲
共230兲
共444兲
共536兲
共298兲
共313兲
共328兲
共343兲
共368兲
共367兲
共367兲
共359兲
共379兲
共402兲
共352兲
EB
EB
EB
EB
CGC
EB
A
A
A
C
C
C
C
C
EB, IPM
EB
C
C
C
MG
43.2⫾0.1
40.9⫾0.1
38.6⫾0.1
36.1⫾0.2
40.1
37.7
36.8
44.6⫾0.1
43.6⫾0.1
42.7⫾0.1
42.0⫾0.1
40.4⫾0.1
41.3
41.3
40.2⫾0.1
38.9⫾0.1
37.4⫾0.1
41.0
共320兲
共360兲
共400兲
共440兲
共389兲
共465兲
共576兲
共298兲
共313兲
共328兲
共343兲
共368兲
共362兲
共362兲
共372兲
共393兲
共417兲
共369兲
EB
EB
EB
EB
A
A
A
C
C
C
C
C
EB, IPM
EB
C
C
C
MG
43.4⫾0.1
41.1⫾0.1
38.8⫾0.1
36.2⫾0.2
44.7
41.4
42.1
40.0
37.9
37.2
44.9⫾0.1
43.9⫾0.1
42.9⫾0.1
42.1⫾0.1
44.8⫾0.1
41.4
41.3
共320兲
共360兲
共400兲
共440兲
共298兲
共363兲
共347兲
共396兲
共467兲
共579兲
共298兲
共313兲
共328兲
共343兲
共298兲
共363兲
共365兲
EB
EB
EB
EB
CGC
A
A
A
A
A
C
C
C
C
C
EB, IPM
MG
44.9⫾0.1
共298兲
C
40.5
共319兲
A
CAS registry number
Reference
关62/7兴
关109-06-8兴
关99/24兴
关99/24兴
关99/24兴
关99/24兴
关95/21兴
关90/6兴
关87/5兴
关87/5兴
关87/5兴
关84/4兴
关84/4兴
关84/4兴
关84/4兴
关84/4兴
关87/5兴关68/4兴
关87/5兴关63/11兴
关63/11兴
关63/11兴
关63/11兴
关53/4兴
关108-99-6兴
关99/24兴
关99/24兴
关99/24兴
关99/24兴
关87/5兴
关87/5兴
关87/5兴
关84/4兴
关84/4兴
关84/4兴
关84/4兴
关84/4兴
关87/5兴关68/4兴
关87/5兴关63/12兴
关63/12兴
关63/12兴
关63/12兴
关53/4兴
关108-89-4兴
关99/24兴
关99/24兴
关99/24兴
关99/24兴
关95/21兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关84/4兴
关84/4兴
关84/4兴
关84/4兴
关81/8兴
关87/5兴关68/4兴
关53/4兴
关26555-56-5兴
关70/21兴
关1628-89-3兴
关87/5兴
关694-85-9兴
ENTHALPIES OF VAPORIZATION
625
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H7 NS
C6 H8
C6 H8
C6 H8
C6 H8
C6 H8 ClN
C6 H8 ClN
C6 H8 Cl2 O4
C6 H8 N2
C6 H8 N2
C6 H8 N2
C6 H8 N2
C6 H8 N2
C6 H8 N2
C6 H8 N2
C6 H8 O
C6 H8 O
C6 H8 O2
C6 H8 O3
C6 H8 O3
C6 H8 O4
C6 H8 O4
C6 H8 S
C6 H8 S
C6 H8 S
C6 H8 S
C6 H8 S
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共353–399兲
60.2
4-共methylthio兲pyridine
共346 –383兲
55.8
cis, anti, cis-tricyclo关 3.1.0.02,4兴 hexane
共273–329兲
30.6
共273–329兲
29.7
1,3-cyclohexadiene
共307–364兲
32.6
共304 –322兲
32.4
1,4-cyclohexadiene
共304 –360兲
34.0
共304 –322兲
33.9
cis 1,3,5-hexatriene
共306 –323兲
33.3
3-methylpyridine hydrochloride
共420– 471兲
68.7
4-methylpyridine hydrochloride
共437– 473兲
64.7
ethylene glycol, bis chloroacetate
共385–557兲
73.9
2,5-dimethylpyrazine
共303– 411兲
44.5
adiponitrile
共348 –523兲
58.7
2-methylaminopyridine
共308 –323兲
49.0
3-methylaminopyridine
共313–343兲
57.2
4-methylaminopyridine
共313–343兲
54.1
1,3-diaminobenzene
共372–559兲
63.7
phenyl hydrazine
共413–518兲
57.3
共345–517兲
59.2
共378 – 465兲
57.2
2-cyclohexen-1-one
共335– 481兲
49.5⫾0.4
2,5-dimethylfuran
共271–308兲
32.3⫾0.3
共271–308兲
31.8⫾0.3
methyl bicyclo关1.1.0兴butane-1-carboxylate
共299–377兲
37.3
2,2-dimethylsuccinic acid anhydride
共334 – 493兲
57.3
2-methylglutaric acid anhydride
共366 –556兲
60.7
dimethyl fumarate
共361– 466兲
53.8
dimethyl maleate
共385– 421兲
52.0
共318 – 478兲
53.9
2,3-dimethylthiophene
共353– 473兲
39.4
2,4-dimethylthiophene
共323– 493兲
41.4
Mean temperature
(T m /K)
Method
共368兲
A
共361兲
A
共293兲
共313兲
共322兲
共313兲
A, EB
MM
共319兲
共313兲
A
MM
共314兲
A, MM
共435兲
A
共452兲
A
共400兲
A
共357兲
共363兲
A
共316兲
A
共326兲
A
共328兲
A
共387兲
A
共428兲
共360兲
共393兲
A
共298兲
EB
共290兲
共298兲
GS
GS
共318兲
BG
共349兲
A
共381兲
A
共376兲
A
共400兲
共334兲
A
共368兲
A
共338兲
A
T
2,5-dimethylthiophene
共333–374兲
39.7
共348兲
I, A
3,4-dimethylthiophene
共328 – 478兲
41.1
共343兲
A
2-ethylthiophene
CAS registry number
Reference
关87/5兴
关22581-72-2兴
关87/5兴
关79/3兴
关79/3兴
关592-57-4兴
关87/5兴关73/12兴
关74/4兴
关628-41-1兴
关87/5兴
关74/4兴
关2612-46-6兴
关87/5兴关74/4兴
关14401-92-4兴
关87/5兴
关14401-93-5兴
关87/5兴
关6941-69-1兴
关87/5兴关47/5兴
关123-32-0兴
关95/4兴
关111-69-3兴
关87/5兴
关4597-87-9兴
关87/5兴
关18364-47-1兴
关87/5兴
关1121-58-0兴
关87/5兴
关108-45-2兴
关87/5兴关47/5兴
关100-63-0兴
关87/5兴关72/20兴
关47/5兴
关42/4兴
关930-68-7兴
关97/8兴
关625-36-3兴
关98/2兴
关98/2兴
关4935-01-7兴
关71/2兴
关17347-61-4兴
关87/5兴关47/5兴
关31468-33-4兴
关87/5兴关47/5兴
关624-49-7兴
关87/5兴
关624-48-6兴
关87/5兴
关47/5兴
关632-16-6兴
关87/5兴关72/20兴
关638-00-6兴
关87/5兴关72/20兴
关99/16兴
关638-02-8兴
关87/5兴关71/3兴
关99/16兴
关632-15-5兴
关87/5兴关72/20兴
关99/16兴
关872-55-9兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
626
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共333–374兲
C6 H8 S
C6 H9 F3 O2
C6 H9 N
3-ethylthiophene
共318 – 473兲
butyl trifluoroacetate
共343–377兲
cyclopentanecarbonitrile
共340– 418兲
C6 H9 N
C6 H9 NO2
C6 H9 P
C6 H10
C6 H10
2,5-dimethylpyrrole
共373– 443兲
ethyl 2-cyanopropionate
共283–323兲
trivinylphosphine
共289–334兲
cis bicyclo关3.1.0兴hexane
共273–300兲
cyclohexene
共312–356兲
共285–357兲
共309–365兲
共305–322兲
C6 H10
共285–357兲
共229–292兲
1-methylcyclopentene
C6 H10
共268 – 403兲
3-methylcyclopentene
C6 H10
C6 H10
C6 H10
C6 H10
C6 H10
C6 H10
C6 H10
C6 H10
C6 H10
C6 H10Br2
共263–392兲
4-methylcyclopentene
共271– 403兲
1,3-dimethylcyclobutene
共269–296兲
2,3-dimethyl-1,3-butadiene
共273–342兲
trans 1,3-hexadiene
共299–319兲
trans 1,4-hexadiene
共304 –323兲
1,5-hexadiene
共299–333兲
共300–319兲
共273–333兲
trans trans 2,4-hexadiene
共304 –354兲
共305–323兲
1-hexyne
共250–290兲
共237–287兲
共265–391兲
3-hexyne
共253–354兲
共253–298兲
trans 1,2-dibromocyclohexane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
39.7
共348兲
I, A
40.7
共333兲
A
37.8
共358兲
A, EB
48.1⫾0.1
43.4⫾0.1
40.9
43.5⫾0.1
共298兲
共298兲
共359兲
共298兲
C
BG
C
49.5
共388兲
A, IPM, EB
58.6⫾0.3
共298兲
GS
33.7
共304兲
33.7
33.5⫾0.4
共286兲
共298兲
32.6
33.5⫾0.5
32.7
33.1
32.7⫾0.1
32.2⫾0.1
31.7⫾0.1
31.2⫾0.1
30.7⫾0.1
33.7
32.6
共327兲
共298兲
共324兲
共308兲
共313兲
共323兲
共333兲
共343兲
共353兲
共300兲
共300兲
EB
A, EB
MM
C
C
C
C
C
MM
32.6⫾0.2
33.4
共298兲
共283兲
GCC
A
31.0⫾0.2
32.1
共298兲
共278兲
GCC
A
33.2
共286兲
A
31.3
共282兲
A
32.2
共288兲
A
32.1
共309兲
A, MM
30.2
共313兲
A, MM
29.4
28.6
30.5
共314兲
共308兲
共288兲
A
33.2
33.2
共319兲
共308兲
A
MM
33.5
34.2
33.4
共270兲
共262兲
共280兲
MM
HSA
A
30.5
31.6
共268兲
共275兲
A
T
A
A
CAS registry number
Reference
关87/5兴关71/3兴
关99/16兴
关1795-01-3兴
关87/5兴关72/20兴
关367-64-6兴
关87/5兴关69/13兴
关4254-02-8兴
关83/6兴
关73/6兴
关71/2兴
关70/21兴
关625-84-3兴
关87/5兴关68/4兴
关1572-99-2兴
关95/11兴
关3746-01-8兴
关57/15兴关84/9兴
关285-58-5兴
关87/5兴
关70/30兴
关110-83-8兴
关01/12兴
关96/4兴
关87/5兴关73/12兴
关74/4兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关50/6兴
关41/6兴
关693-89-0兴
关79/17兴
关87/5兴关72/20兴
关1120-62-3兴
关79/17兴
关87/5兴关72/20兴
关1759-81-5兴
关87/5兴关72/20兴
关1489-61-8兴
关87/5兴
关513-81-5兴
关87/5兴关55/3兴
关592-48-3兴
关87/5兴关74/4兴
关7319-00-8兴
关87/5兴关74/4兴
关592-42-7兴
关87/5兴
关74/4兴
关87/5兴关55/3兴
关72/20兴
关5194-51-4兴
关87/5兴
关74/4兴
关693-02-7兴
关81/19兴
关81/19兴
关87/5兴关72/20兴
关764-35-2兴
关87/5兴
关65/13兴
关7429-37-0兴
ENTHALPIES OF VAPORIZATION
627
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H10ClFO2
C6 H10ClF3 O
C6 H10Cl2
C6 H10Cl2
C6 H10Cl2
C6 H10Cl2
C6 H10Cl2 O2
C6 H10F2 O2
C6 H10O
C6 H10O
C6 H10O
C6 H10O
Compound
共Temperature range/K兲
C6 H10O
C6 H10O
C6 H10O
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共365兲
A
关87/5兴
共288兲
A
共298兲
共313兲
共328兲
共343兲
C
C
C
C
共350兲
A
关87/5兴关72/20兴
关358-36-1兴
关84/2兴
关84/2兴
关84/2兴
关84/2兴
关2108-92-1兴
关87/5兴
关10498-35-8兴
共379兲
A
共359兲
A
共368兲
A
共316兲
A
关87/5兴
关822-86-6兴
关87/5兴
关19398-57-3兴
关87/5兴
关37079-08-6兴
关87/5兴关47/5兴
共288兲
A
关87/5兴关72/20兴
共294兲
共298兲
GS
GS
共319兲
A
36.8
共354兲
A
46.2
46.9
46.7
44.0
44.4⫾0.1
44.0⫾0.1
43.4⫾0.1
43.1⫾0.1
42.2⫾0.1
41.8⫾0.1
41.4⫾0.1
42.3⫾0.2
42.2
40.4
41.5
45.1⫾0.1
40.3
共298兲
共298兲
共298兲
共333兲
共308兲
共313兲
共323兲
共328兲
共338兲
共343兲
共348兲
CGC
CGC
CGC
42.1⫾0.1
39.4⫾0.2
36.6⫾0.3
33.5⫾0.6
34.6
共320兲
共360兲
共400兲
共440兲
共464兲
关98/2兴
关98/2兴
关12655-16-2兴
关87/5兴关68/16兴
关84/9兴
关35656-02-1兴
关87/5兴
关108-94-1兴
关95/21兴
关95/21兴
关95/21兴
关93/2兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关89/16兴
关87/7兴
关84/19兴
关87/5兴关73/12兴
关68/17兴
关38/6兴
关109-49-9兴
关02/21兴
关02/21兴
关02/21兴
关02/21兴
关87/5兴
共350– 416兲
53.3
3-fluorobutyric acid, 2-chloroethyl ester
共273–333兲
60.4
2-chloro-1,1,2-trifluoroethyl butyl ether
45.1⫾0.1
43.9⫾0.1
42.8⫾0.1
41.6⫾0.1
1,1-dichlorocyclohexane
共335– 444兲
43.5
cis
1,2-dichlorocyclohexane
共364 – 480兲
45.8
trans 1,2-dichlorocyclohexane
共344 – 462兲
45.8
1,4-dichlorocyclohexane
共353– 406兲
47.8
isobutyl dichloroacetate
共301– 456兲
51.4
3-fluorobutyric acid, 2-fluoroethyl ester
共273–333兲
54.8
cyclopentenyl methyl ether
共274 –313兲
42.3⫾0.8
共274 –313兲
42.1⫾0.8
2,3-dihydro-4-methyl-2H-pyran
共304 –392兲
38.1
methylenetetrahydro-2H-pyran
共339–382兲
cyclohexanone
共343–383兲
共343–383兲
共343–383兲
共318 – 428兲
共345– 458兲
共395– 426兲
共362– 439兲
C6 H10O
⌬ vapH m
共kJ mol⫺1兲
共273–298兲
5-hexen-2-one
共317– 440兲
共317– 440兲
共317– 440兲
共317– 440兲
共449–561兲
mesityl oxide
C
C
C
C
C
C
C
GC
EB
共360兲
共410兲
共377兲
共298兲
共286兲
A, EB
C
EB
EB
EB
EB
A
35.2
共401兲
关Note: May be a mixture of 2-methyl-1-penten-4-one and 4-methyl-3-penten-2-one兴
2-methyl-1-penten-4-one
共389– 461兲
36.9
共404兲
共286 – 461兲
41.9
共298兲
共306 –398兲
41.1
共321兲
MM
4-methyl-3-penten-2-one
共303– 442兲
共303– 442兲
EB
EB
42.7⫾0.3
41.4⫾0.3
共298兲
共320兲
关1898/2兴关97/18兴
A
关3744-02-3兴
关87/5兴
关75/8兴
关87/5兴关47/9兴
关72/20兴
关141-79-7兴
关97/18兴
关97/18兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
628
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共303– 442兲
共303– 442兲
共303– 442兲
共343–383兲
共399– 471兲
共292– 471兲
共313– 405兲
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O2
C6 H10O3
C6 H10O3
C6 H10O3
C6 H10O3
C6 H10O3
C6 H10O3
C6 H10O4
C6 H10O4
C6 H10O4
C6 H10O4
C6 H10O4
C6 H10O4
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
39.1⫾0.3
36.5⫾0.3
33.5⫾0.6
44.8
37.8
43.3
41.5
共360兲
共400兲
共440兲
共298兲
共414兲
共298兲
共328兲
Method
EB
EB
EB
CGC
A
MM
methyl cyclobutanecarboxylate
44.2⫾0.2
44.7⫾0.1
共319–378兲
41.4
cyclopropanecarboxylic acid ethyl ester
共278 –308兲
44.0⫾0.5
allyl glycidyl ether
共323– 420兲
47.0
butyric acid, vinyl ester
共365–387兲
39.3
4-vinyl-1,3-dioxane
共306 – 416兲
54.5
caprolactone
共395– 436兲
54.0⫾0.2
共395– 436兲
62.0⫾1.3
ethyl crotonate
共329– 420兲
47.1
ethyl methacrylate
共285–390兲
38.3
5,5-dimethyldihydro-2(3H)-furanone
共311– 480兲
52.7
propyl acrylate
共287–395兲
37.9
2,5-hexanedione
共386 – 474兲
50.1
cis/trans 2,5-dimethoxy-2,5-dihydrofuran
44.2⫾0.3
cyclohexene ozonide
共276 –311兲
74.2
共353– 403兲
58.6
ethyl acetoacetate
共301– 454兲
52.5
methyl levulinate
共312– 471兲
50.4
51.1
propionic anhydride
共293– 440兲
48.2
共341– 440兲
52.2
ethyl 3-oxobutanoate
54.2⫾1.0
55.0
1,1-diacetoxyethane
共343– 438兲
49.7
2-acetoxypropionic acid, methyl ester
共337– 445兲
52.9
3-acetoxypropionic acid, methyl ester
共343–358兲
68.0
diethyl oxalate
共343– 457兲
53.9
共320– 459兲
62.3
dimethyl succinate
共340– 470兲
49.3
ethylene glycol diacetate
共311– 464兲
55.2
61.0⫾0.1
共373– 463兲
57.6
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共298兲
共340兲
GS
C
BG
GS
共338兲
A
共376兲
A
共321兲
A
共415兲
共298兲
EB
EB
共344兲
A
共300兲
A
共326兲
A
共302兲
A
共401兲
A
共298兲
CGC
共291兲
共378兲
A
共316兲
A
共327兲
共410兲
A
共308兲
共356兲
A
共298兲
C
共358兲
A
共352兲
A
共350兲
A
共358兲
共335兲
A
A
共364兲
A
共326兲
共298兲
共388兲
A
C
CAS registry number
Reference
关97/18兴
关97/18兴
关97/18兴
关95/21兴
关87/5兴
关75/4兴
关87/5兴关47/9兴
关72/20兴
关765-85-5兴
关98/22兴
关83/6兴
关71/2兴
关98/22兴
关106-92-3兴
关87/5兴
关123-20-6兴
关87/5兴
关1072-96-4兴
关87/5兴
关502-44-3兴
关91/7兴
关91/7兴
关10544-63-5兴
关87/5兴
关97-63-2兴
关87/5兴
关3123-97-5兴
关87/5兴
关925-60-0兴
关87/5兴
关110-13-4兴
关87/5兴
关00/9兴
关284-22-0兴
关87/5兴
关77/9兴
关141-97-9兴
关87/5兴
关624-45-3兴
关87/5兴关47/5兴
关31/1兴
关123-62-6兴
关87/5兴
关1883/1兴
关141-97-9兴
关95/6兴
关75/39兴
关542-10-9兴
关87/5兴
关6284-75-9兴
关87/5兴
关38003-42-8兴
关87/5兴
关95-92-1兴
关87/5兴
关87/5兴关47/5兴
关106-65-0兴
关87/5兴
关111-55-7兴
关87/5兴
关70/17兴
关26/5兴关84/9兴
ENTHALPIES OF VAPORIZATION
629
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H10O4
C6 H10O4
C6 H10O5
C6 H10O5
C6 H10O5
C6 H10O6
C6 H10O6
C6 H10S
C6 H11Br
C6 H11BrO2
C6 H11Cl
C6 H11Cl
C6 H11ClO
C6 H11ClO
C6 H11ClO2
C6 H11ClO2
C6 H11F
C6 H11FO2
C6 H11I
C6 H11N
C6 H11N
C6 H11NO
C6 H11NO
C6 H11NO
Compound
共Temperature range/K兲
dimethyl methylmalonate
共278 –308兲
adipic acid
共432– 611兲
共l兲 glucosane
共468 –528兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
57.8⫾0.8
共293兲
GS
92.0
共447兲
A
92.2
共483兲
A
共363兲
A
共373兲
A
共337兲
共390兲
A, ME
共388兲
A
共278兲
共278兲
A
共l兲 malic acid, dimethyl ester
共348 –516兲
58.7
methyl关1-共methxoycarbonyl兲ethyl兴carbonate
共358 – 483兲
55.9
共d兲 dimethyl tartrate
共322–365兲
76.4
共375–553兲
66.0
(dl) dimethyl tartrate
共373–555兲
62.5
diallyl sulfide
共263– 411兲
46.6
共263– 412兲
43.2
bromocyclohexane
共347– 439兲
42.8
ethyl 2-bromo-2-methylpropionate
共283– 437兲
45.4
chlorocyclohexane
共313–353兲
41.8
40.7⫾0.1
42.9⫾0.6
共350– 416兲
39.3
1-chloro-1-methylcyclopentane
39.7⫾0.1
diethylacetyl chloride
共313– 412兲
39.4
3-ethyl-3-共chloromethyl兲oxetane
49.7⫾0.2
chloroacetic acid, sec-butyl ester
共290– 441兲
49.6
chloroacetic acid, isobutyl ester
共293–323兲
43.9
fluorocyclohexane
共271–301兲
37.5⫾0.3
共316 –373兲
35.0
2-fluorohexanoic acid
共387– 411兲
80.9
iodocyclohexane
共313–353兲
48.3
共358 – 408兲
43.0
hexanenitrile
共371– 442兲
43.3
共344 – 441兲
44.6
4-methylvaleronitrile
共332– 430兲
35.7
cyclohexanone oxime
共370–385兲
63.1⫾1.0
58.7⫾0.6
共371– 446兲
59.5⫾0.5
⑀-caprolactam
共350–568兲
69.2⫾0.3
共350–568兲
65.7⫾0.3
共350–568兲
62.3⫾0.2
共350–568兲
59.0⫾0.2
共350–568兲
55.7⫾0.3
共350–568兲
52.4⫾0.5
共373–543兲
62.3
cis 2-hexenoic acid amide
共362兲
共298兲
A
共298兲
共298兲
共298兲
共365兲
CGC
C
C
A
共297兲
C
共328兲
A
共298兲
C
共305兲
A
共308兲
A
共298兲
共331兲
GS
A
共399兲
A
共298兲
共383兲
CGC
A, I
共386兲
共359兲
A, EB
EB
共347兲
A
共378兲
共368兲
EB
C
共360兲
共400兲
共440兲
共480兲
共520兲
共560兲
共388兲
EB
EB
EB
EB
EB
EB
A
CAS registry number
Reference
关92/13兴
关124-04-9兴
关87/5兴关47/5兴
关498-07-7兴
关87/5兴关64/1兴
关72/20兴
关617-55-0兴
关87/5兴关47/5兴
关87/5兴
关608-68-4兴
关87/5兴关54/6兴
关47/5兴
关609-69-5兴
关87/5兴关47/5兴
关592-88-1兴
关99/16兴
关87/5兴关47/5兴
关108-85-0兴
关97/15兴
关600-00-0兴
关87/5兴关47/5兴
关542-18-7兴
关95/21兴
关95/18兴
关94/20兴
关87/5兴
关6196-85-6兴
关97/20兴
关2736-40-5兴
关87/5兴
关2177-22-2兴
关71/25兴
关17696-64-9兴
关87/5兴
关13361-38-8兴
关87/5兴
关372-46-3兴
关97/14兴
关87/5兴
关1578-57-0兴
关87/5兴
关626-62-0兴
关95/21兴
关87/5兴关56/26兴
关628-73-9兴
关87/5兴关73/12兴
关71/4兴
关542-54-1兴
关87/5兴
关100-64-1兴
关02/20兴
关92/6兴
关92/6兴
关105-60-2兴
关02/17兴
关02/17兴
关02/17兴
关02/17兴
关02/17兴
关02/17兴
关87/5兴
关820-99-5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
630
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H11NO
C6 H11NO
C6 H11NO2
C6 H11NO2
C6 H11NO2
C6 H11NO3
C6 H11NS
C6 H11NS
C6 H12
C6 H12
C6 D12
C6 H12
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共343–383兲
61.7
1-methyl-2-piperidone
共341–385兲
55.4
2,3,4,5-tetrahydro-6-methoxypyridine
共292–338兲
42.8
nitrocyclohexane
共298 –318兲
54.7⫾0.6
1-aminocyclopentanecarboxylic acid
共443– 468兲
123.3
lactic acid N-allyl amide
共359– 419兲
78.2
ethyl acetamidoacetate
共383– 466兲
69.4
2-piperidinethione
共363–370兲
63.3
2,3,4,5-tetrahydro-共methylthio兲pyridine
共313–351兲
52.6
ethylcyclobutane
31.2⫾0.2
32.6⫾0.8
cyclohexane
共300–345兲
32.7
共360– 470兲
32.2
共313–336兲
31.9
共313–336兲
33.1
32.3
31.1
30.3
30.0
共353– 414兲
30.9
共412– 491兲
29.6
共489–553兲
29.6
33.0⫾0.1
33.0
33.0⫾0.1
32.3⫾0.1
31.2⫾0.1
31.0⫾0.1
30.4⫾0.1
30.1⫾0.1
32.2⫾0.1
31.9⫾0.1
31.1⫾0.1
30.6⫾0.1
30.1⫾0.1
32.9⫾0.3
32.9
33.0
共303–343兲
32.5
共298 –348兲
32.9
共316 –354兲
32.8
31.4⫾0.1
30.4⫾0.1
33.0
30.1
共293–355兲
32.9
33.3⫾0.1
33.5
cyclohexane-d12
共283–353兲
33.1
methylcyclopentane
31.6
31.3⫾0.1
30.2⫾0.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共358兲
A
共356兲
A
共307兲
A
共298兲
GS
共455兲
A
共374兲
A
共398兲
A
共366兲
A
共328兲
A
共298兲
共298兲
C
EB
共315兲
共375兲
共324兲
共298兲
共314兲
共332兲
共345兲
共355兲
共368兲
共427兲
共504兲
共298兲
共298兲
共298兲
共313兲
共333兲
共338兲
共348兲
共353兲
共313兲
共323兲
共333兲
共343兲
共354兲
共298兲
共298兲
共298兲
共318兲
共313兲
共331兲
共324兲
共346兲
共298兲
共354兲
共308兲
共298兲
共298兲
EB
EB
C
C
C
C
A
A
A
C
C
C
C
C
C
C
C
C
C
C
C
ME
C
C
C
A, MM
C
共298兲
共298兲
共304兲
共326兲
C
C
CAS registry number
Reference
关87/5兴
关931-20-4兴
关87/5兴
关5693-62-9兴
关87/5兴
关1122-60-7兴
关97/5兴
关52-52-8兴
关87/5兴
关87/5兴
关1906-82-7兴
关87/5兴关72/20兴
关13070-07-0兴
关87/5兴
关19766-29-1兴
关87/5兴
关4806-61-5兴
关83/6兴
关74/3兴
关110-82-7兴
关02/45兴
关93/3兴
关95/9兴
关95/9兴
关88/19兴
关88/19兴
关88/19兴
关88/19兴
关87/5兴
关87/5兴
关87/5兴
关82/18兴
关81/12兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关73/13兴
关72/33兴
关71/7兴
关71/28兴
关68/6兴
关67/21兴
关65/9兴
关51/2兴
关51/2兴
关47/7兴
关46/11兴
关87/5兴关45/2兴
关43/5兴
关27/3兴
关1735-17-7兴
关53/10兴
关96-37-7兴
关71/28兴
关59/8兴
关59/8兴
ENTHALPIES OF VAPORIZATION
631
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
C6 H12
Compound
共Temperature range/K兲
共288 –346兲
1-hexene
共300–337兲
共273–343兲
共289–337兲
共289–337兲
cis 2-hexene
共278 –343兲
共298 –342兲
trans 2-hexene
共283–342兲
共292–341兲
cis 3-hexene
共276 –348兲
共185–340兲
trans 3-hexene
共278 –341兲
共291–341兲
2-methyl-1-pentene
共272–341兲
共300–335兲
3-methyl-1-pentene
共265–333兲
共287–328兲
4-methyl-1-pentene
共310–360兲
共310–360兲
共310–360兲
共310–360兲
共265–333兲
共287–328兲
2-methyl-2-pentene
共277–346兲
共292–341兲
cis 3-methyl-2-pentene
共277–347兲
共300–344兲
trans 3-methyl-2-pentene
共280–349兲
共292–341兲
cis 4-methyl-2-pentene
共267–330兲
共300–330兲
trans 4-methyl-2-pentene
共269–337兲
共291–332兲
2,3-dimethyl-1-butene
共267–335兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
29.1⫾0.1
31.6⫾0.1
31.9
共345兲
共298兲
共303兲
C
C
A, MM
30.6
31.6
30.6
30.6
31.0
共315兲
共288兲
共298兲
共298兲
共304兲
32.2
31.5
31.5
共293兲
共298兲
共298兲
A
32.2
31.6
31.5
共298兲
共298兲
共298兲
A
32.1
31.3
31.3
共291兲
共298兲
共298兲
A
32.3
31.6
31.5
共293兲
共298兲
共298兲
A
31.6
30.5
30.5
共287兲
共298兲
共298兲
A
30.0
28.6
28.6
共280兲
共298兲
共298兲
A
28.6⫾0.2
27.4⫾0.3
26.2⫾0.4
24.9⫾0.5
30.1
28.7
28.7
共298兲
共320兲
共340兲
共360兲
共280兲
共298兲
共298兲
EB
EB
EB
EB
A
32.4
31.6
31.6
共292兲
共298兲
共298兲
A
32.2
31.3
32.1
共292兲
共298兲
共298兲
A
32.8
32.1
31.3
共295兲
共298兲
共298兲
A
30.8
29.5
29.5
共282兲
共298兲
共298兲
A
31.2
30.0
30.0
共284兲
共298兲
共298兲
A
30.5
29.2
共282兲
共298兲
A
A
MM
CAS registry number
Reference
关59/8兴
关47/7兴
关87/5兴关45/2兴
关592-41-6兴
关01/12兴
关87/5兴
关71/28兴
关56/9兴
关50/6兴
关7688-21-3兴
关87/5兴
关71/28兴
关56/9兴
关4050-45-7兴
关87/5兴
关71/28兴
关56/9兴
关7642-09-3兴
关87/5兴
关71/28兴
关56/7兴
关13269-52-8兴
关87/5兴
关71/28兴
关56/7兴
关763-29-1兴
关87/5兴
关71/28兴
关56/9兴
关760-20-3兴
关87/5兴
关71/28兴
关56/9兴
关691-37-2兴
关97/18兴
关97/18兴
关97/18兴
关97/18兴
关87/5兴
关71/28兴
关56/7兴
关625-27-4兴
关87/5兴
关71/28兴
关56/7兴
关922-62-3兴
关87/5兴
关71/28兴
关56/9兴
关616-12-6兴
关87/5兴
关71/28兴
关56/9兴
关691-38-3兴
关87/5兴
关71/28兴
关56/9兴
关674-76-0兴
关87/5兴
关71/28兴
关56/9兴
关563-78-0兴
关87/5兴
关71/28兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
632
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H12
C6 H12
Compound
共Temperature range/K兲
共289–329兲
3,3-dimethyl-1-butene
共254 –316兲
共281–315兲
2,3-dimethyl-2-butene
共289–347兲
共282–348兲
C6 H12
C6 H12Br2
C6 H12ClNO
C6 H12Cl2
C6 H12Cl2
C6 H12Cl2
C6 H12Cl2 O
C6 H12Cl2 O2
C6 H12Cl3 N
C6 H12Cl3 O4 P
C6 H12F2
C6 H12F3 OP
C6 H12F3 PS
C6 H12F4 N2
C6 H12N2
C6 H12N2 O
C6 H12N2 OS
C6 H12N2 O2
C6 H12N2 O6
C6 H12N2 O8
C6 H12N2 S2
C6 H12O
2-ethyl-1-butene
共289–338兲
1,1-dibromohexane
共378 –526兲
4-共2-chloroethyl兲morpholine
共273–333兲
1,1-dichlorohexane
共330– 440兲
共345– 484兲
(dl) 1,2-dichlorohexane
共350– 440兲
共352– 442兲
1,6-dichlorohexane
共380– 480兲
bis共2-chloro-1-methylethyl兲 ether
共302– 456兲
bis共2-chloroethyl兲acetaldehyde acetal
共329– 486兲
tris共2-chloroethyl兲amine
共273–333兲
tris共2-chloroethyl兲phosphate
共293– 445兲
1,1-difluorohexane
共290– 407兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
29.2
共298兲
28.6
26.6
26.6
共269兲
共298兲
共298兲
32.6
32.5
33.1
32.9⫾0.1
32.0⫾0.1
30.9⫾0.1
29.7⫾0.1
共298兲
共298兲
共297兲
共292兲
共308兲
共326兲
共346兲
31.0
共298兲
51.6
共393兲
A, EST
53.8
共288兲
A
48.7
45.1
共298兲
共360兲
A, EST
48.8
44.9
47.9⫾0.7
共298兲
共367兲
共298兲
A
EB
56.3
共298兲
53.6
共317兲
A
59.4
共344兲
A
65.0
共288兲
A, GS
36.7
共308兲
A
37.7
共305兲
A, EST
methyl 共trifluoromethyl兲phosphinous acid, tert-butyl ester
共273–329兲
39.7
methyl 共trifluoromethyl兲phosphinothious acid, tert-butyl ester
共296 –337兲
43.2
N,N,N⬘,N⬘-tetrafluoro-2-methyl-1,2-pentanediamine
共253–293兲
42.8
共diethylamino兲acetonitrile
共283–318兲
49.9⫾0.3
1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)pyrimidinone
共370–520兲
58.0
tetramethyl monothiooxamide
59
tetramethyloxamide
52.5
2,5-dinitroxyhexane
共293–313兲
54.4
triethylene glycol dinitrate
共303–348兲
88.3
tetramethyl dithiooxamide
60.5
(dl) 2,5-dimethyltetrahydrofuran
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
A
C
C
C
C
共296兲
CAS registry number
Reference
关56/9兴
关558-37-2兴
关87/5兴
关71/28兴
关56/9兴
关563-79-1兴
关56/9兴
关71/28兴
关87/5兴关55/3兴
关55/13兴
关55/13兴
关55/13兴
关55/13兴
关760-21-4兴
关56/9兴
关58133-26-9兴
关87/5兴关56/16兴
关72/20兴
关3240-94-6兴
关87/5兴关72/20兴
关62017-16-7兴
关87/12兴关91/2兴
关87/5兴关56/16兴
关72/20兴
关2162-92-7兴
关91/2兴
关87/5兴
关75/16兴
关2163-00-0兴
关88/11兴关91/2兴
关108-60-1兴
关87/5兴关47/5兴
关14689-97-5兴
关87/5兴关47/5兴
关555-77-1兴
关87/5兴关48/13兴
关72/20兴
关87/5兴关72/20兴
关62127-41-7兴
关87/5兴关56/16兴
关72/20兴
共400兲
EB
关70/26兴
关26348-87-8兴
关70/26兴
关16096-76-7兴
关87/5兴关63/9兴
关62/13兴
关3010-02-4兴
关97/10兴
关7226-23-5兴
关87/2兴
共508兲
TGA, DSC
关02/36兴
共460兲
TGA, DSC
关02/36兴
共303兲
B,GS
共318兲
A
共533兲
TGA, DSC
关57/5兴关72/20兴
关111-22-8兴
关87/5兴关72/20兴
关35840-78-9兴
关02/36兴
关100-38-9兴
共312兲
共278兲
A, IPM
GS
ENTHALPIES OF VAPORIZATION
633
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H12O
C6 H12O
C6 H12O
C6 H12O
C6 H12O
C6 H12O
C6 H12O
Compound
共Temperature range/K兲
共278 –370兲
1,2-epoxyhexane
共300–390兲
2-methyl-2,3-epoxypentane
共306 –369兲
allyl isopropyl ether
共253– 415兲
共229–353兲
allyl propyl ether
共261– 428兲
共234 –364兲
butyl vinyl ether
共311– 403兲
共353–393兲
共269–368兲
isobutyl vinyl ether
共266 –357兲
cyclohexanol
共390– 430兲
共341– 471兲
共323–373兲
共350– 456兲
共318 – 434兲
共300– 434兲
共404 – 432兲
共303–373兲
共299–319兲
C6 H12O
C6 H12O
C6 H12O
C6 H12O
共307– 422兲
1-methylcyclopentanol
共354 – 407兲
5-hexen-1-ol
(dl) 3-methyl-2-pentanone
共286 – 400兲
共283–395兲
共385– 455兲
共283– 457兲
2-hexanone
共293– 411兲
共279– 423兲
共310– 427兲
共421–523兲
共513–587兲
共307– 482兲
C6 H12O
共280– 400兲
3-hexanone
共408 –517兲
共511–583兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
35.4
共293兲
A
43.1
共315兲
A
40.6
共321兲
A
36.1
36.8
共268兲
共244兲
A
A
37.5
36.4
共276兲
共249兲
A
A
36.7⫾0.2
36.5
36.1
共298兲
共298兲
共284兲
EB
CGC
A
37.4
共281兲
A
49.8
62.0⫾0.3
63.5⫾0.7
61.3
55.0
59.9
62.7
49.3
58.4
60.4
62.0⫾0.9
62.0⫾0.2
62.0⫾0.3
54.8
共405兲
共298兲
共298兲
共298兲
共365兲
共333兲
共315兲
共418兲
共318兲
共309兲
共298兲
共298兲
共298兲
共322兲
45.7
共369兲
A
60.2⫾0.1
58.0⫾0.1
55.7⫾0.1
共298兲
共343兲
共358兲
C
C
C
39.8
41.5
36.5
41.2
共301兲
共298兲
共400兲
共298兲
A
A
A
43.1⫾0.1
42.5⫾0.1
41.6⫾0.1
40.7⫾0.1
40.1⫾0.1
39.5⫾0.1
40.8
43.8
41.5
36.7
36.1
43.1⫾0.1
43.0⫾0.3
42.9
42.2⫾0.1
53.8
共298兲
共308兲
共323兲
共338兲
共348兲
共358兲
共308兲
共294兲
共325兲
共436兲
共528兲
共298兲
共298兲
共298兲
共298兲
共295兲
C
C
C
C
C
C
A
A
A
A
A
C
GCC
36.5
35.4
共423兲
共526兲
A
A
C
EB
CGC
EB
A
A
C
C
CAS registry number
Reference
关87/5兴
关1436-34-6兴
关87/5兴关69/21兴
关84/9兴
关1192-22-9兴
关87/5兴
关6140-80-3兴
关87/5兴
关87/5兴关47/5兴
关1471-03-0兴
关87/5兴
关87/5兴关47/5兴
关111-34-2兴
关96/5兴
关95/21兴
关87/5兴
关109-53-5兴
关87/5兴
关108-93-0兴
关02/9兴
关99/6兴
关97/8兴
关95/21兴
关87/7兴
关87/5兴
关87/5兴
关84/19兴
关84/27兴
关75/1兴
关75/1兴
关68/17兴
关66/2兴
关46/4兴
关1462-03-9兴
关87/5兴
关821-41-0兴
关96/9兴
关96/9兴
关96/9兴
关565-61-7兴
关87/5兴
关87/5兴
关87/5兴
关75/8兴
关591-78-6兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关83/3兴
关79/7兴
关75/8兴
关70/19兴
关47/5兴
关589-38-8兴
关87/5兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
634
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
40.6⫾0.1
42.3⫾0.3
38.9
42.3
42.2
41.9⫾0.2
38.4⫾0.1
37.0⫾0.1
35.4⫾0.1
38.8
共298兲
共298兲
共363兲
共298兲
共307兲
共298兲
共354兲
共374兲
共396兲
共364兲
37.8⫾0.1
37.5⫾0.1
36.9⫾0.1
36.7⫾0.1
35.8⫾0.1
35.4⫾0.1
35.0⫾0.1
36.9
34.9
33.8
33.1
38.3
38.3
37.9⫾0.1
共308兲
共313兲
共323兲
共328兲
共338兲
共343兲
共348兲
共326兲
共378兲
共411兲
共506兲
共304兲
共298兲
共298兲
C
C
C
C
C
C
C
A
A
A
A
A
40.1⫾0.1
39.0⫾0.1
38.0⫾0.1
37.4⫾0.1
39.2
42.5
37.0
42.5⫾0.1
41.0
41.2
共308兲
共323兲
共338兲
共348兲
共324兲
共296兲
共365兲
共298兲
共298兲
共309兲
C
C
C
C
43.4
41.0
36.2
40.5
39.8⫾0.2
共315兲
共295兲
共392兲
共298兲
共298兲
42.3⫾0.1
41.0
共298兲
共330兲
48.1⫾0.2
共298兲
C
42.9⫾0.2
共298兲
C
44.8⫾0.3
43.1⫾0.3
共298兲
GS
GS
45.3⫾0.3
共298兲
GS
39.3
共377兲
A
44.9⫾0.6
共298兲
GS
37.1
38.8
共348兲
共378兲
A
48.5
共368兲
A
共348 – 413兲
共292– 406兲
C6 H12O
共349– 406兲
3,3-dimethyl-2-butanone 共pinacolone兲
共311–381兲
共363– 400兲
共396 –509兲
共491–567兲
共289– 402兲
C6 H12O
共282– 456兲
共294 –390兲
2-methyl-3-pentanone
共300–387兲
共280–387兲
共377– 450兲
共280– 452兲
C6 H12O
hexanal
C6 H12OS
共315– 402兲
S-butyl thiolacetate
C6 H12OS
S-tert-butyl thiolacetate
C6 H12O2
2-ethyl-2-methyl-1,3-dioxolane
共274 –313兲
共274 –313兲
2-propyl-1,3-dioxolane
共278 –313兲
4-ethyl-1,3-dioxane
共362– 412兲
2,4-dimethyl-1,3-dioxane
共274 –313兲
4,4-dimethyl-1,3-dioxane
共333– 407兲
共363– 406兲
cis 4,5-dimethyl-1,3-dioxane
共353– 410兲
trans 4,5-dimethyl-1,3-dioxane
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C
GCC
A
A
C
C
C
C
GS, EB
C
4-methyl-2-pentanone
共309– 416兲
共281– 400兲
共349–389兲
C6 H12O
Method
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
EB
C
A
A
A
A
C
CAS registry number
Reference
关83/3兴
关79/7兴
关87/5兴关75/8兴
关75/8兴
关87/5兴关72/20兴
关70/19兴
关67/39兴
关67/39兴
关67/39兴
关65/7兴
关75-97-8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴关75/8兴
关75/8兴
关70/19兴
关108-10-1兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关88/6兴
关87/5兴
关85/12兴
关83/3兴
关75/8兴
关87/5兴关52/14兴
关565-69-5兴
关87/5兴
关87/5兴
关87/5兴
关75/8兴
关70/18兴
关66-25-1兴
关81/18兴
关79/15兴
关926-47-2兴
关66/2兴
关999-90-6兴
关66/2兴
关126-39-6兴
关02/32兴
关98/21兴
关3390-13-4兴
关98/21兴关02/29兴
关1121-61-5兴
关87/5兴
关766-20-1兴
关02/32兴
关766-15-4兴
关87/5兴关68/16兴
关69/8兴
关2391-24-4兴
关87/5兴
关1121-20-6兴
ENTHALPIES OF VAPORIZATION
635
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C6 H12O2
共353– 408兲
2-hydroxymethyltetrahydropyran
共344 – 460兲
1,1-dimethoxycyclobutane
共274 –313兲
共273–313兲
共301–348兲
关共1-methylethoxy兲methyl兴oxirane
C6 H12O2
共propoxymethyl兲oxirane
C6 H12O2
1,1-dimethoxy-3-butene
共305–334兲
butyl acetate
C6 H12O2
C6 H12O2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
39.1
共368兲
A
49.0
共359兲
A
42.0⫾0.3
42.3⫾0.3
42.6
共298兲
共325兲
GS
GS
EB
42.0
共320兲
EB
42.4
42.7
43.1
41.0⫾0.5
43.0⫾0.1
41.7⫾0.1
40.6⫾0.1
39.4⫾0.1
41.3
43.6⫾0.5
43.7⫾0.2
40.5
43.6⫾0.2
40.8
共298兲
共298兲
共298兲
共298兲
共313兲
共328兲
共343兲
共358兲
共341兲
共298兲
共298兲
共356兲
共298兲
共347兲
GC
CGC
CGC
GC
C
C
C
C
DTA
GCC
GCC
A, EB
C
A
37.5
共398兲
47.5
共316兲
52.1
51.0
共310兲
39.4
40.2
42.1⫾0.1
43.7⫾1.3
48.3
42.0⫾0.1
41.8
共345兲
共347兲
共323兲
共298兲
共278兲
共298兲
共270兲
36.0
39.8⫾0.1
44.1
共398兲
共298兲
共264兲
A
C
A
39.8
共267兲
A
38.0⫾0.2
共298兲
C
37.7
39.0⫾0.5
38.8
39.7⫾0.3
35.2
共298兲
共298兲
共298兲
共298兲
共319兲
CGC
GC
GCC
BG
38.9
共270兲
A
41.2
共269兲
A
41.3
43.7⫾0.2
共350兲
共298兲
43.5⫾2.1
48.5⫾0.4
C6 H12O2
共313–363兲
共313–353兲
共326 – 404兲
共341–399兲
共332–399兲
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
diacetone alcohol
共301–388兲
4-hydroxy-4-methyl-2-pentanone
共295– 441兲
ethyl butyrate
共330– 435兲
共332–393兲
共310–336兲
共310–336兲
共263– 404兲
共254 –394兲
ethyl isobutyrate
共383– 483兲
共249–393兲
isobutyl acetate
共252–391兲
tert-butyl acetate
methyl 2,2-dimethylpropanoate
共313–363兲
共299–356兲
isopentyl formate
共255–397兲
methyl isovalerate
共254 –390兲
methyl valerate
A, I
EB
EB
A
C
CAS registry number
Reference
关87/5兴
关100-72-1兴
关87/5兴
关4415-90-1兴
关02/32兴
关98/21兴
关94/16兴
关4016-14-2兴
关87/14兴
关3126-95-2兴
关87/14兴
关94/16兴
关123-86-4兴
关97/13兴
关95/21兴
关95/21兴
关87/17兴
关80/13兴
关80/13兴
关80/13兴
关80/13兴
关80/8兴
关80/5兴
关80/5兴
关87/5兴关69/13兴
关66/2兴
关87/5兴关64/24兴
关84/9兴
关61/23兴
关123-42-2兴
关87/5兴关52/14兴
关123-42-2兴
关75/39兴
关47/5兴
关105-54-4兴
关97/11兴
关93/8兴
关91/7兴
关91/7兴
关87/5兴
关66/2兴
关47/5兴
关97-62-1兴
关87/5兴
关66/2兴
关87/5兴关47/5兴
关110-19-0兴
关87/5兴关47/5兴
关540-88-5兴
关66/2兴关96/11兴
关598-98-1兴
关95/21兴
关87/17兴
关U/1兴关85/6兴
关80/5兴
关71/2兴
关110-45-2兴
关87/5兴
关556-24-1兴
关87/5兴关47/5兴
关624-24-8兴
关02/27兴
关02/27兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
636
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
42.5
43.3⫾0.5
46.1⫾0.3
44.1⫾0.1
43.1⫾0.1
共312兲
共298兲
共298兲
共298兲
共298兲
A
GC
GCC
GCC
C
37.6
39.9
43.1
42.1⫾0.1
41.1⫾0.1
40.0⫾0.1
38.8⫾0.1
共392兲
共351兲
共274兲
共313兲
共328兲
共343兲
共358兲
A
C
C
C
C
68.4⫾0.9
69.2⫾0.9
71.3
70.9
73.2⫾2.0
65.9
66.6
64.6
共313兲
共298兲
共298兲
共271兲
共298兲
共350兲
共386兲
共367兲
GS
GS
CGC
58.2
共388兲
A
91.7
共354兲
A
59.4⫾0.3
54.6⫾0.3
50.0⫾0.4
46.0⫾0.7
共370兲
共410兲
共450兲
共490兲
EB
EB
EB
EB
63.6⫾0.9
64.0⫾0.9
共304兲
共298兲
GS
GS
43.9
共363兲
MM
52.3
共316兲
A
41.5
41.4⫾0.4
共338兲
A
74.7
共338兲
A
46.1
共345兲
A
44.3
共335兲
A
50.9
52.7⫾0.1
52.6⫾0.4
共337兲
共298兲
共298兲
A
C
EB
60.9
共362兲
A
44.6
共328兲
A
52.1
共349兲
A
49.9⫾0.1
共298兲
C
75.8
共403兲
A
119.0⫾1.4
共519兲
TE
共297– 411兲
C6 H12O2
C6 H12O2
propyl propionate
共378 – 406兲
共336 –394兲
共259–396兲
hexanoic acid
共297–328兲
共297–328兲
共353–393兲
共270–280兲
共335– 487兲
共371– 452兲
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O2
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O3
C6 H12O4
C6 H12O6
C6 H12S
2-ethyl butyric acid
共373– 466兲
4-methylvaleric acid
共339– 481兲
2,2-dimethylbutanoic acid
共364 – 498兲
共364 – 498兲
共364 – 498兲
共364 – 498兲
3,3-dimethylbutanoic acid
共283–325兲
共283–325兲
1-hexene ozonide
共353–373兲
sec-butyl glycolate
共301– 451兲
2,4,6-trimethyl-1,3,5-trioxane
共323–396兲
glycerol 1-monoallyl ether
共323–383兲
2-ethoxyacetic acid, ethyl ester
共330– 430兲
3-ethoxypropionic acid, methyl ester
共320– 432兲
2-ethoxyethanol acetate
共322– 430兲
共330– 468兲
3-hydroxypropionic acid, propyl ester
共350–375兲
3-methoxypropionic acid, ethyl ester
共313– 432兲
propyl lactate
共334 – 442兲
ethoxymethyl propionate
(dl) glycerol 1-propionate
共388 – 456兲
myo-inositol
共497–524兲
cyclopentyl methyl sulfide
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
TE
A
I
CAS registry number
Reference
关87/5兴
关87/17兴
关80/5兴
关80/5兴
关77/1兴
关106-36-5兴
关94/15兴
关93/8兴
关87/5兴关47/5兴
关80/13兴
关80/13兴
关80/13兴
关80/13兴
关142-62-1兴
关00/6兴
关00/6兴
关95/21兴
关82/4兴
关79/4兴
关87/5兴关72/20兴
关57/16兴关84/9兴
关43/7兴
关88-09-5兴
关87/5兴
关646-07-1兴
关87/5兴
关595-37-9兴
关02/14兴
关02/14兴
关02/14兴
关02/14兴
关1070-83-3兴
关00/6兴
关00/6兴
关767-09-9兴
关77/9兴
关87/5兴关47/5兴
关123-63-7兴
关87/5兴
关59/23兴
关87/5兴关72/20兴
关817-95-8兴
关87/5兴
关14144-33-3兴
关87/5兴关72/20兴
关111-15-9兴
关87/5兴
关70/17兴
关66/3兴
关87/5兴
关10606-42-5兴
关87/5兴
关616-09-1兴
关87/5兴
关54078-53-4兴
关74/37兴
关624-47-5兴
关87/5兴关72/20兴
关90/16兴
关7133-36-0兴
ENTHALPIES OF VAPORIZATION
637
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H12S
C6 H12S
C6 H12S
C6 H12S
C6 H12S
C6 H12S
C6 H12S
C6 H13Br
C6 H12S
Compound
共Temperature range/K兲
C6 H13Br
C6 H13Cl
A, EB
共326兲
共364兲
A, EB
共363兲
EB
2-ethyltetrahydrothiophene
共333– 488兲
42.6
共348兲
A
3-ethyltetrahydrothiophene
共343–503兲
43.1
共358兲
A
42.1
40.2
共332兲
共371兲
A, EB
42.5
40.7
共336兲
共376兲
A, EB
42.8
40.8
共336兲
共376兲
A, EB
39.5
共330兲
A
44.9
44.6⫾0.1
41.2
共298兲
共298兲
共370兲
C
A, EB
45.5
46.1⫾0.1
45.6⫾0.1
43.2
共298兲
共298兲
共298兲
共348兲
CGC
C
C
A, EST
43.8
共318兲
A
29.3
共330兲
A
42.0
42.8⫾0.1
40.5⫾0.1
40.0⫾0.1
39.0⫾0.1
38.4⫾0.1
43.5
共298兲
共298兲
共328兲
共343兲
共358兲
共368兲
共303兲
C
C
C
C
C
A, DTA
42.8⫾0.1
共298兲
C
40.9
共315兲
A
38.0
共316兲
A
38.0
共315兲
A
60.7
61.7
57.2
共288兲
共318兲
共415兲
54.9
共288兲
2-methyltetrahydro-2H-thiopyrane
共317– 455兲
共356 – 438兲
3-methyltetrahydro-2H-thiopyrane
共321– 460兲
共361– 435兲
4-methyltetrahydro-2H-thiopyrane
共321– 461兲
共361– 441兲
2-bromo-3,3-dimethylbutane
共315– 449兲
cyclohexanethiol
1-bromohexane
共323–363兲
(dl) 2-bromohexane
共303– 416兲
2-bromo-4-methylpentane
共315– 448兲
1-chlorohexane
共290– 410兲
共288 – 409兲
C6 H13Cl
C6 H13Cl
C6 H13Cl
C6 H13ClO2 S
C6 H13Cl2 N
C6 H13F
Method
共298兲
共369兲
共333– 456兲
C6 H13Br
Mean temperature
(T m /K)
45.1⫾0.1
共354 – 473兲
41.7
cis 2,5-dimethyltetrahydrothiophene
共311– 444兲
41.7
共349– 427兲
39.7
trans 2,5-dimethyltetrahydrothiophene
共348 –396兲
39.3
共355– 476兲
C6 H13Br
⌬ vapH m
共kJ mol⫺1兲
(dl) 2-chlorohexane
共300–399兲
2-chloro-2,3-dimethylbutane
共301– 426兲
(dl) 2-chloro-3,3-dimethylbutane
共300– 425兲
1-hexanesulfonyl chloride
共273–304兲
共303– 400兲
共400–507兲
N-ethyl-bis共2-chloroethyl兲amine
共273–333兲
1-fluorohexane
A, GS
CAS registry number
Reference
关72/11兴关66/5兴
关87/5兴关66/5兴
关5161-13-7兴
关99/16兴
关87/5兴关52/9兴
关5161-14-8兴
关87/5兴关52/9兴
关99/16兴
关1551-32-2兴
关87/5兴关72/20兴
关99/16兴
关62184-67-2兴
关87/5兴关72/20兴
关99/16兴
关5161-16-0兴
关99/16兴
关87/5兴关52/9兴
关5258-50-4兴
关99/16兴
关87/5兴关52/9兴
关5161-17-1兴
关99/16兴
关87/5兴关52/9兴
关26356-06-9兴
关87/5兴关72/20兴
关1569-69-3兴
关81/8兴
关72/11兴关66/5兴
关87/5兴关66/5兴
关99/16兴
关111-25-1兴
关95/21兴
关68/1兴
关66/2兴
关87/5兴关61/13兴
关72/20兴
关3377-86-4兴
关87/5兴
关30310-22-6兴
关87/5兴关72/20兴
关544-10-5兴
关84/9兴关91/2兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关81/4兴
关87/5兴关69/5兴
关72/20兴
关68/1兴
关638-28-8兴
关87/5兴
关594-57-0兴
关87/5兴关72/20兴
关5750-00-5兴
关87/5兴关72/20兴
关14532-24-2兴
关99/16兴
关99/16兴
关99/16兴
关13426-57-8兴
关87/5兴关48/13兴
关72/20兴
关373-14-8兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
638
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H13F
C6 H13I
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共273–388兲
36.9
共288兲
A, EST
3-fluorohexane
共281–393兲
1-iodohexane
36.8
共296兲
A
49.8⫾0.1
46.2
共298兲
共346兲
C
A, EST
40.6
42.7⫾0.1
40.7⫾0.1
39.6⫾0.1
42.8⫾0.1
40.8
40.8
共378兲
共313兲
共343兲
共358兲
共298兲
共348兲
共349兲
C
C
C
C
A
37.7
40.4
共363兲
共327兲
A
A
38.2
共338兲
EB, IPM
42.3⫾0.3
42.1⫾0.3
共294兲
共298兲
GS
GS
37.3
36.7⫾0.1
共288兲
共298兲
A
54.1
共298兲
A
75.0⫾0.3
共298兲
C
50.8
55.2
methyl 2-共N,N-dimethylamino兲propanoate
共278 –306兲
46.1⫾1.1
ethyl 2-共N,N-dimethylamino兲ethanoate
共278 –308兲
47.6⫾0.8
N-isopropyl lactamide
共369– 407兲
69.9
N-propyl lactamide
共373– 423兲
74.0
hexane
31.5⫾0.1
31.5
共283–323兲
32.1
31.3⫾0.3
共238 –298兲
34.9
共189–259兲
35.7
共298 –343兲
31.5
共341–377兲
30.1
共374 – 451兲
29.3
共445–508兲
29.4
26.6
22.5
15.7
8.9
31.6
共298 –338兲
30.9
31.6⫾0.1
30.7⫾0.1
29.5⫾0.1
28.2⫾0.1
共300–321兲
31.6
共366兲
A
共290兲
GS
关92/13兴
共293兲
GS
关92/13兴
共384兲
A
关87/5兴
共388兲
A
共298兲
共298兲
共298兲
C
关87/5兴
关110-54-3兴
关96/18兴
关94/12兴
关92/9兴
关89/16兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关85/17兴
关85/17兴
关85/17兴
关85/17兴
关U/1兴关85/6兴
关84/15兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关74/4兴关84/9兴
Compound
共Temperature range/K兲
共331– 485兲
C6 H13N
C6 H13N
C6 H13N
C6 H13NO
C6 H13N
cyclohexylamine
共363– 407兲
共333– 408兲
共334 – 401兲
hexahydro-1H-azepine
共348 – 423兲
共312– 411兲
(dl) 2-methylpiperidine
共323– 431兲
N-ethylmorpholine
共274 –313兲
共274 –313兲
N-methylpiperidine
共273–380兲
C6 H13NO
N,N-diethylacetamide
C6 H13NO
N-butylacetamide
C6 H13NO
N,N-dimethyl butyramide
共251– 432兲
C6 H13NO2
C6 H13NO2
C6 H13NO2
C6 H13NO2
C6 H14
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共253兲
共244兲
共313兲
共356兲
共389兲
共460兲
共373兲
共423兲
共473兲
共498兲
共298兲
共313兲
共298兲
共313兲
共333兲
共353兲
共310兲
GC
A
A
A
A
A
A
C
C
C
C
C
C
C
C
CAS registry number
Reference
关87/5兴关61/13兴
关72/20兴
关52688-75-2兴
关87/5兴关72/20兴
关638-45-9兴
关68/1兴
关87/5兴关61/13兴
关72/20兴
关108-91-8兴
关87/5兴
关79/9兴
关79/9兴
关79/9兴
关75/9兴
关87/5兴关72/20兴
关60/17兴关84/9兴
关111-49-9兴
关87/5兴
关87/5兴关72/20兴
关109-05-7兴
关87/5兴关68/4兴
关100-74-3兴
关98/13兴
关98/13兴
关626-67-5兴
关87/5兴
关79/14兴关98/18兴
关127-19-5兴
关85/7兴关85/6兴
关1119-49-9兴
关84/6兴
关760-79-2兴
关87/5兴
关77/29兴
ENTHALPIES OF VAPORIZATION
639
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
32.5
31.55
30.9⫾0.1
29.8⫾0.1
31.5⫾0.1
32.0
31.0⫾0.2
30.5⫾0.2
29.0⫾0.2
28.2⫾0.2
共250兲
共298兲
共309兲
共328兲
共298兲
共301兲
共298兲
共313兲
共333兲
共353兲
30.0
29.7
30.5
29.9
29.9⫾0.1
28.7⫾0.1
27.8⫾0.1
29.9⫾0.1
30.4
29.8⫾0.2
29.0⫾0.2
27.6⫾0.2
26.9⫾0.2
共316兲
共325兲
共308兲
共298兲
共298兲
共318兲
共333兲
共298兲
共301兲
共293兲
共313兲
共333兲
共353兲
29.9
30.5
30.3⫾0.1
29.5⫾0.1
28.3⫾0.1
27.0⫾0.1
30.3
30.0⫾0.1
28.8⫾0.1
28.1⫾0.1
30.3⫾0.1
30.2
共331兲
共308兲
共298兲
共313兲
共333兲
共353兲
共298兲
共303兲
共324兲
共336兲
共298兲
共303兲
C
C
C
C
MM
29.1
29.2⫾0.1
28.9⫾0.1
28.3⫾0.1
27.3⫾0.1
29.6
29.2⫾0.1
28.2⫾0.1
27.0⫾0.1
26.1⫾0.1
共298兲
共296兲
共303兲
共313兲
共331兲
共302兲
共293兲
共313兲
共333兲
共353兲
C
C
C
C
MM
C
C
C
C
27.7
28.7
27.8⫾0.1
26.3⫾0.1
共211–289兲
29.2
共288 –323兲
28.3
fluorophosphoric acid, diisopropyl ester
共273–348兲
29.4
N-共hydroxyethyl兲piperazine
共308 –343兲
77.3⫾0.7
共308 –343兲
78.8⫾0.7
dipropyldiazene
39.9⫾0.4
共295–305兲
39.5
41.1
共298兲
共288兲
共296兲
共323兲
共274兲
共303兲
MM
共288兲
A
共326兲
共298兲
GS
GS
共298兲
共300兲
C
UV
Compound
共Temperature range/K兲
共178 –265兲
共286 –343兲
C6 H14
2-methylpentane
共301–333兲
共310–359兲
共293–335兲
共286 –334兲
C6 H14
C6 H14
3-methylpentane
共316 –361兲
共293–338兲
共288 –337兲
2,3-dimethylbutane
共287–332兲
C6 H14
C6 H14NO
C6 H14N2
C
C
C
A, MM
C
C
C
C
A
C
C
C
C
MM
C
C
C
C
A
C
C
C
C
2,2-dimethylbutane
共273–318兲
C6 H14FO3 P
Method
C
C
CAS registry number
Reference
关73/11兴
关71/28兴
关47/12兴
关47/12兴
关47/7兴
关87/5兴关45/2兴
关43/3兴
关43/3兴
关43/3兴
关43/3兴
关107-83-5兴
关02/5兴
关98/9兴
关87/5兴
关71/28兴
关49/8兴
关49/8兴
关49/8兴
关47/7兴
关45/2兴
关43/3兴
关43/3兴
关43/3兴
关43/3兴
关96-14-0兴
关99/28兴
关87/5兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关71/28兴
关49/8兴
关49/8兴
关49/8兴
关47/7兴
关45/2兴
关79-29-8兴
关71/28兴
关49/8兴
关49/8兴
关49/8兴
关49/8兴
关45/2兴
关43/3兴
关43/3兴
关43/3兴
关43/3兴
关75-83-2兴
关71/28兴
关49/2兴关84/9兴
关47/12兴
关47/12兴
关46/2兴
关45/2兴
关55-91-4兴
关87/5兴
关02/28兴
关02/28兴
关821-67-0兴
关76/3兴
关74/32兴
关68/20兴关74/32兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
640
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H14N2
Compound
共Temperature range/K兲
C6 H14N2 O
1,4-diaminocyclohexane
共383– 473兲
1,4-dimethylpiperazine
共270–309兲
共270–309兲
共276 – 405兲
2,5-dimethylpiperazine
共437– 609兲
propylhydrazone acetone
共288 –318兲
isopropylhydrazone acetone
共288 –323兲
dipropyldiazene N-oxide
C6 H14O
butyl ethyl ether
C6 H14N2
C6 H14N2
C6 H14N2
C6 H14N2
共311–365兲
共311–365兲
共311–365兲
C6 H14O
C6 H14O
共294 –359兲
tert-butyl ethyl ether
共307–346兲
共306 –345兲
共284 –346兲
共248 –350兲
共340– 407兲
dipropyl ether
共385– 467兲
共465–530兲
共292–389兲
C6 H14O
C6 H14O
35.9⫾0.4
36.1
37.7
34.9
共298兲
共302兲
C
UV
I
48.2
共398兲
A
44.3⫾0.3
43.8⫾0.3
41.6
共289兲
共298兲
共291兲
GS
GS
A
48.4
共452兲
A
44.0
共300兲
关80/20兴
44.6
共303兲
51.7⫾0.1
共298兲
C
36.3⫾0.1
36.5
32.1
35.2
共298兲
共298兲
共365兲
共326兲
C
35.3⫾0.4
36.6⫾0.1
34.5⫾0.2
32.1⫾0.5
33.4
35.7⫾1.0
35.5⫾1.0
33.8
35.8
34.3
共298兲
共320兲
共360兲
共400兲
共329兲
共295兲
共298兲
共321兲
共298兲
共309兲
32.1
32.2
33.5
35.3
31.2
共322兲
共321兲
共299兲
共263兲
共355兲
32.2
32.4
35.7⫾0.1
35.6
31.4
34.6
35.1
34.5
共400兲
共480兲
共298兲
共307兲
共363兲
共327兲
共315兲
共360兲
33.0
31.1
29.9
29.5
32.1⫾0.1
32.6
29.2
32.1
30.1
33.2
共293兲
共322兲
共375兲
共451兲
共298兲
共299兲
共341兲
共311兲
共336兲
共288兲
62.0
共288兲
关80/20兴
关17697-55-1兴
关81/7兴
关62881-9兴
关80/3兴
关76/2兴
关76/2兴
关87/5兴关76/2兴
关69/15兴关72/20兴
关994-05-8兴
关U/2兴关02/32兴
关02/15兴
关02/15兴
关02/15兴
关98/9兴
关98/2兴
关98/2兴
关94/10兴
关91/11兴
关84/26兴
关637-92-3兴
关00/13兴
关94/10兴
关87/5兴
关87/5兴
关87/5兴
关111-43-3兴
关87/5兴
关87/5兴
关80/3兴
关87/5兴关76/2兴
关76/2兴
关87/5兴关73/12兴
关69/15兴
关68/13兴
关108-20-3兴
关99/14兴
关99/10兴
关87/5兴
关87/5兴
关80/3兴
关87/5兴关76/2兴
关76/2兴
关87/5兴关69/15兴
关65/22兴关72/20兴
关49/2兴关84/9兴
关111-27-3兴
关01/3兴
Method
A, EB
tert-amyl methyl ether
共309–396兲
共309–396兲
共309–396兲
共314 –362兲
共283–308兲
共283–308兲
共306 –359兲
C6 H14O
Mean temperature
(T m /K)
diisopropyldiazene
共296 –308兲
C6 H14N2
⌬ vapH m
共kJ mol⫺1兲
共312–371兲
共300–362兲
共340–379兲
diisopropyl ether
共278 –323兲
共307–349兲
共360– 440兲
共436 –500兲
共284 –365兲
共284 –365兲
共296 –342兲
共321–350兲
共273–333兲
1-hexanol
共265–328兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
EB
EB
EB
GS
GS
EB
C
EB
EB
A
A
A
A
A
C
A
A, EB
EB
A
A
C
A
A, EB
GS
CAS registry number
Reference
关3880-49-7兴
关76/3兴
关74/32兴
关74/32兴
关68/28兴关74/32兴
关3114-70-3兴
关87/5兴
关106-58-1兴
关98/13兴
关98/13兴
关87/5兴
关106-55-8兴
关87/5兴
ENTHALPIES OF VAPORIZATION
641
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共265–328兲
共373– 423兲
共323–373兲
共253–338兲
共298 –343兲
共380– 417兲
共243–303兲
共308 – 430兲
共325– 431兲
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14O
共334 –381兲
共308 – 428兲
共333– 425兲
(dl) 2-hexanol
共274 –309兲
共224 –323兲
共360– 415兲
共337– 413兲
共351– 412兲
共301– 415兲
共298 – 413兲
(dl) 3-hexanol
共278 –311兲
共244 –318兲
共354 – 410兲
共280–320兲
共333– 409兲
共280–316兲
共298 – 408兲
(dl) 2-methyl-1-pentanol
共275–313兲
共367– 423兲
共261–294兲
共298 – 423兲
共298 – 413兲
(dl) 3-methyl-1-pentanol
共280–316兲
共328 – 427兲
共298 – 427兲
共298 – 423兲
4-methyl-1-pentanol
共357– 427兲
共371– 427兲
共298 – 427兲
共298 – 423兲
2-methyl-2-pentanol
共341–396兲
共330–397兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
61.1
61.5
61.6
61.2
57.7
47.9
58.5⫾0.2
57.6⫾0.2
55.2⫾0.2
53.8⫾0.2
59.1
60.8⫾0.2
57.9
58.5
共298兲
共298兲
共298兲
共296兲
共313兲
共395兲
共328兲
共343兲
共358兲
共368兲
共298兲
共298兲
共323兲
共340兲
GS
CGC
CGC
61.6⫾0.2
56.0
U55.8
57.9
共298兲
共349兲
共323兲
共348兲
C
58.3⫾0.3
61.8
48.7
56.8⫾0.2
55.0⫾0.2
53.0⫾0.2
50.7⫾0.2
49.2⫾0.2
52.4
47.8
53.1
49.7
共298兲
共239兲
共375兲
共313兲
共328兲
共343兲
共358兲
共368兲
共352兲
共366兲
共316兲
共356兲
GS
58.6⫾0.4
U50.7
46.1
57.5
51.5
57.4
46.4
共298兲
共259兲
共369兲
共295兲
共348兲
共295兲
共353兲
GS
59.4⫾0.3
49.3
64.9
57.4⫾0.2
55.7⫾0.2
53.9⫾0.2
52.7⫾0.2
54.2
50.2
共298兲
共382兲
共279兲
共328兲
共343兲
共358兲
共368兲
共313兲
共356兲
GS
A
A
C
C
C
C
61.7⫾0.3
54.8
59.7
47.2
共298兲
共343兲
共313兲
共360兲
GS
A
53.0
51.1
63.9
46.5
共372兲
共386兲
共313兲
共360兲
A
A
44.2
48.9
54.7⫾0.2
共356兲
共345兲
共298兲
A
A
C
Method
A
EB
C
C
C
C
C
DTA
I
A
C
C
C
C
C
A
I
A
A
I
I
I
I
CAS registry number
Reference
关01/3兴
关95/21兴
关95/21兴
关92/14兴
关87/5兴
关85/12兴
关85/3兴
关85/3兴
关85/3兴
关85/3兴
关83/14兴
关77/1兴
关73/26兴
关87/5兴关69/5兴
关72/20兴
关66/2兴
关61/6兴
关38/10兴
关35/6兴关84/9兴
关626-93-7兴
关01/7兴
关99/11兴
关87/5兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关84/10兴
关87/5兴关75/23兴
关73/26兴
关38/10兴
关623-37-0兴
关01/7兴
关99/11兴
关87/5兴
关87/5兴
关84/10兴
关75/1兴
关38/10兴
关105-30-6兴
关01/7兴
关87/5兴
关87/5兴关79/16兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关73/26兴
关38/10兴
关589-35-5兴
关01/7兴
关87/5兴
关73/26兴
关40/9兴
关626-89-1兴
关87/5兴
关87/5兴
关73/26兴
关40/9兴
关590-36-3兴
关87/5兴
关87/5兴
关85/1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
642
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14O
C6 H14OS
C6 H14O2
Compound
共Temperature range/K兲
共288 –396兲
共268 –394兲
共288 –396兲
(dl) 3-methyl-2-pentanol
共275–310兲
共314 – 409兲
共255–295兲
共296 – 408兲
(dl) 4-methyl-2-pentanol
共274 –301兲
共240–295兲
共293– 406兲
共353– 404兲
共298 – 403兲
(dl) 2-methyl-3-pentanol
共275–307兲
共307– 401兲
共342– 400兲
共298 – 401兲
共298 –399兲
3-methyl-3-pentanol
共275–301兲
共322–397兲
共338 –396兲
共298 –393兲
2,2-dimethyl-1-butanol
共356 – 415兲
共298 – 415兲
共298 – 408兲
(dl) 2,3-dimethyl-1-butanol
共324 – 431兲
共373– 422兲
3,3-dimethyl-1-butanol
共276 –312兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
52.8⫾0.2
50.7⫾0.2
48.5⫾0.2
46.1⫾0.2
44.4⫾0.2
58.3
49.1
51.3
共313兲
共328兲
共343兲
共358兲
共368兲
共303兲
共283兲
共303兲
C
C
C
C
C
58.2⫾0.3
54.4
60.4
54.8
共298兲
共329兲
共280兲
共311兲
GS
A
A
57.3⫾0.3
59.6
49.6
47.3
45.6
共298兲
共280兲
共308兲
共368兲
共350兲
GS
A
56.0⫾0.5
52.2
45.4
52.0
44.4
共298兲
共322兲
共357兲
共313兲
共349兲
GS
A
A
55.7⫾0.3
40.1
46.4
56.7⫾0.8
42.1
共298兲
共337兲
共353兲
共298兲
共346兲
GS
A
47.2
53.7
52.1
共371兲
共313兲
共313兲
A
51.4
49.6
共339兲
共388兲
A
58.0⫾0.2
58.6⫾0.1
55.4⫾0.1
52.4⫾0.1
50.8
49.4
共298兲
共328兲
共343兲
共358兲
共334兲
共368兲
GS
C
C
C
A
共319– 424兲
共353– 417兲
2,3-dimethyl-2-butanol
共303–340兲
54.0⫾0.8
共299– 400兲
48.8
共298 –393兲
49.1
(dl) 3,3-dimethyl-2-butanol
共280–315兲
53.8⫾0.3
共302– 401兲
48.3
共338 –393兲
46.8
2-ethyl-1-butanol
共275–313兲
60.3⫾0.3
共321– 426兲
53.1
共262–295兲
65.4
共298 – 426兲
59.6
共298 – 418兲
U45.5
2-methyl-2-propanesulfonic acid, ethyl ester
共337–343兲
U14.0
2-butoxyethanol
共363–382兲
51.2
共336 – 443兲
49.5
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共298兲
共314兲
共313兲
Method
I
A, EB
I
I
I
I
A
共298兲
共317兲
共353兲
GS
A
共298兲
共336兲
共280兲
共313兲
共313兲
GS
A
A
共340兲
A
共373兲
共351兲
MM
A
I
CAS registry number
Reference
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关73/26兴
关47/5兴
关33/9兴
关565-60-5兴
关01/7兴
关87/5兴
关87/5兴关79/16兴
关73/26兴
关108-11-2兴
关01/7兴
关87/5兴
关73/26兴
关87/5兴关70/7兴
关38/10兴
关565-67-3兴
关01/7兴
关87/5兴
关87/5兴关75/23兴
关73/26兴
关40/8兴
关77-74-7兴
关01/7兴
关87/5兴
关73/26兴
关91/8兴
关40/8兴
关1185-33-7兴
关87/5兴
关73/26兴
关40/7兴
关19550-30-2兴
关87/5兴
关73/26兴
关624-95-3兴
关01/7兴
关96/9兴
关96/9兴
关96/9兴
关87/5兴
关73/26兴
关594-60-5兴
关91/8兴
关87/5兴
关73/26兴
关464-07-3兴
关01/7兴
关87/5兴
关73/26兴
关97-95-0兴
关01/7兴
关87/5兴
关87/5兴关79/16兴
关73/26兴
关40/7兴
关87/5兴
关111-76-2兴
关99/15兴
关87/5兴关72/20兴
ENTHALPIES OF VAPORIZATION
643
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H14O2
C6 H14O2
C6 H14O2
Compound
共Temperature range/K兲
共336 – 443兲
1,1-dimethoxybutane
共304 –329兲
1,1-diethoxyethane
共275–308兲
共281–384兲
共273–343兲
共239–392兲
1,2-diethoxyethane
共339–382兲
共239–393兲
C6 H14O2
1-methoxy-2-propoxyethane
C6 H14O2
2-isobutoxyethanol
共344 – 432兲
C6 H14O2
C6 H14O3
1,6-hexanediol
共355–559兲
3-methyl-1,5-pentanediol
共402– 485兲
(dl) 2-methyl-2,4-pentanediol
共373– 473兲
2,3-dimethyl-2,3-butanediol
共346 – 448兲
diethylene glycol, dimethyl ether
C6 H14O3
共286 – 433兲
3,5,7-trioxanonane
C6 H14O3
tert-butyl 2-hydroxyethyl peroxide
C6 H14O2
C6 H14O2
C6 H14O2
C6 H14O3
C6 H14O3
C6 H14O3
C6 H14O3
C6 H14O4
C6 H14O4
C6 H14O6
C6 H14O6
C6 H14O6
C6 H14S
C6 H14S
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
52.6
共351兲
41.2
共317兲
EB
39.6⫾0.3
41.6
39.8
36.2
共298兲
共296兲
共288兲
共255兲
GS
A
39.3
37.9
43.2⫾0.1
共361兲
共254兲
共298兲
A
C
43.7⫾0.1
共298兲
C
48.1
共359兲
A
98.5⫾1.8
共298兲
EB, IPM
76.9
共417兲
A
58.1
共388兲
A
59.1
共361兲
A
48.0⫾0.6
47.4
共298兲
共301兲
CGC
A
44.7⫾0.2
共298兲
C
共333兲
A
共438兲
A
共448兲
A
共408兲
A
共366兲
A
共440兲
共480兲
共520兲
共560兲
共295兲
共402兲
EB
EB
EB
EB
A
A
关57/6兴关84/9兴
关4461-87-4兴
关94/16兴
关105-57-7兴
关98/21兴关02/32兴
关87/5兴关72/20兴
关49/2兴关84/9兴
关47/5兴
关629-14-1兴
关87/16兴
关87/5兴
关70/17兴
关77078-18-3兴
关70/17兴
关4439-24-1兴
关87/5兴关72/20兴
关57/6兴关84/9兴
关629-11-8兴
关96/5兴
关4457-71-0兴
关87/5兴
关107-41-5兴
关87/5兴
关76-09-5兴
关87/5兴
关111-96-6兴
关00/9兴
关87/5兴关47/5兴
关5648-29-3兴
关69/18兴
关15476-85-4兴
关83/11兴
关111-90-0兴
关87/5兴关47/5兴
关25265-71-8兴
关87/5兴
关77-99-6兴
关87/5兴
关106-69-4兴
关87/5兴
关2517-44-4兴
关87/5兴
关112-27-6兴
关02/17兴
关02/17兴
关02/17兴
关02/17兴
关87/5兴
关87/5兴关47/5兴
共482兲
TE
关90/16兴
共479兲
TE
关90/16兴
共477兲
TE
共336兲
共298兲
共298兲
共308兲
GC
EB
关90/16兴
关1741-83-9兴
关99/16兴
关81/12兴
关64/17兴
关61/17兴
关638-46-0兴
关99/16兴
关81/12兴
关71/28兴
66.4⫾1.9
diethylene glycol, monoethyl ether
共318 – 475兲
52.1
dipropylene glycol
共423–505兲
61.2
2-ethyl-2-hydroxymethyl-1,3-propanediol
共433–570兲
81.4
1,2,6-trihydroxyhexane
共393– 433兲
97.2
1,1,2,2-tetramethoxyethane
共351– 432兲
42.9
triethylene glycol
共442–562兲
72.2⫾0.3
共442–562兲
68.5⫾0.3
共442–562兲
64.6⫾0.3
共442–562兲
60.8⫾0.5
共288 –303兲
67.7
共387–552兲
71.5
dulcitol
共464 – 496兲
133.8⫾1.4
D-mannitiol
共458 –501兲
135.6⫾1.1
D-sorbitol
共461– 497兲
132.4⫾2.0
methyl pentyl sulfide
共321–349兲
44.2
45.2
44.6⫾0.8
共321–350兲
42.6
butyl ethyl sulfide
共314 – 445兲
43.7
44.5
44.9
共319兲
共298兲
共298兲
Method
CAS registry number
Reference
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
644
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H14S
C6 H14S
C6 H14S
Compound
共Temperature range/K兲
共316 –348兲
共354 – 424兲
sec-butyl ethyl sulfide
共304 – 434兲
共345– 409兲
tert-butyl ethyl sulfide
共293– 420兲
共332– 400兲
diisopropyl sulfide
共293– 420兲
共324 – 433兲
C6 H14S
C6 H14S
C6 H14S
C6 H14S
C6 H14S
C6 H14S
C6 H14S
共303–328兲
共330– 400兲
dipropyl sulfide
共313– 411兲
共353– 427兲
isopropyl propyl sulfide
共303– 432兲
共343– 416兲
ethyl isobutyl sulfide
共305– 401兲
共345– 414兲
1-hexanethiol
共320– 454兲
共352– 468兲
2-hexanethiol
共310– 440兲
共328 – 423兲
2,3-dimethyl-2-butanethiol
共285–318兲
共318 – 441兲
共328 – 441兲
2-methyl-2-pentanethiol
共327– 439兲
C6 H14S2
diisopropyl disulfide
共383– 423兲
共377– 447兲
C6 H14S2
dipropyl disulfide
共354 – 499兲
共389– 447兲
C6 H14S2
C6 H14S2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
44.6⫾0.8
43.5
40.7
共298兲
共333兲
共369兲
GC
EB
A, EB
41.2
39.0
共319兲
共360兲
A, EB
39.2
39.3
37.1
共308兲
共298兲
共347兲
A, EB
39.4
39.6⫾0.1
37.7
39.6⫾0.8
38.5
37.4
共308兲
共298兲
共339兲
共298兲
共318兲
共345兲
A, EB
GC
EB
EB
42.9
44.2
44.5
39.5
44.7⫾0.8
40.6
共328兲
共298兲
共298兲
共298兲
共298兲
共368兲
GC
A, EB
41.1
41.8
39.0
共318兲
共298兲
共358兲
A, EB
41.3
39.2
共320兲
共360兲
A, EB
43.9
44.8⫾0.2
42.4
共335兲
共298兲
共367兲
A, EB
42.7
41.4
共325兲
共343兲
A
39.3
37.8
39.3⫾0.1
37.4
共300兲
共333兲
共298兲
共343兲
A, EB
40.0⫾0.1
38.0
共298兲
共342兲
A, EB
49.3
39.6
43.8
共298兲
共298兲
共392兲
47.8
53.8⫾0.1
53.8
47.0
共369兲
共298兲
共298兲
共404兲
A, EB
CGC
A, EB
C
共395– 456兲
ethyl 共1,1-dimethylethyl兲 disulfide
共373– 461兲
46.6
共410兲
EB
43.4
共388兲
A, EB
isopropyl propyl disulfide
共383– 433兲
45.4
共398兲
A
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关64/17兴
关62/17兴
关87/5兴关52/9兴
关5008-72-0兴
关99/16兴
关87/5兴关52/9兴
关14290-92-7兴
关99/16兴
关71/28兴
关87/5兴关52/9兴
关625-80-9兴
关99/16兴
关72/11兴关66/5兴
关87/5兴关66/5兴
关64/17兴
关62/17兴
关52/9兴
关111-47-7兴
关99/16兴
关81/12兴
关71/28兴
关71/28兴
关64/17兴
关87/5兴关52/9兴
关5008-73-1兴
关99/16兴
关81/12兴
关87/5兴关52/9兴
关1613-45-2兴
关99/16兴
关87/5兴关52/9兴
关111-31-9兴
关99/16兴
关66/10兴关66/5兴
关87/5兴关66/5兴
关1679-06-7兴
关99/16兴
关87/5兴
关1639-01-6兴
关99/16兴
关99/16兴
关72/11兴关66/5兴
关87/5兴关66/5兴
关1633-97-2兴
关72/11兴关66/5兴
关87/5兴关66/5兴
关99/16兴
关4253-89-8兴
关95/21兴
关81/12兴
关87/5兴关52/9兴
关99/16兴
关629-19-6兴
关99/16兴
关85/2兴
关81/12兴
关87/5兴关58/8兴
关66/5兴
关52/9兴
关4151-69-3兴
关87/5兴关52/9兴
关99/16兴
关33672-51-4兴
关87/5兴关99/16兴
ENTHALPIES OF VAPORIZATION
645
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H14S2
C6 H14S3
C6 H14S3
C6 H15N
C6 H15N
C6 H15N
C6 H15N
C6 H15N
C6 H15N
C6 H15N
C6 H15N
C6 H15NO
C6 H15NO
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
1,6-hexanedithiol
共379–511兲
55.7
trithiodiethylene glycol, dimethyl ether
共391– 418兲
103.7
2,5,8-trithianonane
共391–533兲
116.4
hexylamine
共323–373兲
45.0
共303– 406兲
42.2
45.1⫾0.1
(dl) sec-butyl ethyl amine
共283–372兲
37.9
diisopropylamine
共260– 412兲
35.4
共273–367兲
35.6
34.6⫾0.1
33.7⫾0.1
32.6⫾0.1
31.5⫾0.1
30.2⫾0.1
共300–356兲
34.4
共291–305兲
34.6
34.5⫾0.1
共273–333兲
33.8⫾0.2
N-isopropyl propylamine
37.3⫾0.1
36.2⫾0.1
35.2⫾0.1
34.1⫾0.1
33.0⫾0.1
共312–369兲
36.2
N-butylethylamine
40.2⫾0.1
39.1⫾0.1
38.0⫾0.1
36.9⫾0.1
35.8⫾0.1
共313–375兲
39.9
共283–382兲
41.4
dipropylamine
共321–382兲
40.0
共302– 422兲
39.8
共291–305兲
41.5
40.0⫾0.1
共273–333兲
40.2⫾0.3
triethylamine
共231–319兲
35.2⫾0.9
共302–338兲
34.1
共298 –324兲
34.6
共283–363兲
35.5
34.8⫾0.2
33.9⫾0.1
33.0⫾0.2
32.2⫾0.1
31.3⫾0.2
共303–361兲
34.8
共283–313兲
35.1
34.9⫾0.1
N,N-dimethyl tert-butyl amine
共283–318兲
34.8
N-共methoxymethyl兲diethylamine
共293–318兲
38.0
N,N-diethylethanolamine
共332– 475兲
48.5⫾0.2
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共394兲
A
关1191-43-1兴
关87/5兴关99/16兴
共404兲
A
共406兲
共298兲
共318兲
共298兲
CGC
A
C
共298兲
共275兲
共288兲
共298兲
共313兲
共328兲
共343兲
共358兲
共315兲
共298兲
共298兲
共298兲
A
A
C
C
C
C
C
EB
共298兲
共313兲
共328兲
共343兲
共358兲
共327兲
C
C
C
C
C
EB
共298兲
共313兲
共328兲
共343兲
共358兲
共328兲
共298兲
C
C
C
C
C
EB
A
共336兲
共317兲
共298兲
共298兲
共298兲
C
I
共275兲
共317兲
共311兲
共298兲
共298兲
共313兲
共328兲
共343兲
共358兲
共318兲
共298兲
共298兲
C
I
EB
C
C
C
C
C
EB
C
共298兲
A
共305兲
A
共340兲
EB
关87/5兴
关37460-04-1兴
关99/16兴
关111-26-2兴
关95/21兴
关87/5兴
关69/2兴
关21035-44-9兴
关87/5兴关72/20兴
关108-18-9兴
关87/5兴
关87/5兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关71/13兴
关69/2兴
关69/16兴
关21968-17-2兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关13360-63-9兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关87/5兴关72/20兴
关142-84-7兴
关00/8兴
关87/5兴关72/20兴
关71/13兴
关69/2兴
关69/16兴
关121-44-8兴
关01/9兴
关90/9兴
关87/5兴
关87/5兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关79/9兴
关75/35兴
关69/2兴
关918-02-5兴
关87/5兴
关5888-29-9兴
关87/5兴
关100-37-8兴
关02/21兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
646
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C6 H15NO2
C6 H15NO2
C6 H15NO2 S
C6 H15NO3
C6 H15NS
C6 H15N3
C6 H15O2 PS3
C6 H15O3 P
C6 H15O3 PS
C6 H15O3 PS
C6 H15O3 PS2
C6 H15O3 PS2
C6 H15O4 P
C6 H15P
C6 H16FN2 OP
C6 H16N2
C6 H16N2 O2
C6 H18N3 P
C6 H18N4
C7 ClF17N2 S
C7 F6 O2
C7 F8
C7 F10
C7 F12O2 S4
C7 F12O6
C7 F14
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共332– 475兲
45.0⫾0.2
共332– 475兲
41.6⫾0.4
共332– 475兲
37.8⫾0.7
共328 – 433兲
48.5
diisopropanolamine
共390–521兲
68.0
2-关2-共dimethylamino兲ethoxy兴ethanol
共412– 452兲
54.4
N,N-diethyl ethanesulfonamide
共392–526兲
55.4
triethanolamine
共523–579兲
79.3
Mean temperature
(T m /K)
Method
共380兲
共420兲
共460兲
共343兲
EB
EB
EB
A
共405兲
A
共427兲
A
共407兲
A
共538兲
A
N,N-dimethyl-S-tert-butylthiohydroxylamine
共328 –334兲
28.3
共331兲
1,3,5-trimethylhexahydro-s-triazine
共284 –328兲
50.8⫾0.8
共306兲
共284 –328兲
51.2⫾0.8
共298兲
O,O-dimethyl-S-关2-共ethylthio兲ethyl兴dithiophosphate
共283–394兲
76.8
共298兲
phosphonic acid, dipropyl ester
共318 – 467兲
38.1
共333兲
O,O,O-triethythiophosphate
共305–335兲
87.5
共320兲
O,O,S-triethylthiophosphate
共312–352兲
76.3
共327兲
phosphorothioic acid, O-关2-共ethylthio兲ethyl兴-O,O-dimethyl ester
共283–379兲
71.0
共298兲
phosphorothioic acid, S-关2-共ethylthio兲ethyl兴-O,O-dimethyl ester
共283– 407兲
78.8
共298兲
triethylphosphate
共312– 484兲
46.3
共327兲
triethylphosphine
共291– 402兲
38.3
共306兲
N,N⬘-diisopropyl phosphorodiamidic fluoride
共278 –398兲
58.1
共293兲
1,6-hexanediamine
共348 – 474兲
49.3
共363兲
共338 – 473兲
51.3
共353兲
N,N-bis共2-hydroxyethyl兲ethylenediamine
共399–500兲
106.4⫾6.4
共298兲
tris共dimethylamino兲phosphine
41.5⫾0.6
共298兲
共298 –333兲
63.2
共313兲
triethylenetetramine
共431–550兲
59.8
共446兲
chloro共trifluoromethyl兲bis共heptafluoroisopropylimino兲 sulfur
38.9
共467兲
carbonofluoridic acid pentafluorophenyl ester
42.3
perfluorotoluene
共291–378兲
40.0
共306兲
共285–376兲
40.9
共300兲
共290– 400兲
40.4
共298兲
3,3-difluoro-1,2-bis共trifluoromethyl兲-4-共difluoroethylene兲cyclobutene
共272–316兲
31.5
共287兲
pentanebis共dithioperoxoic兲 acid, hexafluoro-bis共trifluoromethyl兲 ester
33.6
共370兲
hexafluoroperoxyglutaric acid, bis共trifluoromethyl兲 ester
共200–390兲
47.3
共215兲
perfluoromethylcyclohexane
共305– 414兲
33.1
共320兲
共413– 488兲
30.2
共428兲
共306 –384兲
34.0
共298兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关02/21兴
关02/21兴
关02/21兴
关87/5兴
关110-97-4兴
关87/5兴关72/20兴
关1704-62-7兴
关87/5兴
关33718-39-7兴
关87/5兴
关102-71-6兴
关87/5兴关59/1兴
关84/9兴
A
关87/5兴关99/16兴
GS
GS
关02/28兴
关02/28兴
关640-15-3兴
关87/5兴关99/16兴
关1809-21-8兴
关87/5兴关72/20兴
关126-68-1兴
关87/5兴关99/16兴
关1186-09-0兴
关87/5兴关99/16兴
关867-27-6兴
关87/5兴关99/16兴
关919-86-8兴
关87/5兴关99/16兴
关78-40-0兴
关87/5兴关47/5兴
关554-70-1兴
关87/5兴关72/20兴
关371-86-8兴
关87/5兴
关124-09-4兴
关87/5兴
关87/5兴
关4439-20-7兴
关97/6兴关97/7兴
关1608-26-0兴
关95/2兴
关84/15兴
关112-24-3兴
关87/5兴关72/20兴
A
A
A
A
A
A
A
A
A
A
A
EB, IPM
STG
A
I
A
A
I
A
关77/15兴
关59483-82-8兴
关76/30兴
关434-64-0兴
关99/16兴
关87/5兴
关84/9兴关91/2兴
关14451-74-2兴
关87/5兴关99/16兴
关58936-62-2兴
关76/18兴
关32751-20-5兴
关87/5兴关99/16兴
关355-02-2兴
关99/16兴
关99/16兴
关84/9兴关91/2兴
ENTHALPIES OF VAPORIZATION
647
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共305–385兲
C7 F15NS
C7 F16
C7 F16N2 OS
C7 F17N
C7 HF13O2
C7 HF15
C7 H2 F13NO
C7 H3 ClF3 NO2
C7 H3 ClF3 NO2
C7 H3 Cl2 F3
C7 H3 Cl2 NO
C7 H3 Cl5
C7 H3 F5
C7 H4 ClF3
C7 H4 ClF3
C7 H4 ClF3
C7 H4 ClN
C7 H4 ClN
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
34.1⫾0.3
33.4
共298兲
共320兲
A
共306 –384兲
33.3
共321兲
共298 –353兲
33.8
共313兲
共272–349兲
33.3
共310兲
2,2,3,3,4,4,5,5-octafluoro-1,1,2,3,4,5-hexahydro-1-关关1,2,2,2-tetrafluoro-1共trifluoromethyl兲ethyl兴imino兴thiophene
33.9
共371兲
perfluoroheptane
共363– 474兲
32.6
共378兲
共304 –390兲
36.3⫾0.3
共298兲
共290–355兲
35.9
共298兲
33.1
共293–355兲
34.9
共324兲
共271–379兲
37.7
共286兲
1,1,1-trifluoro-N⬘-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-N关2,2,2-trifluoro-1-共trifluromethyl兲ethylidene兴methanesulfonimidamide
33.5
共451兲
perfluoro-N,N-diethylpropylamine
共283–366兲
39.2
共325兲
tridecafluoroheptanoic acid
共359– 485兲
61.4⫾0.3
共370兲
共359– 485兲
55.5⫾0.3
共410兲
共359– 485兲
48.7⫾0.7
共450兲
1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-pentafluoroheptane
共365–369兲
30.7
共367兲
共292–370兲
37.1
共307兲
EB
A
EB
EB
EB
A
共E兲 1,1,1,2,3,3,3-heptafluoro-N-关2,2,2-trifluoro-1-共2,2,2-trifluoro-ethoxy兲ethylidene兴-2-propanamine
35.7
共369兲
1-共trifluoromethyl兲-2-chloro-5-nitrobenzene
共364 –508兲
58.1
共379兲
A
1-共trifluoromethyl兲-4-chloro-3-nitrobenzene
共358 – 495兲
57.6
1-共trifluoromethyl兲-3,4-dichlorobenzene
共353– 453兲
44.1
共284 – 446兲
41.8
3,4-dichlorophenylisocyanate
共373– 473兲
47.4
1-共trichloromethyl兲-3,4-dichlorobenzene
共438 – 663兲
59.3
共373兲
A
共368兲
共299兲
A
共388兲
A
共453兲
A
2,3,4,5,6-pentafluorotoluene
共403–523兲
共493–564兲
共310– 410兲
共312– 416兲
36.1
34.9
41.2
39.9
共418兲
共508兲
共298兲
共327兲
A
1-共trifluoromethyl兲-2-chlorobenzene
共310– 426兲
44.6
共325兲
A
1-共trifluoromethyl兲-3-chlorobenzene
共302– 411兲
43.0
共317兲
A
1-共trifluoromethyl兲-4-chlorobenzene
共302– 412兲
42.2
共317兲
A
53.5
共393兲
EB
2-chlorobenzonitrile
共378 – 486兲
4-chlorobenzonitrile
CAS registry number
Reference
关81/23兴
关87/5兴关70/14兴
关73/18兴
关59/12兴关84/9兴
关57/14兴关84/9兴
关56/14兴关70/14兴
关77984-26-0兴
关81/15兴
关335-57-9兴
关99/16兴
关97/8兴
关84/9兴关91/2兴
关59/28兴
关56/14兴
关87/5兴关51/6兴
关70/14兴关73/18兴
关62609-64-7兴
关77/19兴
关338-81-8兴
关99/16兴
关375-85-9兴
关02/14兴
关02/14兴
关02/14兴
关375-83-7兴
关66/34兴
关87/5兴关53/6兴
关73/18兴关99/16兴
关54181-88-3兴
关75/20兴
关777-37-7兴
关87/5兴关53/6兴
关73/18兴关99/16兴
关121-17-5兴
关87/5兴关73/18兴
关99/16兴
关328-84-7兴
关87/5兴
关47/5兴
关102-36-3兴
关87/5兴
关13014-24-9兴
关87/5兴关70/14兴
关73/18兴关99/16兴
关771-56-2兴
关99/16兴
关99/16兴
关84/9兴关91/2兴
关87/5兴关68/10兴
关73/18兴关99/16兴
关88-16-4兴
关87/5兴关51/9兴
关70/14兴关73/18兴
关98-15-7兴
关87/5兴关51/9兴
关70/14兴关73/18兴
关98-56-6兴
关87/5兴关51/9兴
关70/14兴关73/18兴
关873-32-5兴
关94/18兴
关623-03-0兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
648
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H4 ClNO
C7 H4 ClNO
C7 H4 ClNO3
C7 H4 Cl2 O
C7 H4 Cl2 O
C7 H4 Cl2 O
C7 H4 Cl4
C7 H4 Cl4
C7 H4 F3 NO2
C7 H4 F4
C7 H4 F4
C7 H4 F4
C7 H4 F12O
C7 H5 BrO
C7 H5 ClO
C7 H5 ClO
C7 H5 Cl2 N
C7 H5 Cl3
C7 H5 Cl3
C7 H5 Cl3
C7 H5 FN2 O4
C7 H5 F3
Compound
共Temperature range/K兲
Mean temperature
(T m /K)
Method
51.9
共404兲
EB
53.1
共359兲
A
48.9
44.3
共378兲
共338兲
A
62.4
共443兲
A
53.4
共384兲
A
49.4
共382兲
A
55.7
共381兲
A
55.0
共438兲
A
52.6
共414兲
A
53.8
共356兲
A
共389– 483兲
3-chlorophenyl isocyanate
共344 – 432兲
4-chlorophenyl isocyanate
共363– 443兲
共323– 433兲
3-nitrobenzoyl chloride
共428 –551兲
2-chlorobenzoyl chloride
共374 –395兲
3-chlorobenzoyl chloride
共367–391兲
4-chlorobenzoyl chloride
共370–392兲
1-共trichloromethyl兲-2-chlorobenzene
共423–588兲
2,3,5,6-tetrachlorotoluene
共399–548兲
1-共trifluoromethyl兲-3-nitrobenzene
共341– 475兲
1-共trifluoromethyl兲-2-fluorobenzene
共310– 410兲
38.1
1-共trifluoromethyl兲-3-fluorobenzene
共313– 410兲
36.8
1-共trifluoromethyl兲-4-fluorobenzene
共286 –381兲
35.8
2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol
共355– 446兲
53.4
benzoyl bromide
共320– 492兲
52.3
benzoyl chloride
共305– 470兲
49.6
2-chlorobenzaldehyde
共382–563兲
phenylcarbonimidic dichloride
共273–333兲
1-共chloromethyl兲-2,4-dichlorobenzene
共413–578兲
共298兲
共328兲
A
共301兲
A
共370兲
A
共335兲
A
共320兲
A
49.8
共397兲
A
54.0
共288兲
A
54.6
共428兲
A
57.6
52.0
共333兲
A
62.2
共399兲
A
52.8
共343兲
A
35.6
31.6
35.9
32.4
37.1
35.4⫾0.1
34.1⫾0.1
32.6⫾0.1
35.7
共343兲
共483兲
共338兲
共475兲
共298兲
共334兲
共353兲
共375兲
共343兲
共trichloromethyl兲benzene
共318 – 487兲
2,3,6-trichlorotoluene
共384 –509兲
共fluorodinitromethyl兲benzene
共328 –363兲
共trifluoromethyl兲benzene
共328 – 413兲
共468 –532兲
共323–384兲
共460–530兲
共330– 410兲
共328 – 413兲
C7 H5 F10NS
⌬ vapH m
共kJ mol⫺1兲
I
C
C
C
A, EB
共241–375兲
39.1
共256兲
共275–353兲
38.5
共290兲
2,2,2-trifluoro-N-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-ethanimidothioic acid, ethyl ester
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关94/18兴
关2909-38-8兴
关87/5兴关64/10兴
关104-12-1兴
关87/5兴
关67/17兴
关121-90-4兴
关87/5兴关99/16兴
关609-65-4兴
关87/5兴关99/16兴
关618-46-2兴
关87/5兴关99/16兴
关122-01-0兴
关87/5兴关99/16兴
关2136-89-2兴
关87/5兴关70/14兴
关1006-31-1兴
关87/5兴关73/15兴
关99/16兴
关98-46-4兴
关87/5兴关53/6兴
关99/16兴
关392-85-8兴
关84/9兴关91/2兴
关401-80-9兴
关87/5兴关70/14兴
关402-44-8兴
关87/5兴关70/14兴
关335-99-9兴
关87/5兴关99/16兴
关618-32-6兴
关87/5兴关47/5兴
关98-88-4兴
关87/5兴关47/5兴
关99/16兴
关89-98-5兴
关87/5兴关99/16兴
关622-44-6兴
关87/5兴关73/18兴
关99/16兴
关94-99-5兴
关87/5兴关70/14兴
关73/18兴
关98-07-7兴
关95/30兴
关87/5兴关47/5兴
关2077-46-5兴
关87/5兴关73/15兴
关17003-70-2兴
关87/5兴
关98-08-8兴
关99/16兴
关99/16兴
关92/3兴
关85/15兴
关84/9兴关91/2兴
关59/7兴
关59/7兴
关59/7兴
关87/5兴关51/9兴
关70/14兴关59/7兴
关47/5兴
关46/3兴
ENTHALPIES OF VAPORIZATION
649
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H5 F11O
C7 H5 F11O
C7 H5 N
C7 H5 N
C7 H5 NO
C7 H5 NO
C7 H5 NO3
C7 H5 NO3
C7 H5 NS
C7 H5 NS
C7 H5 N3 O6
C7 H5 N3 O7
C7 H6 Cl2
C7 H6 Cl2
C7 H6 Cl2
C7 H6 Cl3 NO2
C7 H6 F3 N
C7 H6 F3 NS
C7 H6 F6 O4
C7 H6 N2 O4
C7 H6 N2 O4
C7 H6 N2 O4
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
30.1
1-ethoxy-1,1,2,2,3,3,4,4,5,5,5-undecafluoropentane
共288 –373兲
39.0
1-ethoxy-1,1,2,2,3,4,4,4-octafluoro-3-共trifluoromethyl兲butane
共288 –373兲
38.3
benzonitrile
共301– 464兲
49.1
phenyl isocyanide
共285– 438兲
46.2
benzoxazole
51.2
48.6
46.1
43.5
40.7
phenyl isocyanate
共329– 445兲
46.5⫾0.3
共283– 439兲
45.0
2-nitrobenzaldehyde
共390–547兲
58.7
共359–547兲
59.5
3-nitrobenzaldehyde
共401–552兲
62.0
benzothiazole
58.7
56.0
53.5
50.9
48.4
45.7
phenyl isothiocyanate
共320– 492兲
52.6
2,4,6-trinitrotoluene
共353–523兲
93.7
87.0⫾1.9
2,4,6-trinitroanisole
共342–363兲
91.9
共dichloromethyl兲benzene
共308 – 487兲
49.5
2,4-dichlorotoluene
共346 – 475兲
50.6
3,4-dichlorotoluene
共378 –543兲
2,4-dinitrotoluene
共344 –572兲
共473–572兲
共354 – 439兲
2,6-dinitrotoluene
共330–533兲
共423–553兲
共344 – 427兲
3,5-dinitrotoluene
共394兲
CAS registry number
Reference
关75/20兴
关181214-75-5兴
关02/19兴
关203783-57-7兴
关02/19兴
关100-47-0兴
关87/5兴关47/5兴
关931-54-4兴
关87/5兴关47/5兴
关273-53-0兴
关92/10兴
关92/10兴
关92/10兴
关92/10兴
关92/10兴
关103-71-9兴
关96/4兴
关87/5兴关47/5兴
关552-89-6兴
关87/5兴
关47/5兴
关99-61-6兴
关87/5兴
关95-16-9兴
关92/10兴
关92/10兴
关92/10兴
关92/10兴
关92/10兴
关92/10兴
关103-72-0兴
关87/5兴关47/5兴
关118-96-7兴
关87/5兴
关78/2兴
关606-35-9兴
关87/5兴
关98-87-3兴
关87/5兴关47/5兴
关95-73-8兴
关87/5兴关73/15兴
关99/16兴
关95-75-0兴
关87/5兴关0/14兴
关99/16兴
关77765-42-5兴
关80/25兴
关98-16-8兴
关87/5兴关53/6兴
关99/16兴
共303兲
I
共303兲
I
共316兲
A
共300兲
A
共320兲
共360兲
共400兲
共440兲
共480兲
EB
EB
EB
EB
EB
共298兲
共298兲
EB
A
共405兲
共373兲
A
共416兲
A
共320兲
共360兲
共400兲
共440兲
共480兲
共520兲
EB
EB
EB
EB
EB
EB
共335兲
A
共368兲
共298兲
A
ME
共352兲
A
共323兲
A
共361兲
A
共393兲
A
共468兲
GC
共349兲
A
47.0
共348兲
A
关87/5兴
52.3
共298兲
EB
76.9
58.2
共359兲
共488兲
A
共345兲
共438兲
A
A
关76/7兴
关121-14-2兴
关87/5兴
关87/5兴关68/14兴
关73/18兴
关77/6兴关58/1兴
关606-20-2兴
关87/5兴
关87/5兴关68/14兴
关77/6兴关58/1兴
关618-85-9兴
49.4
2,2,4-trichloro-5-共dimethylamino兲-4-cyclopentene-1,3-dione
共453– 483兲
70.9
1-共trifluoromethyl兲-3-aminobenzene
共334 – 464兲
53.1
N-共trifluoromethyl兲thioaniline
共333– 413兲
dimethyl perfluoroglutarate
Method
70.2
77.8
56.9
68.7
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
650
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H6 O
C7 H6 O
C7 H6 O2
C7 H6 O2
C7 H6 O2
C7 H6 O2
C7 H6 O2
Compound
共Temperature range/K兲
共493–543兲
benzaldehyde
共313–353兲
共348 – 452兲
共409– 481兲
共311–376兲
共370– 475兲
共465–541兲
共529–599兲
共311– 404兲
共311– 404兲
共273–373兲
共299– 452兲
2,4,6-cycloheptatrienone 共tropone兲
共273–323兲
benzoic acid
共353–393兲
共405–523兲
共401–520兲
4-hydroxybenzaldehyde
共394 –583兲
2-hydroxybenzaldehyde
共383– 470兲
共306 – 470兲
phenyl formate
共287–305兲
1,3-benzodioxole
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
62.6
共508兲
A
49.1
49.5
43.8
48.6
45.5
41.9
40.6
50.3
42.5
47.0
54.4
共298兲
共363兲
共424兲
共326兲
共385兲
共480兲
共544兲
共298兲
共452兲
共288兲
共314兲
CGC
A
A
A
A
A
A
EB
EB
A, BG
54.2
共288兲
A
78.9
66.3
65.4
67.7
共298兲
共420兲
共428兲
共416兲
CGC
A
I
MM, A
72.3
共409兲
A
30.6
47.7
49.6
共398兲
A
52.9⫾0.6
共298兲
BG
79.4
共460兲
A
53.3⫾0.7
53.7
48.1
50.5⫾0.5
46.9
共298兲
共298兲
共355兲
共298兲
共320兲
GS
CGC
I, A
47.2
45.3
共337兲
共368兲
52.6
48.8
共312兲
共288兲
47.7
48.3
49.4
共366兲
共302兲
共288兲
47.1
55.3
45.8
共335兲
共288兲
共373兲
共321兲
41.4
C7 H6 O3
C7 H7 Br
2-hydroxybenzoic acid
共445–504兲
benzylbromide
共284 –306兲
共340– 409兲
共305– 472兲
C7 H7 Br
C7 H7 Br
C7 H7 Br
2-bromotoluene
共322– 455兲
共353–518兲
共297– 455兲
共273–348兲
3-bromotoluene
共351– 457兲
共287– 457兲
共273–348兲
4-bromotoluene
共320– 458兲
共273– 472兲
共358 –523兲
C7 H7 BrO
2-bromoanisole
C7 H7 BrO
3-bromoanisole
C7 H7 BrO
4-bromoanisole
C7 H7 BrS
共318 – 496兲
2-bromothioanisole
C7 H7 BrS
3-bromothioanisole
52.3
50.2
50.6
48.9
56.5
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共333兲
A
A
A
A
CAS registry number
Reference
关87/5兴关68/14兴
关100-52-7兴
关95/21兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关75/5兴
关75/5兴
关87/5兴关73/4兴
关47/5兴
关539-80-0兴
关87/5兴
关65-85-0兴
关95/21兴
关87/5兴
关43/7兴
关27/5兴
关123-08-0兴
关87/5兴关47/5兴
关100-83-4兴
关87/5兴
关86/10兴
关47/5兴
关1864-94-4兴
关76/9兴关75/36兴
关274-09-9兴
关58/25兴
关69-72-7兴
关87/5兴
关100-39-0兴
关02/29兴
关02/29兴
关76/11兴关87/5兴
关76/11兴
关87/5兴关47/5兴
关99/16兴
关95-46-5兴
关99/16兴
关87/5兴关70/14兴
关73/18兴
关47/5兴
关40/5兴
关591-17-3兴
关99/16兴
关87/5兴关47/5兴
关40/5兴
关108-38-7兴
关99/16兴
关99/16兴
关87/5兴关70/14兴
关73/18兴
关578-57-4兴
关86/10兴
关2398-37-0兴
关86/10兴
关104-92-7兴
关86/10兴
关47/5兴
关19614-16-5兴
关86/10兴
ENTHALPIES OF VAPORIZATION
651
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
54.4
C7 H7 BrS
4-bromothioanisole
C7 H7 Cl
benzyl chloride
共276 –309兲
55.7
共320–390兲
C7 H7 Cl
C7 H7 Cl
C7 H7 Cl
C7 H7 ClO
共295– 453兲
2-chlorotoluene
共370– 432兲
共345– 430兲
共345– 430兲
共338 – 493兲
共278 – 432兲
共273–348兲
3-chlorotoluene
共373– 435兲
共277– 436兲
共273–348兲
4-chlorotoluene
共362– 435兲
共304 – 436兲
共340– 430兲
共338 – 433兲
共279– 435兲
2-chloroanisole
共388 – 460兲
C7 H7 ClO
3-chloroanisole
C7 H7 ClO
4-chloroanisole
C7 H7 ClS
2-chlorothioanisole
C7 H7 ClS
3-chlorothioanisole
C7 H7 ClS
4-chlorothioanisole
C7 H7 F
benzyl fluoride
共278 –318兲
50.1⫾0.3
49.9
48.6
50.1⫾0.5
48.6
共298兲
共298兲
共335兲
共298兲
共310兲
41.6
45.3
42.5
42.8
共385兲
共298兲
共361兲
共353兲
44.8
45.8
共293兲
共288兲
41.9
43.7
46.2
共388兲
共292兲
共288兲
41.8
41.7
46.0
43.5
44.1
共375兲
共319兲
共298兲
共353兲
共293兲
49.4
48.3
共403兲
A
46.2⫾0.3
46.5
46.3⫾0.3
43.7
44.3
44.5⫾0.4
共298兲
共298兲
共298兲
共312兲
共312兲
共298兲
GS
CGC
GS
A
I
42.0
31.5
32.3
38.0
38.7
40.5
共263兲
共465兲
共468兲
共323兲
共310兲
共264兲
41.6
39.2
40.7
共265兲
共308兲
共266兲
39.5
37.0
共298兲
共355兲
GS
CGC
A, I
A
A
A
48.1
47.7
53.6
51.9
53.1
共278 –318兲
共297– 410兲
共298 –356兲
C7 H7 F
C7 H7 F
C7 H7 F
C7 H7 F2 N
2-fluorotoluene
共248 –388兲
共452–531兲
共453–530兲
共308 –348兲
共295–388兲
共248 –387兲
3-fluorotoluene
共250–390兲
共293–390兲
共250–389兲
4-fluorotoluene
共340– 430兲
共340– 429兲
N,N-difluorobenzylamine
A
A
A
CAS registry number
Reference
关86/10兴
关104-95-0兴
关86/10兴
关100-44-7兴
关02/29兴
关02/29兴
关87/5兴关76/11兴
关76/11兴关99/16兴
关87/5兴关47/5兴
关95-49-8兴
关99/16兴
关84/9兴关91/2兴
关84/9兴
关87/5兴关73/18兴
关70/14兴
关47/5兴
关40/5兴
关108-41-8兴
关99/16兴
关87/5兴关47/5兴
关40/5兴
关106-43-4兴
关99/16兴
关87/5兴
关84/9兴关91/2兴
关84/9兴
关47/5兴
关766-51-8兴
关86/10兴
关87/5兴关73/18兴
关99/16兴
关2845-89-8兴
关86/10兴
关623-12-1兴
关86/10兴
关17733-22-1兴
关86/10兴
关4867-37-2兴
关86/10兴
关123-09-1兴
关86/10兴
关350-50-5兴
关02/29兴
关02/29兴
关97/14兴
关87/5兴
关76/11兴
关76/11兴
关95-52-3兴
关99/16兴
关99/16兴
关84/16兴
关74/26兴关84/9兴
关87/5兴关51/9兴
关47/5兴
关352-70-5兴
关99/16兴
关87/5兴关51/9兴
关47/5兴
关352-32-9兴
关84/9兴关91/2兴
关87/5兴关51/9兴
关99/16兴
关23162-99-4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
652
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H7 F9 O
C7 H7 I
C7 H7 I
C7 H7 IO
C7 H7 NO2
C7 H7 NO2
C7 H7 NO2
C7 H7 NO2
C7 H7 NO3
C7 H7 N3
C7 H8
C7 H8
C7 H8
C7 H8
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共313–333兲
77.8
1,1,1,2,2,3,3,4,4-nonafluoro-4-propoxybutane
共288 –369兲
37.9
benzyl iodide
共301–337兲
57.4⫾0.3
57.7
共360– 400兲
46.8
50.6⫾1.4
2-iodotoluene
共310– 484兲
49.7
4-iodoanisole
共401–520兲
54.4
共401– 479兲
53.1⫾0.4
共nitromethyl兲benzene
共363– 413兲
53.8
2-nitrotoluene
共274 –323兲
59.0⫾0.3
59.1⫾0.3
共388 – 448兲
52.0
共402– 496兲
51.0
共387– 493兲
52.2
3-nitrotoluene
共397– 452兲
52.8
共353–505兲
49.8
4-nitrotoluene
共407– 457兲
52.8
共423–512兲
49.8
共387– 493兲
54.2
2-nitroanisole
共424 –545兲
58.6
共azidomethyl兲benzene
共333–363兲
48.0
bicyclo关2.2.1兴hepta-2,5-diene
34.8⫾0.1
共300–364兲
33.6
34.7⫾0.1
33.8⫾0.9
共300–353兲
32.9⫾0.8
1,3,5-cycloheptatriene
共273–338兲
40.8
共273– 416兲
39.4
38.7⫾0.2
tetracyclo关 3.2.0.02,7.04,6兴 heptane 共quadricyclane兲
37.9⫾0.1
37.9⫾0.1
37.0⫾0.8
共302–372兲
37.3⫾0.8
toluene
共331– 496兲
35.7
共210–279兲
40.6
共383– 445兲
34.4
共440–531兲
33.2
共530–592兲
33.3
共273–295兲
38.9
33.5⫾0.1
32.1⫾0.1
29.4⫾0.1
27.1⫾0.1
24.0⫾0.1
35.4
33.4
31.4
28.4
24.0
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共323兲
A
共303兲
I
共298兲
共298兲
共375兲
共298兲
GS
CGC
I, A
共325兲
A
共416兲
共440兲
A
I
共378兲
A
共299兲
共298兲
共403兲
共417兲
共402兲
GS
共413兲
共368兲
EB
A
共422兲
共438兲
共402兲
EB
A
共439兲
A
共348兲
A
共298兲
共315兲
共298兲
共298兲
共298兲
C
A
C
EB
A
BG
共288兲
共288兲
共298兲
A
A, EB
共298兲
共298兲
共298兲
共317兲
C
C
共346兲
共264兲
共398兲
共455兲
共545兲
共284兲
共380兲
共403兲
共441兲
共470兲
共505兲
共333兲
共373兲
共413兲
共453兲
共493兲
BG
A
A
A
A
A
C
C
C
C
C
CAS registry number
Reference
关87/5兴
关72372-80-6兴
关02/19兴
关620-05-3兴
关02/29兴
关02/29兴
关87/5兴关76/11兴
关76/11兴
关615-37-2兴
关87/5兴关47/5兴
关696-62-8兴
关87/5兴关99/16兴
关56/26兴
关622-42-4兴
关87/5兴
关88-72-2兴
关00/15兴
关00/15兴
关94/8兴
关87/5兴
关38/9兴关94/8兴
关99-08-1兴
关94/8兴
关87/5兴
关99-99-0兴
关94/8兴
关87/5兴
关38/9兴关94/8兴
关91-23-6兴
关87/5兴
关622-79-7兴
关87/5兴
关121-46-0兴
关93/1兴
关87/5兴
关85/2兴
关78/1兴
关73/1兴
关544-25-2兴
关87/5兴关73/18兴
关87/5兴关56/20兴
关56/20兴
关278-06-8兴
关93/1兴
关85/2兴
关78/1兴
关87/5兴关73/1兴
关108-88-3兴
关93/3兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关85/10兴
关85/10兴
关85/10兴
关85/10兴
关85/10兴
关84/29兴
关84/29兴
关84/29兴
关84/29兴
关84/29兴
ENTHALPIES OF VAPORIZATION
653
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共343–383兲
共303–343兲
共288 –348兲
共210–293兲
共308 –386兲
C7 H8 O
共286 –362兲
共308 –384兲
共273–323兲
anisole
共353–393兲
共382– 429兲
共382– 437兲
共382– 437兲
共282– 437兲
C7 H8 O
共382– 437兲
benzyl alcohol
共277–381兲
共323–373兲
共303–333兲
共385–573兲
共293–313兲
C7 H8 O
2-hydroxytoluene
共304 – 409兲
共399– 470兲
共463–526兲
共517– 630兲
共383– 473兲
C7 H8 O
C7 H8 O
共415– 462兲
3-hydroxytoluene
共393– 433兲
共284 –313兲
共285– 416兲
共410– 477兲
共471–531兲
共523– 633兲
共383– 473兲
共388 – 429兲
共359– 473兲
共422– 474兲
4-hydroxytoluene
共308 –393兲
共385– 477兲
共463–533兲
共523– 635兲
共383– 473兲
C7 H8 OS
共419– 474兲
4-methoxybenzenethiol
C7 H8 O2
2,4-dihydroxytoluene
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
35.4
38.0
37.3
36.9
37.8
37.0
38.0
37.8
37.0
38.8
共360兲
共298兲
共318兲
共303兲
共278兲
共323兲
共298兲
共301兲
共323兲
共288兲
45.3
41.8
41.0
41.9
46.9
39.0
46.8⫾0.2
42.9⫾0.1
42.0⫾0.1
40.5⫾0.1
38.9⫾0.1
41.9
共298兲
共397兲
CGC
共397兲
共298兲
共426兲
共298兲
共367兲
共382兲
共402兲
共427兲
共397兲
A
64.8⫾0.6
69.5
60.5
66.2
54.6
61.5
共298兲
共298兲
GS
CGC
共318兲
共400兲
共303兲
GS
A
A, ME
58.5
50.1
46.2
44.0
50.2
51.3
共319兲
共414兲
共478兲
共532兲
A
A
A
A
共398兲
GS, EB
48.2
共438兲
62.5
61.7
63.1
52.7
47.6
43.8
55.0
共298兲
共298兲
共300兲
共425兲
共486兲
共538兲
共398兲
CGC
A
A
A
A
A
GS, EB
60.6
58.8
50.7
共409兲
共374兲
共448兲
GS
62.0
55.4
49.2
46.0
54.0
55.6
共323兲
共400兲
共478兲
共538兲
A
A
A
A
共398兲
A, GS, EB
51.3
共446兲
52.3
Method
C
MM
C
C
C
C
C
CAS registry number
Reference
关75/33兴
关71/28兴
关68/23兴
关67/10兴
关56/5兴
关87/5兴关49/6兴
关47/7兴
关46/4兴
关45/2兴
关43/1兴
关100-66-3兴
关95/21兴
关93/4兴
关86/10兴
关87/5兴关76/2兴
关76/2兴
关76/2兴
关75/3兴
关67/39兴
关67/39兴
关67/39兴
关67/39兴
关55/9兴关65/7兴
关100-51-6兴
关99/3兴
关95/21兴
关95/30兴
关82/1兴
关87/5兴关73/18兴
关87/5兴关57/9兴
关73/18兴
关95-48-7兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关86/10兴
关87/5兴关60/4兴
关73/18兴
关39/4兴
关108-39-4兴
关95/21兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴关60/4兴
关73/18兴
关80/17兴
关55/9兴关84/9兴
关39/4兴
关106-44-5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关86/10兴
关87/5兴关60/4兴
关73/18兴
关39/4兴
关106-53-6兴
关86/10兴
关496-73-1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
654
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H8 O2
C7 H8 O2
C7 H8 O2
C7 H8 O2
C7 H8 O2
C7 H8 O2
C7 H8 O2
C7 H8 O2 S
C7 H8 O2 S
C7 H8 O3
C7 H8 O3
C7 H8 O3
C7 H8 S
C7 H8 S
C7 H8 S
C7 H8 S
C7 H8 S
Compound
共Temperature range/K兲
共391– 459兲
2,6-dihydroxytoluene
共398 – 434兲
3,4-dihydroxytoluene
共387– 415兲
3,5-dihydroxytoluene
共402– 468兲
2-methoxyphenol
共378 – 479兲
共355– 478兲
3-methoxyphenol
共413–518兲
4-methoxyphenol
C7 H9 Cl3 OS
C7 H9 F3 N2 O4
C7 H9 F5 O2
C7 H9 N
C7 H9 N
Mean temperature
(T m /K)
Method
72.2
共406兲
A, GC
66.9
共413兲
A, GC
90.0
共401兲
A
76.6
共417兲
A, GC
52.7
52.7
共393兲
共370兲
A
64.8
共428兲
A
共433兲
A
58.6
共418 –518兲
61.4
2,3-dimethyl-2H-pyran-2-one
共352–518兲
64.9
6-methyl-4-methoxy-2H-pyran-2-thione
共401– 415兲
108.9
共367兲
A
共408兲
A
2-methyl-6-共methylthio兲-4H-pyran-4-one
共387– 432兲
62.7
共402兲
A
51.2
52.6
共369兲
共325兲
A
72.8
共377兲
A
57.4
共400兲
A
47.5
56.6⫾0.1
共409兲
共298兲
48.1
46.6
46.0
共366兲
共394兲
A
48.7
47.1
共368兲
共395兲
A
48.1
46.5
46.4
共366兲
共394兲
A
共298兲
共404兲
A, EB
2-furancarboxylic acid, ethyl ester
共354 –389兲
共310– 468兲
3-methoxy-6-methyl-4H-pyran-4-one
共370–384兲
4-methoxy-6-methyl-2H-pyran-2-one
共385– 434兲
benzenemethanethiol
共394 – 436兲
2-methylbenzenethiol
共351– 498兲
共370– 470兲
3-methylbenzenethiol
共353– 498兲
共380– 471兲
4-methylbenzenethiol
共351– 499兲
共379– 471兲
methyl phenyl sulfide
共389– 475兲
C7 H8 S3
⌬ vapH m
共kJ mol⫺1兲
47.7
54.3⫾0.1
47.5
共323–353兲
50.6⫾2.1
4,5,6,7-tetrahydro-1,4-benzodithiol-2-thione
共341–352兲
99.0
2,3,3-trichloro-2-propenethioic acid, O-butyl ester
共383– 433兲
73.3
glycine, N-关N-共trifluoroacetyl兲glycyl兴methyl ester
共420– 443兲
93.8
pentafluoropropionic acid, butyl ester
共354 –389兲
38.6
benzylamine
共302– 458兲
2,3-dimethylpyridine
共283–313兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共298兲
共346兲
GC
共431兲
A
共369兲
A, EB
51.8
共317兲
A
52.0⫾0.6
共298兲
GS
CAS registry number
Reference
关87/5兴关75/24兴
关608-25-3兴
关87/5兴关75/24兴
关452-86-8兴
关87/5兴
关504-15-4兴
关87/5兴关75/24兴
关90-05-1兴
关87/5兴关73/18兴
关55/9兴
关150-19-6兴
关87/5兴关73/18兴
关150-76-5兴
关86/10兴
关87/5兴关73/18兴
关63233-31-8兴
关87/5兴关47/5兴
关52911-98-5兴
关87/5兴关99/16兴
关74/30兴
关52911-99-6兴
关87/5兴关99/16兴
关74/30兴
关614-99-3兴
关87/5兴
关47/5兴
关4225-42-7兴
关87/5兴
关672-89-9兴
关87/5兴
关100-53-8兴
关99/16兴
关72/11兴
关137-06-4兴
关99/16兴
关87/5兴
关86/10兴
关108-40-7兴
关99/16兴
关87/5兴
关106-45-6兴
关99/16兴
关87/5兴
关86/10兴
关100-68-5兴
关86/10兴
关72/11兴关66/5兴
关87/5兴关66/5兴
关99/16兴
关62/20兴
关698-42-0兴
关99/16兴
关79886-21-8兴
关80/24兴
关433-33-0兴
关87/5兴关73/18兴
关680-28-4兴
关87/5兴关69/13兴
关99/16兴
关100-46-9兴
关87/5兴关77/3兴
关47/1兴
关583-61-9兴
关99/3兴
ENTHALPIES OF VAPORIZATION
655
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共328 – 476兲
共328 – 476兲
共328 – 476兲
共328 – 476兲
共323–373兲
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 N
共372– 436兲
2,4-dimethylpyridine
共323–373兲
共288 –373兲
共331– 473兲
共331– 473兲
共331– 473兲
共331– 473兲
共298 – 431兲
共267–358兲
共349– 433兲
2,5-dimethylpyridine
共330– 471兲
共330– 471兲
共330– 471兲
共330– 471兲
共358 – 431兲
2,6-dimethylpyridine
共323–373兲
共288 –373兲
共315– 457兲
共315– 457兲
共315– 457兲
共315– 457兲
共295– 417兲
共267–358兲
共352– 418兲
3,4-dimethylpyridine
共341– 495兲
共341– 495兲
共341– 495兲
共341– 495兲
共288 – 422兲
共385– 454兲
3,5-dimethylpyridine
共323–373兲
共288 –392兲
共335– 487兲
共335– 487兲
共335– 487兲
共335– 487兲
共273–358兲
共373– 446兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
45.2
42.7
40.2
37.4
47.6
46.9
45.0
43.5
43.0
共340兲
共380兲
共420兲
共460兲
共298兲
共313兲
共343兲
共368兲
共387兲
EB
EB
EB
EB
CGC
C
C
C
A
47.5
45.5
44.8
42.3
39.8
37.0
47.1
47.5
46.5
44.6
43.9
43.5
共298兲
共330兲
共340兲
共380兲
共420兲
共460兲
共313兲
共282兲
共313兲
共343兲
共368兲
共364兲
CGC
44.4
41.9
39.4
36.5
42.8
共340兲
共380兲
共420兲
共460兲
共373兲
EB
EB
EB
EB
A, MG
46.4
43.7
43.9
41.4
38.8
36.0
45.0
46.1
44.4
42.5
40.8
41.6
共298兲
共330兲
共320兲
共360兲
共400兲
共440兲
共310兲
共282兲
共313兲
共343兲
共368兲
共367兲
CGC
46.6
44.2
41.7
39.0
47.6
48.8
47.6
45.9
44.8
共360兲
共400兲
共440兲
共480兲
共355兲
共328兲
共343兲
共368兲
共400兲
EB
EB
EB
EB
48.7
47.0
46.7
44.3
41.8
39.2
49.1
49.6
46.5
44.8
44.3
共298兲
共340兲
共340兲
共380兲
共420兲
共460兲
共288兲
共313兲
共343兲
共368兲
共388兲
CGC
EB
EB
EB
EB
EB
MM
C
C
C
A
EB
EB
EB
EB
EB
MM
C
C
C
A, MG
C
C
C
A
EB
EB
EB
EB
MM
C
C
C
A
CAS registry number
Reference
关95/22兴
关95/22兴
关95/22兴
关95/22兴
关95/21兴
关85/1兴
关85/1兴
关85/1兴
关87/5兴关73/18兴
关108-47-4兴
关95/21兴
关95/4兴
关95/22兴
关95/22兴
关95/22兴
关95/22兴
关90/6兴
关86/2兴
关85/1兴
关85/1兴
关85/1兴
关87/5兴关73/18兴
关589-93-5兴
关95/22兴
关95/22兴
关95/22兴
关95/22兴
关87/5兴关53/4兴
关73/18兴
关108-48-5兴
关95/21兴
关95/4兴
关95/22兴
关95/22兴
关95/22兴
关95/22兴
关90/6兴
关86/2兴
关85/1兴
关85/1兴
关85/1兴
关87/5兴关53/4兴
关583-58-4兴
关95/22兴
关95/22兴
关95/22兴
关95/22兴
关95/4兴
关85/1兴
关85/1兴
关85/1兴
关87/5兴关73/18兴
关591-22-0兴
关95/21兴
关95/4兴
关95/22兴
关95/22兴
关95/22兴
关95/22兴
关86/2兴
关85/1兴
关85/1兴
关85/1兴
关87/5兴关73/18兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
656
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 N
C7 H9 NO
C7 H10
C7 H10
C7 H10
C7 H10
C7 H10
C7 H10N2
C7 H10N2
C7 H10N2
C7 H10N2
C7 H10N2
C7 H10O
C7 H10O
C7 H10O
C7 H10O2
C7 H10O3
C7 H10O3
Compound
共Temperature range/K兲
3-ethylpyridine
共334 –373兲
2-ethylpyridine
共323–373兲
4-ethylpyridine
共333–372兲
N-methylaniline
共309– 469兲
o-toluidine
共290–517兲
共290–517兲
共290–517兲
共290–517兲
共290–517兲
共290–517兲
共391– 474兲
m-toluidine
共394 – 477兲
p-toluidine
共393– 474兲
共315– 473兲
1-cyclohexene-1-carbonitrile
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
44.6
共349兲
A
43.7
共338兲
A
45.3
共348兲
A
53.6
共324兲
A
57.8
54.5
51.5
48.6
45.7
42.7
50.0
共300兲
共340兲
共380兲
共420兲
共460兲
共500兲
共406兲
EB, IPM
EB, IPM
EB, IPM
EB, IPM
EB, IPM
EB, IPM
A
51.1
共409兲
A
51.1
54.9
共408兲
共330兲
A
共298兲
C
共382兲
BG
共349兲
A
共298兲
共316兲
EB
A
共348兲
共298兲
A
EB
共317兲
A
共298兲
EB
共337兲
A
共298兲
C
共384兲
A
共318兲
A
共394兲
A
共370兲
A
共298兲
CGC
共335兲
EB
共298兲
共298兲
共298兲
GC
CGC
CGC
共338兲
A
共384兲
A
53.6⫾0.1
bicyclo关3.1.0兴hexane-1-carbonitrile
共366 – 444兲
U43.2
2-methoxyaniline
共334 – 492兲
57.5
bicyclo关2.2.1兴hept-2-ene 共norbornene兲
共338 – 406兲
35.1⫾0.2
共301–350兲
34.3
bicyclo关4.1.0兴hept-3-ene
共333–384兲
36.7
38.4⫾0.6
tricyclo关 2.2.1.02,6兴 heptane
共302–337兲
38.3
tricyclo关 4.1.0.02,4兴 heptane
36.5⫾0.5
tricyclo关 4.1.0.02,6兴 heptane
共322–373兲
35.3
2,3,5-trimethylpyrazine
53.9⫾1.6
diallylcyanamide
共369– 495兲
52.3
1,5-dicyanopentane
共306 –331兲
74.5
2,4-diaminotoluene
共379–553兲
67.7
4-tolyhydrazine
共355–515兲
65.4
1-ethynyl-1-cyclopentanol
共323–373兲
62.1
7-norbornanone
共322–348兲
47.9
2-norbornanone
50.0
共343–383兲
51.5
共343–383兲
49.6
5-methyl-5-hexene-2,4-dione
共323–363兲
26.4
3-acetyl-2,4-pentanedione
共369– 477兲
54.9
glycidyl methacrylate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关536-78-7兴
关87/5兴关73/18兴
关100-71-0兴
关87/5兴关73/18兴
关536-75-4兴
关87/5兴关73/18兴
关100-61-8兴
关87/5兴
关95-53-4兴
关94/17兴
关94/17兴
关94/17兴
关94/17兴
关94/17兴
关94/17兴
关87/5兴关49/1兴
关84/9兴
关108-44-1兴
关87/5兴关49/1兴
关84/9兴
关106-49-0兴
关87/5兴
关47/5兴
关1855-63-6兴
关70/21兴
关31357-72-9兴
关71/2兴
关90-04-0兴
关87/5兴关47/5兴
关498-66-8兴
关96/5兴
关87/5兴
关16554-83-9兴
关87/5兴
关74/20兴
关279-19-6兴
关87/5兴
关74/20兴
关187-26-8兴
关87/5兴
关14667-55-1兴
关96/2兴
关538-08-9兴
关87/5兴
关646-20-8兴
关87/5兴
关95-80-7兴
关87/5兴关47/5兴
关539-44-6兴
关87/5兴关47/5兴
关17356-19-3兴
关95/21兴
关10218-02-7兴
关94/16兴
关497-38-1兴
02/37兴
关95/21兴
关95/21兴
关20583-46-4兴
关87/5兴关73/18兴
关815-68-9兴
关87/5兴
关106-91-2兴
ENTHALPIES OF VAPORIZATION
657
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H10O4
C7 H10O4
C7 H10O4
C7 H10O4
C7 H10O6
C7 H10S
C7 H10S
C7 H11BrO2
C7 H11ClO5
C7 H11Cl3 O2
C7 H11NO2
C7 H11NO2
C7 H11N
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
61.2⫾0.4
60.6⫾0.9
共298兲
共298兲
A
C
关87/14兴
关86/8兴
共341兲
A
共339兲
A
共357兲
A
共334兲
A
关87/5兴关47/5兴
关617-54-9兴
关87/5兴关47/5兴
关617-52-7兴
关87/5兴关47/5兴
关617-53-8兴
关87/5兴关47/5兴
trimethylsuccinic anhydride
共326 –504兲
52.9
dimethyl citraconate
共324 – 484兲
55.8
dimethyl itaconate
共342– 481兲
67.0
dimethyl mesaconate
共319– 479兲
55.2
tris共methoxycarbonyl兲methane
共308 –348兲
74.4⫾0.6
2-propylthiophene
共243–303兲
46.0
2-isopropylthiophene
共352– 468兲
41.5
4-bromo-3-methylcrotonic acid, ethyl ester
共346 –381兲
43.1
共2-chloroethyl兲关共1-methoxycarbonyl兲ethyl兴 carbonate
共365–525兲
66.8
trichloracetic acid, neopentyl ester
共378 – 473兲
57.7
2-methyl-2-acetoxybutyronitrile
共315– 469兲
58.1
5-oxo-2-pyrrolidinecarboxylic acid, ethyl ester
共418 –511兲
73.7
cyclohexanecarbonitrile
共333– 427兲
39.4
51.9⫾0.1
bicyclo关2.2.1兴heptane 共norbornane兲
40.0⫾0.1 sub
cis bicyclo关4.1.0兴heptane
共298 –385兲
38.0⫾0.8
(dl) bicyclo关4.1.0兴heptane
共333–385兲
36.5
1-methylbicyclo关3.1.0兴hexane
共312–362兲
34.0
cycloheptene
共251–313兲
38.5
共251–312兲
36.7
1,2-dimethylcyclopentene
共294 – 431兲
36.4
(dl) 1,3-dimethylcyclopentene
共283– 410兲
35.0
(dl) 1,4-dimethylcyclopentene
共273– 413兲
35.1
(dl) 1,5-dimethylcyclopentene
共273– 423兲
37.1
1-ethylidenecyclopentane
38.6⫾0.2
1-ethylcyclopentene
38.5⫾0.3
共293– 433兲
36.5
3-ethylcyclopentene
共288 – 435兲
36.5
4-ethylcyclopentene
共288 – 435兲
36.5
1-methyl-1-cyclohexene
共275–313兲
37.7⫾0.2
共275–313兲
37.5⫾0.2
共333–384兲
35.7
共309–384兲
(dl) 3-methyl-1-cyclohexene
36.7
GS
共273兲
共367兲
关95/8兴
关1551-27-5兴
关81/2兴关99/16兴
关4095-22-1兴
关99/16兴
关26918-14-9兴
关87/5兴
共361兲
A
共380兲
A
共393兲
A
关87/5兴关99/16兴
关57392-56-0兴
关87/5兴关99/16兴
共330兲
A
关87/5兴关47/5兴
共433兲
A
共351兲
共298兲
BG
C
关87/5兴
关766-05-2兴
关71/2兴
关70/21兴
关279023-2兴
关87/1兴
关286-08-8兴
关87/5兴关70/30兴
关286-08-8兴
关87/5兴
关4625-24-5兴
关87/5兴
关628-92-2兴
关87/5兴关41/6兴
关41/6兴
关765-47-9兴
关87/5兴关73/18兴
关62184-82-1兴
关87/5兴关73/18兴
关57426-81-0兴
关87/5兴关73/18兴
关16491-15-9兴
关87/5兴关73/18兴
共298兲
共313兲
A
共348兲
A
共327兲
A
共266兲
共300兲
A
共309兲
A
共298兲
A
共288兲
A
共288兲
A
共298兲
GCC
共298兲
共308兲
GCC
A
共303兲
A
共303兲
A
共294兲
共298兲
共348兲
GS
GS
A
共324兲
MM
关79/17兴
关2146-38-5兴
关79/17兴
关87/5兴关73/18兴
关694-35-9兴
关87/5兴关73/18兴
关3742-38-9兴
关87/5兴关73/18兴
关591-49-1兴
关00/7兴
关00/7兴
关87/5兴关70/24兴
关84/9兴
关60/20兴
关591-48-0兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
658
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
34.8
共350兲
A
37.0⫾0.6
36.3⫾0.6
36.3
共286兲
共298兲
共307兲
GS
GS
A
36.1⫾0.3
34.4
共298兲
共346兲
GCC
A, EB
37.9
共351兲
A
2-heptyne
共346 –385兲
38.6
共361兲
A
3-heptyne
共343–380兲
39.1
共358兲
A
1,2-dibromocycloheptane
共292–353兲
50.3
共307兲
A
6-chlorohexylisocyanate
共363– 453兲
52.5
共378兲
A
共383兲
A
关87/5兴关99/16兴
共303兲
A, GS
共357兲
共385兲
A
关87/5兴关48/9兴
关99/16兴
关3922-36-9兴
关99/16兴
关87/5兴
Compound
共Temperature range/K兲
共335–376兲
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12
C7 H12Br2
C7 H12ClNO
C7 H12Cl2 O2
C7 H12Cl2 S
C7 H12Cl4
C7 H12N2
C7 H12O
C7 H12O
C7 H12O
C7 H12O2
C7 H12O2
C7 H12O2
C7 H12O2
C7 H12O2
C7 H12O2
C7 H12O3
C7 H12O3
(dl) 4-methyl-1-cyclohexene
共275–296兲
共275–296兲
共292– 429兲
methylenecyclohexane
共331–387兲
1-heptyne
共336 –373兲
dichloroacetic acid, neopentyl ester
共368 – 463兲
57.4
共2-chloroethyl兲共2-chlorocyclopentyl兲 sulfide
共273–333兲
65.9
1,1,1,7-tetrachloroheptane
共342– 455兲
共370– 454兲
2-piperidinoacetonitrile
共303–338兲
exo-norborneol
71.7
69.9
56.0⫾0.5
52.5
cyclohexenyl methyl ether
共274 –313兲
44.0⫾0.2
共274 –313兲
43.7⫾0.2
cycloheptanone
共343–383兲
50.6
共343–383兲
51.9
共343–383兲
50.7
共313– 453兲
48.5
共373– 465兲
44.8
cyclobutanecarboxylic acid, ethyl ester
共274 –308兲
44.9⫾0.4
1,4-dioxaspiro关4.4兴nonane
共278 –313兲
47.6⫾0.5
butyl acrylate
共318 – 419兲
47.3⫾0.3
共272– 421兲
44.8
isobutyl acrylate
共330– 410兲
43.8
heptanolactone
共368 –390兲
48.2⫾0.3
共369–390兲
53.3⫾1.3
propyl methacrylate
共304 – 413兲
41.6
glycidyl butyrate
58.7⫾0.4
58.0⫾0.4
2-acetoxy-2-methyl-3-butanone
共337–368兲
54.8
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
GS
共298兲
GC
共294兲
共298兲
GS
GS
共298兲
共298兲
共298兲
共328兲
共388兲
CGC
CGC
CGC
A
A, EB
GS
共298兲
GS
共298兲
共287兲
EB
A
共345兲
A
共379兲
共298兲
MM
MM
共319兲
A
共298兲
共298兲
C
共352兲
A
CAS registry number
Reference
关87/5兴关70/24兴
关84/9兴
关591-47-9兴
关00/7兴
关00/7兴
关87/5兴
关1192-37-6兴
关79/17兴
关87/5兴关73/12兴
关628-71-7兴
关87/5兴关70/24兴
关84/9兴
关1119-65-9兴
关87/5兴关70/24兴
关84/9兴
关2586-89-2兴
关87/5兴关70/24兴
关84/9兴
关29974-68-3兴
关87/5兴关41/6兴
关73/18兴
关13654-91-6兴
关87/5兴关68/7兴
关73/18兴
关97/10兴
关497-37-0兴
关02/37兴
关98/2兴
关98/2兴
关502-42-1兴
关95/21兴
关95/21兴
关95/21兴
关87/5兴
关87/5兴关76/10兴
关98/22兴
关176-32-9兴
关98/21兴关02/32兴
关141-32-2兴
关96/5兴
关87/5兴关47/5兴
关106-63-8兴
关87/5兴
关539-87-7兴
关91/7兴
关91/7兴
关2210-28-8兴
关87/5兴
关2461-40-7兴
关87/14兴
关86/8兴
关10235-71-9兴
关87/5兴
ENTHALPIES OF VAPORIZATION
659
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H12O3
C7 H12O4
C7 H12O4
C7 H12O4
C7 H12O4
C7 H12O4
C7 H12O4
C7 H12O4
C7 H12O4
C7 H12O4
C7 H12O5
C7 H12O5
C7 H13ClO
C7 H13ClO2
C7 H13F3 O3
C7 H13N
C7 H13N
C7 H13NO
C7 H13NO
C7 H13NO
C7 H13NO
C7 H13NO2
C7 H13NO2
C7 H13NO3
C7 H13O6 P
C7 H14
C7 H14
Compound
共Temperature range/K兲
ethyl levulinate
共320– 480兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
58.3
51.6
共335兲
共420兲
A
共328兲
A
共358兲
A
2-acetoxypropionic acid, ethyl ester
共313– 454兲
57.9
3-acetoxypropionic acid, ethyl ester
共350–367兲
72.1
1,2-propylene glycol diacetate
共318 –367兲
54.9
diethyl malonate
共288 –318兲
64.7⫾0.2
共293–318兲
63.3
共384 – 468兲
59.9
共313– 472兲
51.2
dimethyl dimethylmalonate
共278 –307兲
55.6⫾0.8
glutaric acid, dimethyl ester
共366 – 483兲
54.7
methyl adipate
共453–503兲
82.9
heptanedioic acid 共pimelic acid兲
共436 – 615兲
88.6
2,4,8,10-tetraoxaspiro关5.5兴undecane
56.0
ethyl关共1-methoxycarbonyl兲ethyl兴carbonate
共343– 473兲
60.0
2-共lactyloxy兲propionic acid, methyl ester
共317–384兲
72.0
heptanoyl chloride
共307– 418兲
63.7
chloroacetic acid, neopentyl ester
共378 – 448兲
55.6
tris共2-fluoroethyl兲orthoformate
共273–333兲
59.7
2,2-dimethylpentanenitrile
共274 –303兲
46.9⫾0.4
heptanonitrile
共313– 473兲
46.0
共294 – 457兲
46.4
N-methylcaprolactam
共340– 400兲
49.4
2-butoxypropionitrile
共373– 423兲
46.7
2-methoxy-3,3-dimethylbutanenitrile
共295–324兲
58.8⫾1.1
2-methoxy-2-methylpentanenitrile
共278 –308兲
48.5⫾0.6
lactic acid, N-共methallyl兲 amide
共360– 428兲
81.8
N-lactylmorpholine
共371– 423兲
62.7
(dl) N-acetylalanine ethyl ester
共372– 460兲
65.2
Mevinphos
共293–383兲
68.1
cycloheptane
共282–333兲
38.6
共476 – 604兲
31.7
共333–398兲
36.4
共341– 433兲
36.1
38.5⫾0.2
methylcyclohexane
共295–333兲
36.2
35.1⫾0.4
Method
共323兲
CAS registry number
Reference
关539-88-8兴
关87/5兴关47/5兴
关31/1兴
关2985-28-6兴
关87/5兴
关40326-37-2兴
关87/5兴关73/18兴
关623-84-7兴
关01/19兴
关105-53-3兴
关92/13兴
关87/5兴
关87/5兴
关87/5兴关47/5兴
共293兲
共305兲
共399兲
共328兲
GS
A
A
A
共293兲
GS
共381兲
A
共468兲
A
共451兲
A
共358兲
A
关87/5兴
共332兲
A
共322兲
A
关87/5兴
关2528-61-2兴
关87/5兴关47/5兴
共393兲
A
共288兲
A
GS
共328兲
共309兲
A
共370兲
关92/13兴
关1119-40-0兴
关87/5兴
关627-91-8兴
关87/5兴
关111-16-0兴
关87/5兴关47/5兴
关126-54-5兴
关59/23兴
关87/5兴关99/16兴
关2339-51-7兴
关87/5兴关99/16兴
关94/5兴
关629-08-3兴
关87/5兴
关47/5兴
关2556-73-2兴
关84/18兴
共388兲
A
共298兲
GS
共298兲
GS
关87/5兴关73/18兴
关162047-91-8兴
关95/11兴
关162047-90-7兴
关95/11兴
共375兲
A
关87/5兴
共386兲
A
共387兲
A
共308兲
A
共297兲
共491兲
共348兲
共356兲
共298兲
A
A
A, EB
A, EB
关87/5兴
关5143-72-6兴
关87/5兴关73/18兴
关7786-34-7兴
关87/5兴
关291-64-5兴
关87/5兴
关87/5兴
关87/5兴关76/10兴
关87/5兴关56/20兴
关56/20兴
关108-87-2兴
关91/3兴
关87/17兴
共310兲
共298兲
GC
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
660
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共373–511兲
共501–573兲
共308 –368兲
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
共299–375兲
共273–348兲
1,1-dimethylcyclopentane
共284 –363兲
共289–362兲
cis 1,2-dimethylcyclopentane
共293–375兲
共298 –373兲
(dl) trans 1,2-dimethylcyclopentane
共295–367兲
共299–366兲
cis 1,3-dimethylcyclopentane
共295–366兲
共299–366兲
(dl) trans 1,3-dimethylcyclopentane
共295–367兲
共291–365兲
ethylcyclopentane
共308 –387兲
共386 –507兲
共499–569兲
共302–377兲
1-heptene
共311–368兲
共327–367兲
共295–318兲
共255–312兲
共273–362兲
cis 2-heptene
共276 –304兲
共276 –304兲
共315–372兲
共332–371兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
32.3
31.2
32.2
29.9
26.9
23.4
35.4⫾0.1
34.6⫾0.1
33.5⫾0.1
32.5⫾0.1
35.4
35.3
34.6
共388兲
共516兲
共353兲
共393兲
共433兲
共473兲
共298兲
共313兲
共333兲
共353兲
共298兲
共298兲
共323兲
31.8
34.9
36.1
共374兲
共314兲
共288兲
34.0
33.8
33.8
共299兲
共298兲
共304兲
A
35.5
35.8
35.2
共308兲
共298兲
共313兲
A
34.2
34.6
34.0
共310兲
共298兲
共314兲
A
34.2
34.3
32.8⫾0.1
31.7⫾0.1
30.4⫾0.1
34.0
共310兲
共298兲
共323兲
共342兲
共364兲
共314兲
A
34.0
34.5
34.2
共310兲
共298兲
共306兲
A
35.5
32.9
31.9
35.6⫾0.1
34.8⫾0.1
33.9⫾0.1
33.0⫾0.1
32.5⫾0.1
36.5
35.7
共323兲
共401兲
共514兲
共313兲
共328兲
共343兲
共358兲
共368兲
共298兲
共317兲
A
A
A
C
C
C
C
C
34.6
33.9
35.7
35.3
35.9
34.5
共326兲
共342兲
共298兲
共310兲
共300兲
共288兲
A
39.0⫾0.3
38.6
35.3
34.6
36.0
共290兲
共298兲
共330兲
共347兲
共298兲
Method
A
A
C
C
C
C
GCC
A
MM
C
C
C
MM
GS
GS
A
CAS registry number
Reference
关87/5兴
关87/5兴
关84/29兴
关84/29兴
关84/29兴
关84/29兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关78/16兴
关75/12兴
关87/5兴关70/25兴
关84/9兴
关46/11兴
关45/2兴
关40/5兴
关1638-26-2兴
关87/5兴
关71/28兴
关49/6兴
关1192-18-3兴
关87/5兴
关71/28兴
关49/6兴
关822-50-4兴
关87/5兴
关71/28兴
关49/6兴
关2532-58-3兴
关87/5兴
关71/28兴
关59/8兴
关59/8兴
关59/8兴
关49/6兴
关1759-58-6兴
关87/5兴
关71/28兴
关49/6兴
关1640-89-7兴
关87/5兴
关87/5兴
关87/5兴
关81/14兴
关81/14兴
关81/14兴
关81/14兴
关81/14兴
关71/28兴
关49/6兴
关592-76-7兴
关87/5兴
关70/24兴关84/9兴
关71/28兴
关50/6兴
关41/6兴
关36/3兴
关6443-92-1兴
关00/7兴
关00/7兴
关87/5兴
关70/24兴关84/9兴
关71/28兴
ENTHALPIES OF VAPORIZATION
661
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
Compound
共Temperature range/K兲
trans 2-heptene
共314 –373兲
共331–370兲
cis 3-heptene
共312–369兲
trans 3-heptene
共312–368兲
2-methyl-1-hexene
共318 –390兲
(dl) 3-methyl-1-hexene
共311–381兲
(dl) 4-methyl-1-hexene
共313–384兲
5-methyl-1-hexene
共313–393兲
2-methyl-2-hexene
共322–394兲
cis 3-methyl-2-hexene
共322–396兲
trans 3-methyl-2-hexene
共321–394兲
cis 4-methyl-2-hexene
共313–384兲
trans 4-methyl-2-hexene
共314 –385兲
cis 5-methyl-2-hexene
共354 –372兲
trans 5-methyl-2-hexene
共315–386兲
cis 2-methyl-3-hexene
共262–383兲
trans 2-methyl-3-hexene
共313–383兲
cis 3-methyl-3-hexene
共307–375兲
共302–368兲
trans 3-methyl-3-hexene
共310–368兲
共300–367兲
(dl) 2,3-dimethylpent-1-ene
共311–382兲
2,3-dimethylpent-2-ene
2,4-dimethylpent-1-ene
共311–361兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
35.3
36.0
34.6
共329兲
共298兲
共346兲
A
35.0
35.6
共327兲
共298兲
A
34.6
35.6
共327兲
共298兲
A
33.9
35.1
共333兲
共298兲
A
33.4
34.3
共326兲
共298兲
A
33.6
34.7
共328兲
共298兲
A
33.5
34.3
共328兲
共298兲
A
34.0
35.6
共337兲
共298兲
A
34.2
35.6
共337兲
共298兲
A
34.1
35.6
共336兲
共298兲
A
33.5
34.7
共328兲
共298兲
A
33.6
34.7
共329兲
共298兲
A
32.6
34.7
共363兲
共298兲
A
33.6
34.7
共330兲
共298兲
A
36.1
34.3
共277兲
共298兲
A
33.5
34.3
共328兲
共298兲
A
35.4
36.4
35.7
共322兲
共298兲
共317兲
A
34.8
35.8
35.3
共325兲
共298兲
共315兲
MM
33.4
共326兲
A
34.3
共298兲
32.3
33.1
共326兲
共298兲
Method
MM
A
A
CAS registry number
Reference
关14686-13-6兴
关87/5兴
关71/28兴
关70/24兴
关7642-10-6兴
关87/5兴
关71/28兴
关14686-14-7兴
关87/5兴
关71/28兴
关6094-02-6兴
关87/5兴关73/18兴
关71/28兴
关3404-61-3兴
关87/5兴关73/18兴
关71/28兴
关3769-23-1兴
关87/5兴关73/18兴
关71/28兴
关3524-73-0兴
关87/5兴关73/18兴
关71/28兴
关2738-19-4兴
关87/5兴关73/18兴
关71/28兴
关10574-36-4兴
关87/5兴关73/18兴
关71/28兴
关20710-38-7兴
关87/5兴关73/18兴
关71/28兴
关3683-19-0兴
关87/5兴关73/18兴
关71/28兴
关3683-22-5兴
关87/5兴关73/18兴
关71/28兴
关13151-17-2兴
关87/5兴关73/18兴
关71/28兴
关7385-82-2兴
关87/5兴关73/18兴
关71/28兴
关15840-60-5兴
关87/5兴关73/18兴
关71/28兴
关692-24-0兴
关87/5兴关73/18兴
关71/28兴
关4914-89-0兴
关87/5兴
关71/28兴
关60/20兴
关3899-36-3兴
关87/5兴
关71/28兴
关60/20兴
关3404-72-6兴
关87/5兴关73/18兴
关71/28兴
关2213-32-3兴
关87/5兴
关71/28兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
662
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14
C7 H14Br2
C7 H14Br2
C7 H14Cl2
C7 H14Cl2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
33.2
共304兲
MM
33.0
33.5
共321兲
共298兲
A
33.2
33.9
共324兲
共298兲
A
31.0
31.2
31.0
共314兲
共298兲
共315兲
A
34.2
35.6
共337兲
共298兲
A
35.2⫾1.5
34.5⫾1.5
34.5
34.3
34.2
共286兲
共298兲
共301兲
共298兲
共307兲
GS
GS
A
33.7
34.7
共331兲
共298兲
A
33.9
35.1
共332兲
共298兲
A
32.2
32.6
32.6
共318兲
共298兲
共306兲
A
32.8
32.8
33.0
共310兲
共298兲
共304兲
33.8
34.3
34.4
共318兲
共298兲
共305兲
36.6
35.1
共282兲
共298兲
A
33.4
34.3
共326兲
共298兲
A
34.1
35.6
共336兲
共298兲
A
共303兲
共298兲
共303兲
A
共288 –351兲
1,1-dibromoheptane
共395–548兲
32.4
34.3
32.1
MM
54.4
共410兲
A, EST
(dl) 1,2-dibromoheptane
共295–553兲
52.9
共310兲
A
54.4
共300兲
53.5
48.4
共298兲
共379兲
49.0
共368兲
Compound
共Temperature range/K兲
共289–355兲
3,3-dimethylpent-1-ene
共306 –374兲
(dl) 3,4-dimethylpent-1-ene
共309–378兲
4,4-dimethylpent-1-ene
共299–347兲
共290–346兲
2,3-dimethylpent-2-ene
共322–396兲
2,4-dimethylpent-2-ene
共276 –297兲
共276 –297兲
共286 –363兲
共292–357兲
cis 3,4-dimethylpent-2-ene
共316 –387兲
trans 3,4-dimethylpent-2-ene
共317–390兲
cis 4,4-dimethylpent-2-ene
共303–355兲
共291–354兲
trans 4,4-dimethylpent-2-ene
共295–352兲
共289–350兲
2-ethyl-3-methyl-1-butene
共303–381兲
共290–360兲
2-ethyl-1-pentene
共267–392兲
3-ethyl-1-pentene
共311–382兲
3-ethyl-2-pentene
共321–395兲
2,3,3-trimethyl-1-butene
共288 –353兲
共295–355兲
1,1-dichloroheptane
共375– 460兲
共364 –510兲
1,2-dichloroheptane
共353– 466兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
MM
MM
MM
A
MM
A
MM
A, EST
CAS registry number
Reference
关60/20兴
关3404-73-7兴
关87/5兴关73/18兴
关71/28兴
关7385-78-6兴
关87/5兴关73/18兴
关71/28兴
关762-62-9兴
关87/5兴
关71/28兴
关60/20兴
关10574-37-5兴
关87/5兴关73/18兴
关71/28兴
关625-65-0兴
关00/7兴
关00/7兴
关87/5兴
关71/28兴
关60/20兴
关4914-91-4兴
关87/5兴关73/18兴
关71/28兴
关4914-92-5兴
关87/5兴关73/18兴
关71/28兴
关762-63-0兴
关87/5兴
关71/28兴
关60/20兴
关690-08-4兴
关87/5兴
关71/28兴
关60/20兴
关7357-93-9兴
关87/5兴
关71/28兴
关60/20兴
关3404-71-5兴
关87/5兴关73/18兴
关71/28兴
关4038-04-4兴
关87/5兴关73/18兴
关71/28兴
关816-79-5兴
关87/5兴关73/18兴
关71/28兴
关594-56-9兴
关87/5兴
关71/28兴
关60/20兴
关59104-79-9兴
关87/5兴关56/16兴
关70/14兴
关42474-21-5兴
关87/5兴关73/18兴
关99/16兴
关41/6兴
关821-25-0兴
关87/12兴关91/2兴
关87/5兴关56/16兴
关70/14兴
关10575-87-8兴
关99/16兴
ENTHALPIES OF VAPORIZATION
663
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H14Cl2
C7 H14F2
C7 H14N2
C7 H14N2
C7 H14O
C7 H14O
C7 H14O
C7 H14O
C7 H14O
Compound
共Temperature range/K兲
共350– 470兲
1,7-dichloroheptane
共406 – 491兲
共410– 490兲
1,1-difluoroheptane
共311– 424兲
3-共diethylamino兲propionitrile
共338 – 470兲
2-共diethylamino兲propionitrile
共278 –315兲
1,2-epoxyheptane
共305– 414兲
cycloheptanol
共284 –323兲
共284 –321兲
1-methylcyclohexanol
共340– 430兲
2-methylcyclohexanol
共323–373兲
cis 2-methylcyclohexanol
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
53.2
共298兲
52.3
61.2
共421兲
共298兲
41.1
共326兲
A, EST
53.7
共353兲
A
50.8⫾0.3
Method
GS
45.5
共320兲
A
64.7
67.4
共299兲
共299兲
A
49.1
共355兲
A
63.3
共298兲
CGC
65.5
共298兲
CGC
54.3
共355兲
A
50.0
共365兲
A
65.9
共298兲
CGC
49.9
共355兲
A
52.1
共355兲
A
58.4
共362兲
A
46.1
48.5
47.5
39.1
47.4⫾0.3
47.2⫾0.1
44.7
48.0
46.9
50.9
48.0
共298兲
共298兲
共318兲
共464兲
共298兲
共298兲
共342兲
共298兲
共324兲
共307兲
共288兲
CGC
CGC
A
A
GCC
C
47.8
46.2⫾0.4
45.5
46.7
57.5
40.7
共298兲
共298兲
共319兲
共298兲
共311兲
共303兲
CGC
GCC
A
41.3
共311兲
A
42.3⫾0.1
42.3⫾0.1
共298兲
共298兲
C
C
39.4
41.6⫾0.1
41.5⫾0.1
共336兲
共298兲
共298兲
A
C
C
61.8
C7 H14O
C7 H14O
C7 H14O
C7 H14O
C7 H14O
C7 H14O
C7 H14O
C7 H14O
3-methylcyclohexanol
共323–373兲
(dl) cis 3-methylcyclohexanol
共340– 450兲
(dl) trans 3-methylcyclohexanol
共350– 450兲
4-methylcyclohexanol
共323–373兲
cis 4-methylcyclohexanol
共340– 450兲
trans 4-methylcyclohexanol
共340–350兲
1-ethyl-1-cyclopentanol
共347– 426兲
2-heptanone
共343–383兲
共343–383兲
共303– 424兲
共449– 480兲
共327– 457兲
C7 H14O
共309– 424兲
共292– 423兲
共273–348兲
4-heptanone
共343–383兲
共304 – 490兲
C7 H14O
C7 H14O
C7 H14O
共296 – 417兲
共283–323兲
2-methyl-3-hexanone
共296 – 406兲
2,2-dimethyl-3-pentanone
2,4-dimethyl-3-pentanone
共321–399兲
EB
A
CAS registry number
Reference
关82/12兴关91/2兴
关821-76-1兴
关99/16兴
关88/11兴关91/2兴
关407-96-5兴
关87/5兴关56/16兴
关70/14兴
关5351-04-2兴
关87/5兴
关97/10兴
关5063-65-0兴
关87/5兴关70/28兴
关502-41-0兴
关87/5兴
关75/1兴
关590-67-0兴
关87/5兴
关583-59-5兴
关95/21兴
关7443-70-1兴
关75/39兴
关591-23-1兴
关95/21兴
关24965-90-0兴
关87/5兴
关23068-71-5兴
关87/5兴
关589-91-3兴
关95/21兴
关7731-28-4兴
关87/5兴
关7731-29-5兴
关87/5兴
关1462-96-0兴
关87/5兴关73/18兴
关110-43-0兴
关95/21兴
关95/21兴
关87/5兴
关87/5兴
关79/7兴
关79/1兴
关87/5兴关75/8兴
关75/8兴
关66/12兴
关47/5兴
关40/5兴
关123-19-3兴
关95/21兴
关79/7兴
关87/5兴关75/8兴
关75/8兴
关87/5兴关47/5兴
关37/9兴
关7379-12-6兴
关87/5兴
关564-04-5兴
关70/18兴
关66/2兴
关565-80-0兴
关87/5兴关73/18兴
关70/18兴
关66/2兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
664
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H14O
C7 H14O
C7 H14O
C7 H14O2
C7 H14O2
Compound
共Temperature range/K兲
heptanal
共313–353兲
共285– 428兲
3-methylhexanal
共314 – 417兲
3,4-dimethylpentanal
共319– 417兲
1,1-dimethoxycyclopentane
共278 –318兲
共307–343兲
methyl hexanoate
共313–363兲
共313–353兲
C7 H14O2
C7 H14O2
C7 H14O2
共315–383兲
butyl propionate
共305– 417兲
共305–365兲
ethyl pivalate
共308 – 429兲
共308 – 429兲
共308 – 429兲
C7 H14O2
ethyl isovalerate
共301– 418兲
共267– 407兲
isobutyl propionate
共271– 410兲
isopentyl acetate
共230– 435兲
共278 –305兲
共278 –305兲
共308 – 424兲
共313–368兲
isopropyl isobutyrate
共257–394兲
4-methoxy-4-methyl-2-pentanone
共343– 423兲
methyl tert-butylacetate
共274 –313兲
neopentyl acetate
共301– 400兲
tert-pentyl acetate
共274 –308兲
pentyl acetate
共321– 462兲
共329– 423兲
propyl butyrate
共390– 430兲
共355– 416兲
共271– 416兲
propyl isobutyrate
共267– 407兲
ethyl 2-methylbutanoate
共288 –308兲
butyl glycidyl ether
C7 H14O2
tert-butyl glycidyl ether
C7 H14O2
C7 H14O2
C7 H14O2
C7 H14O2
C7 H14O2
C7 H14O2
C7 H14O2
C7 H14O2
C7 H14O2
C7 H14O2
C7 H14O2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
48.7
47.3⫾0.1
62.0
共298兲
共298兲
共300兲
CGC
42.8
共329兲
EB
42.4
共334兲
EB
44.5⫾0.3
46.1
共298兲
共325兲
GS
EB
45.2
46.4⫾0.1
47.7⫾0.1
47.9
48.2
47.8⫾0.5
48.7⫾0.3
48.0⫾0.1
45.3
共350兲
共325兲
共298兲
共298兲
共298兲
共298兲
共298兲
共298兲
共330兲
CGC
CGC
GC
GCC
C
A
49.1
47.4
共320兲
共320兲
A
39.8⫾0.1
36.9⫾0.2
33.8⫾0.6
41.3⫾0.1
共320兲
共360兲
共400兲
共298兲
EB
EB
EB
C
42.8
44.5
共316兲
共282兲
A
44.9
共286兲
A
46.4
46.8⫾0.2
46.4⫾0.2
44.3
45.1
共300兲
共292兲
共298兲
共323兲
共328兲
GS
GS
A
43.3
共272兲
A
45.0
共358兲
A
44.4⫾0.2
共298兲
GS
49.1
共316兲
A
42.8⫾0.3
共298兲
GS
48.6⫾0.4
43.2
共298兲
共344兲
EB
A
39.6
42.0
44.3
共405兲
共370兲
共286兲
A
50.5
共282兲
A
64.7
共298兲
GS
53.3⫾0.4
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
关111-71-7兴
关95/21兴
关81/18兴
关47/5兴
关19269-28-4兴
关87/10兴
关19353-21-0兴
关87/10兴
关931-94-2兴
关98/21兴关02/32兴
关94/16兴
关106-70-7兴
关02/27兴
关02/27兴
关02/27兴
关95/21兴
关95/21兴
关87/17兴
关80/5兴
关77/1兴
关87/5兴关63/16兴
关590-01-2兴
关87/5兴
关59/13兴关84/9兴
关3938-95-2兴
关02/16兴
关02/16兴
关02/16兴
关66/2兴
关108-64-5兴
关87/5兴
关47/5兴
关540-42-1兴
关87/5兴关47/5兴
关123-92-2兴
关99/27兴
关99/4兴
关99/4兴
关87/5兴
关59/15兴关84/9兴
关617-50-5兴
关87/5兴关47/5兴
关107-70-0兴
关87/5兴
关10250-48-3兴
关96/11兴
关926-41-0兴
关87/5兴
关625-16-1兴
关96/11兴
关628-63-7兴
关96/3兴
关87/5兴
关105-66-8兴
关95/17兴
关93/8兴
关87/5兴关47/5兴
关644-49-5兴
关87/5兴关47/5兴
关92/13兴
关2426-08-6兴
关87/14兴
关7665-72-7兴
ENTHALPIES OF VAPORIZATION
665
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
关87/14兴
50.2⫾0.4
C7 H14O2
2,2,4-trimethyl-1,3-dioxane
C7 H14O2
2-methyl-2-propyl-1,3-dioxolane
共278 –313兲
2-methyl-2-isopropyl-1,3-dioxolane
共274 –303兲
共273–303兲
关共1-methylpropoxy兲methyl兴oxirane
C7 H14O2
C7 H14O2
41.9⫾1.2
共298兲
46.3⫾0.3
共298兲
GS
43.9⫾0.2
44.6⫾0.2
共298兲
GS
GS
共306兲
共298兲
共298兲
共266兲
共298兲
共366兲
GS
GS
CGC
共298兲
C
共354兲
A
共327兲
A
共363兲
A
关67/37兴
关4352-98-1兴
关98/21兴关02/32兴
关4405-16-7兴
关02/32兴
关98/21兴
关3814-55-9兴
关87/14兴
关111-14-8兴
关00/6兴
关00/6兴
关95/21兴
关82/4兴
关79/4兴
关87/5兴关47/5兴
关33415-52-0兴
关87/14兴
关20706-25-6兴
关70/17兴
关138-22-7兴
关87/5兴
关763-69-9兴
关87/5兴
关768-63-8兴
关87/5兴关77/9兴
共344兲
A
关87/5兴
共371兲
A
共338兲
A
共338兲
A
共407兲
A
共388兲
A
共332兲
共329兲
共298兲
A, EB
EB
共356兲
共298兲
共298兲
共298兲
共348兲
CGC
C
C
A, EST
共348兲
A
关87/5兴关73/18兴
关5349-56-4兴
关87/5兴
关14144-39-9兴
关87/5兴
关557-25-5兴
关87/5兴
关14620-87-2兴
关87/5兴关73/18兴
关37850-75-2兴
关99/16兴
关87/5兴关62/16兴
关62/16兴
关629-04-9兴
关99/16兴
关95/21兴
关68/1兴
关66/2兴
关87/5兴关61/13兴
关1974-04-5兴
关87/5兴关99/16兴
关629-06-1兴
关99/16兴
关95/21兴
关84/9兴关91/2兴
关87/5兴关69/5兴
关68/1兴
关1001-89-4兴
关87/5兴关99/16兴
关52802-03-6兴
关87/5兴关48/13兴
关73/18兴
关621-68-1兴
关87/5兴关48/13兴
45.2⫾1.8
C7 H14O2
heptanoic acid
共283–328兲
共283–328兲
共353–393兲
C7 H14O3
共271–291兲
共351– 495兲
tert-butylperoxymethyloxirane
C7 H14O3
2-propoxyethylacetate
72.5⫾0.8
72.9⫾0.8
75.7
76.0
72.0⫾1.5
68.3
TE
A
53.9⫾0.4
C7 H14O3
C7 H14O3
C7 H14O3
C7 H14O3
C7 H14O3
C7 H14O3
C7 H14O3
C7 H14O3
C7 H14O3
C7 H14S
C7 H15Br
C7 H15Br
C7 H15Cl
C7 H15Cl
C7 H15Cl2 N
C7 H15Cl2 N
55.6⫾0.1
(dl) butyl lactate
共339– 456兲
58.7
3-ethoxypropionic acid, ethyl ester
共312– 446兲
45.5
1-heptene ozonide
共353–373兲
44.4
4-共2-hydroxyethyl兲-4-methyl-1,3-dioxane
共329– 455兲
51.7
3-hydroxypropionic acid, butyl ester
共361–382兲
60.3
3-methoxypropionic acid, propyl ester
共323– 433兲
47.0
3-propoxypropionic acid, methyl ester
共323– 453兲
46.6
(dl) butyric acid, 2,3-dihydroxypropyl ester
共392– 449兲
80.4
2-butoxypropionic acid
共373– 473兲
52.8
allyl tert-butyl sulfide
共319–339兲
41.9
共319–339兲
43.1
共319–339兲
44.8
1-bromoheptane
共341– 481兲
47.0
共323–363兲
50.2
50.8⫾0.1
50.4⫾0.2
共333– 483兲
47.5
(dl) 2-bromoheptane
共333– 440兲
45.0
1-chloroheptane
共326 – 462兲
45.1
共313–353兲
47.9
共300– 430兲
47.0
共307– 434兲
46.9
47.7⫾0.1
(dl) 2-chloroheptane
共313– 424兲
44.8
N-methyl-bis共2-chloropropyl兲amine
共273–333兲
54.6
N-propyl-bis共2-chloroethyl兲amine
共273–369兲
CAS registry number
Reference
56.8
共341兲
共298兲
共298兲
共322兲
共298兲
A, DTA
C
共328兲
A
共288兲
A, GS
共288兲
A, GS
CGC
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
666
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H15F
C7 H15I
C7 H15N
C7 H15N
C7 H15NO
C7 H15NO
C7 H15NO2
C7 H15NO2
C7 H15NO2
C7 H15NO2
C7 H15NO2
C7 H16
C7 H16
C7 H16
C7 H16
Compound
共Temperature range/K兲
1-fluoroheptane
共294 – 416兲
共287– 417兲
1-iodoheptane
共373–513兲
⌬ vapH m
共kJ mol⫺1兲
Method
CAS registry number
Reference
关73/18兴
关661-11-0兴
关99/18兴
关87/5兴关61/13兴
关4282-40-0兴
关87/5兴关61/13兴
关70/14兴
关766-09-6兴
关98/12兴
关98/12兴
关1121-92-2兴
关87/5兴
40.3
40.8
共309兲
共302兲
A, EST
47.8
共388兲
A, EST
共294兲
共298兲
GS
GS
共288兲
A
共298兲
ME
共298兲
GS
共293兲
GS
共380兲
A
关92/13兴
关30220-58-7兴
关87/5兴
共383兲
A
关87/5兴
共403兲
A
共366兲
A
关87/5兴
关2666-93-5兴
关87/5兴
关142-85-5兴
关02/8兴
关94/12兴
关84/27兴
关84/15兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关71/28兴
关67/10兴
关87/5兴关49/6兴
关47/10兴
关47/10兴
关46/4兴
关45/2兴
关40/6兴
关40/14兴
关591-76-4兴
关87/5兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关71/28兴
关61/16兴
关49/6兴
关589-34-4兴
关87/5兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关71/28兴
关49/6兴
关590-35-2兴
关98/16兴
关98/16兴
N-ethylpiperidine
共274 –313兲
41.1⫾0.6
共274 –313兲
40.8⫾0.6
octahydroazocine
共273–313兲
46.5
N,N-dimethyl-tert-butylcarboxamide
55.1⫾0.4
1-共diethylamino兲-2-propanone
共278 –318兲
47.7⫾0.3
methyl 2-共N,N-dimethylamino兲-2-methylpropanoate
共278 –308兲
49.2⫾1.0
lactic acid, N-butylamide
共365– 433兲
77.4
lactic acid, N-sec-butylamide
共368 – 418兲
74.6
lactic acid, N-isobutylamide
共388 – 418兲
73.5
共l兲 leucine methyl ester
共320–353兲
39.4
heptane
共330–371兲
34.7
36.6
共298 –363兲
36.1
共298 –338兲
36.1
36.6⫾0.1
35.6⫾0.1
34.4⫾0.1
33.1⫾0.1
36.55
共288 –348兲
36.4
共297–375兲
36.1
34.5⫾0.1
33.2⫾0.1
共313–398兲
35.4
共299–372兲
36.0
32.0
共310–397兲
35.5
2-methylhexane
共296 –365兲
34.6
34.9⫾0.1
33.9⫾0.1
32.7⫾0.1
31.3⫾0.1
34.8
共273–318兲
34.8
共291–364兲
34.8
(dl) 3-methylhexane
共289–366兲
35.1
35.1⫾0.1
34.2⫾0.1
32.9⫾0.1
31.7⫾0.1
35.1
共293–366兲
34.9
2,2-dimethylpentane
32.4⫾0.1
31.8⫾0.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
共345兲
共298兲
共313兲
共313兲
共298兲
共313兲
共333兲
共353兲
共298兲
共303兲
共312兲
共331兲
共350兲
共328兲
共314兲
共371兲
共325兲
C
C
C
C
A
C
C
MM
C
EB
共311兲
共298兲
共313兲
共333兲
共353兲
共298兲
共298兲
共306兲
A
C
C
C
C
共304兲
共298兲
共313兲
共333兲
共353兲
共298兲
共308兲
A
C
C
C
C
共298兲
共308兲
C
C
关95/3兴关93/19兴
关1620-14-0兴
关94/3兴
ENTHALPIES OF VAPORIZATION
667
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共277–354兲
共353– 483兲
共285–353兲
C7 H16
共288 –353兲
(dl) 2,3-dimethylpentane
共309–371兲
共208 –286兲
共286 –365兲
共291–364兲
C7 H16
3,3-dimethylpentane
共213–281兲
共280–360兲
共287–360兲
C7 H16
共285–360兲
3-ethylpentane
共291–368兲
C7 H16
共294 –367兲
共308 –391兲
2,2,3-trimethylbutane
共284 –355兲
共353– 483兲
共286 –355兲
C7 H16N2 S
Mean temperature
(T m /K)
31.4⫾0.1
31.0⫾0.1
30.5⫾0.1
30.1⫾0.1
29.4⫾0.1
28.8⫾0.1
28.1⫾0.1
33.2
30.1
32.8
32.4⫾0.1
32.2⫾0.1
32.6
共315兲
共323兲
共330兲
共338兲
共348兲
共358兲
共368兲
共292兲
共368兲
共300兲
共298兲
共298兲
共303兲
33.0
35.9
34.3⫾0.1
33.4⫾0.1
32.2⫾0.1
31.1⫾0.1
34.5
34.4
34.2⫾0.1
共324兲
共271兲
共298兲
共313兲
共333兲
共353兲
共301兲
共306兲
共298兲
32.7⫾0.1
32.3⫾0.1
31.9⫾0.1
31.5⫾0.1
31.0⫾0.1
30.6⫾0.1
30.0⫾0.1
33.3
33.2
32.9⫾0.1
共298兲
共308兲
共315兲
共323兲
共330兲
共338兲
共348兲
共299兲
共302兲
共298兲
34.8
33.6
33.0⫾0.1
33.0
33.2
33.0⫾0.1
33.3
共266兲
共295兲
共298兲
共298兲
共302兲
共298兲
共300兲
35.1⫾0.1
34.5⫾0.1
34.1⫾0.1
33.7⫾0.1
33.3⫾0.1
32.7⫾0.1
32.2⫾0.1
35.2
35.2
35.2⫾0.1
35.0
34.4
共298兲
共308兲
共315兲
共232兲
共330兲
共338兲
共348兲
共306兲
共298兲
共298兲
共309兲
共323兲
32.4
29.9
32.0
32.3
31.2⫾0.1
31.9
共299兲
共368兲
共298兲
共301兲
共314兲
共311兲
C
EB
107⫾3.0
共370兲
ME, TE
Method
C
C
C
C
C
C
C
A
A
C
C
MM
A
C
C
C
C
C
2,4-dimethylpentane
共284 –355兲
共287–354兲
C7 H16
⌬ vapH m
共kJ mol⫺1兲
共296 –378兲
1,3-dipropylthiourea
共346 –394兲
C
C
C
C
C
C
C
A
C
C
C
MM
C
C
C
C
C
C
C
C
EB
A
A
CAS registry number
Reference
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关87/5兴
关87/5兴
关49/6兴
关47/7兴
关47/7兴
关45/2兴
关565-59-3兴
关99/10兴
关87/5兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关87/5兴关73/18兴
关49/6兴
关47/7兴
关108-08-7兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关87/5兴关73/18兴
关49/6兴
关47/7兴
关562-49-2兴
关87/5兴
关87/5兴
关81/9兴
关71/28兴
关49/6兴
关47/7兴
关87/5兴关45/2兴
关617-78-7兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关87/5兴
关71/28兴
关47/7兴
关45/2兴
关41/9兴关84/9兴
关464-06-2兴
关87/5兴
关87/5兴
关71/28兴
关49/6兴
关47/10兴
关41/9兴
关26536-60-7兴
关94/21兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
668
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H16O
C7 H16O
Compound
共Temperature range/K兲
共318 –374兲
共320–374兲
propyl tert-butyl ether
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
C7 H16O
39.2⫾0.4
38.2⫾0.2
35.7
35.6
共298兲
共298兲
共333兲
共335兲
C
EB
EB
38.3
37.2⫾0.6
36.6⫾0.2
共298兲
共298兲
共298兲
EB
C
36.2
34.4⫾0.6
34.5⫾0.2
34.0
共298兲
共298兲
共298兲
共322兲
EB
C
EB
66.5
66.4
65.2
62.5
66.8⫾0.2
65.2
62.6
62.9
共298兲
共298兲
共310兲
共350兲
共298兲
共348兲
共351兲
共348兲
66.1
54.4
51.6
59.8
共259兲
共366兲
共372兲
共338兲
67.0
60.3
64.7
53.1
59.2
共259兲
共340兲
共280兲
共364兲
共343兲
58.2
53.1
63.1
56.9
共335兲
共364兲
共297兲
共335兲
53.5
共390兲
57.4
共399兲
62.6
共363兲
54.5
共326兲
49.4
共388兲
55.7
共338兲
53.6
共338兲
50.3
共388兲
49.7
共343兲
51.4
共333兲
53.2
共333兲
51.8
48.8
共328兲
共343兲
Method
isopropyl tert-butyl ether
共305–360兲
C7 H16O
Mean temperature
(T m /K)
tert-amyl ethyl ether
共315–370兲
C7 H16O
⌬ vapH m
共kJ mol⫺1兲
共307–360兲
1-heptanol
共323–373兲
共373– 423兲
共258 –363兲
共335– 450兲
共333– 449兲
共336 – 450兲
共333– 425兲
(dl) 2-heptanol
共244 –338兲
共351– 433兲
共357– 431兲
共323– 433兲
(dl) 3-heptanol
共244 –333兲
共325– 430兲
共263–295兲
共349– 430兲
共328 – 429兲
4-heptanol
共320– 428兲
共349– 428兲
共282–320兲
共320– 428兲
2-methyl-1-hexanol
共343– 438兲
3-methyl-1-hexanol
共353– 445兲
4-methyl-1-hexanol
共348 – 448兲
2-methyl-2-hexanol
共311– 415兲
5-methyl-2-hexanol
共348 – 428兲
2-methyl-3-hexanol
共323– 420兲
3-methyl-3-hexanol
共323– 416兲
3,4-dimethyl-1-pentanol
共393– 438兲
2,4-dimethyl-2-pentanol
共328 – 408兲
2,2-dimethyl-3-pentanol
共318 – 411兲
2,3-dimethyl-3-pentanol
共318 – 413兲
2,4-dimethyl-3-pentanol
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CGC
CGC
A
C
DTA
A
A
A
A
A
A
C
C
CAS registry number
Reference
关919-94-8兴
关U/2兴关02/32兴
关02/22兴
关02/22兴
关94/10兴
关29072-93-3兴
关U/2兴关02/32兴
关02/10兴
关02/10兴
关17348-59-3兴
关U/2兴关02/32兴
关02/10兴
关02/10兴
关94/10兴
关111-70-6兴
关95/21兴
关95/21兴
关92/14兴
关87/5兴
关77/1兴
关73/26兴
关87/5兴关69/5兴
关35/6兴关84/9兴
关543-49-7兴
关99/11兴
关84/10兴
关87/5兴关75/23兴
关73/26兴
关589-82-2兴
关99/11兴
关87/5兴
关87/5兴关79/16兴
关84/10兴
关73/26兴
关589-55-9兴
关87/5兴
关84/10兴
关87/5兴关75/1兴
关73/26兴
关624-22-6兴
关73/26兴
关13231-81-7兴
关73/26兴
关818-49-5兴
关73/26兴
关625-23-0兴
关87/5兴关73/26兴
关627-59-8兴
关73/26兴
关617-29-8兴
关73/26兴
关597-96-6兴
关73/26兴
关6570-87-2兴
关73/26兴
关625-06-9兴
关73/26兴
关3970-62-5兴
关73/26兴
关595-41-5兴
关73/26兴
关600-36-2兴
关96/6兴
关96/6兴
ENTHALPIES OF VAPORIZATION
669
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
45.7
53.6
共358兲
共322兲
C
A
51.3
55.2
共332兲
共323兲
A
55.7
共373兲
48.7
共313兲
MM
47.8⫾0.1
共298兲
C
46.8⫾0.1
共298兲
C
45.9⫾0.2
2,2-diethoxypropane
共273–308兲
43.2⫾0.4
共273–308兲
43.9
共286 –304兲
U28.2
1-tert-butoxy-2-propanol
共346 – 420兲
45.4
4-methyl-4-methoxy-2-pentanol
共343– 423兲
46.6
diethylene glycol monopropyl ether
共369– 404兲
65.3
2-共2-propoxyethoxy兲ethanol
共378 – 495兲
65.7⫾0.8
triethoxymethane
共293–323兲
49.0
46.0⫾0.8
共278 – 419兲
47.2
3,5,7,9-tetraoxaundecane
53.6⫾0.7
tert-pentylperoxyethanol
70.1⫾2.5
3-tert-butyldioxy-1,2-propanediol
88.0⫾2.6
1-heptanethiol
共273–345兲
49.5
50.6⫾0.2
共373– 472兲
45.0
共298兲
C
共298兲
共295兲
GS
GS
A, I
共361兲
EB
共358兲
A
共384兲
A
共298兲
EB
共308兲
共298兲
共293兲
A
共298兲
C
共288兲
共298兲
共388兲
A, EB
44.1
47.2
44.2
共358兲
共360兲
共356兲
A
59.0
共407兲
A
35.7⫾1.0
共287兲
42.1⫾0.1
40.9⫾0.1
39.9⫾0.1
38.7⫾0.1
37.6⫾0.1
40.0
共298兲
共313兲
共328兲
共343兲
共358兲
共340兲
C
C
C
C
C
C
49.9
46.5
50.0⫾0.1
共298兲
共341兲
共298兲
CGC
A
C
39.6
共300兲
A
Compound
共Temperature range/K兲
C7 H16O2
共307– 412兲
3-ethyl-3-pentanol
共317– 408兲
共308 – 416兲
2-methyl-2-ethyl-1-butanol
共358 – 428兲
2,3,3-trimethyl-2-butanol
共298 –363兲
1-butoxy-2-methoxyethane
C7 H16O2
1-propoxy-2-ethoxyethane
C7 H16O2
1,3-diethoxypropane
C7 H16O
C7 H16O
C7 H16O
C7 H16O2
C7 H16O2
C7 H16O2
C7 H16O3
C7 H16O3
C7 H16O3
C7 H16O3
C7 H16O3
C7 H16O4
C7 H16S
C7 H16S
C7 H16S2
C7 H17N
C7 H17N
C7 H17N
C7 H17NO
2-heptanethiol
共343– 437兲
共343– 471兲
共341– 443兲
1,7-heptanedithiol
共392–526兲
tert-butylisopropylamine
共275–299兲
N-butyl isopropylamine
共325–395兲
heptylamine
共323–373兲
共326 – 430兲
N-共ethoxymethyl兲diethylamine
共285– 400兲
CAS registry number
Reference
关96/6兴
关87/5兴关73/26兴
关597-49-9兴
关87/5兴关73/18兴
关73/26兴
关18371-13-6兴
关73/26兴
关594-83-2兴
关85/5兴
关13343-98-1兴
关70/17兴
关18854-31-4兴
关70/17兴
关3459-83-4兴
关72/42兴
关126-84-1兴
关02/32兴
关98/21兴
关87/5兴关62/14兴
关57018-52-7兴
关01/6兴
关141-73-1兴
关87/5兴关73/18兴
关6881-94-3兴
关87/5兴
关6881-94-3兴
关96/3兴
关122-51-0兴
关87/5兴
关71/26兴
关87/5兴关47/5兴
关4431-82-7兴
关69/18兴
关51452-08-5兴
关83/11兴
关38578-50-6兴
关83/11兴
关1639-09-4兴
关99/16兴
关66/10兴关66/5兴
关87/5兴关65/8兴
关66/5兴
关628-00-2兴
关99/16兴
关99/16兴
关87/5兴关73/18兴
关62224-02-6兴
关87/5兴关73/18兴
关99/16兴
关97/21兴
关39099-23-5兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关79/8兴
关111-68-2兴
关95/21兴
关87/5兴
关69/2兴
关7352-03-6兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
670
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C7 H17O2 PS3
C7 H18N2
C7 H17N2
C7 H18N2 O
C7 H18N3
C7 H20N4
C8 F8 O2
C8 F8 O4
C8 F16
C8 F16
C8 F16
C8 F16N2
C8 F16O
C8 F18
C8 F18N2 OS
C8 F18N2 S
C8 F18O
C8 F18O2
C8 F18O3 S
C8 F20N2 S
C8 HCl4 F11O2
C8 HF16NO
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
O,O-diethyl-S-关共ethylthio兲methyl兴dithiophosphate
共283–387兲
70.8
Mean temperature
(T m /K)
Method
共298兲
A
N,N-diethyl-1,3-propanediamine
共329– 443兲
46.4
共344兲
1,7-heptanediamine
共273–313兲
46.5
共288兲
1,3-bis共dimethylamino兲-2-propanol
共355– 450兲
50.3
共370兲
N,N-diethyl-2-共1-methylhydrazino兲ethanamine
共283–313兲
61.8
共298兲
1,4,8,11-tetraazaundecane
共332–348兲
98.3⫾1.3
共340兲
共332–348兲
100.0⫾2.5
共298兲
trifluoroacetic acid, pentafluorophenyl ester
42.1
carbonoperoxoic acid, O-共pentafluorophenyl兲 O,O-共trifluoromethyl兲 ester
51.8
perfluoroethylcyclohexane
共308 –512兲
37.2
共323兲
共310– 400兲
38.6
共298兲
38.7⫾0.4
共298兲
共311– 411兲
37.1
共326兲
perfluoro-1,3-dimethylcyclohexane
共308 –375兲
37.4
共323兲
cis/trans perfluoro-1,3-dimethylcyclohexane
38.6⫾0.1
共298兲
2,2,2-trifluoro-N⬘-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-N-关2,2,2-trifluoro-1共trifluoromethyl兲ethylidine兴ethanimidamide
32.8
perfluoro-2-butyltetrahydrofuran
共383– 433兲
34.7
共408兲
perfluorooctane
共437–503兲
32.0
共452兲
共309–378兲
41.2⫾0.8
共298兲
41.1⫾0.1
共298兲
共310–379兲
39.5
共325兲
bis共1,1,1,3,3,3-hexafluoro-2-propanaminato兲oxobis共trifluoromethyl兲 sulfur
共273–333兲
39.6
共288兲
S,S-bis共trifluoromethyl兲-N-关2,2,2-trifluoro-1-共trifluoromethyl兲-1关共2,2,2-trifluoro-1-关trifluoromethyl兴ethylidine兲amino兴ethyl sulfilimine
共329–373兲
41.1
共344兲
bis共nonafluorobutyl兲 ether
共315–374兲
40.3⫾0.8
共298兲
40.7⫾0.1
共298兲
共343–375兲
36.6
共358兲
共288 –313兲
42.2
共300兲
共374 – 413兲
56.3
共389兲
dodecafluoro-1,6-bis共trifluoromethoxy兲hexane
共293–353兲
33.6
共323兲
bis共1,1,1,3,3,3-hexafluoro-2-共trifluoromethyl兲-2-propanol兲 sulfite
38.7
difluoro关1,1,1,3,3,3-hexafluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲-ethylidene兴2,2-propanediaminato共2-兲-N兴-bis共trifluoromethyl兲 sulfur
39.3
共390兲
3,5,7,8-tetrachloro-2,2,3,4,4,5,6,6,7,8,8-undecafluorooctanoic acid
共373–553兲
70.6 6
共388兲
1,1,1,2,3,3,3-heptafluoro-N-关2,2,2-trifluoro-1-关2,2,2-trifluoro-1共trifluoromethyl兲ethoxy兴ethylidene兴-2-propanamine
36.0
共364兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
A
A
TE
TE
A
C
CAS registry number
Reference
关298-02-2兴
关87/5兴关73/18兴
关99/16兴
关104-78-9兴
关87/5兴
关646-19-5兴
关87/5兴
关5966-51-8兴
关87/5兴
关67727-91-7兴
关87/5兴
关4741-99-5兴
关83/16兴
关83/16兴
关14533-84-7兴
关76/31兴
关59483-83-9兴
关76/30兴
关335-21-7兴
关99/16兴
关84/9兴关91/2兴
关81/23兴
关87/5兴关70/14兴
关59/12兴关99/16兴
关335-27-3兴
关99/16兴
关96/26兴
关57682-63-0兴
关75/42兴
EST
EB
C
A
A
A
EB
C
A
A
A
关60/27兴
关307-34-6兴
关99/16兴
关81/23兴
关81/23兴
关87/5兴关62/4兴
关70/14兴
关66632-47-1兴
关87/5兴关78/14兴
关99/16兴
关37826-45-2兴
关87/5兴关72/21兴
关308-48-5兴
关89/13兴
关89/13兴
关87/5兴
关87/5兴
关87/5兴关99/16兴
关99/16兴
关53517-90-1兴
关75/43兴
关65844-11-3兴
I
A
关78/14兴
关2923-68-4兴
关87/5兴关57/17兴
关99/16兴
关54181-87-2兴
关75/20兴
ENTHALPIES OF VAPORIZATION
671
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H2 F16
C8 H3 ClF6
C8 H3 ClF6
C8 H3 Cl4 F3
C8 H3 F5 O2
C8 H3 F15O
C8 H4 ClF3 O
C8 H4 Cl2 O2
C8 H4 Cl2 O2
C8 H4 Cl2 O2
C8 H4 Cl3 F3
C8 H4 F6
C8 H4 F6
C8 H4 O3
C8 H5 Cl2 F3
C8 H5 Cl2 N
C8 H5 Cl5
C8 H5 F5 O
C8 H5 F14OP
C8 H5 NO
C8 H6
C8 H6 BrN
C8 H6 Cl2
C8 H6 Cl2
C8 H6 Cl2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共310兲
A
1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-hexadecafluorooctane
共298 –323兲
41.1
4-chloro-1,3-bis共trifluoromethyl兲benzene
共275–353兲
48.0
共290兲
5-chloro-1,3-bis共trifluoromethyl兲benzene
共275–353兲
46.2
共290兲
A
共432兲
A
共298兲
A
共365兲
A
共386兲
A
共458兲
A
共406兲
A
共463兲
A
共431兲
共402兲
A
共290兲
A
共302兲
A
共422兲
共422兲
A
共380兲
A
共344兲
A
共384兲
A
共357兲
A
1,1,1-trifluoro-2,2-dichloro-2-共3,4-dichlorophenyl兲ethane
共417– 461兲
56.9
acidic acid, pentafluorophenyl ester
共283–322兲
48.1
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol
共350– 437兲
53.3
trifluoromethyl 3-chlorophenyl ketone
共366 – 405兲
52.7
isophthaloyl chloride
共443–550兲
61.5
phthaloyl chloride
共391–549兲
58.0
terephthaloyl chloride
共454 – 473兲
56.2
1,1,1-trifluoro-2,2-dichloro-共3-chlorophenyl兲ethane
共387– 475兲
49.6
共387– 474兲
50.4
1,3-bis共trifluoromethyl兲benzene
共275–353兲
42.4
1,4-bis共trifluoromethyl兲benzene
共287–390兲
41.8
phthalic anhydride
共407–558兲
共411– 450兲
52.1
63.9⫾2.5
65.3⫾0.8
1,1,1-trifluoro-2,2-dichloro-2-phenylethane
共365– 446兲
47.2
␣,␣-dichlorophenylacetonitrile
共329– 497兲
57.2
pentachloroethylbenzene
共369–572兲
58.8
2,2,2-trifluoroacetophenone
共342– 425兲
43.1
ethyl bis共heptafluropropyl兲phosphinite
共303–393兲
41.9
benzoylnitrile
共318 – 481兲
52.0
phenylacetylene
共313– 416兲
42.6⫾0.1
共313– 416兲
40.4⫾0.1
共313– 416兲
38.0⫾0.2
共265–291兲
43.9
共270–292兲
45.2
(dl) ␣-bromophenylacetonitrile
共293–515兲
64.7
2,3-dichlorostyrene
共334 –508兲
55.4
共334 –508兲
54.3
2,4-dichlorostyrene
共327– 498兲
55.0
2,5-dichlorostyrene
共328 –500兲
54.3
共348兲
共333兲
A
共320兲
共360兲
共400兲
共278兲
共281兲
EB
EB
EB
MM
HSA
共308兲
A
共349兲
共349兲
A
共342兲
A
共343兲
A
CAS registry number
Reference
关307-99-3兴
关87/5兴关99/16兴
关327-76-4兴
关87/5兴关46/3兴
关70/14兴关99/16兴
关328-72-3兴
关87/5兴关46/3兴
关70/14兴关99/16兴
关328-82-5兴
关87/5兴关99/16兴
关19220-93-0兴
关87/5兴关99/16兴
关307-30-2兴
关87/5兴关99/16兴
关321-31-3兴
关87/5兴关99/16兴
关99-63-8兴
关87/5兴关99/16兴
关88-95-9兴
关87/5兴关47/5兴
关99/16兴
关100-20-9兴
关87/5兴关99/16兴
关309-12-6兴
关99/16兴
关87/5兴
关402-31-3兴
关87/5兴关51/9兴
关70/14兴关99/16兴
关433-19-2兴
关87/5兴关70/14兴
关99/16兴
关85-44-9兴
关87/5兴
关79/22兴
关46/16兴关79/22兴
关309-10-4兴
关87/5兴关99/16兴
关40626-45-7兴
关87/5兴关47/5兴
关606-07-5兴
关87/5兴关47/5兴
关99/16兴
关434-45-7兴
关87/5兴关99/16兴
关59/21兴
关613-90-1兴
关87/5兴关47/5兴
关536-74-3兴
关02/17兴
关02/17兴
关02/17兴
关81/19兴
关81/19兴
关5798-79-8兴
关87/5兴
关2123-28-6兴
关99/16兴
关87/5兴关47/5兴
关2123-27-5兴
关87/5兴关70/14兴
关1123-84-8兴
关87/5兴关47/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
672
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H6 Cl2
Compound
共Temperature range/K兲
C8 H6 Cl2
C8 H6 Cl2 O
C8 H6 Cl2 O
C8 H6 Cl4
C8 H6 Cl4
C8 H6 F12O3 S
C8 H6 O
C8 H6 O
C8 H6 O2
C8 H6 O2
C8 H6 O3
C8 H6 S
C8 H7 Br
C8 H7 Br
C8 H7 Cl
C8 H7 Cl
C8 H7 Cl
C8 H7 ClO
C8 H7 ClO
Mean temperature
(T m /K)
Method
2,6-dichlorostyrene
共321– 490兲
C8 H6 Cl2
⌬ vapH m
共kJ mol⫺1兲
3,4-dichlorostyrene
共330–503兲
53.8⫾1.5
50.4
共298兲
共336兲
GS
A
53.3
共345兲
A
共341兲
A
共439兲
A
共453兲
A
共365兲
A
共382兲
A
共338兲
A
共315兲
A
共363兲
A
共383兲
A
共331兲
共375兲
A
3,5-dichlorostyrene
共326 – 498兲
55.1
3-共chloromethyl兲benzoyl chloride
共424 – 464兲
54.7
4-共chloromethyl兲benzoyl chloride
共440– 466兲
68.3
2,3,4,6-tetrachloro-1-ethylbenzene
共350–543兲
53.6
3,4,5,6-tetrachloro-1,2-dimethylbenzene
共367–547兲
63.6
bis共1,1,1,3,3,3-hexafluoro-2-methyl-2-propanol兲 sulfite
46.5
2,3-benzofuran
共323– 403兲
46.2
2-ethynylphenol
共300–373兲
33.5
phenyl glyoxal
共348 – 467兲
59.7
phthalide
共368 –563兲
59.3
piperonal
共310–353兲
65.7
共360–536兲
60.6
benzo关b兴thiophene
共349– 424兲
52.1
共424 – 498兲
47.9
共498 – 631兲
45.0
共310–542兲
54.3
共310–542兲
52.0
共310–542兲
49.7
共310–542兲
46.2
共310–542兲
43.8
共310–542兲
41.2
47.2
42.8
36.1
共306 –346兲
53.8
2-bromostyrene
共378 –543兲
48.7
4-bromostyrene
共393– 420兲
48.5
共383–543兲
49.9
2-chlorostyrene
共363–523兲
46.0
3-chlorostyrene
共298 – 463兲
46.1
4-chlorostyrene
共363–523兲
4⬘-chloroacetophenone
共404 – 623兲
共395– 485兲
phenylacetyl chloride
共321– 483兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共364兲
共439兲
共513兲
共320兲
共360兲
共400兲
共460兲
共500兲
共540兲
共425兲
共505兲
共605兲
共326兲
共393兲
A
共406兲
共398兲
A
共378兲
A
共313兲
A
48.1
共378兲
A
54.0
50.7
共419兲
共410兲
A
56.5
共336兲
A
CAS registry number
Reference
关70/14兴
关28469-92-3兴
关01/1兴
关87/5兴关47/5兴
关70/14兴
关2039-83-0兴
关87/5兴关47/5兴
关70/14兴
关2155-42-2兴
关87/5兴关70/14兴
关63024-77-1兴
关87/5兴关99/16兴
关876-08-4兴
关87/5兴关99/16兴
关877-08-7兴
关87/5兴关47/5兴
关877-08-7兴
关87/5兴关70/14兴
关53602-64-5兴
关75/43兴
关271-89-6兴
关87/5兴
关5101-44-0兴
关87/5兴
关1074-12-0兴
关87/5兴关47/5兴
关87-41-2兴
关87/5兴关47/5兴
关120-57-0兴
关53/5兴
关87/5兴关47/5兴
关95-15-8兴
关99/16兴
关99/16兴
关99/16兴
关91/13兴
关91/13兴
关91/13兴
关91/13兴
关91/13兴
关91/13兴
关81/1兴
关81/1兴
关81/1兴
关81/2兴关99/16兴
关2039-88-5兴
关87/5兴关70/14兴
关2039-82-9兴
关99/16兴
关87/5兴关70/14兴
关2039-87-4兴
关87/5兴关70/14兴
关2039-85-2兴
关87/5兴关47/5兴
关70/14兴
关1073-67-2兴
关87/5兴关47/5兴
关70/14兴
关99-91-2兴
关87/5兴关99/16兴
关49/1兴关84/9兴
关103-80-0兴
关87/5兴关47/5兴
关99/16兴
ENTHALPIES OF VAPORIZATION
673
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H7 ClO2
C8 H7 Cl3 O3
C8 H7 FO
C8 H7 F3
C8 H7 N
C8 H7 N
C8 H7 N
C8 H7 N
C8 H7 NO
C8 H7 NO3
C8 H7 NO4
C8 H7 NO4
C8 H7 NS
C8 H7 NS
C8 H7 N3 O7
C8 H8
Compound
共Temperature range/K兲
benzyl chloroformate
共293–303兲
38.5⫾0.1
3,4,5-trichloro-2,6-dimethoxyphenol
共293–323兲
77.4
2-fluoroacetophenone
共273–333兲
62.0
A, GS
46.1⫾0.3
共298兲
GS
60.1⫾0.7
60.5⫾0.7
54.8
共306兲
共298兲
共348兲
GS
GS
A
50.8
共324兲
A
48.0
共330兲
A
48.5
共313兲
A
42.3
共348兲
A
103.6
共308兲
A
56.1
共438兲
A
71.1
共388兲
A
62.2
共367兲
A
61.3
共358兲
A
120.5
共346兲
A
43.9
43.1
共288兲
共298兲
A
42.9⫾0.1
共298兲
C
35.1
共328兲
A
42.5
41.5
42.5
43.1
43.9
43.5⫾0.4
40.2
43.2
共260兲
共349兲
共319兲
共318兲
共298兲
共298兲
共348兲
共298兲
A
A
64.9
共374兲
A
2,5-dichloro-1,4-dimethylbenzene
共393–573兲
52.7
共408兲
A
2,3-dichloro-1-ethylbenzene
共319– 495兲
48.9
共334兲
A
2,5-dichloro-1-ethylbenzene
共311– 490兲
46.0
共326兲
A
3,4-dichloro-1-ethylbenzene
共320–500兲
49.3
共335兲
A
1,1,1-trifluoro-2-phenylethane
共273–313兲
benzylcyanide
共283–328兲
共283–328兲
共333–507兲
2-tolunitrile
共309– 479兲
4-tolunitrile
共315– 491兲
2-tolylisocyanide
共298 – 457兲
benzyl isocyanate
共333–393兲
2⬘-nitroacetophenone
共293–333兲
2-nitrobenzoic acid, methyl ester
共423– 453兲
共2-nitrophenyl兲 acetate
共373–526兲
benzyl isothiocyanate
共352–516兲
2-methylbenzothiazole
共343– 499兲
2,4,6-trinitrophenetole
共342–351兲
cyclooctatetraene
共273–348兲
1,5,7-octatriene-3-yene
共313– 429兲
styrene
共245–334兲
共334 – 419兲
共306 –333兲
共303– 417兲
共285–333兲
C8 H8 Cl2
C8 H8 Cl2
C8 H8 Cl2
共298兲
共288兲
C8 H8
C8 H8 Cl2
Method
CGC
bicyclo关2.2.2兴octa-2,5,7-triene
C8 H8 Br2
Mean temperature
(T m /K)
共308兲
C8 H8
C8 H8
⌬ vapH m
共kJ mol⫺1兲
共306 –389兲
共245–357兲
共1,2-dibromoethyl兲benzene
共359–527兲
CAS registry number
Reference
关501-53-1兴
关90/12兴
关2539-26-6兴
关99/13兴
关450-95-3兴
关87/5兴关48/14兴
关99/16兴
关21249-93-4兴
关97/14兴
关140-29-4兴
关00/2兴
关00/2兴
关87/5兴关47/5兴
关620-22-4兴
关87/5兴关47/5兴
关104-85-8兴
关87/5兴关47/5兴
关10468-64-1兴
关87/5兴关47/5兴
关3173-56-6兴
关87/5兴
关577-59-3兴
关87/5兴
关606-27-9兴
关87/5兴
关610-69-5兴
关87/5兴关47/5兴
关622-78-6兴
关87/5兴关47/5兴
关120-75-2兴
关87/5兴关47/5兴
关99/16兴
关4732-14-3兴
关87/5兴
关629-20-9兴
关87/5兴
49/23兴
关500-24-3兴
关85/2兴
关16607-77-5兴
关87/5兴
关100-42-5兴
关87/5兴
关87/5兴
关59/27兴
关55/22兴
关46/10兴
关46/10兴
关42/3兴
关39/6兴
关93-52-7兴
关87/5兴关47/5兴
关70/14兴
关1124-05-6兴
关87/5兴关70/14兴
关99/16兴
关54484-61-6兴
关87/5兴关47/5兴
关70/14兴
关54484-63-8兴
关87/5兴关47/5兴
关70/14兴
关6623-59-2兴
关87/5兴关47/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
674
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H8 Cl2
C8 H8 Cl2 O2
C8 H8 Cl2 O3
C8 H8 Cl3 O3 PS
C8 H8 N2 O2
C8 H8 N2 O3
C8 H8 O
C8 H8 O
C8 H8 O
C8 H8 O2
C8 H8 O2
C8 H8 O2
C8 H8O2
C8 H8 O2
C8 H8 O2
C8 H8 O2
C8 H8 O2
C8 H8 O2
Compound
共Temperature range/K兲
1,4-bis共chloromethyl兲benzene
共412–504兲
2-共2,4-dichlorophenoxy兲ethanol
共484 –560兲
⌬ vapH m
共kJ mol⫺1兲
50.8
共427兲
65.1
共499兲
3,5-dichloro-2,6-dimethoxyphenol
共293–323兲
70.4
O,O-dimethyl-O-共2,4,5-trichlorophenyl兲thiophosphate
共298 –373兲
56.8
1,4-bis共2-hydroxyethyl兲piperazine
共413–507兲
67.8⫾5.3
2⬘-nitroacetanilide
共473–593兲
44.0
acetophenone
共360–520兲
55.4⫾0.4
共343–383兲
53.4
共343–383兲
52.7
共343–383兲
57.9
共375– 603兲
49.7
共383– 437兲
41.9
共310– 476兲
51.2
2,5-dihydrobenzo-3,4-furan
共285–510兲
53.7⫾0.4
phenylacetaldehyde
共283–333兲
54.5
1,4-benzodioxan
共400– 486兲
50.4
50.4
benzyl formate
共298 –357兲
51.6
2⬘-hydroxyacetophenone
共369– 491兲
58.3
50.2
2-methoxybenzaldehyde
55.2
4-methoxybenzaldehyde
共348 –521兲
58.4
共283–323兲
60.4
共346 –521兲
57.1
methyl benzoate
共358 –517兲
51.1⫾0.2
共358 –517兲
48.5⫾0.2
共358 –517兲
45.8⫾0.2
共358 –517兲
43.0⫾0.4
57.2⫾0.1
共313–353兲
53.4
共313–363兲
53.8
共433– 473兲
54.7
共334 – 428兲
50.7
共334 – 428兲
48.3
共283–323兲
53.9
共373–533兲
49.7
55.6⫾0.1
共341– 433兲
52.8
m-toluic acid
共473–533兲
62.8
phenyl acetate
共313–363兲
53.3
共433– 473兲
53.6
共313–353兲
53.1
共311– 469兲
51.7
phenylacetic acid
共370–539兲
65.0
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
CAS registry number
Reference
A
关70/14兴
关93-52-7兴
关99/16兴
关120-67-2兴
关59/1兴关84/9兴
关99/16兴关87/5兴
共308兲
CGC
共313兲
A
共488兲
A
共298兲
共298兲
共298兲
共298兲
共390兲
共398兲
共325兲
EB
CGC
CGC
CGC
A
GS, EB
共298兲
EB
共298兲
A
共415兲
A
共313兲
A
共384兲
A
共363兲
共298兲
共361兲
A, EB
A
A
共360兲
共400兲
共440兲
共480兲
共303兲
共298兲
共298兲
共298兲
共379兲
共410兲
共298兲
共388兲
共298兲
共363兲
EB
EB
EB
EB
C
CGC
CGC
CGC
BG
BG
A
A
C
BG
共503兲
A
共298兲
共298兲
共298兲
共326兲
CGC
CGC
CGC
A
共385兲
A
关99/13兴
关299-84-3兴
关87/5兴
关122-96-3兴
关98/7兴
关552-32-9兴
关87/5兴
关98-86-2兴
关96/3兴
关95/21兴
关95/21兴
关95/21兴
关87/5兴
关65/7兴
关47/5兴
关496-14-0兴
关96/4兴
关122-78-1兴
关87/5兴
关493-09-4兴
关87/5兴
关58/25兴
关104-57-4兴
关87/5兴
关118-93-4兴
关87/5兴
关86/10兴
关135-02-4兴
关86/10兴
关123-11-5兴
关85/9兴
关87/5兴关55/8兴
关87/5兴关47/5兴
关93-58-3兴
关02/15兴
关02/15兴
关02/15兴
关02/15兴
关98/6兴
关95/21兴
关95/21兴
关95/21兴
关88/2兴
关88/2兴
关87/5兴
关87/5兴
关72/1兴
关71/2兴
关99-04-7兴
关87/5兴关70/34兴
关122-79-2兴
关95/21兴
关95/21兴
关95/21兴
关87/5兴关47/5兴
关103-82-2兴
关87/5兴
ENTHALPIES OF VAPORIZATION
675
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H8 O3
C8 H8 O3
C8 H8 O3
C8 H8 O3
C8 H8 O4
C8 H9 Br
C8 H9 Br
C8 H9 Br
C8 H9 Br
C8 H9 Br
C8 H9 Cl
C8 H9 Cl
C8 H9 Cl
C8 H9 Cl
C8 H9 Cl
C8 H9 Cl
C8 H9 ClNO5 PS
C8 H9 ClO
C8 H9 ClO
C8 H9 ClO
C8 H9 ClO2
C8 H9 ClO3
C8 H9 Cl3 O4
C8 H9 I
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共363兲
共373兲
共307兲
A
共365兲
共373兲
共396兲
A
共391兲
A
共346兲
A
共333兲
A
共411兲
A
共410兲
A
共425兲
A
共308兲
CGC
关99/13兴
共389兲
A
共298兲
GS
关87/5兴关99/16兴
关10604-60-1兴
关02/29兴
46.2
49.4
52.0
共362兲
共393兲
共318兲
52.8⫾0.2
52.4
51.4
47.0
共298兲
共298兲
共351兲
共357兲
共336 –372兲
共342–378兲
共2-chloroethyl兲benzene
共356 – 480兲
53.1
共356 –380兲
51.7
1-chloro-2-ethylbenzene
共353–503兲
46.1
共290– 450兲
47.2
1-chloro-3-ethylbenzene
共348 – 457兲
46.4
共358 –508兲
46.8
共291– 454兲
46.4
1-chloro-4-ethylbenzene
共350– 458兲
45.8
共358 –508兲
46.8
共381– 457兲
45.5
1-共chloromethyl兲-4-methylbenzene
共376 – 457兲
44.9
O,O-共dimethyl兲-O-共3-chloro-4-nitrophenyl兲thiophosphate
共283– 409兲
92.0
1-chloro-2-ethoxybenzene
共318 – 481兲
52.4
4-chlorophenethyl alcohol
共426 – 673兲
59.3
4-chloro-1-ethoxybenzene
共395– 485兲
49.5
ethylene glycol, 4-chlorophenyl ether
共410–554兲
68.5
3-chloro-2,6-dimethoxyphenol
共293–323兲
68.6
2-acetyl-4,4,4-trichloro-3-oxobutyric acid, ethyl ester
共374 – 409兲
53.1
共1-iodoethyl兲benzene
共303–340兲
59.9⫾0.4
CAS registry number
Reference
关935-79-5兴
关84/14兴
关99-76-3兴
关87/5兴
关119-36-8兴
关87/5兴
关87/5兴
关87/5兴
关121-33-5兴
关87/5兴关47/5兴
关520-45-6兴
关87/5兴关47/5兴
关553-94-6兴
关99/16兴关47/5兴
关87/5兴关70/14兴
关585-71-7兴
关02/29兴
关02/29兴
关103-63-9兴
关87/5兴关99/16兴
关1973-22-4兴
关87/5兴关70/14兴
关99/16兴
关1585-07-5兴
关99/16兴
关87/5兴关70/14兴
关47/5兴
关627-65-1兴
关02/29兴
关02/29兴
关99/16兴
关87/5兴
关622-24-2兴
关99/16兴
关87/5兴
关89-96-3兴
关87/5兴关70/14兴
关47/5兴
关620-16-6兴
关99/16兴
关87/5兴关70/14兴
关47/5兴
关622-98-0兴
关99/16兴
关87/5兴关70/14兴
关47/5兴
关104-82-5兴
关87/5兴关99/16兴
关500-28-7兴
关87/5兴关99/16兴
关614-72-2兴
关87/5兴关47/5兴
关1875-88-3兴
关87/5兴关99/16兴
关622-61-7兴
关87/5兴关99/16兴
关7477-64-7兴
关87/5兴关99/16兴
cis 4-cyclohexene-1,2-dicarboxylic acid anhydride
共325–525兲
53.1⫾0.1
4-hydroxybenzoic acid, methyl ester
共446 –517兲
81.5
共461兲
methyl salicylate
共327– 497兲
59.9
共342兲
共329– 496兲
58.7
共344兲
共288 –333兲
56.9
共303兲
4-hydroxy-3-methoxybenzaldehyde 共vanillin兲
共380–558兲
66.9
共395兲
2-acetyl-5-hydroxy-3-oxo-4-hexenoic acid-␦-lactone 共dehydroacetic acid兲
共364 –542兲
62.1
共379兲
1-bromo-2,5-dimethylbenzene
共310– 480兲
50.9
共325兲
共310– 480兲
53.6
共325兲
共1-bromoethyl兲benzene
共298 –333兲
56.4⫾0.3
共298兲
52.4
共298兲
共2-bromoethyl兲benzene
共348 – 401兲
51.5
共363兲
1-bromo-2-ethylbenzene
共368 –523兲
48.1
共383兲
1-bromo-4-ethylbenzene
共347– 479兲
共378 –533兲
共303– 479兲
(dl) 共1-chloroethyl兲benzene
共281–319兲
Method
共368兲
共368兲
共368兲
共305兲
A
A
A
A
A
A
GS
CGC
A
A
A
GS
CGC
A
A
A
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
676
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H9 N
C8 H9 N
C8 H9 NO
C8 H9 NO2
C8 H9 NO2
C8 H9 NO2
C8 H9 NO2
C8 H9 NO2
C8 H9 NO2
C8 H9 NO2
C8 H9 N3
C8 H10
C8 H10
Compound
共Temperature range/K兲
2-methyl-5-vinylpyridine
共342– 457兲
共342– 457兲
N-methylbenzaldehyde-imine
共283–318兲
共283–318兲
acetanilide
共473–577兲
共387–577兲
anthranilic acid, methyl ester
共299–333兲
2-nitro-1,3-dimethylbenzene
共284 –323兲
共373– 498兲
4-nitro-1,3-dimethylbenzene
共368 –518兲
共338 –517兲
1,2-dimethyl-3-nitrobenzene
共383–518兲
1,2-dimethyl-4-nitrobenzene
共399–536兲
2-nitro-1-ethylbenzene
共284 –323兲
共353– 422兲
4-nitro-1-ethylbenzene
共353– 433兲
2,2-dicyanohexanenitrile
共288 –323兲
1,2-dimethylbenzene
共373– 423兲
共333– 419兲
共416 – 473兲
共471–571兲
共567– 630兲
共386 – 416兲
共337– 419兲
共273–323兲
1,3-dimethylbenzene
共360– 410兲
共327– 412兲
共267–301兲
共412– 462兲
共461–554兲
共550– 617兲
共380– 411兲
共331– 415兲
C8 H10
共273–333兲
1,4-dimethylbenzene
共373– 423兲
共293–323兲
共411– 463兲
共460–553兲
共551– 616兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
55.2
54.5
共357兲
共357兲
A
51.1⫾0.2
51.2⫾0.2
共301兲
共298兲
GS
GS
64.8
66.3
共488兲
共402兲
A
62.3
共314兲
A, ME
57.2⫾0.8
57.5⫾0.8
49.7
共303兲
共298兲
共388兲
GS
56.7
57.3
共383兲
共353兲
A
59.4
共398兲
63.6
共414兲
62.7⫾0.4
63.0⫾0.4
56.3
共303兲
共298兲
共368兲
GS
59.4
共368兲
A
61.0⫾0.2
Method
A
A
GS
42.9
41.1
38.0
36.7
36.7
39.8
43.4
43.4⫾0.1
40.8
45.0
共298兲
共348兲
共431兲
共486兲
共582兲
共401兲
共298兲
共298兲
共352兲
共288兲
39.2
40.7
44.7
37.5
36.4
36.2
38.7
42.7
42.7⫾0.1
40.4
共375兲
共342兲
共282兲
共427兲
共476兲
共565兲
共395兲
共298兲
共298兲
共346兲
43.2
共288兲
42.3
43.0⫾0.1
42.3⫾0.01
40.3
37.3
36.1
36.2
36.0⫾0.1
34.5⫾0.1
共298兲
共298兲
共298兲
共353兲
共426兲
共475兲
共566兲
共411兲
共436兲
CGC
A
A
A
A
C
MM
A
A
A
A
C
MM
CGC
A
A
A
C
C
CAS registry number
Reference
关140-76-1兴
关87/5兴
关61/19兴关84/9兴
关97/9兴
关97/9兴
关103-84-4兴
关87/5兴
关47/5兴
关134-20-3兴
关87/5兴关54/7兴
关81-20-9兴
关00/15兴
关00/15兴
关87/5兴
关89-87-2兴
关87/5兴
关47/5兴
关83-41-0兴
关84/9兴
关99-51-4兴
关84/9兴
关612-22-6兴
关00/15兴
关00/15兴
关87/5兴
关100-12-9兴
关87/5兴
关94/5兴
关95-47-6兴
关95/21兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关82/3兴
关71/28兴
关47/7兴
关45/2兴关49/6兴
关43/1兴关84/9兴
关108-38-3兴
关02/9兴
关89/7兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关83/2兴
关71/28兴
关47/7兴
关87/5兴关45/2兴
关49/6兴
关43/1兴关84/9兴
关106-42-3兴
关95/21兴
关90/3兴
关88/16兴
关88/7兴
关87/5兴
关87/5兴
关87/5兴
关85/10兴
关85/10兴
ENTHALPIES OF VAPORIZATION
677
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
30.5⫾0.1
24.7⫾0.1
37.3
42.3⫾0.1
42.6
42.4
42.4
41.6
42.4⫾0.1
40.1
共484兲
共540兲
共395兲
共298兲
共298兲
共301兲
共298兲
共318兲
共298兲
共347兲
41.8
37.0
35.8
40.6
35.5
40.5⫾0.1
39.5⫾0.1
38.6⫾0.1
42.4⫾0.1
42.3
42.2⫾0.1
共330– 410兲
40.0
N-trifluoroacetyl-l-proline, methyl ester
共303–523兲
57.9
N-trifluoroacetyl-l-aspartic acid, dimethyl ester
共303– 423兲
58.2
O,O-dimethyl-O-共4-nitrophenyl兲 thiophosphate
共293– 427兲
88.9
87.0
3-nitro-N,N-dimethylaniline
共427–558兲
52.3
共357– 492兲
48.2
2,3-dimethylphenol
共433– 492兲
52.1
2,4-dimethylphenol
共393– 433兲
64.6
共282–318兲
65.9
共429– 486兲
51.8
2,5-dimethylphenol
共427– 485兲
51.7
2,6-dimethylphenol
75.6
75.1
共417– 476兲
48.5
3,4-dimethylphenol
85.1
85.0
共444 –502兲
54.9
3,5-dimethylphenol
82.0
共427– 497兲
55.3
benzyl methyl ether
共274 –314兲
51.4⫾0.3
ethoxybenzene
共390– 454兲
44.5
共390– 454兲
50.7
共390– 454兲
40.7
51.0⫾0.1
共400– 454兲
44.0
2-ethylphenol
共393– 433兲
64.5
共423– 491兲
50.5
共277–318兲
63.5
共313兲
共424兲
共472兲
共335兲
共564兲
共328兲
共343兲
共358兲
共298兲
共298兲
共298兲
共345兲
C
MM
共318兲
A
共318兲
A
共308兲
A
GS
共442兲
共372兲
A, GS, EB
共448兲
A, GS, EB
共298兲
共297兲
共444兲
CGC
A
A, GS, EB
共442兲
A, GS, EB
共298兲
共298兲
共432兲
A, GS, EB
共298兲
共298兲
共459兲
A, GS, EB
共298兲
共442兲
A, GS, EB
共298兲
GS
共405兲
共298兲
共443兲
共298兲
共415兲
A
共298兲
共438兲
共292兲
CGC
A, GS, EB
A, GS, EB
Compound
共Temperature range/K兲
共380– 410兲
共286 – 453兲
共303–343兲
C8 H10
C8 H10F3 NO3
C8 H10F3 NO5
C8 H10NO5 PS
C8 H10N2 O2
C8 H10O
C8 H10O
C8 H10O
C8 H10O
C8 H10O
C8 H10O
C8 H10O
C8 H10O
C8 H10O
共332– 413兲
ethylbenzene
共298 – 420兲
共409– 459兲
共457–554兲
共320– 400兲
共549– 617兲
Method
C
C
C
IPM, EB
C
MM
A
A
A
A
C
C
C
C
C
CAS registry number
Reference
关85/10兴
关85/10兴
关82/3兴
关81/10兴
关74/13兴
关87/5兴关74/11兴
关71/28兴
关68/23兴
关47/7兴
关45/2兴关49/6兴
关100-41-4兴
关87/5兴
关87/5兴
关87/5兴
关86/13兴
关87/5兴
关82/10兴
关82/10兴
关82/10兴
关81/10兴
关71/28兴
关47/7兴
关45/2兴关49/6兴
关715-58-2兴
关87/5兴关99/16兴
关81084-01-7兴
关87/5兴关99/16兴
关298-00-0兴
关87/5兴
关79/19兴
关619-31-8兴
关87/5兴关60/4兴
关55/9兴
关526-75-0兴
关87/5兴关60/4兴
关105-67-9兴
关95/21兴
关87/5兴
关87/5兴关60/4兴
关95-87-4兴
关87/5兴关60/4兴
关576-26-1兴
关71/7兴
关68/9兴
关87/5兴关60/4兴
关96-65-8兴
关71/7兴
关68/9兴
关87/5兴关60/4兴
关108-68-9兴
关71/7兴
关87/5兴关60/4兴
关538-86-3兴
关02/29兴
关103-73-1兴
关87/5兴关76/2兴
关76/2兴
关76/2兴
关75/3兴
关65/7兴关84/9兴
关90-00-6兴
关95/21兴
关87/5兴关63/10兴
关87/5兴关63/10兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
678
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C8 H10O
共359– 480兲
共321– 492兲
共321– 492兲
共321– 492兲
共321– 492兲
共321– 492兲
3-ethylphenol
共445–503兲
共277–323兲
共334 –501兲
共334 –501兲
共334 –501兲
共334 –501兲
共334 –501兲
4-ethylphenol
共444 –503兲
共337–503兲
共337–503兲
共337–503兲
共337–503兲
共337–503兲
4-methylbenzyl alcohol
共338 –376兲
(dl) 1-phenylethanol
共353– 480兲
2-phenylethanol
共394 – 613兲
共283–318兲
2-methylanisole
C8 H10O
4-methylanisole
C8 H10OS
4-methoxythioanisole
C8 H10O2
ethyl trans ␤-共2-furyl兲acrylate
共428 –500兲
4-methoxybenzyl alcohol
共394 – 424兲
共354 – 453兲
1,3-dihydroxy-2,5-dimethylbenzene
共393– 459兲
1,3-dihydroxy-4,5-dimethylbenzene
共424 – 453兲
1,3-dihydroxy-4,6-dimethylbenzene
共388 – 466兲
1,4-dihydroxy-2,5-dimethylbenzene
共331–361兲
1,3-dihydroxy-5-ethylbenzene
共408 – 479兲
1,2-dimethoxybenzene
C8 H10O
C8 H10O
C8 H10O
C8 H10O
C8 H10O
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
51.6
51.4
49.5
48.6
47.0
43.1
共374兲
共348兲
共373兲
共398兲
共423兲
共473兲
53.1
68.1
58.3
56.5
55.2
53.7
48.8
共460兲
共292兲
共348兲
共373兲
共398兲
共423兲
共473兲
A, GS, EB
A, GS, EB
53.2
56.5
54.7
53.8
51.3
47.6
共459兲
共348兲
共373兲
共398兲
共423兲
共473兲
A, GS, EB
64.2
共353兲
A
53.5
共368兲
A
55.1
68.4
共409兲
共298兲
A
A, ME
Method
45.2
46.0
53.6
C8 H10O2
C8 H10O2
C8 H10O2
C8 H10O2
C8 H10O2
C8 H10O2
C8 H10O2
56.8
共464兲
95.6
71.7
共409兲
共369兲
A
EB
74.7
共408兲
A, GC
67.5
共438兲
A, GC
74.7
共403兲
A, GC
101.1
共346兲
A
81.3
共423兲
A, GC
60.8
共373兲
A, GC
62.1
51.5
共313兲
A
共366兲
A
共371兲
A
共470兲
A
66.9
C8 H10O2
C8 H10O2
C8 H10O2
C8 H10O2
C8 H10O2 S
C8 H10O3
1,3-dimethoxybenzene
共358 – 423兲
1,4-dimethoxybenzene
共298 –357兲
2-phenoxyethanol
共351–519兲
66.0
3-methoxy-4-hydroxytoluene
共356 – 495兲
53.2
benzyl methyl sulfone
共455–529兲
64.9
cis cyclohexane-1,2-dicarboxylic acid anhydride
共325–525兲
48.8⫾0.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关55/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关620-17-7兴
关87/5兴关63/10兴
关87/5兴关63/10兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关123-07-9兴
关87/5兴关63/10兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关589-18-4兴
关87/5兴
关13323-81-4兴
关87/5兴
关60-12-8兴
关87/5兴
关87/5兴关54/10兴
关578-58-5兴
关86/10兴
关104-93-8兴
关86/10兴
关1879-16-9兴
关86/10兴
关56/11兴
关105-13-5兴
关87/5兴
关85/9兴
关488-87-9兴
关87/5兴关75/24兴
关527-55-9兴
关87/5兴关75/24兴
关615-89-4兴
关75/24兴
关615-90-7兴
关87/5兴
关4299-72-3兴
关87/5兴关75/24兴
关91-16-7兴
关58/25兴
关151-10-0兴
关87/5兴关75/24兴
关150-78-7兴
关87/5兴
关86/10兴
关122-99-6兴
关87/5兴关47/5兴
关2896-67-5兴
关87/5兴
关3112-90-1兴
关87/5兴关99/16兴
关13149-00-3兴
关84/14兴
ENTHALPIES OF VAPORIZATION
679
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H10O6
C8 H10S
C8 H10S
C8 H10S
C8 H10S
C8 H11Cl3 OS
C8 H11F3 O2
C8 H11N
C8 H11N
C8 H11N
C8 H11N
C8 H11N
C8 H11N
C8 H11N
C8 H11N
C8 H11N
C8 H11N
Compound
共Temperature range/K兲
dioxobutanedioic acid, diethyl ester
共343–507兲
59.3
benzyl methyl sulfide
共336 –368兲
51.8
共336 –368兲
50.8
共323–358兲
55.2⫾2.1
ethyl phenyl sulfide
共338 –367兲
50.9
共338 – 477兲
51.7
共323–358兲
53.6⫾2.1
2-共methylthio兲toluene
50.2
4-共methylthio兲toluene
50.2
2,3,3-trichloro-2-propenethioic acid, O-pentyl ester
共413– 455兲
74.1
trifluoroacetic acid, cyclohexyl ester
共345– 420兲
43.0
N,N-dimethylaniline
共284 –323兲
共363– 418兲
共302– 467兲
2,4-dimethylaniline
共295–339兲
共383– 485兲
共326 – 485兲
2,5-dimethylaniline
共295–339兲
2,6-dimethylaniline
共286 –326兲
共373– 490兲
共317– 491兲
N-ethylaniline
共279–318兲
共311– 477兲
2-ethylaniline
共283–323兲
4-ethylaniline
共393– 491兲
共325– 490兲
5-ethyl-2-methylpyridine
共348 – 451兲
共253–276兲
␣-methylbenzylamine
共283–318兲
共283–318兲
(dl) ␣-methylbenzylamine
共292–318兲
C8 H11N
共⫹兲␣-methylbenzylamine
C8 H11N
共⫺兲␣-methylbenzylamine
C8 H11N
4-methylbenzylamine
共353– 466兲
2,3,5-trimethylpyridine
共293– 426兲
2,3,6-trimethylpyridine
C8 H11N
C8 H11N
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共358兲
A
共351兲
共351兲
共298兲
A
共353兲
共353兲
A
CAS registry number
Reference
关59743-08-7兴
关87/5兴关47/5兴
关766-92-7兴
关99/16兴
关87/5兴
关62/20兴
关622-38-8兴
关99/16兴
关87/5兴
关62/20兴
共360兲
A, EB
53.7⫾0.5
49.2
52.8⫾0.1
47.6
共304兲
共378兲
共298兲
共317兲
A
C
A
61.3⫾0.6
55.5
56.9
共317兲
共398兲
共341兲
61.7⫾0.7
共317兲
59.2⫾0.3
59.6⫾0.3
48.5
50.7
共306兲
共298兲
共388兲
共332兲
58.3⫾0.6
52.2
共298兲
共326兲
60.3⫾0.9
60.6⫾0.9
共304.3兲
共298兲
GS
53.1
54.6
共408兲
共340兲
A
45.4
51.6
共363兲
共264兲
A
GS
54.7⫾0.3
54.9⫾0.3
共301兲
共298兲
GS
GS
36.7
54.5⫾0.1
共305兲
共298兲
A
C
关86/10兴
关623-13-2兴
关86/10兴
关76619-94-8兴
关80/24兴
关1549-45-7兴
关87/5兴关69/13兴
关99/16兴
关121-69-7兴
关97/21兴
关87/5兴
关82/18兴
关87/5兴关47/5兴
关95-68-1兴
关97/21兴
关87/5兴
关47/5兴
关95-78-3兴
关97/21兴
关87-62-7兴
关00/14兴
关00/14兴
关87/5兴
关47/5兴
关103-69-5兴
关97/21兴
关87/5兴
关578-54-1兴
关00/14兴
关00/14兴
关589-16-2兴
关87/5兴
关47/5兴
关104-90-5兴
关87/5兴
关80/6兴
关98-84-0兴
关99/3兴
关99/3兴
关618-36-0兴
关87/5兴
关87/8兴
54.1⫾0.1
共298兲
C
关87/8兴
54.6⫾0.1
共298兲
C
54.4
共368兲
A
44.0
共359兲
48.5
47.5
共328兲
共343兲
关87/8兴
关104-84-7兴
关87/5兴
关695-98-7兴
关95/4兴
关1462-84-6兴
关85/1兴
关85/1兴
GC
A
A
A
C
C
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
680
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H11N
C8 H11N
C8 H11N
C8 H11N
C8 H11NO
C8 H11NO
C8 H11NO
C8 H12
C8 H12
C8 H12
C8 H12
C8 H12
C8 H12
C8 H12Cl2 O5
C8 H12N2
C8 H12O
Compound
共Temperature range/K兲
2,4,6-trimethylpyridine
共323–373兲
共303– 424兲
共298 – 444兲
2-propylpyridine
共338 – 445兲
3-propylpyridine
共350– 450兲
4-propypyridine
共354 – 465兲
2-anilinoethanol
共377–553兲
2-ethoxyaniline
共373– 458兲
4-ethoxyaniline
共421–523兲
tricyclo关 3.3.0.02,6兴 octane
共273–343兲
共273–343兲
共273–343兲
cyclooctadiene 共mixed isomers兲
共290– 474兲
cis cis 1,5-cyclooctadiene
1,5-cyclooctadiene
共348 –386兲
(dl) trans 1,2-divinylcyclobutane
共319–371兲
共350–385兲
(dl) 4-vinyl-1-cyclohexene
共292– 405兲
diethylene glycol bis共chloroacetate兲
共421–586兲
suberic acid dinitrile
共303–339兲
1-methylnorcamphor
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
45.7
共368兲
C
50.2
46.5
51.2
50.3⫾0.2
48.3
47.2
45.5
共298兲
共363兲
共313兲
共298兲
共328兲
共343兲
共368兲
CGC
46.6
共353兲
A
49.9
共365兲
A
47.8
共369兲
A
69.9
共392兲
A
57.3
共388兲
A
61.2
共436兲
A
40.0
39.1
38.3
共273兲
共298兲
共323兲
34.6
共305兲
A
43.4⫾0.1
共298兲
C
40.9
共363兲
A
38.9⫾0.5
39.1
42.3
39.0⫾0.5
共298兲
共365兲
共298兲
共367兲
EB
A
40.1
共307兲
A
87.3
共436兲
77.3
共318兲
A
38.7⫾0.4
38.1⫾0.4
共289兲
共298兲
GS
GS
53.2
共341兲
A
55.2
共345兲
A
77.7
共400兲
54.9
41.5⫾0.4
43.1⫾0.8
共308兲
共318兲
共298兲
A
49.6
41.3⫾0.4
42.7⫾0.8
共309兲
共320兲
共298兲
A
51.1
共313兲
A
EB
C
C
C
47.6
C8 H12O
C8 H12O4
C8 H12O4
C8 H12O4 S
C8 H14
C8 H14
C8 H14
2-tert-butylfuran
共270–308兲
共270–308兲
diethyl fumerate
共326 – 492兲
diethyl maleate
共330– 498兲
thiodiacetic acid, diethyl ether
共385– 448兲
cis bicyclo关3.3.0兴octane
共298 –318兲
trans bicyclo关3.3.0兴octane
共298 –320兲
cis bicyclo关4.2.0兴octane
共298 –347兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关85/1兴
关108-75-8兴
关95/21兴
关95/4兴
关90/6兴
关85/1兴
关85/1兴
关85/1兴
关85/1兴
关622-39-9兴
关87/5兴
关4673-31-8兴
关87/5兴
关1122-81-2兴
关87/5兴
关122-98-5兴
关87/5兴关47/5兴
关94-70-2兴
关87/5兴
关156-43-4兴
关87/5兴
关250-21-5兴
关88/9兴
关88/9兴
关88/9兴
关87/5兴
关1552-12-1兴
关96/18兴
关10092-71-4兴
关87/5兴
关6553-48-6兴
关96/18兴
关87/5兴
关73/8兴
关73/8兴
关100-40-3兴
关87/5兴
关87/5兴关47/5兴
关99/16兴
关629-40-3兴
关87/5兴
关59348-18-4兴
关84/17兴
关7040-43-9兴
关98/2兴
关98/2兴
关623-91-6兴
关87/5兴关47/5兴
关141-05-9兴
关87/5兴关47/5兴
关925-47-3兴
关99/16兴
关1755-05-1兴
关87/5兴
关70/30兴
关70/30兴
关5597-89-7兴
关87/5兴
关70/30兴
关70/30兴
关28282-35-1兴
关87/5兴
ENTHALPIES OF VAPORIZATION
681
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H14
Compound
共Temperature range/K兲
C8 H14
cis bicyclo关5.1.0兴octane
共297–322兲
cyclooctene
共273– 411兲
共273–333兲
vinylcyclohexane
C8 H14
allylcyclopentane
C8 H14
2,5-dimethyl-1,5-hexadiene
共330–388兲
3,3-dimethyl-1,5-hexadiene
共293–371兲
1-ethylcyclohexene
共353– 412兲
共332– 411兲
1-methylbicyclo关4.1.0兴heptane
共340–394兲
1-octyne
C8 H14
C8 H14
C8 H14
C8 H14
C8 H14
共357– 400兲
C8 H14
C8 H14Cl2 S
C8 H14N2
C8 H14O
C8 H14O
C8 H14O
C8 H14O
C8 H14O
C8 H14O2
C8 H14O2
C8 H14O2
共347兲
共298兲
43.6⫾0.8
共309兲
A
42.0
41.6
共288兲
共300兲
A
39.7⫾0.2
共298兲
GCC
40.4⫾0.2
共298兲
GCC
38.8
共345兲
A
35.2
共308兲
A
39.1
40.1
共368兲
共347兲
A
MM
37.2
共355兲
A
42.3⫾0.1
38.5
共298兲
共372兲
C
A
44.5⫾0.1
39.9
共298兲
共383兲
C
A
43.9
39.7
共298兲
共378兲
A
42.7⫾0.1
39.6
共298兲
共377兲
C
A
共307兲
A
共308兲
A, GS
4-octyne
共362– 405兲
C8 H14Br2
39.5⫾0.4
42.7⫾1.2
Method
3-octyne
共363– 406兲
C8 H14
Mean temperature
(T m /K)
2-octyne
共368 – 412兲
C8 H14
⌬ vapH m
共kJ mol⫺1兲
1,2-dibromocyclooctane
共292–354兲
50.3
共2-chlorocyclohexyl兲共2-chloroethyl兲 sulfide
共293–333兲
62.5
2-piperidinopropionitrile
共283–318兲
cyclooctanone
共343–383兲
共343–383兲
共343–383兲
共323– 403兲
共394 – 484兲
2-ethyl-2-hexenal
共326 – 448兲
2-ethyl-4-methyl-2-pentenal
共311– 436兲
6-methyl-5-hepten-2-one
共364 –393兲
共328 – 451兲
(dl) 2-propylcyclopentanone
共332– 457兲
octanolactone
共345–380兲
共345–380兲
acrylic acid, neopentyl ester
共301–325兲
1,4-butanediol divinyl ether
57.6⫾0.3
GS
54.4
53.6
54.2
47.3
46.8
共298兲
共298兲
共298兲
共338兲
共409兲
CGC
CGC
CGC
A
A, EB
48.4
共341兲
A
46.7
共326兲
A
45.9
44.7⫾0.2
共379兲
共390兲
46.0
共347兲
A
48.9⫾0.2
52.8⫾1.3
共362兲
共298兲
MM
MM
45.7
共313兲
A
CAS registry number
Reference
关70/30兴
关70/30兴
关16526-90-2兴
关87/5兴关70/30兴
关931-88-4兴
关87/5兴
关41/6兴
关695-12-5兴
关79/17兴
关3524-75-2兴
关79/17兴
关627-58-7兴
关87/5兴
关24253-25-6兴
关87/5兴
关1453-24-3兴
关87/5兴
关60/20兴
关2439-79-4兴
关87/5兴
关629-05-0兴
关83/7兴
关87/5兴关70/24兴
关84/9兴
关2809-67-8兴
关83/7兴
关87/5兴关70/24兴
关84/9兴
关15232-76-5兴
关U/1兴关85/6兴
关87/5兴关70/24兴
关84/9兴
关1942-45-6兴
关83/7兴
关87/5兴关70/24兴
关84/9兴
关29974-69-4兴
关87/5兴关41/6兴
关16660-53-0兴
关87/5兴关48/9兴
关99/16兴
关97/10兴
关502-49-8兴
关95/21兴
关95/21兴
关95/21兴
关87/5兴
关87/5兴关76/10兴
关66266-68-2兴
关87/5兴关61/12兴
关28419-86-5兴
关87/5兴关61/12兴
关110-93-0兴
关89/8兴
关88/4兴
关1193-70-0兴
关87/5兴
关5698-29-3兴
关91/7兴
关91/7兴
关87/5兴
关3891-33-6兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
682
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H14O2
C8 H14O2
C8 H14O2
C8 H14O2
C8 H14O2
C8 H14O2
C8 H14O3
C8 H14O3
C8 H14O3
C8 H14O3
C8 H14O3
C8 H14O4
C8 H14O4
C8 H14O4
C8 H14O4
C8 H14O4
C8 H14O4
C8 H14O4
C8 H14O4
C8 H14O4 S
C8 H14O5
C8 H14O5
C8 H14O5
C8 H14O5
C8 H14O6
C8 H14O6
C8 H14O6 S
C8 H15Br
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共335– 440兲
49.0
butyl methacrylate
共343–373兲
47.4
共344 – 437兲
45.1
cyclopentanecarboxylic acid ethyl ester
共275–308兲
51.2⫾0.6
1,4-dioxaspiro关4.5兴decane
共278 –308兲
50.6⫾0.6
cyclohexyl acetate
共278 –318兲
51.7⫾0.2
共368 – 446兲
46.7
methylacrylic acid, tert-butyl ester
共313– 410兲
42.9
pentyl acrylate
共325– 440兲
44.9
butyric anhydride
共349– 470兲
49.1
diethylene glycol divinyl ether
共336 – 470兲
50.0
2-ethylacetoacetic acid, ethyl ester
共313– 471兲
53.3
isopropyl levulinate
共321– 481兲
56.6
52.0
propyl levulinate
共332– 495兲
56.3
54.0
2-acetoxypropionic acid, propyl ester
共318 – 469兲
59.5
3-acetoxypropionic acid, propyl ester
共361–373兲
74.7
diethyl succinate
共327– 490兲
56.5
diisopropyl oxalate
共418 –501兲
57.8
共316 – 467兲
57.6
dimethyl adipate
共382–500兲
58.8
dipropyl oxalate
共326 – 487兲
57.8
2-methylmalonic acid, diethyl ester
共312– 475兲
52.5
octanedioic acid 共suberic acid兲
共445– 619兲
91.4
thiodiacetic acid, diethyl ester
共384 – 448兲
77.3
isopropyl关1-共methoxycarbonyl兲ethyl兴 carbonate
共330– 493兲
55.5
2-共lactyloxy兲propionic acid, ethyl ester
共321–389兲
72.8
malic acid, diethyl ester
共353–527兲
59.6
propyl关1-共methoxycarbonyl兲ethyl兴 carbonate
共373– 495兲
58.0
共d兲 diethyl tartrate
共375–553兲
65.9
(dl) diethyl tartrate
共375–553兲
67.3
sulfonyldiacetic acid, diethyl ester
共421– 494兲
88.2
共421– 494兲
87.6
共2-bromoethyl兲cyclohexane
共311– 486兲
54.2
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共350兲
A
共358兲
共359兲
A
A
GS
CAS registry number
Reference
关87/5兴
关97-88-1兴
关87/5兴
关87/5兴
关96/22兴
关177-10-6兴
关98/21兴关02/32兴
关622-45-7兴
关96/11兴
关87/5兴关69/13兴
关585-07-9兴
关87/5兴
关2998-23-4兴
关87/5兴
关106-31-0兴
关87/5兴
关764-99-8兴
关87/5兴
关607-97-6兴
关87/5兴关47/5兴
关21884-26-4兴
关87/5兴关47/5兴
关31/1兴
关645-67-0兴
关87/5兴
关31/1兴
共298兲
GS
共298兲
共383兲
GS
A, EB
共328兲
A
共340兲
A
共364兲
A
共351兲
A
共328兲
A
共336兲
共422兲
A
共347兲
共436兲
A
共333兲
A
关87/5兴
共367兲
A
共342兲
A
共433兲
共331兲
A
A
共397兲
A
共341兲
A
共327兲
A
共460兲
A
共399兲
A
关87/5兴
关123-25-1兴
关87/5兴关47/5兴
关615-81-6兴
关87/5兴
关87/5兴关47/5兴
关627-93-0兴
关87/5兴
关615-98-5兴
关87/5兴关47/5兴
关609-08-5兴
关87/5兴关47/5兴
关505-48-6兴
关87/5兴关47/5兴
关925-47-3兴
关87/5兴
共345兲
A
关87/5兴
共336兲
A
共368兲
A
关87/5兴
关7554-12-3兴
关87/5兴关47/5兴
共388兲
A
共390兲
共390兲
A
共426兲
共436兲
A
共326兲
A
关87/5兴
关13811-71-7兴
关47/5兴
关87-91-2兴
关87/5兴关47/5兴
关29771-87-7兴
关99/16兴
关87/5兴
关1647-26-3兴
关87/5兴关47/5兴
关70/14兴
ENTHALPIES OF VAPORIZATION
683
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H15ClO
C8 H15ClO
C8 H15Cl3 O4
C8 H15N
C8 H15N
C8 H15NO
C8 H15NO
C8 H15NO2
C8 H15NO2
C8 H15NO2
C8 H15NO3
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
Compound
共Temperature range/K兲
octanoyl chloride
共343–373兲
5-methylheptanoyl chloride
共338 –373兲
trichlorohydrine pentaerythritol
共404 – 449兲
3-azabicyclo关3.2.2兴nonane
共303– 443兲
octanenitrile
共373– 480兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
74.5
共358兲
A
关111-64-8兴
关87/5兴关99/16兴
66.3
共353兲
A
关87/5兴关99/16兴
80.4
共419兲
52.2
共318兲
A
50.0
56.8⫾0.3
49.8
48.0
56.7
共388兲
共298兲
共389兲
共435兲
共331兲
A
C
EB
EB
共341兲
A
共355兲
A
共387兲
A
共361兲
A
共298兲
C
共364兲
A
共298兲
C
共374 – 420兲
共420– 479兲
共316 – 477兲
heptyl isocyanate
共326 – 461兲
47.5
methacrylic acid, N-tert-butylamide
共340– 467兲
49.6
methacrylic acid, 2-共dimethylamino兲ethyl ester
共372– 460兲
48.8
1-lactopiperidine
共346 – 408兲
62.1
N-acetyl-N-butylacetamide
64.4⫾0.4
N,N-diethyloxamic acid, ethyl ester
共349–525兲
60.5
1-ethyl-1-methylcyclopentane
38.8
cyclooctane
43.1⫾0.2
共289–369兲
43.3
共373– 434兲
39.3
43.3⫾0.2
共369– 467兲
39.4
1,1-dimethylcyclohexane
共271–303兲
39.6⫾0.1
38.8⫾0.1
37.9
37.8
共313–395兲
36.6
cis 1,2-dimethylcyclohexane
39.4
39.7
35.5⫾0.1
34.5⫾0.1
39.7⫾0.1
共322– 405兲
38.0
(dl) trans 1,2-dimethylcyclohexane
38.3
38.4
34.4⫾0.1
33.5⫾0.1
38.4⫾0.1
共316 –399兲
37.0
cis 1,3-dimethylcyclohexane
共318 –396兲
36.8
38.1
38.2
34.9⫾0.1
33.3⫾0.1
38.2⫾0.1
共316 –398兲
37.7
(dl) trans 1,3-dimethylcyclohexane
共314 – 400兲
37.9
共304兲
共388兲
共298兲
共384兲
共287兲
共298兲
共298兲
共298兲
共328兲
GC
A
EB
A, EB
GS
A
共298兲
共298兲
共370兲
共387兲
共298兲
共337兲
C
C
C
A, MM
共298兲
共298兲
共373兲
共387兲
共298兲
共331兲
C
C
C
A, MM
共333兲
共298兲
共298兲
共363兲
共385兲
共298兲
共331兲
C
C
C
MM
共329兲
A
A
关65/10兴
关283-24-9兴
关87/5兴
关124-12-9兴
关87/5兴
关77/5兴
关71/4兴
关71/4兴
关47/5兴
关4747-81-3兴
关87/5兴
关6554-73-0兴
关87/5兴
关2867-47-2兴
关87/5兴
关87/5兴
关1563-86-6兴
关65/12兴
关5411-58-5兴
关87/5兴关47/5兴
关16747-50-5兴
关81/10兴
关292-64-8兴
关89/16兴
关87/5兴
关76/10兴
关56/20兴
关87/5兴关56/20兴
关590-66-9兴
关95/27兴
关95/27兴
关75/12兴
关71/28兴
关87/5兴关49/6兴
关2207-01-4兴
关75/12兴
关71/28兴
关51/2兴
关51/2兴
关47/7兴
关87/5兴关45/2兴
关6876-23-9兴
关75/12兴
关71/28兴
关51/2兴
关51/2兴
关47/7兴
关87/5兴关45/2兴
关638-04-0兴
关87/5兴
关75/12兴
关71/28兴
关51/2兴
关51/2兴
关47/7兴
关45/2兴
关2207-03-6兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
684
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
C8 H16
Compound
共Temperature range/K兲
共314 –394兲
cis 1,4-dimethylcyclohexane
共317– 400兲
(dl) trans 1,4-dimethylcyclohexane
共313–395兲
ethylcyclohexane
共323– 407兲
propylcyclopentane
共323– 406兲
isopropylcyclopentane
共320– 403兲
1,1,2-trimethylcyclopentane
共309–389兲
1,1,3-trimethylcyclopentane
共301–379兲
1-ethyl-1-methylcyclopentane
共331–397兲
共238 –288兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
39.1
39.2
39.2⫾0.1
37.4
共298兲
共298兲
共298兲
共329兲
C
MM
39.0
39.0
39.0⫾0.1
37.6
共298兲
共298兲
共298兲
共332兲
C
A, MM
37.6
37.9
35.6⫾0.1
34.6⫾0.1
33.5⫾0.1
39.9⫾0.1
36.7
共298兲
共298兲
共341兲
共357兲
共377兲
共298兲
共328兲
C
C
C
C
A, MM
39.2⫾0.4
39.8⫾0.1
38.9⫾0.1
37.9⫾0.1
37.0⫾0.1
36.3⫾0.1
40.0⫾0.4
40.4
40.5
40.5⫾0.1
38.6
共298兲
共313兲
共328兲
共343兲
共358兲
共368兲
共298兲
共298兲
共298兲
共298兲
共338兲
C
A, MM
41.1
41.1⫾0.1
39.2
共298兲
共298兲
共338兲
C
A, MM
37.9
39.4⫾0.1
37.9
共298兲
共298兲
共335兲
C
A, MM
36.3
共324兲
A, MM
35.4
共316兲
A, MM
36.7
40.2
38.9
37.3
共346兲
共273兲
共298兲
共331兲
A
IPM
共253兲
共318兲
共273兲
共298兲
共337兲
A
A
IPM
共316 –396兲
(dl) cis 1-ethyl-2-methylcyclopentane
共238 –304兲
42.5
共303– 403兲
39.3
共238 –288兲
41.6
40.2
共322– 402兲
38.3
trans 1-ethyl-2-methylcyclopentane
39.3
cis 1-ethyl-3-methylcyclopentane
39.3
trans 1-ethyl-3-methylcyclopentane
38.9
1,1,2-trimethylcyclopentane
37.2
1,1,3-trimethylcyclopentane
36.0
cis, cis 1,2,3-trimethylcyclopentane
38.9
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
GC
C
C
C
C
C
GCC
CAS registry number
Reference
关75/12兴
关71/28兴
关47/7兴
关45/2兴
关624-29-3兴
关75/12兴
关71/28兴
关47/7兴
关87/5兴关45/2兴
关2207-04-7兴
关75/12兴
关71/28兴
关51/2兴
关51/2兴
关51/2兴
关47/7兴
关87/5兴关45/2兴
关1678-91-7兴
关87/17兴
关81/14兴
关81/14兴
关81/14兴
关81/14兴
关81/14兴
关78/16兴
关75/12兴
关41/28兴
关47/7兴
关87/5兴关45/2兴
关2040-96-2兴
关71/28兴
关47/7兴
关87/5兴关45/2兴
关3875-51-2兴
关71/28兴
关47/7兴
关87/5兴关45/2兴
关4259-00-1兴
关87/5兴关49/6兴
关4516-69-2兴
关87/5兴关49/6兴
关16747-50-5兴
关87/5兴
关87/5兴关74/11兴
关71/28兴
关49/6兴
关930-89-2兴
关87/5兴
关87/5兴
关74/11兴
关71/28兴
关49/6兴
共298兲
关71/28兴
共298兲
关41/7兴
共298兲
共298兲
关41/7兴
关4259-00-1兴
关71/28兴
关4516-69-2兴
关71/28兴
共298兲
关71/28兴
共298兲
ENTHALPIES OF VAPORIZATION
685
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C8 H16
cis, cis 1,2,4-trimethylcyclopentane
C8 H16
cis 1,2-trans-3-trimethylcyclopentane
C8 H16
cis 1,2-trans-4-trimethylcyclopentane
共311–392兲
trans 1,2-cis-4-trimethylcyclopentane
C8 H16
C8 H16
共305–385兲
1-octene
共373– 423兲
共263–291兲
共260–291兲
C8 H16
C8 H16
共317–395兲
cis 2-octene
共356 – 400兲
trans 2-octene
共356 –399兲
C8 H16
cis 3-octene
C8 H16
trans 3-octene
共354 –396兲
C8 H16
C8 H16
cis 4-octene
共353–395兲
trans 4-octene
共276 –308兲
共276 –308兲
共353–396兲
C8 H16
2-methyl-1-heptene
C8 H16
3-methyl-1-heptene
C8 H16
4-methyl-1-heptene
C8 H16
5-methyl-1-heptene
C8 H16
6-methyl-1-heptene
C8 H16
2-methyl-2-heptene
C8 H16
共257–396兲
3-methyl-cis-2-heptene
C8 H16
3-methyl-trans-2-heptene
C8 H16
4-methyl-cis-2-heptene
C8 H16
4-methyl-trans-2-heptene
C8 H16
5-methyl-cis-2-heptene
C8 H16
5-methyl-trans-2-heptene
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
38.1
共298兲
关71.28兴
38.1
共298兲
36.8
共326兲
A, MM
36.8
36.0
共298兲
共320兲
A, MM
40.6
39.5⫾0.1
38.6⫾0.1
37.6⫾0.1
36.6⫾0.1
35.8⫾0.1
40.2
41.2
40.3⫾0.2
38.0
38.8
共298兲
共313兲
共328兲
共343兲
共358兲
共368兲
共277兲
共275兲
共298兲
共298兲
共332兲
A, MM
40.2
37.8
共298兲
共371兲
A
37.9
40.2
共371兲
共298兲
39.7
共298兲
37.6
40.2
共369兲
共298兲
A
37.2
39.7
共368兲
共298兲
A
43.2⫾0.3
42.9⫾0.3
37.4
39.7
共292兲
共298兲
共368兲
共298兲
GS
GS
A
39.3
共298兲
38.5
共298兲
38.9
共298兲
38.9
共298兲
38.9
共298兲
39.7
41.2
共298兲
共272兲
39.7
共298兲
39.7
共298兲
关71/28兴
关4850-28-6兴
关87/5兴关49/6兴
关13398-35-1兴
关71/28兴
关87/5兴关49/6兴
关111-66-0兴
关95/21兴
关82/10兴
关82/10兴
关82/10兴
关82/10兴
关82/10兴
关81/19兴
关81/19兴
关77/1兴
关71/28兴
关87/5兴关50/6兴
关7642-04-8兴
关71/28兴
关87/5兴
关13389-42-9兴
关87/5兴
关71/28兴
关14850-22-7兴
关71/28兴
关14919-01-8兴
关87/5兴
关71/28兴
关7642-15-1兴
关87/5兴
关71/28兴
关14850-23-8兴
关00/7兴
关00/7兴
关87/5兴
关71/28兴
关15870-10-7兴
关71/28兴
关4810-09-7兴
关71/28兴
关13151-05-8兴
关71/28兴
关13151-04-7兴
关71/28兴
关5026-76-6兴
关71/28兴
关627-97-4兴
关71/28兴
关87/5兴关47/5兴
关22768-19-0兴
关71/28兴
关22768-20-3兴
关71/28兴
38.9
共298兲
关71/28兴
38.9
共298兲
39.3
共298兲
关71/28兴
关24608-84-2兴
关71/28兴
关24608-85-3兴
Method
CGC
C
C
C
C
C
MM
HSA
C
A
A
CAS registry number
Reference
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
686
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C8 H16
6-methyl-cis-2-heptene
C8 H16
6-methyl-trans-2-heptene
C8 H16
2-methyl-cis-3-heptene
C8 H16
2-methyl-trans-3-heptene
C8 H16
3-methyl-cis-3-heptene
C8 H16
3-methyl-trans-3-heptene
C8 H16
4-methyl-cis-3-heptene
C8 H16
4-methyl-trans-3-heptene
C8 H16
5-methyl-cis-3-heptene
C8 H16
5-methyl-trans-3-heptene
C8 H16
6-methyl-cis-3-heptene
C8 H16
6-methyl-trans-3-heptene
C8 H16
2-ethyl-1-hexene
C8 H16
3-ethyl-1-hexene
C8 H16
4-ethyl-1-hexene
C8 H16
2,3-dimethyl-1-hexene
C8 H16
2,4-dimethyl-1-hexene
C8 H16
2,5-dimethyl-1-hexene
C8 H16
3,3-dimethyl-1-hexene
C8 H16
3,4-dimethyl-1-hexene
C8 H16
3,5-dimethyl-1-hexene
C8 H16
4,4-dimethyl-1-hexene
C8 H16
4,5-dimethyl-1-hexene
C8 H16
5,5-dimethyl-1-hexene
C8 H16
3-ethyl-cis-2-hexene
C8 H16
3-ethyl-trans-2-hexene
C8 H16
4-ethyl-cis-2-hexene
C8 H16
4-ethyl-trans-2-hexene
C8 H16
2,3-dimethyl-2-hexene
C8 H16
2,4-dimethyl-2-hexene
C8 H16
2,5-dimethyl-2-hexene
C8 H16
3,4-dimethyl-cis-2-hexene
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
39.3
共298兲
关71/28兴
39.3
共298兲
39.3
共298兲
38.9
共298兲
38.9
共298兲
39.7
共298兲
39.7
共298兲
39.7
共298兲
39.7
共298兲
38.9
共298兲
38.9
共298兲
38.9
共298兲
38.9
共298兲
39.7
共298兲
38.5
共298兲
38.9
共298兲
38.5
共298兲
38.5
共298兲
38.9
共298兲
36.0
共298兲
38.9
共298兲
38.1
共298兲
31.0
共298兲
38.5
共298兲
37.7
共298兲
39.7
共298兲
39.7
共298兲
38.9
共298兲
38.9
共298兲
39.7
共298兲
38.5
共298兲
38.9
共298兲
关71/28兴
关51065-65-7兴
关71/28兴
关20488-34-0兴
关71/28兴
关692-96-6兴
关71/28兴
关22768-17-8兴
关71/28兴
关22768-18-9兴
关71/28兴
关14255-24-4兴
关71/28兴
关13714-85-7兴
关71/28兴
关50422-80-5兴
关71/28兴
关53510-18-2兴
关71/28兴
关66225-19-2兴
关71/28兴
关66225-20-5兴
关71/28兴
关1632-16-2兴
关71/28兴
关3404-58-8兴
关71/28兴
关16746-85-3兴
关71/28兴
关16746-86-4兴
关71/28兴
关16746-87-5兴
关71/28兴
关6795-92-4兴
关71/28兴
关3404-77-1兴
关71/28兴
关16745-94-1兴
关71/28兴
关7423-69-0兴
关71/28兴
关1647-08-1兴
关71/28兴
关16106-59-5兴
关71/28兴
关7116-86-1兴
关71/28兴
关36880-72-5兴
关71/28兴
关19781-63-6兴
关71/28兴
关54616-49-8兴
关71/28兴
关19781-63-6兴
关71/28兴
关7145-20-2兴
关71/28兴
关14255-23-3兴
关71/28兴
关3404-78-2兴
关71/28兴
关19550-81-3兴
Method
CAS registry number
Reference
ENTHALPIES OF VAPORIZATION
687
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C8 H16
3,4-dimethyl-trans-2-hexene
C8 H16
3,5-dimethyl-cis-2-hexene
C8 H16
3,5-dimethyl-trans-2-hexene
C8 H16
4,4-dimethyl-cis-2-hexene
C8 H16
4,4-dimethyl-trans-2-hexene
C8 H16
4,5-dimethyl-cis-2-hexene
C8 H16
4,5-dimethyl-trans-2-hexene
C8 H16
5,5-dimethyl-cis-2-hexene
C8 H16
5,5-dimethyl-trans-2-hexene
C8 H16
3-ethyl-3-hexene
C8 H16
cis 2,2-dimethyl-3-hexene
共319–380兲
C8 H16
共305–379兲
trans 2,2-dimethyl-3-hexene
共306 –379兲
C8 H16
共303–374兲
cis 2,3-dimethyl-3-hexene
C8 H16
trans 2,3-dimethyl-3-hexene
C8 H16
cis 2,4-dimethyl-3-hexene
C8 H16
trans 2,4-dimethyl-3-hexene
C8 H16
cis 2,5-dimethyl-3-hexene
C8 H16
trans 2,5-dimethyl-3-hexene
C8 H16
cis 3,4-dimethyl-3-hexene
C8 H16
trans 3,4-dimethyl-3-hexene
C8 H16
2-n-propyl-1-pentene
C8 H16
2-isopropyl-1-pentene
C8 H16
2-ethyl-3-methyl-1-pentene
共307–389兲
C8 H16
共308 –383兲
2-ethyl-4-methyl-1-pentene
C8 H16
3-ethyl-2-methyl-1-pentene
C8 H16
3-ethyl-3-methyl-1-pentene
C8 H16
3-ethyl-4-methyl-1-pentene
C8 H16
2,3,3-trimethyl-1-pentene
C8 H16
2,3,4-trimethyl-1-pentene
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
39.3
共298兲
39.3
共298兲
38.9
共298兲
38.9
共298兲
38.1
共298兲
38.1
共298兲
38.5
共298兲
38.5
共298兲
38.1
共298兲
38.1
共298兲
39.3
共298兲
35.3
37.2
36.1
共334兲
共298兲
共320兲
36.1
37.2
36.3
共321兲
共298兲
共318兲
38.9
共298兲
38.9
共298兲
38.5
共298兲
38.5
共298兲
37.2
共298兲
37.5
共298兲
39.7
共298兲
39.7
共298兲
39.3
共298兲
38.8
共298兲
36.4
38.9
36.4
共322兲
共298兲
共323兲
38.5
共298兲
37.7
共298兲
38.9
共298兲
38.5
共298兲
38.5
共298兲
Method
CAS registry number
Reference
关71/28兴
关19550-82-4兴
关71/28兴
关66225-31-8兴
关71/28兴
关66225-12-5兴
关71/28兴
关66225-13-6兴
关71/28兴
关19550-83-5兴
关71/28兴
A
MM
A
MM
A
MM
关71/28兴
关66225-14-7兴
关71/28兴
关39761-61-0兴
关71/28兴
关39782-43-9兴
关71/28兴
关16789-51-8兴
关71/28兴
关690-92-6兴
关87/5兴
关71/28兴
关60/20兴
关690-93-7兴
关87/5兴
关71/28兴
关60/20兴
关59643-75-3兴
关71/28兴
关66225-30-7兴
关71/28兴
关37549-89-6兴
关71/28兴
关61847-78-7兴
关71/28兴
关10557-44-5兴
关71/28兴
关692-70-6兴
关71/28兴
关19550-87-9兴
关71/28兴
关19550-88-0兴
关71/28兴
关71/28兴
关61847-79-8兴
关71/28兴
关3404-67-9兴
关87/5兴
关71/28兴
关60/20兴
关3404-80-6兴
关71/28兴
关19780-66-6兴
关71/28兴
关6196-60-7兴
关71/28兴
关61847-80-1兴
关71/28兴
关560-23-6兴
关71/28兴
关565-76-4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
688
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H16
Compound
共Temperature range/K兲
2,4,4-trimethyl-1-pentene
共343–381兲
C8 H16
共301–375兲
3,3,4-trimethyl-1-pentene
C8 H16
2-methyl-3-ethyl-2-pentene
C8 H16
4-methyl-3-ethyl-cis-2-pentene
C8 H16
4-methyl-3-ethyl-trans-2-pentene
C8 H16
2,3,4-trimethyl-2-pentene
C8 H16
2,4,4-trimethyl-2-pentene
共319–380兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
38.5
共298兲
33.5
35.7
35.1
共358兲
共298兲
共316兲
38.1
共298兲
39.3
共298兲
39.3
共298兲
38.9
共298兲
39.3
共298兲
35.7
39.3
37.2
共334兲
共298兲
共320兲
38.9
共298兲
38.9
共298兲
关71/28兴
关107-39-1兴
关87/5兴
关71/28兴
关60/20兴
关564-03-4兴
关71/28兴
关19780-67-7兴
关71/28兴
关42067-48-1兴
关71/28兴
关42067-49-2兴
关71/28兴
关565-77-5兴
关71/28兴
关107-40-4兴
关87/5兴
关71/28兴
关60/20兴
关39761-64-3兴
关71/28兴
关39761-64-3兴
关71/28兴
38.1
共298兲
关71/28兴
关71/28兴
关62168-26-7兴
关87/5兴关56/16兴
关70/14兴关99/16兴
关20395-24-8兴
关87/12兴关91/2兴
关87/5兴关56/16兴
关70/14兴关99/16兴
关21948-46-9兴
关82/12兴关99/16兴
关82/12兴关92/1兴
关2162-99-4兴
关99/16兴
关88/11兴关91/2兴
关2162-99-4兴
关99/16兴
关61350-03-6兴
关87/5兴关56/16兴
关70/14兴关99/16兴
Method
A
MM
A
CAS registry number
Reference
C8 H16
共305–378兲
3,4,4-trimethyl-cis-2-pentene
C8 H16
3,4,4-trimethyl-trans-2-pentene
C8 H16
3-methyl-2-isopropyl-1-butene
C8 H16
3,3-dimethyl-2-ethyl-1-butene
38.5
共298兲
C8 H16Br2
1,1-dibromooctane
共412–571兲
57.1
共427兲
A, EST
1,1-dichlorooctane
共380– 480兲
共382–533兲
57.7
51.4
共298兲
共397兲
A
A, EST
52.0
57.6
共385兲
共298兲
55.9
65.6
共426兲
共298兲
47.3
共415兲
44.2
共344兲
A, EST
共298兲
GS
关96/20兴
关5921-54-0兴
关93/21兴
共298兲
C
关76/3兴
GS
关97/10兴
关124-13-0兴
关95/21兴
关87/5兴
关81/18兴
关18641-70-8兴
关87/5兴
关1940-18-7兴
关87/5兴
关13019-20-0兴
关87/5兴
关51500-48-2兴
C8 H16Cl2
C8 H16Cl2
C8 H16Cl2
C8 H16Cl2
C8 H16F2
C8 H16NO2
C8 H16N2
C8 H16N2
C8 H16N2
C8 H16O
C8 H16O
C8 H16O
C8 H16O
C8 H16O
1,2-dichlorooctane
共370– 490兲
共370– 490兲
1,8-dichlorooctane
共410–510兲
共410–510兲
erythro-4,5-dichlorooctane
共351– 480兲
1,1-difluorooctane
共329– 459兲
ethyl 2-共N,N-dimethylamino兲-2-methylpropanoate
共278 –313兲
51.6⫾0.5
methyl ethyl ketazine
共439–524兲
40.0
1,1,4,4-tetramethyltetramethylenediazine
50.1⫾0.4
2-diethylamino-2-methylpropionitrile
56.3⫾1.1
octanal
共313–353兲
53.8
共293– 438兲
43.4
51.3⫾0.2
2,4-dimethyl-3-hexanone
共350– 418兲
42.5
1-ethylcyclohexanol
共324 – 440兲
46.9
2-methyl-3-heptanone
共350– 428兲
43.5
6-methyl-3-hepten-2-ol
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
MM
共298兲
共308兲
共298兲
CGC
A
共365兲
A
共339兲
A
共365兲
A
ENTHALPIES OF VAPORIZATION
689
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H16O
C8 H16O
C8 H16O
C8 H16O
C8 H16O
C8 H16O
C8 H16O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共314 – 449兲
(dl) 6-methyl-5-hepten-2-ol
共314 – 448兲
2-octanone
共343–383兲
共317– 446兲
59.7
共329兲
A
57.0
共329兲
A
52.6
49.8
52.0⫾0.3
49.1
51.8
50.6
共298兲
共332兲
共298兲
共339兲
共298兲
共311兲
CGC
A
GCC
A
43.8
共308兲
A
36.4
共303兲
A
64.2
共359兲
A
55.7
43.3⫾0.2
43.3⫾0.1
共302兲
共298兲
共298兲
A
C
C
关87/5兴关47/5兴
关4630-06-2兴
关87/5兴关47/5兴
关111-13-7兴
关95/21兴
关87/5兴
关79/7兴
关87/5兴关75/8兴
关75/8兴
关47/5兴
关106-68-3兴
关87/5兴
关589-63-9兴
关87/5兴
关1604-02-0兴
关87/5兴
关5857-36-2兴
关87/5兴关47/5兴
关70/18兴
关66/2兴
36.7
共338兲
A
关87/5兴
41.9⫾1.2
共298兲
关67/37兴
42.3⫾1.2
共298兲
48.6⫾0.2
49.0⫾0.2
52.4
共298兲
79.8⫾0.6
81.0⫾0.6
81.2
66.6
85.3
74.4
80.0
82.9⫾1.0
70.0
共320兲
共298兲
共298兲
共432兲
共311兲
共375兲
共290兲
共298兲
共407兲
GS
GS
CGC
A, EB
A
A
47.4⫾0.3
51.5⫾1.3
51.8
48.6
共359兲
共298兲
共311兲
共315兲
EB
EB
A
A
76.3⫾0.9
61.8
75.6⫾0.5
共298兲
共418兲
共298兲
EB
A
C
52.1
50.9
48.9
46.2
共298兲
共318兲
共319兲
共387兲
GC
A
DTA
41.7
共292兲
A
44.5⫾0.1
46.9
共298兲
共292兲
GS
A
44.1
共296兲
A
49.1
50.2⫾0.1
共350兲
共326兲
关67/37兴
关933-40-4兴
关02/32兴
关98/21兴
关94/16兴
关124-07-2兴
关00/6兴
关00/6兴
关95/21兴
关87/9兴
关87/5兴
关87/5兴
关82/4兴
关79/4兴
关43/7兴
关123-66-0兴
关91/7兴
关91/7兴
关87/5兴
关87/5兴
关149-57-5兴
关97/8兴
关87/5兴
关76/1兴
关142-92-7兴
关97/13兴
关95/16兴
关87/5兴
关80/8兴
关539-90-2兴
关87/5兴关47/5兴
关97-85-8兴
关96/11兴
关87/5兴关47/5兴
关624-54-4兴
关87/5兴
关106-73-0兴
关02/27兴
关02/27兴
共324 –520兲
共324 –520兲
共296 – 446兲
3-octanone
共293–348兲
4-octanone
共288 – 433兲
1-propylcyclopentanol
共344 – 447兲
2,2,4-trimethyl-3-pentanone
共287– 408兲
C8 H16O2
3-butoxy-2-butanone
共323–398兲
trans 2,2,4,6-tetramethyl-1,3-dioxane
C8 H16O2
cis 2,2,4,6-tetramethyl-1,3-dioxane
C8 H16O2
1,1-dimethoxycyclohexane
共278 –308兲
共278 –308兲
共315–347兲
octanoic acid 共caprylic acid兲
共297–343兲
共297– 434兲
共353–393兲
共417–514兲
共296 –331兲
共360–512兲
C8 H16O2
共291–303兲
C8 H16O2
C8 H16O2
C8 H16O2
C8 H16O2
C8 H16O2
C8 H16O2
C8 H16O2
ethyl hexanoate
共345–374兲
共345–379兲
共396 – 449兲
共300–376兲
(dl) 2-ethylhexanoic acid
共397–514兲
共403–500兲
共331兲
GS
GS
EB
TE
I
hexyl acetate
共303– 444兲
共304 –381兲
共378 – 459兲
isobutyl butyrate
共277– 430兲
isobutyl isobutyrate
共278 –313兲
共277– 421兲
isopentyl propionate
共281– 434兲
methyl heptanoate
CAS registry number
Reference
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
690
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
51.8⫾0.1
53.4
53.7
53.5
49.7⫾0.5
53.1⫾0.4
53.1⫾0.1
51.6⫾0.5
49.0
共298兲
共298兲
共298兲
共298兲
共298兲
共298兲
共298兲
共298兲
共347兲
CGC
CGC
CGC
GC
GCC
C
C
A, EST
45.4
共299兲
A
44.3
共296兲
A
50.8⫾0.4
50.6⫾0.4
共294兲
共298兲
GS
GS
共298兲
C
共363兲
A
共326兲
A
共358兲
A
共308兲
A
共399兲
A
共326兲
A
共303兲
A
共308兲
A
共298兲
共298兲
CGC
C
共298兲
共298兲
共388兲
CGC
C
A, EST
48.4
共358兲
A
51.4
50.3
52.4⫾0.1
共298兲
共342兲
共298兲
A, DTA
C
47.8
共345兲
A
44.2
ether
68.6
共386兲
A
共398兲
A
60.7
共288兲
A,GS
59.5
共288兲
GS
N-tert-butyl bis共2-chloromethyl兲amine
共273–345兲
58.4
共288兲
A, GS
Compound
共Temperature range/K兲
共313–363兲
共433– 473兲
共313–353兲
C8 H16O2
共332– 402兲
4-methylvaleric acid, ethyl ester
共284 – 434兲
propyl isovalerate
共281– 429兲
ethyl hexanoate
共279–309兲
共279–309兲
关共3-methylbutoxy兲methyl兴oxirane
C8 H16O3
2-butoxyethyl acetate
C8 H16O2
C8 H16O2
C8 H16O2
55.8⫾1.9
C8 H16O3
C8 H16O3
C8 H16O3
C8 H16O3
C8 H16O3
C8 H16O3
C8 H16O3
C8 H16O3
C8 H16O4
C8 H17Br
C8 H17Br
C8 H17Cl
C8 H17Cl
C8 H17Cl
C8 H17ClO4
C8 H17Cl2 N
C8 H17Cl2 N
C8 H17Cl2 N
59.5⫾0.1
2-butoxypropionic acid, methyl ester
共348 – 417兲
51.9
3-butoxypropionic acid, methyl ester
共311– 469兲
51.1
3-ethoxypropionic acid, propyl ester
共343– 461兲
48.6
ethylene glycol monobutyl ether acetate
共293– 465兲
51.9
2-hydroxyisobutyric acid, butyl ester
共384 – 458兲
47.7
3-methoxypropionic acid, butyl ester
共311– 469兲
50.9
pentyl lactate
共288 – 469兲
73.9
diethylene glycol monoethyl ether acetate
共293– 491兲
51.7
1,4,7,10-tetraoxacyclododecane 共12-crown-4兲
65.7⫾3.7
65.6⫾0.4
1-bromooctane
共323–363兲
55.1
55.8⫾0.1
共373– 475兲
49.3
(dl) 2-bromooctane
共343– 463兲
1-chlorooctane
共330– 460兲
共327– 457兲
(dl) 2-chlorooctane
共330– 446兲
共3-chloromethyl兲heptane
共371– 443兲
triethylene glycol mono共2-chloroethyl兲
共383–555兲
N-butyl bis共2-chloroethyl兲amine
共273–380兲
N-sec-butyl bis共2-chloromethyl兲amine
共273–373兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关02/27兴
关95/21兴
关95/21兴
关95/21兴
关87/17兴
关80/5兴
关80/5兴
关77/1兴
关87/5兴关63/16兴
关25415-67-2兴
关87/5兴关47/5兴
关557-00-6兴
关87/5兴关47/5兴
关123-66-0兴
关99/4兴
关99/4兴
关15965-97-6兴
关87/14兴
关112-07-2兴
关70/17兴
关4126-55-0兴
关87/5兴
关14144-34-4兴
关87/5兴
关87/5兴关54/15兴
关112-07-2兴
关87/5兴
关816-50-2兴
关87/5兴
关4195-88-4兴
关87/5兴
关6382-06-5兴
关87/5兴
关112-15-2兴
关87/5兴
关294-93-9兴
关00/9兴
关82/9兴
关111-83-1兴
关95/21兴
关76/6兴关77/1兴
关87/5兴关61/13兴
关70/14兴
关555-35-7兴
关87/5兴关99/16兴
关111-85-3兴
关84/9兴关91/2兴
关87/5兴关69/5兴
关68/1兴
关628-61-5兴
关87/5兴关99/16兴
关123-04-6兴
关87/5兴关99/16兴
关5197-66-0兴
关87/5兴关47/5兴
关42520-97-8兴
关87/5兴关48/13兴
关99/16兴
关87/5兴关48/13兴
关99/16兴
关10125-86-7兴
关87/5兴关48/13兴
ENTHALPIES OF VAPORIZATION
691
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H17Cl2 N
C8 H17F
C8 H17I
C8 H17NO
C8 H17NO
C8 H17NO
C8 H17NO
C8 H17NO
C8 H17NO
C8 H17NO2
C8 H17NO2
C8 H17NO2
C8 H17NO2
C8 H17NO2
C8 H17NO2
C8 H18
C8 H18
C8 H18
C8 H18
C8 H18
C8 H18
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
60.3
共288兲
A, GS
共307– 446兲
49.7
44.1
共298兲
共322兲
A, EST
1-iodooctane
共391–554兲
50.7
共406兲
A, EST
共294兲
共298兲
GS
GS
共313兲
A
共328兲
A
共308兲
A
共308兲
A
共308兲
A
关99/16兴
关87289-70-1兴
关87/5兴关48/13兴
关99/16兴
关463-11-6兴
关U/1兴关85/6兴
关87/5兴关61/13兴
关70/14兴
关629-27-6兴
关87/5兴关61/13兴
关70/14兴
关5470-07-0兴
关98/12兴
关98/12兴
关1114-76-7兴
关87/5兴
关929-55-5兴
关87/5兴
关7207-49-0兴
关87/5兴
关7207-50-3兴
关87/5兴
关7207-51-4兴
关87/5兴
共298兲
GS
关97/5兴
共401兲
A
关87/5兴
共388兲
A
共348兲
A
关87/5兴
关2743-60-4兴
关87/5兴
共283兲
DSC
关93/15兴
共318兲
A
共298兲
共258兲
共298兲
共317兲
C
A, MM
共298兲
共265兲
共298兲
共325兲
C
A, MM
共298兲
共261兲
共298兲
共320兲
C
A, MM
共298兲
共261兲
共298兲
共322兲
C
A, MM
共262兲
共298兲
共323兲
C
A, MM
共266兲
共298兲
共328兲
C
A, MM
关87/5兴
关590-73-8兴
关71/28兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
关584-94-1兴
关71/28兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
关589-43-5兴
关71/28兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
关592-13-2兴
关71/28兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
关563-16-6兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
关583-48-2兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
N-isobutyl bis共2-chloromethyl兲amine
共273–345兲
1-fluorooctane
N-propylpiperidine
共275–314兲
45.2⫾0.4
共275–314兲
44.9⫾0.4
butyric acid, N,N-diethylamide
共298 –373兲
38.7
caprylaldehyde oxime
共313– 400兲
71.3
2-octanone oxime
共293– 487兲
67.5
3-octanone oxime
共293– 400兲
67.2
4-octanone oxime
共293– 400兲
68.8
2,4,4-trimethyl-2-nitropentane
共288 –324兲
54.2⫾0.8
lactic acid, N-isopentylamide
共386 – 433兲
77.9
lactic acid, N-pentylamide
共373– 448兲
81.8
共l兲 leucine ethyl ester
共333– 449兲
43.5
ethyl 2-共N,N-dimethylamino兲-2-methylpropionate
55.6⫾0.4
共1-methylheptyl兲nitrite
共303–338兲
44.9
2,2-dimethylhexane
37.3
共243–380兲
39.7
37.3⫾0.1
共302–381兲
36.6
2,3-dimethylhexane
38.8
共250–388兲
41.4
38.8⫾0.1
共310–390兲
37.6
2,4-dimethylhexane
37.8
共246 –382兲
41.0
37.8⫾0.1
共305–385兲
36.9
2,5-dimethylhexane
37.9
共246 –382兲
41.1
37.9⫾0.1
共307–383兲
36.9
3,3-dimethylhexane
共247–385兲
41.2
37.5⫾0.1
共308 –386兲
36.6
3,4-dimethylhexane
共251–390兲
41.3
39.0⫾0.1
共313–392兲
37.7
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
692
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H18
Compound
共Temperature range/K兲
C8 H18
共314 –393兲
3-ethyl-2-methylpentane
共311–390兲
3-ethyl-3-methylpentane
共249–391兲
C8 H18
共312–393兲
2-methylheptane
共285–392兲
共233–283兲
C8 H18
共315–391兲
3-methylheptane
共286 –393兲
共238 –286兲
C8 H18
共316 –393兲
4-methylheptane
共253–391兲
C8 H18
共312–392兲
octane
共297– 400兲
共216 –278兲
共396 – 432兲
共428 –510兲
共506 –569兲
共295– 402兲
共298 –333兲
共217–297兲
C8 H18
C8 H18
Mean temperature
(T m /K)
39.7
42.4
39.6⫾0.1
38.2
共298兲
共268兲
共298兲
共329兲
C
A, MM
38.5
38.5⫾0.1
37.4
共298兲
共298兲
共326兲
C
A, MM
38.0
40.2
38.0⫾0.1
36.9
共298兲
共264兲
共298兲
共327兲
C
A, MM
39.8
39.7⫾0.1
38.7⫾0.1
37.3⫾0.1
36.0⫾0.1
41.6
39.7
39.8⫾0.1
38.1
共300兲
共298兲
共313兲
共333兲
共353兲
共268兲
共298兲
共298兲
共330兲
39.8⫾0.2
40.1
41.6
39.8
39.8⫾0.1
38.3
共298兲
共301兲
共271兲
共298兲
共298兲
共331兲
C
A
IPM
39.7⫾0.1
38.7⫾0.1
37.4⫾0.1
36.1⫾0.1
39.7
42.3
39.7⫾0.1
38.2
共298兲
共313兲
共333兲
共353兲
共298兲
共268兲
共298兲
共327兲
C
C
C
C
41.6
41.0
44.4
36.3
35.5
34.9
41.2
41.9
41.5⫾0.1
41.5⫾0.1
40.5⫾0.1
39.1⫾0.1
37.8⫾0.1
43.0
41.5
38.0⫾0.1
36.7⫾0.1
35.4⫾0.1
41.5⫾0.1
39.2
共298兲
共312兲
共263兲
共411兲
共443兲
共521兲
共310兲
共313兲
共298兲
共298兲
共313兲
共333兲
共353兲
共282兲
共298兲
共311兲
共328兲
共344兲
共298兲
共341兲
C
C
C
C
MM
333.0
共383兲
A
Method
3-ethylhexane
共251–391兲
C8 H18
⌬ vapH m
共kJ mol⫺1兲
共326 – 400兲
2,2,3,3-tetramethylbutane
共377–390兲
(dl) 2,2,3-trimethylpentane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
C
C
C
C
IPM
C
MM
C
MM
C
A, MM
A
A
A
A
A
C
C
C
C
C
CAS registry number
Reference
关619-99-8兴
关71/28兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
关609-26-7兴
关71/28兴
关47/7兴
关87/5兴关45/2兴
关1067-08-9兴
关71/28兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
关592-27-8兴
关87/5兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关87/5兴关74/11兴
关71/28兴
关47/7兴
关45/2兴
关589-81-1兴
关87/19兴
关87/5兴
关87/5兴关74/11兴
关71/28兴
关47/7兴
关45/2兴
关589-53-7兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关71/28兴
关47/5兴
关47/7兴
关87/5兴关45/2兴
关111-65-9兴
关94/12兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关86/13兴
关84/15兴
关81/9兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关73/11兴
关71/28兴
关60/21兴
关60/21兴
关60/21兴
关47/7兴
关45/2兴
关594-82-1兴
关87/5兴
关560-21-4兴
ENTHALPIES OF VAPORIZATION
693
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H18
Compound
共Temperature range/K兲
共306 –384兲
2,2,4-trimethylpentane
共373– 423兲
共289–333兲
共423–523兲
共372– 416兲
共413– 494兲
共490–544兲
共194 –299兲
共297–374兲
C8 H18
C8 H18
共318 –399兲
2,3,3-trimethylpentane
共308 –390兲
2,3,4-trimethylpentane
共288 – 400兲
共223–289兲
共223– 426兲
共223–278兲
C8 H18N2
共310–388兲
dibutyldiazene
C8 H18N2
di-tert-butyldiazene
共294 –305兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
37.7⫾0.1
37.1⫾0.1
36.6⫾0.1
36.0⫾0.1
35.5⫾0.1
35.1⫾0.1
34.8⫾0.1
34.1⫾0.1
33.5⫾0.1
36.9
36.9⫾0.1
36.1
共298兲
共308兲
共315兲
共323兲
共330兲
共338兲
共348兲
共358兲
共368兲
共298兲
共298兲
共321兲
34.9
36.1
31.6
32.2
31.5
31.4
35.2⫾0.1
34.4⫾0.1
33.4⫾0.1
32.6⫾0.1
31.7⫾0.1
31.0⫾0.1
35.1⫾0.1
34.3⫾0.1
33.2⫾0.1
32.0⫾0.1
35.1
40.7
35.1⫾0.1
34.8
31.0
33.9
共298兲
共304兲
共438兲
共387兲
共428兲
共505兲
共298兲
共313兲
共328兲
共343兲
共358兲
共368兲
共298兲
共313兲
共333兲
共353兲
共298兲
共209兲
共298兲
共312兲
共371兲
共333兲
37.6⫾0.1
36.9⫾0.1
36.5⫾0.1
36.0⫾0.1
35.5⫾0.1
35.1⫾0.1
34.4⫾0.1
33.9⫾0.1
33.3⫾0.1
37.2
36.9⫾0.1
37.2⫾0.1
36.4
共298兲
共308兲
共315兲
共323兲
共330兲
共338兲
共348兲
共358兲
共368兲
共298兲
共298兲
共298兲
共323兲
37.7
39.1
37.7⫾0.1
41.3
39.8
37.7
37.7⫾0.1
36.7
共303兲
共274兲
共298兲
共238兲
共263兲
共298兲
共298兲
共325兲
A
A
C
IPM, EB
IPM
49.3⫾0.2
共298兲
C
39.1⫾0.3
39.6
32.7
共298兲
共299兲
C
UV
I
Method
C
C
C
C
C
C
C
C
C
C
A, MM
CGC
A
A
A
A
C
C
C
C
C
C
C
C
C
C
A
C
A, MM
C
EB
C
C
C
C
C
C
C
C
C
C
C
A, MM
C
MM
CAS registry number
Reference
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关71/28兴
关47/7兴
关87/5兴关45/2兴
关540-84-1兴
关95/21兴
关91/3兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关82/10兴
关82/10兴
关82/10兴
关82/10兴
关82/10兴
关82/10兴
关79/13兴
关79/13兴
关79/13兴
关79/13兴
关71/28兴
关87/5兴关56/5兴
关47/7兴
关87/5兴关45/2兴
关40/6兴
关40/14兴
关560-21-4兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关98/16兴
关71/28兴
关47/7兴
关47/7兴
关87/5兴关45/2兴
关565-75-3兴
关87/5兴
关87/5兴
关81/9兴
关74/11兴
关74/11兴
关71/28兴
关47/7兴
关45/2兴
关2159-75-3兴
关78/3兴
关927-83-3兴
关76/3兴
关74/32兴
关74/32兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
694
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H18N2
Compound
共Temperature range/K兲
C8 H18N2 O
butylhydrazone butyraldehyde
共298 –323兲
isobutylhydrazone isobutyraldehyde
共288 –313兲
dibutyldiazene N-oxide
C8 H18O
heptyl methyl ether
C8 H18O
butyl tert-butyl ether
C8 H18N2
C8 H18O
共293–397兲
共356 –397兲
tert-butyl isobutyl ether
共273–308兲
C8 H18O
C8 H18O
butyl isobutyl ether
共328 – 406兲
sec-butyl tert-butyl ether
C8 H18O
1-methyl-1-tert-butoxypropane
C8 H18O
dibutyl ether
共339– 415兲
共336 – 415兲
C8 H18O
共362– 414兲
共362– 414兲
共362– 413兲
共386 – 440兲
di-tert-butyl ether
共290–386兲
共289–382兲
共289–382兲
共289–382兲
C8 H18O
共277–382兲
diisobutyl ether
共320–396兲
propyl tert-amyl ether
C8 H18O
isopropyl tert-amyl ether
C8 H18O
2-ethyl-1-hexanol
共373–398兲
共347– 457兲
3-ethyl-3-hexanol
共331– 433兲
2-ethyl-4-methyl-1-pentanol
共343– 450兲
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
2-methyl-1-heptanol
共350– 449兲
3-methyl-1-heptanol
共360– 459兲
4-methyl-1-heptanol
共357– 456兲
共354 – 456兲
(dl) 5-methyl-1-heptanol
共364 – 460兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
55.6
共310兲
关80/20兴
57.2
共300兲
45.9⫾0.1
共298兲
46.9
共298兲
43.2
41.6⫾0.2
42.3⫾0.3
41.7
38.3
共298兲
共298兲
共298兲
共308兲
共371兲
C
C
A
EB
41.2⫾0.3
39.2⫾0.3
40.9⫾0.3
40.1⫾0.1
共298兲
共298兲
共298兲
共298兲
C
GS
C
40.3
共343兲
A
关80/20兴
关16649-52-8兴
关81/7兴
关629-32-3兴
关U/1兴关85/6兴
关1000-63-1兴
关U/2兴关02/32兴
关02/11兴
关91/12兴
关87/5兴
关87/5兴关69/13兴
关33021-02-2兴
关U/2兴关02/32兴
关02/11兴
关96/11兴
关91/12兴
关17071-47-5兴
关87/5兴
41.3
共298兲
40.3⫾0.2
共298兲
C
40.9
41.7
44.7⫾0.1
45.0⫾0.1
44.4
36.4
40.6
39.4
共354兲
共351兲
共298兲
共298兲
共298兲
共413兲
共377兲
共413兲
A
A
C
C
37.7⫾0.3
37.3
37.2
31.6
37.6⫾0.1
38.7
共298兲
共304兲
共298兲
共380兲
共298兲
共292兲
EB
A
38.9
共335兲
A
43.8⫾0.7
共298兲
关U/2兴关02/32兴
41.6
共298兲
52.7
60.2
共388兲
共362兲
49.2
共345兲
58.9
共358兲
A
53.3
共365兲
A
53.4
共375兲
A
55.9
56.7
共372兲
共369兲
A
57.6
共379兲
A
关U/2兴关02/32兴
关104-76-7兴
关73/14兴
关87/5兴关61/12兴
关597-76-2兴
关73/26兴
关10137-88-9兴
关87/5兴关61/12兴
关73/26兴
关106-67-2兴
关87/5兴关73/26兴
关1070-32-2兴
关87/5兴关73/26兴
关817-91-4兴
关87/5兴
关73/26兴
关7212-53-5兴
关87/5兴关73/26兴
Method
C
EB
C
A
A
CAS registry number
Reference
关U2/兴关02/32兴
关32970-45-9兴
关91/12兴
关142-96-1兴
关87/5兴
关87/5兴
关82/6兴
关80/3兴
关76/2兴
关76/2兴
关69/15兴
关65/20兴
关6163-66-2兴
关96/5兴
关87/5兴关76/2兴
关76/2兴
关76/2兴
关75/3兴
关87/5兴关61/20兴
关628-55-7兴
关87/5兴
ENTHALPIES OF VAPORIZATION
695
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
C8 H18O
Compound
共Temperature range/K兲
6-methyl-1-heptanol
共368 – 610兲
2-methyl-2-heptanol
共343– 430兲
共339– 429兲
3-methyl-2-heptanol
共341– 440兲
4-methyl-2-heptanol
共351– 445兲
5-methyl-2-heptanol
共348 – 445兲
共348 – 445兲
(dl) 6-methyl-2-heptanol
共354 – 445兲
(dl) 2-methyl-3-heptanol
共349– 441兲
3-methyl-3-heptanol
共344 – 433兲
共338 – 433兲
4-methyl-3-heptanol
共330– 429兲
5-methyl-3-heptanol
共330– 427兲
(dl) 6-methyl-3-heptanol
共333– 432兲
2-methyl-4-heptanol
共348 – 440兲
共345– 437兲
(dl) 3-methyl-4-heptanol
共340– 438兲
4-methyl-4-heptanol
共344 – 434兲
共331– 434兲
2,5-dimethyl-3-hexanol
共337– 431兲
1-octanol
共282–321兲
共282–321兲
共373– 423兲
共273–363兲
共328 – 400兲
共430– 474兲
共397– 479兲
共475–555兲
共343– 468兲
共386 – 480兲
共352– 468兲
共293–353兲
共267–282兲
共365– 427兲
(dl) 2-octanol
共253–353兲
共333– 453兲
共367– 453兲
共345– 453兲
(dl) 3-octanol
共253–348兲
共313– 450兲
共366 – 450兲
共349– 449兲
(dl) 4-octanol
共343– 450兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
61.0
共383兲
A
53.1
55.0
共358兲
共354兲
A
48.0
共356兲
A
54.2
共366兲
A
51.9
47.2
共363兲
共363兲
A
55.2
共369兲
A
54.8
共364兲
A
54.1
54.7
共359兲
共353兲
A
43.9
共345兲
A
46.5
共345兲
A
47.6
共348兲
A
54.8
56.3
共363兲
共360兲
A
48.0
共355兲
A
54.4
54.8
共359兲
共345兲
A
55.0
共352兲
69.6
70.1
71.6
68.7
67.3
52.5
56.6
47.8
71.0⫾0.4
67.5
58.3
65.0
70.4
64.0
61.6
共303兲
共298兲
共298兲
共318兲
共343兲
共445兲
共412兲
共490兲
共298兲
共358兲
共401兲
共367兲
共308兲
共274兲
共380兲
70.7
60.7
56.1
60.0
共268兲
共348兲
共382兲
共360兲
71.6
64.1
54.5
58.8
共268兲
共328兲
共381兲
共364兲
57.3
共358兲
GS
GS
CGC
A
A
A
A
C
EB
DTA
A, ME
A
A
A
CAS registry number
Reference
关1653-40-3兴
关87/5兴关73/26兴
关625-25-2兴
关87/5兴
关73/26兴
关31367-46-1兴
关87/5兴关73/26兴
关56298-90-9兴
关87/5兴关73/26兴
关54630-50-1兴
关87/5兴
关73/26兴
关4730-22-7兴
关87/5兴关73/26兴
关18720-62-2兴
关87/5兴关73/26兴
关5582-82-1兴
关87/5兴
关73/26兴
关14979-39-6兴
关87/5兴关73/26兴
关18720-65-5兴
关87/5兴关73/26兴
关18720-66-6兴
关87/5兴
关21570-35-4兴
关87/5兴
关73/26兴
关1838-73-9兴
关87/5兴关73/26兴
关598-01-6兴
关87/5兴
关73/26兴
关19550-07-3兴
关73/26兴
关111-87-5兴
关01/3兴
关01/3兴
关95/21兴
关92/14兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关77/1兴
关73/26兴
关87/5兴关70/2兴
关69/5兴
关66/7兴
关87/5兴关65/15兴
关58/2兴
关123-96-6兴
关99/11兴
关87/5兴
关84/10兴
关73/26兴
关20296-29-1兴
关99/11兴
关87/5兴
关84/10兴
关73/26兴
关589-62-8兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
696
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H18O
C8 H18O
C8 H18O
C8 H18O2
C8 H18O2
C8 H18O2
C8 H18O2
C8 H18O2
C8 H18O2
C8 H18O2
C8 H18O3
C8 H18O3
C8 H18O4
C8 H18O4 S2
C8 H18O5
C8 H18S
C8 H18S
C8 H18S
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
54.8
62.1
共379兲
共356兲
60.6⫾0.1
58.6⫾0.1
56.5⫾0.1
54.2
54.7
共328兲
共343兲
共358兲
共367兲
共348兲
47.3
共333兲
57.1
共343兲
37.0
38.9
32.0
31.0
共333兲
共298兲
共261兲
共288兲
A
A
U28.2
50.6⫾0.1
共249兲
共298兲
A
C
50.9⫾0.1
ethylene glycol mono共2-ethylbutyl兲 ether
共357– 470兲
53.4
ethylene glycol monohexyl ether
共363– 483兲
54.6
3-hydroxymethyl-4-heptanol
共375–518兲
61.6
2,2,4-trimethyl-1,3-pentanediol
共396 – 489兲
66.6⫾2.1
共396 – 489兲
60.3⫾1.7
共396 – 489兲
55.0⫾1.6
共413–502兲
58.5
diethylene glycol diethyl ether
56.4⫾1.4
共330– 461兲
48.3
diethylene glycol monobutyl ether
共415–505兲
55.7
1,2-bis共2-methoxyethoxy兲ethane 共triglyme兲
63.7⫾3.3
2,2-butanediol bis共ethylsulfonate兲
共443– 493兲
75.7
tetraethylene glycol
共426 –581兲
92.2
dibutyl sulfide
共283–390兲
40.3
53.0
54.2⫾0.8
共390– 470兲
46.5
di-tert-butyl sulfide
共264 –329兲
44.9
共329– 470兲
41.4
共390– 470兲
46.4
共278 –308兲
44.8
共324 – 420兲
42.4
43.8
43.8⫾0.1
49.3⫾0.8
共325–350兲
42.3
diisobutyl sulfide
共325–346兲
46.4
48.7
48.5⫾0.8
共326 –346兲
43.1
共298兲
C
共372兲
A
共378兲
A
共390兲
A
共400兲
共440兲
共480兲
共428兲
EB
EB
EB
A
共298兲
共345兲
CGC
A
共430兲
A
共298兲
CGC
共458兲
A
共441兲
A
共298兲
共298兲
共298兲
共405兲
GC
A, EB
Compound
共Temperature range/K兲
共364 – 449兲
共341– 449兲
(dl) 2,4,4-trimethyl-1-pentanol
共352– 446兲
共333– 441兲
2,2,3-trimethyl-3-pentanol
共318 – 426兲
2,2,4-trimethyl-3-pentanol
共328 – 428兲
di-tert-butyl peroxide
共308 –358兲
共308 –358兲
共246 –311兲
共273–384兲
1,2-dipropoxyethane
共234 – 453兲
Method
C
C
C
A
1-butoxy-2-ethoxyethane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共279兲
共344兲
共405兲
共293兲
共339兲
共298兲
共298兲
共298兲
共333兲
共335兲
共298兲
共298兲
共336兲
A
GC
EB
A
GC
EB
CAS registry number
Reference
关84/10兴
关73/26兴
关123-44-4兴
关96/9兴
关96/9兴
关96/9兴
关87/5兴
关73/26兴
关7294-05-5兴
关73/26兴
关5162-48-1兴
关73/26兴
关110-05-4兴
关95/23兴
关95/23兴
关87/5兴关78/6兴
关87/5兴关51/10兴
关18854-56-3兴
关87/5兴
关70/17兴
关4413-13-2兴
关70/17兴
关4468-93-3兴
关87/5兴
关112-25-4兴
关87/5兴
关87/5兴
关144-19-4兴
关02/14兴
关02/14兴
关02/14兴
关87/5兴
关112-36-7兴
关00/9兴
关87/5兴
关112-36-7兴
关87/5兴
关112-49-2兴
关00/9兴
关76-20-0兴
关87/5兴关99/16兴
关112-60-7兴
关87/5兴关47/5兴
关544-40-1兴
关99/16兴
关81/12兴
关64/17兴
关87/5兴关52/9兴
关626-26-6兴
关99/16兴
关99/16兴
关99/16兴
关98/25兴
关87/5兴
关81/12兴
关72/11兴
关64/17兴
关62/17兴
关592-65-4兴
关87/5兴关99/16兴
关81/12兴
关64/17兴
关62/17兴
ENTHALPIES OF VAPORIZATION
697
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H18S
C8 H18S
C8 H18S
C8 H18S2
Compound
共Temperature range/K兲
1-octanethiol
共372– 473兲
2-octanethiol
共347– 489兲
(dl) 2-octanethiol
共361– 460兲
dibutyl disulfide
共383– 423兲
C8 H18S2
diisobutyl disulfide
C8 H18S2
2,7-dimethyl-4,5-dithiaoctane
C8 H18S2
2,2,5,5-tetramethyl-3,4-dithiahexane
共383– 423兲
C8 H18S2
C8 H19N
C8 H19N
1,8-octanedithiol
共405–543兲
N-butyl isobutylamine
共313– 423兲
N,N-dibutylamine
共343– 479兲
共291–305兲
C8 H19N
C8 H19N
C8 H19N
C8 H19N
C8 H19O2 PS3
C8 H19O3 P
C8 H19O3 P
C8 H19O3 PS2
C8 H19O3 PS2
C8 H20ClN
C8 H20N2
C8 H20N2
C8 H20N2 O2 S
C8 H20N2 O3
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
49.6
共387兲
A
49.0
共362兲
48.0
共376兲
A
64.1
62.3⫾0.2
62.3
共298兲
共298兲
共298兲
CGC
C
57.2
共298兲
57.2⫾0.1
共298兲
C
53.8
52.5⫾0.2
52.5
共298兲
共298兲
共298兲
CGC
C
60.9
共420兲
A
41.2
共328兲
A
46.0
46.0⫾0.1
44.8⫾0.1
48.1
49.4⫾0.1
45.7⫾0.3
共358兲
共343兲
共358兲
共298兲
共298兲
共298兲
A
C
C
共273–333兲
N,N-diisobutylamine
共291–305兲
39.3
共273–333兲
43.1⫾0.3
共268 – 413兲
43.8
N,N-di-sec-butylamine
共273–333兲
41.3⫾0.3
2-ethylhexylamine
共341– 447兲
44.8
octylamine
共343– 494兲
54.8⫾0.5
共323–373兲
54.6
共308 – 453兲
50.8
O,O-diethyl-S-关2-共ethylthio兲ethyl兴 dithiophosphate
共283– 401兲
76.7
dibutyl phosphite
共298 – 438兲
37.8
diisopropyl ethylphosphonate
60.7⫾4.2
O,O-diethyl-O-关2-共ethylthio兲ethyl兴 thiophosphate
共283– 411兲
78.7
O,O-diethyl-S-关2-共ethylthio兲ethyl兴 thiophosphate
共283– 401兲
76.4
dibutylammonium chloride
共553–563兲
116.7
tetraethylhydrazine
共308 –368兲
33.4
N,N,N⬘,N⬘-tetramethyl-1,3-butanediamine
共273–363兲
49.2
共335– 439兲
42.7
N,N,N⬘,N⬘-tetraethylsulfamide
共407–528兲
59.1
tris共2-hydroxyethyl兲ethylenediamine
C
I
共298兲
共298兲
共283兲
I
A
共298兲
I
共356兲
A
共298兲
共298兲
共323兲
EB
CGC
A
共298兲
A
共313兲
A
共298兲
A
共298兲
A
共558兲
A
共323兲
A
共288兲
共350兲
A
共422兲
A
CAS registry number
Reference
关111-88-6兴
关87/5兴关99/16兴
关32/2兴
关3001-66-9兴
关99/16兴
关10435-81-1兴
关87/5兴关99/16兴
关32/2兴
关629-45-8兴
关95/21兴
关85/2兴
关81/12兴
关81/12兴
关1518-72-5兴
关85/2兴
关110-06-5兴
关95/21兴
关85/2兴
关81/12兴
关1191-62-4兴
关87/5兴关43/6兴
关99/16兴
关20810-06-4兴
关87/5兴
关111-92-2兴
关87/5兴
关79/8兴
关79/8兴
关71/13兴
关69/2兴
关69/16兴
关110-93-3兴
关71/13兴
关69/16兴
关87/5兴关47/5兴
关69/16兴
关104-75-6兴
关87/5兴
关111-86-4兴
关96/4兴
关95/21兴
关87/5兴
关298-04-4兴
关87/5兴关99/16兴
关1809-19-4兴
关87/5兴
关56/23兴关82/15兴
关298-03-3兴
关87/5兴关99/16兴
关126-75-0兴
关87/5兴关99/16兴
关6287-40-7兴
关87/5兴关99/16兴
关4267-00-9兴
关87/5兴
关97-84-7兴
关02/42兴
关87/5兴
关2832-49-7兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
698
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C8 H20O5 P2 S2
C8 H20O7 P2
C8 H23N5
C8 H24N4 O3 P2
C9 F16
C9 F17NO3 S
C9 F18
C9 F18
C9 F18N2
C9 F18O3
C9 F19NO
C9 F20
C9 F21N
C9 F21N
C9 H4 O5
C9 H5 ClN2 O2
C9 H6 Cl6 O3 S
C9 H6 Cl6 O3 S
C9 H6 Cl6 O4 S
C9 H6 N2 O2
C9 H6 N2 O2
C9 H6 O2
C9 H7 Cl3 O3
C9 H7 F3 O2
C9 H7 F3 O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共373– 472兲
90.0
GS
dithiopyrophosphoric acid, tetraethyl ester
共293– 409兲
80.6
共308兲
A
pyrophosphoric acid, tetraethyl ester
共283– 411兲
82.2
共298兲
A
tetraethylene pentamine
共464 – 615兲
71.3
共478兲
A
pyrophosphoric acid tetrakis共dimethylamide兲
共273– 415兲
65.5
共288兲
A
trans perfluorohydrindane
45.2⫾0.1
共298兲
C
perfluoro-1-octanesulfonylisocyanate
共324 – 470兲
67.7
共339兲
A
perfluoro共propylcyclohexane兲
共321–396兲
40.4
共336兲
43.1⫾0.1
共298兲
C
43.1⫾0.5
共298兲
EB
43.1⫾0.1
共298兲
C
perfluoro共isopropylcyclohexane兲
46.7⫾0.1
共298兲
C
1,1,1,3,3,3-hexafluoro-N,N⬘-bis关2,2,2-trifluoro-1-共trifluoromethy兲-ethyidene兴-2,2-propanediamine
共314 –381兲
35.5
共329兲
A
carbonic acid, bis关1,1,1,3,3,3-hexafluoro-2-共trifluoromethyl兲-2-propyl兴 ester
共316 –358兲
39.7
共331兲
A
2,2,2-trifluoro-N-关1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl兴-ethanimidic acid,
1,2,2,2-tetrafluoro-1-共trifluoromethyl兲ethyl ester
37.6
共385兲
perfluorononane
共387–524兲
32.8
共402兲
A
perfluoro-N-methyl-N,N-dibutylamine
共339– 407兲
48.8⫾0.8
48.2⫾0.1
tris共heptafluoropropyl兲amine
46.6⫾0.3
共329– 403兲
46.9⫾0.7
共333– 403兲
40.6
trimellitic acid anhydride
共558 –596兲
65.6
5-chloro-2,4-diisocyanato-1-methylbenzene
共373– 433兲
66.7
共373– 433兲
60.2⫾0.2
Endosulfan I
共343– 453兲
80.4
Endosulfan II
共343– 453兲
82.4
Endosulfan sulfate
共343– 453兲
85.6
2,4-toluene diisocyanate
共373–530兲
59.7
共393–530兲
59.5
共373–530兲
61.3
共373– 433兲
57.7⫾0.2
2,6-toluene diisocyanate
共373– 463兲
60.4
coumarin
共379– 463兲
63.2
2,4,5-trichlorophenoxyacetic acid, methyl ester
共444 –573兲
76.9
trifluoroacetic acid, 3-tolyl ester
共363– 439兲
47.4
trifluoroacetic acid, 4-tolyl ester
共365– 442兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
47.8
共298兲
共298兲
EB
C
共298兲
共298兲
共348兲
C
EB
A
共573兲
A
共388兲
共403兲
A
共398兲
GC
共398兲
GC
共398兲
GC
共388兲
共408兲
共388兲
共403兲
A
A
I
共388兲
A
共394兲
A
共459兲
A
共378兲
A, EB
共380兲
A, EB
CAS registry number
Reference
关98/7兴
关3689-24-5兴
关87/5兴关99/16兴
关107-49-3兴
关87/5兴
关112-57-2兴
关87/5兴
关152-16-9兴
关87/5兴
关96/26兴
关34834-20-3兴
关87/5兴关99/16兴
关374-59-4兴
关99/16兴
关96/26兴
关81/23兴
关81/23兴
关96/26兴
关34451-14-4兴
关87/5兴关72/21兴
关40719-69-5兴
关87/5兴关75/22兴
关54120-06-8兴
关75/20兴
关375-96-2兴
关87/5兴关67/12兴
关99/16兴
关514-03-4兴
关95/20兴
关95/20兴
关338-83-3兴
关95/20兴
关95/20兴
关87/5兴
关552-30-7兴
关87/5兴
关15166-26-4兴
关87/5兴
关72/26兴
关959-98-8兴
关90/2兴
关33213-65-9兴
关90/2兴
关1031-07-8兴
关90/2兴
关584-84-9兴
关87/5兴
关87/5兴
关75/13兴
关72/26兴
关91-08-7兴
关87/5兴
关91-64-5兴
关87/5兴关47/5兴
关1928-37-6兴
关87/5兴关99/16兴
关1736-09-0兴
关87/5兴关69/13兴
关99/16兴
关1813-29-2兴
关87/5兴关69/13兴
ENTHALPIES OF VAPORIZATION
699
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H7 N
C9 H7 N
C9 H8
C9 H8 Cl2 O3
C9 H8 Cl3 NO3
C9 H8 N2
C9 H8 N2
C9 H8 O
C9 H8 O
C9 H8 O2
C9 H8 O2
C9 H9 F6 NO5
C9 H9 N
C9 H9 N
C9 H9 NO4
C9 H10
C9 H10
C9 H10
C9 H10
C9 H10
C9 H10
C9 H10
C9 H10
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
isoquinoline
共439–517兲
51.0
quinoline
共573– 668兲
46.9
共504 – 616兲
46.5
共463–794兲
46.1
共286 –309兲
58.1
共433–511兲
49.2
indene
共369– 457兲
45.3
共289– 455兲
43.6
共329– 454兲
43.9
2,4-dichlorophenoxyacetic acid, methyl ester
共403–548兲
68.0
2,2,4-trichloro-5-共4-morpholinyl兲-4-cyclopentene-1,3-dione
共453– 483兲
79.6
1-phenylpyrazole
70.2⫾3.4
1-phenylimidazole
84.6⫾3.7
1-indanone
共318 –348兲
60.3⫾0.4
3-phenyl-2-propenal 共cinnamaldehyde兲
62.4
共408 – 482兲
51.7
共349–519兲
58.2
共353–373兲
72.7
trans cinnamic acid
共430–573兲
73.9
7,7-dimethoxynorborane
共321–357兲
49.0
共l兲 N,O-bis共trifluoroacetal兲-threonine methyl ester
共323– 413兲
72.5
3-methylindole 共skatole兲
共368 –540兲
64.5
␣-methylbenzylcyanide
共284 –318兲
60.8⫾0.7
共284 –318兲
60.9⫾0.7
3-nitrobenzoic acid, ethyl ester
共381–571兲
65.1
indane
共374 – 466兲
44.0
49.0
共355– 482兲
45.0
2-methylstyrene
共305–385兲
47.9
3-methylstyrene
共314 –385兲
47.5
4-methylstyrene
共304 –390兲
47.6
␣-methylstyrene
共274 –314兲
49.2⫾0.3
48.9⫾0.3
共331– 467兲
48.6⫾0.4
共343– 493兲
44.3
共353– 413兲
44.8
cis ␤-methylstyrene
共348 – 498兲
44.8
trans ␤-methylstyrene
共291– 452兲
46.4
allylbenzene
共274 –313兲
46.5⫾0.2
46.3⫾0.2
Method
共454兲
A, EB
共588兲
共519兲
共478兲
共298兲
共448兲
DSC
共384兲
共304兲
共392兲
A
A
共418兲
A
共468兲
GC
共298兲
C
共298兲
C
A
GS
EB
GS
共298兲
共444兲
共364兲
共363兲
GC
TGA
A
A
共445兲
A
共339兲
EB
共338兲
A
共383兲
A
共301兲
共298兲
GS
GS
共396兲
A
共389兲
共298兲
共370兲
A
C
共320兲
A
共329兲
A
共319兲
A
共294兲
共298兲
共298兲
共358兲
共368兲
GS
共363兲
A
共306兲
A
共294兲
共298兲
GS
EB
A
A
CAS registry number
Reference
关99/16兴
关119-65-3兴
关87/5兴关61/10兴
关91-22-5兴
关96/10兴
关92/1兴
关87/5兴
关80/6兴
关87/5兴关61/10兴
关95-13-6兴
关87/5兴
关87/5兴关47/5兴
关42/3兴
关1928-38-7兴
关87/5兴关99/16兴
关75907-45-8兴
关80/25兴
关1126-00-7兴
关00/1兴
关7164-98-9兴
关00/1兴
关83-33-0兴
关98/3兴
关14371-10-9兴
关02/37兴
关02/40兴
关87/5兴关47/5兴
关87/5兴
关140-10-3兴
关87/5兴
关39869-70-0兴
关94/16兴
关1548-45-4兴
关87/5兴关99/16兴
关83-34-1兴
关87/5兴关47/5兴
关1823-91-2兴
关00/2兴
关00/2兴
关618-98-4兴
关87/5兴关47/5兴
关496-11-7兴
关87/5兴
关81/10兴
关76/26兴
关611-15-4兴
关87/5兴关53/13兴
关100-80-1兴
关87/5兴关53/13兴
关622-97-9兴
关87/5兴关53/13兴
关98-83-9兴
关99/21兴
关99/21兴
关97/6兴
关87/5兴
关87/5兴
关766-90-5兴
关87/5兴
关873-66-5兴
关87/5兴关47/5兴
关300-57-2兴
关99/21兴
关99/21兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
700
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H10Cl2 O4
Compound
共Temperature range/K兲
C9 H10O2
2,6-dichlorosyringaldehyde
共293–323兲
1,1-difluoro-3-phenylpropane
共278 –318兲
allyl phenyl ether
共349– 456兲
cinnamyl alcohol
共295–325兲
共310–328兲
共373–523兲
2,4-dimethylbenzaldehyde
共358 – 489兲
5-hydroxyindane
共393–524兲
4⬘-methylacetophenone
共288 –333兲
2-phenylpropionaldehyde
共364 –517兲
共364 –517兲
共364 –517兲
共364 –517兲
3-phenylpropionaldehyde
共330–363兲
benzyl methyl ketone
共343–383兲
共343–383兲
共273–328兲
ethyl phenyl ketone 共propiophenone兲
共388 – 623兲
共391– 454兲
2-vinylanisole
共314 – 467兲
3-vinylanisole
共316 – 471兲
4-vinylanisole
共318 – 478兲
methyl o-toluate
C9 H10O2
methyl m-toluate
C9 H10F2
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O
C9 H10O2
C9 H10O2
C9 H10O2
acetic acid, 3-tolyl ester
共385– 480兲
acetic acid, 4-tolyl ester
共385– 480兲
2-acetylanisole
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
82.2
共308兲
CGC
关99/13兴
53.3⫾0.4
共298兲
GS
49.4
共364兲
A
68.1⫾0.1
79.8
56.2
共310兲
共319兲
共388兲
TG,DTA
A
A
57.4
共373兲
A
55.4
共408兲
A
59.6
共303兲
A
52.3⫾0.2
49.4⫾0.2
46.6⫾0.3
43.4⫾0.5
共360兲
共400兲
共440兲
共480兲
EB
EB
EB
EB
67.5
共345兲
A
56.1
55.0
53.5⫾0.3
共298兲
共298兲
共298兲
CGC
CGC
52.1
44.4
共403兲
共406兲
A
EB, GS
56.7
共329兲
A
55.9
共331兲
A
54.9
共333兲
A
57.3⫾0.2
共293兲
C
60.3⫾0.2
53.5
共296兲
共388兲
C
55.7
共400兲
A, EB
55.9
共400兲
A, EB
共322兲
A, ME
55.5
60.4
共298兲
共305兲
A
ME
52.5⫾0.2
49.6⫾0.2
46.7⫾0.3
43.6⫾0.5
57.0
50.5
55.9
50.4
51.9
共380兲
共420兲
共460兲
共500兲
共356兲
共419兲
共303兲
共373兲
共332兲
EB
EB
EB
EB
BG
BG
A
A
关97/14兴
关1746-13-0兴
关87/5兴
关104-54-1兴
关02/3兴
关87/5兴
关87/5兴
关15764-16-6兴
关87/5兴
关1470-94-6兴
关87/5兴
关122-00-9兴
关87/5兴
关93-53-8兴
关02/21兴
关02/21兴
关02/21兴
关02/21兴
关104-53-0兴
关87/5兴
关103-79-7兴
关95/21兴
关95/21兴
关54/8兴
关93-55-0兴
关87/5兴
关65/7兴
关612-15-7兴
关87/5兴关47/5兴
关626-20-0兴
关87/5兴关47/5兴
关637-69-4兴
关87/5兴关47/5兴
关89-71-4兴
关98/6兴
关99-36-5兴
关98/6兴
关74/1兴
关122-46-3兴
关87/5兴关69/13兴
关140-39-6兴
关87/5兴关69/13兴
关579-74-8兴
关86/10兴
关100-06-1兴
关87/5兴关54/9兴
关7216-18-4兴
关58/25兴
关140-11-4兴
关87/5兴
关54/10兴
关93-89-0兴
关02/15兴
关02/15兴
关02/15兴
关02/15兴
关88/2兴
关88/2兴
关87/5兴
关87/5兴
关47/5兴
56.5
C9 H10O2
C9 H10O2
4-acetylanisole
共311–334兲
3,4-dihydro-2H-1,5-benzodioxepin
66.5
55.6
C9 H10O2
C9 H10O2
benzyl acetate
共283– 490兲
共283–328兲
ethylbenzoate
共369–531兲
共369–531兲
共369–531兲
共369–531兲
共344 – 440兲
共344 – 440兲
共288 –333兲
共358 – 487兲
共317– 486兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
ENTHALPIES OF VAPORIZATION
701
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H10O2
C9 H10O2
C9 H10O2
C9 H10O2
C9 H10O3
C9 H10O3
C9 H10O3
C9 H10O3
C9 H10O3
C9 H11Br
C9 H11Br
C9 H11Br
C9 H11Cl
C9 H11Cl
C9 H11Cl
C9 H11ClO2
C9 H11ClO4
C9 H11ClS
C9 H11F5 O2
C9 H11I
C9 H11NO
C9 H11NO2
C9 H11NO2
C9 H11NO2
C9 H12
Compound
共Temperature range/K兲
3-phenylpropionic acid
共375–553兲
3-methylbenzoic acid, methyl ester
共359–500兲
共phenoxymethyl兲oxirane
共400–532兲
共400–532兲
共400–532兲
共400–532兲
共400–532兲
共400–532兲
共343–373兲
2-phenyl-1,3-dioxolane
共285–333兲
共298 –333兲
ethyl salicylate
共288 –333兲
共334 –505兲
2-furanacrylic acid, ethyl ester
共428 –500兲
methyl 4-methoxybenozate
共382– 472兲
ethyl 4-hydroxybenzoate
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
67.0
共390兲
A
54.8
共374兲
A
69.9⫾0.7
60.3⫾0.5
56.7⫾0.4
53.1⫾0.4
51.3⫾0.5
49.4⫾0.6
65.6⫾0.1
共298兲
共400兲
共440兲
共480兲
共500兲
共520兲
EB
EB
EB
EB
EB
EB
62.6⫾0.7
62.1⫾0.3
共298兲
共316兲
GS
GS
59.2
55.2
共303兲
共349兲
A
A
56.8
共443兲
A
61.1
共397兲
EB
72.6
cis,cis 3-methyl-4-cyclohexene-1,2-dicarboxylic acid anhydride
共325–525兲
49.5⫾1.0
1-bromo-2-isopropylbenzene
共404 – 484兲
48.4
共419兲
共378 –528兲
49.8
共393兲
1-bromo-4-isopropylbenzene
共362– 493兲
51.1
共377兲
共388 –528兲
50.4
共403兲
cumyl bromide
58.0
共298兲
1-chloro-2-isopropylbenzene
共341– 465兲
48.1
共356兲
共363–508兲
47.7
共378兲
1-chloro-4-isopropylbenzene
共307– 472兲
51.4
共322兲
共368 –513兲
48.5
共383兲
cumyl chloride
54.7
共298兲
propylene glycol mono共4-chlorophenyl兲 ether
共417–542兲
64.9
共432兲
2-chlorosyringaldehyde
共293–323兲
77.7
共308兲
benzyl 共2-chloroethyl兲 sulfide
共293–333兲
52.3
共308兲
pentafluoropropionic acid, cyclohexyl ester
共335– 428兲
46.4
cumyl iodide
63.3
N-methylacetanilide
共383–519兲
60.1
共377–526兲
56.7
1-nitro-2-isopropylbenzene
共278 –323兲
65.5⫾0.7
65.6⫾0.7
ethyl 2-aminobenzoate 共ethyl anthranilate兲
共433–593兲
59.6
ethyl carbanilate
共380–510兲
84.2
cis bicyclo关4.3.0兴nona-3,7-diene
TGA
A
A
CGC
A
A
CGC
A
CGC
A, GS
共350兲
A, EB
共298兲
CGC
共398兲
共392兲
A
共301兲
共298兲
GS
共448兲
A
共395兲
A
CAS registry number
Reference
关501-52-0兴
关87/5兴
关99-36-5兴
关87/5兴
关122-60-1兴
关97/18兴
关97/18兴
关97/18兴
关97/18兴
关97/18兴
关97/18兴
关76/21兴
关936-51-6兴
关02/32兴
关95/25兴
关118-61-6兴
关87/5兴
关87/5兴
关623-20-1兴
关87/5兴
关121-98-2兴
关85/9兴
关120-47-8兴
关01/20兴
关35438-32-5兴
关84/14兴
关7073-94-1兴
关99/16兴
关87/5兴关70/14兴
关586-61-8兴
关99/16兴
关87/5兴关70/14兴
关3575-19-7兴
关02/29兴
关2077-13-6兴
关99/16兴
关87/5兴关70/14兴
关2621-46-7兴
关99/16兴
关87/5兴关70/14兴
关934-53-2兴
关02/29兴
关67146-43-4兴
关87/5兴关99/16兴
关99/13兴
关4322-51-8兴
关87/5兴关48/9兴
关99/16兴
关24262-73-5兴
关87/5兴关69/13兴
关54290-22-1兴
关02/29兴
关579-10-2兴
关87/5兴
关47/5兴
关6526-72-3兴
关00/15兴
关00/15兴
关87-25-2兴
关87/5兴
关101-99-5兴
关87/5兴关47/5兴
关38451-18-2兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
702
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H12
C9 H12
C9 H12
C9 H12
C9 H12
C9 H12
C9 H12
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
41.8
共371兲
A
44.3⫾0.3
43.0⫾0.3
40.5⫾0.3
38.0⫾0.3
35.2⫾0.5
共298兲
共320兲
共360兲
共400兲
共440兲
EB
EB
EB
EB
EB
42.3⫾0.3
共298兲
EB
41.2
共361兲
A
46.9
47.7
43.6
共298兲
共298兲
共368兲
A
46.6
46.9
43.4
共298兲
共298兲
共363兲
A
46.5
46.6
43.2
共298兲
共298兲
共364兲
A
45.1
41.2
42.1
45.1⫾0.1
44.0
45.1
45.1
41.9
共298兲
共364兲
共354兲
共298兲
共298兲
共298兲
共298兲
共358兲
C
MM
46.2
43.8
45.0
46.2
46.2
42.7
共298兲
共355兲
共298兲
共298兲
共298兲
共363兲
C
A, MM
3a,4,7,7a-tetrahydro-1H-indene
共338 – 440兲
1,2,3-trimethylbenzene
42.3
共353兲
A
共363– 456兲
49.0
48.8
44.8
49.1
49.1
共298兲
共298兲
共378兲
共298兲
共298兲
A
C
48.0
47.2
47.9
44.1
47.9
共298兲
共298兲
共298兲
共372兲
共298兲
A
C
47.6
46.2⫾1.3
47.5⫾2.1
43.5
49.7
47.5⫾0.1
43.9
47.7
47.5
共298兲
共319兲
共298兲
共363兲
共264兲
共298兲
共369兲
共286兲
共298兲
Compound
共Temperature range/K兲
共356 – 429兲
共Z兲 5-ethylidene-2-norbornene
共315– 462兲
共315– 462兲
共315– 462兲
共315– 462兲
共315– 462兲
5-ethylidene-2-norbornene
共314 – 420兲
trans 5-ethylidene-2-norbornene
共346 – 416兲
2-ethyltoluene
共353– 443兲
3-ethyltoluene
共348 – 438兲
4-ethyltoluene
共349– 442兲
isopropylbenzene
共349– 426兲
共339– 433兲
C9 H12
共343– 426兲
propylbenzene
共340–391兲
共348 – 433兲
C9 H12
C9 H12
C9 H12
1,2,4-trimethylbenzene
共357– 450兲
C9 H12
A
C
1,3,5-trimethylbenzene
共296 –342兲
共296 –342兲
共348 – 424兲
共249–356兲
共354 – 445兲
共273–299兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
MM
MM
A
C
A
MM
CAS registry number
Reference
关87/5兴
关28304-66-7兴
关97/18兴
关97/18兴
关97/18兴
关97/18兴
关97/18兴
关3048-64-4兴
关96/5兴
关28304-67-8兴
关87/5兴
关611-14-3兴
关94/11兴
关71/28兴
关87/5兴关49/6兴
关620-14-4兴
关94/11兴
关71/28兴
关87/5兴关49/6兴
关622-96-8兴
关94/11兴
关71/28兴
关87/5兴关49/6兴
关98-82-8兴
关94/11兴
关89/6兴
关87/5兴
关82/5兴
关75/12兴
关71/28兴
关47/7兴
关49/6兴关45/2兴
关103-65-1兴
关94/11兴
关86/13兴
关75/12兴
关71/28兴
关47/7兴
关87/5兴关49/6兴
关45/2兴
关3048-65-5兴
关87/5兴
关526-73-8兴
关94/11兴
关74/14兴
关87/5兴关49/6兴
关71/28兴
关47/7兴
关95-63-6兴
关94/11兴
关74/14兴
关71/28兴
关87/5兴关49/6兴
关47/7兴
关108-67-8兴
关94/11兴
关91/7兴
关91/7兴
关89/7兴
关87/5兴
关87/19兴
关87/5兴关49/6兴
关81/19兴
关71/28兴
ENTHALPIES OF VAPORIZATION
703
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H12
C9 H12NO5 PS
C9 H12N2
C9 H12N2
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
47.5
5-vinyl-2-norbornene
共301– 410兲
42.0
共354 – 409兲
48.9
O,O-dimethyl-O-共3-methyl-4-nitrophenyl兲thiophosphate
共293–382兲
78.0
n-pentylmalodinitrile
共298 –328兲
66.9⫾0.4
phenylhydrazone acetone
共413– 436兲
74.6
共1-methoxyethyl兲benzene
共298 –313兲
49.2⫾0.4
共298 –313兲
49.1⫾0.4
benzyl ethyl ether
共278 –314兲
53.5⫾0.4
共299– 460兲
48.0
2-ethylanisole
共302– 460兲
49.8
3-ethylanisole
共306 – 470兲
49.3
4-ethylanisole
共306 – 470兲
51.9
5-ethyl-3-methylphenol
共468 –521兲
55.0
共385–506兲
58.5
2-isopropylphenol
共375– 493兲
63.5
共370– 489兲
55.1
共375– 493兲
56.1
共335–501兲
57.3
3-isopropylphenol
共377– 497兲
64.3
4-isopropylphenol
共391–507兲
63.7
共380– 496兲
63.1
isopropyl phenyl ether
共345– 448兲
49.5
3-phenyl-1-propanol
共284 –328兲
共347–508兲
2-phenyl-2-propanol
共391– 423兲
phenyl propyl ether
共374 – 463兲
2-propylphenol
共377– 495兲
共381–504兲
共381–504兲
共381–504兲
3-propylphenol
共408 –538兲
共386 –512兲
共386 –512兲
共386 –512兲
4-propylphenol
共383–508兲
共347–517兲
共347–517兲
共347–517兲
共347–517兲
共347–517兲
2,3,5-trimethylphenol
共459–521兲
Mean temperature
(T m /K)
Method
共298兲
C
共316兲
共369兲
A
A
共308兲
A
GS
共424兲
A
共296兲
共298兲
GS
GS
共298兲
共314兲
GS
A
共317兲
A
共321兲
A
共321兲
A
共483兲
A, GS, EB
共390兲
共385兲
共390兲
共350兲
EB
A
共392兲
A
共406兲
共395兲
EB
A
共360兲
A
62.8
62.6
共299兲
共362兲
A
52.9
共406兲
A
46.5
共389兲
A
56.9
59.9
57.2
53.0
共392兲
共398兲
共423兲
共473兲
A
60.2
59.9
57.2
53.0
共423兲
共398兲
共423兲
共473兲
A
56.7
61.3
59.5
58.4
56.2
51.5
共398兲
共348兲
共373兲
共398兲
共423兲
共473兲
A
53.9
共474兲
A, GS, EB
CAS registry number
Reference
关47/7兴
关3048-64-4兴
关87/5兴
关87/5兴
关122-14-5兴
关87/5兴
关90/4兴
关103-02-6兴
关87/5兴
关01/16兴
关01/16兴
关539-30-0兴
关02/29兴
关87/5兴关47/5兴
关14804-32-1兴
关87/5兴关47/5兴
关10568-38-4兴
关87/5兴关47/5兴
关1515-95-3兴
关87/5兴关47/5兴
关87/5兴关64/14兴
关55/9兴
关88-69-7兴
关90/5兴
关87/5兴
关86/7兴
关47/5兴
关618-45-1兴
关87/5兴
关99-89-8兴
关90/5兴
关87/5兴
关2741-16-4兴
关87/5兴关65/25兴
关84/9兴
关122-97-4兴
关87/5兴
关47/5兴
关617-94-7兴
关87/5兴
关622-85-5兴
关87/5兴
关644-35-9兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关621-27-2兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关645-56-7兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关697-82-5兴
关87/5兴关64/14兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
704
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O
C9 H12O2
C9 H12O2
C9 H12O2
C9 H12O2
C9 H12O2
C9 H12O2
C9 H12O2
C9 H12O2
C9 H12O3
C9 H12S
C9 H12S
C9 H12S
C9 H12S
C9 H12S
C9 H12S
C9 H13Cl3 OS
C9 H13N
C9 H13N
C9 H13N
C9 H13N
C9 H13N
C9 H13N
C9 H13N
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共379–506兲
55.1
2,4,5-trimethylphenol
共379–505兲
56.5
2,4,6-trimethylphenol
共367– 494兲
53.2
3,4,5-trimethylphenol
共396 –521兲
61.1
2,5,6-trimethylphenol
共359–503兲
51.1⫾0.2
␣,␣-dimethylbenzyl alcohol
共311–338兲
63.4⫾0.5
共311–338兲
65.0⫾0.5
trimethylhydroquinone
共450–501兲
45.5⫾0.3
cumene hydroperoxide
共283–333兲
69.9
共347–390兲
74.0
1,3-dihydroxy-5-methyl-2-ethylbenzene
共388 – 453兲
77.1
3,5-dimethoxytoluene
共374 –520兲
59.5
ethylene glycol monobenzyl ether
共453–530兲
58.6
propylene glycol 1-phenyl ether
共389–509兲
59.5
isopropyl catechol 共isomer not specified兲
共393– 453兲
65.3
benzaldehyde dimethyl acetal
共278 –318兲
60.9⫾0.5
共283–318兲
56.5⫾0.7
1,3,5-trimethoxybenzene
68.2⫾2.0
benzyl ethyl sulfide
共346 –370兲
56.0
共345–500兲
54.8
56.9⫾2.1
2-ethylthioanisole
共481–511兲
44.3
ethyl m-tolyl sulfide
共472–502兲
43.5
ethyl p-tolyl sulfide
共473–503兲
43.6
共isopropylthio兲benzene
共461– 491兲
U23.6
共propylthio兲benzene
共473–503兲
44.3
2,3,3-trichloro-2-propenethioic acid, O-hexyl ester
共433– 483兲
69.5
␣,␣-dimethylbenzylamine
共283–323兲
56.4⫾0.7
共283–323兲
56.7⫾0.7
N,N-dimethylbenzylamine
共288 –328兲
48.9⫾0.4
共288 –328兲
49.5⫾0.4
50.1⫾0.9
N,N-dimethyl-2-toluidine
共301– 458兲
52.4
N,N-dimethyl-3-toluidine
58.2⫾6.9
N,N-dimethyl-4-toluidine
共323– 483兲
60.7
N-ethyl-3-toluidine
60.0⫾3.0
2-isopropylaniline
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共394兲
共394兲
A
共382兲
A
共411兲
A
共431兲
共325兲
共298兲
GS
GS
共475兲
共298兲
共362兲
A
A
共403兲
A, GC
共389兲
A
共468兲
A
共404兲
A
共423兲
共298兲
共300兲
GS
GS
共298兲
CGC
共358兲
共360兲
共298兲
A
共496兲
共487兲
共488兲
共476兲
共488兲
GC
共303兲
共298兲
GS
GS
共308兲
共298兲
共298兲
GS
GS
C
共316兲
A
共298兲
CGC
共338兲
A
共298兲
CGC
CAS registry number
Reference
关55/9兴
关496-78-6兴
关87/5兴关55/9兴
关527-60-6兴
关87/5兴关55/9兴
关527-54-8兴
关87/5兴
关2416-94-6兴
关88/4兴
关617-94-7兴
关99/3兴
关99/3兴
关700-13-0兴
关88/4兴
关80-15-9兴
关87/5兴
关87/5兴
关87/5兴关75/24兴
关4179-19-5兴
关87/5兴
关622-08-2兴
关87/5兴
关770-35-4兴
关87/5兴
关65/21兴
关1125-88-8兴
关02/32兴
关95/25兴
关621-23-8兴
关00/9兴
关6263-62-3兴
关99/16兴
关87/5兴
关62/20兴
关20760-06-9兴
关99/16兴
关34786-24-8兴
关99/16兴
关622.63-9兴
关99/16兴
关3019-20-3兴
关99/16兴
关874-79-3兴
关99/16兴
关76619-95-9兴
关80/24兴
关99/3兴
关99/3兴
关103-83-3兴
关99/3兴
关99/3兴
关96/21兴
关609-72-3兴
关87/5兴关47/5兴
关121-72-2兴
关96/1兴
关99-97-8兴
关87/5兴关47/5兴
关102-27-2兴
关96/1兴
关643-28-7兴
ENTHALPIES OF VAPORIZATION
705
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共286 –326兲
C9 H13N
C9 H14
4-isopropylaniline
共333–500兲
1-phenyl-2-propylamine
共333–353兲
2,4,6-trimethylaniline
共341–510兲
1-ethyltricyclo关 2,2,1,02,6兴 heptane
C9 H14
2-methylenebicyclo关2.2.2兴octane
C9 H14
2-methylbicyclo关2.2.2兴oct-2-ene
共363– 402兲
C9 H13N
C9 H13N
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
61.3⫾0.9
61.8⫾0.9
共306兲
共298兲
GS
57.5
共348兲
A
53.4
共343兲
A
64.1
共356兲
A
42.0⫾0.1
共298兲
C
共378兲
共298兲
A
EB
共365兲
A
共288兲
A
共323兲
A
Method
45.2
C9 H14
C9 H14F3 NO3
C9 H14N2
C9 H14O
C9 H14O
C9 H14O
C9 H14O
C9 H14O
C9 H14O2
C9 H14O2
C9 H14O4
C9 H14O4
C9 H14O4
C9 H14O4
C9 H14O5
C9 H14O5
C9 H14O5
C9 H14O6
C9 H14O7
C9 H15Cl3 O2
C9 H15NOS
C9 H15NOS
C9 H16
40.2
43.5⫾0.4
2-vinylbicyclo关2.2.1兴heptane
共350–385兲
38.6
N-trifluoroacetyl-l-leucine, methyl ester
共273– 463兲
55.9
azelaic acid dinitrile
共308 –341兲
80.4
cis 2-hexahydroindanone
57.5
trans 2-hexahydroindanone
56.1
2,5,6-trimethyl-2-cyclohexen-1-one
共371– 478兲
45.5⫾0.3
3,3,5-trimethyl-2-cyclohex-1-one 共isophorone兲
共311– 489兲
48.6
2,6-dimethyl-2,5-heptadien-4-one 共phorone兲
共315– 471兲
54.1
bicyclo关2.2.1兴heptan-7-one ethylene ketal
共283–318兲
53.8⫾0.2
methyl 2-octynoate
共283–312兲
64.5
diethyl citraconate
共332–504兲
54.9
diethyl itaconate
共324 –501兲
51.0
diethyl mesaconate
共335–502兲
55.9
1,1-cyclopropanedicarboxylic acid diethyl ester
共288 –318兲
63.9⫾0.5
diethyl acetylmalonate
共363–510兲
54.0
ethyl关共1-allyloxycarbonyl兲ethyl兴 carbonate
共342– 496兲
61.3
2-lactyloxypropionic acid, allyl ester
共331– 401兲
75.1
glycerol triacetate
共284 –319兲
82.0
83.4⫾1.0
trimethyl citrate
共379–560兲
67.4
3-chloro-2,2-bis共chloromethyl兲propyl butyrate
共426 – 482兲
73.6
carbamothioic acid, 共1-methylethyl兲-2-propynyl-S-ethyl ester
共298 –313兲
72.8
carbamothioic acid, propyl-2-propynyl-S-ethyl ester
共298 –313兲
64.6
1-nonyne
共320– 464兲
45.6⫾0.2
共320– 464兲
42.7⫾0.2
共320– 464兲
39.7⫾0.3
共298兲
共298兲
共425兲
共326兲
A
共330兲
A
CAS registry number
Reference
关00/14兴
关00/14兴
关99-88-7兴
关87/5兴关47/5兴
关300-62-9兴
关87/5兴
关88-05-1兴
关87/5兴关47/5兴
关96/18兴
关2972-20-5兴
关74/33兴
关4893-13-4兴
关87/5兴
关74/20兴关74/33兴
关2146-39-6兴
关87/5兴
关1115-39-5兴
关87/5兴关99/16兴
关1675-69-0兴
关87/5兴
关5689-04-3兴
关71/8兴
关16484-17-6兴
关71/8兴
关20030-30-2兴
关88/4兴
关78-59-1兴
关87/5兴关47/5兴
关504-20-1兴
关87/5兴关47/5兴
共378兲
A
关98/21兴关02/32兴
关111-12-6兴
关87/5兴关55/8兴
关691-83-8兴
关87/5兴关47/5兴
关2409-52-1兴
关87/5兴关47/5兴
关2418-31-7兴
关87/5兴关47/5兴
关1559-02-0兴
关98/22兴
关570-08-1兴
关87/5兴
共357兲
A
关87/5兴
共346兲
A
共299兲
共298兲
A
GCC
共394兲
A
关87/5兴
关102-76-1兴
关87/5兴
关80/5兴
关1587-20-8兴
关87/5兴关47/5兴
共441兲
A
共305兲
A
共305兲
A
共320兲
共360兲
共400兲
EB
EB
EB
GS
共297兲
A, ME
共347兲
A
共339兲
A
共350兲
A
GS
关87/5兴关99/16兴
关59300-33-3兴
关87/5兴关99/16兴
关59300-33-3兴
关87/5兴
关3452-09-3兴
关02/16兴
关02/16兴
关02/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
706
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共320– 464兲
trans bicyclo关6.1.0兴nonane
36.4⫾0.5
共440兲
EB
C9 H16
C9 H16
cis bicyclo关6.1.0兴nonane
C9 H16
共297–360兲
1,4-dimethylbicyclo关2.2.1兴heptane
共328 –393兲
Molecular formula
42.7⫾0.6
C9 H16
C9 H16
49.8⫾0.8
50.4⫾0.8
共312兲
EB
A
36.8
共343兲
A
trans 2,3-dimethylbicyclo关2.2.1兴heptane
共345– 411兲
39.3
共360兲
A
44.4
共364兲
A
47.1
45.9
41.9
42.6
共278兲
共305兲
共378兲
共365兲
A
A
A
GS
45.1
41.1
45.9
41.0
41.6
共296兲
共371兲
共272兲
共373兲
共360兲
A
A
A
A
GS
44.0⫾0.2
共298兲
GCC
42.0⫾0.2
共298兲
GCC
44.5⫾0.6
共298兲
GS
78.0
89.0
共318兲
共313兲
A
C9 H16
2-ethylbicyclo关2.2.1兴heptane
共349–396兲
cis hexahydroindan
共263–293兲
共290–366兲
共363– 463兲
共350– 442兲
trans hexahydroindan
共281–362兲
共356 – 457兲
共262–283兲
共358 – 479兲
共345– 435兲
allylcyclohexane
C9 H16
ethylidenecyclohexane
C9 H16
spiro关4.4兴nonane
共278 –313兲
1,1,1,9-tetrachlorononane
共303– 434兲
共298 –338兲
2-methyl-2-piperdinopropionitrile
C9 H16
C9 H16
C9 H16Cl4
C9 H16N2
C9 H16O
C9 H16O
C9 H16O
C9 H16O
C9 H16O
C9 H16O
C9 H16OS
C9 H16O2
C9 H16O2
C9 H16O2
C9 H16O2
C9 H16O2
C9 H16O2
EB
57.6⫾0.4
cyclononanone
共333– 413兲
51.4
1-共1-methyl-3-cyclohexen-3-yl兲ethanol
共358 – 410兲
54.6
methyl 共1-methylcyclohexyl兲 ketone
共374 – 414兲
46.1
trans 2-nonenal
共363–398兲
56.1
(dl) 3,5,5-trimethylcyclohexanone
共423– 463兲
39.3
2,5,5-trimethyl-4-hexene-1-al
共293–353兲
57.0
tetrahydro-2,2,6,6-tetramethyl-4H-thiopyran-4-one
共300–360兲
34.7
bicyclo关2.2.1兴heptan-7-one dimethyl ketal
共283–318兲
50.2⫾0.2
acetic acid, 2-methylcyclohexyl ester, mixed isomers
共337– 457兲
49.0
2-butyl-4,7-dihydro-1,3-dioxepine
共318 – 453兲
50.9
hexyl acrylate
共342– 461兲
48.2
methacrylic acid, neopentyl ester
共313–338兲
40.5
oxo-2-cyclodecanone 共nonanolactone兲
共352–381兲
54.5⫾0.2
共352–381兲
59.0⫾1.3
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
GS
共348兲
A
共373兲
A
共389兲
A
共378兲
A
共438兲
A
共308兲
A
共315兲
A
GS
共353兲
A
共333兲
A
共357兲
A
共325兲
A
共366兲
共298兲
MM
MM
CAS registry number
Reference
关02/16兴
关39124-79-3兴
关78/15兴
关13757-43-2兴
关78/15兴
关87/5兴关70/30兴
关20454-81-3兴
关87/5兴关70/6兴
关84/9兴
关20558-16-1兴
关87/5兴关70/6兴
关84/9兴
关2146-41-0兴
关87/5兴
关4551-51-3兴
关87/5兴
关87/5兴
关87/5兴
关55/7兴
关3296-50-2兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关55/7兴
关2114-42-3兴
关79/17兴
关1003-64-1兴
关79/17兴
关175-93-9兴
关02/32兴
关1561-48-4兴
关99/16兴
关87/5兴
关2273-41-8兴
关97/10兴
关3350-30-9兴
关87/5兴
关2890-62-2兴
关87/5兴
关2890-62-2兴
关87/5兴
关18829-56-6兴
关87/5兴
关873-94-9兴
关87/5兴
关1000-30-2兴
关87/5兴
关22842-41-7兴
关87/5兴关72/27兴
关99/16兴
关39869-70-0兴
关98/21兴关02/32兴
关5726-19-2兴
关87/5兴
关61732-95-4兴
关87/5兴
关2499-95-8兴
关87/5兴
关87/5兴
关6008-27-1兴
关91/7兴
关91/7兴
ENTHALPIES OF VAPORIZATION
707
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H16O2
C9 H16O2
C9 H16O3
C9 H16O3
C9 H16O3
C9 H16O4
C9 H16O4
C9 H16O4
C9 H16O4
C9 H16O4
C9 H16O5
C9 H16O5
C9 H16O5
C9 H16O5
C9 H17N
C9 H17N
C9 H17NO3
C9 H17NO3 S
C9 H18
C9 H18
C9 H18
C9 H18
C9 H18
Compound
共Temperature range/K兲
共333–383兲
2,6-dimethyl-3,5-heptanedione
pentyl methacrylate
共339– 456兲
butyl levulinate
共338 –511兲
sec-butyl levulinate
共393– 499兲
isobutyl levulinate
共338 –503兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
60.9
共348兲
A
56.1
共298兲
47.6
共354兲
A
55.5
56.0
共373兲
共452兲
A
51.0
共408兲
A
61.5
54.7
共353兲
共444兲
A
共340兲
A
共382兲
A
共353兲
A
共338兲
A
共466兲
A
关87/5兴
关40326-38-3兴
关87/5兴
关818-38-2兴
关87/5兴关47/5兴
关133-13-1兴
关87/5兴关47/5兴
关123-99-9兴
关87/5兴关47/5兴
共364兲
A
关87/5兴
共355兲
A
关87/5兴
共342兲
A
关87/5兴
共326兲
A
共340兲
共380兲
共420兲
共460兲
共500兲
EB, IPM
EB, IPM
EB, IPM
EB, IPM
EB,IPM
共343兲
A
共397兲
A
共447兲
A
共422兲
共328兲
共343兲
共358兲
共368兲
共298兲
A
C
C
C
C
共388兲
A
共310兲
共359兲
A
共298兲
共298兲
共298兲
共298兲
共361兲
GC
GCC
C
A, MM
共363兲
A
关87/5兴
关767-92-0兴
关94/17兴
关94/17兴
关94/17兴
关94/17兴
关94/17兴
关2243-27-8兴
关87/5兴
关56430-36-5兴
关87/5兴
关33280-93-2兴
关87/5兴关99/16兴
关2040-95-1兴
关87/5兴
关81/14兴
关81/14兴
关81/14兴
关81/14兴
关71/28兴
关19489-10-2兴
关87/5兴
关696-29-7兴
关87/5兴
关49/6兴
关1678-92-8兴
关87/17兴
关78/16兴
关71/28兴
关47/7兴
关87/5兴关47/5兴
关49/6兴
关3073-66-3兴
关87/5兴
2-acetoxypropionic acid, butyl ester
共325– 485兲
63.2
3-acetoxypropionic acid, butyl ester
共373–391兲
75.4
diethyl glutarate
共338 –510兲
55.7
ethylmalonic acid, diethyl ester
共323– 485兲
55.3
nonanedioic acid 共azelaic acid兲
共451– 630兲
89.3
butyl关1-共methoxycarbonyl兲ethyl兴 carbonate
共349–510兲
61.7
isobutyl关1-共methoxycarbonyl兲ethyl兴 carbonate
共340–501兲
59.1
2-lactoylpropionic acid, propyl ester
共327–397兲
73.5
methyl关1-共butoxycarbonyl兲ethyl兴 carbonate
共311–503兲
60.2
trans 共R,S兲-decahydroquinoline
共325–525兲
50.4
共325–525兲
47.6
共325–525兲
45.0
共325–525兲
42.3
共325–525兲
39.5
octyl cyanide
共328 –503兲
56.8
(dl) N-acetylvaline ethyl ester
共382– 466兲
67.7
(dl) N-acetylmethionine ethyl ester
共432–519兲
81.6
butylcyclopentane
共413– 432兲
39.4
43.8⫾0.1
42.7⫾0.1
41.6⫾0.1
40.9⫾0.1
46.0
cis 1-ethyl-3-methylcyclohexane
共373– 465兲
39.0
isopropylcyclohexane
共295– 431兲
44.1
共344 – 429兲
41.1
propylcyclohexane
42.8⫾0.5
44.7⫾0.4
45.2
45.2
共346 – 431兲
41.7
1,1,3-trimethylcyclohexane
共348 – 411兲
37.7
CAS registry number
Reference
关87/5兴
关18362-64-6兴
关78/18兴
关2849-98-1兴
关87/5兴
关2052-15-5兴
关87/5兴
关31/1兴
关2052-15-5兴
关87/5兴
关3757-32-2兴
关87/5兴关47/5兴
关31/1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
708
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H18
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共327– 410兲
共328 – 411兲
1,1,4-trimethylcyclohexane
38.6
38.4
共342兲
共343兲
Method
45.6
C9 H18
C9 H18
C9 H18
C9 H18
C9 H18
C9 H18
C9 H18
C9 H18
C9 H18
C9 H18Br2
C9 H18Cl2
C9 H18Cl2
C9 H18F2
C9 H18F2
C9 H18N2
C9 H18O
C9 H18O
C9 H18O
cis 1,3,5-trimethylcyclohexane
共318 – 410兲
2,6-dimethyl-1-heptene
共273–306兲
共273–306兲
1-nonene
共278 –318兲
共339– 423兲
cis 2-nonene
共379– 424兲
trans 2-nonene
共379– 422兲
cis 3-nonene
共376 – 422兲
trans 3-nonene
共377– 421兲
cis 4-nonene
共376 – 421兲
trans 4-nonene
共376 – 420兲
1,1-dibromononane
共427–591兲
1,1-dichlorononane
共420– 490兲
共398 –556兲
1,2-dichlorononane
共430–510兲
共430–510兲
1,1-difluorononane
共347– 482兲
2,2-difluorononane
共279–313兲
2-共diethylamino兲pentanenitrile
共283–318兲
共283–326兲
1-butylcyclopentanol
共359– 466兲
2,2,4,4-tetramethyl-3-pentanone
C9 H18O
共333兲
A
46.3⫾0.5
45.9⫾0.5
共290兲
共298兲
GS
GS
44.7⫾0.2
45.5
42.0
共298兲
共298兲
共354兲
GS
A, MM
40.7
共394兲
A
40.8
共394兲
A
40.3
共391兲
A
40.6
共392兲
A
40.1
共391兲
A
40.4
共391兲
A
59.5
共442兲
A, EST
62.3
54.0
共298兲
共413兲
A, EST
52.1
62.1
共443兲
共298兲
47.2
共362兲
A, EST
46.7⫾0.2
共298兲
GS
57.4⫾0.4
58.8
共298兲
GS
A
63.5
共374兲
A
45.5⫾0.4
45.4⫾0.1
45.4⫾0.1
共298兲
共298兲
共298兲
C
C
C
49.8⫾0.1
49.3⫾0.1
48.4⫾0.1
47.9⫾0.1
47.1⫾0.1
46.6⫾0.1
46.1⫾0.1
45.2⫾0.1
51.0
50.9⫾0.1
46.8
共308兲
共313兲
共323兲
共328兲
共338兲
共343兲
共348兲
共358兲
共298兲
共298兲
共351兲
C
C
C
C
C
C
C
C
C
A, MM
55.5
共373兲
A
2,6-dimethyl-4-heptanone
共322– 471兲
C9 H18O
38.3
共336 – 451兲
1-共1-methylcyclohexyl兲ethanol
共358 – 408兲
nonanal
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关62/24兴关84/9兴
关49/6兴
关7094-27-1兴
关95/31兴
关1795-27-3兴
关87/5兴
关3074-78-0兴
关00/7兴
关00/7兴
关124-11-8兴
关00/7兴
关71/28兴
关87/5兴关50/6兴
关6434-77-1兴
关87/5兴
关6434-78-2兴
关87/5兴
关20237-46-1兴
关87/5兴
关20063-92-7兴
关87/5兴
关10405-84-2兴
关87/5兴
关10405-85-3兴
关87/5兴
关62168-27-8兴
关87/5兴关56/16兴
关70/14兴关99/16兴
关821-88-5兴
关87/12兴关91/2兴
关87/5兴关56/16兴
关70/14兴关99/16兴
关56375-96-3兴
关99/16兴
关86/5兴关91/2兴
关62127-42-8兴
关87/5兴关56/16兴
关70/14兴关99/16兴
关97/14兴
关19340-91-9兴
关97/10兴
关87/5兴
关1462-97-1兴
关87/5兴
关815-24-7兴
关77/7兴
关70/18兴
关66/2兴
关108-83-8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关92/8兴
关75/8兴
关70/18兴
关87/5兴关47/8兴
关87/5兴
关124-19-6兴
ENTHALPIES OF VAPORIZATION
709
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共323–343兲
共313–353兲
共306 – 458兲
C9 H18O
C9 H18O
2-nonanone
共285– 454兲
共335– 468兲
共342–545兲
共335– 437兲
5-nonanone
共443– 486兲
共357– 468兲
C9 H18O
C9 H18O
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O2
共283–323兲
3,3,5-trimethylcyclohexanol
共343– 473兲
2,2,5-trimethyl-4-hexene-1-ol
共323–373兲
2-butoxy-3-pentanone
共333–398兲
2-butyl-1,3-dioxepane
共325–358兲
2-ethylheptanoic acid
共386 – 475兲
2-methyl-2-pentyl-1,3-dioxolane
共278 –318兲
2,2-diisopropyl-1,3-dioxolane
共278 –318兲
2-hexyl-1,3-dioxolane
共325–353兲
methyl 2,4,4-trimethylpentanoate
共278 –318兲
butyl pivalate
共274 –313兲
isobutyl isovalerate
共289– 442兲
isopentyl butyrate
共294 – 452兲
isopentyl isobutyrate
共287– 442兲
isopropyl caproate
共307–383兲
methyl octanoate 共methyl caprylate兲
共347– 470兲
共373– 419兲
共307–350兲
nonanoic acid
共381–528兲
共292–313兲
共293–303兲
共387– 483兲
propyl caproate
共315–394兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
55.2
58.9
51.1
56.3⫾0.2
共298兲
共298兲
共321兲
共298兲
55.6
52.6
56.6⫾0.6
56.4⫾0.1
56.4
52.7
共300兲
共350兲
共298兲
共298兲
共298兲
共348兲
44.7
54.9⫾0.4
49.7
55.0
53.3⫾0.1
40.2
共458兲
共298兲
共372兲
共298兲
共298兲
共298兲
A
GCC
A
61.8
共358兲
A
61.5
共338兲
A
39.8
共348兲
A
57.4
共340兲
A
63.4
共401兲
A, EB
54.0⫾0.3
共298兲
GS
49.9⫾0.3
共293兲
GS
55.0
共339兲
A
48.4⫾0.2
共298兲
GS
50.4⫾0.3
共298兲
GS
47.3
共304兲
A
47.4
共309兲
A
47.4
共302兲
A
51.6
共322兲
A
53.3
52.6⫾0.1
56.9⫾0.1
54.7⫾0.6
57.3⫾0.4
57.9⫾0.4
56.4⫾0.5
52.4
50.8
55.2
共350兲
共363兲
共298兲
共298兲
共298兲
共298兲
共298兲
共362兲
共388兲
共322兲
76.9
85.3⫾2.0
82.4⫾0.4
64.2
共396兲
共304兲
共298兲
52.8
共330兲
Method
CGC
CGC
A
A
GCC
C
C
A
GC
GCC
C
C
A, EST
MG, OM
A
ME, TE
EB
A
CAS registry number
Reference
关96/7兴关00/10兴
关95/21兴
关87/5兴
关81/18兴
关925-78-0兴
关99/27兴
关87/5兴
关79/7兴
关77/2兴
关75/8兴
关66/12兴
关502-56-7兴
关87/5兴
关79/7兴
关87/5兴关75/8兴
关75/8兴
关70/19兴
关87/5兴关37/9兴
关116-02-9兴
关87/5兴
关53965-16-5兴
关87/5兴
关22432-66-2兴
关87/5兴
关22432-66-2兴
关87/5兴
关3274-29-1兴
关87/5兴关60/22兴
关4352-95-8兴
关98/21兴关02/32兴
关4421-10-7兴
关98/21兴关02/32兴
关1708-34-5兴
关87/5兴
关64198-22-7兴
关96/11兴
关5129-37-3兴
关96/11兴
关589-59-3兴
关87/5兴关47/5兴
关106-27-4兴
关87/5兴关47/5兴
关2050-01-3兴
关87/5兴关47/5兴
关2311-46-8兴
关87/5兴
关111-11-5兴
关02/27兴
关02/27兴
关02/27兴
关87/17兴
关80/5兴
关77/7兴
关77/1兴
关87/5兴关63/16兴
关61/6兴关84/9兴
关52/13兴
关112-05-0兴
关87/5兴
关82/4兴
关68/20兴
关60/22兴
关626-77-7兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
710
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H18O2
C9 H18O2
C9 H18O2
C9 H18O3
C9 H18O3
C9 H18O3
C9 H18O3
C9 H18O3
C9 H18O3
C9 H19Br
C9 H19Cl
C9 H19F
C9 H19I
C9 H19N
C9 H19N
C9 H19N
C9 H19NO
C9 H19NO
C9 H19NO2
C9 H19NO2
C9 H19NO2
C9 H20
Compound
共Temperature range/K兲
共315–394兲
heptyl acetate
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
52.1
共330兲
1-iodononane
共391–551兲
共408 –577兲
共343– 493兲
2,2,6,6-tetramethylpiperidine
共288 –313兲
N-butylpiperidine
共275–313兲
共275–313兲
N,N-diethyl-4-pentenylamine
共338 – 430兲
1-共cyclohexylamino兲-2-propanol
共423–512兲
关61/6兴关84/9兴
关112-06-1兴
关9713兴
关80/8兴
关2050-00-2兴
关96/11兴
关15706-73-7兴
关96/11兴
GC
DTA
共298兲
GS
共298兲
GS
共363兲
A
共361兲
A
共420兲
A
共322兲
A
共337兲
A
共332兲
A
共391兲
共406兲
A, EST
51.5
55.9
53.4
共378兲
共298兲
共357兲
A, DTA
50.8⫾0.9
46.8
共298兲
共348兲
GS
A, EST
54.6
53.5
64.3
共406兲
共423兲
共358兲
A
44.5⫾0.5
共300兲
49.2⫾0.2
48.9⫾0.2
共294兲
共298兲
GS
GS
41.5
共353兲
A
56.6
共438兲
A
共361兲
A
共383兲
A
关97/21兴
关4945-48-6兴
关98/12兴
关98/12兴
关13173-21-2兴
关87/5兴
关103-00-4兴
关87/5兴关84/9兴
关59/1兴
关1120-07-6兴
关87/5兴
关35601-84-4兴
关87/5兴
共298兲
GS
关96/20兴
共298兲
GS
共299兲
共314兲
共298兲
共298兲
共337兲
共328兲
共343兲
共358兲
共298兲
C
C
C
关96/20兴
关111-84-2兴
关96/22兴
关96/22兴
关96/18兴
关94/12兴
关86/13兴
关84/8兴
关84/8兴
关84/8兴
关71/28兴
nonanamide
共353–370兲
114.8
heptylcarbamic acid, methyl ester
共368 – 408兲
109.8
propyl 2-共N,N-dimethylamino兲-2-methylpropanoate
共282–318兲
54.0⫾0.5
ethyl 2-共N,N-diethylamino兲-2-propanoate
共283–313兲
54.9⫾0.6
nonane
46.7
46.0
46.6⫾0.2
46.6
共322– 413兲
43.9
44.3
43.2
42.1
46.4
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
共298兲
共402兲
56.9
共387– 478兲
49.2
tert-amyl butyrate
共278 –308兲
50.8⫾0.6
butyl 2-methylbutanoate
共278 –313兲
50.6⫾0.5
2-butoxypropionic acid, ethyl ester
共348 – 438兲
80.3
3-ethoxypropionic acid, butyl ester
共346 – 479兲
51.8
3-hydroxypropionic acid, hexyl ester
共408 – 432兲
69.6
lactic acid, hexyl ester
共307– 494兲
67.4
3-methoxypropionic acid, pentyl ester
共322– 485兲
53.3
3-propoxypropionic acid, propyl ester
共317– 484兲
50.9
1-bromononane
共376 –525兲
53.1
共391–549兲
52.2
1-chlorononane
共363–509兲
共340– 480兲
共342– 478兲
1-fluorononane
共278 –313兲
共333– 473兲
Method
C
C
C
关87/5兴
关14144-35-5兴
关87/5兴
关87/5兴
关20279-51-0兴
关87/5兴
关10500-16-0兴
关87/5兴
关14144-41-3兴
关87/5兴
关693-58-3兴
关99/16兴
关87/5兴关61/13兴
关70/14兴
关2473-01-0兴
关99/16兴
关84/9兴关91/2兴
关87/5兴关69/5兴
关463-18-3兴
关94/17兴
关87/5兴关61/13兴
关70/14兴关99/16兴
关4282-42-2兴
关99/16兴
关87/5兴关70/14兴
关47/5兴
ENTHALPIES OF VAPORIZATION
711
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共219–308兲
共344 – 426兲
C9 H20
2-methyloctane
共305– 417兲
C9 H20
3-methyloctane
C9 H20
4-methyloctane
C9 H20
3-ethylheptane
C9 H20
4-ethylheptane
C9 H20
2,2-dimethylheptane
C9 H20
2,3-dimethylheptane
C9 H20
2,4-dimethylheptane
C9 H20
2,5-dimethylheptane
C9 H20
2,6-dimethylheptane
C9 H20
3,3-dimethylheptane
C9 H20
3,4-dimethylheptane
C9 H20
3,5-dimethylheptane
C9 H20
4,4-dimethylheptane
C9 H20
3,3-diethylpentane
C9 H20
共335– 426兲
2-methyl-3-ethylhexane
C9 H20
2-methyl-4-ethylhexane
C9 H20
3-methyl-3-ethylhexane
C9 H20
3-methyl-4-ethylhexane
C9 H20
2,2,3-trimethylhexane
共238 –303兲
C9 H20
C9 H20
2,2,4-trimethylhexane
共288 – 410兲
共238 –393兲
共238 –303兲
2,2,5-trimethylhexane
共288 –399兲
共238 –303兲
共319–398兲
C9 H20
C9 H20
2,3,3-trimethylhexane
共238 –303兲
共288 – 422兲
2,3,4-trimethylhexane
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
48.3
46.4
42.7
共234兲
共298兲
共359兲
A
C
A, MM
43.2
44.9
共320兲
共298兲
A
44.9
共298兲
44.5
共298兲
44.5
共298兲
44.1
共298兲
42.3
共298兲
43.6
共298兲
42.9
共298兲
43.3
共298兲
43.3
共298兲
42.6
共298兲
43.6
共298兲
43.3
共298兲
42.2
共298兲
42.6⫾0.3
43.6
39.8
共298兲
共298兲
共350兲
43.2
共298兲
42.9
共298兲
42.9
共298兲
43.6
共298兲
42.2
41.7
共288兲
共298兲
IPM
39.5
41.0
40.5
40.7
共303兲
共278兲
共288兲
共298兲
A
A
IPM
40.1
41.1
40.2
38.5
40.2
共303兲
共288兲
共298兲
共334兲
共298兲
A
A, IPM
44.2
39.4
42.1
共253兲
共303兲
共298兲
A
A
GCC
A
C
CAS registry number
Reference
关87/5兴关73/11兴
关47/7兴
关87/5兴关45/2兴
关49/6兴
关3221-61-2兴
关87/5兴
关71/28兴关61/30兴
关2216-33-3兴
关71/28兴关61/30兴
关2216-34-4兴
关71/28兴关61/30兴
关15869-80-4兴
关71/28兴关61/30兴
关2216-32-2兴
关61/30兴
关1071-26-7兴
关71/28兴关61/30兴
关3074-71-3兴
关71/28兴关61/30兴
关2213-23-2兴
关71/28兴关61/30兴
关2216-30-0兴
关71/28兴关61/30兴
关1072-05-5兴
关71/28兴关61/30兴
关4032-86-4兴
关71/28兴关61/30兴
关922-28-1兴
关71/28兴关61/30兴
关926-82-9兴
关71/28兴
关1068-19-5兴
关71/28兴关61/30兴
关1067-20-5兴
关79/17兴
关71/28兴关61/30兴
关87/5兴关49/6兴
关16789-46-1兴
关61/30兴
关3074-75-7兴
关61/30兴
关3074-76-8兴
关61/30兴
关61/30兴
关16747-25-4兴
关74/11兴
关71/28兴关61/30兴
关16747-26-5兴
关87/5兴
关87/5兴
关74/11兴
关71/28兴
关3522-94-9兴
关87/5兴
关87/5兴关74/11兴
关71/28兴
关49/6兴
关47/7兴
关16747-28-7兴
关87/5兴
关87/5兴
关71/28兴关61/30兴
关921-47-1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
712
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H20
Compound
共Temperature range/K兲
2,4,4-trimethylhexane
C9 H20
共323– 406兲
3,3,4-trimethylhexane
C9 H20
2,2-dimethyl-3-ethylpentane
C9 H20
2,3-dimethyl-3-ethylpentane
C9 H20
2,4-dimethyl-3-ethylpentane
C9 H20
2,2,3,3-tetramethylpentane
C9 H20
共328 – 415兲
2,2,3,4-tetramethylpentane
C9 H20
共325– 413兲
2,2,4,4-tetramethylpentane
C9 H20ClF3 N2 S
C9 H20ClF3 N2 OS
C9 H20N2 S
C9 H20O
C9 H20O
C9 H20O
C9 H20O
C9 H20O
C9 H20O
C9 H20O
C9 H20O
Mean temperature
(T m /K)
42.7
共298兲
41.4
41.4
共298兲
共298兲
C
41.1
38.5
共298兲
共338兲
A
42.2
共298兲
41.7
共298兲
42.7
共298兲
42.3
共298兲
41.2
39.2
共298兲
共343兲
A
40.8
38.4
共298兲
共340兲
A
38.5⫾0.1
38.5⫾0.3
38.2
37.2
36.5
34.8
共298兲
共298兲
共298兲
共328兲
共346兲
共390兲
Method
2,3,5-trimethylhexane
C9 H20
C9 H20
⌬ vapH m
共kJ mol⫺1兲
共313–397兲
共331–375兲
共375– 422兲
2,3,3,4-tetramethylpentane
41.8
共331– 416兲
39.3
chlorobis共N-ethylethanaminato兲共trifluoromethyl兲 sulfur
39.8
chlorobis共N-ethylethanaminato兲oxo共trifluoromethyl兲 sulfur
44.4
1,3-dibutylthiourea
共368 – 403兲
105⫾2.0
1-nonanol
72.2
共373– 423兲
76.7
共273–323兲
77.4
共368 –500兲
65.0
共381– 495兲
62.9
76.9⫾0.8
共425– 494兲
59.7
共368 – 487兲
64.5
共365– 487兲
65.5
2-nonanol
共253–353兲
79.6
共364 – 471兲
55.5
3-nonanol
共263–363兲
75.5
共366 – 468兲
57.1
2-methyl-2-octanol
共338 – 451兲
64.6
2-methyl-3-octanol
共388 – 453兲
49.5
3-methyl-3-octanol
共353–388兲
53.2
2,2-dimethyl-4-heptanol
共320– 445兲
50.2
2,6-dimethyl-4-heptanol
共363– 453兲
54.5
共374 – 452兲
52.8
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
GCC
A
EB
共298兲
共346兲
A
共479兲
I
共486兲
I
共386兲
ME, TE
共298兲
共298兲
共298兲
共383兲
共396兲
共298兲
共440兲
共383兲
共380兲
CGC
CGC
A
A
C
EB
DTA
共268兲
共379兲
共278兲
共381兲
共353兲
共403兲
共368兲
共335兲
共378兲
共389兲
A, MM
CAS registry number
Reference
关71/28兴关61/30兴
关1069-53-0兴
关71/28兴
关47/7兴
关16747-30-0兴
关71/28兴关61/30兴
关87/5兴关49/6兴
关16747-31-2兴
关71/28兴关61/30兴
关16747-32-3兴
关71/28兴关61/30兴
关16747-33-4兴
关71/28兴关61/30兴
关1068-87-7兴
关71/28兴关61/30兴
关7154-79-2兴
关71/28兴关61/30兴
关87/5兴关49/6兴
关1186-53-4兴
关71/28兴关61/30兴
关87/5兴关49/6兴
关1070-87-7兴
关82/6兴
关79/17兴
关71/28兴关61/30兴
关87/5兴关49/6兴
关41/9兴关84/9兴
关41/9兴
关16747-38-9兴
关71/28兴关61/30兴
关87/5兴关49/6兴
关63265-72-5兴
关77/15兴
关63265-74-7兴
关77/15兴
关109-46-6兴
关94/21兴
关143-08-8兴
关00/10兴
关95/21兴
关92/14兴
关87/5兴
关87/5兴
关77/1兴
关76/13兴
关73/26兴
关69/5兴
关628-99-9兴
关99/11兴
关73/26兴
关624-51-1兴
关99/11兴
关73/26兴
关628-44-4兴
关73/26兴
关26533-34-6兴
关73/26兴
关5340-36-3兴
关73/26兴
关73/26兴
关108-82-7兴
关73/26兴
关87/5兴关47/8兴
ENTHALPIES OF VAPORIZATION
713
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C9 H20O
Compound
共Temperature range/K兲
C9 H20O
2,2,3-trimethyl-3-hexanol
共343– 441兲
2,4-dimethyl-3-ethyl-3-pentanol
共369– 451兲
2,2,3,4-tetramethyl-3-pentanol
共329– 448兲
butyl 1,1-dimethylpropyl ether
共278 –308兲
2-methoxy-2,4,4-trimethylpentane
共381– 418兲
methyl tert-octyl ether
C9 H20O
pentyl tert-butyl ether
C9 H20O
共319–365兲
共319–365兲
isobutyl tert-amyl ether
C9 H20O
sec-butyl tert-amyl ether
C9 H20O
butyl tert-amyl ether
C9 H20O2
2,6,6-trimethyl-5-oxa-2-heptanol
共329– 454兲
dibutoxymethane
共366 – 452兲
1-butoxy-2-propoxyethane
C9 H20O
C9 H20O
C9 H20O
C9 H20O
C9 H20O2
C9 H20O2
C9 H20O2
C9 H20O2
C9 H20O2
C9 H20O3
C9 H20O4
C9 H20S
C9 H20S
C9 H20S2
C9 H21N
C9 H21N
C9 H21N
C9 H21NO3
C9 H21O4 P
C9 H21P
C9 H22ClN2 PS
C10Cl8
2-butyl-2-ethyl-1,3-propanediol
共424 –523兲
共424 –523兲
共424 –523兲
4-tert-butoxy-2-methyl-2-butanol
共367– 483兲
2,2,4-trimethyl-1,6-hexanediol
共419–541兲
dipropylene glycol isopropyl ether
共319– 479兲
tripropylene glycol
共369–541兲
1-nonanethiol
共390– 494兲
2-nonanethiol
共379– 482兲
1,9-nonanedithiol
共418 –557兲
N-methyl octylamine
共365–508兲
nonylamine
共377– 478兲
tripropylamine
共341– 475兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
55.1
共358兲
50.0
共384兲
60.8
共344兲
46.1⫾0.3
共298兲
38.5
共396兲
关01/14兴
45.3
共298兲
48.3
43.7
46.9⫾1.0
共298兲
共334兲
共298兲
关U/2兴关02/32兴
关10100-95-5兴
关U/2兴关02/32兴
关90/15兴
关90/15兴
46.3
共298兲
关U/2兴关02/32兴
46.8
共298兲
关U/2兴关02/32兴
48.3
共298兲
关U/2兴关02/32兴
53.3
共344兲
关68/16兴关84/9兴
47.9
共381兲
EB
54.7⫾0.1
共298兲
C
74.3⫾0.3
67.2⫾0.3
61.4⫾0.6
共420兲
共460兲
共500兲
EB
EB
EB
61.5
共382兲
A
68.0
共434兲
A
关00/17兴
关18854-58-5兴
关70/17兴
关115-84-4兴
关02/14兴
关02/14兴
关02/14兴
关22419-28-9兴
关87/5兴
关3089-24-5兴
关87/5兴
55.0
共334兲
A
关87/5兴关47/5兴
63.3
共384兲
A
52.6
共405兲
A
50.3
共394兲
63.6
共433兲
A
49.2
共380兲
A
50.7
共392兲
A
45.6
46.2⫾0.1
共356兲
共298兲
A
C
关87/5兴
关1455-21-6兴
关87/5兴关99/16兴
关32/2兴
关13281-11-3兴
关99/16兴关32/2兴
关3489-28-9兴
关87/5兴关99/16兴
关43/6兴
关2439-54-5兴
关87/5兴
关112-20-9兴
关87/5兴
关102-69-2兴
关87/5兴
关69/2兴
关122-20-3兴
关87/5兴
关513-08-6兴
关87/5兴
关2234-97-1兴
关01/9兴
关58023-20-4兴
关87/5兴关99/16兴
关2234-13-1兴
triisopropanolamine
共428 –573兲
73.7
共443兲
tripropylphosphate
共394 –525兲
56.7
共409兲
tripropylphosphine
共324 –368兲
39.4⫾0.2
共346兲
P-共chloromethyl兲-N,N⬘-bis共1-methylpropyl兲phosphorothioic diamide
共333–368兲
66.8
共348兲
octachloronaphthalene
Method
CAS registry number
Reference
GS
关5340-41-0兴
关73/26兴
关3970-59-0兴
关73/26兴
关29772-39-2兴
关73/26兴
关3249-47-6兴
关96/11兴
EB
EB
A
A
A
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
714
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10Cl12
C10F16
C10F18
C10F18
C10F20
C10F20
C10F20
C10F20N2 S
C10F22
C10F22O
C10HCl5 F14O2
C10HCl7
C10H2 Cl6
C10H2 Cl6
C10H2 Cl6
C10H2 Cl6
C10H2 O6
C10H3 Cl5
C10H3 Cl5
C10H3 Cl5
C10H4 Cl4
C10H4 Cl4
C10H4 Cl4
C10H5 Cl3
Compound
共Temperature range/K兲
共323– 423兲
Mirex
共343– 453兲
perfluorobicyclo关4.4.0兴dec-1,6-diene
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
96.1
共373兲
GC
90.3
共398兲
GC
45.3⫾0.1
共298兲
C
perfluoro共cis-decahydronaphthalene兲
共313– 415兲
43.9
共328兲
46.2⫾0.1
共298兲
46.7⫾0.6
共298兲
46.2⫾0.1
共298兲
perfluoro共trans-decahydronaphthalene兲
共315– 417兲
43.3
共330兲
45.4⫾0.1
共298兲
45.9⫾0.6
共298兲
45.4⫾0.1
共298兲
perfluoro-1-decene
共315–399兲
42.3
共330兲
45.2⫾0.6
共298兲
perfluoro共1-methyl-4-isopropyl兲cyclohexane
共339– 418兲
42.7
共354兲
46.7⫾0.5
共298兲
perfluoro共isobutylcyclohexane兲
共327– 415兲
43.4
共342兲
46.3⫾0.6
共298兲
46.7⫾0.1
共298兲
2,2,3,3,4,4,5,5-octafluoro-1,1,2,3,4,5-hexahydro-1-关关2,2,2-trifluoro-1-共trifluoromethyl兲-1关关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-amino兴ethyl兴imino兴thiophene
29.3
共389兲
perfluorodecane
共404 –543兲
34.0
共420兲
bis共undecafluoropentyl兲ether
共337– 411兲
49.9⫾1.5
共298兲
49.5⫾0.1
共298兲
共288 –313兲
51.5
共300兲
47.3⫾0.8
共298兲
2,2,3,4,4,5,6,6,7,8,8,9,10,10-tetradecafluoro-3,5,7,9,10-penta-chlorodecanoic acid
共373–578兲
80.6
共388兲
1,2,3,4,5,6,7-heptachloronaphthalene
共323– 423兲
1,2,4,5,6,8-hexachloronaphthalene
共323– 423兲
1,2,3,5,7,8-hexachloronaphthalene
共323– 423兲
1,2,3,5,6,7-hexachloronaphthalene
共323– 423兲
1,2,3,4,6,7-hexachloronaphthalene
共323– 423兲
pyromellitic acid dianhydride
共641– 665兲
1,2,3,5,8-pentachloronaphthalene
共323– 423兲
1,2,3,5,7-pentachloronaphthalene
共323– 423兲
1,2,3,4,6-pentachloronaphthalene
共323– 423兲
1,2,4,7-tetrachloronaphthalene
共323– 423兲
1,2,3,5-tetrachloronaphthalene
共323– 423兲
1,2,3,4-tetrachloronaphthalene
共323– 423兲
1,2,3-trichloronaphthalene
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
EB
C
C
EB
C
EB
EB
EB
C
A
EB
C
A
EB
A
90.6
共373兲
GC
85.3
共373兲
GC
85.0
共373兲
GC
84.5
共373兲
GC
84.5
共373兲
GC
79.6
共576兲
A
80.5
共373兲
GC
78.2
共373兲
GC
78.9
共373兲
GC
72.1
共373兲
GC
73.4
共373兲
GC
73.2
共373兲
GC
CAS registry number
Reference
关99/9兴
关2385-85-5兴
关90/2兴
关96/26兴
关60433-11-6兴
关99/16兴
关96/26兴
关81/23兴
关81/23兴
关60433-12-7兴
关99/16兴
关96/26兴
关81/23兴
关81/23兴
关35328-43-9兴
关99/16兴
关81/23兴
关116667-53-9兴
关99/16兴
关81/23兴
关132868-02-1兴
关99/16兴
关81/23兴
关81/23兴
关77984-27-1兴
关81/15兴
关307-45-9兴
关87/5兴关67/18兴
关99/16兴
关464-36-8兴
关89/13兴
关89/13兴
关87/5兴关99/16兴
关76/7兴
关335-74-0兴
关87/5兴关57/17兴
关99/16兴
关58863-14-2兴
关99/9兴
关90948-28-0兴
关99/9兴
关103426-94-4兴
关99/9兴
关103426-97-7兴
关99/9兴
关103426-96-6兴
关99/9兴
关89-32-7兴
关87/5兴
关150224-24-1兴
关99/9兴
关53555-65-0兴
关99/9兴
关67922-26-3兴
关99/9兴
关67922-21-8兴
关99/9兴
关53555-63-8兴
关99/9兴
关20020-02-4兴
关99/9兴
关50402-52-3兴
ENTHALPIES OF VAPORIZATION
715
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H5 Cl7
C10H5 Cl9
C10H5 Cl9
C10H6 Cl2
C10H6 Cl2
C10H6 Cl8
C10H6 Cl8
C10H6 N2 O4
C10H6 N2 O4
C10H7 Br
C10H7 Br
C10H7 Cl
C10H7 Cl
C10H7 Cl7
C10H7 F5 O2
C10H7 F5 O2
C10H7 I
C10H7 NO2
C10H8
C10H8
Compound
共Temperature range/K兲
共323– 423兲
Heptachlor
共343– 453兲
cis Nonachlor
共343– 453兲
trans Nonachlor
共343– 453兲
1,2-dichloronaphthalene
共323– 423兲
1,4-dichloronaphthalene
共323– 423兲
cis Chlordane
共323– 409兲
共343– 453兲
trans Chlordane
共373– 409兲
共343– 453兲
1,5-dinitronaphthalene
共506 – 642兲
1,8-dinitronaphthalene
共553–715兲
1-bromonaphthalene
共357–555兲
共295–359兲
共469–559兲
2-bromonaphthalene
共330–378兲
共322–359兲
1-chloronaphthalene
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
68.0
共373兲
GC
76.5
共398兲
GC
83.8
共398兲
GC
85.5
共398兲
GC
60.7
共373兲
GC
58.7
共373兲
GC
83.0
82.0
共338兲
共398兲
GC
81.7
80.7
共388兲
共398兲
GC
74.7
共521兲
A
78.5
共568兲
A
58.5
56⫾6
45.8
共372兲
共329兲
共484兲
ME
A, EB
42.5
40.4
共354兲
共340兲
ME, TE
共298兲
共373兲
共368兲
共415兲
GS
GC
A
A
共417兲
共373兲
GC
64.0⫾0.3
共323– 423兲
58.6
共353–553兲
59.6
共400– 435兲
57.8
2-chloronaphthalene
共400– 435兲
57.9
共323– 423兲
58.5
1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro-4,7-methanoindan
共333–353兲
83.8
pentafluoropropionic acid, 3-tolyl ester
共371– 446兲
48.3
pentafluoropropionic acid, 4-tolyl ester
共371– 448兲
48.3
1-iodonaphthalene
共321– 428兲
1-nitronaphthalene
共332–580兲
azulene
共369–515兲
共442–534兲
共373– 423兲
naphthalene
共323– 473兲
共460– 647兲
共403– 453兲
共513– 613兲
共343兲
共386兲
A, EB
共386兲
A, EB
78.9
共336兲
66.4
共347兲
A
52.8
53.0
51.2
55.5
共298兲
共384兲
共457兲
共373兲
CGC
A
EB
56.1
53.4
45.4
56.6
48.7⫾0.3
46.4
44.0
41.5
44.4
共398兲
共298兲
共475兲
共298兲
共400兲
共440兲
共480兲
共520兲
共528兲
GC
CGC
DSC
CGC
EB
EB
EB
EB
CAS registry number
Reference
关99/9兴
关76-44-8兴
关90/2兴
关5103-73-1兴
关90/2兴
关39765-80-5兴
关90/2兴
关2050-69-3兴
关99/9兴
关1825-31-6兴
关99/9兴
关5103-71-9兴
关99/16兴
关90/2兴
关5103-74-2兴
关99/16兴
关90/2兴
关605-71-0兴
关87/5兴
关602-38-0兴
关87/5兴
关90-11-9兴
关87/5兴
关80/7兴
关87/5兴关76/13兴
关99/16兴
关580-13-2兴
关99/16兴
关81/22兴
关90-13-1兴
关01/1兴
关99/9兴
关87/5兴关47/5兴
关87/5兴
关91-58-7兴
关99/16兴
关99/9兴
关2589-15-3兴
关99/16兴
关24277-51-0兴
关87/5兴关69/13兴
关99/16兴
关24271-52-1兴
关87/5兴关69/13兴
关99/16兴
关90-14-2兴
关99/16兴
关86-57-7兴
关87/5兴
关275-51-4兴
关98/11兴
关87/5兴
关77/10兴
关62/25兴
关91-20-3兴
关02/18兴
关98/11兴
关96/10兴
关95/21兴
关93/11兴
关93/11兴
关93/11兴
关93/11兴
关93/3兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
716
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共418 – 613兲
共352–500兲
共491–565兲
共563– 663兲
共661–750兲
共441–727兲
共353–388兲
共354 – 453兲
共399– 491兲
C10H8 N2 O2
C10H8 N2 O2
C10H8 N2 O2
C10H8 O
C10H8 O
C10H9 Cl3 O3
C10H9 N
C10H9 N
C10H9 N
3-methylquinoline
共443–528兲
4-methylquinoline 共lepidine兲
C10H9 N
6-methylquinoline
C10H9 N
共453–540兲
7-methylquinoline
共493–532兲
8-methylquinoline
C10H9 N
C10H9 N
C10H9 NO
C10H10
C10H10
C10H10
C10H10
Mean temperature
(T m /K)
47.9
50.6
44.8
43.2
43.3
44.7
50.3⫾0.2
50.7
49.0
46.4
48.3
47.2
47.7
共423兲
共367兲
共506兲
共578兲
共676兲
共466兲
共370兲
共369兲
共414兲
共441兲
共379兲
共423兲
共427兲
EB
A
A
A
A
共418兲
A
共418兲
A
共378兲
A
共414兲
共473兲
A
共298兲
共416兲
共432兲
共473兲
CGC
A
共459兲
A
共298兲
共297兲
共548兲
C
GS
A, EB
55.8
共458兲
A
67.6⫾1.8
58.2
共298兲
共478兲
C
A, EB
67.7⫾1.8
56.1
共298兲
共468兲
C
A
56.7
共508兲
A, EB
65.7⫾1.9
52.2
共298兲
共508兲
C
A, EB
63.6
共392兲
A
63.5
共403兲
A
78.1⫾2.3
共298兲
C
48.3
共320兲
A
42.4
共322兲
51.9⫾0.4
51.9⫾0.4
共296兲
共298兲
GS
53.2⫾0.4
54.2⫾0.4
共296兲
共298兲
GS
共373– 473兲
共360– 494兲
1,3-bis共isocyanatomethyl兲benzene
共403– 473兲
46.7
1,4-bis共isocyanatomethyl兲benzene
共403– 473兲
56.9
benzene, ethyldiisocyanato 共mixed isomers兲
共363– 473兲
60.7
1-naphthol
共399–556兲
58.5
共423–563兲
60.8
2-naphthol
共393– 433兲
76.2
共401–561兲
59.7
共417–561兲
59.7
共423–563兲
61.8
共2,4,5-trichlorophenoxy兲acetic acid, ethyl ester
共444 –573兲
76.4
2-methylquinoline 共quinaldine兲
66.1⫾1.9
共281–313兲
61.2
共443–521兲
54.7
共463–539兲
C10H9 N
⌬ vapH m
共kJ mol⫺1兲
共493–523兲
1-naphthylamine
共377–574兲
2-naphthylamine
共388 –579兲
6-methoxyquinoline
1,3-divinylbenzene
共305– 453兲
dicyclopentadiene
共307– 440兲
1,2-dihydronaphthalene
共274 –319兲
1,4-dihydronaphthalene
共300–333兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
C
I
I
I
CAS registry number
Reference
关90/7兴
关87/5兴
关87/5兴
关87/5兴
关87/5兴
关81/21兴关86/15兴
关81/6兴
关68/11兴
关55/7兴
关51/7兴
关43/7兴
关23/1兴
关22/1兴
关3634-83-1兴
关87/5兴
关1014-98-8兴
关87/5兴
关64711-83-7兴
关87/5兴关77/22兴
关90-15-3兴
关87/5兴
关27/4兴
关135-19-3兴
关95/21兴
关87/5兴
关55/9兴
关27/4兴
关1928-39-8兴
关87/5兴关99/16兴
关91-63-4兴
关95/1兴
关80/6兴
关87/5兴关61/11兴
关61/10兴
关612-58-8兴
关87/5兴关61/11兴
关491-35-0兴
关95/1兴
关87/5兴关61/11兴
关61/10兴
关91-62-3兴
关95/1兴
关87/5兴
关612-60-2兴
关87/5兴关61/10兴
关611-32-5兴
关95/1兴
关87/5兴关61/10兴
关134-32-7兴
关87/5兴关47/5兴
关91-59-8兴
关87/5兴关47/5兴
关5263-87-6兴
关02/35兴
关108-57-6兴
关87/5兴关47/5兴
关47/5兴
关447-53-0兴
关99/21兴
关99/21兴
关612-17-9兴
关99/21兴
关99/21兴
ENTHALPIES OF VAPORIZATION
717
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H10
C10H10Cl2 O3
C10H10N2
C10H10O
C10H10O
C10H10O
C10H10O2
C10H10O2
C10H10O2
C10H10O2
C10H10O2
C10H10O2
C10H10O2
C10H10O4
C10H10O4
C10H10O4
C10H10O4
C10H11N
C10H11N
C10H13NO2
C10H12
C10H12
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
diisopropenyldiacetylene
50.2
共2,4-dichlorophenoxy兲acetic acid, ethyl ester
共444 –573兲
72.6
1-benzylpyrazole
73.8⫾2.0
2-methyl-3-phenyl-2-propenal
共401–556兲
59.3⫾0.2
共401–556兲
56.3⫾0.2
共401–556兲
53.4⫾0.2
共401–556兲
50.5⫾0.4
共401–556兲
47.7⫾0.6
共343–393兲
71.5
4-phenyl-3-buten-2-one
共354 –534兲
58.5
1-tetralone
共284 –324兲
65.0⫾0.3
共388 –535兲
61.5
cinnamic acid, methyl ester
共409–557兲
59.9⫾0.2
共409–557兲
56.9⫾0.2
共409–557兲
53.8⫾0.3
共409–557兲
50.5⫾0.5
共288 –333兲
62.4
共350–536兲
58.3
1,3-diacetylbenzene
共323– 418兲
43.2
1,4-diacetylbenzene
共388 – 431兲
82.2
isosafrole
共393–531兲
59.4
␣-methylcinnamic acid
共398 –561兲
78.5
safrole
共336 –506兲
54.6
4-carboxypentacyclo关 4.3.0.0.2,50 4,7兴 nonane
82.0
1,2-diacetoxybenzene
共371–551兲
62.9
dimethyl isophthalate
共350– 607兲
77.2⫾0.8
共393–550兲
60.5
dimethyl phthalate
共466 –518兲
61.5
69.4⫾0.1
72.5⫾0.6
74.5⫾0.3
共304 –371兲
78.7
共371–547兲
63.7
共377– 440兲
68.6
dimethyl terephthalate
共413–523兲
62.0
␣,␣-dimethylbenzylcyanide
共284 –323兲
60.3⫾0.6
共284 –323兲
60.6⫾0.6
␣-ethylbenzylcyanide
共283–313兲
64.3⫾0.6
2-nitro-1-tert-butylbenzene
共278 –323兲
64.8⫾0.6
65.0⫾0.6
endo dicyclopentadiene
共350– 446兲
43.6
2,4-dimethylstyrene
共307– 453兲
50.0
共459兲
A
共298兲
C
共400兲
共440兲
共480兲
共520兲
共560兲
共358兲
EB
EB
EB
EB
EB
A
共369兲
A
共298兲
共403兲
GS
A
共420兲
共460兲
共500兲
共540兲
共303兲
共365兲
EB
EB
EB
EB
A
A
共338兲
A
共403兲
A
共408兲
A
共413兲
A
共351兲
A
CAS registry number
Reference
关5187-81-5兴
关77/25兴
关533-23-3兴
关87/5兴关99/16兴
关10199-67-4兴
关99/5兴
关101-39-3兴
关02/16兴
关02/16兴
关02/16兴
关02/16兴
关02/16兴
关87/5兴
关122-57-6兴
关87/5兴关47/5兴
关529-34-0兴
关98/4兴
关87/5兴
关103-26-4兴
关02/16兴
关02/16兴
关02/16兴
关02/16兴
关87/5兴
关87/5兴关47/5兴
关6781-42-6兴
关87/5兴
关1009-61-6兴
关87/5兴
关120-58-1兴
关87/5兴
关1199-77-5兴
关87/5兴关47/5兴
关94-59-7兴
关87/5兴关47/5兴
共386兲
A
共298兲
共408兲
EB, IPM
A, GS
共481兲
共365兲
共344兲
共326兲
共319兲
共386兲
共409兲
EB
C
C
C
A
A
共428兲
A
关84/12兴
关635-67-6兴
关87/5兴
关1459-93-4兴
关96/7兴
关87/5兴关63/13兴
关131-11-3兴
关99/25兴
关98/6兴
关98/6兴
关98/6兴
关87/5兴
关87/5兴
关69/1兴
关120-61-6兴
关87/5兴
共303兲
共298兲
GS
GS
关00/2兴
关00/2兴
共298兲
GS
关00/2兴
共301兲
共298兲
GS
共365兲
A
共322兲
A
关00/15兴
关00/15兴
关77-73-6兴
关87/5兴
关2234-20-0兴
关87/5兴关47/5兴
C
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
718
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H12
C10H12
C10H12
C10H12
C10H12
C10H12Cl4 NOPS
C10H12N2
C10H12O
C10H12O
C10H12O
C10H12O
C10H12O
C10H12O
C10H12O
C10H12O
C10H12O
C10H12O
C10H12O
C10H12O2
C10H12O2
C10H12O2
C10H12O2
C10H12O2
C10H12O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
2,5-dimethylstyrene
共302– 453兲
48.1
共317兲
A
1-ethyl-2-vinylbenzene
共363– 413兲
46.3
共378兲
A
1-ethyl-3-vinylbenzene
共343– 453兲
49.6
共358兲
A
1-ethyl-4-vinylbenzene
共341– 448兲
48.4
共356兲
A
1,2,3,4-tetrahydronaphthalene 共tetralin兲
共465–580兲
44.1
共480兲
共311– 481兲
51.1
共326兲
A
41.3⫾0.1
共498兲
C
37.6⫾0.1
共552兲
C
35.7⫾0.1
共567兲
C
33.9⫾0.1
共585兲
C
32.0⫾0.1
共604兲
C
共331– 437兲
52.1
共346兲
共367– 479兲
48.6
共382兲
P-chloromethyl-N-共1-methylethyl兲amidothiophosphonic acid, O-共2,4,6-trichlorophenyl兲 ester
共323–363兲
78.3
共338兲
2-diethylamino-2-piperidinoacetonitrile
共298 –338兲
62.8⫾0.4
GS
anethole
61.9
共298兲
GC
cis anethole
共333–363兲
68.7
共348兲
A
trans anethole
共333–363兲
78.3
共348兲
A
estragole
共325– 488兲
56.3
共340兲
A
2⬘-ethylacetophenone
共363–397兲
52.8
共378兲
A
共293– 423兲
U23.7
共368兲
4⬘-ethylacetophenone
共294 –368兲
42.2
共309兲
A
共293– 423兲
39.8
共368兲
4-isopropylbenzaldehyde 共cuminal兲
共331–505兲
55.3
共346兲
A
2-methyl-3-phenylpropanal
共333–373兲
59.1
共348兲
A
4⬘-methypropiophenone
共332–512兲
52.6
共347兲
A
4-vinylphenetole
共337– 498兲
59.2
共352兲
A
4-methoxy-␣-methylstyrene
共308 –343兲
60.6⫾0.3
共326兲
GS
62.1⫾0.3
共298兲
acetic acid, phenethyl ester
共283–318兲
67.4
共298兲
A
共422–506兲
52.2
共437兲
A
methyl 2-phenylpropionate
共284 –318兲
61.8⫾0.7
共301兲
GS
共284 –318兲
62.0⫾0.7
共298兲
GS
4-allyl-2-methoxyphenol 共eugenol兲
66.3
共298兲
GC
共395–527兲
57.7
共410兲
A
共285–333兲
66.1
共300兲
ME
共351–526兲
60.3
共366兲
benzyl propionate
共298 –378兲
59.0
共313兲
A
5-allyl-2-methoxyphenol
共345–527兲
61.4
共371兲
A
2-methoxy-4-共1-propenyl兲phenol 共isoeugenol兲
共359–540兲
60.7
共374兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关2039-89-6兴
关87/5兴关47/5兴
关7564-63-8兴
关87/5兴
关7525-62-4兴
关87/5兴
关3454-07-7兴
关87/5兴
关119-64-2兴
关92/2兴
关87/5兴
关85/10兴
关85/10兴
关85/10兴
关85/10兴
关85/10兴
关84/24兴
关47/5兴
关21844-03-1兴
关87/5兴
关97/10兴
关104-46-1兴
关02/37兴
关25679-28-1兴
关87/5兴
关4180-23-8兴
关87/5兴
关140-67-0兴
关87/5兴
关2142-64-5兴
关87/5兴
关68/31兴
关937-30-4兴
关87/5兴
关68/31兴
关122-03-2兴
关87/5兴关47/5兴
关5445-77-2兴
关87/5兴
关5337-93-9兴
关87/5兴关47/5兴
关5459-40-5兴
关87/5兴关47/5兴
关99/21兴
关99/21兴
关103-45-7兴
关87/5兴
关87/5兴
关99/2兴
关99/2兴
关97-53-0兴
关02/37兴
关87/5兴
关87/5兴关59/7兴
关47/5兴
关122-63-4兴
关87/5兴
关501-19-9兴
关87/5兴
关57/6兴
ENTHALPIES OF VAPORIZATION
719
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H12O2
C10H12O2
C10H12O2
C10H12O2
C10H12O2
Compound
共Temperature range/K兲
cis isoeugenol
共373– 403兲
trans isoeugenol
共363– 420兲
phenylacetic acid, ethyl ester
共288 –328兲
共288 –328兲
共393–500兲
propylbenzoate
共359– 458兲
共359– 458兲
共327–504兲
关共phenylmethoxy兲methyl兴oxirane
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
69.7
共388兲
A
69.1
共378兲
A
63.9⫾0.4
64.5⫾0.4
54.0
共308兲
共298兲
共408兲
GS
GS
A
60.2
52.7
53.8
共379兲
共440兲
共342兲
BG
BG
A
共370兲
A
71.0⫾0.4
C10H12O3
C10H12O3
acetic acid, 共2-phenoxyethyl兲 ester
共355–533兲
propyl 4-hydroxybenzoate
56.8
76.5
C10H12O4
C10H13Br
C10H13Br
C10H13Cl
C10H13Cl
C10H13ClO
C10H13ClO3
C10H13Cl3 O2 P
C10H13Cl3 NOPS
C10H13NO
C10H13NO2
C10H13NO2
C10H13NO2
C10H14
C10H14
TGA
maleic acid, diallyl ester
共392– 426兲
2-bromo-4-isopropyltoluene
共400–510兲
77.7
共407兲
A
50.2
共415兲
A
3-bromo-4-isopropyltoluene
共400–510兲
48.3
共415兲
A
2-chloro-4-isopropyltoluene
共400– 490兲
49.3
共415兲
A
47.1
共415兲
A
54.8
共350兲
A
3-chloro-4-isopropyltoluene
共400– 490兲
2-chloroethyl ␣-methylbenzyl ether
共335–508兲
diethylene glycol 4-chlorophenyl ether
共450–523兲
75.9
共465兲
A
4-tert-butyl phenyl dichlorophosphate
共369–572兲
59.6
共384兲
P-chloromethyl-N-共1-methylethyl兲amidothiophosphonic acid, O-共2,4-dichlorophenyl兲 ester
共323–368兲
93.1
共345兲
A
N,N-dimethyl-m-toluamide
共374 – 405兲
29.9
共390兲
4⬘-ethoxyacetanilide
共463–533兲
82.6
共478兲
A
2-nitro-4-isopropyltoluene
共370– 415兲
67.7
共385兲
A
3-nitro-4-isopropyltoluene
共330– 430兲
54.0
共345兲
A
butylbenzene
共343–501兲
47.4⫾0.2
共350兲
EB
共343–501兲
43.5⫾0.2
共410兲
EB
共343–501兲
40.6⫾0.4
共450兲
EB
共343–501兲
37.5⫾0.7
共490兲
EB
50.8
共298兲
共243– 403兲
53.5
共258兲
48.0⫾0.1
共343兲
C
46.8⫾0.1
共358兲
C
46.0⫾0.1
共368兲
C
50.1
共298兲
共374 – 454兲
45.2
共389兲
共369– 463兲
45.7
共384兲
A
(dl) sec-butylbenzene
共335– 491兲
45.7⫾0.2
共340兲
EB
共335– 491兲
43.2⫾0.2
共380兲
EB
CAS registry number
Reference
关5912-86-7兴
关87/5兴
关5932-68-3兴
关87/5兴
关101-97-3兴
关99/2兴
关99/2兴
关87/5兴
关2315-68-6兴
关88/2兴
关88/2兴
关87/5兴关47/5兴
关2930-05-4兴
关87/14兴
关6192-44-5兴
关87/5兴关47/5兴
关94-13-3兴
关01/20兴
关999-21-3兴
关87/5兴
关2437-76-5兴
关87/5兴关70/14兴
关99/16兴
关4478-10-8兴
关87/5兴关70/14兴
关99/16兴
关4395-79-3兴
关87/5兴关70/14兴
关99/16兴
关15146-00-6兴
关87/5兴关70/14兴
关4446-91-7兴
关87/5兴关47/5兴
关99/16兴
关58498-77-4兴
关87/5兴关99/16兴
关47/5兴
关18361-88-1兴
关87/5兴关99/16兴
关69/1兴
关62-44-2兴
关87/5兴
关943-15-7兴
关87/5兴
关35480-94-5兴
关87/5兴
关104-51-8兴
关02/14兴
关02/14兴
关02/14兴
关02/14兴
关94/11兴
关93/10兴
关82/10兴
关82/10兴
关82/10兴
关71/28兴
关65/26兴关84/9兴
关87/5兴关49/6兴
关135-98-8兴
关02/14兴
关02/14兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
720
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共335– 491兲
共335– 491兲
共243–373兲
共384 – 448兲
C10H14
共368 – 448兲
tert-butylbenzene
共332– 486兲
共332– 486兲
共332– 486兲
共332– 486兲
共278 –308兲
共368 – 444兲
C10H14
共357– 443兲
1,2-diethylbenzene
C10H14
共369– 464兲
1,3-diethylbenzene
C10H14
共368 – 457兲
1,4-diethylbenzene
C10H14
C10H14
C10H14
C10H14
C10H14
C10H14
C10H14
共369– 464兲
1,2-dimethyl-3-ethylbenzene
共344 – 497兲
1,2-dimethyl-4-ethylbenzene
共340– 493兲
1,3-dimethyl-2-ethylbenzene
共341– 493兲
共299– 461兲
1,3-dimethyl-4-ethylbenzene
共339– 492兲
1,3-dimethyl-5-ethylbenzene
共336 – 487兲
共295– 456兲
1,4-dimethyl-2-ethylbenzene
共338 – 490兲
共299– 440兲
isobutylbenzene
共373– 447兲
C10H14
C10H14
C10H14
共360– 447兲
2-isopropyltoluene
共354 – 453兲
3-isopropyltoluene
共351– 450兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
40.6⫾0.3
37.8⫾0.5
48.1
50.6
42.8
49.5
44.0
共420兲
共460兲
共298兲
共258兲
共399兲
共298兲
共375兲
EB
EB
45.3⫾0.2
42.6⫾0.2
39.9⫾0.3
37.0⫾0.5
47.8⫾0.4
47.5⫾0.4
47.6
43.1
47.7
49.1
43.7
共340兲
共380兲
共420兲
共460兲
共293兲
共298兲
共298兲
共383兲
共298兲
共298兲
共372兲
EB
EB
EB
EB
GS
52.8
46.0
共298兲
共384兲
A
52.5
45.8
共298兲
共383兲
A
52.5
45.8
共298兲
共384兲
A
49.7
54.9
共359兲
共298兲
A
48.9
53.9
共355兲
共298兲
A
48.8
53.9
48.6
共356兲
共298兲
共314兲
A
48.5
53.3
共354兲
共298兲
A
48.0
52.4
47.5
共351兲
共298兲
共310兲
A
48.0
52.6
48.7
共353兲
共298兲
共313兲
A
48.0
43.2
49.5
43.8
共298兲
共388兲
共298兲
共375兲
44.4
共369兲
50.6
共298兲
44.7
共366兲
50.0
共298兲
48.9
共298兲
4-isopropyltoluene
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
A
A
A
A
CAS registry number
Reference
关02/14兴
关02/14兴
关94/11兴
关93/10兴
关87/5兴
关71/28兴
关49/6兴
关98-06-6兴
关02/14兴
关02/14兴
关02/14兴
关02/14兴
关98/19兴
关98/19兴
关94/11兴
关87/5兴
关74/14兴
关71/28兴
关49/6兴
关135-01-3兴
关71/28兴
关87/5兴关49/6兴
关141-93-5兴
关71/28兴
关87/5兴关49/6兴
关105-05-5兴
关71/28兴
关87/5兴关49/6兴
关933-98-2兴
关87/5兴
关71/28兴
关934-80-5兴
关87/5兴
关71/28兴
关2870-04-0兴
关87/5兴
关71/28兴
关47/5兴
关874-41-9兴
关87/5兴
关71/28兴
关934-74-7兴
关87/5兴
关71/28兴
关47/5兴
关1758-88-9兴
关87/5兴
关71/28兴
关47/5兴
关538-93-2兴
关94/11兴
关87/5兴
关71/28兴
关49/6兴
关527-84-4兴
关87/5兴关59/1兴
关84/9兴
关71/28兴
关535-77-3兴
关87/5兴关59/1兴
关84/9兴
关71/28兴
关99-87-6兴
关94/11兴
ENTHALPIES OF VAPORIZATION
721
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共380– 452兲
C10H14
C10H14
C10H14
C10H14
2-propyltoluene
共337– 488兲
3-propyltoluene
共334 – 485兲
4-propyltoluene
共335– 487兲
共316 – 477兲
1,2,3,5-tetramethylbenzene
共348 –502兲
C10H14
C10H14
C10H14NO5 PS
C10H14NO5 PS
C10H14NO5 PS
C10H14NO6 P
C10H14N2
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
Mean temperature
(T m /K)
Method
44.0
共395兲
A
50.3
共298兲
48.0
52.7
共352兲
共298兲
A
47.8
52.1
共349兲
共298兲
A
47.6
51.9
共350兲
共298兲
A
54.0
52.6⫾0.2
50.7
57.2
55.7
共298兲
共298兲
共367兲
共298兲
共331兲
53.2
52.0⫾0.2
50.0
55.8
58.9
共298兲
共298兲
共363兲
共298兲
共329兲
1,2,3,4-tetramethylbenzene
共352–509兲
C10H14
⌬ vapH m
共kJ mol⫺1兲
共314 – 471兲
1,2,4,5-tetramethylbenzene
共363–381兲
47.7⫾0.3
共353–500兲
49.4
spirocyclopropane-1,6-tricyclo关 3.2.1.02,4兴 octane
47.8⫾0.1
Parathion
共293– 433兲
93.4
phosphorothioic acid, O,O⬘-diethyl-S-共4-nitrophenyl兲
共313–366兲
75.9
phosphorothioic acid, O,S-diethyl-O⬘-共4-nitrophenyl兲
共332–364兲
75.1
O,O-diethyl-O-共4-nitrophenyl兲 phosphate
共273– 422兲
87.9
(dl) nicotine
共406 –520兲
53.3
2-butylphenol
共403–533兲
55.1
共382–520兲
52.9
共382–520兲
51.0
共382–520兲
47.0
2-sec-butylphenol
共451–513兲
52.1
2-tert-butylphenol
共289–329兲
62.6⫾0.2
63.2⫾0.2
共409– 467兲
74.1
共409– 465兲
52.9
共353– 498兲
54.9
共330–507兲
55.6
共330–507兲
53.9
共330–507兲
51.0
共330–507兲
47.0
3-butylphenol
共396 –533兲
62.5
共396 –533兲
56.6
共396 –533兲
54.4
共396 –533兲
49.9
3-tert-butylphenol
共320–348兲
69.1⫾0.8
71.3⫾0.8
C
A
C
A
共375兲
共368兲
DM
A
共298兲
C
共308兲
A
共328兲
A
共347兲
A
共288兲
A
共421兲
A
共418兲
共398兲
共423兲
共473兲
A
共466兲
A, GS, EB
共309兲
共298兲
共424兲
共424兲
共368兲
共348兲
共373兲
共423兲
共473兲
GS
共411兲
共398兲
共423兲
共473兲
A
共334兲
共298兲
GS
EB
A
CAS registry number
Reference
关87/5兴关59/1兴
关84/9兴
关71/28兴
关1074-17-5兴
关87/5兴
关71/28兴
关1074-43-7兴
关87/5兴
关71/28兴
关1074-55-1兴
关87/5兴
关71/28兴
关488-23-3兴
关94/11兴
关94/1兴
关87/5兴
关71/28兴
关47/5兴
关527-53-7兴
关94/11兴
关94/1兴
关87/5兴
关71/28兴
关47/5兴
关95-93-2兴
关01/8兴
关87/5兴
关98/17兴关96/18兴
关58-38-2兴
关87/5兴关99/16兴
关3270-86-8兴
关87/5兴关99/16兴
关597-88-6兴
关87/5兴关99/16兴
关311-45-5兴
关87/5兴
关22083-74-5兴
关87/5兴
关3180-09-4兴
关87/5兴关75/17兴
关53/9兴
关53/9兴
关53/9兴
关89-72-5兴
关87/5兴关64/14兴
关88-18-6兴
关99/18兴
关99/18兴
关90/5兴
关86/7兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关4074-43-5兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关585-34-2兴
关99/18兴
关99/18兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
722
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H14O
C10H14O
C10H14O
Compound
共Temperature range/K兲
共391–524兲
共391–524兲
共391–524兲
共391–524兲
4-butylphenol
共395– 653兲
共357–529兲
共357–529兲
共357–529兲
共357–529兲
4-sec-butylphenol
共344 –516兲
4-tert-butylphenol
共471–525兲
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
C10H14O
共346 –523兲
共346 –523兲
共346 –523兲
共346 –523兲
共346 –523兲
butyl phenyl ether
共391– 483兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
62.4
56.6
54.4
49.9
共406兲
共398兲
共423兲
共473兲
A
61.7
57.6
56.6
54.4
49.9
共410兲
共373兲
共398兲
共423兲
共473兲
A
59.0
共359兲
A
67.9⫾1.0
54.3
共298兲
共486兲
C
A, GS, EB
59.6
57.6
56.6
54.4
49.9
共348兲
共373兲
共398兲
共423兲
共473兲
48.9
共406兲
A
共380兲
EB
共397兲
EB
共298兲
共402兲
共358兲
GC
EB
A
共386兲
EB
共402兲
A
共360兲
A
共396兲
A
共298兲
共298兲
共396兲
共373兲
共398兲
共423兲
共448兲
共473兲
共352兲
GC
CGC
A
共345兲
A
共336兲
A
共435兲
A
共435兲
A
共362兲
A
共358兲
A
关87/5兴
关22545-13-7兴
关87/5兴
关536-60-7兴
关87/5兴关47/5兴
关7384-80-7兴
关87/5兴
共302兲
GS
关01/16兴
3-isopropyl-2-methylphenol
共365–516兲
60.2
4-isopropyl-2-methylphenol
共382–503兲
59.8
5-isopropyl-2-methylphenol 共carvacrol兲
68.2
共387–512兲
59.4
共343–510兲
56.5
6-isopropyl-2-methylphenol
共371– 499兲
54.5
3,5-diethylphenol
共387–521兲
54.3
4-isobutylphenol
共345–510兲
58.1
2,3,5,6-tetramethylphenol
共381–522兲
51.2
2-isopropyl-5-methylphenol 共thymol兲
68.7
共393– 433兲
70.5
共381–514兲
58.4
共339–514兲
63.2
共339–514兲
58.4
共339–514兲
55.2
共339–514兲
52.8
共339–514兲
51.5
共337–505兲
54.9
(dl) carvone
共330–501兲
55.0
4-ethylphenetole
共321– 481兲
54.3
2-共2-ethylphenyl兲ethanol
共420– 653兲
59.5
2-共4-ethylphenyl兲ethanol
共420– 653兲
59.1
4-isopropylbenzyl alcohol
共347–520兲
59.7
2-methyl-3-phenyl-1-propanol
共343–393兲
71.9
共1-ethoxyethyl兲benzene
共286 –318兲
52.4⫾0.2
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关1638-22-8兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关99-71-8兴
关87/5兴关47/5兴
关98-54-4兴
关99/7兴
关87/5兴关47/5兴
关64/14兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关1126-79-0兴
关87/5兴关49/1兴
关84/9兴
关4371-48-6兴
关69/23兴
关1740-97-2兴
关69/23兴
关499-75-2兴
关02/37兴
关69/23兴
关87/5兴关47/5兴
关3228-04-4兴
关69/23兴
关1197-34-8兴
关87/5兴关55/9兴
关4167-74-2兴
关87/5兴关47/5兴
关527-35-5兴
关87/5兴关55/9兴
关89-83-8兴
关02/37兴
关95/21兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关47/5兴
关22327-39-5兴
关87/5兴关47/5兴
关1585-06-4兴
关87/5兴关47/5兴
ENTHALPIES OF VAPORIZATION
723
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H14O
C10H14O2
C10H14O2
C10H14O2
C10H14O2
C10H14O2
C10H14O2
C10H14O2
C10H14O3
C10H14O5
C10H15Cl3 OS
C10H15N
C10H15N
C10H15N
C10H15N
C10H15N
C10H15N
C10H15NO
C10H15NO
C10H15NO2
C10H15O3 PS2
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
Compound
共Temperature range/K兲
共286 –318兲
2-adamantanone
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
52.6⫾0.2
共298兲
GS
共298兲
GC
共359兲
共298兲
GS
GS
共298兲
EB
共428兲
A, GC
共388兲
A
60.7
1,2-dihydroxy-3-tert-butylbenzene
共334 –384兲
70.1⫾0.8
共334 –384兲
73.5⫾0.8
1,2-dihydroxy-4-tert-butylbenzene
共439–516兲
96.5⫾2.8
1,3-dihydroxy-2-butylbenzene
共413– 469兲
75.3
2-methoxy-4-propylphenol
共373– 413兲
78.0
tert-butylcatechol 共isomer not specified兲
共421– 466兲
58.2
1,1-dimethoxy-2-phenylcyclopropane
共278 –313兲
63.7⫾0.6
acetophenone dimethyl ketal
共268 –303兲
54.0⫾0.8
共268 –303兲
55.0⫾1.3
trimethyl orthobenzoate
共294 –333兲
59.9⫾0.4
共294 –333兲
58.6⫾0.4
allyl关共1-allyloxycarbonyl兲ethyl兴 carbonate
共353–503兲
61.9
2,3,3-trichloro-2-propenethioic acid, O-heptyl ester
共433– 483兲
72.7
2-tert-butylaniline
共279–318兲
62.7⫾0.4
2,6-diethylaniline
共284 –328兲
69.5⫾0.6
65.9⫾0.6
5-isopropyl-2-methylaniline
共360–386兲
72.0
N-␣-dimethylphenethylamine
共270–304兲
52.8
N-butylaniline
共413– 643兲
55.6
N,N-diethylaniline
共343– 493兲
54.5
2-共dimethylamino兲-1-phenylethanone
共293–333兲
69.7⫾0.5
4-共butylamino兲phenol
共464 –511兲
71.2
N,N-bis共2-hydroxyethyl兲aniline
共418 – 611兲
77.6
O,O-dimethyl-O-关3-methyl-4-共methylthio兲phenyl兴thiophosphate
共293–373兲
75.6
adamantane
48.2
共403– 453兲
51.7
(dl) camphene
共320– 434兲
44.0
共d兲 3,7,7-trimethylbicyclo关4.1.0兴hept-2-ene 共2-carene兲
共293– 450兲
45.5
共d兲 3,7,7-trimethylbicyclo关4.1.0兴hept-3-ene 共3-carene兲
共359– 443兲
42.8
共⫹兲 limonene
共373– 423兲
49.6
共S兲-共⫺兲 limonene
共320– 451兲
47.4
共d兲 limonene
49.9
共339– 495兲
46.1⫾0.2
共339– 495兲
43.5⫾0.2
共443兲
共298兲
GS
共298兲
共286兲
GS
GS
共298兲
GS
GS
共368兲
A
共298兲
CAS registry number
Reference
关01/16兴
关700-58-3兴
关02/37兴
关4026-05-5兴
关00/5兴
关00/5兴
关98-29-3兴
关97/6兴
关13331-20-9兴
关87/5兴关75/24兴
关2785-87-7兴
关87/5兴
关65/21兴
关18523-34-7兴
关02/32兴
关4316-35-2兴
关02/32兴
关95/25兴
关707-07-3兴
关02/32兴
关95/7兴
GC
关87/5兴
关76633-71-1兴
关80/24兴
GS
关00/14兴
共306兲
共298兲
关00/14兴
关00/14兴
关2051-53-8兴
关87/5兴
关537-46-2兴
关87/5兴
关1126-78-9兴
关87/5兴
关91-66-7兴
关87/5兴
共373兲
A
共285兲
A
共428兲
A
共358兲
A
共298兲
GS
共478兲
A
共433兲
A
共308兲
A
共298兲
共298兲
GC
CGC
共335兲
A
共308兲
A
共374兲
A
关94/3兴
关103-62-8兴
关87/5兴
关120-07-0兴
关87/5兴关47/5兴
关55-38-9兴
关87/5兴关99/16兴
关281-23-2兴
关02/37兴
关95/21兴
关79-92-5兴
关87/5兴关47/5兴
关4497-92-1兴
关87/5兴关54/12兴
关498-15-7兴
关87/5兴
共298兲
CGC
关95/21兴
GC
EB
EB
关96/15兴
关5989-27-5兴
关02/37兴
关02/15兴
关02/15兴
共335兲
共298兲
共350兲
共390兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
724
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
40.9⫾0.3
37.9⫾0.6
49.2
48.9⫾0.1
44.5
47.7
共430兲
共470兲
共300兲
共298兲
共302兲
共303兲
EB
EB
49.0⫾0.1
共298兲
共303–363兲
45.5
共318兲
(dl) limonene
共287– 448兲
45.9
共302兲
limonene
共353– 405兲
39.4
共379兲
␤-myrcene
共303–363兲
47.0
共318兲
7-methyl-3-methylene-1,6-octadiene 共myrcene兲
50.6
共298兲
共287– 445兲
45.7
共302兲
5-isopropyl-2-methyl-1,3-cyclohexadiene
共293– 448兲
47.7
共308兲
3-isopropyl-6-methylenecyclohexene
共303–363兲
47.7
共318兲
␣-pinene
共320– 429兲
42.5
共335兲
共365– 430兲
40.2
共380兲
44.6⫾0.1
共298兲
共d兲 ␣-pinene
共292– 433兲
45.0
共307兲
共293–363兲
43.4
共308兲
␤-pinene
共290– 439兲
46.0
共305兲
共364 – 439兲
41.6
共379兲
45.8⫾0.1
共298兲
共l兲 ␤-pinene
共291– 441兲
46.1
共306兲
共293–363兲
44.9
共308兲
terpinolene
共313–363兲
50.8
共328兲
共305– 458兲
50.5
共320兲
tetrahydrodicyclopentadiene
共358 – 465兲
43.5
共373兲
lactic acid, O-ethoxycarbonyl, 2-共2-chloroethoxy兲ethyl ester 共solid兲
共406 –523兲
83.8
共421兲
carbamothioic acid, bis共isopropyl兲, S-共2,3,3-trichloroallyl兲 ester
共293–318兲
84.3
共305兲
sebaconitrile
共303–343兲
83.7
共318兲
N⬘-共2,4-dimethylphenyl兲-N-methylformamidine
89.2
共303兲
3,7-dimethyl-6-octen-1-yn-3-ol 共dehydrolinalool兲
共406 – 471兲
52.1
共421兲
共359–381兲
Unreliable
共369– 445兲
50.4⫾0.1
共407兲
camphor
共343–383兲
54.4
共298兲
共343–383兲
54.5
共298兲
共343–383兲
55.2
共298兲
共⫹兲 camphor
55.3
共298兲
␣-pinene oxide
53.6
共298兲
共d兲 3-bornanone
共452– 488兲
44.6
共467兲
共d兲 1,3,3-trimethylbicyclo关2.2.1兴heptan-2 one 共fenchone兲
C
A
Compound
共Temperature range/K兲
共339– 495兲
共339– 495兲
共250– 434兲
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16
C10H16ClO6
C10H16Cl3 NOS
C10H16N2
C10H16N2
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
共287– 448兲
共288 –323兲
共l兲 limonene
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
A
关02/15兴
关02/15兴
关99/27兴
关87/8兴
关87/5兴
关87/5兴
关5989-54-8兴
关87/8兴
关87/5兴关54/12兴
关138-86-3兴
关87/5兴
TGA
关02/40兴
C
A
A
GC
A
A
A
C
A
关54/12兴
关123-35-3兴
关02/37兴
关87/5兴关47/5兴
关99-83-2兴
关87/5兴
关555-10-2兴
关87/5兴关54/12兴
关96/15兴
关93/4兴
关87/19兴
关80-56-8兴
关87/5兴
关54/12兴
A
关96/15兴
关93/4兴
关87/19兴
关127-91-3兴
关87/5兴
关54/12兴
关586-62-9兴
关54/12兴
关87/5兴关47/5兴
关6004-38-2兴
关87/5兴
A
关87/5兴
A
关87/5兴
关1871-96-1兴
关87/5兴
C
A
A
A
EB
CGC
CGC
CGC
GC
GC
A
关98/23兴
关29171-20-8兴
关01/13兴
关99/33兴
关88/4兴
关95/21兴
关95/21兴
关95/21兴
关464-49-3兴
关02/37兴
关1686-14-2兴
关02/37兴
关13854-85-8兴
关87/5兴
关4695-62-9兴
ENTHALPIES OF VAPORIZATION
725
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
CAS registry number
Reference
C
C
C
A
关02/13兴
关87/8兴
关87/8兴
关85/2兴
关87/5兴关47/5兴
共365–384兲
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O
C10H16O2
C10H16O2
C10H16O2
C10H16O2
C10H16O2
C10H16O4
C10H16O6
C10H16O6
C10H16S
C10H17N
C10H17NOS
C10H17NO3
C10H17NO5
C10H18
C10H18
47.0
共374兲
51.7⫾0.1
共298兲
51.4⫾0.1
共298兲
51.1⫾0.1
共298兲
共301– 464兲
48.9
共316兲
共l兲 1,3,3-trimethylbicyclo关2.2.1兴heptan-2one 共fenchone兲
51.1⫾0.1
共298兲
51.3⫾0.1
共298兲
51.4⫾0.1
共298兲
pulegone
62.0
共298兲
共331– 494兲
U99.8
共346兲
共d兲 1-isopropyl-4-methylbicyclo关3.1.0兴hexan-3-one 共thujone兲
共311– 474兲
51.8
共326兲
(dl) 3-isopropyl-6-methyl-2-cyclohexene-1-one
共364 –507兲
56.9
共379兲
5-isopropyl-2-methyl-2-cyclohexen-1-one
共361–503兲
56.8
共376兲
3,4-epoxycarane 共␣-isomer兲
49.4
3,4-epoxycarane 共␤-isomer兲
50.2
(dl) dihydrocarvone
共319– 496兲
51.2
共334兲
geranial 共citral兲
共283–333兲
61.0
共298兲
共373–501兲
54.9
共388兲
1-adamantanol
60.8
共298兲
trans octahydro-3a-methyl-2H-inden-2-one
58.3⫾0.2
共298兲
3-acetyl-2,2-dimethylcyclobutaneacetaldehyde 共pinonaldehyde兲
共283–308兲
75.5⫾5.6
2,2-dimethyl-3-共2-oxopropyl兲cyclopropaneacetaldehyde 共caronaldehyde兲
共283–308兲
77.4⫾6.9
diosphenol
共339–505兲
56.2
共354兲
fencholic acid
共374 –537兲
77.5
共389兲
共2,3,3-trimethyl-3-cyclopentadienyl兲acetic acid
共370–529兲
71.3
共385兲
1,1-cyclobutanedicarboxylic acid, diethyl ester
共288 –318兲
65.8⫾0.4
lactic acid, O-ethoxycarbonyl, tetrafurfuryl ester
共390–523兲
71.2
共405兲
tris-共carboethoxy兲methane
共297–338兲
79.1⫾0.7
共298兲
共1R兲 共⫺兲-thiocamphor
55.5
共298兲
1-cyclohexylimino-2-butene
58.3
carbamothioic acid, N,N-dipropyl, S-共2-propynyl兲 ester 共solid兲
共298 –313兲
92.4
共305兲
2-共2-cyanoethoxy兲propionic acid, butyl ester
共328 –382兲
61.7
共343兲
共l兲 N-acetylaspartic acid, diethyl ester
共418 –508兲
76.0
共433兲
spiro关4.5兴decane
54.8
共298兲
共348 –389兲
44.0
共363兲
cis bicyclo关5.3.0兴decane
共298 –377兲
49.8
共313兲
46.9⫾0.8
共377兲
53.6⫾1.2
共298兲
Method
C
C
C
GC
A
A
A
A
关87/8兴
关87/8兴
关85/2兴
关89-82-7兴
关02/37兴
关87/5兴关47/5兴
关471-15-8兴
关87/5兴关47/5兴
关499-74-1兴
关87/5兴
关43205-82-9兴
关87/5兴
关77/27兴
C
关77/27兴
关4584-09-2兴
关87/5兴关47/5兴
关141-27-5兴
关87/5兴
关87/5兴
关768-95-6兴
关02/37兴
关20379-99-1兴
关70/38兴
ME
关97/24兴
ME
关97/24兴
关490-03-9兴
关87/5兴关47/5兴
A
A
A
GC
A
关47/5兴
A
关87/5兴关47/5兴
GS
关98/22兴
A
关87/5兴
GS
GC
关92/13兴
关53402-10-1兴
关02/37兴
A
关93/20兴
关59300-36-6兴
关87/5兴
A
A
C
A
关87/5兴
关1069-39-2兴
关87/5兴
关176-63-6兴
关75/14兴
关65/11兴
关16189-46-1兴
关87/5兴
关70/30兴
关70/30兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
726
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H18
C10H18
C10H18
C10H18
C10H18
C10H18
C10H18Cl4
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
bicyclopentyl
共350–393兲
cis carane
共362– 445兲
cis decahydronaphthalene
共371– 473兲
trans decahydronaphthalene
共363– 461兲
5-decyne
共477– 487兲
cis 2,6,6-trimethylbicyclo关3.1.1兴heptane
共378 – 441兲
1,2,9,10-tetrachlorodecane
Mean temperature
(T m /K)
Method
43.2
共365兲
A
42.8
共377兲
A
45.5
共386兲
A, GS
44.2
共378兲
A, GS
45.5
共cis-pinane兲
41.8
共366兲
A
共393兲
75.4
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
1,8-epoxy-p-menthane
共264 –303兲
(dl) borneol
共477– 487兲
1,4-cineole
共353– 403兲
35.6
共279兲
A
50.9
共482兲
A
41.1
53.2
46.1
共378兲
共298兲
共303兲
TGA
GC
A
共351兲
A
共333兲
A
共303兲
共357兲
A
A
共350兲
A
共297兲
共328兲
A
共399兲
共424兲
TGA
EB
共349兲
A
共340兲
A
共298兲
GC
共409兲
A
共368兲
A
共403兲
A
共385兲
共365兲
A
共303兲
共332兲
A
A
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共288 – 449兲
共d兲 dihydrocarveol
共336 – 498兲
58.2
(dl) fenchyl alcohol
共318 – 474兲
89.1
geraniol
共288 –333兲
62.9
共342–503兲
59.1
共d兲 isopulegol
共335– 485兲
49.8
共d兲 linalool
共273–321兲
65.4
共313– 471兲
52.4
linalool
共368 – 428兲
51.4
共409– 465兲
50.3
cis 3,7-dimethyl-2,6-octadien-1-ol 共nerol兲
共334 – 499兲
55.4
(dl) ␣-terpineol
共325– 491兲
54.0
共⫹兲 ␣-terpineol
60.7
1-共1-methylcyclohex-3-enyl兲-1-propanol
共397– 422兲
53.6
cyclodecanone
共353– 423兲
55.2
ethyl 共1-methylcyclohexyl兲 ketone
共388 – 431兲
45.2
2-isopropyl-5-methylcyclohexanone 共menthone兲
共372–397兲
50.1
共350– 483兲
51.2
共d兲 citronellal
共288 –333兲
54.9
共317– 480兲
53.2
共Z兲 3-decenal
共323–343兲
59.2
共E兲 3-decenal
共323–343兲
59.8
共Z兲 4-decenal
共323–343兲
59.3
共E兲 4-decenal
共323–343兲
60.0
共Z兲 5-decenal
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关1636-39-1兴
关87/5兴
关18968-24-6兴
关87/5兴
关493-01-6兴
关87/5兴关55/7兴
关493-02-7兴
关87/5兴关55/7兴
关1942-46-7兴
关87/5兴
关4755-33-3兴
关02/41兴
关98/20兴
关470-82-6兴
关87/5兴
关6627-72-1兴
关87/5兴
关470-82-6兴
关02/40兴
关02/37兴
关87/5兴
关619-01-2兴
关87/5兴
关2217-01-8兴
关87/5兴
关106-24-1兴
关87/5兴
关87/5兴
关7786-67-6兴
关87/5兴
关126-90-9兴
关99/27兴
关87/5兴
关78-70-6兴
关02/40兴
关02/2兴
关106-25-2兴
关87/5兴
关98-55-5兴
关87/5兴
关7785-53-7兴
关02/37兴
关87/5兴
关1502-06-3兴
关87/5兴
关87/5兴
关10458-14-7兴
关02/13兴
关87/5兴
关2385-77-5兴
关87/5兴
关87/5兴关47/5兴
关69891-94-7兴
关96/7兴关00/10兴
关68676-85-7兴
关96/7兴关00/10兴
关21662-09-9兴
关96/7兴关00/10兴
关65405-70-1兴
关96/7兴关00/10兴
关21662-08-8兴
ENTHALPIES OF VAPORIZATION
727
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O
C10H18O2
C10H18O2
C10H18O2
C10H18O2
C10H18O2
C10H18O2
C10H18O2
C10H18O2
C10H18O3
C10H18O3
C10H18O3
C10H18O3
C10H18O3
C10H18O3
C10 H18O3
C10H18O4
C10H18O4
C10H18O4
C10H18O4
C10H18O4
C10H18O4
C10H18O5
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共323–343兲
58.5
共E兲 5-decenal
共323–343兲
59.2
共Z兲 6-decenal
共323–343兲
59.3
共E兲 6-decenal
共323–343兲
59.5
共Z兲 7-decenal
共323–343兲
59.9
共E兲 7-decenal
共323–343兲
59.8
共Z兲 8-decenal
共323–343兲
60.5
共E兲 8-decenal
共323–343兲
60.2
3,7-dimethyl-6-octenoic acid
共372–530兲
68.7
8,8-dimethyl-6,10-dioxaspiro关4.5兴decane
共283–313兲
53.7⫾0.5
2,2,6-trimethyl-3,5-heptanedione
57.7
decanolactone
共365–387兲
57.7⫾0.8
共365–387兲
63.0⫾1.5
cyclohexyl butyrate
共283–313兲
60.0⫾0.6
heptyl acrylate
共359– 481兲
51.1
hexyl methacrylate
共354 – 475兲
50.5
1-methyl-3-isopropylcyclopentane carboxylic acid
共374 –538兲
91.6
3-hydroxy-2,3-dimethyl-4-hexenoic acid, ethyl ester
共362–387兲
57.4
isopentyl levulinate
共403–521兲
59.4
56.3
1-ethylpropyl levulinate
共397–513兲
58.6
1-methylbutyl levulinate
共397–513兲
57.2
2-methylbutyl levulinate
共391– 473兲
56.5
pentyl levulinate
共354 –527兲
66.3
56.2
trimethylacetic acid anhydride
共355–513兲
50.7⫾0.2
共355–513兲
47.4⫾0.2
共355–513兲
44.0⫾0.4
共355–513兲
40.3⫾0.7
pentyl 2-acetoxypropionate
共312–501兲
68.5
diethyl adipate
共347–513兲
57.5
diisobutyl oxalate
共336 –503兲
55.5
dipropyl succinate
共350–524兲
59.4
diethyl ethylmethylmalonate
共317– 481兲
53.2
sebacic acid
共456 – 625兲
85.9
ethyl关1-共butoxycarbonyl兲ethyl兴 carbonate
Mean temperature
(T m /K)
Method
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共387兲
A
CAS registry number
Reference
关96/7兴关00/10兴
关21662-11-3兴
关96/7兴关00/10兴
关147159-48-6兴
关96/7兴关00/10兴
关147159-48-6兴
关96/7兴关00/10兴
关21661-97-2兴
关96/7兴关00/10兴
关21662-10-2兴
关96/7兴关00/10兴
关174155-46-5兴
关96/7兴关00/10兴
关174155-47-6兴
关96/7兴关00/10兴
关502-47-6兴
关87/5兴关47/5兴
共376兲
共298兲
MM
MM
共298兲
GS
共374兲
A
共369兲
A
共389兲
A
关98/21兴关02/32兴
关7333-23-5兴
关78/18兴
关706-14-9兴
关91/7兴
关91/7兴
关1551-44-6兴
关96/11兴
关2499-58-3兴
关87/5兴
关142-09-6兴
关87/5兴
关512-77-6兴
关87/5兴
共374兲
A
关87/5兴
共418兲
共461兲
A
关87/5兴
关31/1兴
共412兲
A
关87/5兴
共412兲
A
关87/5兴
共406兲
A
共369兲
共466兲
A
共360兲
共400兲
共440兲
共480兲
EB
EB
EB
EB
关87/5兴
关20279-49-6兴
关87/5兴关47/5兴
关31/1兴
关1538-75-6兴
关02/16兴
关02/16兴
关02/16兴
关02/16兴
共327兲
A
共362兲
A
共351兲
A
共365兲
A
共332兲
A
GS
共298兲
共471兲
关87/5兴
关141-28-6兴
关87/5兴关47/5兴
关2050-61-5兴
关87/5兴关47/5兴
关925-15-5兴
关87/5兴关47/5兴
关2049-70-9兴
关87/5兴
关111-20-6兴
关47/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
728
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H18O5
C10H18O5
C10H18O5
C10H18O5
C10H18O6
C10H18O6
C10H19ClNO5 P
C10H19Cl2 N
C10H19N
C10H19N
C10H19NO3
C10H19NO3
C10H19O6 PS2
C10H19O7 PS
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共339兲
A
关87/5兴
共351兲
A
关87/5兴
共344兲
A
关87/5兴
共398兲
A
关87/5兴
共375兲
A
共391兲
A
共403兲
A
共308兲
A
共288兲
A, GS
54.9⫾0.3
55.1⫾0.3
共301兲
共298兲
GS
GS
58.0
66.8⫾0.4
57.8
54.4
共396兲
共298兲
共396兲
共446兲
A
C
EB
EB
关87/5兴
关62961-64-2兴
关87/5兴关47/5兴
关2217-14-3兴
关87/5兴关47/5兴
关13171-21-6兴
关87/5兴关99/16兴
关4261-59-0兴
关87/5兴关48/13兴
关99/16兴
关7335-04-8兴
关98/12兴
关98/12兴
关1975-78-6兴
关87/5兴
关77/5兴
关71/4兴
关71/4兴
A
关87/5兴
A
关87/5兴
关121-75-5兴
关87/5兴
共324 – 473兲
70.2
2-lactoyloxypropionic acid, butyl ester
共336 – 407兲
74.8
2-lactoyloxypropionic acid, sec-butyl ester
共329–399兲
74.3
pentyl关1-共ethoxycarbonyl兲methyl兴 carbonate
共383–503兲
68.2
pentyl关1-共methoxycarbonyl兲ethyl兴 carbonate
共360–524兲
63.7
共d兲 diisopropyl tartrate
共376 –548兲
65.7
共d兲 dipropyl tartrate
共388 –576兲
71.8
Phosphamidon
共293–388兲
90.1
N,N-bis共2-chloroethyl兲cyclohexylamine
共273–333兲
62.4
N-cyclopentylpiperidine
共283–318兲
共283–318兲
decanenitrile 共caprinitrile兲
共381–519兲
共381– 431兲
共431–518兲
共l兲 N-acetylisoleucine, ethyl ester
共391– 476兲
69.1
共406兲
共l兲 N-acetylleucine, ethyl ester
共396 – 476兲
74.8
共411兲
(dl) Malathion
共283– 419兲
71.1
共298兲
O,O-dimethyl-S-关1,2-bis共ethoxycarbonyl兲ethyl兴thiophosphate
共283– 406兲
93.4
共298兲
1,1,4-trimethylcycloheptane
45.5⫾0.2
共298兲
45.6⫾0.2
共298兲
关Note: Text in 关96/18兴 states 1,1,4-trimethylcycloheptane; however,
the molecular structure of 1,1,4-trimethylcyclohexane is given in the paper.兴
cyclodecane
共404 – 489兲
45.1
共419兲
共343–386兲
48.2
共358兲
butylcyclohexane
共274 –313兲
47.4⫾0.2
共294兲
47.0⫾0.2
共298兲
48.9⫾0.5
共298兲
49.4⫾0.4
共298兲
49.4
共298兲
50.0
共298兲
共367– 457兲
44.9
共382兲
sec-butylcyclohexane
共369– 455兲
44.1
共384兲
tert-butylcyclohexane
45.0⫾0.1
共328兲
44.0⫾0.1
共343兲
43.0⫾0.1
共358兲
42.4⫾0.1
共368兲
共355– 446兲
42.9
共370兲
isobutylcyclohexane
47.5
共298兲
共355– 446兲
43.5
共370兲
1-isopropyl-4-methylcyclohexane
共382– 443兲
43.6
共297兲
n-pentylcyclopentane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
C
A, EB
EB
GS
GC
GCC
A
A
C
C
C
C
A
A
A
关87/5兴
关2158-55-6兴
关96/18兴
关95/19兴
关293-96-9兴
关87/5兴关76/10兴
关87/5兴关76/10兴
关1678-93-9兴
关95/27兴
关95/27兴
关87/17兴
关78/16兴
关75/12兴
关71/28兴
关87/5兴关49/6兴
关7058-01-7兴
关87/5兴关49/6兴
关3178-22-1兴
关81/14兴
关81/14兴
关81/14兴
关81/14兴
关87/5兴关49/6兴
关1678-98-4兴
关75/12兴
关87/5兴关49/6兴
关99-82-1兴
关87/5兴
关3741-00-2兴
ENTHALPIES OF VAPORIZATION
729
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20
C10H20Br2
C10H20Br2
C10H20Cl2
C10H20Cl2
C10H20F2
C10H20NO2
C10H20N2 O2
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
Compound
共Temperature range/K兲
1-decene
共383– 445兲
共360– 445兲
cis 2-decene
共401– 447兲
trans 2-decene
共401– 447兲
cis 3-decene
共398 – 444兲
trans 3-decene
共398 – 445兲
cis 4-decene
共397– 444兲
trans 4-decene
共398 – 444兲
cis 5-decene
共397– 443兲
trans 5-decene
共398 – 444兲
4-propyl-3-heptene
共333–371兲
trans 2,2,4,4-tetramethyl-3-hexene
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
51.0
共298兲
43.8
50.4⫾0.2
50.5
45.1
共398兲
共298兲
共298兲
共375兲
A
C
43.6
共416兲
A
43.7
共416兲
A
43.1
共413兲
A
43.4
共413兲
A
43.0
共412兲
A
43.2
共413兲
A
42.9
共412兲
A
42.3
共413兲
A
43.7
共348兲
A, MG
Method
42.0⫾0.2
共298兲
GCC
1,1-dibromodecane
共442– 610兲
62.2
共457兲
A, EST
1,2-dibromodecane
共368 –524兲
67.0
共383兲
A
1,1-dichlorodecane
共415–577兲
56.9
共430兲
A, EST
61.1
67.3
73.1
共456兲
共298兲
50.2
共379兲
A, EST
共298兲
GS
共464兲
TGA, DSC
1,10-dichlorodecane
共441–520兲
共440–540兲
1,1-difluorodecane
共364 –504兲
ethyl 2-共N,N-diethylamino兲butanoate
共283–313兲
57.3⫾0.2
tetraethyloxamide
63
bis共3-methyl-2-butenyl兲 ether
共383– 413兲
47.8
共2-ethylhexyl兲 vinyl ether
共330– 451兲
44.7
1-butylcyclohexanol
共362– 481兲
55.7
3,7-dimethyl-6-octene-1-ol
共293–333兲
72.6
共373–500兲
65.9
共l兲 menthol
共372– 488兲
59.1
共329– 485兲
58.2
1-共1-methylcyclohexyl兲-1-propanol
共396 – 420兲
55.4
2-共1-methylcyclohexyl兲-2-propanol
共393– 418兲
53.0
共Z兲 3-decen-1-ol
共323–363兲
78.7
共398兲
共345兲
A
共377兲
A
共308兲
共388兲
A
A
共387兲
共344兲
A
共408兲
A
共405兲
A
共298兲
CGC
CAS registry number
Reference
关71/28兴
关872-05-9兴
关87/5兴
关77/1兴
关71/28兴
关50/6兴
关20348-51-0兴
关87/5兴
关20063-97-2兴
关87/5兴
关19398-86-8兴
关87/5兴
关19150-21-1兴
关87/5兴
关19398-88-0兴
关87/5兴
关19398-89-1兴
关87/5兴
关7433-78-5兴
关87/5兴
关7433-56-9兴
关87/5兴
关4485-13-6兴
关87/5兴关55/11兴
关79/17兴
关59104-80-2兴
关87/5兴关56/16兴
关70/14兴关99/16兴
关28467-71-2兴
关87/5兴关47/5兴
关70/14兴
关3162-62-7兴
关87/5兴关56/16兴
关70/14兴
关2162-98-3兴
关99/16兴
关98/20兴
关91/2兴
关62127-43-9兴
关87/5兴关56/16兴
关70/14兴关99/16兴
关96/20兴
关14288-05-2兴
关02/36兴
关89/8兴
关103-44-6兴
关87/5兴
关5445-30-7兴
关87/5兴
关106-22-9兴
关87/5兴
关87/5兴
关2216-51-5兴
关87/5兴
关47/5兴
关87/5兴
关27331-02-8兴
关87/5兴
关10340-22-4兴
关00/10兴关94/13兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
730
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O
C10H20O2
C10H20O2
C10H20O2
C10H20O2
C10H20O2
C10H20O2
C10H20O2
C10H20O2
C10H20O2
C10H20O2
C10H20O2
C10H20O2
Compound
共Temperature range/K兲
共E兲 3-decen-1-ol
共323–363兲
共Z兲 4-decen-1-ol
共323–363兲
共E兲 4-decen-1-ol
共323–363兲
共Z兲 5-decen-1-ol
共323–363兲
共E兲 5-decen-1-ol
共323–363兲
共Z兲 6-decen-1-ol
共323–363兲
共E兲 6-decen-1-ol
共323–363兲
共Z兲 7-decen-1-ol
共323–363兲
共E兲 7-decen-1-ol
共323–363兲
共Z兲 8-decen-1-ol
共323–363兲
共E兲 8-decen-1-ol
共323–363兲
2-decanone
共317– 484兲
共357–560兲
共358 –568兲
2,2,5,5-tetramethyl-3-hexanone
decanal
共308 –353兲
共288 –333兲
共293–358兲
共324 – 482兲
2-heptyl-1,3-dioxolane
共318 – 453兲
2-共1-ethylpentyl兲-1,3-dioxolane
共333– 453兲
4-hexyl-1,3-dioxane
共318 – 453兲
3-pentyl-4-hydroxytetrahydropyran
共383– 453兲
2-butoxy-3-hexanone
共333– 418兲
hydroxycitronellal
共283–333兲
octyl acetate
共334 – 417兲
共345– 472兲
ethyl octanoate
共382– 412兲
共382– 412兲
共330– 480兲
2-ethylhexylacetate
共333– 472兲
isopentyl isovalerate
共341– 479兲
共300– 467兲
neopentyl pivalate
共280–310兲
共280–310兲
methyl nonanoate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
78.8
共298兲
CGC
79.6
共298兲
CGC
80.3
共298兲
CGC
80.3
共298兲
CGC
80.6
共298兲
CGC
80.3
共298兲
CGC
80.6
共298兲
CGC
80.8
共298兲
CGC
81.1
共298兲
CGC
81.6
共298兲
CGC
81.5
共298兲
CGC
51.7
55.1
60.9⫾0.5
44.6
共332兲
共372兲
共298兲
共487兲
A
48.8⫾0.2
共298兲
C
60.5
57.3
57.3
60.4⫾0.3
56.3
共298兲
共303兲
共308兲
共298兲
共339兲
CGC
A
A
62.0
共333兲
A
55.3
共348兲
A
56.9
共333兲
A
72.6
共398兲
A
39.5
共348兲
A
75.3
共298兲
A, ME
61.7
54.9
47.8
共298兲
共349兲
共360兲
GC
A
A
52.5⫾0.2
59.5⫾1.3
53.2
共397兲
共298兲
共345兲
EB
EB
A
50.1
共348兲
A
46.4
47.2
共356兲
共315兲
A
49.1⫾0.5
48.9⫾0.5
共295兲
共298兲
GS
GS
GCC
CAS registry number
Reference
关10339-60-3兴
关00/10兴关94/13兴
关57074-37-0兴
关00/10兴关94/13兴
关10339-62-5兴
关00/10兴关94/13兴
关51652-47-2兴
关00/10兴关94/13兴
关56578-18-8兴
关00/10兴关94/13兴
关68760-59-8兴
关00/10兴关94/13兴
关38421-92-0兴
关00/10兴关94/13兴
关16504-66-8兴
关00/10兴关94/13兴
关52957-12-7兴
关00/10兴关94/13兴
关83799-67-1兴
关00/10兴关94/13兴
关83799-68-2兴
关00/10兴关94/13兴
关693-54-9兴
关87/5兴关47/5兴
关87/5兴
关79/7兴
关75/8兴
关868-91-7兴
关70/18兴
关112-31-2兴
关96/7兴关00/10兴
关87/5兴
关87/5兴
关81/18兴
关87/5兴关47/5兴
关4359-57-3兴
关87/5兴
关4359-47-1兴
关87/5兴
关2244-85-1兴
关87/5兴
关61827-60-9兴
关87/5兴
关87/5兴
关107-75-5兴
关87/5兴关55/8兴
关112-14-1兴
关97/22兴
关87/5兴
关87/5兴
关106-32-1兴
关91/7兴
关91/7兴
关87/5兴
关103-09-3兴
关87/5兴
关659-70-1兴
关87/5兴
关47/5兴
关5340-26-1兴
关99/4兴
关99/4兴
关1731-84-6兴
ENTHALPIES OF VAPORIZATION
731
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H20O2
C10H20O3
C10H20O3
C10H20O3
C10H20O4
C10H20O5
C10H21Br
C10H21Cl
C10H21F
C10H21I
C10H21N
C10H21NO
C10H22
C10H22
Compound
共Temperature range/K兲
共364 – 439兲
decanoic acid 共capric acid兲
共398 –543兲
共305–323兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
57.4
56.7⫾0.3
61.6⫾0.4
57.7⫾0.7
62.0⫾0.5
62.0⫾0.4
55.6
共350兲
共364兲
共298兲
共298兲
共298兲
共298兲
共379兲
GC
GCC
C
A, EST
76.4
88.6
71.4
共413兲
共314兲
共418兲
A
ME, TE
I
共388兲
A
共389兲
A
共388兲
A
共408兲
A
共298兲
共298兲
CGC
C
共406兲
共398兲
A, EST
propyl 3-butoxypropionate
共373– 473兲
44.2
pentyl 3-ethoxypropionate
共374 – 498兲
54.1
methyl 3-hexyloxypropionate
共373– 473兲
55.1
diethylene glycol monobutyl ether acetate
共393–520兲
57.7
1,4,7,10,13-pentaoxacyclopentadecane 共15-crown-5兲
75.7⫾1.7
79.6⫾0.3
1-bromodecane
共391–545兲
56.1
共383–570兲
56.6
1-chlorodecane
64.0⫾0.2
共379–530兲
54.4
共359– 499兲
56.2
1-fluorodecane
共342–503兲
50.4
1-iododecane
共407–571兲
57.4
共397–598兲
58.1
N,␣-dimethylcyclohexanethylamine
共270–300兲
50.2
N,N-diethylhexanamide
共373– 443兲
47.7
decane
共337–376兲
46.6
51.1⫾3.9
51.5
50.5
50.1
49.2
共403– 453兲
50.9
共423– 473兲
51.5
51.4
共409–584兲
42.5
共268 – 490兲
48.1
共268 – 490兲
51.4
共252–383兲
53.8
共447–526兲
41.7
共524 – 617兲
38.6
共298 –347兲
50.3
共308 –351兲
49.8⫾1.7
51.4⫾0.1
共243–310兲
55.9
51.4
共373– 443兲
45.3
51.4
共368 – 440兲
45.5
2-methylnonane
共324 – 441兲
46.4⫾0.2
Method
共298兲
共394兲
共374兲
A, DTA
共357兲
A
共422兲
共412兲
A, EST
共285兲
A
共388兲
A
共352兲
共298兲
共299兲
共314兲
共324兲
共334兲
共298兲
共298兲
共298兲
共424兲
共340兲
共298兲
共267兲
共462兲
共539兲
共313兲
GS
CGC
C
C
C
C
CGC
CGC
EB, IPM
EB, IPM
A
A
A
GS
共298兲
共258兲
共298兲
共388兲
共298兲
共383兲
C
MM
共339兲
A
C
CAS registry number
Reference
关02/27兴
关02/27兴
关02/27兴
关87/17兴
关80/5兴
关77/1兴
关87/5兴关63/16兴
关334-48-5兴
关87/5兴
关82/4兴
关43/7兴
关14144-47-9兴
关87/5兴
关14144-36-6兴
关87/5兴
关7419-97-8兴
关87/5兴
关124-17-4兴
关87/5兴
关33100-27-5兴
关00/9兴
关82/9兴
关112-29-8兴
关99/16兴
关87/5兴关61/13兴
关1002-69-3兴
关01/1兴
关99/16兴
关87/5兴关69/5兴
关334-56-5兴
关87/5兴关61/13兴
关2050-77-3兴
关99/16兴
关87/5兴关61/13兴
关101-40-6兴
关87/5兴
关6282-97-9兴
关87/5兴
关124-18-5兴
关02/13兴
关00/9兴
关96/22兴
关96/22兴
关96/22兴
关96/22兴
关95/21兴
关95/21兴
关94/12兴
关92/2兴
关89/1兴
关89/1兴
关87/5兴
关87/5兴
关87/5兴
关86/6兴
关84/12兴
关82/18兴
关73/11兴
关71/28兴
关87/5兴关70/6兴
关47/7兴
关45/2兴
关871-83-0兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
732
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H22
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
47.3⫾0.2
46.2⫾0.2
45.0⫾0.2
51.0
共328兲
共343兲
共358兲
共298兲
C
C
C
47.3⫾0.2
46.2⫾0.2
45.1⫾0.2
50.2
共328兲
共343兲
共358兲
共298兲
C
C
C
49.5
共298兲
47.0⫾0.2
45.9⫾0.2
44.6⫾0.2
49.8
共328兲
共343兲
共358兲
共298兲
49.0
共298兲
48.1
共298兲
48.5
44.1
共298兲
共346兲
47.3
共298兲
49.0
共298兲
48.1
共298兲
44.9⫾0.2
43.6⫾0.2
42.4⫾0.2
48.5
共328兲
共343兲
共358兲
共298兲
49.0
共298兲
49.3
共298兲
47.7
45.2
共298兲
共294兲
48.5
共298兲
48.1
共298兲
48.5
共298兲
47.3
共298兲
48.1
共298兲
48.5
共298兲
48.1
共298兲
47.3
共298兲
48.1
共298兲
47.7
共298兲
47.7
共298兲
Method
3-methylnonane
C10H22
4-methylnonane
C10H22
5-methylnonane
C10H22
3-ethyloctane
C10H22
4-ethyloctane
C10H22
4-propylheptane
C10H22
共331– 430兲
4-isopropylheptane
C10H22
2,2-dimethyloctane
C10H22
2,3-dimethyloctane
C10H22
2,4-dimethyloctane
C10H22
2,5-dimethyloctane
C10H22
2,6-dimethyloctane
C10H22
2,7-dimethyloctane
C10H22
共279– 433兲
3,3-dimethyloctane
C10H22
3,4-dimethyloctane
C10H22
3,5-dimethyloctane
C10H22
3,6-dimethyloctane
C10H22
4,4-dimethyloctane
C10H22
4,5-dimethyloctane
C10H22
2-methyl-3-ethylheptane
C10H22
2-methyl-4-ethylheptane
C10H22
2-methyl-5-ethylheptane
C10H22
3-methyl-3-ethylheptane
C10H22
3-methyl-4-ethylheptane
C10H22
3-methyl-5-ethylheptane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
C
C
A, MG
C
C
C
A
CAS registry number
Reference
关84/8兴
关84/8兴
关84/8兴
关71/28兴
关5911-04-6兴
关84/8兴
关84/8兴
关84/8兴
关71/28兴
关17301-94-9兴
关61/30兴
关15869-85-9兴
关84/8兴
关84/8兴
关84/8兴
关71/28兴
关5881-17-4兴
关71/28兴
关15869-86-0兴
关71/28兴
关3178-29-8兴
关71/28兴
关87/5兴关55/11兴
关71/28兴
关15869-87-1兴
关71/28兴
关7146-60-3兴
关71/28兴
关4032-94-4兴
关84/4兴
关84/4兴
关84/4兴
关71/28兴
关15869-89-3兴
关71/28兴
关2051-30-1兴
关71/28兴
关1072-16-8兴
关71/28兴
关87/5兴关47/5兴
关4110-44-5兴
关71/28兴
关15869-92-8兴
关71/28兴
关15869-93-9兴
关71/28兴
关15869-94-0兴
关71/28兴
关15869-95-1兴
关71/28兴
关15869-96-2兴
关71/28兴
关14676-29-0兴
关71/28兴
关52896-88-5兴
关71/28兴
关13475-78-0兴
关71/28兴
关17302-01-1兴
关71/28兴
关52896-89-6兴
关71/28兴
ENTHALPIES OF VAPORIZATION
733
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C10H22
4-methyl-3-ethylheptane
C10H22
4-methyl-4-ethylheptane
C10H22
2,2,3-trimethylheptane
C10H22
2,2,4-trimethylheptane
C10H22
2,2,5-trimethylheptane
C10H22
2,2,6-trimethylheptane
C10H22
2,3,3-trimethylheptane
C10H22
2,3,4-trimethylheptane
C10H22
2,3,5-trimethylheptane
C10H22
2,3,6-trimethylheptane
C10H22
2,4,4-trimethylheptane
C10H22
2,4,5-trimethylheptane
C10H22
2,4,6-trimethylheptane
C10H22
2,5,5-trimethylheptane
C10H22
3,3,4-trimethylheptane
C10H22
3,3,5-trimethylheptane
C10H22
3,4,4-trimethylheptane
C10H22
3,4,5-trimethylheptane
C10H22
2-methyl-3-isopropylhexane
C10H22
3,3-diethylhexane
C10H22
3,4-diethylhexane
C10H22
2,2-dimethyl-3-ethylhexane
C10H22
2,2-dimethyl-4-ethylhexane
C10H22
2,3-dimethyl-3-ethylhexane
C10H22
2,3-dimethyl-4-ethylhexane
C10H22
2,4-dimethyl-3-ethylhexane
C10H22
2,4-dimethyl-4-ethylhexane
C10H22
2,5-dimethyl-3-ethylhexane
C10H22
3,3-dimethyl-4-ethylhexane
C10H22
3,4-dimethyl-3-ethylhexane
C10H22
2,2,3,3-tetramethylhexane
C10H22
2,2,3,4-tetramethylhexane
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
47.7
共298兲
关71/28兴
48.1
共298兲
关61/30兴
47.2
共298兲
46.9
共298兲
45.6
共298兲
46.0
共298兲
46.4
共298兲
46.9
共298兲
47.3
共298兲
47.3
共298兲
47.3
共298兲
45.2
共298兲
46.9
共298兲
46.4
共298兲
46.0
共298兲
46.9
共298兲
46.0
共298兲
46.4
共298兲
47.3
共298兲
关61/30兴
关52896-92-1兴
关71/28兴
关14720-74-2兴
关71/28兴
关20291-95-6兴
关71/28兴
关1190-83-6兴
关71/28兴
关52896-93-2兴
关71/28兴
关52896-95-4兴
关71/28兴
关20278-85-7兴
关71/28兴
关4032-93-3兴
关71/28兴
关4032-92-2兴
关71/28兴
关20278-84-6兴
关71/28兴
关2613-61-8兴
关71/28兴
关1189-99-7兴
关71/28兴
关20278-88-0兴
关71/28兴
关7154-80-5兴
关71/28兴
关20278-88-0兴
关71/28兴
关20278-89-1兴
关71/28兴
46.4
共298兲
47.3
共298兲
47.7
共298兲
46.0
共298兲
45.2
共298兲
46.9
共298兲
46.9
共298兲
46.9
共298兲
46.4
共298兲
46.4
共298兲
46.4
共298兲
46.4
共298兲
45.2
共298兲
Method
CAS registry number
Reference
关71/28兴
关17302-02-2兴
关71/28兴
关19398-77-7兴
关71/28兴
关20291-91-2兴
关71/28兴
关52896-99-8兴
关71/28兴
关52897-00-4兴
关71/28兴
关52897-01-5兴
关71/28兴
关7220-26-0兴
关71/28兴
关52897-03-7兴
关71/28兴
关52897-04-8兴
关71/28兴
关52897-05-9兴
关71/28兴
关52897-06-0兴
关71/28兴
关13475-81-5兴
关71/28兴
关52897-08-2兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
734
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C10H22
2,2,3,5-tetramethylhexane
C10H22
2,2,4,4-tetramethylhexane
C10H22
2,2,4,5-tetramethylhexane
C10H22
2,2,5,5-tetramethylhexane
C10H22
2,3,3,4-tetramethylhexane
C10H22
2,3,3,5-tetramethylhexane
C10H22
2,3,4,4-tetramethylhexane
C10H22
2,3,4,5-tetramethylhexane
C10H22
3,3,4,4-tetramethylhexane
C10H22
2,4-dimethyl-3-isopropylpentane
C10H22
2-methyl-3,3-diethylpentane
C10H22
2,2,3-trimethyl-3-ethylpentane
C10H22
2,2,4-trimethyl-3-ethylpentane
C10H22
2,3,4-trimethyl-3-ethylpentane
C10H22
2,2,3,3,4-pentamethylpentane
C10H22
2,2,3,4,4-pentamethylpentane
C10H22O
hexyl tert-butyl ether
C10H22O
pentyl tert-amyl ether
C10H22O
ethyl tert-octyl ether
C10H22O
dipentyl ether
共373– 460兲
共423– 480兲
butyl hexyl ether
C10H22O
C10H22O
C10H22O
diisopentyl ether
共353–393兲
共417– 470兲
共291– 447兲
1-decanol
共281–327兲
共281–327兲
共278 –378兲
共373– 423兲
共353–393兲
共283–388兲
共349– 410兲
共405–528兲
共474 –529兲
共298 –325兲
共400–529兲
共378 –504兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
45.6
共298兲
45.2
共298兲
43.5
共298兲
44.4
共298兲
43.5
共298兲
46.4
共298兲
45.2
共298兲
46.0
共298兲
46.0
共298兲
42.3
共298兲
45.6
共298兲
47.3
共298兲
46.0
共298兲
44.8
共298兲
46.4
共298兲
45.2
共298兲
43.5
共298兲
53.2
共298兲
关71/28兴
关52897-09-3兴
关71/28兴
关51750-65-3兴
关71/28兴
关16747-42-5兴
关71/28兴
关1071-81-4兴
关71/28兴
关52897-10-6兴
关71/28兴
关52897-11-7兴
关71/28兴
关52897-12-8兴
关71/28兴
关52897-15-1兴
关71/28兴
关5171-84-6兴
关71/28兴
关13475-79-1兴
关71/28兴
关52897-16-2兴
关71/28兴
关52897-17-3兴
关71/28兴
关52897-18-4兴
关71/28兴
关52897-19-5兴
关71/28兴
关16747-44-7兴
关71/28兴
关16747-45-8兴
关71/28兴
关69775-79-7兴
关U/2兴关02/32兴
53.5
共298兲
关U/2兴关02/32兴
45.3⫾0.3
共298兲
46.2
45.6
共388兲
共451兲
A
53.2⫾0.1
共298兲
C
51.4
41.4
47.6
共298兲
共443兲
共306兲
CGC
79.5
80.9
81.1
81.7
79.3
75.4
71.6
62.6
53.9
78.2⫾0.8
81.5⫾0.8
81.5⫾0.8
77.6
63.5
69.5
共309兲
共298兲
共293兲
共298兲
共298兲
共336兲
共364兲
共420兲
共489兲
共323兲
共298兲
共298兲
共313兲
共415兲
共393兲
GS
GS
关U/2兴关02/32兴
关693-65-2兴
关87/5兴
关68/13兴
关54459-71-1兴
关85/2兴
关544-01-4兴
关95/21兴
关68/13兴
关87/5兴关47/5兴
关112-30-1兴
关01/3兴
关01/3兴
关99/11兴
关95/21兴
关94/13兴关00/10兴
关92/14兴
关87/5兴
关87/5兴
关87/5兴
关79/6兴
关79/6兴
关77/1兴
关73/26兴
关87/5兴关70/2兴
关69/5兴
Method
A
CGC
CGC
A
A
A
C
C
C
A, EB
DTA
CAS registry number
Reference
ENTHALPIES OF VAPORIZATION
735
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C10H22O
C10H22O2
C10H22O2
C10H22O2
C10H22O2
C10H22O2
C10H22O2
C10H22O3
C10H22O3
C10H22O4
C10H22O5
C10H22S
C10H22S
C10H22S
C10H22S
C10H22S
C10H22S2
C10H22S2
C10H23N
C10H23N
C10H23N
C10H23N2
C10H23N3
C10H24NO3 PS
C10H24N4
Compound
共Temperature range/K兲
共298 –325兲
共364 – 461兲
(dl) 3,7-dimethyl-1-octanol
共341– 467兲
ethylene glycol dibutyl ether
共356 – 476兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
77.6
69.6
共311兲
共379兲
ME
79.1
共356兲
A
55.9
58.8⫾0.1
共371兲
共298兲
A
C
共351兲
A
共396兲
A
共318兲
A
共420兲
A, EB
ethylene glycol diisobutyl ether
共336 – 456兲
46.1
ethylene glycol mono共2-ethylhexyl兲 ether
共381–502兲
56.5
acetaldehyde dibutyl ether
共303– 464兲
47.3
3,4-diethyl-3,4-hexanediol
共405–507兲
54.7
3-ethyl-3-hydroxymethyl-2-heptanol
共338 –500兲
63.4
diethylene glycol monohexyl ether
共406 –531兲
62.7
dipropylene glycol monobutyl ether
共337–500兲
63.2
tripropylene glycol monomethyl ether
共308 –515兲
58.7
tetraethylene glycol dimethyl ether 共tetraglyme兲
76.9⫾2.6
共419–553兲
58.0
1-ethylthiooctane
共384 –545兲
63.9⫾0.6
1-decanethiol
共390–544兲
56.4
共283–293兲
58.6
共413–534兲
54.6
65.5⫾0.5
2-decanethiol
共380–534兲
54.6
diisopentyl sulfide
共339–366兲
57.9
共340–365兲
56.9
dipentyl sulfide
共346 –365兲
U66.3
共346 –366兲
58.7
共346 –366兲
57.5
dipentyl disulfide
共410–571兲
59.8
71.1⫾0.2
1,10-decanedithiol
共434 –571兲
72.3
decylamine
共410–506兲
52.4
N,N-dimethyloctylamine
共284 –323兲
54.0⫾0.5
共371–517兲
50.2
dipentylamine
共379–527兲
51.2
N-methyl-N-共-dimethylamino兲hydrazone acetone
共288 –315兲
62.3
关2-共dimethylamino兲ethyl兴methylhydrazone-2-propanone
共288 –315兲
62.3
O,O-diethyl-S-关2-共diethylamino兲ethyl兴thiophosphate
共358 – 407兲
94.5
tetrakis共dimethylamino兲ethylene
共358 – 485兲
53.9⫾0.5
Method
共353兲
共421兲
A
共352兲
A
共323兲
A
共298兲
共434兲
CGC
A
共298兲
EB
共405兲
共288兲
共428兲
共298兲
A
A
C
共395兲
共352兲
共352兲
A
C
共356兲
共356兲
共358兲
A
EB
共425兲
共298兲
C
共449兲
A
共425兲
A, EST
共303兲
共386兲
A
共394兲
A
共301兲
共301兲
A
共373兲
A
共298兲
EB
CAS registry number
Reference
关65/15兴
关58/2兴
关106-21-8兴
关87/5兴
关112-48-1兴
关87/5兴
关70/17兴
关5669-09-0兴
关87/5兴
关1559-35-9兴
关87/5兴
关871-22-7兴
关87/5兴
关6931-71-1兴
关87/5兴关79/10兴
关87/5兴
关112-59-4兴
关87/5兴
关24083-03-2兴
关87/5兴关47/5兴
关20324-33-8兴
关87/5兴
关143-24-8兴
关00/9兴
关87/5兴
关3698-94-0兴
关96/3兴
关143-10-2兴
关99/16兴
关87/5兴
关87/5兴
关77/1兴
关13402-60-3兴
关99/16兴
关544-02-5兴
关87/5兴关99/16兴
关62/17兴
关872-10-6兴
关99/16兴
关87/5兴
关62/17兴
关112-51-6兴
关99/16兴
关85/2兴
关1191-67-9兴
关87/5兴关99/16兴
关43/6兴
关2016-57-1兴
关87/5兴关56/17兴
关7378-99-6兴
关97/21兴
关87/5兴
关2050-92-2兴
关87/5兴
关80/20兴
关67752-90-3兴
关87/5兴
关78-53-5兴
关87/5兴关99/16兴
关996-70-3兴
关97/7兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
736
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C11F21N3
C11F22
C11F22
C11F24O2
C11H4 Cl5 NO2
C11H5 BrCl3 NO2
C11H5 BrCl3 NO2
C11H5 BrCl3 NO2
C11H5 Cl4 NO2
C11H7 N3
C11H8 N4
C11H8 O2
C11H8 O2
C11H9 Cl
C11H9 N
C11H9 N
C11H10
C11H10
C11H11Cl3 O3
C11H11N
C11H11N
C11H12Cl2 O3
C11H12Cl2 O3
C11H12Cl2 O4
C11H12O
C11H12O2
C11H12O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
2,2,2-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-N⬘-关2,2,2-trifluoro-1-共trifluoromethyl兲-1关关2,2,2-trifluoro-1-共trifluoro-methyl兲ethylidene兴amino兴ethyl兴 ethanimidamide
39.8
perfluoro共1-methyl-4-tert-butylcyclohexane兲 共mix cis⫹trans兲
共345– 442兲
45.8
共360兲
perfluoro共1-methyl-4-tert-butylcyclohexane兲 共isomer not specified兲
54.1⫾0.5
共298兲
EB
octadecafluoro-1,9-bis共trifluoromethoxy兲nonane
共293–353兲
43.0
共323兲
2,2,4-trichloro-5-关共3,4-dichlorophenyl兲amino兴-4-cyclopentene-1,3-dione
共453– 483兲
87.5
共468兲
GC
2,2,4-trichloro-5-关共2-bromophenyl兲amino兴-4-cyclopentene-1,3-dione
共453– 483兲
67.5
共468兲
GC
2,2,4-trichloro-5-关共3-bromophenyl兲amino兴-4-cyclopentene-1,3-dione
共453– 483兲
78.1
共468兲
GC
2,2,4-trichloro-5-关共4-bromophenyl兲amino兴-4-cyclopentene-1,3-dione
共453– 483兲
82.9
共468兲
GC
2,2,4-trichloro-5-关共4-chlorophenyl兲amino兴-4-cyclopentene-1,3-dione
共453– 483兲
86.2
共468兲
GC
2,2-dicyano-1-phenylpropionitrile
共318 –388兲
66.9
B
1,1,2,2-tetracyano-4-methyl-4-cyclohexene
82.0⫾2.1
MG
1-naphthoic acid
共457–573兲
97.2
共472兲
A
2-naphthoic acid
共463–582兲
98.9
共478兲
A
1-共chloromethyl兲naphthalene
共423–565兲
59.8
共494兲
共407– 447兲
U90.2
共422兲
A
2-phenylpyridine
68.7⫾4.6
共298兲
CGC
3-phenylpyridine
64.5⫾4.5
共298兲
CGC
1-methylnaphthalene
共323– 473兲
62.4
共298兲
GC
共485–595兲
50.0
共500兲
共259–388兲
63.3
共274兲
共424 –536兲
49.6
共455兲
共424 –536兲
45.9
共525兲
共278 –313兲
57.5
共293兲
A, GS
57.3⫾0.4
共298兲
C
共415–526兲
52.3
共430兲
A, GS
2-methylnaphthalene
共424 –535兲
48.4
共465兲
共424 –535兲
46.4
共505兲
共423–515兲
51.2
共438兲
A, GS
2,4,5-trichlorophenoxyacetic acid, propyl ester
共444 –573兲
83.2
共459兲
A
2,4-dimethylquinoline
共458 –543兲
56.3
共473兲
A
2,6-dimethylquinoline
共461–541兲
55.7
共476兲
A
2,4-dichlorophenoxyacetic acid, isopropyl ester
共460–573兲
69.5
共475兲
A
2,4-dichlorophenoxyacetic acid, propyl ester
共444 –573兲
77.3
共459兲
A
2,4-dichlorophenoxyacetic acid, 3-hydroxypropyl ester
共463– 483兲
72.1
共473兲
A
2-ethylidiene-3-phenylpropanal
共333–374兲
73.6
共348兲
A
benzyl methacrylate
共347– 431兲
70.5
共362兲
A
ethyl cinnamate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关57731-09-6兴
关75/42兴
关75169-50-5兴
关99/16兴
关81/23兴
关99/16兴
关77765-41-4兴
关80/25兴
关73373-59-8兴
关80/25兴
关73373-60-1兴
关80/25兴
关73373-61-2兴
关80/25兴
关73373-63-4兴
关80/25兴
关6023-46-7兴
关94/5兴
关71/37兴
关86-55-5兴
关87/5兴
关93-09-4兴
关87/5兴
关86-52-2兴
关99/16兴
关87/5兴
关1009-89-5兴
关00/3兴
关1008-88-4兴
关00/3兴
关92-12-0兴
关02/18兴
关92/2兴
关88/12兴
关81/1兴
关81/1兴
关87/5兴关79/11兴
关74/28兴
关87/5兴关55/7兴
关91-57-6兴
关81/1兴
关81/1兴
关87/5兴关55/7兴
关1928-40-1兴
关87/5兴关99/16兴
关1198-37-4兴
关87/5兴
关877-43-0兴
关87/5兴
关94-11-1兴
关87/5兴关99/16兴
关1928-61-1兴
关87/5兴关99/16兴
关28191-20-0兴
关87/5兴关99/16兴
关87/5兴
关2495-37-6兴
关87/5兴
关103-36-6兴
ENTHALPIES OF VAPORIZATION
737
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C11H12O2
C11H12O2
C11H12O2
C11H12O3
C11H12O3
C11H12O3
C11H13Cl3
C11H14
C11H14
C11H14
C11H14
C11H14
C11H14
C11H14
C11H14
C11H14Cl2
C11H14N2 O4
C11H14O
C11H14O
C11H14O
C11H14O
C11H14O2
C11H14O2
C11H14O2
C11H14O2
C11H14O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共453–544兲
57.8
1-phenyl-1,3-pentanedione
共371–550兲
64.6
1-phenyl-4,7-dioxaspiro关2.4兴heptane
共307–333兲
71.3⫾0.7
共288 –302兲
69.6⫾0.7
4-carboxymethylpentacyclo关 4.3.0.0.2,50 4,7兴 nonane
共303–343兲
80.0⫾1.7
benzoylacetic acid, ethyl ester
共380–538兲
72.1
myristicin
共368 –553兲
61.2
2-piperonylpropanal
共373– 423兲
74.5
4-tert-butyl-2,3,6-trichlorotoluene
共423–570兲
62.7
1,1-dimethylindane
共313–348兲
共313– 467兲
共387– 467兲
4,6-dimethylindane
共313– 467兲
共313–363兲
共415– 467兲
4,7-dimethylindane
共313– 470兲
共313–363兲
共417– 470兲
4-isopropylstyrene
共408 – 478兲
5-methyl-1,2,3,4-tetrahydronaphthalene
共416 –508兲
6-methyl-1,2,3,4-tetrahydronaphthalene
共411–502兲
2,4,5-trimethylstyrene
共352– 490兲
2,4,6-trimethylstyrene
共362– 483兲
4-tert-butyl-2,5-dichlorotoluene
共395–538兲
Mean temperature
(T m /K)
Method
共468兲
A
共386兲
A
共298兲
GS
GS
共333兲
CAS registry number
Reference
关87/5兴
关5331-64-6兴
关87/5兴
关39522-76-4兴
关02/32兴
关98/21兴
关40317-63-3兴
关84/12兴
关94-02-0兴
关87/5兴
关607-91-0兴
关87/5兴
共395兲
A
共383兲
A
共388兲
A
共438兲
A
50.1
50.5
45.9
共328兲
共328兲
共402兲
A
A
A
56.9
56.4
50.3
共328兲
共328兲
共430兲
A
A
A
54.7
56.9
50.6
共328兲
共328兲
共432兲
A
A
A
48.5
共423兲
A
53.4
共431兲
A
53.7
共426兲
A
56.4
共367兲
A
50.9
共377兲
A
57.0
共410兲
A
共298兲
GS
共345兲
A
共358兲
A
共346兲
A
关87/5兴
关582-62-7兴
关87/5兴关47/5兴
共367兲
A
关87/5兴关47/5兴
GS
关98/21兴
共306兲
A
共394兲
共452兲
共358兲
BG
BG
A
共373兲
A
共393兲
BG
关87/5兴
关120-50-3兴
关88/2兴
关88/2兴
关87/5兴
关93-16-3兴
关87/5兴关47/5兴
关136-60-7兴
关88/2兴
3-nitro-共4-nitrophenyl兲pentane
共321–358兲
88.0⫾0.8
tert-butyl phenyl ketone
共330– 493兲
55.5
2-ethyl-3-phenylpropanal
共343–388兲
64.6
isobutyl phenyl ketone
共331–501兲
55.7
2,3,5-trimethylacetophenone
共352–557兲
57.9
1,1-dimethoxy-2-phenylcyclopropane
共278 –313兲
63.9⫾0.6
3-acetoxy-1-phenylpropane
共293–333兲
74.3
butyl benzoate
共374 – 474兲
63.2
共374 – 474兲
55.7
共343– 405兲
59.1
1,2-dimethoxy-4-共1-propenyl兲benzene
共358 –521兲
61.9
isobutyl benzoate
共370– 467兲
60.4
关87/5兴
关61468-36-8兴
关87/5兴关73/15兴
关99/16兴
关4912-92-9兴
关87/5兴
关87/5兴
关87/5兴
关1685-82-1兴
关87/5兴
关87/5兴
关87/5兴
关6682-71-9兴
关87/5兴
关87/5兴
关87/5兴
关2055-40-5兴
关87/5兴
关2809-64-5兴
关87/5兴
关1680-51-9兴
关87/5兴
关3937-24-4兴
关87/5兴关49/18兴
关769-25-5兴
关87/5兴关49/18兴
关61468-35-7兴
关87/5兴关73/15兴
关99/16兴
关97/5兴
关938-16-9兴
关87/5兴关47/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
738
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C11H14O2
C11H14O2
C11H14O3
Compound
共Temperature range/K兲
共370– 467兲
共291–300兲
共338 –510兲
ethyl 2-phenylpropionate
共293–329兲
共293–329兲
1-共4-methoxyphenyl兲-2-butanone
共373– 443兲
butyl 4-hydroxybenzoate
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
54.4
58.1
57.1
共449兲
共295兲
共353兲
BG
A
A
63.2⫾0.3
64.0⫾0.3
共311兲
共298兲
GS
GS
62.6
共388兲
A
关88/2兴
关87/5兴
关87/5兴关47/5兴
关2510-99-8兴
关99/2兴
关99/2兴
关53917-01-4兴
关87/5兴
TGA
关01/20兴
关87/5兴
关42597-10-4兴
关87/5兴关73/15兴
关99/16兴
关42525-65-2兴
关87/5兴关76/22兴
关4096-20-2兴
关98/12兴
关98/12兴
关1696-17-9兴
关87/5兴
关69/1兴
72.2
C11H14O3
C11H15Cl
C11H15N
C11H15N
C11H15NO
C11H15NO
C11H15NO
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16
C11H16O
C11H16O
2-piperonylpropanol
共373– 443兲
4-tert-butyl-2-chlorotoluene
共372–503兲
84.8
共388兲
A
54.0
共387兲
A
共317兲
A
共303兲
共298兲
GS
GS
共388兲
共389兲
A
2-phenylethylazetidine
共302–333兲
62.2
N-phenylpiperidine
共284 –323兲
64.0⫾0.4
共284 –323兲
64.3⫾0.4
N,N-diethylbenzamide
共373– 403兲
56.5
共374 – 405兲
53.2
共4R,5R兲-3,4-dimethyl-5-phenyl-1,3-oxazolidine
共293–303兲
50.0⫾1.3
共4S,5R兲-3,4-dimethyl-5-phenyl-1,3-oxazolidine
共293–303兲
52.4⫾0.9
tetracyclo关 6,2,1,02,7,03,5兴 undecane
55.3⫾0.3
pentylbenzene
55.3
55.1
(dl) 2-phenylpentane
共302– 466兲
50.3
1-tert-butyl-3-methylbenzene
共279–314兲
51.4⫾0.6
51.3⫾0.6
1-tert-butyl-4-methylbenzene
共279–314兲
52.3⫾0.5
52.2⫾0.6
4-tert-butyltoluene
共342– 465兲
49.1
3,5-diethyltoluene
共307– 474兲
49.6
1-ethyl-3-isopropylbenzene
共301– 466兲
48.8
1-ethyl-4-isopropylbenzene
共304 – 469兲
49.4
2-ethyl-1,3,5-trimethylbenzene
共312– 481兲
52.6
3-ethyl-1,2,4-trimethylbenzene
共347– 488兲
61.3
5-ethyl-1,2,4-trimethylbenzene
共317– 481兲
56.4
pentamethylbenzene
共338 –503兲
57.8
2-sec-butyl-4-methylphenol
共413–548兲
58.4
共383–523兲
59.0
共383–523兲
58.0
共383–523兲
55.8
共383–523兲
51.4
2-tert-butyl-4-methylphenol
共327–358兲
63.0⫾0.3
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
共298兲
关98/3兴
共298兲
关98/3兴
关1777-44-2兴
关96/18兴
关538-68-1兴
关94/11兴
关71/28兴
关2719-52-0兴
关87/5兴
关1075-38-3兴
关98/19兴
关98/19兴
关98-51-1兴
关98/19兴
关98/19兴
关98-15-1兴
关87/5兴关73/15兴
关2050-24-0兴
关87/5兴关47/5兴
关4920-99-4兴
关87/5兴关47/5兴
关4218-48-8兴
关87/5兴关47/5兴
关3982-67-0兴
关87/5兴
关18262-85-6兴
关87/5兴
关17851-27-3兴
关87/5兴关47/5兴
关700-12-9兴
关87/5兴
关51528-17-7兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关2409-55-4兴
关99/18兴
共298兲
C
共298兲
共298兲
共317兲
A
共296兲
共298兲
GS
共296兲
共298兲
GS
共357兲
A
共322兲
A
共316兲
A
共319兲
A
共327兲
A
共362兲
A
共332兲
A
共353兲
A
共428兲
共373兲
共398兲
共423兲
共473兲
A
共343兲
GS
ENTHALPIES OF VAPORIZATION
739
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C11H16O
C11H16O
C11H16O
C11H16O
C11H16O
C11H16O
C11H16O
C11H16O
C11H16O
C11H16O
C11H16O
C11H16O2
C11H16O2
C11H16O2
C11H16O2
C11H16O2
C11H16O5
C11H16O5
C11H17Cl3 OS
C11H17NO
Compound
共Temperature range/K兲
共385–517兲
共343–507兲
共343–507兲
共343–507兲
共343–507兲
2-tert-butyl-5-methylphenol
共296 –343兲
共378 – 490兲
共383–518兲
2-tert-butyl-6-methylphenol
共308 –343兲
共375–505兲
4-tert-butyl-2-methylphenol
共291–333兲
共347–520兲
共275–297兲
共347–532兲
共347–532兲
共347–532兲
共347–532兲
共347–532兲
2-ethyl-3-phenyl-1-propanol
共348 –393兲
2-共2-pentyl兲phenol
共397–501兲
共397–501兲
4-pentylphenol
共423–563兲
4-tert-pentylphenol
共297–333兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
65.7⫾0.3
58.9
57.7
55.7
52.6
48.5
共298兲
共400兲
共348兲
共373兲
共423兲
共473兲
65.9⫾0.3
67.2⫾0.3
59.8
53.0
共320兲
共298兲
共393兲
共398兲
GS
62.2⫾0.5
63.8⫾0.5
55.2
共326兲
共298兲
共390兲
GS
71.3⫾0.6
72.1⫾0.6
61.5
75.7
55.7
53.9
53.2
50.9
46.7
共312兲
共298兲
共362兲
共286兲
共348兲
共373兲
共398兲
共423兲
共473兲
GS
70.9
共363兲
A
74.4
59.6
共413兲
共412兲
EB
60.9
共438兲
A
64.2⫾0.2
65.3⫾0.2
58.2
共329兲
共298兲
共400兲
GS
共388兲
A
共305兲
共298兲
GS
GS
共298兲
GS
共296兲
共298兲
GS
GS
共418兲
A
共438兲
A, GC
共298兲
GS
共298兲
GS
GS
共385–548兲
5-phenyl-1-pentanol
共373– 430兲
58.2
共1-propoxyethyl兲benzene
共288 –321兲
56.4⫾0.2
共288 –321兲
56.7⫾0.2
共1-isopropoxyethyl兲benzene
共278 –313兲
55.4⫾0.3
cumyl ethyl ether
共278 –313兲
54.8⫾0.5
共278 –313兲
54.7⫾0.5
2-tert-butyl-4-methoxyphenol
共403– 463兲
54.4
1,3-dihydroxy-4-pentylbenzene
共423– 488兲
84.9
phenyldiethoxymethane
共283–329兲
62.8⫾0.6
1,1-dimethoxy-1-phenylpropane
共288 –328兲
58.9⫾0.3
共288 –328兲
57.9⫾0.3
tert-pentylcatechol 共isomer not specified兲
共398 – 473兲
58.2
ethylcamphoric acid anhydride
共391–571兲
70.8
共1-methylallyl兲关1-共allyloxycarbonyl兲ethyl兴carbonate
共368 –508兲
60.2
2,3,3-trichloro-2-propenethioic acid, O-octyl ester
共443– 483兲
74.2
2-共dimethylamino兲-1-phenyl-1-propanone
Method
A
A
A
A
A
A
A
共436兲
CAS registry number
Reference
关99/18兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关88-60-8兴
关99/18兴
关99/18兴
关87/5兴
关87/5兴
关2219-82-1兴
关99/19兴
关99/19兴
关87/5兴
关98-27-1兴
关99/18兴
关99/18兴
关87/5兴
关87/5兴关60/1兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关3968-87-4兴
关87/5兴
关87-26-3兴
关90/5兴
关93/10兴
关14938-35-3兴
关87/5兴
关80-46-6兴
关99/18兴
关99/18兴
关87/5兴
关10521-91-2兴
关87/5兴
关01/16兴
关01/16兴
关65757-61-1兴
关02/29兴关02/38兴
关1712-74-9兴
关01/18兴
关01/18兴
关121-00-6兴
关87/5兴
关533-24-4兴
关87/5兴关75/24兴
关774-48-1兴
关02/32兴
关25310-92-3兴
关02/32兴
关98/21兴
关65/21兴
共406兲
A
关87/5兴关47/5兴
共383兲
A
关87/5兴
关76619-96-0兴
关80/24兴
GC
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
740
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C11H18O
C11H18O2
C11H18O2
C11H18O2
C11H18O2
C11H18O4
C11H18O5
C11H18O6
C11H18O6
C11H19NO2
C11H19O5
C11H20
C11H20
C11H20Cl4
C11H20Cl4
C11H20O
C11H20O2
C11H20O2
C11H20O2
C11H20O2
C11H20O2
C11H20O2
C11H20O2
C11H20O2
C11H20O3
C11H20O4
C11H20O4
C11H20O4
C11H20O5
C11H20O5
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共293–333兲
64.8⫾1.2
6-methyl-3-isopropenyl-5-hepten-2-one
共390– 420兲
49.7
borneol formate
共320– 487兲
52.7
3,7-dimethyl-cis-2,6-octadienyl formate
共330– 498兲
58.1
3,7-dimethyl-trans-2,6-octadienyl formate
共334 –503兲
57.1
isoborneol formate
共383– 441兲
53.5
1,1-cyclopentanedicarboxylic acid, diethyl ester
共293–323兲
66.8⫾0.4
4-oxononanedioic acid, dimethyl ester
共394 –559兲
72.7
1,1,1-tris共ethoxycarbonyl兲methane
共298 –338兲
74.1⫾0.4
1,1,1-tris共methoxycarbonyl兲pentane
共298 –338兲
81.0⫾0.4
ethyl bis共isopropyl兲cyanoacetate
共284 –319兲
65.0⫾0.9
N-acetyl-共l兲-glutamic acid, diethyl ester
共403–503兲
67.2
spiro关5.5兴undecane
56.1
cyclopentylcyclohexane
共383– 488兲
47.9
1,1,1,11-tetrachloroundecane
共303–353兲
92.5
1,2,10,11-tetrachloroundecane
78.7
cycloundecanone
共363– 433兲
60.3
共448 –501兲
51.8
2,2,6,6-tetramethyl-3,5-heptanedione
59.5
(dl) 2-ethylhexyl acrylate
共323– 489兲
55.3
formic acid, 3-para-menthol ester
共320– 492兲
52.0
2-hexyl-4,7-dihydro-1,3-dioxepin
共333– 453兲
66.0
octyl acrylate
共331–500兲
56.2
oxa-2-cyclododecanone 共undecanolactone兲
共365–387兲
57.7⫾0.8
共365–387兲
66.2⫾1.3
共353– 413兲
70.5
10-undecenoic acid
共387–548兲
70.6
3,3-dimethyl-1,5-dioxaspiro关5.5兴undecane
共283–323兲
59.0⫾0.6
hexyl levulinate
共363–540兲
66.6
59.1
(dl) hexyl 2-acetoxypropionate
共322–517兲
70.3
azelaic acid, dimethyl ester
共413–540兲
63.6
diethyl diethylmalonate
共386 – 491兲
68.5
hexyl关1-共methoxycarbonyl兲ethyl兴carbonate
共371–538兲
65.9
propyl关1-共butoxycarbonyl兲ethyl兴carbonate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共298兲
GS
关94/3兴
共345兲
A
共349兲
A
共398兲
A
关89/8兴
关7492-41-3兴
关87/5兴关47/5兴
关2142-94-1兴
关87/5兴
关105-86-2兴
关87/5兴关47/5兴
关1200-67-5兴
关87/5兴
GS
关98/22兴
A
关87/5兴
GS
关95/8兴
GS
关95/8兴
关62391-95-1兴
关95/11兴
关1446-19-1兴
关87/5兴
关180-43-8兴
关75/14兴
关1606-08-2兴
关87/5兴
关3922-34-7兴
关87/5兴关99/16兴
共405兲
共335兲
共409兲
共298兲
GS
共418兲
A
共298兲
C
共398兲
A
共318兲
A
共378兲
共463兲
A
A, EB
共298兲
共338兲
A
共335兲
A
共348兲
A
共346兲
A
共376兲
共298兲
共368兲
MM
MM
A
共402兲
A
关98/20兴
关878-13-7兴
关87/5兴
关87/5兴关76/10兴
关1118-71-4兴
关78/18兴
关103-11-7兴
关87/5兴关47/5兴
共378兲
共479兲
A
共337兲
A
共428兲
A
共401兲
A
关87/5兴关47/5兴
关61732-96-5兴
关87/5兴
关2499-59-4兴
关87/5兴关47/5兴
关1725-03-7兴
关91/7兴
关91/7兴
关87/5兴
关112-38-9兴
关87/5兴关47/5兴
关关7-7-29-9兴
关98/21兴关02/32兴
关24431-34-3兴
关87/5兴关47/5兴
关31/1兴
关77008-66-3兴
关87/5兴
关1732-10-1兴
关87/5兴
关77-25-8兴
关87/5兴
共386兲
A
关87/5兴
GS
ENTHALPIES OF VAPORIZATION
741
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C11H21N
C11H21N
C11H21N
C11H21NO
C11H22
Compound
共Temperature range/K兲
共330– 463兲
2-butyl-2-methylhexanenitrile
共298 –388兲
undecanonitrile
共355–534兲
N-cyclohexylpiperidine
共288 –328兲
共288 –328兲
N-hexanoylpiperidone
共383– 433兲
pentylcyclohexane
C11H22
hexylcyclopentane
C11H22
1-undecene
共283–312兲
C11H22
C11H22
C11H22
C11H22
C11H22
C11H22
C11H22
C11H22
C11H22
C11H22Cl2
C11H22N2
C11H22O
C11H22O
C11H22O
共378 – 473兲
cis 2-undecene
共333–393兲
trans 2-undecene
共333–393兲
cis 3-undecene
共333–393兲
trans 3-undecene
共333–393兲
cis 4-undecene
共333–393兲
trans 4-undecene
共333–393兲
cis 5-undecene
共333–393兲
trans 5-undecene
共333–393兲
3-methyl-3-propyl-1-heptene
共263–293兲
1,1-dichloroundecane
共430–500兲
共430–500兲
bis共piperidino兲methane
共283–322兲
共283–322兲
1-hexylcyclopentanol
共387–509兲
cyclohexyl tert-amyl ether
2-undecanone
共461–538兲
共393–523兲
C11H22O
共335– 433兲
共341– 497兲
6-undecanone
共343–383兲
共343–383兲
共388 –543兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
66.4
共345兲
A
59.8⫾0.4
GS
63.7
71.1⫾0.1
共370兲
共298兲
A
C
59.9⫾0.6
60.5⫾0.6
共308兲
共298兲
GS
GS
66.3
共398兲
A
52.9⫾0.5
54.1⫾0.3
53.9
55.0
共298兲
共298兲
共298兲
共298兲
55.9
共298兲
54.3⫾0.3
55.4
48.2
共298兲
共298兲
共393兲
GS
53.2
共348兲
A
53.0
共348兲
A
52.3
共348兲
A
52.0
共348兲
A
51.6
共348兲
A
52.1
共348兲
A
51.4
共348兲
A
51.8
共348兲
A
52.8⫾1.0
50.9
51.5
共278兲
共298兲
共298兲
HSA
59.5
71.7
共445兲
共298兲
61.9⫾0.9
62.2⫾0.9
共303兲
共298兲
GS
GS
59.2
共402兲
A
54.3⫾0.2
共298兲
51.5
69.7⫾0.5
67.0⫾0.4
56.2
46.4
61.6
61.9
共476兲
共298兲
共298兲
共408兲
共506兲
共350兲
共356兲
59.0
61.8
55.3
共298兲
共298兲
共403兲
GCC
A
CGC
A
GCC
C
A
A, EB
CGC
CGC
A
CAS registry number
Reference
关87/5兴
关80606-32-2兴
关94/5兴
关2244-07-1兴
关87/5兴
关77/5兴
关3319-01-5兴
关98/12兴
关98/12兴
关15770-38-4兴
关87/5兴
关4292-92-6兴
关87/17兴
关78/16兴
关75/12兴
关71/28兴
关4457-00-5兴
关71/28兴
关821-95-4兴
关00/7兴
关71/28兴
关87/5兴关50/6兴
关821-96-5兴
关87/5兴
关693-61-8兴
关87/5兴
关821-97-6兴
关87/5兴
关1002-68-2兴
关87/5兴
关821-98-7兴
关87/5兴
关693-62-9兴
关87/5兴
关764-96-5兴
关87/5兴
关764-97-6兴
关87/5兴
关95/27兴
关95/27兴
关95/27兴
关822-01-5兴
关99/16兴关87/12兴
关87/12兴关91/2兴
关880-09-1兴
关02/28兴
关02/28兴
关36633-49-5兴
关87/5兴
关02/32兴
关112-12-9兴
关87/5兴
关79/7兴
关79/1兴
关87/5兴关75/8兴
关75/8兴
关87/5兴关66/12兴
关47/5兴
关927-49-1兴
关95/21兴
关95/21兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
742
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
50.4
63.5⫾0.5
45.8
共476兲
共298兲
共500兲
A
GCC
关87/5兴
关79/7兴
关75/6兴
52.9⫾0.2
undecanal
共323–343兲
69.3
共288 – 400兲
60.2
heptyl butyrate
共384 – 498兲
58.7
4,5-dimethyl-2-hexyl-1,3-dioxolane
共333– 453兲
65.6
4-heptyl-1,3-dioxane
共353– 453兲
64.4
3-hexyl-4-hydroxytetrahydro-2H-pyran
共383– 453兲
73.6
isopropyl caprylate
共338 – 420兲
57.5
共338 – 419兲
58.3
methyl decanoate 共methyl caprate兲
62.0
62.9⫾0.1
66.1⫾0.2
共373– 433兲
66.9
共453–543兲
49.9
66.3⫾0.5
66.8⫾0.6
共379–500兲
57.1
共324 –370兲
63.0
2-octyl-1,3-dioxolane
共333– 453兲
60.3
propyl caprylate
共343–500兲
58.8
共343– 426兲
58.2
nonyl acetate
66.8
共313–358兲
67.0
undecanoic acid
共393–557兲
81.3
共310–332兲
90.7⫾2.0
共303–308兲
97.9⫾6.3
butyl 2-butoxypropionate
共373–398兲
40.8
butyl 3-butoxypropionate
共343– 493兲
57.6
hexyl 3-ethoxypropionate
共373–514兲
56.7
octyl lactate
共328 –528兲
71.5
1-bromoundecane
共407–564兲
58.8
共398 –591兲
59.5
共298兲
C
共298兲
共303兲
CGC
A
共399兲
A
共348兲
A
共368兲
A
共398兲
A
共353兲
共353兲
A
关71/31兴
关112-44-7兴
关96/7兴关00/10兴
关87/5兴
关5870-93-9兴
关87/5兴
关6454-22-4兴
关87/5兴
关2244-84-0兴
关87/5兴
关41277-7502兴
关87/5兴
关5458-59-3兴
关87/5兴
关48/8兴关84/9兴
关110-42-9兴
关02/27兴
关02/27兴
关02/27兴
关97/28兴
关93/9兴
关80/5兴
关77/1兴
关87/5兴关63/16兴
关52/13兴
关5432-30-4兴
关87/5兴
关624-13-5兴
关87/5兴
关48/8兴关84/9兴
关143-13-5兴
关97/22兴
关97/13兴关00/10兴
关112-37-8兴
关87/5兴
关82/4兴
关68/20兴
关38611-89-1兴
关87/5兴
关14144-48-0兴
关87/5兴
关14144-37-7兴
关87/5兴
关51191-33-4兴
关87/5兴
关693-67-4兴
关99/16兴
关87/5兴关61/13兴
关70/14兴
关2473-03-2兴
关84/9兴关91/2兴
关87/5兴关69/5兴
关506-05-8兴
关87/5兴关61/13兴
关70/14兴
关4282-44-4兴
关99/16兴
关87/5兴关61/13兴
关70/14兴
关6225-08-7兴
Compound
共Temperature range/K兲
共461–513兲
C11H22O
C11H22O
C11H22O2
C11H22O2
C11H22O2
C11H22O2
C11H22O2
C11H22O2
C11H22O2
C11H22O2
C11H22O2
C11H22O2
C11H22O3
C11H22O3
C11H22O3
C11H22O3
C11H23Br
C11H23Cl
C11H23F
C11H23I
C11H23NO
共383–514兲
2,2,6,6-tetramethyl-4-heptanone
1-chloroundecane
共370–520兲
共374 –519兲
1-fluoroundecane
共373–523兲
1-iodoundecane
共422–589兲
共412– 618兲
N,N-dimethyl nonamide
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
共350兲
共337兲
共298兲
共298兲
共498兲
共298兲
共298兲
共394兲
共339兲
GC
GC
GCC
C
A, EST
MG, OM
共348兲
A
共358兲
共358兲
A
共298兲
共298兲
GC
共408兲
共323兲
共305兲
A
ME, TE
共385兲
A
共358兲
A
共388兲
A
共343兲
A
共422兲
共413兲
A, EST
65.9
59.4
共298兲
共389兲
A, DTA
52.3
共388兲
A, EST
60.1
60.9
共437兲
共427兲
A, EST
CAS registry number
Reference
ENTHALPIES OF VAPORIZATION
743
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C11H23NO2
C11H23NO2
C11H24
Compound
共Temperature range/K兲
共411–509兲
N,N-dibutyl lactamide
共393– 418兲
N-octyl lactamide
共428 – 468兲
undecane
共278 – 470兲
C11H24
C11H24
C11H24
C11H24
C11H24
C11H24
C11H24
C11H24
C11H24O
共378 – 470兲
2-methyldecane
共273–353兲
共379– 463兲
共273–293兲
3-methyldecane
共340– 464兲
4-methyldecane
共339– 460兲
5-methyldecane
共334 – 452兲
2,3-dimethylnonane
共336 – 460兲
2,4-dimethylnonane
共334 – 452兲
2,4,6-trimethyloctane
共325– 442兲
2,4,7-trimethyloctane
decyl methyl ether
共341– 429兲
共341– 471兲
共341– 471兲
共341– 471兲
C11H24O
ethyl nonyl ether
C11H24O
propyl octyl ether
C11H24O
butyl heptyl ether
C11H24O
heptyl tert-butyl ether
C11H24O
hexyl tert-amyl ether
C11H24O
propyl tert-octyl ether
C11H24O
1-undecanol
共313–354兲
共313–354兲
共373– 423兲
共353–393兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
69.3
共426兲
A
88.3
共405兲
A
96.3
共443兲
A
56.2
55.4
54.5
54.0
53.1
56.6
60.0
56.3
49.1
共299兲
共314兲
共324兲
共334兲
共344兲
共298兲
共293兲
共298兲
共393兲
C
C
C
C
C
55.5
47.4
51.9
50.6
49.5
55.4
共288兲
共394兲
共328兲
共343兲
共358兲
共283兲
A
A
C
C
C
IPM
46.5
共355兲
A
46.6
50.4
49.2
48.5
共354兲
共343兲
共358兲
共368兲
A
C
C
C
46.0
共349兲
A
45.1
共351兲
A
46.8
共349兲
A
44.9
共340兲
A
47.6
46.4
45.3
共328兲
共343兲
共358兲
C
C
C
56.9
57.0
62.6
45.5
62.3⫾0.3
共356兲
共356兲
共298兲
共489兲
共298兲
A
60.3⫾0.1
共298兲
C
58.8⫾0.1
共298兲
C
58.2⫾0.1
共298兲
C
56.6
共298兲
关U/2兴关02/32兴
58.6
共298兲
关U/2兴关02/32兴
50.1⫾0.3
共298兲
79.5
84.7
86.8
85.6
共336兲
共298兲
共298兲
共298兲
关U/2兴关02/32兴
关112-42-5兴
关01/3兴
关01/3兴
关95/21兴
关94/13兴关00/10兴
A
C
GS
GS
CGC
CGC
CAS registry number
Reference
关87/5兴
关6288-16-0兴
关87/5兴
关87/5兴
关1120-21-4兴
关96/22兴
关96/22兴
关96/22兴
关96/22兴
关96/22兴
关94/12兴
关87/5兴
关71/28兴
关55/7兴
关6975-98-0兴
关87/5兴
关87/5兴
关84/8兴
关84/8兴
关84/8兴
关74/11兴
关13151-34-3兴
关87/5兴
关2847-72-5兴
关87/5兴
关84/8兴
关84/8兴
关84/8兴
关13151-35-4兴
关87/5兴
关2884-06-2兴
关87/5兴
关17302-24-8兴
关87/5兴
关62016-37-9兴
关87/5兴
关62016-38-0兴
关84/8兴
关84/8兴
关84/8兴
关7289-52-3兴
关87/5兴
关87/5兴关76/2兴
关76/2兴
关76/2兴
关75/3兴
关16979-32-1兴
关85/2兴
关29379-41-7兴
关85/2兴
关71112-90-8兴
关85/2兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
744
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C11H24O
C11H24O
C11H24O
C11H24O4
C11H24S
C11H24S2
C11H25N
C11H26NO2 PS
C12Cl10
C12F10
C12F18
C12F18
C12F18
C12F27N
Compound
共Temperature range/K兲
共293–342兲
共283–393兲
共393–523兲
共393–534兲
共393–516兲
2-undecanol
共344 –505兲
2,5-dimethyl-3-isopropyl-3-hexanol
共321– 458兲
2,2,4-trimethyl-3-isopropyl-3-pentanol
共321– 458兲
tripropylene glycol, monoethyl ether
共317–521兲
1-undecanethiol
共405–563兲
1,11-undecanedithiol
共444 –582兲
C12H3 Br7 O
C12H3 Cl7
C12H3 Cl7
C12H3 Cl7
C12H3 Cl7
C12H4 Br6 O
C12H4 Br6 O
C12H4 Cl6
C12H4 Cl6
Mean temperature
(T m /K)
83.6
83.5
68.7
68.5
72.3
共318兲
共298兲
共408兲
共408兲
共408兲
61.4
共359兲
57.2
共336兲
67.1
共336兲
60.0
共332兲
59.3
共420兲
75.1
共459兲
undecylamine
共428 –527兲
55.1
共443兲
methylthiophosphonic acid, O-ethyl-S-关2-共N,N-diisopropylamino兲-ethyl兴 ester
共280–315兲
101.0
共295兲
decachlorobiphenyl
共343–393兲
103.4
共368兲
共343– 453兲
103.4
共398兲
decafluorobiphenyl
共453– 608兲
49.9
共468兲
hexakis共trifluoromethyl兲bicyclo关2.2.0兴hexa-2,5-diene
共293–343兲
41.4
共308兲
Method
A
A
A
A
A, EST
A
GC
GC
DSC
A
hexakis共trifluoromethyl兲tetracyclo关 2.2.0.02,60 3,5兴 hexane
共313–353兲
33.1
共328兲
A
hexakis共trifluoromethyl兲tricyclo关 3.1.0.02,6兴 hex-3-ene
共293–353兲
38.6
共308兲
A
共298兲
共313兲
共386兲
共298兲
C
A
A
共368兲
共398兲
GC
GC
共418兲
GC
CGC
共368兲
GC
共268兲
GC
共298兲
共368兲
CGC
GC
共368兲
GC
perfluorotributylamine
共298 – 450兲
共371–544兲
C12H2 Cl8
⌬ vapH m
共kJ mol⫺1兲
60.3⫾0.1
57.4
51.1
60.4⫾1.2
2,2⬘,3,3⬘,5,5⬘,6,6⬘-octachlorobiphenyl
共343–393兲
92.9
共343– 453兲
92.9
2⬘,3,3⬘,4,4⬘,5,6-heptabromodiphenyl ether
共363– 473兲
115.8
共403– 475兲
121.2
2,2⬘,3,4⬘,5,5⬘,6-heptachlorobiphenyl
共343–393兲
94.0
2,2⬘,3,4,4⬘,5,5⬘-heptachlorobiphenyl
共343–393兲
96.5
2,2⬘,3,3⬘,4,4⬘,6-heptachlorobiphenyl
109.1
共343–393兲
95.9
2,2⬘,3,3⬘,4,4⬘,5-heptachlorobiphenyl
共343–393兲
98.4
2,2⬘,3,4,4⬘,5⬘-hexabromodiphenyl ether
共403– 475兲
114.1
2,2⬘,4,4⬘,5,5⬘-hexabromodiphenyl ether
共363– 473兲
107.6
2,3,3⬘,4,4⬘,5-hexachlorobiphenyl
112.6⫾0.4
共343–393兲
94.8
2,2⬘,4,4⬘,5,5⬘-hexachlorobiphenyl
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CGC
共418兲
GC
共298兲
共368兲
CGC
GC
CAS registry number
Reference
关92/14兴
关99/11兴
关87/5兴
关87/5兴
关73/26兴
关1653-30-1兴
关47/5兴
关57233-26-8兴
关73/26兴
关5457-41-0兴
关73/26兴
关75899-69-3兴
关87/5兴
关5332-52-5兴
关99/16兴
关63476-06-2兴
关87/5兴关43/6兴
关99/16兴
关7307-55-3兴
关87/5兴关56/17兴
关50782-69-9兴
关87/5兴关99/16兴
关2051-24-3兴
关94/6兴
关90/2兴
关434-90-2兴
关96/10兴
关23174-55-2兴
关87/5兴关70/33兴
关99/16兴
关22736-20-5兴
关87/5兴关70/33兴
关99/16兴
关22186-64-7兴
关87/5兴关70/33兴
关99/16兴
关311-89-7兴
关95/20兴
关87/5兴
关87/5兴
关77/13兴关77/20兴
关2136-99-4兴
关94/6兴
关90/2兴
关327185-13-7兴
关01/2兴
关01/11兴
关52663-68-0兴
关94/6兴
关35065-29-3兴
关94/6兴
关52663-71-5兴
关01/1兴
关94/6兴
关35065-30-6兴
关94/6兴
关01/11兴
关68631-49-2兴
关01/2兴
关38380-08-4兴
关01/1兴
关94/6兴
关35065-27-1兴
ENTHALPIES OF VAPORIZATION
745
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C12H5 Cl5
共343–393兲
2,2⬘,3,4⬘,5⬘,6-hexachlorobiphenyl
共343–393兲
2,2⬘,3,4,4⬘,5⬘-hexachlorobiphenyl
共343–393兲
2,2⬘,3,3⬘,4,4⬘-hexachlorobiphenyl
共343–393兲
2,2⬘,3,4,4⬘-pentabromodiphenyl ether
共403– 475兲
2,2⬘,3,3⬘,4-pentabromodiphenyl ether
共363– 473兲
2,2⬘,4,4⬘,5-pentabromodiphenyl ether
共363– 473兲
共405– 475兲
2,2⬘,4,4⬘,6-pentabromodiphenyl ether
共363– 473兲
2,3⬘,4,4⬘,5-pentachlorobiphenyl
共343–393兲
2,3,3⬘,4,4⬘-pentachlorobiphenyl
共343–393兲
2,2⬘,4,5,5⬘-pentachlorobiphenyl
共343–393兲
共343– 453兲
2,2⬘,3,5⬘,6-pentachlorobiphenyl
C12H5 Cl5
2,2⬘,3,6,6⬘-pentachlorobiphenyl
C12H5 Cl5
2,2⬘,4,5⬘,6-pentachlorobiphenyl
C12H5 Cl5
C12H6 Cl4
2,2⬘,3,4,5⬘-pentachlorobiphenyl
共343–393兲
2,2⬘,4,4⬘,5-pentachlorobiphenyl
共343–393兲
2,2⬘,4,4⬘-tetrabromodiphenyl ether
共363– 473兲
共403– 475兲
2,3⬘,4,4⬘-tetrabromodiphenyl ether
共363– 473兲
2,3⬘,4,6-tetrabromodiphenyl ether
共363– 473兲
2,4,4⬘,6-tetrabromodiphenyl ether
共363– 473兲
3,3⬘,4,4⬘-tetrabromodiphenyl ether
共363– 473兲
2,2⬘,3,3⬘-tetrachlorobiphenyl
共343–398兲
2,2⬘,5,5⬘-tetrachlorobiphenyl
共343–398兲
共343– 453兲
2,3⬘,4,4⬘-tetrachlorobiphenyl
共343–398兲
2,3⬘,4⬘,5-tetrachlorobiphenyl
共343–398兲
2,2⬘,4,5⬘-tetrachlorobiphenyl
C12H6 Cl4
2,2⬘,5,6⬘-tetrachlorobiphenyl
C12H4 Cl6
C12H4 Cl6
C12H4 Cl6
C12H5 Br5 O
C12H5 Br5 O
C12H5 Br5 O
C12H5 Br5 O
C12H5 Cl5
C12H5 Cl5
C12H5 Cl5
C12H5 Cl5
C12H6 Br4 O
C12H6 Br4 O
C12H6 Br4 O
C12H6 Br4 O
C12H6 Br4 O
C12H6 Cl4
C12H6 Cl4
C12H6 Cl4
C12H6 Cl4
C12H6 Cl4
C12H7 Br3 O
C12H7 Br3 O
共343–398兲
3,3⬘,4,4⬘-tetrachlorobiphenyl
共343–393兲
2,4,4⬘-tribromodiphenyl ether
共403– 475兲
3,4,4⬘-tribromodiphenyl ether
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
103.5⫾0.1
91.4
共298兲
共368兲
CGC
GC
89.8
共368兲
GC
91.9
共368兲
GC
93.5
共368兲
GC
111.0
CGC
99.1
共418兲
GC
100.3
104.8
共418兲
GC
CGC
101.8
共418兲
GC
89.3
共368兲
GC
91.1
共368兲
GC
86.4
83.7
共368兲
共398兲
GC
GC
92.3⫾0.6
共298兲
CGC
89.6⫾0.2
共298兲
CGC
91.6⫾0.5
共298兲
CGC
87.3
共368兲
GC
86.8
共368兲
GC
92.0
103.1
共418兲
GC
CGC
93.5
共418兲
GC
91.1
共418兲
GC
90.1
共418兲
GC
95.3
共418兲
GC
81.8
共368兲
GC
80.8
79.0
共368兲
共398兲
GC
GC
83.3
共368兲
GC
84.8
共368兲
GC
87.4⫾0.8
共298兲
CGC
84.9⫾0.6
78.8
共298兲
共368兲
CGC
GC
87.2
共368兲
GC
94.1
CGC
CAS registry number
Reference
关01/1兴
关94/6兴
关38380-04-0兴
关94/6兴
关35065-28-2兴
关94/6兴
关38380-07-3兴
关94/6兴
关01/11兴
关327185-11-5兴
关01/2兴
关60348-60-9兴
关01/2兴
关01/11兴
关189084-66-0兴
关01/2兴
关31508-00-6兴
关94/6兴
关32598-14-4兴
关94/6兴
关37680-73-2兴
关94/6兴
关90/2兴
关38379-99-6兴
关01/1兴
关73575-54-9兴
关01/1兴
关60145-21-3兴
关01/1兴
关38380-02-8兴
关94/6兴
关38380-01-7兴
关94/6兴
关5436-43-1兴
关01/2兴
关01/1兴
关189084-61-5兴
关01/2兴
关327185-09-1兴
关01/2兴
关189084-63-7兴
关01/2兴
关93703-48-1兴
关01/2兴
关38444-93-8兴
关94/6兴
关35693-99-3兴
关94/6兴
关90/2兴
关32598-10-0兴
关94/6兴
关32598-11-1兴
关94/6兴
关41464-40-8兴
关01/1兴
关41464-41-9兴
关01/1兴
关94/6兴
关32598-13-3兴
关94/6兴
关01/11兴
关147217-81-0兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
746
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H7 Br3 O
C12H7 Br3 O
C12H7 Br3 O
C12H7 Br3 O
C12H7 Cl2 NO3
C12H7 Cl3
C12H7 Cl3
C12H7 Cl3
C12H7 Cl3
C12H8 Br2 O
C12H8 Br2 O
C12H8 Br2 O
C12H8 Br2 O
C12H8 Br2 O
C12H8 Br2 O
C12H8 Cl2
C12H8 Cl2
C12H8 Cl2
C12H8 Cl2
C12H8 Cl2 O2 S
C12H8 Cl3 NO2
C12H8 Cl3 NO3
C12H8 Cl3 NO3
C12H8 Cl6
C12H8 Cl6
C12H8 O
C12H8 OS
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共363– 473兲
86.7
共418兲
2,4,6-tribromodiphenyl ether
共363– 473兲
85.1
共418兲
2,4⬘,6-tribromodiphenyl ether
共363– 473兲
83.3
共418兲
2⬘,3,4-tribromodiphenyl ether
共363– 473兲
81.0
共418兲
3,3⬘,4-tribromodiphenyl ether
共363– 473兲
86.4
共418兲
2,4-dichlorophenyl 4-nitrophenyl ether
共328 – 403兲
90.4
共343兲
2,4,5-trichlorobiphenyl
共343–393兲
76.6
共368兲
2,4,6-trichlorobiphenyl
共343–393兲
74.4
共368兲
2,4⬘,5-trichlorobiphenyl
共343–398兲
77.7
共368兲
2,2⬘,5-trichlorobiphenyl
80.2⫾0.9
共298兲
2,4-dibromodiphenyl ether
共363– 473兲
75.4
共418兲
3,4-dibromodiphenyl ether
共363– 473兲
77.4
共418兲
3,4⬘-dibromodiphenyl ether
共363– 473兲
77.4
共418兲
4,4⬘-dibromodiphenyl ether
共363– 473兲
78.0
共418兲
2,4⬘-dibromodiphenyl ether
共363– 473兲
76.4
共418兲
2,6-dibromodiphenyl ether
共363– 473兲
73.1
共418兲
2,4-dichlorobiphenyl
75.3⫾1.5
共298兲
共343–393兲
73.5
共368兲
2,5-dichlorobiphenyl
76.8⫾0.4
共298兲
共343–393兲
73.9
共368兲
3,3⬘-dichlorobiphenyl
81.0⫾0.2
共298兲
共343–393兲
75.4
共368兲
4,4⬘-dichlorobiphenyl
81.4⫾0.3
共298兲
共343–393兲
76.0
共368兲
4,4⬘-dichlorodiphenylsulfone
共463–573兲
59.7
共478兲
2,2,4-trichloro-5-关共2-methylphenyl兲amino兴-4-cyclopentene-1,3-dione
共453– 483兲
85.0
共468兲
2,2,4-trichloro-5-关共2-methoxyphenyl兲amino兴-4-cyclopentene-1,3-dione
共453– 483兲
84.6
共468兲
2,2,4-trichloro-5-关共3-methoxyphenyl兲amino兴-4-cyclopentene-1,3-dione
共453– 483兲
63.1
共468兲
Aldrin
共343– 453兲
75.1
共398兲
Dieldrin
共343– 453兲
82.5
共398兲
dibenzofuran
共323– 473兲
66.2
共398兲
共403–559兲
55.1
共418兲
共403– 418兲
66.2
共410兲
phenoxathiin
共365– 640兲
68.7
共400兲
共365– 640兲
66.0
共440兲
共365– 640兲
63.4
共480兲
共365– 640兲
60.8
共520兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
GC
GC
GC
GC
GC
GC
GC
GC
CGC
GC
GC
GC
GC
GC
GC
CGC
GC
CGC
GC
CGC
GC
CGC
GC
GC
GC
GC
GC
GC
GC
A
EB,
EB,
EB,
EB,
IPM
IPM
IPM
IPM
CAS registry number
Reference
关01/2兴
关155999-95-4兴
关01/2兴
关189084-60-4兴
关01/2兴
关147217-78-5兴
关01/2兴
关147217-80-9兴
关01/2兴
关1836-75-5兴
关87/5兴
关15862-07-4兴
关94/6兴
关35693-92-6兴
关94/6兴
关16606-02-3兴
关94/6兴
关36780-65-2兴
关01/1兴
关171977-44-9兴
关01/2兴
关189084-59-1兴
关01/2兴
关83694-71-7兴
关01/2兴
关2050-47-7兴
关01/2兴
关147217-71-8兴
关01/2兴
关51930-04-2兴
关01/1兴
关33284-50-3兴
关01/1兴
关94/6兴
关34883-39-1兴
关01/1兴
关94/6兴
关2050-67-1兴
关01/1兴
关94/6兴
关2050-68-2兴
关01/1兴
关94/6兴
关80-07-9兴
关99/16兴
关77765-39-0兴
关80/25兴
关77765-40-3兴
关80/25兴
关73373-64-5兴
关80/25兴
关309-00-2兴
关90/2兴
关60-57-1兴
关90/2兴
关132-64-9兴
关02/18兴
关87/5兴
关58/23兴
关262-20-4兴
关93/13兴
关93/13兴
关93/13兴
关93/13兴
ENTHALPIES OF VAPORIZATION
747
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H8 S
Compound
共Temperature range/K兲
共365– 640兲
共365– 640兲
dibenzothiophene
共373– 424兲
共424 – 608兲
共385–574兲
C12H9 Cl
共373– 403兲
thianthrene
共429– 460兲
共460–539兲
共395– 639兲
共395– 639兲
共395– 639兲
共395– 639兲
共395– 639兲
共430–593兲
共430–593兲
共428 – 448兲
4-bromobiphenyl
共371–583兲
2-bromodiphenyl ether
共363– 473兲
3-bromodiphenyl ether
共363– 473兲
4-bromodiphenyl ether
共463– 673兲
2-bromo-4-phenylphenol
共373–584兲
2-chlorobiphenyl
C12H9 Cl
共343–393兲
共409–540兲
共306 –350兲
共410–540兲
共362–541兲
3-chlorobiphenyl
C12H9 Cl
共343–393兲
共310–359兲
共341– 402兲
共452–536兲
4-chlorobiphenyl
C12H9 ClO
共343–393兲
共451–536兲
共348 – 409兲
共369–566兲
2-chloro-3-phenylphenol
C12H8 S2
C12H9 Br
C12H9 BrO
C12H9 BrO
C12H9 BrO
C12H9 BrO
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
58.0
55.1
共560兲
共600兲
EB, IPM
EB, IPM
65.6
63.4
69.5
66.8
64.3
61.8
59.3
56.8
54.0
68.0
64.9
61.8
58.7
55.4
51.8
60.1
56.9
55.3
53.6
69.4
共388兲
共439兲
共380兲
共420兲
共460兲
共500兲
共540兲
共580兲
共620兲
共400兲
共450兲
共500兲
共550兲
共600兲
共650兲
共400兲
共590兲
共610兲
共630兲
共385兲
71.2
68.4
72.7
69.9
67.2
64.5
61.7
69.1
68.7
71.1
共444兲
共475兲
共440兲
共480兲
共520兲
共560兲
共600兲
共465兲
共515兲
共438兲
62.2
共386兲
A
63.7
共418兲
GC
65.4
共418兲
GC
64.6
共478兲
A
57.8
共388兲
A
72.1⫾2.0
64.4
57.8
74.5
55.8
61.1
共298兲
共368兲
共424兲
共328兲
共424兲
共377兲
CGC
GC
A
ME
QM
A
74.3⫾1.1
66.6
66.2
69.2
66.0
共298兲
共368兲
共335兲
共372兲
共494兲
CGC
GC
ME
TE
QM
71.6⫾0.7
66.8
65.9
67.8
59.0
共298兲
共368兲
共466兲
共378兲
共384兲
CGC
GC
A
C
C
C
EB,
EB,
EB,
EB,
EB,
IPM
IPM
IPM
IPM
IPM
TE
A
CAS registry number
Reference
关93/13兴
关93/13兴
关132-64-0兴
关99/16兴
关99/16兴
关95/24兴
关95/24兴
关95/24兴
关95/24兴
关95/24兴
关95/24兴
关95/24兴
关91/10兴
关91/10兴
关91/10兴
关91/10兴
关91/10兴
关91/10兴
关87/5兴
关84/3兴
关84/3兴
关84/3兴
关81/2兴
关92-85-3兴
关99/16兴
关99/16兴
关93/13兴
关93/13兴
关93/13兴
关93/13兴
关93/13兴
关83/4兴
关83/4兴
关81/2兴
关92-66-0兴
关87/5兴关47/5兴
关7025-06-1兴
关01/2兴
关6876-00-2兴
关01/2兴
关101-55-3兴
关87/5兴
关92-03-5兴
关87/5兴关47/5兴
关2051-60-7兴
关01/1兴
关94/6兴
关87/5兴
关83/9兴
关75/28兴
关87/5兴关47/5兴
关2051-61-8兴
关01/1兴
关94/6兴
关83/9兴
关83/9兴
关75/28兴
关2051-62-9兴
关01/1兴
关94/6兴
关87/5兴
关83/9兴
关87/5兴关47/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
748
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H9 ClO
C12H9 N
Compound
共Temperature range/K兲
共391–591兲
2-chloro-6-phenylphenol
共393–590兲
carbazole
共525– 631兲
C12H10
共517– 624兲
acenaphthene
共323– 473兲
共368 –552兲
共368 – 413兲
C12H10
C12H10N2
C12H10O
C12H10O
C12H10O
C12H10O
C12H10O
C12H10O2
C12H10O2
C12H10O4 S2
C12H10S
共413–561兲
共420–561兲
biphenyl
共323– 473兲
共495– 688兲
共403– 453兲
共348 – 453兲
共350–578兲
共350–578兲
共350–578兲
共350–578兲
共333–393兲
共390–563兲
共396 – 437兲
共528 –766兲
共342–544兲
trans azobenzene
共436 – 626兲
共376 –566兲
1-acetylnaphthalene
共388 –569兲
2-acetylnaphthalene
共393–574兲
diphenyl ether
共353–393兲
共477–544兲
共477–544兲
共477–544兲
共313–333兲
2-hydroxybiphenyl
共434 –547兲
4-hydroxybiphenyl
共450–581兲
2,2⬘-dihydroxybiphenyl
共444 –598兲
3-phenoxyphenol
共416 – 494兲
diphenyl disulfone
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
65.0
共406兲
67.6
共408兲
A
NA
65.7
共540兲
A
66.0
共532兲
63.9
66.2
54.0
60.3
共398兲
共298兲
共403兲
共383兲
GC
CGC
A
A
61.3
54.3
55.4
共395兲
共466兲
共435兲
I
I
62.5
64.5⫾2.2
66.2
51.2
66.0
59.6
64.9
57.4
60.3
50.4
60.4
57.3
54.9
48.0
59.4
共298兲
共298兲
共298兲
共510兲
共298兲
共363兲
共298兲
共400兲
共360兲
共500兲
共363兲
共405兲
共417兲
共647兲
共357兲
GC
GS
CGC
DSC
CGC
GS
EB
EB
EB
EB
72.8⫾0.7
62.3
共298兲
共391兲
EB
A
65.4
共403兲
A
74.1
共408兲
A
67.1
65.0
48.2
53.0
15.8⫾0.1
共298兲
共298兲
共531兲
共492兲
共298兲
CGC
GS, EB
C
64.2
共323兲
A
94.2
共449兲
A
72.3
共465兲
A
61.7
共459兲
A
69.5
共431兲
A
149.0⫾2.9
共298兲
161.9⫾3.3共sub兲
关Note: Enthalpy of sublimation value incorrectly given in our earlier paper兴7
diphenyl sulfide
共369–566兲
60.5
共384兲
共345– 611兲
67.3
共360兲
共345– 611兲
64.3
共400兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
EST
EST
关87/5兴关47/5兴
关85-97-2兴
关87/5兴关47/5兴
关86-74-8兴
关83/17兴
关87/5兴关23/2兴
关84/9兴
关23/1兴关84/9兴
关83-32-9兴
关02/18兴
关98/11兴
关87/5兴
关87/5兴关75/11兴
关84/9兴
关43/7兴
关23/1兴
关23/1兴关84/9兴
关92-52-4兴
关02/18兴
关01/1兴
关98/11兴
关96/10兴
关95/21兴
关89/9兴
关89/4兴
关89/4兴
关89/4兴
关89/4兴
关89/14兴
关87/5兴
关80/17兴
关57/12兴
关30/4兴关84/9兴
关17082-12-1兴
关96/5兴
关87/5兴关47/5兴
关941-98-0兴
关87/5兴
关93-08-3兴
关87/5兴
关101-84-8兴
关95/21兴
关76/2兴
关76/2兴
关87/5兴关76/2兴
关72/28兴
关65/7兴
关87/5兴关48/11兴
关90-43-7兴
关87/5兴
关92-69-3兴
关87/5兴
关1806-29-7兴
关87/5兴
关713-68-8兴
关87/5兴
关10409-06-0兴
关64/33兴
关64/33兴
EB, IPM
EB, IPM
关139-66-2兴
关99/16兴
关95/24兴
关95/24兴
A
GS
ENTHALPIES OF VAPORIZATION
749
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H10S2
C12H11N
C12H11N
C12H12
C12H12
C12H12
Compound
共Temperature range/K兲
共345– 611兲
共345– 611兲
共345– 611兲
共345– 611兲
共369–566兲
diphenyl disulfide
共405–583兲
共404 –583兲
2-aminobiphenyl
共340– 623兲
共340– 623兲
共340– 623兲
共340– 623兲
共340– 623兲
共340– 623兲
diphenylamine
共381–575兲
共573– 673兲
1,5-dimethylnaphthalene
共323– 473兲
1,6-dimethylnaphthalene
共323– 473兲
1,8-dimethylnaphthalene
共338 – 413兲
C12H12
2,3-dimethylnaphthalene
C12H12
共378 – 408兲
2,6-dimethylnaphthalene
共384 – 418兲
C12H12
C12H12
C12H12N2
C12H12O6
C12H12O6
C12H12O6
C12H13Cl3 O3
C12H14Cl2
C12H14Cl2 O3
C12H14Cl2 O3
Mean temperature
(T m /K)
Method
61.3
58.3
55.3
52.0
58.2
共440兲
共480兲
共520兲
共560兲
共384兲
EB, IPM
EB, IPM
EB, IPM
EB, IPM
A
72.4
78.7⫾2.9
74.4
共420兲
共298兲
共419兲
68.6
65.1
61.8
58.5
55.2
51.7
共400兲
共440兲
共480兲
共520兲
共560兲
共600兲
64.1
54.2
共396兲
共588兲
A
A
64.1
共398兲
GC
63.6
共398兲
GC
62.8
共353兲
A
64.8
共336兲
60.9⫾0.7
60.0
共380兲
共393兲
A
57.3
共399兲
A
57.3
54.8
52.2
49.5
46.6
58.5
共400兲
共440兲
共480兲
共520兲
共560兲
共384兲
A
共408兲
A, GS
共398兲
共284兲
共301兲
共408兲
GC
共414兲
A
共468兲
A, GS
共399兲
共458兲
C
A, GS
共458兲
A
共475兲
A
EB,
EB,
EB,
EB,
EB,
EB,
IPM
IPM
IPM
IPM
IPM
IPM
2,7-dimethylnaphthalene
共369– 400兲
C12H12
⌬ vapH m
共kJ mol⫺1兲
1-ethylnaphthalene
共393–565兲
57.3
2-ethylnaphthalene
共323– 473兲
64.7
共269–398兲
69.3
共286 –319兲
61.9
共393–565兲
56.7
1,1-diphenylhydrazine
共399–596兲
68.8
1,2,3-benzenetricarboxylic acid, trimethyl ester
共453–513兲
72.5
1,2,4-benzenetricarboxylic acid, trimethyl ester
78.5⫾0.4
共443– 493兲
61.1
1,3,5-benzenetricarboxylic acid, trimethyl ester
共443–513兲
75.4
2,4,5-trichlorophenoxyacetic acid, butyl ester
共460–573兲
87.3
cyclohexyl-3,4-dichlorobenzene
共383– 488兲
64.7
2,4-dichlorophenoxyacetic acid, butyl ester
共444 –573兲
76.3
2,4-dichlorophenoxyacetic acid, sec-butyl ester
A
A
共398兲
共459兲
A
CAS registry number
Reference
关95/24兴
关95/24兴
关95/24兴
关95/24兴
关87/5兴关49/5兴
关882-33-7兴
关99/16兴
关62/16兴
关87/5兴关47/5兴
关90-41-5兴
关91/14兴
关91/14兴
关91/14兴
关91/14兴
关91/14兴
关91/14兴
关122-39-4兴
关87/5兴关47/5兴
关87/5兴
关571-61-7兴
关02/18兴
关575-43-9兴
关02/18兴
关569-41-5兴
关87/5兴关75/11兴
关84/9兴
关77/22兴
关581-40-8兴
关88/16兴
关87/5兴
关581-42-0兴
关87/5兴关75/11兴
关84/9兴
关582-16-1兴
关93/11兴
关93/11兴
关93/11兴
关93/11兴
关93/11兴
关87/5兴关75/11兴
关84/9兴
关1127-76-0兴
关87/5兴关79/11兴
关939-27-5兴
关02/18兴
关88/12兴
关87/5兴
关87/5兴
关530-50-7兴
关87/5兴关47/5兴
关2672-57-3兴
关87/5兴关63/13兴
关28904-30-5兴
关98/6兴
关87/5兴关63/13兴
关2672-58-4兴
关87/5兴
关93-79-8兴
关87/5兴
关81/20兴
关94-80-4兴
关87/5兴关99/16兴
关94-79-1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
750
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H14Cl2 O4
C12H14Cl2 O4
C12H14N2 O5
C12H14O2
C12H14O3
C12H14O4
C12H14O4
C12H15N
C12H16
C12H16
C12H16
C12H16
C12H16O2
C12H16O2
C12H16O2
C12H16O3
C12H16O3
C12H16O4
C12H17NO
C12H17NO
C12H17NO2
C12H18
C12H18
C12H18
C12H18
C12H18
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共444 –573兲
74.2
2,4-dichlorophenoxyacetic acid, 2-ethoxyethyl ester
共443–503兲
63.5
2,4-dichlorophenoxyacetic acid, 4-hydroxybutyl ester
共443–503兲
72.1
2-cyclohexyl-4,6-dinitrophenol
共405–565兲
88.6
ethyl cis-2-phenylcyclopropanecarboxylate
70.7⫾0.6
1-acetoxy-2-methoxy-4-allylbenzene 共eugenol acetate兲
共374 –555兲
63.1
1,3-benzodioxole 共apiol兲
共389–558兲
70.6
diethyl phthalate
74.6
共345– 453兲
77.9
共421–570兲
59.1
共307–333兲
86.8
81.1⫾0.8
共381–567兲
65.9
N,N-diallyl aniline
共421–513兲
54.8
cyclohexylbenzene
共283– 462兲
60.4
共421–513兲
51.3
59.9⫾0.3
dicyclohexadiene
共377–505兲
77.9
2,5-diethylstyrene
共322– 496兲
52.2
1-isopropenyl-4-isopropylbenzene
共403– 479兲
50.9
pentyl benzoate
共395– 492兲
85.9
isopentyl benzoate
共345–535兲
51.6
ethyl 2-phenylbutyrate
共404 – 489兲
56.0
pentyl salicylate
共402–540兲
66.5
isopentyl salicylate
共287–329兲
73.0
benzo-12-crown-4
82.7⫾2.3
N-butylacetanilide
共443– 653兲
60.2
N,N-diethyl-2-phenylacetamide
共404 – 460兲
82.8
1-nitro-2,6-diisopropylbenzene
共308 –343兲
66.9⫾0.6
68.4⫾0.6
1-cis-5-trans-9-trans-cyclododecatriene
共344 –387兲
49.9
共400– 423兲
60.0
共426 –503兲
47.8
1-trans-5-trans-9-cis-cyclododecatriene
共286 –373兲
68.0
hexylbenzene
60.2
共274 – 463兲
61.6
60.0
1,2-diisopropylbenzene
共388 – 476兲
48.9
1,3-diisopropylbenzene
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共459兲
A
共458兲
A
共458兲
A
共420兲
A
共298兲
C
共389兲
A
共404兲
A
共426兲
共360兲
共436兲
共310兲
共298兲
共396兲
BG
A
A
GS
GCC
共436兲
A
共298兲
共436兲
共298兲
A
C
共329兲
A
共337兲
A
共418兲
A
共410兲
A
共360兲
A
共419兲
A
共417兲
A
共302兲
A, ME
共298兲
CGC
共458兲
A
共419兲
A
共326兲
共298兲
GS
共359兲
共411兲
共441兲
A
A
A
共301兲
A
共298兲
共289兲
共298兲
共403兲
A
CAS registry number
Reference
关87/5兴关99/16兴
关74944-83-5兴
关87/5兴
关36227-43-7兴
关87/5兴
关131-89-5兴
关87/5兴关47/5兴
关98/17兴
关93-28-7兴
关87/5兴关47/5兴
关523-80-8兴
关87/5兴
关84-66-2兴
关88/17兴
关87/5兴
关87/5兴
关82/1兴
关80/5兴
关47/5兴
关6247-00-3兴
关87/5兴
关827-52-1兴
关93/10兴
关87/5兴
关78/7兴
关87/5兴
关2715-29-9兴
关87/5兴关47/5兴
关2388-14-9兴
关87/5兴
关2049-96-9兴
关87/5兴
关94-46-2兴
关87/5兴关47/5兴
关94-46-2兴
关87/5兴
关2050-08-0兴
关87/5兴
关87-20-7兴
关87/5兴关55/8兴
关14174-08-4兴
关00/9兴
关91-49-6兴
关87/5兴
关2431-96-1兴
关87/5兴关69/1兴
关00/15兴
关00/15兴
关4904-61-4兴
关87/5兴
关87/5兴
关87/5兴
关706-31-0兴
关87/5兴
关1077-16-3兴
关94/11兴
关93/10兴
关71/28兴
关577-55-9兴
关87/5兴
关99-62-7兴
ENTHALPIES OF VAPORIZATION
751
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H18
C12H18
C12H18
C12H18
C12H18
C12H18
C12H18
C12H18Cl2 NOPS
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
Compound
共Temperature range/K兲
共283–318兲
共283–318兲
共387– 477兲
1,4-diisopropylbenzene
共366 –530兲
共366 –530兲
共366 –530兲
共366 –530兲
共283–318兲
共283–318兲
共393– 485兲
共393– 485兲
1,3-dimethyl-5-tert-butylbenzene
共284 –318兲
共253– 443兲
hexamethylbenzene
共443–537兲
1,2,4-triethylbenzene
共319– 491兲
1,3,5-triethylbenzene
共371–534兲
1,2,4-trimethyl-5-isopropylbenzene
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
56.0⫾0.8
56.2⫾0.8
48.9
共301兲
共298兲
共402兲
GS
GS
A
50.7⫾0.2
46.3⫾0.3
43.0⫾0.5
39.3⫾0.9
56.3⫾0.3
56.5⫾0.3
47.6
48.9
共400兲
共440兲
共480兲
共520兲
共301兲
共298兲
共408兲
共408兲
EB
EB
EB
EB
GS
GS
A
56.5⫾0.6
56.6⫾0.6
59.8
共301兲
共298兲
共268兲
GS
56.8
共458兲
A
51.2
共334兲
A
59.2⫾0.3
共298兲
EB
64.9
共298兲
2-isopropenyl-1-methyl-1-vinyl-3-cyclohexane
共348 – 404兲
47.8
共363兲
A
P-共chloromethyl兲-N,-共1-methylpropyl兲amidothiophosphonic acid, O-共2-chloro-4-methylphenyl兲 ester
共309–363兲
62.6
共324兲
A
共1-butoxyethyl兲benzene
共278 –318兲
59.8⫾0.3
共298兲
GS
R,S 共1-sec-butoxyethyl兲benzene
共296 –332兲
58.7⫾0.5
共298兲
GS
S,S 共1-sec-butoxyethyl兲benzene
共297–332兲
59.1⫾0.5
共298兲
GS
propyl cumyl ether
共278 –325兲
59.1⫾0.2
共302兲
GS
共278 –325兲
59.3⫾0.2
共298兲
GS
benzyl pentyl ether
共363–512兲
50.8
共378兲
A
2,4-diisopropylphenol
共395–528兲
58.4
共410兲
A
2,4-diisopropylphenol
共293–328兲
67.9⫾0.3
共310兲
GS
68.7⫾0.3
共298兲
2,3-dimethyl-4-tert-butylphenol
共418 –523兲
60.2
共433兲
A
2,3-dimethyl-6-tert-butylphenol
共412–525兲
60.0
共427兲
2,4-dimethyl-6-tert-butylphenol
共304 –333兲
67.2⫾0.8
共318兲
GS
68.4⫾0.8
共298兲
共388 –522兲
58.4
共403兲
A
共344 –535兲
54.4
共348兲
共344 –535兲
52.7
共373兲
共344 –535兲
51.7
共398兲
共344 –535兲
49.7
共423兲
共344 –535兲
45.4
共473兲
2,5-dimethyl-4-tert-butylphenol
共408 –538兲
61.7
共423兲
A
共361–548兲
62.0
共373兲
共361–548兲
59.4
共398兲
共361–548兲
57.1
共423兲
共361–548兲
52.8
共473兲
2,6-dimethyl-4-tert-butylphenol
CAS registry number
Reference
关98/10兴
关98/10兴
关87/5兴
关100-18-5兴
关02/20兴
关02/20兴
关02/20兴
关02/20兴
关98/10兴
关98/10兴
关87/5兴
关59/1兴关84/9兴
关98-19-1兴
关98/19兴
关98/19兴
关93/10兴
关87-85-4兴
关87/5兴
关877-44-1兴
关87/5兴关47/5兴
关102-25-0兴
关97/6兴
关10222-95-4兴
关75/39兴
关6902-73-4兴
关87/5兴
关42585-08-0兴
关87/5兴
关01/16兴
关6857-85-1兴
关02/29兴关02/38兴
关8760-63-8兴
关02/29兴关02/39兴
关24142-77-6兴
关01/18兴
关01/18兴
关6382-14-5兴
关87/5兴关69/17兴
关2934-05-6兴
关87/5兴
关99/19兴
关99/19兴
关68189-19-5兴
关87/5兴
关46170-85-8兴
关87/5兴
关1879-09-0兴
关99/19兴
关99/19兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关17696-37-6兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关879-97-0兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
752
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O
C12H18O2
C12H18O2
C12H18O4
C12H18O6
C12H19N
C12H19N
C12H19NO
C12H19NO
C12H19F3 N2 O4
C12H20
C12H20
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共392–522兲
59.7
共407兲
共347–530兲
58.4
共348兲
共347–530兲
57.0
共373兲
共347–530兲
55.4
共398兲
共347–530兲
54.2
共423兲
共347–530兲
49.3
共473兲
3,4-dimethyl-6-tert-butylphenol
共413–532兲
62.7
共428兲
2-ethyl-4-tert-butylphenol
共428 – 623兲
61.6
共443兲
共397–543兲
55.4
共398兲
共397–543兲
54.2
共423兲
共397–543兲
49.3
共473兲
2-ethyl-6-tert-butylphenol
共393– 443兲
58.2
共408兲
3-ethyl-6-tert-butylphenol
共415–530兲
59.5
共430兲
4-ethyl-2-tert-butylphenol
共394 –523兲
59.2
共409兲
共349–533兲
57.0
共373兲
共349–533兲
55.4
共398兲
共349–533兲
54.2
共423兲
共349–533兲
49.3
共473兲
2-methyl-4-tert-pentylphenol
共443– 653兲
65.6
共458兲
共409–561兲
55.3
共423兲
共409–561兲
50.7
共473兲
3-methyl-4-tert-pentylphenol
共443– 683兲
65.1
共458兲
共409–561兲
55.3
共423兲
共409–561兲
50.7
共473兲
4-methyl-2-tert-pentylphenol
共423– 653兲
61.4
共438兲
共394 –538兲
58.1
共398兲
共394 –538兲
55.3
共423兲
共394 –538兲
50.7
共473兲
1,3-dihydroxy-2-hexylbenzene
共433– 494兲
76.8
共448兲
1,3-dihydroxy-4-hexylbenzene
共434 – 494兲
88.1
共449兲
3,4-dihydro-2,2-dimethyl-4-oxo-2H-pyran-6-carboxylic acid, butyl ester
共357– 435兲
64.7
共372兲
triethyl aconitrate
共423–540兲
79.6
共438兲
2,6-diisopropylaniline
共284 –323兲
69.2⫾0.3
共303兲
69.5⫾0.3
共298兲
N-methyl-3-methyl-3-phenyl-2-butaneamine
共283–330兲
67.0⫾0.8
共307兲
共283–330兲
67.5⫾0.8
共298兲
2-共dimethylamino兲-2-methyl-1-phenylpropanone
共298 –338兲
66.7⫾0.4
共298兲
2-共diethylamino兲-1-phenylethanone
共293–338兲
71.6⫾0.9
共298兲
N关N-共trifluoroacetyl兲valyl兴alanine ethyl ester
共425– 453兲
86.4
共439兲
1-ethyladamantane
55.3⫾1.1
共298兲
共383– 492兲
49.1
共398兲
1,3-dimethyladamantane
49.2⫾0.2
共308兲
49.7⫾0.2
共298兲
共352–526兲
49.4⫾0.3
共298兲
67.8⫾1.3
共298兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
A
A
A
A
A
A
A
A
A, GC
A, GC
A
CAS registry number
Reference
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关1445-23-4兴
关87/5兴
关63452-61-9兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关63551-41-7兴
关87/5兴
关4237-25-6兴
关87/5兴
关96-70-8兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关71745-63-6兴
关87/5兴
关53/9兴
关53/9兴
关87/5兴
关53/9兴
关53/9兴
关34072-71-4兴
关87/5兴
关53/9兴
关53/9兴
关53/9兴
关5673-09-6兴
关87/5兴关75/24兴
关136-77-6兴
关87/5兴关75/24兴
关532-34-3兴
关87/5兴
A
关87/5兴
关24544-04-5兴
关00/14兴
关00/14兴
GS
GS
关98/1兴
关98/1兴
GS
关94/3兴
GS
关94/3兴
A
关87/5兴关99/16兴
关770-69-4兴
关00/22兴
关87/5兴
关707-79-4兴
关01/4兴
关01/4兴
关96/3兴
关77/4兴
A
C
C
EB
EB
ENTHALPIES OF VAPORIZATION
753
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H20O
C12H20O2
C12H20O2
C12H20O2
C12H20O2
C12H20O2
C12H20O2
C12H20O4
C12H20O5
C12H20O7
C12H21O4 P
C12H21N2 O3 PS
C12H22
C12H22
C12H22
C12H22
C12H22Cl4
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
2,5-di-tert-butylfuran
共274 –323兲
56.1⫾1.1
bornyl acetate
共319– 496兲
50.8
geranyl acetate
共346 –516兲
58.1
isobornyl acetate
共404 – 450兲
56.1
bicyclo关2,2,1兴heptane-7-one 2,2-dimethylpropylene acetal
共293–323兲
60.5⫾0.9
3,7-dimethyl-1,6-octadien-3-ol acetate 共linalyl acetate兲
共281– 490兲
57.8
共328 – 493兲
56.8
terpineol acetate
共310– 424兲
68.1
dibutyl maleate
共255–550兲
41.1
2-ethoxycarbonylpropionic acid, cyclohexyl ester
共388 –523兲
67.6
triethyl citrate
共380–567兲
68.2
trimethylallyl phosphate
共367–597兲
53.9
Diazinon
共293–398兲
87.4
cis bicyclohexyl
共331–511兲
53.8
bicyclohexyl
50.1
42.5
58.0⫾0.2
6-dodecyne
共373–388兲
60.9
perhydroacenaphthylene
共422–514兲
49.6
1,2,11,12-tetrachlorododecane
81.9
trans 2-cyclohexylcyclohexanol
共324 –364兲
83.2⫾1.2
cyclododecanone
共373– 443兲
61.0
共408 – 450兲
57.9
共458 –556兲
54.7
共Z兲 2-dodecenal
共323–363兲
72.5
共E兲 2-dodecenal
共323–363兲
72.6
共Z兲 3-dodecenal
共323–363兲
69.6
共E兲 3-dodecenal
共323–363兲
70.2
共Z兲 4-dodecenal
共323–363兲
69.4
共E兲 4-dodecenal
共323–363兲
69.9
共Z兲 5-dodecenal
共323–363兲
69.1
共E兲 5-dodecenal
共323–363兲
69.6
共Z兲 6-dodecenal
共323–363兲
69.2
共E兲 6-dodecenal
共323–363兲
67.7
共Z兲 7-dodecenal
Mean temperature
(T m /K)
Method
共298兲
GS
共334兲
A
共361兲
A
共419兲
A
共298兲
GS
共296兲
共343兲
A
共325兲
A
共270兲
A
共403兲
A
共395兲
A
共381兲
CAS registry number
Reference
关4789-40-6兴
关98/2兴
关76-49-3兴
关87/5兴关47/5兴
关105-87-3兴
关87/5兴关47/5兴
关125-12-2兴
关87/5兴
关02/32兴
关115-95-7兴
关87/5兴
关47/5兴
关80-26-2兴
关87/5兴
关105-76-0兴
关87/5兴
关87/5兴
关77-93-0兴
关87/5兴
共308兲
A
共346兲
A
共435兲
共525兲
共298兲
C
共380兲
A
关47/5兴
关333-41-5兴
关87/5兴关99/16兴
关92-51-3兴
关87/5兴
关92-51-3兴
关81/1兴
关81/1兴
关78/12兴
关6975-99-1兴
关87/5兴
共437兲
EB
关00/16兴
关98/20兴
共344兲
ME
共388兲
共423兲
共473兲
A
A, EB
A, EB
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
关97/23兴
关830-13-7兴
关87/5兴
关87/5兴关76/10兴
关87/5兴关76/10兴
关81149-96-4兴
关96/7兴关00/10兴
关20407-84-5兴
关96/7兴关00/10兴
关68141-15-1兴
关96/7兴关00/10兴
关76595-72-7兴
关96/7兴关00/10兴
关21944-98-9兴
关96/7兴关00/10兴
关174155-48-7兴
关96/7兴关00/10兴
关68820-33-7兴
关96/7兴关00/10兴
关68820-34-8兴
关96/7兴关00/10兴
关12674-61-7兴
关96/7兴关00/10兴
关174155-49-8兴
关96/7兴关00/10兴
关63851-40-1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
754
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O2
C12H22O3
C12H22O3
C12H22O4
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共323–363兲
69.4
共E兲 7-dodecenal
共323–363兲
69.6
共Z兲 8-dodecenal
共323–363兲
70.0
共E兲 8-dodecenal
共323–363兲
69.8
共Z兲 9-dodecenal
共323–363兲
70.1
共E兲 9-dodecenal
共323–363兲
70.4
共Z兲 10-dodecenal
共323–363兲
71.0
共E兲 10-dodecenal
共323–363兲
70.9
dodecanolactone
共377– 403兲
64.2⫾1.1
共377– 403兲
70.5⫾1.7
acetic acid, 4-tert-butylcyclohexyl ester
共285–318兲
63.8
共d兲 menthyl acetate
共330–500兲
55.3
citronellyl acetate
共347– 490兲
68.7
2-共1-ethylpentyl兲-4,7-dihydro-1,3-dioxepin
共333– 453兲
66.3
octyl methacrylate
共384 –513兲
55.6
methyl 10-undecenoate
共397–524兲
59.2
共Z兲 3-decenyl acetate
共313–358兲
69.5
共299–313兲
72
共E兲 3-decenyl acetate
共313–358兲
70.1
共Z兲 4-decenyl acetate
共313–358兲
69.0
共E兲 4-decenyl acetate
共313–358兲
70.1
共Z兲 5-decenyl acetate
共313–358兲
69.7
共299–313兲
72
共E兲 5-decenyl acetate
共313–358兲
70.6
共Z兲 6-decenyl acetate
共313–358兲
70.1
共E兲 6-decenyl acetate
共313–358兲
70.6
共299–313兲
72
共Z兲 7-decenyl acetate
共313–358兲
70.7
共E兲 7-decenyl acetate
共313–358兲
71.1
共Z兲 8-decenyl acetate
共313–358兲
71.5
共E兲 8-decenyl acetate
共313–358兲
71.5
heptyl levulinate
共393–558兲
62.6
60.0
3-pentyl-4-acetoxytetrahydro-2H-pyran
共383– 453兲
65.8
dipropyl adipate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共390兲
共298兲
MM
MM
共300兲
A, ME
共345兲
A
共362兲
A
共348兲
A
共399兲
A
共412兲
A
共298兲
共306兲
GC
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
共306兲
GC
GC
共298兲
GC
共298兲
GC
共298兲
共306兲
GC
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共408兲
共496兲
A
共398兲
A
CAS registry number
Reference
关96/7兴关00/10兴
关82944-76-1兴
关96/7兴关00/10兴
关139909-65-2兴
关96/7兴关00/10兴
关144298-64-6兴
关96/7兴关00/10兴
关56219-03-5兴
关96/7兴关00/10兴
关155235-07-7兴
关96/7兴关00/10兴
关81892-61-7兴
关96/7兴关00/10兴
关81892-62-8兴
关96/7兴关00/10兴
关947-05-7兴
关91/7兴
关91/7兴
关87/5兴关58/9兴
关57/9兴
关16409-45-3兴
关87/5兴关47/5兴
关150-84-5兴
关87/5兴关47/5兴
关61732-97-6兴
关87/5兴
关2157-01-9兴
关87/5兴
关111-81-9兴
关87/5兴
关81634-99-3兴
关97/13兴关00/10兴
关83/10兴
关81634-98-2兴
关97/13兴关00/10兴
关67452-27-1兴
关97/13兴关00/10兴
关69222-16-8兴
关97/13兴关00/10兴
关67446-07-5兴
关97/13兴关00/10兴
关83/10兴
关38421-90-8兴
关97/13兴关00/10兴
关68760-70-3兴
关97/13兴关00/10兴
关97/13兴关00/10兴
关83/10兴
关13857-03-9兴
关97/13兴关00/10兴
关13857-04-0兴
关97/13兴关00/10兴
关83808-51-9兴
关97/13兴关00/10兴
关83808-51-9兴
关97/13兴关00/10兴
关87/5兴
关31/1兴
关18871-14-2兴
关87/5兴
关106-19-4兴
ENTHALPIES OF VAPORIZATION
755
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H22O4
C12H22O4
C12H22O4
C12H22O4 S
C12H22O5
C12H22O5
C12H22O6
C12H22O6
C12H22O6
C12H22S
C12H23N
C12H23N
Compound
共Temperature range/K兲
Mean temperature
(T m /K)
Method
共428兲
A
共392兲
A
共410兲
A
共373兲
A
共313兲
A
关87/5兴
关5398-08-3兴
关87/5兴
关22328-91-2兴
关87/5兴
关2051-00-5兴
关87/5兴关47/5兴
关4121-12-4兴
关87/5兴关99/16兴
共353兲
A
关87/5兴
共383兲
A
关87/5兴
共398兲
A
共443兲
A
共405兲
A
共298兲
EB
共423兲
A
共298兲
共408兲
共455兲
C
EB
A, EB
63.0
62.8
52.6
49.8
共298兲
共298兲
共401兲
共455兲
CGC
CGC
A, EB
A, EB
60.8⫾0.3
60.3
51.1
共298兲
共298兲
共411兲
C
55.9⫾0.5
59.0⫾0.5
59.9
共298兲
共298兲
共298兲
60.8
trans 2,2,4,6,6-pentamethyl-3-heptene
共291–318兲
65.6⫾0.5
共291–318兲
65.9⫾0.3
cis 2,2,4,6,6-pentamethyl-3-heptene
共288 –318兲
63.0⫾0.5
共288 –318兲
63.2⫾0.5
1,12-dichlorododecane
73.1
cyclododecanol
共405– 468兲
68.8
共467–557兲
57.1
dodecanal
共308 –353兲
70.2
共350–530兲
56.5
2-dodecanone
共350–520兲
61.1
71.8⫾0.6
共386 – 609兲
60.8
共386 – 609兲
48.1
ethyl p-menthyl ether
共366 – 414兲
50.9
共298兲
关87/5兴
关87-92-3兴
关87/5兴
关4054-82-4兴
关87/5兴
关7133-46-2兴
关97/7兴
关101-83-7兴
关87/5兴
关2437-25-4兴
关77/5兴
关71/4兴
关87/5兴关71/4兴
关73/12兴
关294-62-2兴
关98/11兴
关95/21兴
关87/5兴关76/10兴
关87/5兴关76/10兴
关112-41-4兴
关76/5兴关77/1兴
关71/28兴
关87/5兴关50/6兴
关4292-75-5兴
关87/17兴
关78/16兴
关71/28兴
关5617-42-5兴
关71/28兴
共413–540兲
63.6
isopentylmalonic acid, diethyl ester
共377– 420兲
64.1
共1-methylbutyl兲malonic acid, diethyl ester
共395–516兲
67.4
diisopentyl oxalate
共358 –538兲
58.6
thiodiglycolic acid, diethyl ester
共298 –383兲
75.7
butyl关1-共butoxycarbonyl兲ethyl兴 carbonate
共338 –513兲
68.1
pentyl关1-共ethoxycarbonyl兲isopropyl兴 carbonate
共368 –513兲
63.8
lactic acid, O-ethoxycarbonyl, 2-butoxyethyl ester
共383–521兲
74.6
dibutyl tartrate
共428 –511兲
79.8
共d兲 diisobutyl tartrate
共390–597兲
64.6
dicyclohexyl sulfide
共421–523兲
69.0⫾0.7
dicyclohexylamine
共408 –529兲
54.0
lauronitrile
76.1⫾0.1
共393– 462兲
65.2
共440–556兲
60.7
C12H24
cyclododecane
C12H24
共403– 453兲
共386 – 441兲
共440–529兲
1-dodecene
C12H24
C12H24
C12H24
C12H24
C12H24Cl2
C12H24O
C12H24O
C12H24O
C12H24O
⌬ vapH m
共kJ mol⫺1兲
共396 – 493兲
hexylcyclohexane
A
GC
GCC
heptylcyclopentane
CAS registry number
Reference
共305兲
共298兲
GS
GS
关00/7兴
关00/7兴
共303兲
共298兲
GS
GS
关00/7兴
关00/7兴
共420兲
共482兲
A
A
共298兲
共365兲
CGC
A
共365兲
共298兲
共401兲
共524兲
A
C
A
共381兲
A
关98/20兴
关1724-39-6兴
关87/5兴
关87/5兴
关112-54-9兴
关96/7兴关00/10兴
关87/5兴关47/5兴
关6175-49-1兴
关87/5兴关47/5兴
关77/2兴
关87/5兴关75/8兴
关75/8兴
关19321-39-2兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
756
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O
C12H24O2
C12H24O2
C12H24O2
C12H24O2
C12H24O2
C12H24O2
C12H24O2
C12H24O2
C12H24O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
1-heptylcyclopentanol
共395–524兲
58.6
1-hexylcyclohexanol
共380– 491兲
53.5
共Z兲 2-dodecen-1-ol
共333–373兲
90.7
共E兲 2-dodecen-1-ol
共333–373兲
91.0
共Z兲 3-dodecen-1-ol
共333–373兲
89.3
共E兲 3-dodecen-1-ol
共333–373兲
89.2
共Z兲 4-dodecen-1-ol
共333–373兲
89.9
共E兲 4-dodecen-1-ol
共333–373兲
90.6
共Z兲 5-dodecen-1-ol
共333–373兲
90.2
共E兲 5-dodecen-1-ol
共333–373兲
90.7
共Z兲 6-dodecen-1-ol
共333–373兲
90.2
共E兲 6-dodecen-1-ol
共333–373兲
90.7
共Z兲 7-dodecen-1-ol
共333–373兲
90.5
共E兲 7-dodecen-1-ol
共333–373兲
90.8
共Z兲 8-dodecen-1-ol
共333–373兲
91.0
共E兲 8-dodecen-1-ol
共333–373兲
91.0
共Z兲 9-dodecen-1-ol
共333–373兲
91.1
共E兲 9-dodecen-1-ol
共333–373兲
91.7
共Z兲 10-dodecen-1-ol
共333–373兲
92.4
共E兲 10-dodecen-1-ol
共333–373兲
91.9
ethyl decanoate
共404 – 440兲
58.4⫾0.1
共404 – 440兲
67.4⫾1.3
共359–515兲
59.6
decyl acetate
共313–358兲
71.6
共363–515兲
61.9
共299–313兲
72
共445–530兲
56.3
4,5-dimethyl-2-heptyl-1,3-dioxolane
共333– 453兲
69.8
dodecanoic acid
共393–573兲
88.8
共321–341兲
95.8
81.3
2-共1-ethylpentyl兲-1,3-dioxepane
共333–373兲
68.1
2-heptyl-1,3-dioxepane
共328 –373兲
70.3
3-heptyl-4-hydroxytetrahydro-2H-pyran
共383– 453兲
77.6
4-octyl-1,3-dioxane
共353– 453兲
65.5
methyl undecanoate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共410兲
A
共395兲
A
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共422兲
共298兲
共374兲
MM
MM
A
共298兲
共378兲
共306兲
共460兲
GC
A
GC
DTA
共346兲
A
共408兲
共332兲
共437兲
A
ME, TE
I
共348兲
A
共343兲
A
共398兲
A
共368兲
A
CAS registry number
Reference
关20999-39-7兴
关87/5兴
关3964-63-4兴
关87/5兴
关69064-36-4兴
关00/10兴关94/13兴
关69064-37-5兴
关00/10兴关94/13兴
关32451-95-9兴
关00/10兴关94/13兴
关68900-87-8兴
关00/10兴关94/13兴
关40642-37-3兴
关00/10兴关94/13兴
关81745-38-2兴
关00/10兴关94/13兴
关40642-38-4兴
关00/10兴关94/13兴
关62936-12-3兴
关00/10兴关94/13兴
关40642-39-5兴
关00/10兴关94/13兴
关52957-14-9兴
关00/10兴关94/13兴
关20056-92-2兴
关00/10兴关94/13兴
关16695-40-2兴
关00/10兴关94/13兴
关40642-40-8兴
关00/10兴关94/13兴
关42513-42-8兴
关00/10兴关94/13兴
关35148-18-6兴
关00/10兴关94/13兴
关35237-62-8兴
关00/10兴关94/13兴
关35289-30-6兴
关00/10兴关94/13兴
关35237-63-9兴
关00/10兴关94/13兴
关110-38-3兴
关91/7兴
关91/7兴
关87/5兴
关112-17-4兴
关97/13兴关00/10兴
关87/5兴
关83/10兴
关80/8兴
关61732-91-0兴
关87/5兴
关143-07-7兴
关87/5兴
关82/5兴
关43/7兴
关61732-93-2兴
关87/5兴
关61732-92-1兴
关87/5兴
关62159-06-2兴
关87/5兴
关23433-02-5兴
关87/5兴
关1731-86-8兴
ENTHALPIES OF VAPORIZATION
757
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共350兲
共340兲
共298兲
共298兲
共298兲
共408兲
CGC
C
A, EST
关02/27兴
关02/27兴
关02/27兴
关95/21兴
关77/1兴
关87/5兴关63/16兴
47.3
共385兲
A
59.8
共388兲
A
86.1⫾6.7
共298兲
CGC
74.8⫾0.4
62.2
共298兲
共426兲
C
A, EST
73.9⫾1.4
70.5
71.9⫾0.3
70.3⫾0.5
62.4
共298兲
共298兲
共298兲
共298兲
共404兲
GS
C
C
A, DTA
65.3
共298兲
A
(dl) 3-chlorododecane
共283–328兲
65.9
共298兲
A
(dl) 4-chlorododecane
共283–328兲
64.1
共298兲
A
(dl) 5-chlorododecane
共283–328兲
65.9
共298兲
A
6-chlorododecane
共283–328兲
65.5
共298兲
A
1-fluorododecane
共288 –328兲
共374 –533兲
64.0⫾0.2
56.2
共298兲
共389兲
GS
A, EST
63.5
共441兲
A, EST
71.2
共388兲
A
62.1⫾0.2
60.3⫾0.8
61.4
58.1
57.4
60.7
61.2
61.2
61.5
65.7
61.8
61.1
61.8⫾0.5
60.4⫾0.3
61.3
51.6
共298兲
共298兲
共299兲
共334兲
共344兲
共298兲
共298兲
共298兲
共298兲
共278兲
共293兲
共313兲
共298兲
共298兲
共298兲
共415兲
GS
CGC
C
C
C
CGC
CGC
CGC
C12H24O6
C12H25Br
1-bromododecane
共411– 610兲
C12H25Cl
1-chlorododecane
共390–520兲
C12H25Cl
C12H25Cl
C12H25Cl
C12H25Cl
C12H25Cl
C12H25F
C12H25I
C12H25NO
C12H26
共389–519兲
(dl) 2-chlorododecane
共283–328兲
1-iodododecane
共426 – 636兲
N,N-diethylcaprylamide
共373–510兲
dodecane
共373– 423兲
共363– 413兲
共423– 473兲
共263–371兲
共278 – 400兲
共298 –389兲
C12H26
66.1
67.0⫾0.1
70.8⫾0.4
70.6
71.4⫾0.3
60.9
CAS registry number
Reference
共393– 473兲
pentyl 2-butoxypropionate
共373–398兲
methyl 3-octyloxypropionate
共373–513兲
18-crown-6
C12H24O3
Mean temperature
(T m /K)
Method
共433– 473兲
C12H24O3
⌬ vapH m
共kJ mol⫺1兲
共400– 492兲
2-methylundecane
A
GS
C
C
A, MM
关87/5兴
关7419-98-9兴
关87/5兴
关17455-13-9兴
关00/9兴
关143-15-7兴
关76/6兴关77/1兴
关87/5兴关61/13兴
关70/14兴
关112-52-7兴
关01/1兴
关84/9兴关91/2兴
关77/1兴
关75/6兴
关87/5兴关69/5兴
关2350-12-1兴
关87/5兴关70/14兴
关62/30兴
关2350-12-1兴
关87/5兴关70/14兴
关62/30兴
关2350-13-2兴
关87/5兴关70/14兴
关62/30兴
关2350-14-3兴
关87/5兴关70/14兴
关62/30兴
关26535-66-0兴
关87/5兴关70/14兴
关62/30兴
关334-68-9兴
关97/14兴
关87/5兴关61/13兴
关70/14兴
关4292-19-7兴
关87/5兴关61/13兴
关70/14兴
关996-97-4兴
关87/5兴
关112-40-3兴
关01/1兴
关00/9兴
关96/22兴
关96/22兴
关96/22兴
关95/21兴
关95/21兴
关95/21兴
关94/12兴
关88/12兴
关87/5兴
关86/6兴
关76/4兴
关72/29兴
关71/28兴
关87/5兴关45/2兴
关7045-71-8兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
758
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C12H26
共356 – 484兲
(dl) 3-methylundecane
共357– 485兲
4-methylundecane
共359– 481兲
5-methylundecane
共357– 480兲
2,3-dimethyldecane
共369– 480兲
2,4-dimethyldecane
共348 – 472兲
2,4,6-trimethylnonane
共339– 459兲
3,3,6,6-tetramethyloctane
共347– 463兲
2,2,4,6,6-pentamethylheptane
C12H26O
ethyl decyl ether
C12H26O
dihexyl ether
C12H26
C12H26
C12H26
C12H26
C12H26
C12H26
C12H26
共353–393兲
共372–510兲
C12H26O
octyl tert-butyl ether
C12H26O
isobutyl tert-octyl ether
C12H26O
butyl tert-octyl ether
C12H26O
1-dodecanol
共303–348兲
共303–348兲
共373– 423兲
共353–393兲
共303– 413兲
共383– 438兲
共505–550兲
C12H26O
C12H26O
C12H26O
C12H26O
C12H26O
C12H26O2
C12H26O3
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
49.5
共371兲
A
48.8
共372兲
A
51.6
共374兲
A
50.3
共372兲
A
50.0
共384兲
A
47.5
共363兲
A
46.4
共354兲
A
52.9
共362兲
A
49.0⫾0.2
共298兲
C
65.9⫾0.1
共298兲
C
63.6⫾0.8
63.5
52.9
64.1⫾0.1
共298兲
共298兲
共387兲
共298兲
CGC
CGC
A
C
61.4
共298兲
关U/2兴关02/32兴
51.6
共298兲
关U/2兴关02/32兴
52.9⫾0.4
共298兲
85.8
90.0
91.7
91.7
80.5
73.8
57.1
84.7⫾0.5
91.8⫾0.6
92.0⫾0.6
92.5
67.6
66.7
71.5
95.4
83.3
67.6
共327兲
共298兲
共298兲
共298兲
共358兲
共398兲
共520兲
共343兲
共298兲
共298兲
共312兲
共426兲
共440兲
共415兲
共305兲
共333兲
共426兲
关U/2兴关02/32兴
关112-53-8兴
关01/3兴
关01/3兴
关95/21兴
关94/13兴关00/10兴
关92/14兴
关87/5兴
关87/5兴
关79/6兴
关79/6兴
关77/1兴
关73/26兴
关73/26兴
关87/5兴关70/2兴
关69/5兴
关65/15兴
关87/5兴关62/12兴
关58/2兴
关10203-28-8兴
关99/11兴
关87/5兴关62/12兴
关10203-30-2兴
关87/5兴关62/12兴
关10203-32-4兴
关87/5兴关62/12兴
关10203-33-5兴
关87/5兴关62/12兴
关6836-38-0兴
关87/5兴关62/12兴
共297–363兲
共411– 487兲
共425–550兲
共400–538兲
共297–313兲
共303–363兲
共411– 487兲
2-dodecanol
共293–393兲
87.0
共293–343兲
85.0
(dl) 3-dodecanol
共293–343兲
78.3
4-dodecanol
共293–343兲
80.6
5-dodecanol
共293–343兲
79.4
6-dodecanol
共293–343兲
81.5
(dl) 3,4-diethyl-3,4-dimethoxyhexane
共302–332兲
59.8⫾1.3
diethylene glycol dibutyl ether
73.8⫾1.7
共293–528兲
56.6
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
GS
GS
CGC
CGC
A
A
C
C
C
A, EB
DTA
ME
A, ME
共308兲
共318兲
A, ME
共318兲
A, ME
共318兲
A, ME
共318兲
A, ME
共318兲
A, ME
共317兲
GS
共298兲
共308兲
GCG
A
CAS registry number
Reference
关87/5兴
关1002-43-3兴
关87/5兴
关2980-69-0兴
关87/5兴
关1632-70-8兴
关87/5兴
关17312-44-6兴
关87/5兴
关2801-84-5兴
关87/5兴
关62184-10-5兴
关87/5兴
关62199-46-6兴
关87/5兴
关13475-82-6兴
关76/4兴
关55962-01-1兴
关85/2兴
关112-58-3兴
关00/9兴
关95/21兴
关87/5兴
关85/2兴
关90/17兴
关112-73-2兴
关00/9兴
关87/5兴
ENTHALPIES OF VAPORIZATION
759
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C12H26O4
C12H26O4
C12H26S
C12H26S2
C12H26S2
Compound
共Temperature range/K兲
2,2-bis共tert-butylperoxy兲butane
共299–323兲
77.1
tripropylene glycol monoisopropyl ether
共355–530兲
56.9
1-dodecanethiol
共420–581兲
62.0
1,12-dodecanedithiol
共454 –593兲
77.8
C12H30N3 P
dihexyl disulfide
共435– 601兲
dodecylamine
共443–545兲
共356 –521兲
dihexylamine
共408 –569兲
N,N-dimethyldecylamine
共405–564兲
tributylamine
共298 –337兲
共333– 487兲
triisobutylamine
共305– 452兲
tributyl phosphate
共500–562兲
triisobutyl phosphate
共411–537兲
tributyl phosphine
共353– 428兲
1,12-dodecanediamine
共313–353兲
tetrapropyl hydrazine
共362– 423兲
tris共diethylamino兲phosphine
C13H8 O
9-fluorenone
C13H9 ClO2
5-chloro-2-hydroxybenzophenone
共367– 493兲
acridine
共423– 621兲
共423– 621兲
共423– 621兲
共402– 619兲
fluorene
共323– 473兲
C12H27N
C12H27N
C12H27N
C12H27N
C12H27N
C12H27O4 P
C12H27O4 P
C12H27P
C12H28N2
C12H28N2
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共311兲
A
关41407-59-4兴
关87/5兴
共370兲
A
共435兲
共469兲
A
64.9
共450兲
61.0
63.4
共458兲
共371兲
A, EST
55.1
共423兲
A
55.2
共420兲
A
64.4
48.1
共313兲
共348兲
A
A
54.3
共320兲
A
61.4
共515兲
A
62.8
共426兲
A
51.7⫾0.5
共390兲
110.1
共328兲
A
65.2
共377兲
A
60.7⫾0.4
NA
C13H9 N
C13H10
C13H10N2
C13H10O
C13H10O
共403– 453兲
共323–363兲
共383– 427兲
共402–568兲
共423–573兲
N,N⬘-diphenylcarbondiimide
共500–599兲
benzophenone
共433– 673兲
共473–579兲
共530–575兲
xanthene
73.3
共382兲
A, UV
62.9
62.1
61.5
66.2
共465兲
共515兲
共595兲
共417兲
A
66.9
72.3
72.2
65.7
63.3
54.2
56.6
共398兲
共298兲
共298兲
共298兲
共398兲
共417兲
共498兲
GC
CGC
CGC
B
65.6
共515兲
A
65.1
62.2
59.0
共448兲
共488兲
共545兲
A
64.5
61.1
59.2
56.7
54.4
共435兲
共475兲
共515兲
共555兲
共585兲
A
I
关87/5兴关47/5兴
关112-55-0兴
关99/16兴
关33528-63-1兴
关87/5兴关43/6兴
关99/16兴
关10496-15-8兴
关99/16兴
关124-22-1兴
关87/5兴关56/17兴
关47/5兴
关143-16-8兴
关87/5兴
关1120-24-7兴
关87/5兴
关102-82-9兴
关87/5兴
关87/5兴
关1116-40-1兴
关87/5兴关47/5兴
关126-73-8兴
关87/5兴
关126-71-6兴
关87/5兴
关998-40-3兴
关01/9兴
关4843-89-4兴
关87/5兴
关60678-69-5兴
关87/5兴
关59/24兴
关486-25-9兴
关83/17兴
关85-19-8兴
关87/5兴关60/2兴
关260-94-6兴
关83/4兴
关83/4兴
关83/4兴
关87/5兴关47/5兴
关86-73-7兴
关02/18兴
关98/11兴
关95/21兴
关94/4兴
关88/12兴
关87/5兴
关23/1兴
关622-16-2兴
关87/5兴
关119-61-9兴
关87/5兴
关49/1兴关84/9兴
关1904/1兴关84/9兴
关92-83-1兴
关84/25兴
关84/25兴
关84/25兴
关84/25兴
关85/25兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
760
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C13H10O
C13H10O2
C13H10O3
C13H10O3
C13H11Cl
C13H11F
C13H11N
C13H11N
C13H11N3 O
C13H12
C13H12
C13H12O
C13H12O
C13H12O
C13H13N
C13H13N
C13H14
C13H14
C13H14
C13H14N2
C13H14N2
Compound
共Temperature range/K兲
共413– 433兲
9-hydroxyfluorene
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
88.7
共423兲
A
NA
phenylbenzoate
共379–587兲
62.4
共394兲
2,4-dihydroxybenzophenone
共418 – 485兲
87.1
共433兲
phenyl salicyate
共423–587兲
69.9
共438兲
chlorodiphenylmethane
共381– 450兲
70.4
共396兲
fluorodiphenylmethane
共288 –333兲
69.8⫾0.4
共298兲
benzophenone imine
共308 –338兲
74.2⫾1.0
共323兲
共308 –338兲
75.7⫾1.0
共298兲
共373– 422兲
62.3
共388兲
9-methylcarbazole
共373– 673兲
73.4
共400兲
共373– 673兲
70.5
共440兲
共373– 673兲
67.7
共480兲
共373– 673兲
65.0
共520兲
共373– 673兲
62.1
共560兲
共373– 673兲
59.1
共600兲
共373– 673兲
55.9
共640兲
共348 –384兲
74.9
共366兲
2-共2⬘-hydroxy-5⬘-methylphenyl兲benzotriazole
共413– 433兲
79.1
共423兲
共404 – 435兲
70.6
共419兲
3-methylbiphenyl
共283– 463兲
69.6
共298兲
diphenylmethane
65.7
共298兲
共303–343兲
66.4⫾0.5
共323兲
共303–343兲
67.9⫾0.5
共298兲
共303– 402兲
63.7
共363兲
共295–383兲
72.2
共310兲
共423–583兲
56.7
共438兲
55.8
共445兲
49.0
共535兲
66.6⫾0.1
共298兲
共490–555兲
54.2
共505兲
benzyl phenyl ether
共368 –560兲
58.8
共383兲
diphenylmethanol
共438 –574兲
65.4
共453兲
ethyl 1-naphthyl ketone
共397–579兲
74.1
共412兲
N-methyldiphenylamine
共376 –555兲
65.2
共391兲
N-benzylaniline
共316 –343兲
79.6⫾1.1
共330兲
79.5
关Note: The value reported in 关80/21兴 for the enthalpy of vaporization
is larger than the value given for the enthalpy of sublimation.兴
1,6,7-trimethylnaphthalene
共323– 473兲
68.6
共398兲
1-isopropylnaphthalene
共402–541兲
50.4
共417兲
2-isopropylnaphthalene
共402–541兲
60.3
共417兲
2,4⬘-diaminodiphenylmethane
共353– 403兲
111.5
共368兲
4,4⬘-diaminodiphenylmethane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A, UV
A, UV
A
GS
GS
GS
A
EB, IPM
EB, IPM
EB, IPM
EB, IPM
EB, IPM
EB, IPM
EB, IPM
GS
ME
A, UV
GC
GS
GS
A
A
C
A
A
A
A
GC
A
A
A
CAS registry number
Reference
关87/5兴关58/23兴
关1689-64-1兴
关83/17兴
关93-99-2兴
关87/5兴关47/5兴
关131-56-6兴
关87/5兴关60/2兴
关118-55-8兴
关87/5兴关60/2兴
关90-99-3兴
关87/5兴
关579-55-5兴
关97/14兴
关1013-88-3兴
关97/9兴
关97/9兴
关87/5兴
关1484-12-4兴
关92/15兴
关92/15兴
关92/15兴
关92/15兴
关92/15兴
关92/15兴
关92/15兴
关80/6兴
关2440-22-4兴
关84/1兴
关87/5兴关60/2兴
关643-93-6兴
关93/10兴
关101-81-5兴
关02/37兴
关99/8兴
关99/8兴
关89/14兴
关87/5兴
关87/5兴
关81/1兴
关81/1兴
关72/28兴
关15/1兴关84/9兴
关946-80-5兴
关87/5兴关47/5兴
关91-01-0兴
关87/5兴
关2876-63-3兴
关87/5兴关47/5兴
关552-82-9兴
关87/5兴关47/5兴
关103-32-2兴
关97/21兴
关80/21兴
关2245-38-7兴
关02/18兴
关6158-45-8兴
关87/5兴
关2027-17-0兴
关87/5兴
关1208-52-2兴
关87/5兴
关101-77-9兴
ENTHALPIES OF VAPORIZATION
761
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C13H15Cl3 O3
C13H15N
C13H15NO
C13H16Cl2 O3
C13H16Cl2 O3
C13H16N2
C13H17NO
C13H17NO
C13H17NO3
C13H18
C13H18
C13H18O
C13H18O
C13H18O
C13H19NO
C13H19NO
C13H20
C13H20O
C13H20O
C13H20O
C13H20O
C13H20O
C13H20O
C13H20O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共343–393兲
109.3
共486 –545兲
98.0
共471–545兲
100.6
2,4,6-trichlorophenoxyacetic acid, pentyl ester
共460–573兲
78.8
1,2,3,4-tetrahydro-9-methylcarbazole
共370– 655兲
72.5
共370– 655兲
69.6
共370– 655兲
66.7
共370– 655兲
63.8
共370– 655兲
60.7
共370– 655兲
57.4
共370– 655兲
53.8
1-共1-isocyanato-1-methylethyl兲-4-共1-methylethylbenzene兲
共298 – 463兲
68.5
2,4-dichlorophenoxyacetic acid, isopentyl ester
共460–573兲
75.8
2,4-dichlorophenoxyacetic acid, pentyl ester
共444 –573兲
73.6
2-phenyl-2-piperidinoacetonitrile
共338 –378兲
73.2⫾0.4
1-共phenacyl兲piperidine
共381– 446兲
51.4
共382– 450兲
47.2
1-共m-toluoyl兲piperidine
共373– 403兲
53.8
(dl) N-acetylphenylalanine, ether ester
共438 –528兲
82.4
1,1,4,6-tetramethylindane
共313–383兲
59.4
共313– 469兲
60.2
共242– 469兲
51.9
1,1,4,7-tetramethylindane
共313–388兲
59.6
共313– 469兲
60.4
共431– 469兲
52.0
4,4-dimethyl-1-phenyl-3-pentanone
共405–520兲
63.5
p-isopropyl-␣-methylhydrocinnamaldehyde
共283– 499兲
72.6
1-phenyl-1-heptanone
共373–550兲
64.6
3-phenylpropionic acid, N,N-diethylamide
共353– 439兲
46.5
共4R,5R兲-2,2,3,4-tetramethyl-5-phenyl-1,3-oxazolidine
共293–301兲
61.6⫾1.8
heptylbenzene
共423–527兲
54.0
64.9
butyl cumyl ether
共278 –318兲
63.8⫾0.5
␣-ionone
共352–523兲
62.0
共286 –333兲
67.5
␤-ionone
共291–334兲
69.0
6,10-dimethyl-4,5,9-undecatrien-2-one
共349– 421兲
63.6⫾1.4
6,10-dimethyl-3,5,9-undecatrien-2-one
共382– 457兲
67.6⫾1.1
4-共2,6,6-trimethyl-1-cyclohexen-1-yl兲-3-buten-2-one
共373– 442兲
49.6⫾1.1
1,3-dihydroxy-5-heptylbenzene
Mean temperature
(T m /K)
Method
共358兲
共501兲
共502兲
A
A
A
共475兲
A
共400兲
共440兲
共480兲
共520兲
共560兲
共600兲
共640兲
EB,
EB,
EB,
EB,
EB,
EB,
EB,
共308兲
DTA, T,
HSA
共475兲
A
共459兲
A
IPM
IPM
IPM
IPM
IPM
IPM
IPM
GS
共396兲
共416兲
A
共388兲
A
共453兲
A
共328兲
共328兲
共439兲
A
A
A
共328兲
共328兲
共446兲
A
A
A
共420兲
A
共298兲
A
共388兲
A
共368兲
A
共298兲
共438兲
共298兲
A
共298兲
GS
共367兲
共301兲
A
A, ME
共306兲
A, ME
共385兲
共420兲
共408兲
CAS registry number
Reference
关87/5兴
关87/5兴
关66/28兴
关120-39-8兴
关87/5兴
关17058-12-7兴
关92/15兴
关92/15兴
关92/15兴
关92/15兴
关92/15兴
关92/15兴
关92/15兴
关86/3兴
关67821-07-2兴
关87/5兴
关1917-96-6兴
关87/5兴
关97/10兴
关3626-62-8兴
关87/5兴关69/1兴
关69/1兴
关13290-48-7兴
关87/5兴关69/1兴
关4134-09-2兴
关87/5兴
关941-60-6兴
关87/5兴
关87/5兴
关87/5兴
关1078-04-2兴
关87/5兴
关87/5兴
关87/5兴
关5195-24-4兴
关87/5兴
关103-95-7兴
关87/5兴
关1671-75-6兴
关87/5兴关47/5兴
关87/5兴
关141271-51-4兴
关98/3兴
关1078-71-3兴
关87/5兴
关71/28兴
关01/18兴
关127-41-3兴
关87/5兴关47/5兴
关87/5兴关57/9兴
关14901-07-6兴
关87/5兴关57/9兴
关16647-05-5兴
关88/4兴
关141-10-6兴
关88/4兴
关79-77-6兴
关88/4兴
关500-67-4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
762
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C13H20O2
C13H21Cl3 OS
C13H21N
C13H21N
C13H21NO
C13H22
C13H22
C13H22
C13H22
C13H22Cl2 O4
C13H22O2
C13H24Cl4
C13H24O
C13H24O2
C13H24O2
C13H24O2
C13H24O3
C13H24O3
C13H24O3
C13H24O3
C13H24O3
C13H24O4
C13H24O4
C13H24O5
C13H24O5
C13H25N
C13H25NO
C13H26
C13H26
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共443–504兲
91.6
1,3-dihydroxy-5-methyl-2-hexylbenzene
共433– 493兲
82.8
2,3,3-trichloro-2-propenethioic acid, O-decyl ester
共483–503兲
79.9
N,N-dimethyl-3-methyl-3-phenyl-2-butaneamine
共283–330兲
59.8⫾0.7
共283–330兲
60.3⫾0.7
N-methyl-2,3-dimethyl-3-phenyl-2-butaneamine
共285–332兲
71.9⫾1.1
共285–332兲
72.5⫾1.1
2-共diethylamino兲-1-phenyl-1-propanone
共293–333兲
71.6⫾1.0
2-allyl-cis-decahydronaphthalene
共296 –320兲
89.9
2-allyl-trans-decahydronaphthalene
共296 –320兲
91.7
dodecahydrofluorene
共332–525兲
55.8
1,3,5-trimethyladamantane
51.7⫾0.2
2,2-bis共chloromethyl兲-1,3-propanediol dibutyrate
共454 –572兲
43.1
bornyl propionate
共337–508兲
55.9
1,1,1,13-tetrachlorotridecane
共320–370兲
97.4
5-methyl-2-ethyl-2-butyl-4-hexenal
共323–393兲
69.1
decyl acrylate
共404 –536兲
59.6
oxa-2-cyclotetradecanone 共tridecanolactone兲
共375– 405兲
66.6⫾1.1
共375– 405兲
72.9⫾1.7
共393– 443兲
67.5
ethyl 10-undecenoate
共404 –532兲
77.4
1,4-dioxa-5-cyclopentadecanone
共403– 443兲
69.6
1,6-dioxa-7-cyclopentadecanone
共403– 443兲
75.7
1,8-dioxa-9-cyclopentadecanone
共403– 443兲
66.5
3-hexyl-4-acetoxytetrahydro-2H-pyran
共383– 453兲
72.1
octyl levulinate
共413–565兲
66.3
65.1
octyl 3-acetoxypropionate
共420– 440兲
88.4
ethylisopentylmalonic acid, ethyl methyl ester
共392–501兲
73.1
octyl关1-共methoxycarbonyl兲ethyl兴 carbonate
共391–566兲
70.0
pentyl关1-共butoxycarbonyl兲ethyl兴 carbonate
共348 –513兲
70.1
tridecanonitrile
共380–566兲
69.5
1-octanoyl piperidine
共373– 443兲
50.0
5-butyl-4-nonene
共310–361兲
55.8
1-tridecene
65.3
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共458兲
A, GC
共448兲
A, GC
CAS registry number
Reference
GC
关87/5兴关75/24兴
关41395-27-1兴
关87/5兴关75/24兴
关76619-97-1兴
关80/24兴
共307兲
共298兲
GS
GS
关98/1兴
关98/1兴
共309兲
共298兲
GS
GS
关98/1兴
关98/1兴
共298兲
GS
关94/3兴
共308兲
A
关87/5兴
共308兲
A
共347兲
A
关87/5兴
关5744-03-6兴
关87/5兴
关707-35-7兴
关00/21兴关00/22兴
共298兲
共469兲
A
共352兲
A
共335兲
A
共338兲
A
共419兲
A
共390兲
共298兲
共408兲
MM
MM
A
共419兲
A
共418兲
A, GC
共418兲
A, GC
共418兲
A, GC
共398兲
A
共428兲
共507兲
A
共430兲
A
共407兲
A
关87/5兴
关72030-39-8兴
关87/5兴
共406兲
A
关87/5兴
共363兲
A
共395兲
A
共388兲
A
共325兲
A, MG
关87/5兴
关629-60-7兴
关87/5兴
关20299-83-6兴
关87/5兴
关7367-38-6兴
关87/5兴关55/11兴
关2437-56-1兴
关71/28兴
共298兲
关87/5兴
关78548-53-5兴
关87/5兴关47/5兴
关3922-33-6兴
关87/5兴
关42023-59-6兴
关87/5兴
关2156-96-9兴
关87/5兴
关1725-04-8兴
关91/7兴
关91/7兴
关87/5兴
关692-86-4兴
关87/5兴
关1898-91-1兴
关87/5兴关71/33兴
关36575-54-9兴
关87/5兴关71/33兴
关36575-53-8兴
关87/5兴关71/33兴
关18871-17-5兴
关87/5兴
关41780-57-8兴
关87/5兴
关33/6兴
ENTHALPIES OF VAPORIZATION
763
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C13H26
共413–509兲
n-octylcyclopentane
C13H26
n-heptylcyclohexane
C13H26O
C13H26O
C13H26O
C13H26O
C13H26O
C13H26O
C13H26O
C13H26O
C13H26O
C13H26O
C13H26O
C13H26O2
C13H26O2
C13H26O2
C13H26O2
C13H26O2
C13H26O2
C13H26O2
C13H26O3
C13H26O3
C13H26O3
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
53.9
共428兲
A
65.8
共298兲
64.9
5-methyl-2-ethyl-2-butyl-4-hexene-1-ol
共333–393兲
76.9
1-octylcyclopentanol
共468 –541兲
60.9
2-tridecanone
共335–534兲
69.6
共424 –510兲
61.0
共400– 628兲
49.6
共335– 431兲
69.8
共360–535兲
62.1
7-tridecanone
共395– 600兲
62.7
共396 – 623兲
49.3
共Z兲 7-tridecen-1-ol
共343–383兲
95.1
共E兲 7-tridecen-1-ol
共343–383兲
95.6
共Z兲 9-tridecen-1-ol
共343–383兲
95.8
共E兲 9-tridecen-1-ol
共343–383兲
96.4
共Z兲 11-tridecen-1-ol
共343–383兲
97.1
共E兲 1,1-tridecen-1-ol
共343–383兲
97.2
6,10-dimethyl-2-undecanone
共379– 473兲
59.3⫾0.4
4,5-dimethyl-2-octyl-1,3-dioxolane
共333– 453兲
72.8
2-octyl-1,3-dioxepane
共323–373兲
61.2
undecyl acetate
共333–378兲
77.2
isopropyl decanoate
共363– 451兲
60.8
propyl decanoate
共369– 459兲
62.4
methyl laurate
71.4
70.7⫾0.2
76.6⫾0.4
共295– 452兲
74.9
共393– 463兲
76.8
共453–543兲
53.3
共287–333兲
83.6
76.5⫾0.7
77.2⫾0.6
共407–540兲
63.6
共336 – 409兲
71.4
共373– 439兲
62.3
tridecanoic acid
共409–585兲
90.1
共328 –350兲
100.4⫾2.0
decyl lactate
共349–556兲
76.6
octyl 3-ethoxypropionate
共398 –543兲
56.9
pentyl 3-pentyloxypropionate
共378 – 498兲
62.3
共298兲
共348兲
A
共483兲
A
共350兲
共439兲
共541兲
共348兲
共375兲
A
A
EB
共410兲
共536兲
A
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共426兲
共348兲
A
共338兲
A
共298兲
GC
共378兲
A
共384兲
A
共350兲
共356兲
共298兲
共310兲
共298兲
共498兲
共302兲
共298兲
共298兲
共422兲
共351兲
共388兲
GC
GC
A
C,GC
C
A
MG,OM
共424兲
共340兲
A
ME, TE
共364兲
A
共413兲
A
共393兲
A
CAS registry number
Reference
关87/5兴关55/7兴
关1795-20-6兴
关71/28兴
关5617-41-4兴
关71/28兴
关53144-53-9兴
关87/5兴
关30089-09-9兴
关87/5兴
关593-08-8兴
关87/5兴
关87/5兴
关75/8兴
关66/12兴
关47/5兴
关462-18-0兴
关87/5兴
关75/8兴
关64470-31-1兴
关00/10兴关94/13兴
关64437-28-1兴
关00/10兴关94/13兴
关52957-10-5兴
关00/10兴关94/13兴
关52957-15-0兴
关00/10兴关94/13兴
关34010-24-7兴
关00/10兴关94/13兴
关56195-34-7兴
关00/10兴关94/13兴
关1604-34-8兴
关88/4兴
关5452-11-9兴
关87/5兴
关61732-94-3兴
关87/5兴
关1731-81-3兴
关97/13兴关00/10兴
关2311-59-3兴
关87/5兴
关30673-60-0兴
关87/5兴
关111-82-0兴
关02/27兴
关02/27兴
关02/27兴
关01/10兴
关97/28兴
关93/9兴
关87/5兴
关80/5兴
关77/1兴
关87/5兴关63/16兴
关52/13兴
关44/7兴
关638-53-9兴
关87/5兴
关82/4兴
关42175-34-8兴
关87/5兴
关87/5兴
关14144-56-0兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
764
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C13H27Br
C13H27Cl
C13H27F
C13H27I
C13H27NO2
C13H27NO2
C13H28
C13H28
C13H28
C13H28
C13H28
C13H28
C13H28
C13H28
C13H28
C13H28
C13H28O
C13H28O
C13H28O
C13H28O
C13H28O
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
1-bromotridecane
共425– 628兲
64.6
共440兲
A, EST
1-chlorotridecane
共414 – 611兲
63.0
共429兲
A, EST
1-fluorotridecane
共387–558兲
58.9
共402兲
A, EST
1-iodotridecane
共440– 655兲
66.1
共455兲
A, EST
97.9
共428兲
A
关87/5兴
95.0
共428兲
A
65.3
64.9
64.2
63.3
62.4
62.3
66.7
65.6
64.6
61.7
66.5⫾0.2
66.4⫾0.3
66.2
54.5
共309兲
共314兲
共324兲
共334兲
共344兲
共349兲
共298兲
共308兲
共318兲
共348兲
共298兲
共298兲
共298兲
共432兲
C
C
C
C
C
C
52.5
共388兲
A
51.4
共387兲
A
52.0
共387兲
A
50.6
共383兲
A
53.2
共398兲
A
52.1
共380兲
A
关87/5兴
关629-50-5兴
关96/22兴
关96/22兴
关96/22兴
关96/22兴
关96/22兴
关96/22兴
关94/12兴
关79/2兴
关79/2兴
关79/2兴
关79/2兴
关72/29兴
关71/28兴
关87/5兴关55/7兴
关1560-97-0兴
关87/5兴
关17312-57-1兴
关87/5兴
关6117-97-1兴
关87/5兴
关17453-93-9兴
关87/5兴
关17312-77-5兴
关87/5兴
关17312-80-0兴
关87/5兴
48.7
共367兲
A
关87/5兴
61.4⫾1.1
60.5⫾1.1
61.4⫾1.8
共290兲
共298兲
共298兲
HSA
CGC
52.6
共313兲
A, MG
关95/27兴
关95/27兴
关95/27兴
关17312-63-9兴
关87/5兴关55/11兴
Compound
共Temperature range/K兲
N-decyl lactamide
共413– 483兲
O-decyl lactamide
共413– 483兲
tridecane
共417–511兲
2-methyldodecane
共373–503兲
3-methyldodecane
共372–504兲
4-methyldodecane
共372–501兲
5-methyldodecane
共368 –500兲
2,3-dimethylundecane
共383–500兲
2,4-dimethylundecane
共365– 490兲
2,4,6-trimethyldecane
共352– 478兲
5-ethyl-5-methyldecane
共273–307兲
5-butylnonane
共298 –365兲
pentyl tert-octyl ether
55.9⫾0.3
1-tridecanol
共307–348兲
91.1
共307–348兲
95.8
共313–373兲
87.4
共431–568兲
69.2
2,2-dimethyl-3-tert-butyl-3-heptanol
共379–513兲
58.3
3,3,5,5-tetramethyl-4-ethyl-4-heptanol
共393–526兲
55.9
3,3,6-trimethyl-4-isopropyl-4-heptanol
共381–512兲
59.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
C
C
C
C
A
共298兲
CAS registry number
Reference
关765-09-3兴
关87/5兴关61/13兴
关70/14兴
关822-13-9兴
关87/5兴关61/13兴
关70/14兴
关1536-21-6兴
关87/5兴关61/13兴
关70/14兴
关35599-77-0兴
关87/5兴关61/13兴
关70/14兴
共394兲
关U/2兴关02/32兴
关112-70-9兴
关01/3兴
关01/3兴
关92/14兴
关87/5兴
关42930-67-6兴
关73/26兴
共408兲
关73/26兴
共396兲
关73/26兴
共327兲
共298兲
共343兲
共446兲
GS
GS
A
ENTHALPIES OF VAPORIZATION
765
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C13H28O
C13H28O
C13H28O4
C13H28S
C13H29N
C14H8 Cl4
C14H8 O2
C14H8 O4
C14H9 Cl5
C14H9 Cl5
C14H9 Cl5
C14H10
C14H10
C14H10
C14H10Cl4
C14H10Cl4
C14H10Cl4
C14H10Cl4
C14H10Cl4
C14H10Cl4
C14H10Cl4
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
3,3,6-trimethyl-4-propyl-4-heptanol
共383–513兲
60.1
共398兲
2,2,5-trimethyl-3-tert-butyl-3-hexanol
共377–513兲
57.6
共392兲
tripropylene glycol, monobutyl ether
共374 –543兲
67.1
共389兲
1-tridecanethiol
共433–598兲
64.7
共448兲
tridecylamine
共458 –562兲
60.1
共473兲
p,p⬘-DDE
共343– 453兲
87.2
共398兲
9,10-anthraquinone
共559– 660兲
64.3
共574兲
1,4-dihydroxy-9,10-anthraquinone
共469– 633兲
74.0
共484兲
1,1,1-trichloro-2,2-bis共4-chlorophenyl兲ethane 共p,p⬘DDT兲
106.1⫾1.3
共398兲
共343– 453兲
93.2
共398兲
1,1,1-trichloro-2-共4-chlorophenyl兲2-共2-chlorophenyl兲ethane 共p,o⬘DDT兲
共343– 453兲
88.6
共398兲
DDT
共313–363兲
83.7
共338兲
anthracene
共323– 473兲
72.4
共398兲
79.1
共298兲
79.8
共298兲
共453–503兲
79.6
共298兲
共343– 453兲
69.7
共398兲
共504 – 615兲
58.6
共519兲
共500– 616兲
59.2
共558兲
共500– 616兲
60.3
共515兲
共496 – 614兲
59.6
共555兲
共496 – 614兲
60.7
共511兲
phenanthrene
共323– 473兲
72.2
共398兲
78.7
共298兲
共403– 453兲
78.5
共298兲
共343– 453兲
71.2
共398兲
共391– 613兲
58.2
共406兲
共373– 423兲
69.6
共388兲
71.2
共372兲
共476 – 620兲
57.2
共548兲
共476 – 620兲
61.2
共491兲
共505– 614兲
59.3
共560兲
共505– 614兲
61.2
共520兲
diphenylacetylene
共439–517兲
63.8⫾0.2
共440兲
共439–517兲
60.9⫾0.2
共480兲
共439–517兲
58.1⫾0.3
共520兲
1,1-dichloro-2,2-bis共4-chlorophenyl兲ethane p,p⬘-DDD
共343– 453兲
88.5
共398兲
共2,2⬘,4,6⬘-tetrachloro-5-methyldiphenyl兲methane
98.6
共298兲
共2,2⬘,4,5⬘-tetrachloro-5-methyldiphenyl兲methane
101.0
共298兲
共2,2⬘,5,5⬘-tetrachloro-4-methyldiphenyl兲methane
101.2
共298兲
共2,2⬘,4,4⬘-tetrachloro-5-methyldiphenyl兲methane
101.3
共298兲
共2,2⬘,4,6⬘-tetrachloro-3-methyldiphenyl兲methane
100.1
共298兲
共2⬘,3,4,6⬘-tetrachloro-6-methyldiphenyl兲methane
101.1
共298兲
Method
A
A, EST
GC
A
A
GS
GC
GC
GC
CGC
CGC
CGC
GC
A
I
I
I
I
GC
CGC
CGC
GC
A
A
I
I
I
I
EB
EB
EB
GC
GC
GC
GC
GC
GC
GC
CAS registry number
Reference
关73/26兴
关32579-70-7兴
关73/26兴
关57499-93-1兴
关87/5兴关47/5兴
关19484-26-5兴
关99/16兴
关2869-34-3兴
关87/5兴关56/17兴
关72-55-9兴
关90/2兴
关84-65-1兴
关87/5兴
关81-64-1兴
关87/5兴关47/5兴
关50-29-3兴
关01/1兴
关90/2兴
关789-02-6兴
关90/2兴
关49/3兴
关120-12-7兴
关02/18兴
关01/1兴
关98/11兴
关95/21兴
关90/2兴
关87/5兴
关23/1兴
关23/1兴关84/9兴
关22/1兴
关22/1兴关84/9兴
关85-01-8兴
关02/18兴
关98/11兴
关95/21兴
关90/2兴
关87/5兴
关87/5兴关75/11兴
关77/22兴
关23/1兴
关23/1兴关84/9兴
关22/1兴
关22/1兴关84/9兴
关501-65-5兴
关02/17兴
关02/17兴
关02/17兴
关72-54-8兴
关90/2兴
关121107-48-0兴
关96/24兴
关121107-46-8兴
关96/24兴
关121107-54-8兴
关96/24兴
关121107-44-6兴
关96/24兴
关121107-47-9兴
关96/24兴
关121107-83-5兴
关96/24兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
766
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C14H10Cl4
C14H10Cl4
C14H10Cl4
C14H10O2
C14H10O3
C14H11F3
C14H12
C14H12
C14H12
C14H12
C14H12
C14H12
C14H12O
C14H12O
C14H12O
C14H12O
C14H12O2
C14H12O2
C14H12O3
C14H12O3
C14H12O4
C14H13N
C14H14
C14H14
C14H14
C14H14
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共2,2⬘,4,4⬘-tetrachloro-3-methyldiphenyl兲methane
101.8
共2,3⬘,4,4⬘-tetrachloro-5-methyldiphenyl兲methane
103.8
共2⬘3,4,4⬘-tetrachloro-6-methyldiphenyl兲methane
103.0
benzil
共401– 620兲
69.2
benzoic acid anhydride
共416 – 633兲
69.1
1,1,1-trifluoro-2,2-diphenylethane
共286 –328兲
69.1⫾0.9
1-methylfluorene
共323– 473兲
71.1
9-methylfluorene
共318 –358兲
66.5
9,10-dihydrophenanthene
共417– 453兲
64.0
共353– 418兲
72.3⫾0.6
共353– 418兲
76.6⫾0.1
1,1-diphenylethylene
共360–550兲
59.3
cis 1,2-diphenylethylene 共cis stilbene兲
共373– 428兲
66.5
trans 1,2-diphenylethylene 共trans stilbene兲
79.7
共453–503兲
79.8
共403– 453兲
79.6
共419–580兲
65.5
benzyl phenyl ketone
共396 –594兲
68.1
2-methylbenzophenone
共435–580兲
65.1
3-methylbenzophenone
共445–585兲
68.4
4-methylbenzophenone
共450– 492兲
72.0
(dl) benzoin
共408 – 616兲
69.0
benzyl benzoate
共497– 602兲
59.7
共297–353兲
77.7
benzyl salicylate
共295–334兲
78.7
2-hydroxy-4-methoxybenzophenone
共337– 413兲
74.7
2,2⬘-dihydroxy-4-methoxybenzophenone
共342– 481兲
75.6
N-benzylbenzaldehyde-imine
共309–340兲
83.4⫾1.2
共309–340兲
85.0⫾1.2
共4-methylphenyl兲phenylmethane
共293–333兲
68.6⫾0.3
共293–333兲
69.5⫾0.3
3,3⬘-dimethylbiphenyl
共288 –308兲
71.9
1,1-diphenylethane
共293–328兲
68.2⫾0.6
共293–328兲
68.9⫾0.6
共348 – 405兲
62.4
1,2-diphenylethane
共323– 473兲
67.4
66.2⫾0.2
共333– 413兲
64.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共298兲
GC
共298兲
GC
共298兲
GC
共416兲
A
共431兲
A
共298兲
GS
共398兲
GC
共298兲
B
共432兲
共340兲
共298兲
A
共375兲
A
共388兲
A
共298兲
共298兲
共298兲
共434兲
CGC
CGC
CGC
A
共411兲
A
共450兲
A
共460兲
A
共465兲
A
共423兲
A
共512兲
共312兲
A, EB
A, ME
共310兲
A, ME
共352兲
A, UV
共357兲
A, UV
关121107-43-5兴
关96/24兴
关121107-65-1兴
关96/24兴
关121107-77-5兴
关96/24兴
关134-81-6兴
关87/5兴关47/5兴
关93-97-0兴
关87/5兴关47/5兴
关384-94-1兴
关97/14兴
关1730-37-6兴
关02/18兴
关2523-37-7兴
关94/4兴
关776-35-2兴
关87/5兴
关79/5兴
关79/5兴
关530-48-3兴
关87/5兴关47/5兴
关645-49-8兴
关87/5兴
关103-30-0兴
关98/11兴
关95/21兴
关95/21兴
关87/5兴
关451-40-1兴
关87/5兴关47/5兴
关131-58-8兴
关87/5兴
关643-65-2兴
关87/5兴
关134-84-9兴
关87/5兴
关579-44-2兴
关87/5兴关47/5兴
关120-51-4兴
关87/5兴关76/13兴
关87/5兴关57/9兴
关118-58-1兴
关87/5兴关55/8兴
关131-57-7兴
关87/5兴关60/2兴
关131-53-3兴
关87/5兴关60/2兴
共324兲
共298兲
GS
GS
关97/9兴
关97/9兴
共313兲
共298兲
GS
GS
共298兲
A
共313兲
共298兲
共363兲
GS
GS
A
共398兲
共340兲
共373兲
GC
关99/8兴
关99/8兴
关612-75-9兴
关87/5兴
关612-00-0兴
关99/8兴
关99/8兴
关87/5兴
关103-29-7兴
关02/18兴
关88/16兴
关89/14兴
ENTHALPIES OF VAPORIZATION
767
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C14H14N2 O3
C14H14O
C14H14O
C14H14O
C14H14O
C14H14O2
C14H15N
C14H15N
C14H16N2 O2
C14H16N2 O2
C14H17Cl3 O3
C14H18
C14H18
C14H18Cl2 O3
C14H18Cl2 O3
C14H18O
C14H18O4
C14H18O4
C14H19NO
C14H20
C14H20
C14H20
C14H20Cl2
C14H20Cl2
C14H20O
C14H20O3
C14H20O5
C14H21F3 N2 O4
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共359–557兲
57.0
4,4⬘-dimethoxyazoxybenzene
共395– 418兲
73.7
dibenzyl ether
共275– 417兲
45.6
共413– 461兲
59.4
isopropyl 2-naphthyl ketone
共406 –586兲
75.9
2-共1-phenylethyl兲phenol
共443–521兲
82.8
共442–523兲
72.8
4-共1-phenylethyl兲phenol
共447–517兲
90.8
共447–523兲
75.4
2-共2-biphenyloxy兲ethanol
共410– 608兲
71.9
dibenzylamine
共391–573兲
70.5
N,N-diphenyl-N-ethylamine
共371–559兲
63.2
1,3-bis共1-isocyanato-1-methylethyl兲benzene
共298 – 426兲
65.2
1,4-bis共1-isocyanato-1-methylethyl兲benzene
共373– 428兲
74.0
hexyl 2,4,5-trichlorophenoxyacetate
共460–573兲
85.3
1,2,3,4,5,6,7,8-octahydroanthracene
共437– 498兲
45.6
共348 – 433兲
NA
1,2,3,4,5,6,7,8-octahydrophenanthrene
共402–570兲
55.8
hexyl 2,4-dichlorophenoxyacetate
共444 –573兲
81.3
isohexyl 2,4-dichlorophenoxyacetate
共460–573兲
69.1
␣-pentylcinnamaldehyde
共282–333兲
75.3
dipropyl phthalate
共403–578兲
73.2
diisopropyl phthalate
74.8
hexahydro-1-共phenylacetyl兲-1H-azepine
共370– 418兲
53.9
共371– 420兲
49.4
1-cyclohexyl-1-phenylethane
共359– 400兲
70.8
1-cyclohexyl-2-phenylethane
共372– 406兲
60.7
1-cyclopentyl-3-phenylpropane
共373–540兲
61.3
1,2-dichloro-3,4,5,6-tetraethylbenzene
共378 –575兲
66.2
1,4-dichloro-2,3,5,6-tetraethylbenzene
共364 –570兲
60.8
共1-cyclohexyloxyethyl兲benzene
共286 –338兲
69.8⫾0.5
2-共4-tert-butylphenoxy兲ethyl acetate
共391–578兲
78.8
benzo-15-crown-5
98.9⫾1.3
proline, 1-关N-共trifluoroacetyl兲-共l兲-leucyl兴methyl ester
共366 – 453兲
105.8
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共374兲
A
共406兲
A
共290兲
共428兲
A
A
共421兲
A
共458兲
共482兲
A
共462兲
共485兲
A
共425兲
A
共406兲
A
共386兲
A
关87/5兴关47/5兴
关1562-94-3兴
关87/5兴
关103-50-4兴
关87/5兴
关87/5兴
关59502-28-2兴
关87/5兴关47/5兴
关52857-29-1兴
关87/5兴
关39/4兴
关1988-89-2兴
关87/5兴
关39/4兴
关7501-02-2兴
关87/5兴
关103-49-1兴
关87/5兴关47/5兴
关606-99-5兴
关87/5兴关47/5兴
共361兲
HSA, T, DTA
关86/3兴
共400兲
HSA, T, DTA
共475兲
A
共452兲
A
IPM
共417兲
A
共459兲
A
关86/3兴
关2630-13-9兴
关87/5兴
关1079-71-6兴
关87/5兴
关82/16兴
关5325-97-3兴
关87/5兴
关1917-95-9兴
关87/5兴
共475兲
A
共297兲
A, ME
共418兲
A
共430兲
BG
共385兲
共396兲
A
共374兲
A, MG
共387兲
A, MG
共388兲
A, MG
关87/5兴关99/16兴
关122-40-7兴
关87/5兴关55/8兴
关131-16-8兴
关87/5兴
关88/17兴
关18494-61-6兴
关87/5兴关69/1兴
关69/1兴
关4413-16-5兴
关87/5兴关55/11兴
关1603-61-8兴
关87/5兴关55/11兴
关2883-12-7兴
关87/5兴关55/11兴
共393兲
关87/5兴关47/5兴
关70/14兴
共379兲
关87/5兴关47/5兴
关70/14兴
关61812-55-3兴
关02/29兴关02/38兴
共298兲
GS
共406兲
A
共298兲
CGC
关87/5兴关47/5兴
关14098-44-3兴
关00/9兴
共381兲
A
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
768
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C14H22
C14H22
C14H22
C14H22
C14H22
C14H22
C14H22
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O
C14H22O11
C14H23N
C14H24
C14H24N2
C14H24O
C14H24O
Compound
共Temperature range/K兲
1,4-di-tert-butylbenzene
共387–559兲
1,3-di-tert-butylbenzene
共288 –333兲
共346 –374兲
octylbenzene
共293– 462兲
共368 – 400兲
共316 –399兲
2-phenyloctane
共361–392兲
1,2,3,4-tetraethylbenzene
共423–525兲
1,2,3,5-tetraethylbenzene
共413–521兲
1,2,4,5-tetraethylbenzene
共338 –521兲
2,4-di-tert-butylphenol
共333–368兲
共403–537兲
2,6-di-tert-butylphenol
共313–368兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
63.0⫾0.6
共298兲
EB
58.9⫾0.5
59.6⫾0.5
58.0
共310兲
共298兲
共360兲
GS
67.4
63.1
66.2
共308兲
共383兲
共336兲
61.6
70.0
共376兲
共298兲
A
62.6
共438兲
A
64.8
共428兲
A
54.5
共353兲
A
69.2⫾0.5
72.4⫾0.5
60.1
共350兲
共298兲
共418兲
GS
63.5⫾0.2
66.0⫾0.2
60.4
共341兲
共298兲
共401兲
GS
共419兲
A
共463兲
A
共430兲
A
关87/5兴
关59048-99-6兴
关87/5兴
共424兲
A
关87/5兴
共428兲
A
共303兲
A
共303兲
A
共428兲
A
共303兲
A
共303兲
A
共329兲
共298兲
共396兲
GS
关87/5兴
关79-70-9兴
关87/5兴
关127-51-5兴
关87/5兴
关1988-35-8兴
关87/5兴
关127-42-4兴
关87/5兴
关127-43-5兴
关87/5兴
关140-66-9兴
关99/18兴
关99/18兴
关87/5兴关59/1兴
关84/9兴
共386 –530兲
4-共1,1-diethylbutyl兲phenol
共404 –549兲
69.5
2,4-diisobutylphenol
共448 –598兲
65.0
4-关共1,2-dimethyl-1-ethyl兲butyl兴phenol
共415–578兲
64.7
4-关共1,3-dimethyl-1-ethyl兲butyl兴phenol
共409–571兲
60.9
4-关共2,2-dimethyl-1-ethyl兲butyl兴phenol
共413–553兲
67.0
␤-irone
共288 –333兲
72.1
␣-isomethylionone
共288 –333兲
69.5
4-关共1-methyl-1-ethyl兲pentyl兴phenol
共413–578兲
62.8
␣-methylionone
共288 –333兲
70.1
␤-methylionone
共288 –333兲
70.3
4-共1,1,3,3-tetramethylbutyl兲phenol
共309–350兲
68.8⫾0.3
70.7⫾0.3
共381–563兲
72.4
diethylenel glycol, O,O-dicarboxylic acid, di关1-共methoxycarbonyl兲-ethyl兴 ester
共403– 493兲
98.2
共418兲
N,N-dimethyl-2,3-dimethyl-3-phenyl-2-butanamine
共280–335兲
65.8⫾1.3
共308兲
共280–335兲
66.4⫾1.3
共298兲
perhydrophenanthrene
共455–551兲
55.7
共470兲
N,N⬘-di-sec-butyl-1,4-phenylenediamine
共370–507兲
70.3
共385兲
2,2,5,9-tretamethyl-4,8-decanedienal
共353– 416兲
66.4
共368兲
borneol butyrate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
GS
A
A
A
CAS registry number
Reference
关1012-72-2兴
关97/8兴
关1014-60-4兴
关98/19兴
关98/19兴
关87/5兴
关2189-60-8兴
关93/10兴
关87/5兴
关86/6兴
关777-22-0兴
关87/5兴
关71/28兴
关642-32-0兴
关87/5兴
关38842-05-6兴
关87/5兴
关635-81-4兴
关87/5兴
关96-76-4兴
关99/18兴
关99/18兴
关87/5兴
关128-39-2兴
关99/19兴
关99/19兴
关87/5兴
关63264-81-3兴
关87/5兴
A
关87/5兴
GS
GS
关98/1兴
关98/1兴
关5743-97-5兴
关00/16兴
关101-96-2兴
关87/5兴
关53131-20-7兴
关87/5兴
EB
A
A
ENTHALPIES OF VAPORIZATION
769
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C14H24O
C14H24O
C14H24O
C14H24O6
C14H26
C14H26
C14H26
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
C14H26O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共347–520兲
59.6
(dl) borneol isobutyrate
共343–516兲
58.8
geraniol butyrate
共369–531兲
68.6
geraniol isobutyrate
共363–524兲
67.8
1,1,1-tris共ethoxycarbonyl兲pentane
共298 –343兲
81.4⫾0.4
1-cyclohexyl-3-cyclopentylpropane
共371– 403兲
64.5
1,1-dicyclohexylethane
共370– 402兲
62.1
1,2-dicyclohexylethane
共371– 402兲
65.4
cis 2,2,5,9-tetramethyl-4,8-decadiene-1-ol
共363–393兲
94.0
trans 2,2,5,9-tetramethyl-4,8-decadiene-1-ol
共363–393兲
86.3
共Z兲 2-tetradecenal
共353–393兲
82.5
共E兲 2-tetradecenal
共353–393兲
82.6
共Z兲 3-tetradecenal
共353–393兲
79.4
共E兲 3-tetradecenal
共353–393兲
80.1
共Z兲 4-tetradecenal
共353–393兲
79.2
共E兲 4-tetradecenal
共353–393兲
79.9
共Z兲 5-tetradecenal
共353–393兲
78.4
共E兲 5-tetradecenal
共353–393兲
79.1
共Z兲 6-tetradecenal
共353–393兲
78.5
共E兲 6-tetradecenal
共353–393兲
79.3
共Z兲 7-tetradecenal
共353–393兲
78.7
共E兲 7-tetradecenal
共353–393兲
79.2
共Z兲 8-tetradecenal
共353–393兲
78.8
共E兲 8-tetradecenal
共353–393兲
79.3
共Z兲 9-tetradecenal
共353–393兲
79.1
共E兲 9-tetradecenal
共353–393兲
79.5
共Z兲 10-tetradecenal
共353–393兲
79.6
共E兲 10-tetradecenal
共353–393兲
79.8
共Z兲 11-tetradecenal
共353–393兲
80.3
共E兲 11-tetradecenal
共353–393兲
80.5
共Z兲 12-tetradecenal
共353–393兲
80.8
共E兲 12-tetradecenal
共353–393兲
80.8
2-共1,2-dimethylpropyl兲-5,6-dimethylheptenal
Mean temperature
(T m /K)
Method
共362兲
A
共358兲
A
关87/5兴关47/5兴
关24717-86-0兴
关87/5兴关47/5兴
共384兲
A
关87/5兴关47/5兴
共378兲
A
关87/5兴关47/5兴
GS
关95/8兴
关2883-07-0兴
关87/5兴
关2319-61-1兴
关87/5兴
关3321-50-4兴
关87/5兴
关53965-17-6兴
关87/5兴
关53965-18-7兴
关87/5兴
关142628-55-5兴
关96/7兴关00/10兴
关51534-36-2兴
关96/7兴关00/10兴
关174155-51-2兴
关96/7兴关00/10兴
关174155-50-1兴
关96/7兴关00/10兴
关115018-49-0兴
关96/7兴关00/10兴
关115018-39-8兴
关96/7兴关00/10兴
关63851-42-3兴
关96/7兴关00/10兴
关174155-52-3兴
关96/7兴关00/10兴
关174155-53-4兴
关96/7兴关00/10兴
关174155-54-5兴
关96/7兴关00/10兴
关65128-96-3兴
关96/7兴关00/10兴
关37011-96-4兴
关96/7兴关00/10兴
关169054-69-7兴
关96/7兴关00/10兴
关174155-55-6兴
关96/7兴关00/10兴
关53939-27-8兴
关96/7兴关00/10兴
关71377-13-4兴
关96/7兴关00/10兴
关144525-16-6兴
关96/7兴关00/10兴
关148238-39-5兴
关96/7兴关00/10兴
关35237-64-0兴
关96/7兴关00/10兴
关35746-21-5兴
关96/7兴关00/10兴
关174155-56-7兴
关96/7兴关00/10兴
关124499-92-9兴
关96/7兴关00/10兴
共386兲
A
共385兲
A
共386兲
A
共378兲
A
共378兲
A
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
CAS registry number
Reference
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
770
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C14H26O
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O2
C14H26O3
C14H26O3
C14H26O3
C14H26O4
C14H26O4
C14H26O4
C14H26O4
C14H26O5
C14H26O5
C14H27N
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共385–535兲
2-pentyl-2-nonenal
共385–553兲
decyl methacrylate
共350–541兲
共Z兲 2-dodecenyl acetate
共333–378兲
共E兲 2-dodecenyl acetate
共333–378兲
共Z兲 3-dodecenyl acetate
共333–378兲
共E兲 3-dodecenyl acetate
共333–378兲
共Z兲 4-dodecenyl acetate
共333–378兲
共E兲 4-dodecenyl acetate
共333–378兲
共Z兲 5-dodecenyl acetate
共333–378兲
共E兲 5-dodecenyl acetate
共333–378兲
共Z兲 6-dodecenyl acetate
共333–378兲
共E兲 6-dodecenyl acetate
共333–378兲
共Z兲 7-dodecenyl acetate
共333–378兲
共303–317兲
共E兲 7-dodecenyl acetate
共333–378兲
共Z兲 8-dodecenyl acetate
共333–378兲
共E兲 8-dodecenyl acetate
共333–378兲
共Z兲 9-dodecenyl acetate
共333–378兲
共E兲 9-dodecenyl acetate
共333–378兲
共Z兲 10-dodecenyl acetate
共333–378兲
共E兲 10-dodecenyl acetate
共333–378兲
1,7-dioxa-8-cyclohexadecanone
共403– 453兲
3-heptyl-4-acetoxytetrahydro-2H-pyran
共383– 453兲
nonyl levulinate
共423–571兲
Mean temperature
(T m /K)
Method
60.0
共400兲
EB
65.0
共409兲
EB
62.7
共365兲
A
79.7
共298兲
GC
81.0
共298兲
GC
79.3
共298兲
GC
79.8
共298兲
GC
78.6
共298兲
GC
79.8
共298兲
GC
79.2
共298兲
GC
80.0
共298兲
GC
79.3
共298兲
GC
80.0
共298兲
GC
79.8
77.5
共298兲
共310兲
GC
GC
80.2
共298兲
GC
80.2
共298兲
GC
80.5
共298兲
GC
80.7
共298兲
GC
81.0
共298兲
GC
81.4
共298兲
GC
81.5
共298兲
GC
73.3
共418兲
A
74.4
共398兲
A
69.4
68.4
共438兲
共516兲
A
共450兲
A
关87/5兴
关33/6兴
关105-99-7兴
关87/5兴
共403兲
A
关87/5兴
共409兲
A
共413兲
A
关87/5兴
关110-40-7兴
关87/5兴关47/5兴
共428兲
A
关87/5兴
共372兲
A
共406兲
共298兲
A
C
关87/5兴
关629-63-0兴
关87/5兴
关77/5兴
dibutyl adipate
共435–563兲
68.7
diethyl isopentylmalonate
共388 –526兲
75.3
2-methylheptane-5,5-dicarboxylic acid, diethyl ester
共394 – 427兲
70.1
diethyl decanedioate
共398 –579兲
74.1
ethyl关1-共1-octyloxycarbonyl兲ethyl兴carbonate
共413–513兲
74.0
hexyl关1-共1-butoxycarbonyl兲ethyl兴carbonate
共357–501兲
72.1
myristonitrile
共391–580兲
71.4
85.3⫾0.5
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关87/3兴
关3021-89-4兴
关87/3兴
关3179-47-3兴
关87/5兴
关84801-15-0兴
关97/13兴关00/10兴
关84801-16-1兴
关97/13兴关00/10兴
关38363-24-5兴
关97/13兴关00/10兴
关56218-63-4兴
关97/13兴关00/10兴
关38363-25-6兴
关97/13兴关00/10兴
关38363-26-7兴
关97/13兴关00/10兴
关16676-96-3兴
关97/13兴关00/10兴
关16676-97-4兴
关97/13兴关00/10兴
关16974-12-2兴
关97/13兴关00/10兴
关29868-16-4兴
关97/13兴关00/10兴
关14959-86-5兴
关97/13兴关00/10兴
关83/10兴
关16695-41-3兴
关97/13兴关00/10兴
关28079-04-1兴
关97/13兴关00/10兴
关38363-29-0兴
关97/13兴关00/10兴
关16974-11-1兴
关97/13兴关00/10兴
关35148-19-7兴
关97/13兴关00/10兴
关35148-20-0兴
关97/13兴关00/10兴
关35153-09-4兴
关97/13兴关00/10兴
关5963-13-3兴
关87/5兴
关23144-23-2兴
关87/5兴
ENTHALPIES OF VAPORIZATION
771
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C14H28
C14H28
C14H28
C14H28
C14H28
C14H28
C14H28
C14H28N2 O2
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
C14H28O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
关295-17-0兴
关92/4兴
关92/4兴
cyclotetradecane
62.3⫾0.2
65.3⫾0.2
3-tert-butyl-1-methyl-4-isopropylcyclohexane
共329–505兲
53.8
共1-methylheptyl兲cyclohexane
共364 –397兲
60.4
octylcyclohexane
共367–399兲
62.7
69.8
nonylcyclopentane
70.7
1-tetradecene
70.2
共430–527兲
56.5
2,2,3,5,5,6,6-heptamethyl-3-heptene
共303–355兲
51.2
tetrapropyloxamide
67
1-octylcyclohexanol
共373– 403兲
105.6
共Z兲 2-tetradecen-1-ol
共353–393兲
101.1
共E兲 2-tetradecen-1-ol
共353–393兲
101.5
共Z兲 3-tetradecen-1-ol
共353–393兲
99.8
共E兲 3-tetradecen-1-ol
共353–393兲
99.7
共Z兲 4-tetradecen-1-ol
共353–393兲
100.0
共E兲 4-tetradecen-1-ol
共353–393兲
100.7
共Z兲 5-tetradecen-1-ol
共353–393兲
100.3
共E兲 5-tetradecen-1-ol
共353–393兲
100.8
共Z兲 6-tetradecen-1-ol
共353–393兲
100.0
共E兲 6-tetradecen-1-ol
共353–393兲
100.5
共Z兲 7-tetradecen-1-ol
共353–393兲
99.9
共E兲 7-tetradecen-1-ol
共353–393兲
100.5
共Z兲 8-tetradecen-1-ol
共353–393兲
100.3
共E兲 8-tetradecen-1-ol
共353–393兲
101.4
共Z兲 9-tetradecen-1-ol
共353–393兲
100.6
共E兲 9-tetradecen-1-ol
共353–393兲
101.0
共Z兲 10-tetradecen-1-ol
共353–393兲
101.1
共E兲 10-tetradecen-1-ol
共353–393兲
101.5
共Z兲 11-tetradecen-1-ol
共353–393兲
101.7
共E兲 11-tetradecen-1-ol
共353–393兲
101.8
共Z兲 12-tetradecen-1-ol
共353–393兲
102.5
共E兲 12-tetradecen-1-ol
CAS registry number
Reference
共343兲
共298兲
共344兲
A
关87/5兴
共379兲
A
共382兲
共298兲
A
共298兲
共445兲
A
关87/5兴
关1795-15-9兴
关87/5兴
关71/28兴
关2882-98-6兴
关71/28兴
关1120-36-1兴
关71/28兴
关87/5兴关55/7兴
共318兲
A, MG
关87/5兴关55/11兴
共489兲
TGA, DSC
共388兲
A
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
关02/36兴
关5770-04-7兴
关87/5兴
关75039-85-9兴
关00/10兴关94/13兴
关75039-86-0兴
关00/10兴关94/13兴
关68892-27-3兴
关00/10兴关94/13兴
关68900-86-7兴
关00/10兴关94/13兴
关40642-41-9兴
关00/10兴关94/13兴
关59101-24-5兴
关00/10兴关94/13兴
关40642-42-0兴
关00/10兴关94/13兴
关62936-14-5兴
关00/10兴关94/13兴
关68760-63-4兴
关00/10兴关94/13兴
关68760-62-3兴
关00/10兴关94/13兴
关40642-43-1兴
关00/10兴关94/13兴
关37011-95-3兴
关00/10兴关94/13兴
关64470-32-2兴
关00/10兴关94/13兴
关64437-34-9兴
关00/10兴关94/13兴
关35153-15-2兴
关00/10兴关94/13兴
关52957-16-1兴
关00/10兴关94/13兴
关57393-02-9兴
关00/10兴关94/13兴
关64437-35-0兴
关00/10兴关94/13兴
关34010-15-6兴
关00/10兴关94/13兴
关35153-18-5兴
关00/10兴关94/13兴
关70711-48-7兴
关00/10兴关94/13兴
关70711-49-8兴
共298兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
772
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C14H28O
C14H28O
C14H28O
C14H28O2
C14H28O2
C14H28O2
C14H28O2
C14H28O3
C14H29Br
C14H29Cl
C14H29F
C14H29I
C14H30
Compound
共Temperature range/K兲
共353–393兲
2-tetradecanone
共411–560兲
共549– 643兲
共412– 643兲
共372–551兲
7-tetradecanone
共438 – 462兲
tetradecanal
共343–383兲
共372–571兲
dodecyl acetate
共333–378兲
共398 –540兲
ethyl dodecanoate
共423– 483兲
共386 – 435兲
methyl tridecanoate
共377–504兲
tetradecanoic acid
共383– 459兲
共423–599兲
共339–358兲
decyl 3-methoxypropionate
共403–513兲
1-bromotetradecane
共437– 645兲
1-chlorotetradecane
共313–373兲
共313–373兲
共313–373兲
共313–373兲
共414 –570兲
1-fluorotetradecane
共288 –335兲
共400–593兲
1-iodotetradecane
共452– 672兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
102.5
共298兲
CGC
65.6
55.6
51.6
64.4
共426兲
共564兲
共556兲
共387兲
A
A
66.9
共450兲
A, ME
80.2
63.4
共298兲
共387兲
CGC
A
81.8
70.5
共298兲
共413兲
GC
A
80.0
67.2
共298兲
共401兲
GC
A
74.0
72.3⫾0.1
80.0⫾0.5
81.3⫾0.7
82.7⫾0.8
72.6
共350兲
共368兲
共298兲
共298兲
共298兲
共392兲
GC, C
C
A, EST
100.4
91.6
104.1⫾2.0
88.9
共398兲
共438兲
共349兲
共455兲
A
A
ME, TE
I
68.9
共418兲
A
67.1
共452兲
A, EST
80.2
78.0
74.4
72.9
68.7
共313兲
共333兲
共353兲
共373兲
共429兲
GC
GC
GC
GC
A, DTA
73.5⫾0.4
61.4
共298兲
共415兲
GS
A, EST
68.6
共467兲
A, EST
72.1
72.0⫾2.4
69.0
68.6
67.9
66.8
65.7
71.2
71.4
71.7
67.8
64.1
70.1
68.9
71.8⫾0.6
71.1⫾0.4
共298兲
共298兲
共324兲
共329兲
共334兲
共344兲
共359兲
共298兲
共298兲
共298兲
共328兲
共361兲
共313兲
共328兲
共298兲
共298兲
GS
CGC
C
C
C
C
C
CGC
CGC
A
tetradecane
共423– 473兲
共363– 413兲
共313– 433兲
共343–395兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
GS
C
C
C
C
CAS registry number
Reference
关00/10兴关94/13兴
关2345-27-9兴
关87/5兴
关87/5兴
关75/8兴
关87/5兴关47/5兴
关6137-34-4兴
关87/5兴关38/8兴
关124-25-4兴
关96/7兴关00/10兴
关87/5兴关47/5兴
关112-66-3兴
关97/13兴关00/10兴
关87/5兴
关106-33-2兴
关97/28兴
关87/5兴
关1731-88-0兴
关02/27兴
关02/27兴
关02/27兴
关80/5兴
关77/1兴
关87/5兴关63/16兴
关544-63-8兴
关87/5兴
关87/5兴
关82/4兴
关43/7兴
关87/5兴
关112-71-0兴
关87/5兴关61/13兴
关70/14兴
关2425-54-9兴
关80/14兴
关80/14兴
关80/14兴
关80/14兴
关87/5兴关69/5兴
关593-33-9兴
关97/14兴
关87/5兴关61/13兴
关70/14兴
关19218-94-1兴
关87/5兴关61/13兴
关70/14兴
关629-54-4兴
关01/1兴
关00/9兴
关96/22兴
关96/22兴
关96/22兴
关96/22兴
关96/22兴
关95/21兴
关95/21兴
关94/12兴
关87/5兴
关86/6兴
关79/2兴
关79/2兴
关79/2兴
关72/29兴
ENTHALPIES OF VAPORIZATION
773
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C14H30
C14H30
C14H30
C14H30
C14H30
C14H30
C14H30
C14H30
C14H30
C14H30
C14H30
C14H30O
C14H30O
C14H30O
C14H30O
C14H30O
C14H30O
C14H30O
C14H30O2
C14H30S
C14H30S2
C14H31N
C14H31N
C14H31N
C14H31O2 P
C15H8 Cl3 NO2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
71.7
共298兲
共432–529兲
57.1
共447兲
共429– 468兲
57.8
共449兲
2-methyltridecane
共388 –530兲
56.3
共403兲
3-methyltridecane
共389–521兲
55.1
共404兲
4-methyltridecane
共386 –520兲
54.2
共401兲
5-methyltridecane
共385–518兲
53.8
共400兲
7-methyltridecane
共357–389兲
59.0
共372兲
2,3-dimethyldodecane
共385–519兲
53.4
共400兲
2,4-dimethyldodecane
共379–509兲
54.0
共394兲
2,4,6-trimethylundecane
共368 – 491兲
53.2
共383兲
2,2,3,4,6,6-heptamethylheptane
共313–366兲
54.5
共366兲
hexaethylethane 共3,3,4,4-tetraethylhexane兲
共298 –307兲
63.9⫾1.2
共298兲
共283–302兲
65.7⫾1.2
共292兲
65.0⫾1.2
共298兲
2,2,3,3,4,4,5,5-octamethylhexane
共288 –325兲
56.9⫾0.7
共298兲
diheptyl ether
共360–547兲
63.1
共375兲
4-methylpentyl tert-octyl ether
57.5
共298兲
3-methylpentyl tert-octyl ether
58.0
共298兲
3,3-dimethylbutyl tert-octyl ether
56.4
共298兲
hexyl tert-octyl ether
59.2
共298兲
1-tetradecanol
共312–346兲
93.6
共328兲
共312–346兲
98.7
共298兲
共333– 438兲
81.8
共386兲
共317–358兲
109.0
共332兲
102.2⫾2.3
共298兲
共313–358兲
106.4
共328兲
共424 –569兲
76.6
共439兲
共313–326兲
104.2
共320兲
2-tetradecanol
共313– 428兲
95.7
共328兲
2-共dodecyloxy兲ethanol
共414 – 467兲
71.5
共429兲
1-tetradecanethiol
共446 – 614兲
67.3
共461兲
diheptyl disulfide
共458 – 630兲
69.8
共473兲
diheptylamine
共435– 605兲
60.0
共450兲
N,N-dimethyldodecylamine
共380– 604兲
64.4
共395兲
tetradecylamine
共471–577兲
62.4
共486兲
diheptylphosphinic acid
共482– 664兲
64.1
共573兲
2,2,4-trichloro-5-共2-naphthaleneylamino兲-4-cyclopentene-1,3-dione
共453– 483兲
91.4
共468兲
Method
A
ME
A
A
A
A
A
A
A
A
A, MG
GS
GS
GS
A
CAS registry number
Reference
关71/28兴
关87/5兴关55/7兴
关38/8兴
关1560-96-9兴
关87/5兴
关6418-41-3兴
关87/5兴
关26730-12-1兴
关87/5兴
关25117-31-1兴
关87/5兴
关26730-14-3兴
关87/5兴
关6117-98-2兴
关87/5兴
关6117-99-3兴
关87/5兴
关87/5兴
关7225-67-4兴
关87/5兴关55/11兴
关5171-86-8兴
关97/29兴
关73/30兴关95/27兴
关73/30兴
关65149-84-0兴
关97/29兴
关629-64-1兴
关87/5兴
关U/2兴关02/32兴
关U/2兴关02/32兴
关U/2兴关02/32兴
A, EST
关U/2兴关02/32兴
关112-72-1兴
关01/3兴
关01/3兴
关92/14兴
关87/5兴
关77/1兴
关73/26兴
关87/5兴关69/5兴
关65/15兴
关4706-81-4兴
关99/11兴
关4536-30-5兴
关87/5兴
关2079-95-0兴
关99/16兴
关10496-16-9兴
关99/16兴
关2470-68-0兴
关87/5兴
关112-18-5兴
关87/5兴
关2016-42-4兴
关87/5兴关56/17兴
GC
关71/32兴
关77765-38-9兴
关80/25兴
GS
GS
A
C
A
ME
A
A
A
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
774
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C15H9 N3
C15H9 N3
C15H10N2 O2
C15H10N2 O2
C15H10N2 O2
C15H11NO2
C15H12
C15H12
C15H12
C15H12O
C15H12O2
C15H14Cl3 O2 PS
C15H14O
C15H14O2
C15H14O2
C15H14O3
C15H14O5
C15H15Cl
C15H16
C15H16
C15H16
C15H16N4 O2
C15H16O
C15H16O
C15H16O2
C15H17NO2
C15H18
C15H18O
C15H19Cl3 O3
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
pyrido关2,3-f兴关1,7兴phenanthroline
共648 –707兲
65.1
共663兲
pyrido关3,2-f兴关1,7兴phenanthroline
共648 –706兲
67.4
共663兲
2,2⬘-diisocyanatodiphenylmethane
共343– 413兲
90.1
共358兲
2,4⬘-diisocyanatodiphenylmethane
共343– 413兲
89.3
共358兲
4,4⬘-diisocyanatodiphenylmethane
共343– 413兲
90.5
共358兲
共442–530兲
93.8
共457兲
共442–530兲
90.6
共483兲
1-methylamino-9,10-anthraquinone
共433– 493兲
103.5
共448兲
2-methylanthracene
共323– 473兲
76.1
共398兲
9-methylanthracene
共354 – 402兲
98.9
共369兲
共423–587兲
58.5
共465兲
共423–515兲
58.1
共515兲
共423–515兲
56.5
共555兲
1-methylphenanthrene
共323– 473兲
76.3
共398兲
dibenzosuberone
共314 –338兲
90.0⫾1.5
1,3-diphenyl-1,3-propanedione
共368 –383兲
60.1
共375兲
共chloromethyl兲thiophosphnic acid, O,O-bis共2-chloro-4-methylphenyl兲 ester
共343–365兲
93.2
共354兲
1,3-diphenylacetone
共398 – 604兲
65.7
共413兲
2,2-diphenyl-1,3-dioxolane
共331–370兲
84.6⫾0.6
共298兲
共331–370兲
81.2⫾0.6
1-biphenyloxy-2,3-epoxypropane
共408 – 613兲
80.0
共423兲
2-hydroxy-4-ethoxybenzophenone
共373– 433兲
90.7
共403兲
2,2⬘-dihydroxy-4,4⬘-dimethoxybenzophenone
共406 – 497兲
77.4
共423兲
chloro-di-4-tolylmethane
共406 – 453兲
75.2
共421兲
ditolylmethane
共573– 673兲
51.8
共588兲
1,1-diphenylpropane
共298 –343兲
71.4⫾0.4
共321兲
共298 –343兲
72.8⫾0.4
共298兲
1,3-diphenylpropane
共342–577兲
61.5
共357兲
3-methyl-3⬘-nitro-4-N,N-dimethylaminoazobenzene
共370–388兲
98.6
共379兲
di-共4-tolyl兲methanol
共413– 478兲
81.7
共428兲
1-isovaleronaphthone
共409–593兲
76.2
共424兲
Bisphenol A
共466 – 634兲
102.2
共481兲
N-共2-hydroxy-3-phenoxypropyl兲phenylamine
共343–373兲
113.9
共358兲
1-pentylnaphthalene
共415–535兲
62.7
共430兲
2,4,6-triallylphenol
共423–571兲
61.0
共438兲
2,4,5-trichlorophenoxyacetic acid, heptyl ester
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
A
关87/5兴
A
关87/5兴
关2536-05-2兴
关87/5兴
关5873-54-1兴
关87/5兴
关101-68-8兴
关87/5兴
关87/5兴
关66/28兴
关82-38-2兴
关87/5兴
关613-12-7兴
关02/18兴
关779-02-0兴
关87/5兴
关83/4兴
关83/4兴
关83/4兴
关832-69-9兴
关02/18兴
关1210-35-1兴
关98/4兴
关120-46-7兴
关87/5兴
关57875-65-7兴
关87/5兴关99/16兴
关102-04-5兴
关87/5兴关47/5兴
关4359-34-6兴
关02/32兴
关98/21兴
关7144-65-2兴
关87/5兴
关15889-70-0兴
关84/1兴
关131-54-4兴
关87/5兴关60/2兴
关13389-70-3兴
关87/5兴
关1335-47-3兴
关64/11兴
1530-03-6兴
关99/8兴
关99/8兴
关1081-75-0兴
关87/5兴
A
A
A
A
A
A
GC
A
GC
GS
A
A
A
GS
GS
A
ME
A, UV
A
GS
GS
A
A
A
A
A
A
A
A
关87/5兴
关885-77-8兴
关87/5兴
关87/5兴关47/5兴
关80-05-7兴
关87/5兴关47/5兴
关87/5兴
关86-89-5兴
关87/5兴
关20490-22-6兴
关87/5兴
ENTHALPIES OF VAPORIZATION
775
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C15H20Cl2 O3
C15H20Cl2 O3
C15H20Cl2 O4
C15H20O2
C15H22N2 O2
C15H24
C15H24
C15H24
C15H24O
C15H24O
C15H24O
C15H24O
C15H24O
C15H24O
C15H24O
C15H24O
C15H24O
C15H24O2
C15H24O2
C15H24O2
C15H24O6
C15H26O
C15H26O6
C15H26O6
C15H26O6
C15H28Cl4
C15H28O
C15H28O2
C15H28O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共460–573兲
92.3
共475兲
2,4-dichlorophenoxyacetic acid, heptyl ester
共460–573兲
88.3
共475兲
2,4-dichlorophenoxyacetic acid, 1-propylbutyl ester
共460–573兲
77.3
共475兲
2,4-dichlorophenoxyacetic acid, 共1-methyl-2-butoxy兲ethyl ester
共443–573兲
82.5
共458兲
helenine, alantolactone
共430–548兲
112.7
共445兲
dicyclohexylmethane-4,4⬘-diisocyanate
共326 – 404兲
80.4
共341兲
nonylbenzene
共316 – 415兲
69.7
共331兲
74.8
共298兲
1,3,5-triisopropylbenzene
共283–323兲
64.3⫾0.3
共303兲
共283–323兲
64.6⫾0.6
共298兲
共282–388兲
67.4
共297兲
1,3-di-tert-butyl-5-methylbenzene
共309–338兲
61.8⫾0.9
共310兲
63.3⫾0.9
共298兲
2,4-di-tert-butyl-5-methylphenol
共376 –555兲
67.0
共391兲
2,4-di-tert-butyl-6-methylphenol
共359–543兲
59.8
共374兲
2,6-di-tert-butyl-4-methylphenol
共303–343兲
87.8
共318兲
共358 –536兲
61.5
共373兲
2-methyl-4-共1,1,3,3-tetramethylbutyl兲phenol
共447– 683兲
67.1
共462兲
3-methyl-4-共1,1,3,3-tetramethylbutyl兲phenol
共436 –549兲
65.5
共451兲
4-methyl-2-共1,1,3,3-tetramethylbutyl兲phenol
共415–545兲
65.0
共430兲
4-共3⬘,6⬘-dimethyl-3⬘-heptyl兲phenol
89.4
共298兲
4-nonylphenol
共487–595兲
65.0
共502兲
␣-santalol
共293– 450兲
58.3
共308兲
2,5-di-tert-butyl-4-methoxyphenol
共423– 453兲
64.4
共438兲
1,3-dimethoxy-5-heptylbenzene
共419– 488兲
75.5
共434兲
1,3-dimethoxy-5-methyl-2-hexylbenzene
共410– 475兲
72.3
共425兲
aconitic acid, tripropyl ester
共359–500兲
72.3
共374兲
guaiol
共373–561兲
62.2
共388兲
camphorenic acid, triethyl ester
共423–574兲
69.0
共438兲
tripropyl 1,2,3-propanetricarboxylate
共360– 460兲
76.5
共375兲
glycerol tributyrate
共318 –364兲
81.4
共333兲
1,1,1,15-tetrachloropentadecane
共340–392兲
103.5
共355兲
3,7,11-trimethyl-1-dodecyn-3-ol
共401–524兲
43.2⫾1.1
共463兲
dodecyl acrylate
共432–573兲
64.6
共447兲
pentadecanolide
共363– 443兲
78.2
共378兲
Method
A
A
A
A
A
A
GS
GS
GS
GS
A
A
A
A
A
A
A
ME
A, EB
A
A
A, GC
A, GC
A
A
A
A
A
A
A
A
CAS registry number
Reference
关87/5兴
关1917-96-0兴
关87/5兴
关87/5兴
关3966-11-8兴
关87/5兴
关1407-13-3兴
关87/5兴
关5124-30-1兴
关87/5兴
关1081-77-2兴
关86/6兴
关71/28兴
关717-74-8兴
关98/10兴
关98/10兴
关93/10兴
关98/19兴
关98/19兴
关497-39-2兴
关87/5兴关47/5兴
关616-55-7兴
关87/5兴
关128-37-0兴
关87/5兴
关87/5兴关47/5兴
关2219-84-3兴
关87/5兴
关2219-84-3兴
关87/5兴
关4979-46-8兴
关87/5兴
关01/21兴
关104-40-5兴
关87/5兴关76/13兴
关115-71-9兴
关87/5兴
关1991-52-2兴
关87/5兴
关6121-64-8兴
关87/5兴关75/24兴
关41442-51-7兴
关87/5兴关75/24兴
关64617-28-3兴
关87/5兴
关489-86-1兴
关87/5兴
关87/5兴关47/5兴
关5333-54-0兴
关87/5兴
关60-01-1兴
关87/5兴
关3922-32-5兴
关87/5兴
关1604-35-9兴
关88/4兴关86/16兴
关2156-97-0兴
关87/5兴
关106-02-5兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
776
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C15H28O2
C15H28O2
C15H28O2
C15H28O2
C15H28O2
C15H28O2
C15H28O3
C15H28O3
C15H28O5
C15H29N
C15H29NO3
C15H30
C15H30
C15H30
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O
C15H30O2
Compound
共Temperature range/K兲
共310–320兲
共Z兲 7-tridecenyl acetate
共343–388兲
共E兲 7-tridecenyl acetate
共343–388兲
共Z兲 9-tridecenyl acetate
共343–388兲
共E兲 9-tridecenyl acetate
共343–388兲
共Z兲 11-tridecenyl acetate
共343–388兲
共E兲 11-tridecenyl acetate
共343–388兲
decyl levulinate
共423–580兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
74.2
共315兲
A, ME
84.3
共298兲
GC
84.8
共298兲
GC
85.1
共298兲
GC
85.5
共298兲
GC
86.4
共298兲
GC
86.4
共298兲
GC
76.1
72.0
共438兲
共524兲
A
共418兲
A
共426兲
A
共418兲
A
共393兲
A
共373兲
共298兲
共468兲
A
1,6-dioxa-7-cycloheptadecanone
共403– 463兲
75.9
decyl关1-共methoxycarbonyl兲ethyl兴carbonate
共411–592兲
73.8
pentadecanenitrile
共403–596兲
75.5
2-关2-ethyl共hexanoyloxy兲兴propionic acid, butylamide
共378 – 433兲
81.0
decylcyclopentane
共358 – 411兲
71.1
75.7
共453–553兲
59.7
nonylcyclohexane
74.7
1-pentadecene
共375– 407兲
65.2
共423– 658兲
53.2
75.1
共443–543兲
59.3
共Z兲 9-pentadecen-1-ol
共363– 403兲
105.3
共E兲 9-pentadecen-1-ol
共363– 403兲
105.9
共Z兲 10-pentadecen-1-ol
共363– 403兲
105.9
共E兲 10-pentadecen-1-ol
共363– 403兲
106.2
共Z兲 11-pentadecen-1-ol
共363– 403兲
106.3
共E兲 11-pentadecen-1-ol
共363– 403兲
106.5
共Z兲 12-pentadecen-1-ol
共363– 403兲
106.7
共E兲 12-pentadecen-1-ol
共363– 403兲
107.0
共Z兲 13-pentadecen-1-ol
共363– 403兲
107.7
共E兲 13-pentadecen-1-ol
共363– 403兲
107.7
2-pentadecanone
共422–575兲
67.8
共559– 658兲
57.9
8-pentadecanone
共443–568兲
65.3
共443–589兲
65.4
共444 –590兲
53.0
共438 – 462兲
61.9
methyl tetradecanoate 共methyl myristate兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A, MM
共298兲
共390兲
共570兲
共298兲
共458兲
A
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共437兲
共574兲
A
A
共458兲
共458兲
共567兲
共450兲
A
A
A
A, ME
CAS registry number
Reference
关87/5兴关54/9兴
关34270-22-9兴
关97/13兴关00/10兴
关56577-30-1兴
关97/13兴关00/10兴
关35835-78-0兴
关97/13兴关00/10兴
关52957-19-4兴
关97/13兴关00/10兴
关33951-95-0兴
关97/13兴关00/10兴
关56195-36-9兴
关97/13兴关00/10兴
关37826-51-0兴
关87/5兴
关33/6兴
关6707-60-4兴
关87/5兴
关87/5兴
关2570-26-5兴
关87/5兴
关87/5兴
关1795-21-7兴
关87/5兴
关71/28兴
关87/5兴关54/7兴
关2883-02-5兴
关71/28兴
关13360-61-7兴
关87/5兴
关75/8兴
关71/28兴
关87/5兴关55/7兴
关56218-94-1兴
关00/10兴关94/13兴
关64437-40-7兴
关00/10兴关94/13兴
关64437-42-9兴
关00/10兴关94/13兴
关64437-44-1兴
关00/10兴关94/13兴
关69282-63-9兴
关00/10兴关94/13兴
关69222-14-6兴
关00/10兴关94/13兴
关158906-50-4兴
关00/10兴关94/13兴
关69222-15-7兴
关00/10兴关94/13兴
关158906-51-5兴
关00/10兴关94/13兴
关158906-52-6兴
关00/10兴关94/13兴
关2345-28-0兴
关87/5兴
关87/5兴
关818-23-5兴
关87/5兴
关87/5兴关75/8兴
关75/8兴
关87/5兴关38/8兴
关124-10-7兴
ENTHALPIES OF VAPORIZATION
777
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
79.8
76.0⫾0.2
85.9⫾0.8
86.6
65.3
86.2⫾1.0
87.0⫾0.9
75.6
77.4
共350兲
共382兲
共298兲
共298兲
共498兲
共298兲
共298兲
共404兲
共379兲
GC
GC
GC, C
C
A
MG, OM
81.5
66.1
共320兲
共405兲
A
84.7
66.9
共298兲
共411兲
GC
A
87.2
共298兲
GC
94.0
108.5⫾2.0
共446兲
共357兲
A
ME, TE
80.5
共382兲
A
69.8
共438兲
A
69.5
共465兲
A, EST
1-chloropentadecane
共439– 645兲
55.4
共454兲
A, EST
1-fluoropentadecane
共413–593兲
63.8
共428兲
A, EST
1-iodopentadecane
共464 – 673兲
70.6
共479兲
A, EST
79.4
共433兲
A
关87/5兴
103.9
共423兲
A
72.9
71.8
75.7
76.2
76.4
76.8
67.5
66.4
75.4⫾1.2
70.8
68.8
72.2⫾1.2
76.2⫾0.4
76.2
59.6
61.9
共334兲
共344兲
共298兲
共298兲
共298兲
共298兲
共381兲
共350兲
共298兲
共353兲
共373兲
共333兲
共298兲
共298兲
共462兲
共447兲
C
C
CGC
CGC
CGC
58.8
共417兲
A
58.4
共418兲
A
关87/5兴
关629-62-9兴
关96/22兴
关96/22兴
关95/21兴
关95/21兴
关95/21兴
关94/12兴
关87/5兴
关86/6兴
关79/2兴
关79/2兴
关79/2兴
关79/2兴
关72/29兴
关71/28兴
关87/5兴关55/7兴
关38/8兴
关1560-95-8兴
关87/5兴
关18435-22-8兴
关87/5兴
关25117-24-2兴
Compound
共Temperature range/K兲
共393– 473兲
共453–543兲
C15H30O2
C15H30O2
C15H30O2
C15H30O2
C15H30O3
C15H30O3
C15H31Br
C15H31Cl
C15H31F
C15H31I
C15H31NO2
C15H31NO2
C15H32
共389–519兲
共364 – 417兲
isopropyl dodecanoate
共305– 452兲
共390– 469兲
propyl dodecanoate
共423– 483兲
共396 – 479兲
tridecyl acetate
共313–358兲
pentadecanoic acid
共431– 613兲
共347–367兲
dodecyl lactate
共367–583兲
decyl 2-ethoxypropionate
共423–523兲
1-bromopentadecane
共450– 661兲
N,N-dihexyl lactamide
共418 – 453兲
N-dodecyl lactamide
共408 – 476兲
pentadecane
共453–503兲
共423– 473兲
共363– 413兲
共366 – 409兲
共333– 409兲
C15H32
C15H32
C15H32
共447–546兲
共430– 464兲
2-methyltetradecane
共402–537兲
3-methyltetradecane
共403–538兲
4-methyltetradecane
Method
A
GS
C
C
C
C
C
A
ME
CAS registry number
Reference
关02/27兴
关02/27兴
关02/27兴
关97/28兴
关93/9兴
关80/5兴
关77/1兴
关87/5兴关63/16兴
关52/13兴
关10233-13-3兴
关01/10兴
关87/5兴关48/8兴
关84/9兴
关3681-78-5兴
关97/28兴
关87/5兴关48/8兴
关84/9兴
关1072-33-9兴
关97/13兴关00/10兴
关1002-84-2兴
关87/5兴
关82/4兴
关6283-92-7兴
关87/5兴
关70160-09-7兴
关87/5兴
关629-72-1兴
关87/5兴关61/13兴
关70/14兴
关4862-03-7兴
关87/5兴关61/13兴
关70/14兴
关1555-17-5兴
关87/5兴关61/13兴
关70/14兴
关35599-78-1兴
关87/5兴关61/13兴
关70/14兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
778
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C15H32
C15H32
C15H32
C15H32
C15H32O
C15H32O5
C15H32S
C15H33N
C16H10
C16H10
C16H13N
C16H13N
C16H14
C16H14
C16H14O2
C16H16
C16H16
C16H18
C16H18
C16H18
C16H18
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共398 –536兲
55.9
5-methyltetradecane
共398 –535兲
56.1
2,3-dimethyltridecane
共399–537兲
56.3
2,4-dimethyltridecane
共393–523兲
57.9
2,4,6-trimethyldodecane
共382–508兲
55.8
1-pentadecanol
共319–358兲
95.5
共319–358兲
102.5
共353–393兲
107.2
共343–393兲
92.4
共438 – 600兲
75.0
共453–584兲
72.4
tetrapropylene glycol monoisopropyl ether
共389–566兲
71.5
1-pentadecanethiol
共459– 629兲
69.8
1-aminopentadecane
共400–594兲
71.2
fluoranthene
共323– 473兲
79.3
共343– 453兲
77.4
共503– 658兲
62.2
pyrene
共343– 453兲
78.6
共413– 467兲
76.0
共398 – 458兲
76.4
共513– 668兲
73.0
N-phenyl-1-naphthylamine
共338 –368兲
89.6
N-phenyl-2-naphthylamine
共383–520兲
88.7
4,5,9,10-tetrahydropyrene
70.9
68.1
65.3
62.5
59.5
56.4
1,2,3,10b-tetrahydrofluoranthene
共400– 469兲
68.0
benzyl cinnamate
共446 – 623兲
89.4
1,2,3,6,7,8-hexahydropyrene
72.0
69.4
66.8
64.2
61.5
1,1-di共4-methylphenyl兲ethene
共309–332兲
100.3⫾1.4
101.0⫾1.4
1-共2-tolyl兲-2-共4-tolyl兲ethane
共298 – 473兲
85.6
1,1-diphenylbutane
共298 –342兲
75.9⫾0.6
共298 –342兲
77.2⫾0.6
2-methyl-1,1-diphenylpropane
共298 –338兲
72.0⫾0.5
共298 –338兲
73.2⫾0.5
1,1-bis共4-methylphenyl兲ethane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共413兲
A
共413兲
A
共414兲
A
共408兲
A
共397兲
A
共339兲
共298兲
共298兲
共368兲
共453兲
共468兲
GS
GS
CGC
共404兲
A
A
A
共474兲
共415兲
A, EST
共398兲
共398兲
共518兲
GC
GC
A
共398兲
共428兲
共440兲
共528兲
GC
共353兲
A
共398兲
A
共440兲
共480兲
共520兲
共560兲
共600兲
共640兲
EB,IPM
EB, IPM
EB, IPM
EB, IPM
EB, IPM
EB, IPM
共415兲
A
共461兲
A
共440兲
共480兲
共520兲
共560兲
共600兲
A
EB,
EB,
EB,
EB,
EB,
IPM
IPM
IPM
IPM
IPM
CAS registry number
Reference
关87/5兴
关25117-32-2兴
关87/5兴
关18435-20-6兴
关87/5兴
关61868-05-1兴
关87/5兴
关87/5兴
关629-76-5兴
关01/3兴
关01/3兴
关94/13兴关00/10兴
关92/14兴
关87/5兴
关87/5兴
关87/5兴关47/5兴
关25276-70-4兴
关99/16兴
关2570-26-5兴
关87/5兴关56/17兴
关206-44-0兴
关02/18兴
关90/2兴
关87/5兴关55/10兴
关129-00-0兴
关90/2兴
关88/12兴
关80/12兴
关87/5兴关55/10兴
关90-32-2兴
关87/5兴
关135-88-6兴
关87/5兴
关781-17-9兴
关93/12兴
关93/12兴
关93/12兴
关93/12兴
关93/12兴
关93/12兴
关20279-21-4兴
关87/5兴
关103-41-3兴
关87/5兴关47/5兴
关1732-13-4兴
关93/12兴
关93/12兴
关93/12兴
关93/12兴
关93/12兴
共320兲
共298兲
GS
关99/21兴
关99/21兴
共313兲
A
共320兲
共298兲
GS
GS
共318兲
共298兲
GS
GS
关87/5兴关63/14兴
关719-79-9兴
关99/8兴
关99/8兴
关1634-11-3兴
关99/8兴
关99/8兴
关530-45-0兴
ENTHALPIES OF VAPORIZATION
779
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C16H18Cl4 O4
C16H18O
C16H21Cl3 O3
C16H21Cl3 O3
C16H22Cl2 O3
C16H22Cl2 O3
C16H22Cl2 O3
C16H22O4
C16H22O4
C16H22O4
C16H25Cl
C16H26
C16H26
C16H26O
C16H26O
C16H26O
C16H26O
C16H26O
C16H26O11
C16H28
C16H30O
C16H30O
C16H30O
C16H30O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共298 –338兲
共298 –338兲
dibutyl tetrachlorophthalate
共368 – 421兲
75.3⫾0.6
76.5⫾0.6
共318兲
共298兲
GS
GS
99.7
共383兲
A, T
bis共␣-methylbenzyl兲 ether
共369–554兲
62.1
共384兲
2,4,5-trichlorophenoxyacetic acid, 共2-ethylhexyl兲 ester
共460–575兲
85.4
共475兲
2,4,5-trichlorophenoxyacetic acid, octyl ester
共460–575兲
92.2
共475兲
2,4-dichlorophenoxyacetic acid, 共2-ethylhexyl兲 ester
共460–575兲
83.0
共475兲
2,4-dichlorophenoxyacetic acid, 共1-methylheptyl兲 ester
共460–575兲
83.0
共475兲
2,4-dichlorophenoxyacetic acid, octyl ester
共460–573兲
87.9
共475兲
dibutyl phthalate
80.4
共462兲
共314 – 469兲
94.0
共329兲
共468 – 605兲
76.1
共483兲
共288 –313兲
91.7
共300兲
di-sec-butyl phthalate
共313–373兲
93.8
共328兲
dibutyl terephthalate
共393– 483兲
86.2
共408兲
chloropentaethylbenzene
共363–558兲
60.3
共378兲
decylbenzene
共313– 433兲
78.0
共328兲
共371– 427兲
75.1
共386兲
79.8
共298兲
共475–571兲
61.6
共490兲
pentaethylbenzene
共359–550兲
56.5
共374兲
2,6-di-tert-butyl-4-ethylphenol
共362–557兲
62.8
共348兲
共362–557兲
60.4
共373兲
共362–557兲
58.6
共398兲
共362–557兲
57.3
共423兲
共362–557兲
52.6
共473兲
4,6-di-tert-butyl-2-ethylphenol
共413–556兲
61.9
共428兲
共413–562兲
57.3
共423兲
共413–562兲
52.6
共473兲
2,4-di-tert-butyl-5,6-dimethylphenol
共431–565兲
69.1
共446兲
2,4-di-tert-butyl-5-ethylphenol
共384 –563兲
69.3
共399兲
2,4,5-triisopropylbenzyl alcohol
共312–346兲
113.1
共327兲
diethylene glycol dicarboxylic acid, di关1-共ethoxycarbonyl兲-ethyl兴 ester
共418 –503兲
99.3
共433兲
tricyclopentylmethane
共273–351兲
77.8
共288兲
共371– 429兲
71.4
共386兲
3-methylcyclopentadecanone
共391– 601兲
63.5
共406兲
共Z兲 3-hexadecenal
共373– 413兲
89.9
共298兲
共E兲 3-hexadecenal
共373– 413兲
89.6
共298兲
共Z兲 4-hexadecenal
共373– 413兲
88.7
共298兲
A
A
A
A
A
A
A
A
A, ME
A
CAS registry number
Reference
关99/8兴
关99/8兴
关3015-66-5兴
关87/5兴关49/9兴
关99/16兴
关93-96-9兴
关87/5兴关47/5兴
关1928-47-8兴
关87/5兴
关2630-15-1兴
关87/5兴
关1928-43-4兴
关87/5兴
关1917-97-1兴
关87/5兴
关1928-44-5兴
关87/5兴
关84-74-2兴
关88/17兴
关87/5兴
关87/5兴
关49/15兴
关4489-61-6兴
关87/5兴关48/10兴
关1962-75-0兴
关87/5兴
A
关87/5兴关47/5兴
关104-72-3兴
关93/10兴
关87/5兴
关71/28兴
关87/5兴关54/7兴
关605-01-6兴
关87/5兴关47/5兴
关4130-42-1兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关53/9兴
关6287-47-4兴
关87/5兴
关53/9兴
关53/9兴
关70766-54-0兴
关87/5兴
关19245-41-1兴
关87/5兴
A
关87/5兴
A
关87/5兴
关3752-92-9兴
关87/5兴关64/12兴
关87/5兴
关541-91-3兴
关87/5兴
关174155-58-9兴
关96/7兴关00/10兴
关174155-57-8兴
关96/7兴关00/10兴
关88373-69-7兴
关96/7兴关00/10兴
A
A
A, MM
A
A
A
A
A
A
CGC
CGC
CGC
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
780
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
Compound
共Temperature range/K兲
共E兲 4-hexadecenal
共373– 413兲
共Z兲 5-hexadecenal
共373– 413兲
共E兲 5-hexadecenal
共373– 413兲
共Z兲 6-hexadecenal
共373– 413兲
共E兲 6-hexadecenal
共373– 413兲
共Z兲 7-hexadecenal
共373– 413兲
共E兲 7-hexadecenal
共373– 413兲
共Z兲 8-hexadecenal
共373– 413兲
共E兲 8-hexadecenal
共373– 413兲
共Z兲 9-hexadecenal
共373– 413兲
共E兲 9-hexadecenal
共373– 413兲
共Z兲 10-hexadecenal
共373– 413兲
共E兲 10-hexadecenal
共373– 413兲
共Z兲 11-hexadecenal
共373– 413兲
共E兲 11-hexadecenal
共373– 413兲
共Z兲 12-hexadecenal
共373– 413兲
共E兲 12-hexadecenal
共373– 413兲
共Z兲 13-hexadecenal
共373– 413兲
共E兲 13-hexadecenal
共373– 413兲
dodecyl methacrylate
共438 –580兲
oxa-2-cycloheptadecanone
共403– 463兲
共Z兲 2-tetradecenyl acetate
共353–398兲
共E兲 2-tetradecenyl acetate
共353–398兲
共Z兲 3-tetradecenyl acetate
共353–398兲
共E兲 3-tetradecenyl acetate
共353–398兲
共Z兲 4-tetradecenyl acetate
共353–398兲
共E兲 4-tetradecenyl acetate
共353–398兲
共Z兲 5-tetradecenyl acetate
共353–398兲
共E兲 5-tetradecenyl acetate
共353–398兲
共Z兲 6-tetradecenyl acetate
共353–398兲
共E兲 6-tetradecenyl acetate
共353–398兲
共Z兲 7-tetradecenyl acetate
共353–398兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
88.9
共298兲
CGC
87.8
共298兲
CGC
88.6
共298兲
CGC
87.9
共298兲
CGC
88.5
共298兲
CGC
87.8
共298兲
CGC
88.6
共298兲
CGC
87.7
共298兲
CGC
88.4
共298兲
CGC
88.0
共298兲
CGC
88.6
共298兲
CGC
88.2
共298兲
CGC
88.8
共298兲
CGC
88.5
共298兲
CGC
89.2
共298兲
CGC
89.3
共298兲
CGC
89.3
共298兲
CGC
89.7
共298兲
CGC
90.0
共298兲
CGC
64.9
共453兲
A
71.6
共418兲
A
89.1
共298兲
GC
90.3
共298兲
GC
88.5
共298兲
GC
89.2
共298兲
GC
87.8
共298兲
GC
89.0
共298兲
GC
88.3
共298兲
GC
89.1
共298兲
GC
88.1
共298兲
GC
88.9
共298兲
GC
88.4
共298兲
GC
CAS registry number
Reference
关174155-59-0兴
关96/7兴关00/10兴
关88373-68-6兴
关96/7兴关00/10兴
关99142-11-7兴
关96/7兴关00/10兴
关88373-67-5兴
关96/7兴关00/10兴
关103346-18-5兴
关96/7兴关00/10兴
关56797-40-1兴
关96/7兴关00/10兴
关72698-27-2兴
关96/7兴关00/10兴
关66644-98-2兴
关96/7兴关00/10兴
关72698-28-3兴
关96/7兴关00/10兴
关56219-04-6兴
关96/7兴关00/10兴
关72698-29-4兴
关96/7兴关00/10兴
关68279-24-3兴
关96/7兴关00/10兴
关72698-30-7兴
关96/7兴关00/10兴
关53939-28-9兴
关96/7兴关00/10兴
关57491-33-5兴
关96/7兴关00/10兴
关72698-31-8兴
关96/7兴关00/10兴
关72698-32-9兴
关96/7兴关00/10兴
关71545-96-5兴
关96/7兴关00/10兴
关72698-33-0兴
关96/7兴关00/10兴
关142-90-5兴
关87/5兴
关109-29-5兴
关87/5兴
关51309-20-7兴
关97/13兴关00/10兴
关51309-21-8兴
关97/13兴关00/10兴
关54897-65-3兴
关97/13兴关00/10兴
关56221-90-0兴
关97/13兴关00/10兴
关54897-66-4兴
关97/13兴关00/10兴
关56209-67-7兴
关97/13兴关00/10兴
关35153-13-0兴
关97/13兴关00/10兴
关34010-13-4兴
关97/13兴关00/10兴
关39650-11-8兴
关97/13兴关00/10兴
关39650-10-7兴
关97/13兴关00/10兴
关16974-10-0兴
关97/13兴关00/10兴
ENTHALPIES OF VAPORIZATION
781
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O2
C16H30O3
C16H30O3
C16H30O4
C16H30O5
C16H31N
C16H32
C16H32
C16H32
C16H32
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共E兲 7-tetradecenyl acetate
共353–398兲
89.0
共Z兲 8-tetradecenyl acetate
共353–398兲
88.7
共E兲 8-tetradecenyl acetate
共353–398兲
89.2
共Z兲 9-tetradecenyl acetate
共353–398兲
89.1
共303–317兲
90
共E兲 9-tetradecenyl acetate
共353–398兲
89.6
共Z兲 10-tetradecenyl acetate
共353–398兲
89.6
共E兲 10-tetradecenyl acetate
共353–398兲
89.9
共Z兲 11-tetradecenyl acetate
共353–398兲
90.0
共E兲 11-tetradecenyl acetate
共353–398兲
90.4
共Z兲 12-tetradecenyl acetate
共353–398兲
90.9
共E兲 12-tetradecenyl acetate
共353–398兲
90.8
1,7-dioxa-8-cyclooctadecanone
共403– 463兲
73.3
1,9-dioxa-2-cyclooctadecanone
共403– 463兲
74.5
dipentyl adipate
共449–575兲
74.7
octyl关1-共butoxycarbonyl兲ethyl兴carbonate
共374 –503兲
76.2
palmitonitrile
共503– 608兲
70.1
tetraisobutylene
共381– 440兲
54.5
decylcyclohexane
共371– 425兲
76.7
79.7
共469–571兲
61.6
undecylcyclopentane
80.6
1-hexadecene
80.3⫾0.4
80.3⫾0.4
80.1
共461–558兲
61.5
共Z兲 3-hexadecen-1-ol
共373– 413兲
110.7
共E兲 3-hexadecen-1-ol
共373– 413兲
110.8
共Z兲 4-hexadecen-1-ol
共373– 413兲
110.6
共E兲 4-hexadecen-1-ol
共373– 413兲
111.5
共Z兲 5-hexadecen-1-ol
共373– 413兲
110.9
共E兲 5-hexadecen-1-ol
共373– 413兲
111.4
共Z兲 6-hexadecen-1-ol
共373– 413兲
110.5
共E兲 6-hexadecen-1-ol
共373– 413兲
111.0
共Z兲 7-hexadecen-1-ol
共373– 413兲
110.2
Mean temperature
(T m /K)
Method
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
共310兲
GC
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共418兲
A
共418兲
A
共464兲
A
共389兲
A
共518兲
A
共397兲
共386兲
共298兲
共484兲
A
A, MM
共298兲
共298兲
共298兲
共298兲
共476兲
C
C
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
共298兲
CGC
A
CAS registry number
Reference
关28540-79-6兴
关97/13兴关00/10兴
关35835-80-4兴
关97/13兴关00/10兴
关56218-64-5兴
关97/13兴关00/10兴
关16725-53-4兴
关97/13兴关00/10兴
关83/10兴
关23192-82-7兴
关97/13兴关00/10兴
关35153-16-3兴
关97/13兴关00/10兴
关35153-17-4兴
关97/13兴关00/10兴
关20711-10-8兴
关97/13兴关00/10兴
关33189-72-9兴
关97/13兴关00/10兴
关35153-20-9兴
关97/13兴关00/10兴
关35153-21-0兴
关97/13兴关00/10兴
关6720-22-5兴
关87/5兴
关36575-58-3兴
关87/5兴
关14027-78-2兴
关87/5兴
关87/5兴
关629-79-8兴
关87/5兴
关43/2兴
关1795-16-0兴
关87/5兴
关71/28兴
关87/5兴关54/7兴
关6785-23-5兴
关71/28兴
关629-73-2兴
关77/1兴
关76/5兴
关71/28兴
关87/5兴关54/7兴
关141694-91-9兴
关00/10兴关94/13兴
关128999-42-8兴
关00/10兴关94/13兴
关145235-63-8兴
关00/10兴关94/13兴
关59101-23-4兴
关00/10兴关94/13兴
关106463-48-3兴
关00/10兴关94/13兴
关85388-16-5兴
关00/10兴关94/13兴
关40642-45-3兴
关00/10兴关94/13兴
关34500-33-9兴
关00/10兴关94/13兴
关24880-48-6兴
关00/10兴关94/13兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
782
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O
C16H32O2
Compound
共Temperature range/K兲
共E兲 7-hexadecen-1-ol
共373– 413兲
共Z兲 8-hexadecen-1-ol
共373– 413兲
共E兲 8-hexadecen-1-ol
共373– 413兲
共Z兲 9-hexadecen-1-ol
共373– 413兲
共E兲 9-hexadecen-1-ol
共373– 413兲
共Z兲 10-hexadecen-1-ol
共373– 413兲
共E兲 10-hexadecen-1-ol
共373– 413兲
共Z兲 11-hexadecen-1-ol
共373– 413兲
共E兲 11-hexadecen-1-ol
共373– 413兲
共Z兲 12-hexadecen-1-ol
共373– 413兲
共E兲 12-hexadecen-1-ol
共373– 413兲
共Z兲 13-hexadecen-1-ol
共373– 413兲
共E兲 13-hexadecen-1-ol
共373– 413兲
2-hexadecanone
共382–580兲
hexadecanal
共343–383兲
共394 –594兲
methyl pentadecanoate
共433– 473兲
C16H32O2
C16H32O2
C16H32O2
C16H32O2
C16H32O2
C16H33Br
共295–303兲
共400–527兲
ethyl tetradecanoate
共407–568兲
butyl dodecanoate
共423– 483兲
共343–383兲
isobutyl dodecanoate
共345– 452兲
tetradecyl acetate
共353–398兲
共411– 462兲
hexadecanoic acid 共palmitic acid兲
共440– 625兲
共347–374兲
C16H33F
Mean temperature
(T m /K)
Method
111.4
共298兲
CGC
110.4
共298兲
CGC
111.1
共298兲
CGC
110.6
共298兲
CGC
111.3
共298兲
CGC
111.0
共298兲
CGC
111.5
共298兲
CGC
111.3
共298兲
CGC
111.8
共298兲
CGC
111.8
共298兲
CGC
112.1
共298兲
CGC
112.3
共298兲
CGC
112.6
共298兲
CGC
72.3
共397兲
A
89.7
67.6
共298兲
共409兲
CGC
A
82.1
79.8⫾0.2
89.3⫾0.8
88.8
91.6⫾0.9
93.5⫾1.0
87.9⫾1.3
78.3
共350兲
共372兲
共298兲
共298兲
共298兲
共298兲
共299兲
共415兲
A, EST
71.8
共422兲
A
89.2
75.8
共298兲
共358兲
GC
A
80.0
共360兲
91.7
72.7
共298兲
共426兲
GC
A
97.5
110.2⫾2.0
90.1
共455兲
共364兲
共475兲
A
ME, TE
I
94.4⫾1.5
71.9
共298兲
共476兲
C
A, EST
96.4⫾0.9
91.8⫾1.1
73.3
共298兲
共298兲
共454兲
GS
C
DTA
66.1
共440兲
A, EST
CGC
GC,C
C
1-bromohexadecane
共461– 673兲
C16H33Cl
⌬ vapH m
共kJ mol⫺1兲
1-chlorohexadecane
共439– 600兲
1-fluorohexadecane
共425– 608兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
CAS registry number
Reference
关51824-10-3兴
关00/10兴关94/13兴
关64437-46-3兴
关00/10兴关94/13兴
关64470-33-3兴
关00/10兴关94/13兴
关10378-01-5兴
关00/10兴关94/13兴
关64437-47-4兴
关00/10兴关94/13兴
关64437-48-5兴
关00/10兴关94/13兴
关54502-94-2兴
关00/10兴关94/13兴
关56683-54-6兴
关00/10兴关94/13兴
关61301-56-2兴
关00/10兴关94/13兴
关72698-34-1兴
关00/10兴关94/13兴
关72698-35-2兴
关00/10兴关94/13兴
关69282-65-1兴
关00/10兴关94/13兴
关69282-66-2兴
关00/10兴关94/13兴
关18787-63-8兴
关87/5兴
关629-80-1兴
关96/7兴关00/10兴
关87/5兴关47/5兴
关7132-64-1兴
关02/26兴
关02/26兴
关02/26兴
关95/21兴
关80/5兴
关77/1兴
关68/20兴
关87/5兴关63/16兴
关124-06-1兴
关87/5兴
关106-18-3兴
关97/28兴
关87/5兴
关01/10兴
关638-59-5兴
关97/13兴关00/10兴
关87/5兴
关57-10-3兴
关87/5兴
关82/4兴
关43/7兴
关112-82-3兴
关96/6兴
关87/5兴关61/13兴
关70/14兴
关4860-03-1兴
关01/1兴
关77/1兴
关69/5兴
关408-38-8兴
关87/5兴关61/13兴
ENTHALPIES OF VAPORIZATION
783
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C16H33I
C16H34
Compound
共Temperature range/K兲
1-iodohexadecane
共475– 673兲
共505–589兲
共323– 423兲
C16H34
C16H34
C16H34
C16H34
C16H34
C16H34
C16H34
C16H34
C16H34
共467–563兲
共299–324兲
共293–308兲
共442– 469兲
2-methylpentadecane
共417–554兲
3-methylpentadecane
共417–555兲
4-methylpentadecane
共411–553兲
5-methylpentadecane
共408 –551兲
7-methylpentadecane
共355– 410兲
2,3-dimethyltetradecane
共412–554兲
2,4-dimethyltetradecane
共404 –539兲
2,4,6-trimethyltridecane
共395–521兲
2,2,4,4,6,8,8-heptamethylnonane
共423–545兲
3,3.6,6-tetraethyloctane
共301–330兲
C16H34N2
bis共1,1,3,3-tetramethylbutyl兲diazene
C16H34O
1-hexadecanol
共328 –362兲
共328 –362兲
C16H34O
C16H34O3
Mean temperature
(T m /K)
Method
共343– 463兲
共509–569兲
共415– 487兲
共323–376兲
共418 – 463兲
共498 –569兲
共445–598兲
共323–335兲
2-hexadecanol
共333– 453兲
2关2-共dodecyloxy兲ethoxy兴ethanol
共448 – 489兲
CAS registry number
Reference
关70/14兴
关544-77-4兴
关87/5兴关61/13兴
关70/14兴
关544-76-3兴
关00/9兴
关95/21兴
关95/21兴
关95/21兴
关94/14兴
关94/12兴
关92/2兴
关87/5兴
关77/34兴
关77/34兴
关77/34兴
关77/34兴
关77/34兴
关72/29兴
关71/28兴
关87/5兴关54/7兴
关49/14兴
关49/17兴
关38/8兴
关1560-93-6兴
关87/5兴
关2882-96-4兴
关87/5兴
关2801-87-8兴
关87/5兴
关25117-33-3兴
关87/5兴
关6165-40-8兴
关87/5兴
关18435-23-9兴
关87/5兴
关61868-06-2兴
关87/5兴
73.0
共490兲
A, EST
81.8⫾1.3
81.4
81.4
81.2
68.5
81.4
59.8
74.9
66.9
66.2
65.6
64.9
64.2
81.4⫾0.4
81.1
61.7
93.4
80.2
65.7
共298兲
共298兲
共298兲
共298兲
共408兲
共298兲
共520兲
共338兲
共343兲
共353兲
共363兲
共373兲
共383兲
共298兲
共298兲
共482兲
共311兲
共300兲
共455兲
CGC
CGC
CGC
CGC
A, MM
ME
ME
ME
62.0
共432兲
A
61.0
共432兲
A
57.8
共426兲
A
57.3
共423兲
A
66.3
共370兲
A
57.4
共427兲
A
60.6
共419兲
A
59.1
共410兲
A
52.4
共438兲
关87/5兴
关4390-04-9兴
关88/8兴
73.0⫾1.9
74.3⫾1.9
72.3⫾1.8
共308兲
共298兲
共298兲
HSA
CGC
66.5⫾0.6
共298兲
C
100.4
108.8
112.5
88.2
68.9
83.2
112.3
78.8
70.0
77.3
109.5
共347兲
共298兲
共298兲
共403兲
共524兲
共430兲
共338兲
共423兲
共513兲
共460兲
共329兲
GS
GS
CGC
102.2
共348兲
82.1
共463兲
关95/27兴
关95/27兴
关95/27兴
关39198-34-0兴
关76/3兴
关36653-82-4兴
关01/3兴
关01/3兴
关00/10兴
关92/14兴
关87/5兴
关87/5兴关74/13兴
关73/26兴
关73/26兴
关87/5兴关70/2兴
关69/5兴
关65/15兴
关14852-31-4兴
关99/11兴
关3055-93-4兴
关87/5兴
hexadecane
共453–503兲
共423– 473兲
共363– 413兲
共393–583兲
C16H34
⌬ vapH m
共kJ mol⫺1兲
A
GC
GC
GC
GC
GC
C
A
A
A, EB
DTA
ME
A
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
784
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C16H34S
C16H34S
C16H34S2
C16H35N
C16H35N
C16H35N
C16H36N2
C17H10O
C17H12
C17H12
C17H13N
C17H18O3
C17H18O3
C17H24O2
C17H28
C17H28O
C17H28O2
C17H32
C17H32
C17H32
C17H32Cl4
C17H32O2
C17H32O2
C17H32O2
C17H32O2
C17H32O2
C17H32O2
C17H32O2
C17H32O2
C17H32O2
C17H32O2
C17H32O2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
1-hexadecanethiol
共470– 643兲
72.4
dioctyl sulfide
共465–550兲
95.0⫾10.7
dioctyl disulfide
共479– 656兲
73.9
dioctylamine
共448 –597兲
87.1⫾1.3
hexadecylamine
共498 – 609兲
66.9
N,N-dimethyl-2-pentylnonylamine
共401–552兲
64.8
tetrabutyl hydrazine
共392– 453兲
51.1
benzanthrone
共498 – 673兲
91.4
1,2-benzofluorene
共323– 473兲
83.7
2,3-benzofluorene
共323– 473兲
84.7
5-methyl-5H-indeno关2,1-b兴quinoline
共375–388兲
122.2
2-hydroxy-4-butoxybenzophenone
共393– 443兲
92.7
4-共tert-butylphenyl兲 salicylate
共336 – 438兲
90.4
menthyl benzoate
共396 –574兲
69.9
undecylbenzene
共450– 622兲
66.7
84.7
4-methyl-2,6-di-tert-pentylphenol
共438 –556兲
65.9
1,3-dimethoxy-2-nonylbenzene
共443–509兲
79.2
1-heptadecyne
共438 – 607兲
62.7
2-heptadecyne
共446 – 619兲
63.7
3-heptadecyne
共438 – 607兲
62.5
1,1,1,17-tetrachloroheptadecane
共351– 418兲
108.0
oxa-2-cyclooctadecanone
共403– 463兲
73.5
tetradecyl acrylate
共458 – 601兲
69.4
共Z兲 9-pentadecenyl acetate
共363– 408兲
93.6
共E兲 9-pentadecenyl acetate
共363– 408兲
94.3
共Z兲 10-pentadecenyl acetate
共363– 408兲
94.1
共E兲 10-pentadecenyl acetate
共363– 408兲
94.6
共Z兲 11-pentadecenyl acetate
共363– 408兲
94.6
共E兲 11-pentadecenyl acetate
共363– 408兲
94.9
共Z兲 12-pentadecenyl acetate
共363– 408兲
95.1
共E兲 12-pentadecenyl acetate
共363– 408兲
94.5
共Z兲 13-pentadecenyl acetate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共485兲
共298兲
EB
共494兲
共298兲
EB
共513兲
A
共425兲
EB
共407兲
A
共513兲
A
共398兲
GC
共398兲
GC
共381兲
A
共418兲
ME
共351兲
A, UV
共411兲
A
共465兲
共298兲
共453兲
A
共458兲
A, GC
共453兲
共461兲
共453兲
共366兲
A
共418兲
A
共473兲
A
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
CAS registry number
Reference
关2917-26-2兴
关99/16兴
关2690-08-6兴
关97/7兴
关822-27-5兴
关99/16兴
关1120-48-5兴
关96/4兴
关143-27-1兴
关87/5兴
关87/3兴
关60678-70-8兴
关87/5兴
关82-05-3兴
关87/5兴关47/5兴
关238-84-6兴
关02/18兴
关243-17-4兴
关02/18兴
关6626-64-8兴
关87/5兴
关84/1兴
关87-18-3兴
关87/5兴关60/2兴
关6284-35-1兴
关87/5兴关47/5兴
关6742-54-7兴
关99/16兴
关71/28兴
关56103-67-4兴
关87/5兴
关55095-35-7兴
关87/5兴关75/24兴
关26186-00-5兴
关99/16兴
关61847-96-9兴
关99/16兴
关61886-63-3兴
关99/16兴
关93479-16-4兴
关87/5兴
关5637-97-8兴
关87/5兴
关21643-42-5兴
关87/5兴
关35835-77-9兴
关97/13兴关00/10兴
关64437-41-8兴
关97/13兴关00/10兴
关64437-43-0兴
关97/13兴关00/10兴
关64437-45-2兴
关97/13兴关00/10兴
关35153-25-4兴
关97/13兴关00/10兴
关40535-40-8兴
关97/13兴关00/10兴
关70711-45-4兴
关97/13兴关00/10兴
关73304-17-3兴
关97/13兴关00/10兴
关70711-46-5兴
ENTHALPIES OF VAPORIZATION
785
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C17H32O2
C17H32O3
C17H32O4
C17H32O5
C17H33N
C17H34
C17H34
C17H34
C17H34O
C17H34O
C17H34O2
C17H34O2
C17H34O2
C17H34O2
C17H34O3
C17H35Br
C17H35Cl
C17H35F
C17H35I
C17H35NO2
C17H36
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共363– 408兲
95.9
共E兲 13-pentadecenyl acetate
共363– 408兲
95.9
1,8-dioxa-9-cyclononadecanone
共403– 463兲
77.0
dibutyl nonadioate
共313– 450兲
88.4
nonyl关1-共butoxycarbonyl兲ethyl兴carbonate
共420–534兲
73.8
heptadecanonitrile
共425– 620兲
81.2
dodecylcyclopentane
共450– 619兲
68.0
85.5
undecylcyclohexane
共450– 622兲
67.0
84.6
1-heptadecene
共598 –746兲
55.5
共376 – 432兲
72.3
84.9
2-heptadecanone
共402–593兲
77.0
9-heptadecanone
共439– 482兲
78.3
methyl hexadecanoate 共methyl palmitate兲
93.4
83.3⫾0.4
96.8⫾0.6
共463–523兲
96.4
共433– 473兲
93.2
共453–543兲
78.2
共287–322兲
U69.6
共411–543兲
82.4
共378 – 445兲
82.6
共422– 475兲
71.4
isopropyl tetradecanoate
共413– 466兲
70.2
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共298兲
GC
关97/13兴关00/10兴
共298兲
GC
共418兲
A
共328兲
A
关97/13兴关00/10兴
关1725-00-4兴
关87/5兴
关2917-73-9兴
关87/5兴
共435兲
A
共440兲
A
共465兲
共298兲
共465兲
共298兲
共613兲
共391兲
共298兲
A
共417兲
A
共454兲
A, ME
共350兲
共397兲
共298兲
共298兲
共298兲
共498兲
共302兲
共426兲
共393兲
共437兲
GC
CGC
GC
A
A
MG, OM
共428兲
A
71.3
共435兲
A
100.7
112.7⫾2.0
共464兲
共372兲
A
ME, TE
86.4
共403兲
A
71.6
共487兲
A, EST
1-chloroheptadecane
共450– 673兲
73.2
共465兲
A, EST
1-fluoroheptadecane
共437– 623兲
68.4
共452兲
A, EST
1-iodoheptadecane
共517– 673兲
73.0
共532兲
A, EST
107.5
共428兲
A
86.5
91.1
共298兲
共304兲
A
propyl tetradecanoate
共420– 474兲
heptadecanoic acid
共449– 637兲
共357–382兲
tetradecyl lactate
共388 – 608兲
1-bromoheptadecane
共472– 673兲
N-tetradecyllactamide
共413– 491兲
heptadecane
共289–320兲
关87/5兴
关5399-02-0兴
关87/5兴
关5634-30-0兴
关99/16兴
关71/28兴
关54105-66-7兴
关99/16兴
关71/28兴
关6765-39-5兴
关99/16兴
关87/5兴
关71/28兴
关2922-51-2兴
关87/5兴关47/5兴
关540-08-9兴
关87/5兴关38/8兴
关112-39-0兴
关02/27兴
关02/27兴
关02/27兴
关97/28兴
关95/21兴
关93/9兴
关87/5兴
关87/5兴关63/16兴
关52/13兴
关48/8兴
关110-27-0兴
关87/5兴关48/8兴
关84/9兴
关14303-70-9兴
关87/5兴关48/8兴
关84/9兴
关506-12-7兴
关87/5兴
关82/4兴
关1323-03-1兴
关87/5兴
关3508-00-7兴
关87/5兴关61/13兴
关70/14兴
关62016-75-5兴
关87/5兴关70/14兴
关61/13兴
关117374-49-9兴
关87/5兴关61/13兴
关70/14兴
关26825-83-2兴
关87/5兴关61/13兴
关70/14兴
关87/5兴
关629-78-7兴
关94/12兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
786
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
62.9
86.0⫾0.8
86.2
71.6
共503兲
共298兲
共298兲
共457兲
ME
63.5
共443兲
A
63.4
共443兲
A
58.7
共435兲
A
59.8
共437兲
A
60.6
共439兲
A
65.2
共434兲
A
64.5
共426兲
A
78.0⫾1.8
共298兲
CGC
78.3
75.9
共475兲
共488兲
A
A
74.6
共496兲
68.2
共537兲
A
91.0
共398兲
GC
88.5
67.7
共398兲
共550兲
GC
89.6
共398兲
GC
81.0⫾0.4
84.2⫾0.4
60.5
77.6
68.5
共352兲
共298兲
共591兲
共403兲
共477兲
GS
GS
DSC
97.2⫾0.3
共462– 691兲
76.1
p-terphenyl
共323– 473兲
79.2
共499–700兲
79.2
1,4-bis关共4-hydroxyphenyl兲azo兴benzene
共473–533兲
68.0
triphenylamine
共473– 640兲
65.2
N-9-anthryldiacetamide
共399– 455兲
106.3
triphenyl phosphate
共548 – 683兲
81.4
triphenylphosphine
共483– 660兲
71.2
共364 –392兲
91.4⫾2
2-tert-butyl-9,10-anthraquinone
共483–523兲
101.4
2-共tert-butyl兲anthracene
共323– 473兲
84.5
9-butylanthracene
共422– 492兲
77.1
共328 –373兲
83.9
共298兲
共477兲
CGC
A
共398兲
共514兲
GC
A
共488兲
A
共488兲
A
共414兲
A
共563兲
IA
共498兲
共378兲
A
TE, ME
共498兲
A
共398兲
GC
共437兲
共343兲
A
A
Compound
共Temperature range/K兲
共488 –577兲
C17H36
C17H36
C17H36
C17H36
C17H36
C17H36
C17H36
C17H36
C17H36O
C17H36S
C17H37N
C18H12
C18H12
C18H12
C18H14
C18H14
C18H14
C18H14N4 O2
C18H15N
C18H15NO2
C18H15O4 P
C18H15P
C18H16O2
C28H18
C18H18
共445– 470兲
2-methylhexadecane
共428 –569兲
3-methylhexadecane
共428 –567兲
4-methylhexadecane
共420–567兲
5-methylhexadecane
共422–566兲
2,3-dimethylpentadecane
共424 –569兲
2,4-dimethylpentadecane
共419–546兲
2,4,6-trimethyltetradecane
共411–534兲
4,4-dipropylundecane
1-heptadecanol
共460– 620兲
共473– 623兲
1-heptadecanethiol
共481– 657兲
heptadecylamine
共522– 636兲
benz关a兴anthracene
共343– 453兲
triphenylene
共323– 473兲
共535–768兲
chrysene
共323– 473兲
o-terphenyl
共335–368兲
共335–368兲
共576 –786兲
共343– 462兲
共462– 650兲
m-terphenyl
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
A
C
A
CAS registry number
Reference
关87/5兴
关72/29兴
关71/28兴
关38/8兴
关1560-92-5兴
关87/5兴关59/15兴
关6418-43-5兴
关87/5兴关59/15兴
关25117-26-4兴
关87/5兴关59/15兴
关25117-34-4兴
关87/5兴关59/15兴
关2882-97-5兴
关87/5兴关59/15兴
关61868-07-3兴
关87/5兴关59/15兴
关101791-53-1兴
关87/5兴
关95/27兴
关1454-85-9兴
关87/5兴
关87/5兴
关53193-22-9兴
关99/16兴
关4200-95-7兴
关87/5兴关56/17兴
关56-55-3兴
关90/2兴
关217-59-4兴
关02/18兴
关99/16兴
关218-01-9兴
关02/18兴
关84-15-1兴
关97/1兴
关97/1兴
关96/10兴
关89/14兴
关87/5兴
关92-06-8兴
关01/1兴
关87/5兴
关92-94-4兴
关02/18兴
关87/5兴
关21811-64-3兴
关87/5兴
关603-34-9兴
关87/5兴
关3808-37-5兴
关87/5兴
关115-86-6兴
关87/5兴关57/8兴
关603-35-0兴
关87/5兴
关81/3兴
关84-47-9兴
关87/5兴
关02/18兴
关1498-69-7兴
关87/5兴
关87/5兴关64/12兴
ENTHALPIES OF VAPORIZATION
787
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C18H18
C18H22
C18H22
C18H22
C18H22
C18H22N4
C18H24
C18H24O4
C18H26O4
C18H26O4
C18H28
C18H30
C18H30
C18H30
C18H30
C18H30O2
C18H30O2
C18H30O4
C18H30O6
C18H30O6
C18H30O6
C18H32
C18H32
C18H32
C18H32O
C18H32O6
C18H34
C18H34
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
1-methyl-7-isopropylphenanthrene
共539– 678兲
54.0
共554兲
1,6-diphenylhexane
共293–373兲
88.0
共308兲
2,2-di共p-tolyl兲butane
共298 – 473兲
85.4
共313兲
1-p-tolyl-共1-p-propylphenyl兲ethane
共298 – 473兲
85.4
共313兲
1-o-tolyl-p-tolylbutane
共298 – 473兲
85.4
共313兲
trans, trans-1,6-diphenyl-3,3,4,4-tetramethyl-1,2,5,6-tetraazahexane
共348 –388兲
92.8⫾1.5
共368兲
1,2,3,4,4a,7,8,9,10,12,12a-dodecahydrochrysene
共318 –358兲
84.2
共333兲
butylcyclohexylphthalate
共368 – 485兲
94.3
共383兲
diisopentylphthalate
共390– 610兲
81.6
共405兲
dipentylphthalate
共323–390兲
87.3
共338兲
共303–500兲
99.4
共318兲
1,2,3,4-tetrahydro-6-octylnaphthalene
共503–574兲
103.3
共538兲
dodecylbenzene
92.0
共275兲
共333– 453兲
83.2
共348兲
共496 – 609兲
67.4
共511兲
共336 – 456兲
80.6
共356兲
89.6
共298兲
perhydrochrysene
共273–353兲
82.4
共288兲
hexaethylbenzene
共407–572兲
62.6
共422兲
1,2,4,5-tetraisopropylbenzene
共410–575兲
61.1⫾0.3
共420兲
共410–575兲
56.8⫾0.3
共460兲
共410–575兲
52.3⫾0.5
共500兲
共410–575兲
47.5⫾0.9
共540兲
1,3-dimethoxy-4-decylbenzene
共443– 493兲
76.6
共458兲
1,3-dimethoxy-5-decylbenzene
共459–519兲
78.4
共474兲
1,4-bis共1,1-diethoxyethyl兲lbenzene
共329–347兲
88.5
共338兲
trans aconitic acid, tributyl ester
共385– 483兲
87.4
共400兲
diethylene glycol dicarboxylic acid, di关1-共isopropoxycarbonyl兲 ethyl兴 ester
共418 – 493兲
97.6
共433兲
diethylene glycol dicarboxylic acid, di关1-共propoxycarbonyl兲 ethyl兴 ester
共418 –514兲
101.5
共433兲
9-butyltetrahydroanthracene
共420– 456兲
72.8
共435兲
1,2-dicyclohexylcyclohexane
共375–563兲
72.8
共390兲
1,6-dicyclohexylcyclohexane
共288 –373兲
85.9
共303兲
6,10,14-trimethyl-3,5-pentadecadien-2-one
共404 –560兲
43.4⫾0.5
共482兲
tributyl 1,2,3-propanetricarboxylate
共385– 482兲
87.8
共400兲
共323–368兲
81.9
共328兲
1-octadecyne
共450– 623兲
64.9
共465兲
2-octadecyne
Method
A
A
CAS registry number
Reference
关483-65-8兴
关87/5兴
关1087-49-6兴
关87/5兴关64/12兴
关99/16兴
关99/16兴
关99/16兴
A
关93/16兴
关1610-22-6兴
关87/5兴关47/5兴
关84-64-0兴
关87/5兴
关606-50-5兴
关87/5兴
关131-18-0兴
关49/9兴
关87/5兴关48/10兴
关66553-12-6兴
关99/16兴
关123-01-3兴
关00/4兴
关93/10兴
关87/5兴
关86/6兴
关71/28兴
关2090-14-4兴
关64/12兴
关604-88-6兴
关87/5兴关47/5兴
关635-11-0兴
关02/20兴
关02/20兴
关02/20兴
关02/20兴
关59968-12-6兴
关87/5兴关75/24兴
关41442-52-8兴
关87/5兴关75/24兴
关47189-08-2兴
关87/5兴
关7568-58-3兴
关87/5兴
A
关87/5兴
A
关87/5兴
A
关87/5兴
关2456-43-1兴
关87/5兴
关1610-23-7兴
关87/5兴关64/12兴
关1604-32-6兴
关88/4兴
关38094-11-0兴
关87/5兴
关49/16兴
关629-89-0兴
关99/16兴
关61847-97-0兴
GS
A
A
A
T
A, ME
A
GS
A
EB
EB
EB
EB
A, GC
A, GC
A
A
A
A
T
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
788
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C18H34
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O2
C18H34O4
C18H34O4
C18H34O5
C18H34O6
C18H35N
C18H36
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共458 – 633兲
65.7
3-octadecyne
共449– 622兲
64.5
cis 9-octadecenoic acid
共441– 633兲
83.8
trans 9-octadecenoic acid
共444 – 635兲
82.3
tetradecyl methacrylate
共463– 611兲
69.1
共Z兲 3-hexadecenyl acetate
共373– 418兲
98.5
共E兲 3-hexadecenyl acetate
共373– 418兲
99.1
共Z兲 4-hexadecenyl acetate
共373– 418兲
97.7
共E兲 4-hexadecenyl acetate
共373– 418兲
98.9
共Z兲 5-hexadecenyl acetate
共373– 418兲
98.0
共E兲 5-hexadecenyl acetate
共373– 418兲
98.8
共Z兲 6-hexadecenyl acetate
共373– 418兲
97.8
共E兲 6-hexadecenyl acetate
共373– 418兲
98.6
共Z兲 7-hexadecenyl acetate
共373– 418兲
97.8
共E兲 7-hexadecenyl acetate
共373– 418兲
98.5
共Z兲 8-hexadecenyl acetate
共373– 418兲
97.8
共E兲 8-hexadecenyl acetate
共373– 418兲
98.6
共Z兲 9-hexadecenyl acetate
共373– 418兲
98.2
共E兲 9-hexadecenyl acetate
共373– 418兲
98.9
共Z兲 10-hexadecenyl acetate
共373– 418兲
98.5
共E兲 10-hexadecenyl acetate
共373– 418兲
99.1
共Z兲 11-hexadecenyl acetate
共373– 418兲
98.9
共E兲 11-hexadecenyl acetate
共373– 418兲
99.5
共Z兲 12-hexadecenyl acetate
共373– 418兲
99.5
共E兲 12-hexadecenyl acetate
共373– 418兲
99.8
共Z兲 13-hexadecenyl acetate
共373– 418兲
100.0
共E兲 13-hexadecenyl acetate
共373– 418兲
100.3
dihexyl adipate
共470–595兲
80.4
dibutyl decanedioate
共401–520兲
94.3
decyl关1-共butoxycarbonyl兲ethyl兴carbonate
共391–503兲
79.3
triethylene glycol, bis共2-ethylbutyrate兲
共313–528兲
91.7
stearonitrile
共478 – 631兲
78.6
tridecylcyclopentane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共473兲
共464兲
共456兲
A
共459兲
A
共478兲
A
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共485兲
A
共416兲
A
共406兲
A
共328兲
A
共493兲
A
CAS registry number
Reference
关99/16兴
关61886-64-4兴
关99/16兴
关112-80-1兴
关87/5兴
关112-79-8兴
关87/5兴关47/5兴
关2549-53-3兴
关87/5兴
关141694-86-2兴
关97/13兴关00/10兴
关128984-60-1兴
关97/13兴关00/10兴
关65954-24-7兴
关97/13兴关00/10兴
关155055-27-9兴
关97/13兴关00/10兴
关34010-18-9兴
关97/13兴关00/10兴
关56218-65-6兴
关97/13兴关00/10兴
关34010-19-0兴
关97/13兴关00/10兴
关56218-66-7兴
关97/13兴关00/10兴
关23192-42-9兴
关97/13兴关00/10兴
关23192-83-8兴
关97/13兴关00/10兴
关56218-67-8兴
关97/13兴关00/10兴
关56218-68-9兴
关97/13兴关00/10兴
关34010-20-3兴
关97/13兴关00/10兴
关56218-69-0兴
关97/13兴关00/10兴
关56218-70-3兴
关97/13兴关00/10兴
关56218-71-4兴
关97/13兴关00/10兴
关34010-21-4兴
关97/13兴关00/10兴
关56218-72-5兴
关97/13兴关00/10兴
关56218-73-6兴
关97/13兴关00/10兴
关64789-90-8兴
关97/13兴关00/10兴
关56218-74-7兴
关97/13兴关00/10兴
关69282-67-3兴
关97/13兴关00/10兴
关110-33-8兴
关87/5兴
关109-43-3兴
关87/5兴
关87/5兴
关95-08-9兴
关87/5兴
关638-65-3兴
关87/5兴
关6006-34-4兴
ENTHALPIES OF VAPORIZATION
789
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共463– 634兲
C18H36
C18H36
C18H36O
C18H36O
C18H36O
C18H36O
C18H36O
C18H36O
C18H36O
C18H36O
C18H36O
C18H36O
C18H36O2
C18H36O2
C18H36O2
C18H36O2
C18H37Br
C18H37Cl
C18H37F
C18H37I
C18H38
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
70.9
90.5
共478兲
共298兲
88.9⫾0.8
89.5
93.4
共298兲
共298兲
共311兲
76.4
90.0
共414兲
共298兲
A
120.5
共298兲
CGC
120.0
共298兲
CGC
119.3
共298兲
CGC
120.1
共298兲
CGC
119.6
共298兲
CGC
120.4
共298兲
CGC
120.8
共298兲
CGC
121.2
共298兲
CGC
56.0⫾0.6
共451兲
75.7
共428兲
A
102.3
70.3
共298兲
共446兲
GC
A
73.9
100.7
共444兲
共308兲
A
ME
89.3
89.0⫾0.7
97.0⫾1.2
84.4
共350兲
共353兲
共298兲
共436兲
A, EST
124.3
100.6
118.9⫾2.0
79.8
共364兲
共472兲
共379兲
共515兲
A
A
ME, TE
I
81.0
共445兲
A, EST
96.9
93.4
88.4
86.7
74.2
共333兲
共353兲
共373兲
共393兲
共487兲
GC
GC
GC
GC
A
68.2
共492兲
A, EST
77.2
共511兲
A, EST
90.6⫾1.0
91.3⫾2.9
91.4⫾1.3
共298兲
共298兲
共298兲
CGC
GS
CGC
Method
dodecylcyclohexane
共299–324兲
1-octadecene
共399–589兲
共Z兲 3-octadecen-1-ol
共393– 433兲
共E兲 3-octadecen-1-ol
共393– 433兲
共Z兲 9-octadecen-1-ol
共393– 433兲
共E兲 9-octadecen-1-ol
共393– 433兲
共Z兲 11-octadecen-1-ol
共393– 433兲
共E兲 11-octadecen-1-ol
共393– 433兲
共Z兲 13-octadecen-1-ol
共393– 433兲
共E兲 13-octadecen-1-ol
共393– 433兲
6,10,14-trimethyl-2-pentadecanone
共402–500兲
octadecanal
共413– 616兲
hexadecyl acetate
共373– 418兲
共431– 469兲
ethyl palmitate
共429– 466兲
共298 –318兲
methyl heptadecanoate
共421–525兲
octadecanoic acid 共stearic acid兲
共349– 415兲
共457– 649兲
共366 –389兲
1-bromooctadecane
共430– 673兲
1-chlorooctadecane
共333–393兲
共333–393兲
共333–393兲
共333–393兲
共472– 673兲
1-fluorooctadecane
共477– 633兲
1-iodooctadecane
共496 – 673兲
GCC
A, ME
octadecane
CAS registry number
Reference
关99/16兴
关71/28兴
关1795-17-1兴
关78/16兴
关71/28兴
关87/5兴关49/14兴
关112-88-9兴
关87/5兴
关71/28兴
关41207-35-6兴
关00/10兴关94/13兴
关41207-36-7兴
关00/10兴关94/13兴
关143-28-2兴
关00/10兴关94/13兴
关506-42-3兴
关00/10兴关94/13兴
关57716-88-8兴
关00/10兴关94/13兴
关62972-93-4兴
关00/10兴关94/13兴
关69820-27-5兴
关00/10兴关94/13兴
关76836-10-7兴
关00/10兴关94/13兴
关502-69-2兴
关88/4兴
关638-66-4兴
关87/5兴关47/5兴
关629-70-9兴
关97/13兴关00/10兴
关87/5兴
关628-97-7兴
关87/5兴
关87/5兴关67/22兴
关1731-92-6兴
关02/27兴
关02/27兴
关02/27兴
关87/5兴关63/16兴
关55-11-4兴
关87/5兴
关87/5兴
关82/4兴
关43/7兴
关112-89-0兴
关87/5兴关61/13兴
关70/14兴
关3386-33-2兴
关80/14兴
关80/14兴
关80/14兴
关80/14兴
关87/5兴关70/14兴
关1649-73-6兴
关87/5兴关61/13兴
关70/14兴
关629-93-6兴
关87/5兴关61/13兴
关70/14兴
关593-45-3兴
关02/44兴
关01/1兴
关00/9兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
790
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共363– 413兲
共423– 473兲
共453–503兲
共413–588兲
共501–548兲
共335– 439兲
共318 –361兲
C18H38
C18H38
C18H38
C18H38
C18H38
C18H38
C18H38
C18H38
C18H38O
C18H38S
C18H38S2
C18H38O4
C18H39N
C18H39N
C18H39N
C18H39N
C19H13NO
C19H16
C19H17NO2
C19H20O2
C19H20O4
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
91.8
91.8
92.8
74.4
91.4
64.8
80.0
84.3
72.5
71.8
71.1
70.5
69.8
90.8
78.1
69.4
共298兲
共298兲
共298兲
共428兲
共298兲
共516兲
共348兲
共333兲
共343兲
共353兲
共363兲
共373兲
共383兲
共298兲
共460兲
共462兲
共447– 474兲
共447–590兲
2-methylheptadecane
共442–581兲
67.8
3-methylheptadecane
共441–583兲
65.6
4-methylheptadecane
共429–580兲
58.9
5-methylheptadecane
共432–581兲
61.1
2,3-dimethylhexadecane
共466 –583兲
64.9
2,4-dimethylhexadecane
共434 –562兲
69.0
2,4,6-trimethylpentadecane
共420–550兲
64.3
4,9-diisopropyldodecane
共368 – 424兲
70.0
1-octadecanol
共435–504兲
86.4
共500–573兲
76.3
共494 –575兲
76.9
共334 –356兲
113.5
1-octadecanethiol
共492– 670兲
77.1
dinonyl disulfide
共490– 650兲
78.3
2-关2-共2-关dodecyloxy兴ethoxy兲ethoxy兴ethanol
共475–523兲
102.7
N,N-dimethylhexadecylamine
共483– 671兲
67.3
dinonylamine
共486 – 676兲
67.7
N-ethylhexadecylamine
共406 – 613兲
66.4
octadecylamine
共450– 635兲
76.2
2-共1-naphthyl兲-5-phenyloxazole
共510–595兲
89.2
triphenylmethane
94.6
共453–503兲
95.0
共343– 462兲
82.0
共512– 643兲
58.6
1-piperidinoanthraquinone
共395– 404兲
82.0
3-共diphenylmethyl兲-3-methyl-2,4-pentanedione
共353–386兲
83.1⫾0.5
butyl benzyl phthalate
共416 –516兲
89.0
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CGC
CGC
CGC
GS
A, GS
GC
GC
GC
GC
GC
ME
共457兲
A
共456兲
A
共444兲
A
共447兲
A
共481兲
A
共449兲
A
共435兲
A
共383兲
A
共450兲
共515兲
共509兲
共345兲
A
A
A, EB
A, ME
共507兲
EST
共514兲
共490兲
A
共498兲
A
共501兲
A
共421兲
A
共465兲
A
共525兲
A
共298兲
共298兲
共403兲
共527兲
CGC
CGC
共399兲
A
共370兲
GS
共431兲
A
A
CAS registry number
Reference
关95/21兴
关95/21兴
关95/21兴
关94/14兴
关94/12兴
关87/5兴
关86/6兴
关87/5兴关79/11兴
关77/34兴
关77/34兴
关77/34兴
关77/34兴
关77/34兴
关71/28兴
关38/8兴
关1882/1兴关84/9兴
关1560-89-0兴
关87/5兴关59/15兴
关6418-44-6兴
关87/5兴关59/15兴
关26429-11-8兴
关87/5兴关59/15兴
关26730-95-0兴
关87/5兴关59/15兴
关61868-02-8兴
关87/5兴关59/15兴
关61868-08-4兴
关87/5兴关59/15兴
关101882-67-1兴
关87/5兴关99/16兴
关59/15兴
关87/5兴
关112-92-5兴
关87/5兴
关87/5兴
关87/5兴关70/2兴
关87/5兴关65/15兴
关2885-00-9兴
关99/16兴
关4485-77-2兴
关99/16兴
关3055-94-5兴
关87/5兴
关112-69-6兴
关87/5兴
关2044-21-5兴
关87/5兴
关5877-76-9兴
关87/5兴关47/5兴
关124-30-1兴
关87/5兴
关846-63-9兴
关87/5兴
关519-73-3兴
关98/11兴
关95/21兴
关89/14兴
关87/5兴
关4946-83-2兴
关87/5兴
关95/28兴
关85-68-7兴
关87/5兴
ENTHALPIES OF VAPORIZATION
791
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C19H20O4
C19H24
C19H30
C19H32
C19H32
C19H32O2
C19H34
C19H34O2
C19H36
C19H36
C19H36
C19H36
C19H36O2
C19H36O2
C19H36O3
C19H36O5
C19H37NO
C19H37NO3
C19H38
C19H38
C19H38
C19H38
C19H38
C19H38O2
Compound
共Temperature range/K兲
dibenzyl ethylmalonate
共403– 483兲
dicumenylmethane
共303– 402兲
共608 –704兲
共323– 402兲
7-phenyl-6-tridecene
共391– 449兲
tridecylbenzene
共473– 651兲
共343– 463兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
94.1
共418兲
A
71.0
57.9
73.7
共318兲
共623兲
共338兲
A
77.2
共406兲
A, MG
72.0
90.0
94.6
共488兲
共358兲
共298兲
7-phenyltridecane
共413– 470兲
76.2
methyl linolenate
共423–503兲
102.1
共394 – 459兲
87.7
tricyclohexylmethane
共333–365兲
81.4
共428 – 605兲
73.3
linoleic acid, methyl ester 共methyl linoleate兲
共423–503兲
102.2
共453–543兲
77.2
共391– 459兲
86.3
1,1-dicyclohexylheptane
共293–368兲
87.8
共422– 458兲
73.8
1-nonadecyne
共462– 637兲
66.9
2-nonadecyne
共469– 648兲
67.8
3-nonadecyne
共460– 635兲
66.5
methyl cis-9-octadecenoate 共methyl oleate兲
共423–503兲
103.3
共433– 473兲
99.6
共453–543兲
77.2
106.8⫾1.0
共428 – 486兲
83.0
共401– 458兲
86.7
methyl elaidate
共453–543兲
77.2
methyl ricinoleate
共453–543兲
89.3
undecyl关1-共butoxycarbonyl兲ethyl兴carbonate
共438 – 637兲
77.0
octadecyl isocyanate
共388 – 494兲
77.8
2-关2-ethyl-共hexanoyloxy兲兴-N,N-dibutylpropionamide
共403– 448兲
83.0
tridecylcyclohexane
共474 – 651兲
72.2
94.5
7-cyclohexyltridecane
共391– 449兲
75.6
tetradecylcyclopentane
共475– 648兲
73.6
95.4
7-共cyclopentylmethyl兲tridecane
共389– 446兲
76.5
1-nonadecene
共560– 604兲
63.3
95.0
methyl stearate
共428兲
A, MG
共298兲
共409兲
GC
A, MG, OM
共348兲
共443兲
A
A
共298兲
共498兲
共406兲
GC
GC
A, MG, OM
共330兲
共437兲
A
A, MG
共477兲
共484兲
共475兲
共298兲
共298兲
共498兲
共298兲
共443兲
共416兲
GC
CGC
GC
GCC
A
MG, OM
共498兲
GC
共498兲
GC
共453兲
A
共403兲
A
共418兲
A
共489兲
共298兲
共406兲
A, MG
共490兲
共298兲
共404兲
A, MG
共575兲
共298兲
A
CAS registry number
Reference
关74254-53-8兴
关87/5兴
关25566-92-1兴
关99/16兴
关99/16兴
关87/5兴
关87/5兴关55/11兴
关123-02-4兴
关99/16兴
关90/13兴
关71/28兴
关2400-01-3兴
关87/5兴关55/11兴
关301-00-8兴
关97/28兴
关87/5兴关52/13兴
关1610-24-8兴
关87/5兴关64/12兴
关87/5兴
关112-62-9兴
关97/28兴
关93/9兴
关87/5兴关52/13兴
关2090-15-5兴
关87/5兴关99/16兴
关87/5兴关55/11兴
关26186-01-6兴
关99/16兴
关61847-98-1兴
关99/16兴
关61886-65-5兴
关99/16兴
关112-62-9兴
关97/28兴
关95/21兴
关93/9兴
关80/5兴
关87/5兴关64/13兴
关52/13兴
关1937-62-8兴
关93/9兴
关141-24-2兴
关93/9兴
关87/5兴
关112-96-9兴
关87/5兴
关87/5兴
关6006-33-3兴
关99/16兴
关71/28兴
关13151-92-3兴
关87/5兴关55/11兴
关1795-22-8兴
关99/16兴
关71/28兴
关55044-77-4兴
关87/5兴关55/11兴
关18435-45-5兴
关87/5兴
关71/28兴
关112-61-8兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
792
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C19H38O2
C19H38O2
C19H38O2
C19H38O3
C19H38O3
C19H39Br
C19H39Cl
C19H39F
C19H39I
C19H39NO2
C19H39NO2
C19H40
Compound
共Temperature range/K兲
共463–523兲
共453–543兲
共427– 484兲
propyl palmitate
共439– 477兲
isopropyl palmitate
共433– 471兲
nonadecanoic acid
共511– 659兲
共371–394兲
hexadecyl lactate
共405–556兲
3-octyloxypropionic acid, octyl ester
共443–513兲
1-bromononadecane
共493– 673兲
C19H40
C19H40
C19H40
C19H40
C19H40
C19H40
C19H40
C19H40O
Mean temperature
(T m /K)
98.0
90.0⫾0.3
105.9⫾1.4
106.2
75.4
83.2
共350兲
共401兲
共298兲
共298兲
共498兲
共442兲
GC
GC
A
74.5
共454兲
A
73.6
共448兲
A
94.4
121.8
共526兲
共386兲
A
ME, TE
90.5
共420兲
A
73.6
共458兲
A
77.9
共508兲
A, EST
Method
CAS registry number
Reference
关02/27兴
关02/27兴
关02/27兴
关97/28兴
关93/9兴
关87/5兴关64/13兴
关2239-78-3兴
关87/5兴关48/8兴
关84/9兴
关142-91-6兴
关87/5兴关48/8兴
关84/9兴
关646-30-0兴
关87/5兴
关82/4兴
关35274-05-6兴
关87/5兴
关87/5兴
关4434-66-6兴
关87/5兴关61/13兴
关70/14兴
关62016-76-6兴
关87/5兴关70/14兴
关1480-63-3兴
关87/5兴关61/13兴
关70/14兴
关62127-51-9兴
关87/5兴关61/13兴
关70/14兴
1-chlorononadecane
共483– 673兲
1-fluorononadecane
共458 – 648兲
76.3
共498兲
A
72.5
共473兲
A, EST
1-iodononadecane
共506 – 673兲
79.1
共521兲
A, EST
111.0
共438兲
A
关87/5兴
99.3
共468兲
A
76.2
96.4
73.0
95.8
共438兲
共298兲
共471兲
共298兲
2-methyloctadecane
共451–595兲
67.5
共466兲
A
3-methyloctadecane
共455–597兲
69.2
共470兲
A
4-methyloctadecane
共445–596兲
63.3
共460兲
A
5-methyloctadecane
共445–595兲
63.8
共460兲
A
64.1
67.2
共462兲
共508兲
A
70.6
共459兲
A
67.3
共450兲
A
75.2
共426兲
A
81.7
共494兲
A
关87/5兴
关629-92-5兴
关94/14兴
关94/12兴
关87/5兴
关71/28兴
关1560-88-9兴
关87/5兴关99/16兴
关59/15兴
关6561-44-0兴
关87/5兴关99/16兴
关59/15兴
关10544-95-3兴
关87/5兴关99/16兴
关59/15兴
关25117-35-5兴
关87/5兴关99/16兴
关59/15兴
关61868-03-9兴
关99/16兴关59/15兴
关87/5兴
关61868-09-5兴
关87/5兴关99/16兴
关59/15兴
关102013-94-5兴
关87/5兴关99/16兴
关59/15兴
关7225-66-3兴
关87/5兴
关1454-84-8兴
关87/5兴
N-hexadecyl lactamide
共423–508兲
N,N-dioctyl lactamide
共453– 488兲
nonadecane
共423–588兲
共456 – 606兲
C19H40
⌬ vapH m
共kJ mol⫺1兲
2,3-dimethylheptadecane
共447–598兲
共493–598兲
2,4-dimethylheptadecane
共444 –574兲
2,4,6-trimethylhexadecane
共435–568兲
7-hexyltridecane
共411– 444兲
1-nonadecanol
共479– 640兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
ENTHALPIES OF VAPORIZATION
793
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
C20H10
共494 – 635兲
1-nonadecanethiol
共502– 682兲
nonadecylamine
共532– 647兲
corannulene
C20H12
perylene
C19H40S
C19H41N
C20H12
C20H12
C20H12
C20H12
C20H14
C20H14O4
C20H16
C20H16
C20H22N2 O2
C20H24O6
C20H26O4
C20H28
C20H16
C20H28
C20H28
C20H28
C20H30
C20H30O4
C20H32
共323– 473兲
benzo关a兴pyrene
共323– 473兲
共343– 453兲
benzo关e兴pyrene
共343– 453兲
benzo关k兴fluoranthene
共323– 473兲
benzo关b兴fluoranthene
共323– 473兲
9-phenylanthracene
共323– 473兲
共430–510兲
共435–513兲
dibenzoyl resorcinol
共399– 493兲
7,12-dimethylbenz关a兴anthracene
共323– 473兲
共396 – 408兲
5,6-dimethylchrysene
共380–394兲
1,4-bis共propylamino兲anthraquinone
共409– 463兲
dibenzo-18-crown-6
dicyclohexyl phthalate
共391– 475兲
2-butyl-3-hexylnaphthalene
共422– 485兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
80.0
共509兲
A
79.2
共517兲
EST
72.7
共547兲
A, EST
115.5⫾2.5
共298兲
CGC
123.1⫾1.7
89.9
共298兲
共398兲
CGC
GC
91.0
95.5
共398兲
共398兲
GC
GC
92.0
共398兲
GC
88.5
共398兲
GC
89.7
共398兲
GC
91.6
84.4
86.2
共398兲
共445兲
共450兲
GC
A
76.0
共414兲
A, UV
88.9
112.9
共398兲
共402兲
GC
A, ME
121.7
共387兲
A
118.3
共424兲
A
137.0⫾7.4
共298兲
CGC
97.0
共406兲
A
80.8
共437兲
triphenylethylene
共353– 443兲
7-butyl-1-hexylnaphthalene
共418 – 481兲
89.7
共398兲
78.1
共433兲
1,4-dimethyl-5-octylnaphthalene
共432– 496兲
81.6
共447兲
2,6-dimethyl-3-octylnaphthalene
共430– 494兲
80.8
共445兲
hexacyclopropylethane
共333–373兲
85.8⫾0.2
dihexyl phthalate
共453–533兲
92.0
共343–387兲
103.0
1,2,3,4-tetrahydro-6-butyl-7-hexylnaphthalene
共413– 475兲
78.1
共298兲
GS
共468兲
共358兲
A
A, ME
共428兲
C20H32
1,2,3,4-tetrahydro-7-butyl-1-hexylnaphthalene
共409– 471兲
76.7
共424兲
C20H32
1,2,3,4-tetrahydro-2,6-dimethyl-7-octylnaphthalene
共418 – 480兲
79.4
共433兲
CAS registry number
Reference
关87/5兴
关53193-23-0兴
关99/16兴
关14130-05-3兴
关87/5兴关56/17兴
关5821-51-2兴
关02/44兴
关198-55-0兴
关02/44兴
关02/18兴
关50-32-8兴
关02/18兴
关90/2兴
关192-97-2兴
关90/2兴
关207-08-9兴
关02/18兴
关205-99-2兴
关02/18兴
关602-55-1兴
关02/18兴
关87/5兴
关99/16兴关74/35兴
关94-01-9兴
关87/5兴关60/2兴
关313-74-6兴
关02/18兴
关87/5兴关64/22兴
关99/16兴
关3697-27-6兴
关87/5兴
关87/5兴
关14187-32-7兴
关00/9兴
关84-61-7兴
关87/5兴
关55000-56-1兴
关63/24兴关84/9兴
关99/16兴
关58-72-0兴
关89/14兴
关55000-55-0兴
关63/24兴关84/9兴
关99/16兴
关55000-53-8兴
关63/24兴关84/9兴
关99/16兴
关55000-54-9兴
关63/24兴关84/9兴
关99/16兴
关26902-55-6兴
关95/27兴
关84-75-3兴
关87/5兴
关87/5兴关48/10兴
关66538-96-3兴
关63/24兴关84/9兴
关99/16兴
关66205-02-5兴
关63/24兴关84/9兴
关99/16兴
关55255-59-9兴
关63/24兴关84/9兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
794
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
C20H32
1,2,3,4-tetrahydro-5,8-dimethyl-1-octylnaphthalene
共419– 481兲
78.6
C20H34
9-cyclohexyltetradecahydroanthracene
共419– 488兲
tetradecylbenzene
共485– 665兲
C20H34
C20H34O2
C20H34O11
C20H34O11
C20H34O11
C20H36O2
C20H36O6
C20H38
C20H38
Mean temperature
(T m /K)
74.5
共434兲
74.5
99.6
共500兲
共298兲
C20H38O2
C20H38O2
C20H38O2
C20H38O2
C20H38O2
C20H38O2
C20H38O2
C20H38O2
C20H38O2
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
关87/5兴
关544-35-4兴
关87/5兴
A
GC
关97/13兴关00/10兴
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
共298兲
GC
关97/13兴关00/10兴
关693-80-1兴
关97/13兴关00/10兴
关22147-38-2兴
关97/13兴关00/10兴
关6186-98-7兴
关97/13兴关00/10兴
关69282-64-0兴
关97/13兴关00/10兴
关60037-58-3兴
关97/13兴关00/10兴
共298兲
GC
关97/13兴关00/10兴
共298兲
GC
关97/13兴关00/10兴
2,6-dimethyl-3-octyldecahydronaphthalene
共406 – 469兲
76.4
3,4-dicyclohexyl-3,4-dimethylhexane
共343–365兲
78.4
1-eicosyne
共473– 651兲
68.9
2-eicosyne
共480– 661兲
69.8
3-eicosyne
共470– 648兲
68.4
3,7,11,15-tetramethyl-1-hexadecyn-3-ol
共403– 457兲
43.8⫾1.9
ethyl oleate
共384 – 481兲
92.4
hexadecyl methacrylate
共431–541兲
73.1
共Z兲 3-octadecenyl acetate
共393– 438兲
108.7
共E兲 3-octadecenyl acetate
共393– 438兲
109.3
共Z兲 9-octadecenyl acetate
共393– 438兲
107.8
共E兲 9-octadecenyl acetate
共393– 438兲
108.7
共Z兲 11-octadecenyl acetate
共393– 438兲
108.4
共E兲 11-octadecenyl acetate
共393– 438兲
109.1
共Z兲 13-octadecenyl acetate
共393– 438兲
108.7
共E兲 13-octadecenyl acetate
共393– 438兲
109.8
共Z兲 15-octadecenyl acetate
共393– 438兲
110.2
C20H38O2
A
共298兲
C20H38
C20H38O2
关87/5兴
A
共419兲
C20H38O
A
共446兲
1,4-dimethyl-5-octyldecahydronaphthalene
共404 – 466兲
73.9
C20H38
关87/5兴
A
C20H38
C20H38
A
共399兲
共422兲
C20H38
A
A
关00/9兴
关66455-55-8兴
关63/24兴关84/9兴
关99/16兴
关66455-54-7兴
关63/24兴关84/9兴
关99/16兴
关54964-83-9兴
关63/24兴关84/9兴
关99/16兴
关54964-85-1兴
关63/24兴关84/9兴
关26527-76-4兴
关99/16兴关80/16兴
关765-27-5兴
关99/16兴
关61847-99-2兴
关99/16兴
关61886-66-6兴
关99/16兴
关29171-23-1兴
关88/4兴
关111-62-6兴
关87/5兴
关2495-27-4兴
关87/5兴
80.0
C20H38
CAS registry number
Reference
关99/16兴
关55255-58-8兴
关63/24兴关84/9兴
关99/16兴
关55255-70-4兴
关87/5兴
关1459-10-5兴
关99/16兴
关71/28兴
关1191-41-9兴
关87/5兴
共434兲
ethyl linolenate
共447– 491兲
72.7
共462兲
diethylene glycol dicarboxylic acid, di关1-共butoxycarbonyl兲ethyl兴 ester
共433–525兲
103.6
共448兲
diethylene glycol dicarboxylic acid, di关1-共sec-butoxycarbonyl兲ethyl兴 ester
共418 –513兲
103.1
共433兲
diethylene glycol dicarboxylic acid, di关1-共isobutoxycarbonyl兲ethyl兴 ester
共415–513兲
103.1
共430兲
ethyl linoleate
共448 – 497兲
72.6
共463兲
共syn-cis/anti-cis兲 dicyclohexano-18-crown-6
124.2⫾4.0
共298兲
2-butyl-3-hexyldecahydronaphthalene
共407– 472兲
76.9
共422兲
7-butyl-1-hexyldecahydronaphthalene
共407– 467兲
Method
CGC
共421兲
共359兲
共488兲
共495兲
共485兲
共430兲
ENTHALPIES OF VAPORIZATION
795
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C20H38O2
C20H38O4
C20H38O4
C20H38O5
C20H40
C20H40
C20H40
C20H40O
C20H40O2
C20H40O2
C20H40O2
C20H40O2
C20H40O2
C20H40O2
C20H40O2
C20H41Br
C20H41Cl
C20H41F
C20H41I
C20H42
C20H42
C20H42
C20H42
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共E兲 15-octadecenyl acetate
共393– 438兲
110.5
dioctyl succinate
共503–523兲
94.2
dipentyl sebacate
共353– 408兲
99.2
dodecyl关1-共butoxycarbonyl兲ethyl兴 carbonate
共408 – 498兲
82.8
1-eicosene
共478 – 638兲
74.3
共573– 615兲
65.0
100.0
tetradecylcyclohexane
共486 – 665兲
74.7
99.4
pentadecylcyclopentane
共486 – 661兲
76.5
100.3
3,7,11,15-tetramethyl-1-hexadecen-3-ol
共439– 468兲
67.0⫾2.0
octadecyl acetate
共393– 438兲
113.5
共341–500兲
94.3
butyl palmitate
共353–383兲
93.8
decyl decanoate
共341–398兲
97.8
eicosanoic acid
共477– 670兲
114.5
共380– 404兲
125.5
ethyl stearate
共454 – 469兲
111.9
共310–328兲
106.8
methyl nonadecanoate
101.2
105.0⫾2.4
109.5⫾2.7
共441–529兲
90.1
2-ethylhexyl laurate
共371– 452兲
91.4
共443–503兲
104.5
1-bromoeicosane
共502– 673兲
79.8
Mean temperature
(T m /K)
Method
共298兲
GC
共513兲
A
共368兲
A
共423兲
A
共493兲
共588兲
共298兲
A
共501兲
共298兲
共501兲
共298兲
共453兲
共298兲
共356兲
GC
A
共368兲
A
共356兲
A
共492兲
共392兲
A
ME, TE
共461兲
共319兲
A
A, ME
共350兲
共326兲
共298兲
共456兲
A, EST
共386兲
共298兲
GC
共517兲
A, EST
1-chloroeicosane
共492– 673兲
1-fluoroeicosane
共468 – 663兲
78.3
共507兲
A
74.3
共483兲
A, EST
1-iodoeicosane
共516 – 673兲
80.9
共531兲
A, EST
77.3
共438兲
A, MG
65.7
共473兲
A
75.8
共471兲
A
102.6⫾1.0
102.8⫾2.2
101.1⫾2.0
103.5
78.0
共298兲
共298兲
共298兲
共298兲
共448兲
CGC
GS
CGC
CGC
5-butylhexadecane
共423– 457兲
2,3-dimethyloctadecane
共458 – 612兲
2,4-dimethyloctadecane
共456 –583兲
eicosane
共453–503兲
共433–583兲
CAS registry number
Reference
关97/13兴关00/10兴
关14491-66-8兴
关87/5兴
关6819-09-6兴
关87/5兴
关87/5兴
关3452-07-1兴
关99/16兴
关87/5兴
关71/28兴
关1795-18-2兴
关99/16兴
关71/28兴
关4669-01-6兴
关99/16兴
关71/28兴
关60046-87-9兴
关88/4兴
关822-23-1兴
关97/13兴关00/10兴
关87/5兴
关111-06-8兴
关87/5兴
关1654-86-0兴
关87/5兴
关506-30-9兴
关87/5兴
关82/4兴
关111-61-5兴
关87/5兴
关87/5兴关67/22兴
关1731-94-8兴
关02/27兴
关02/27兴
关02/27兴
关87/5兴关63/16兴
关01/10兴
关97/28兴
关4276-49-7兴
关87/5兴关61/13兴
关70/14兴
关42217-02-7兴
关87/5兴关70/14兴
关676-44-8兴
关87/5兴关61/13兴
关70/14兴
关34994-81-5兴
关87/5兴关61/13兴
关70/14兴
关6912-07-8兴
关87/5兴关55/11兴
关61868-04-0兴
关87/5兴关59/15兴
关61868-10-8兴
关87/5兴关59/15兴
关112-95-8兴
关02/44兴
关01/1兴
关00/9兴
关95/21兴
关94/14兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
796
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共347–388兲
共345– 470兲
共388 – 625兲
共388 – 625兲
共363– 460兲
共528 – 620兲
共344 –380兲
C20H42
C20H42
C20H42
C20H42
C20H42
C20H42
C20H42O
C20H42O5
C20H42S
C20H42S2
C20H43N
C20H43N
C20H43N
C20H43N
C21H8 F28O8
C21H16
C21H19F
C21H21O4 P
C21H21O4 P
C21H21O4 P
C21H21P
C21H24O2
C21H26O3
C21H26O3
C21H26O3
C21H30
C21H36
⌬ vapH m
共kJ mol⫺1兲
101.8
110⫾2
79.0
80.8
68.3
89.6
71.1
93.3
100.8
2-methylnonadecane
共465– 607兲
72.4
3-methylnonadecane
共463– 609兲
71.3
4-methylnonadecane
共460– 609兲
68.4
5-methylnonadecane
共462– 609兲
69.1
4-propylheptadecane
共425– 459兲
79.2
2,4,6-trimethylheptadecane
共449–579兲
71.9
1-eicosanol
共488 – 653兲
83.5
共493– 648兲
83.4
共339–358兲
118.9
3,6,9,12-tetraoxa-1-tetracosanol
共501–543兲
135.5
1-eicosanethiol
共512– 694兲
81.3
didecyl disulfide
共518 –702兲
83.4
didecylamine
共506 –705兲
70.9
N,N-diethylhexadecylamine
共412– 628兲
71.9
N,N-dimethyloctadecylamine
共504 –701兲
74.7
eicosylamine
共543– 659兲
74.5
pentaerythritol, tetraperfluorobutyrate
共293– 433兲
35.5
3-methylcholanthrene
共323– 473兲
93.8
1-fluoro-3,3,3-triphenylpropane
共349–384兲
95.9⫾0.6
phosphoric acid, tri共2-tolyl兲 ester
共293–700兲
86.8
phosphoric acid, tri共3-tolyl兲 ester
共398 –530兲
123.2
phosphoric acid, tri共4-tolyl兲 ester
共388 –530兲
104.9
tris共4-tolyl兲phosphine
共372–394兲
126⫾5
3-共diphenylmethyl兲-3-propyl-2,4-pentanedione
共364 –392兲
96.7⫾1.7
2-hydroxy-4-共2-ethylhexyloxy兲benzophenone
共393– 443兲
98.7
2-hydroxy-4-octyloxybenzophenone
共413– 453兲
102.1
2-hydroxy-4-butoxy-5-tert-butylbenzophenone
共403– 453兲
90.2
1-undecylnaphthalene
共436 –502兲
84.3
pentadecylbenzene
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
共298兲
共368兲
共360兲
共440兲
共540兲
共378兲
共543兲
共359兲
共298兲
Method
TE
TE, ME, GS
EB, IPM
EB, IPM
A
A, GS
CAS registry number
Reference
关94/12兴
关94/2兴
关91/9兴
关89/1兴
关89/1兴
关88/12兴
关87/5兴
关87/5兴关79/11兴
关71/28兴
关1560-86-7兴
关87/5兴关59/19兴
关6418-45-7兴
关87/5兴关59/15兴
关25117-27-5兴
关87/5兴关59/15兴
关57160-72-2兴
关87/5兴关59/15兴
关55044-10-5兴
关87/5兴关55/11兴
关102155-32-8兴
关87/5兴关99/16兴
关629-96-9兴
关87/5兴
关87/5兴
关87/5兴关65/15兴
关5274-68-0兴
关87/5兴
关13373-97-2兴
关99/16兴
关10496-18-1兴
关99/16兴
关1120-49-6兴
关87/5兴
关30951-88-3兴
关87/5兴关47/5兴
关124-28-7兴
关87/5兴
关10525-37-8兴
关87/5兴关56/17兴
共480兲
A
共478兲
A
共475兲
A
共477兲
A
共440兲
A, MG
共464兲
A
共503兲
共508兲
共348兲
A
A
ME
共516兲
A
共527兲
EST
共533兲
EST
共521兲
A
共427兲
A
共519兲
A
共558兲
A
共308兲
IA
共398兲
GC
共298兲
GS
共308兲
A, I
共413兲
A
共408兲
A
共385兲
ME, TE
关97/14兴
关78-30-8兴
关87/5兴关57/8兴
关563-04-2兴
关87/5兴
关78-32-0兴
关87/5兴
关1038-95-5兴
关81/3兴
共378兲
GS
关95/28兴
共418兲
ME
关84/1兴
共433兲
ME
关84/1兴
共428兲
ME
共451兲
A, MG
关84/1兴
关7225-71-0兴
关87/5兴关55/11兴
关2131-18-2兴
关87/5兴关57/8兴
关56-49-5兴
关02/18兴
ENTHALPIES OF VAPORIZATION
797
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
77.0
104.6
共510兲
共298兲
88.3
共411兲
A
91.4
共418兲
A
94.2
共371兲
A, T
88.2
共411兲
A
90.2
共419兲
A
83.3
共411兲
A
92.8
共407兲
79.2
105.3
共513兲
共298兲
77.2
104.4
共511兲
共298兲
109.2
97.8⫾0.2
116.4⫾1.5
116.2
76.9
92.4
共350兲
共406兲
共298兲
共298兲
共498兲
共465兲
GC
GC
A, EST
76.6
共468兲
A
111.0
共320兲
A, ME
87.9
共470兲
A
112.8
共449兲
A
109.4⫾2.6
110⫾2
84.7
88.4
共298兲
共382兲
共367兲
共437兲
CGC
TE
TE, ME, GS
A, EST
70.3
共488兲
A
74.5
共492兲
A
4-methyleicosane
共471– 621兲
70.2
共486兲
A
5-methyleicosane
共519– 621兲
73.2
共534兲
A
2,3-dimethylnonadecane
共493– 635兲
68.8
共508兲
A
2,4-dimethylnonadecane
共465–594兲
77.0
共480兲
A
74.9
共475兲
A
78.5
共420兲
A
Compound
共Temperature range/K兲
共495– 677兲
C21H36O6
C21H36O6
C21H38O6
C21H38O6
C21H38O6
C21H40
C21H42
C21H42
C21H42
C21H42O2
C21H42O2
C21H42O2
C21H42O2
C21H43NO2
C21H44
C21H44
C21H44
C21H44
C21H44
C21H44
C21H44
C21H44
C21H44
C21H45PO
triisopentyl trans aconitate
共396 – 499兲
tripentyl trans aconitate
共403–505兲
glycerol tricaproate
共356 – 410兲
triisopentyl 1,2,3-propanetricarboxylate
共396 –508兲
tripentyl 1,2,3-propanetricarboxylate
共404 –508兲
1-undecyldecahydronaphthalene
共426 – 488兲
1-heneicosene
共392– 628兲
hexadecylcyclopentane
共498 – 674兲
pentadecylcyclohexane
共496 – 677兲
Method
关99/16兴
关71/28兴
methyl eicosanoate
共463–523兲
共453–543兲
共450–540兲
isopropyl stearate
共453– 483兲
ethyl nonadecanoate
共312–328兲
propyl stearate
共458 – 483兲
N-octadecyl lactamide
共434 –542兲
heneicosane
共365– 400兲
共352– 478兲
共422– 630兲
2-methyleicosane
共473– 621兲
3-methyleicosane
共477– 620兲
2,4,6-trimethyloctadecane
共460–576兲
8-hexylpentadecane
共405– 466兲
trioctylphosphine oxide
CAS registry number
Reference
关87/5兴
关64617-29-4兴
关87/5兴
关621-70-5兴
关87/5兴关49/16兴
关87/5兴
关5333-53-9兴
关87/5兴
关66326-27-0兴
关87/5兴
关1599-68-4兴
关99/16兴
关6812-39-1兴
关99/16兴
关71/28兴
关6006-95-7兴
关99/16兴
关71/28兴
关1120-28-1兴
关02/27兴
关02/27兴
关02/27兴
关97/28兴
关93/9兴
关87/5兴关63/16兴
关112-10-7兴
关87/5兴
关18281-04-4兴
关87/5兴关67/22兴
关3634-92-2兴
关87/5兴
关87/5兴
关629-94-7兴
关97/17兴
关94/2兴
关91/9兴
关87/5兴关66/8兴
关1560-84-5兴
关87/5兴
关6418-46-8兴
关87/5兴关99/16兴
关59/15兴
关25117-28-6兴
关87/5兴关99/16兴
关59/15兴
关25117-36-6兴
关87/5兴关99/16兴
关59/15兴
关75163-99-4兴
关87/5兴关99/16兴
关59/15兴
关115209-60-4兴
关87/5兴关99/16兴
关59/15兴
关11400-79-2兴
关87/5兴关99/16兴
关13475-75-7兴
关87/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
798
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C22H12
C22H14
C22H14
C22H22
C22H18O4
C22H38
C22H38
C22H38
C22H38
C22H40
C22H42O2
C22H42O2
C22H42O2
C22H42O4
C22H42O6
C22H44
C22H44
C22H44O2
C22H44O2
C22H44O2
C22H44O2
C22H46
C22H46
C22H46
C22H46
C22H46
C22H46
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共507– 638兲
70.8
benzo关ghi兴perylene
共323– 473兲
96.1
dibenz关a,c兴anthracene
共323– 473兲
97.5
dibenz关a,h兴anthracene
共323– 473兲
99.4
tribenzylmethane
共395– 648兲
79.0
dibenzyl phthalate
共445–513兲
121.4
hexadecylbenzene
共505– 688兲
79.5
1,1-bis共decahydro-1-naphthyl兲ethane
共432–503兲
77.3
1,2-bis共decahydro-1-naphthyl兲ethane
共440–507兲
89.3
1,5-dicylopentyl-3-共2-cyclopentylethyl兲-2-pentene
共427– 492兲
81.4
1,5-dicylopentyl-3-共2-cyclopentylethyl兲-2-pentane
共430– 494兲
83.6
butyl oleate
共353–393兲
97.7
cis 13-docosenoic acid 共erucic acid兲
共479– 655兲
98.2
trans 13-docosenoic acid
共482– 656兲
103.4
dioctyl adipate
共373– 493兲
99.0
bis共2-butoxyethyl兲 sebacoate
共368 – 423兲
120.3
1-docosene
共401– 640兲
95.6
hexadecylcyclohexane
共507– 689兲
79.6
109.3
butyl stearate
共352–399兲
99.9
ethyl eicosanoate
共318 – 460兲
113.7
methyl heneicosanoate
共459–529兲
95.6
docosanoic acid
共373– 600兲
122.3
docosane
114.9⫾0.3
115.6⫾1.9
共453–503兲
115.6
共453–573兲
84.3
共372– 410兲
124⫾2
共358 – 490兲
89.9
共353– 462兲
100.9
共431– 642兲
91.3
2-methylheneicosane
共485– 640兲
76.1
3-methylheneicosane
共484 – 631兲
74.4
4-methylheneicosane
共497– 632兲
5-methylheneicosane
共483– 632兲
2,4-dimethyleicosane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共573兲
共398兲
GC
共398兲
GC
共398兲
GC
共521兲
共460兲
A
共520兲
共447兲
A, MG
共455兲
A
共442兲
A, MG
共445兲
A, MG
共368兲
A
共494兲
A
共497兲
A
共388兲
A
共383兲
A, ME
共416兲
共522兲
共298兲
共367兲
A, T
共333兲
A
共474兲
A, EST
共388兲
A
共298兲
共298兲
共298兲
共468兲
共391兲
共373兲
共368兲
共446兲
CGC
CGC
CGC
TE
TE, ME, GS
A, EST
共500兲
A
共499兲
A
70.9
共494兲
A
73.9
共498兲
A
CAS registry number
Reference
关71/32兴
关191-24-2兴
关02/18兴
关215-58-7兴
关02/18兴
关53-70-3兴
关02/18兴
关4742-04-5兴
关99/16兴
关523-31-9兴
关87/5兴
关1459-09-2兴
关99/16兴
关54934-70-2兴
关87/5兴关55/11兴
关54934-69-9兴
关87/5兴
关54934-71-3兴
关87/5兴关55/11兴
关55255-85-1兴
关87/5兴关55/11兴
关142-77-8兴
关87/5兴
关112-86-7兴
关87/5兴
关506-33-2兴
关87/5兴
关123-79-5兴
关87/5兴
关141-19-5兴
关87/5兴关48/10兴
关1599-67-3兴
关99/16兴
关6812-38-0兴
关99/16兴
关71/28兴
关123-95-5兴
关87/5兴关49/9兴
关18281-05-5兴
关87/5兴
关6064-90-0兴
关87/5兴关63/16兴
关112-85-6兴
关87/5兴
关629-97-0兴
关02/44兴
关97/17兴
关95/21兴
关94/14兴
关94/2兴
关91/9兴
关88/12兴
关87/5兴关66/8兴
关1560-82-3兴
关87/5兴
关6418-47-9兴
关87/5兴关99/16兴
关59/15兴
关25117-29-7兴
关87/5兴关99/16兴
关59/15兴
关25117-37-7兴
关87/5兴关99/16兴
关75163-98-3兴
ENTHALPIES OF VAPORIZATION
799
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C22H46
C22H46
C22H46O
C22H46S
C23H24O6
C23H26O6
C23H40
C23H42O3
C23H44O2
C23H45NO3
C23H46
C23H46
C23H46
C23H46O2
C23H46O3
C23H48
C23H48
C23H48
C23H48
C23H48
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共471– 603兲
77.5
共486兲
A
2,4,6-trimethylnonadecane
共470–587兲
77.3
共485兲
A
共305兲
A
共351兲
A, ME
共452兲
EST
关87/5兴关99/16兴
关59/15兴
关102886-19-1兴
关87/5兴关99/16兴
关59/15兴
关71005-15-7兴
关87/5兴
关661-19-8兴
关87/5兴关65/15兴
关7773-83-3兴
关99/16兴
GS
关95/8兴
GS
关95/8兴
关14752-75-1兴
关99/16兴
关5420-17-7兴
关87/5兴
关1120-34-9兴
关97/28兴
关93/9兴
Compound
共Temperature range/K兲
8-heptylpentadecane
共298 –313兲
107.7
1-docosanol
共344 – 459兲
115.3
1-docosanethiol
共437– 680兲
107.7
tris共ethoxycarbonyl兲-9-fluorenylmethane
共359–393兲
107.5⫾0.7
1,1,1-tris共ethoxycarbonyl兲-2,2-diphenylethane
共344 –394兲
109.3⫾1.0
heptadecylbenzene
共414 – 664兲
98.5
tetrahydrofurfuryl oleate
共353–398兲
98.7
methyl erucate
共463–523兲
123.8
共453–543兲
93.5
2-lauryloxy-N,N-dibutylpropionamide
共443– 458兲
90.6
9-cyclohexylheptadecane
共456 – 492兲
83.9
hexadecylcyclohexane
共414 – 664兲
97.6
1-tricosene
共409– 652兲
98.5
methyl docosanoate 共methyl behenate兲
共463–523兲
126.1
共453–543兲
81.0
共467–539兲
98.2
decyl 3-decyloxypropionate
共453–523兲
90.2
9-hexylheptadecane
共450– 486兲
82.6
2-methyldocosane
共495– 652兲
79.7
4-methyldocosane
共493– 643兲
76.3
5-methyldocosane
共492– 644兲
共368兲
A
共298兲
共498兲
GC
GC
共450兲
A
共471兲
A
共429兲
共424兲
共298兲
共498兲
共482兲
GC
共468兲
A
共465兲
A
共510兲
A
共508兲
A
75.6
共507兲
A
118.7⫾0.1
119.7⫾2.3
120.5⫾2.0
123⫾1
92.0
110.4
94.0
共298兲
共298兲
共298兲
共393兲
共385兲
共329兲
共455兲
GS
CGC
CGC
TE
TE, ME, GS
A
A, EST
110.1
共459兲
EST
148.0⫾0.5
104.2
共298兲
共398兲
CGC
GC
140.0
77.5
118.0
共298兲
共515兲
共469兲
CGC
A
A
A
tricosane
C24H12
共370– 416兲
共370– 490兲
共314 –353兲
共440– 653兲
1-tricosanethiol
共444 – 690兲
coronene
C24H18
共323– 473兲
1,3,5-triphenylbenzene
C24H20O6
共500–735兲
共454 –500兲
glycerol tribenzoate
C23H48S
共429兲
CAS registry number
Reference
关87/5兴
关55124-77-1兴
关87/5兴
关19781-73-8兴
关99/16兴
关18835-32-0兴
关99/16兴
关929-77-1兴
关97/28兴
关93/9兴
关87/5兴关63/16兴
关87/5兴
关55124-79-3兴
关87/5兴
关1560-81-2兴
关87/5兴
关25117-30-0兴
关87/5兴关99/16兴
关59/15兴
关25163-52-4兴
关87/5兴关99/16兴
关59/15兴
关638-67-5兴
关01/1兴
关00/9兴
关91/17兴
关94/2兴
关91/9兴
关87/5兴
关87/5兴关66/8兴
关66375-01-7兴
关99/16兴
关191-07-1兴
关02/44兴
关02/18兴
关612-71-5兴
关98/11兴
关87/5兴
关87/5兴关74/29兴
关614-33-5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
800
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C24H27NO4
C24H30O4
C24H38O4
C24H38O4
C24H38O4
C24H38O4
C24H42
C24H42
C24H42O6
C24H42O11
C24H42O11
C24H44
C24H44
C24H44O6
C24H44O6
C24H44O6
C24H46O4
C24H48
C24H48
C24H48O2
C24H48O2
C24H49Cl
C24H50
C24H50
C24H50
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共423– 476兲
123.5
共438兲
bis关N,N-共2-hydroxy-3-phenoxy兲propyl兴phenylamine
共388 – 423兲
131.0
共403兲
dibenzyl sebacate
共368 –550兲
114.3
共383兲
共405– 463兲
112.2
共420兲
共373– 432兲
121
共388兲
bis共2-ethylhexyl兲phthalate
共373– 660兲
102.5
共388兲
共385– 440兲
110.7
共390兲
bis共1-methylheptyl兲phthalate
共393– 435兲
93.1
共408兲
bis共6-methylheptyl兲phthalate
共383– 490兲
92.4
共398兲
dioctyl phthalate
共423–523兲
99.5
共438兲
共383– 433兲
107.6
共398兲
hexapropylbenzene
共458 – 606兲
68.4
共473兲
octadecylbenzene
共423– 675兲
101.0
共438兲
trans trihexyl aconitate
共423–512兲
98.2
共438兲
di关1-共2-ethylbutyloxycarbonyl兲ethyl兴 diethylene glycol dicarboxylate
共448 –538兲
110.1
共463兲
di关1-共2-hexyloxycarbonyl兲ethyl兴 diethylene glycol dicarboxylate
共443–548兲
111.0
共458兲
9-decyltetradecahydroanthracene
共501–536兲
103.2
共516兲
9-decyltetradecahydrophenanthrene
共502–542兲
92.0
共517兲
O-acetylricinoleic acid, butyl ester
共378 – 423兲
105.2
共393兲
trihexyl 1,2,3-propanetricarboxylate
共422–526兲
98.1
共437兲
glycerol triheptanoate
共401– 452兲
84.4
共416兲
bis共3,5,5-trimethylhexyl兲adipate
共353– 413兲
107.6
共368兲
octadecylcyclohexane
共422– 675兲
100.3
共437兲
1-tetracosene
共418 – 663兲
101.0
共433兲
ethyl docosanoate
共327–344兲
127.5
共335兲
methyl tricosanoate
共473–528兲
99.8
共488兲
1-chlorotetracosane
共543–774兲
72.4
共558兲
2-methyltricosane
共450– 664兲
89.3
共465兲
5-methyltricosane
共503– 653兲
79.6
共518兲
Method
A
关87/5兴关49/6兴
关3088-05-9兴
关87/5兴
关140-24-9兴
关87/5兴
关49/9兴
关39/3兴
关117-81-7兴
关87/5兴
关49/9兴
关131-15-7兴
关87/5兴
关131-20-4兴
关87/5兴
关117-84-0兴
关87/5兴
关49/9兴
关2456-68-0兴
关87/5兴关37/8兴
关4445-07-2兴
关99/16兴
关64617-30-7兴
关87/5兴
A
关87/5兴
A
关87/5兴
A
关87/5兴
A
关87/5兴
关140-04-5兴
关87/5兴
关38094-13-2兴
关87/5兴
A, T
A
A
T
T
A
T
A
A
A
T
A
A
A
A, ME
A, ME
A, EST
A
A
A
tetracosane
共453–588兲
共386 – 425兲
共382–523兲
共451– 497兲
共373– 463兲
共498 –573兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
126.8⫾0.4
125.7⫾1.6
126.2⫾2.3
92.6
126⫾2
95.2
86.2⫾4.6
111.2
86.6
共298兲
共298兲
共298兲
共468兲
共405兲
共397兲
共474兲
共388兲
共513兲
CAS registry number
Reference
CGC
CGC
CGC
TE
TE, ME, GS
GS
A, EST
关01/10兴
关20270-50-2兴
关87/5兴关48/10兴
关4445-06-1兴
关99/16兴
关10192-32-2兴
关99/16兴
关5908-87-2兴
关87/5兴关67/12兴
关2433-97-8兴
关87/5兴关63/16兴
关6422-18-0兴
关87/5兴关70/14兴
关1928-30-9兴
关87/5兴
关22331-09-5兴
关87/5兴关99/16兴
关59/15兴
关646-31-1兴
关02/44兴
关00/9兴
关97/17兴
关94/14兴
关94/2兴
关91/9兴
关90/14兴
关88/12兴
关87/5兴关66/8兴
ENTHALPIES OF VAPORIZATION
801
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C24H50
C24H50S
C24H51N
C25H26
C25H28
C25H34O3
C25H36
C25H38
C25H40
C25H40
C25H42
C25H42
C25H44
C25H44
C25H44
C25H44
C25H44
C25H44
C25H44
C25H46
C25H46
C25H46
C25H46
C25H48
C25H48
C25H48
C25H48
C25H48O4
C25H50
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
12-methyltricosane
共435– 454兲
84.5
1-tetracosanethiol
共451–700兲
112.2
trioctylamine
共415–536兲
110.4⫾1.5
共505–702兲
70.6
3-phenylethyl-1,5-diphenyl-2-pentene
共469–541兲
86.8
3-phenylethyl-1,5-diphenylpentane
共498 –542兲
87.3
2-hydroxy-4-dodecyloxybenzophenone
共413– 453兲
115.5
1-phenyl-3-phenethylundecane
共456 –521兲
91.9
1-pentadecylnaphthalene
共474 –524兲
98.1
共474 –540兲
96.7
1-cyclohexyl-6-cyclopentyl-3-phenethylhexane
共486 –525兲
87.7
1,7-dicyclopentyl-4-共2-phenethyl兲heptane
共487–525兲
92.0
1-hexadecylindane
共495–536兲
87.0
5-pentadecyl-1,2,3,4-tetrahydronaphthalene
共471–534兲
99.4
nonadecylbenzene
共431– 686兲
103.6
1,5-dicyclohexyl-3-共2-cyclohexylethyl兲-2-pentene
共485–524兲
88.0
1,7-dicyclopentyl-4-共3-cyclopentylpropyl兲-3-heptene
共483–522兲
89.0
3-octyl-1-phenylundecane
共476 –513兲
89.4
9-共2-phenylethyl兲heptadecane
共448 –513兲
88.3
9-共4-tolyl兲octadecane
共472–507兲
92.0
6-octyl共hexylhydrobenz关de兴anthracene兲
共467–534兲
93.8
1-cyclohexyl-3-共cyclohexylethyl兲-6-cyclopentylhexane
共487–524兲
91.4
4-共2-cyclohexylethyl兲-1,7-dicyclopentylheptane
共471–524兲
88.8
1,5-dicyclohexyl-3-共2-cyclohexylethyl兲pentane
共318 – 418兲
107.6
共488 –528兲
86.2
1,7-dicyclopentyl-4-共3-cyclopentylpropyl兲heptane
共457–525兲
87.6
共486 –525兲
88.9
1-cyclohexyl-3-共2-cyclohexylethyl兲undecane
共480–516兲
95.2
1-cyclopentyl-4-共3-cyclopentylpropyl兲dodecane
共480–518兲
88.5
1-hexyldecylhexahydroindane
共492–532兲
87.6
1-pentadecyldecahydronaphthalene
共464 –529兲
93.4
dioctyl nonanedioate
共393–523兲
104.3
nonadecylcyclohexane
Mean temperature
(T m /K)
Method
共445兲
GC
共466兲
EST
共298兲
共520兲
EB
A
共484兲
共513兲
A
共433兲
ME
共471兲
A
共489兲
共489兲
A
A
共501兲
A
共502兲
A, MG
共510兲
A, MG
共486兲
A
共446兲
共500兲
A, MG
共498兲
A, MG
共491兲
A
共463兲
A, MG
共487兲
A, MG
共482兲
共502兲
A
共486兲
A
共333兲
共503兲
A
A
共472兲
共501兲
A
A, MG
共495兲
A, MG
共495兲
A, MG
共507兲
A, MG
共479兲
A, MG
共408兲
A
CAS registry number
Reference
关22331-52-8兴
关82/14兴关99/16兴
关16331-24-1兴
关99/16兴
关1116-76-3兴
关96/4兴
关87/5兴
关55334-57-1兴
关99/16兴
关66374-88-7兴
关87/5兴关99/16兴
关84/1兴
关7225-70-9兴
关87/5兴关99/16兴
关55191-63-4兴
关87/5兴
关87/5兴
关55334-30-0兴
关87/5兴关99/16兴
关55334-31-1兴
关87/5兴关55/11兴
关99/16兴
关334-29-2兴
关87/5兴关55/11兴
关99/16兴
关66374-91-2兴
关87/5兴关99/16兴
关29136-19-4兴
关99/16兴
关66374-92-3兴
关87/5兴关55/11兴
关66374-93-4兴
关87/5兴关55/11兴
关5637-96-7兴
关87/5兴
关5637-96-7兴
关87/5兴关55/11兴
关4445-08-3兴
关87/5兴关55/11兴
关99/16兴
关7225-65-2兴
关99/16兴
关55401-70-2兴
关87/5兴
关87/5兴
关2090-16-6兴
关87/5兴关64/12兴
关87/5兴
关55429-35-1兴
关87/5兴
关87/5兴关55/11兴
关7225-69-6兴
关87/5兴关55/11兴
关7225-68-5兴
关87/5兴关55/11兴
关55401-73-5兴
关87/5兴关55/11兴
关66359-82-8兴
关87/5兴关55/11兴
关2064-80-4兴
关87/5兴
关22349-03-7兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
802
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C25H50
C25H50
C25H50
C25H50
C25H50O2
C25H50O2
C25H52
C25H52
C25H52
C25H52
C25H52
C25H52
C25H52S
C26H18
C26H18
C26H18N2 O4
C26H32
C26H34
C26H34
C26H38
C26H38
C26H40
C26H42
C26H42O4
C26H42O4
C26H46
C26H46
C26H46
Compound
共Temperature range/K兲
共430– 686兲
1-pentacosene
共426 – 674兲
9-共2-cyclohexylethyl兲heptadecane
共490–513兲
9-共3-cyclopentylpropyl兲heptadecane
共476 –514兲
9-octyl-8-heptadecene
共441–500兲
methyl tetracosanoate
共422– 452兲
共483–536兲
ethyl tricosanoate
共336 –359兲
9-octylheptadecane
共470–505兲
pentacosane
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
102.8
共445兲
103.7
共441兲
88.6
共495兲
A, MG
86.9
共491兲
A
92.3
共456兲
A
146.2
100.8
共437兲
共498兲
A
121.8
共347兲
A, ME
93.4
共485兲
A, MG
128.6⫾2.2
127.6⫾0.8
129.8⫾2.9
126⫾1
97.6
90.9⫾5.7
99.2
共298兲
共298兲
共298兲
共415兲
共405兲
共479兲
共472兲
GS
CGC
CGC
TE
TE, ME, GS
GS
A, EST
共444兲
GC
共397– 434兲
共390–531兲
共461– 498兲
共457– 675兲
12-ethyltricosane
共435– 454兲
84.6
2-methyltetracosane
共425– 670兲
104.6
5,5-bis共3,3⬘-dimethylbutyl兲-2,2,8,8-tetramethylnonane
91.9⫾1.8
7,7-dihexyltridecane
115.3⫾1.8
1-pentacosanethiol
共458 –709兲
114.2
9,10-diphenylanthracene
共323– 473兲
102.7
9,9⬘-bifluorenyl
共383– 408兲
95.7
disperse violet 31
共453–523兲
59.9
6-octyl-1,2,3,4-tetrahydronaphthacene
共503–574兲
103.2
9-dodecylanthracene
共495–566兲
99.4
9-dodecylphenathrene
共495–568兲
95.7
1,1-diphenyltetradecane
共467–530兲
98.2
1,1-di共4-tolyl兲dodecane
共466 –529兲
98.3
5-octyl-1,2,3,4,4a,5,7,8,9,10,12,12a-dodecahydronaphthacene
共479–549兲
91.9
1,1-bis共dodecahydroacenaphthylene-5-yl兲ethane
共482–541兲
110.9
bis共3,5,5-trimethylhexyl兲phthalate
共333–393兲
113.6
dinonyl phthalate
共333–393兲
108.9
1,4-didecylbenzene
共468 –536兲
95.2
1-phenyleicosane
共499–538兲
94.7
2-phenyleicosane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
共440兲
CAS registry number
Reference
关99/16兴
关16980-85-1兴
关99/16兴
关25446-35-9兴
关87/5兴关55/11兴
关5638-09-5兴
关87/5兴关99/16兴
关24306-18-1兴
关87/5兴关99/16兴
关2442-49-1兴
关01/10兴
关87/5兴
关18281-07-7兴
关87/5兴关67/12兴
关7225-64-1兴
关87/5兴关55/11兴
关629-99-2兴
关01/1兴
关00/9兴
关97/17兴
关94/2兴
关91/9兴
关90/14兴
关87/5兴关66/8兴
关79370-85-7兴
关82/14兴关99/16兴
关1560-78-7兴
关99/16兴
共298兲
CGC
关95/27兴
共298兲
CGC
共473兲
EST
共398兲
GC
B
关95/27兴
关66359-74-8兴
关99/16兴
关1499-10-1兴
关02/18兴
关1530-12-7兴
关94/4兴
共468兲
A
关87/5兴
共518兲
A
共510兲
A
共510兲
A
共482兲
A
共481兲
A
共494兲
A, MG
关87/5兴
关2883-70-7兴
关87/5兴
关3788-61-2兴
关87/5兴
关55268-63-8兴
关87/5兴
关55268-62-7兴
关87/5兴
关95258-25-6兴
关87/5兴关55/11兴
关99/16兴
共497兲
A, MG
共348兲
A
共348兲
A
共483兲
A
共514兲
A, MG
关87/5兴关55/11兴
关14103-61-8兴
关87/5兴
关84-76-4兴
关87/5兴
关2655-95-0兴
关87/5兴
关2398-68-7兴
关87/5兴关55/11兴
关2398-66-5兴
ENTHALPIES OF VAPORIZATION
803
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C26H46
C26H46
C26H46
C26H46
C26H46
C26H46
C26H48
C26H48
C26H50
C26H50
C26H50
C26H50
C26H50
C26H50O4
C26H50O4
C26H52
C26H52
C26H52
C26H52
C26H52
C26H52
C26H52
C26H52
C26H52
C26H52
C26H54
C26H54
C26H54
C26H54
C26H54
C26H54
C26H54
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共492–531兲
90.4
3-phenyleicosane
共489–526兲
92.1
4-phenyleicosane
共487–527兲
88.2
5-phenyleicosane
共485–521兲
94.3
7-phenyleicosane
共483–520兲
93.8
9-phenyleicosane
共483–520兲
91.9
8-共4-tolyl兲nonadecane
共482–517兲
94.5
9-dodecyltetrahydroanthracene
共501–536兲
102.7
9-dodecyltetrahydrophenanthrene
共502–542兲
90.8
9-关␣-共cis-bicyclo关3.3.0兴octyl兲methyl兴heptadecane
共455–518兲
92.3
1,1-bis共4-methylcyclohexyl兲dodecane
共484 –520兲
93.5
1,1-dicyclohexyltetradecane
共493–529兲
97.7
1,1-dicyclopentylhexadecane
共471–525兲
113.1
2-hexadecylbicyclopentyl
共495–532兲
97.7
(dl) bis共2-ethylhexyl兲sebacate
共308 – 453兲
114.9
dioctyl sebacate
共413–523兲
107.1
1-cyclohexyleicosane
共499–538兲
94.2
2-cyclohexyleicosane
共494 –530兲
98.3
3-cyclohexyleicosane
共492–530兲
94.0
4-cyclohexyleicosane
共488 –524兲
98.3
5-cyclohexyleicosane
共488 –524兲
98.3
7-cyclohexyleicosane
共486 –523兲
93.6
9-cyclohexyleicosane
共486 –523兲
93.6
1-cyclopentylheneicosane
共498 –537兲
93.8
11-cyclopentylheneicosane
共486 –524兲
92.4
1-hexacosene
共434 – 684兲
106.1
5-butyldocosane
共482–518兲
94.0
7-butyldocosane
共480–514兲
97.2
9-butyldocosane
共479–516兲
91.9
11-butyldocosane
共480–516兲
93.3
5,14-dibutyloctadecane
共458 –508兲
89.3
6,11-dipentylhexadecane
共468 –504兲
88.9
3-ethyl-5-共2-ethylbutyl兲octadecane
Mean temperature
(T m /K)
Method
共507兲
A, MG
共504兲
A, MG
共502兲
A, MG
共500兲
A, MG
共498兲
A, MG
共498兲
A, MG
共497兲
A
共519兲
共522兲
共470兲
A
共499兲
A, MG
共508兲
A, MG
共486兲
A, MG
共510兲
A, MG
共323兲
A
共428兲
A
共514兲
A, MG
共509兲
A, MG
共507兲
A, MG
共503兲
A, MG
共503兲
A, MG
共501兲
A, MG
共501兲
A, MG
共513兲
A, MG
共501兲
A, MG
共449兲
共497兲
A, MG
共495兲
A, MG
共494兲
A, MG
共495兲
A, MG
共473兲
A, MG
共483兲
A, MG
CAS registry number
Reference
关87/5兴关55/11兴
关2400-02-4兴
关87/5兴关55/11兴
关2400-03-5兴
关87/5兴关55/11兴
关2400-04-6兴
关87/5兴关55/11兴
关2398-64-3兴
关87/5兴关55/11兴
关2398-65-4兴
关87/5兴关55/11兴
关55191-36-1兴
关87/5兴
关55401-75-7兴
关99/16兴
关55334-01-5兴
关99/16兴
关700004-11-1兴
关87/5兴关99/16兴
关55334-09-3兴
关87/5兴关55/11兴
关55334-08-2兴
关87/5兴关55/11兴
关55401-76-8兴
关87/5兴关55/11兴
关55334-11-7兴
关87/5兴关55/11兴
关122-62-3兴
关87/5兴
关2432-87-3兴
关87/5兴
关4443-55-4兴
关87/5兴关55/11兴
关4443-56-5兴
关87/5兴关55/11兴
关4443-57-6兴
关87/5兴关55/11兴
关4443-58-7兴
关87/5兴关55/11兴
关4443-59-8兴
关87/5兴关55/11兴
关4443-60-1兴
关87/5兴关55/11兴
关4443-61-2兴
关87/5兴关55/11兴
关6703-82-8兴
关87/5兴关55/11兴
关6703-81-7兴
关87/5兴关55/11兴
关18835-33-1兴
关99/16兴
关55282-16-1兴
关87/5兴关55/11兴
关55282-15-0兴
关87/5兴关55/11兴
关55282-14-9兴
关87/5兴关55/11兴
关13475-76-8兴
关87/5兴关55/11兴
关55282-13-8兴
关87/5兴关55/11兴
关15874-03-0兴
关87/5兴关55/11兴
关55282-12-7兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
804
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C26H54
C26H54
C26H54
C26H54
C26H54
C26H54
C26H54
C26H54
C26H54S
C27H19NO
C27H40
C27H46O
C27H48
C27H48
C27H48
C27H50
C27H50O6
C27H54
C27H54
C27H54
C27H54
C27H54
C27H56
C27H56
C27H56
C27H56
Compound
共Temperature range/K兲
共467–503兲
11-共1-ethylpropyl兲heneicosane
共474 –509兲
2-methylpentacosane
共433– 680兲
12-propyltricosane
共435– 454兲
3-ethyltetracosane
共490–529兲
hexacosane
共391– 437兲
共404 –546兲
共455–519兲
共466 – 685兲
共478 –530兲
7-hexyleicosane
共479–512兲
11-neopentylheneicosane
共476 –511兲
11-pentylheneicosane
共478 –512兲
1-hexacosanethiol
共465–718兲
2,5-bis共1,1⬘-biphenylyl兲oxazole
共595– 685兲
5-pentadecylacenaphthene
共500–568兲
cholesterol
共411– 447兲
5-␣-cholestane
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
88.4
共482兲
A, MG
93.5
共489兲
A, MG
107.2
共448兲
91.0
共445兲
90.0
共505兲
A
139.3⫾0.5
136.4⫾0.2
140.0⫾2.2
132⫾1
97.6
99.0⫾3.8
101.6
94.5
共298兲
共298兲
共298兲
共414兲
共419兲
共487兲
共481兲
共493兲
CGC
GS
CGC
TE
TE, ME, GS
GS
A, EST
A
101.1
共494兲
A, MG
93.0
共491兲
A, MG
96.3
共493兲
A, MG
116.2
共480兲
EST
109.7
共610兲
A
105.7
共515兲
A, MG
114.9
共426兲
A
共352兲
共496兲
A
108.4
共481–538兲
115.6
henicosylbenzene
共446 –705兲
108.4
11-phenylheneicosane
共491–529兲
93.5
5-pentadecyldodecahydroacenaphthalene
共486 –554兲
98.1
glycerol trioctanoate
共396 – 453兲
116.0
11-cyclohexylheneicosane
共485–529兲
107.0
11-共cyclopentylmethyl兲heneicosane
共492–529兲
94.4
henicosylcyclohexane
共445– 460兲
107.8
1-heptacosene
共441– 694兲
108.7
1-decyl-1-undecylcyclohexane
133.6⫾1.8
heptacosane
共401– 441兲
132⫾1
共508 –570兲
94.2
共401– 441兲
116.9⫾3.0
共473– 695兲
104.3
2-methylhexacosane
共441– 690兲
109.6
8-hexyl-8-pentylhexadecane
125.7⫾1.8
8,8-dipentylheptadecane
128.1⫾1.8
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共461兲
共506兲
A, MG
共501兲
A
共411兲
A, T
共500兲
A
共507兲
A
共460兲
共456兲
CAS registry number
Reference
关87/5兴关55/11兴
关55282-11-6兴
关87/5兴关55/11兴
关629-87-8兴
关99/16兴
关79370-84-6兴
关82/14兴关99/16兴
关55282-17-2兴
关87/5兴
关630-01-3兴
关02/44兴
关01/1兴
关97/17兴
关94/2兴
关91/9兴
关90/14兴
关87/5兴关66/8兴
关87/5兴
关55333-99-8兴
关87/5兴关55/11兴
关55282-10-5兴
关87/5兴关55/11兴
关14739-72-1兴
关87/5兴关55/11兴
关16331-25-2兴
关99/16兴
关2083-09-2兴
关87/5兴
关55334-13-9兴
关87/5兴关55/11兴
关57-88-5兴
关87/5兴
关481-21-0兴
关00/4兴
关87/5兴
关40775-09-5兴
关99/16兴
关6703-80-6兴
关87/5兴关55/11兴
关55282-69-4兴
关87/5兴
关538-23-8兴
关87/5兴关49/16兴
关6703-99-7兴
关87/5兴
关6703-79-3兴
关87/5兴
关26718-82-1兴
关99/16兴
关15306-27-1兴
关99/16兴
共298兲
CGC
共423兲
共523兲
共421兲
共488兲
TE
ME, TE, GS
TE
A, EST
关95/27兴
关593-49-7兴
关94/2兴
关91/9兴
关90/13兴
关87/5兴关66/8兴
关1561-02-0兴
关99/16兴
共298兲
CGC
关95/27兴
共298兲
CGC
关95/27兴
共456兲
ENTHALPIES OF VAPORIZATION
805
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
129.9⫾1.8
共298兲
CGC
关95/27兴
133.8⫾1.8
共298兲
1-heptacosanethiol
共471–727兲
118.3
共486兲
phenanthro关1,10,9,8-opqra兴perylene
共580– 630兲
180.5
共595兲
9,9⬘-dimethyl-9,9⬘-bifluorenyl
共368 – 403兲
94.6
1,7-diphenyl-4-共3-phenylpropyl兲-3-heptene
共488 –556兲
98.0
共503兲
1,7-diphenyl-4-共3-phenylpropyl兲heptane
共490–557兲
100.3
共505兲
ergosterol
共421– 454兲
118.7
共436兲
diisodecyl phthalate
共371– 496兲
79.3
共386兲
docosylbenzene
共453–715兲
110.8
共468兲
2-decyl-1-phenyldodecane
共497–532兲
102.5
共512兲
di关1-共2-ethylhexyl兲oxycarbonyl兴ethyl diethylene glycol dicarboxylate
共463–553兲
116.6
共478兲
di关1-共octyloxycarbony兲ethyl兴 diethylene glycol dicarboxylate
共463–564兲
112.5
共478兲
1,7-dicyclohexyl-4-共3-cyclohexylpropyl兲heptane
共482–549兲
98.7
共497兲
1-cyclohexyl-2-共cyclohexylmethyl兲pentadecane
共501–536兲
105.4
共516兲
docosylcyclohexane
共452–715兲
110.0
共467兲
1-octacosene
共448 –703兲
111.0
共463兲
11-共cyclohexylmethyl兲heneicosane
共499–538兲
94.2
共514兲
2,2,4,10,12,12-hexamethyl-7-共3,5,5-trimethylhexyl兲-6-tridecene
共426 – 488兲
83.8
共441兲
2-methylheptacosane
共448 –700兲
111.9
共463兲
2,2,4,10,12,12-hexamethyl-7-共3,5,5-trimethylhexyl兲tridecane
共308 –393兲
98.5
共323兲
共429– 491兲
84.9
共444兲
7-hexyldocosane
共506 –531兲
100.7
共518兲
octacosane
150.8⫾0.5
共298兲
150.7⫾1.7
共298兲
152.4⫾2.9
共298兲
共483–588兲
100.5
共498兲
共407– 456兲
135⫾3
共431兲
共426 – 493兲
105.5
共441兲
共473–515兲
103.1⫾3.0
共494兲
共450–575兲
100.6
共500兲
共450–575兲
98.1
共560兲
共300–390兲
131.7
共315兲
共481–705兲
106.6
共496兲
9-octyleicosane
共460–530兲
106.8
共475兲
1-octacosanethiol
共477–736兲
120.2
共492兲
11-共2,5-dimethylphenyl兲-10-heneicosene
共471–534兲
99.2
共486兲
tricosylbenzene
CGC
关95/27兴
关66291-85-8兴
关99/16兴
关190-39-6兴
关87/5兴
Compound
共Temperature range/K兲
C27H56
10-hexyl-10-methyleicosane
C27H56
5-ethyl-5-methyltetracosane
C27H56S
C28H14
C28H22
C28H32
C28H34
C28H44O
C28H46O4
C28H50
C28H50
C28H50O11
C28H50O11
C28H52
C28H54
C28H56
C28H56
C28H56
C28H56
C28H58
C28H58
C28H58
C28H58
C28H58
C28H58S
C29H50
C29H52
EST
A
A
关94/4兴
关55282-03-6兴
关87/5兴关55/11兴
关55282-64-9兴
关87/5兴关55/11兴
关57-87-4兴
关87/5兴
关26761-40-0兴
关87/5兴
关5634-22-0兴
关99/16兴
关55334-72-0兴
关87/5兴
A
关87/5兴
A
关87/5兴
关55334-73-1兴
关87/5兴关55/11兴
关55255-74-8兴
关87/5兴关55/11兴
关61828-07-7兴
关99/16兴
关18835-34-2兴
关99/16兴
B
A, MG
A, MG
A
A
A, MG
A, MG
A, MG
A, MG
A
A, MG
A
CGC
CGC
CGC
TE
TE, ME, GS
GS
EB, IPM
EB, IPM
A
A, EST
A
EST
A, MG
关87/5兴关55/11兴
关55255-73-7兴
关87/5兴关55/11兴
关1561-00-8兴
关99/16兴
关3035-75-4兴
关87/5兴关64/12兴
关87/5兴关55/11兴
关55373-86-9兴
关87/5兴
关630-02-4兴
关02/44兴
关00/9兴
关97/17兴
关94/14兴
关94/2兴
关91/9兴
关90/14兴
关89/1兴
关89/1兴
关87/5兴
关87/5兴关66/8兴
关13475-77-9兴
关87/5兴
关16331-26-3兴
关99/16兴
关87/5兴关55/11兴
关61828-04-4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
806
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C29H52
C29H52
C29H58
C29H60
C29H60
C29H60S
C30H30
C30H34
C30H54
C30H54
C30H54
C30H54O6
C30H54O6
C30H60
C30H60
C30H62
C30H62
C30H62
C30H62
C30H62S
C30H63N
C31H34
C31H48
C31H52O3
C31H56
C31H56
C31H56
C31H60
C31H62
C31H62
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共459–724兲
113.2
1-nonacosene
共455–713兲
113.3
11-共2,5-dimethylphenyl兲heneicosane
共472–535兲
100.8
tricosylcyclohexane
共459–724兲
112.3
2-methyloctacosane
共455–709兲
114.2
nonacosane
共423– 457兲
137⫾3
共423– 456兲
137.1⫾3.0
共488 –714兲
109.0
1-nonacosanethiol
共483–744兲
122.0
1,1,6,6-tetraphenylhexane
共511–579兲
108.1
1,10-di共1-naphthyl兲decane
共540– 616兲
108.6
1,10-bis共decahydro-1-naphthyl兲decane
共520–583兲
119.7
1,1,6,6-tetracyclohexylhexane
共501–569兲
103.0
tetracosylbenzene
共466 –732兲
115.3
trans, tris共2-ethylhexyl兲 aconitate
共437–551兲
97.1
tris共2-ethylhexyl兲 1,2,3-propanetricarboxylate
共438 –551兲
97.9
tetracosylcyclohexane
共465–733兲
114.6
1-tricontene
共462–721兲
115.4
2,6,10,15,19,23-hexamethyltetracosane 共squalane兲
共363–513兲
116.2
9-octyldocosane
共518 –588兲
109.3
triacontane
164.5⫾0.4
共422– 487兲
143⫾2
共495–723兲
111.3
2-methylnonacosane
共461–718兲
116.8
1-triacontanethiol
共488 –751兲
124.0
tridecylamine
共545–759兲
76.8
1,1-di共1-naphthyl兲-1-undecene
共518 –588兲
109.3
1-共1-decylundec-1-enyl兲naphthalene
共499–567兲
105.1
␣-tocopherol acetate
共466 –524兲
60.1⫾1.3
1,1-bis共decahydro-1-naphthyl兲undecane
共525–561兲
110.5
pentacosylbenzene
共472–741兲
117.5
13-phenylpentacosane
共495–560兲
106.7
1-共1-decylundecyl兲decahydronaphthalene
共523–560兲
107.0
1-hentriacontene
共468 –730兲
117.7
pentacosylcyclohexane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共474兲
共470兲
共487兲
A, MG
共474兲
共470兲
共440兲
共439兲
共503兲
TE
TE
A, EST
共498兲
EST
共526兲
A, MG
共555兲
A, MG
共535兲
A, MG
共516兲
A
共481兲
共452兲
A
共453兲
A
共480兲
共477兲
共378兲
A
共533兲
A
共298兲
共454兲
共510兲
CGC
TE
A, EST
共476兲
共503兲
EST
共560兲
A
共533兲
A
共514兲
A, MG
共496兲
共540兲
A, MG
共487兲
共510兲
A, MG
共538兲
A, MG
共483兲
CAS registry number
Reference
关99/16兴
关18835-35-3兴
关99/16兴
关55373-91-6兴
关87/5兴关55/11兴
关61828-08-8兴
关99/16兴
关1560-98-1兴
关99/16兴
关630-03-5兴
关94/2兴
关90/13兴
关87/5兴关66/8兴
关66213-92-1兴
关99/16兴
关2819-41-2兴
关87/5兴关55/11兴
关40339-27-3兴
关87/5兴关55/11兴
关55268-64-9兴
关87/5兴关55/11兴
关55281-91-9兴
关87/5兴
关61828-05-5兴
关99/16兴
关52193-50-7兴
关87/5兴
关5400-99-7兴
关87/5兴
关61828-09-9兴
关99/16兴
关18435-53-5兴
关99/16兴
关111-01-3兴
关87/5兴
关55319-83-0兴
关87/5兴
关638-68-6兴
关00/9兴
关94/2兴
关87/5兴关66/8兴
关1560-75-4兴
关99/16兴
关66213-99-8兴
关99/16兴
关2869-34-3兴
关87/5兴
关56247-76-8兴
关87/5兴
关55319-81-8兴
关87/5兴关55/11兴
关58-95-7兴
关88/4兴
关55373-96-1兴
关87/5兴关55/11兴
关61828-06-6兴
关99/16兴
关6006-90-2兴
关87/5兴关55/11兴
关55320-00-8兴
关87/5兴关55/11兴
关18435-54-6兴
关99/16兴
关61828-10-2兴
ENTHALPIES OF VAPORIZATION
807
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C31H62
C31H64
C31H64
C31H64
C31H64S
C32H58
C32H64
C32H64
C32H66
C32H66
C32H66
C32H66
C32H66S
C33H54O6
C33H54O6
C33H60
C33H62O6
C33H66
C33H66
C33H68
C33H68
C33H68S
C34H62
C34H68
C34H68
C34H70
C34H70
C34H70
C34H70
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共472–741兲
13-cyclohexylpentaconsane
共495–560兲
2-methyltriacontane
共468 –726兲
11-decylheneicosane
共298 –313兲
hentriacontane
共433– 474兲
共503–732兲
1-hentriacontanethiol
共494 –759兲
hexacosylbenzene
共478 –749兲
1-dotriacontene
共474 –738兲
hexacosylcyclohexane
共478 –749兲
11-decyldocosane
共523–559兲
dotriacontane
共437– 477兲
共361–395兲
共510–741兲
9-octyltetracosane
共501–563兲
2-methylhentriacontane
共474 –735兲
1-dotriacontanethiol
共499–766兲
tri共2-ethylhexyl兲trimellitate
共331–371兲
triisooctyltrimellitate
共331–372兲
heptacosylbenzene
共484 –756兲
glycerol tricaprate
共437– 485兲
heptacosylcyclohexane
共484 –757兲
1-tritriacontene
共480–746兲
tritriacontane
共438 – 480兲
共517–749兲
2-methyldotriacontane
共480–743兲
1-tritriacontanethiol
共504 –773兲
octacosylbenzene
共490–764兲
octacosylcyclohexane
共490–764兲
1-tetratriacontene
共486 –754兲
11-decyltetracosane
共537–574兲
9-octylhexacosane
共537–575兲
tetratriacontane
共446 – 497兲
共372– 402兲
共523–756兲
2-methyltritriacontane
116.6
共487兲
106.7
共510兲
118.8
共483兲
110.9
共305兲
A, MG
146⫾2
113.8
共450兲
共518兲
TE
A, EST
125.7
共509兲
EST
119.6
共493兲
119.8
共489兲
118.6
共493兲
108.7
共538兲
A, MG
147⫾1
130.5
116.0
共456兲
共376兲
共535兲
TE
A
A, EST
114.8
共516兲
A, MG
120.9
共489兲
127.5
共514兲
EST
关99/16兴
关6697-15-0兴
关87/5兴关55/11兴
关1560-72-1兴
关99/16兴
关55320-06-4兴
关87/5兴关55/11兴
关630-04-6兴
关94/2兴
关87/5兴关66/8兴
关534-24-9兴
关99/16兴
关13024-80-1兴
关99/16兴
关18435-55-7兴
关99/16兴
关61828-11-3兴
关99/16兴
关55401-55-3兴
关87/5兴关55/11兴
关544-85-4兴
关94/2兴
关87/5兴
关87/5兴关66/8兴
关55401-54-2兴
关87/5兴关55/11兴
关1720-12-3兴
关99/16兴
关66256-05-1兴
关99/16兴
81.1
共346兲
ME
关00/11兴
79.0
共346兲
ME
121.5
共499兲
124.6
共452兲
120.6
共499兲
121.8
共495兲
148⫾1
118.0
共458兲
共532兲
122.9
共495兲
129.1
共519兲
123.4
共505兲
122.4
共505兲
123.7
共501兲
113.1
共552兲
A, MG
110.3
共552兲
A, MG
152⫾2
149.7
120.3
共471兲
共387兲
共538兲
TE
A
A, EST
关00/11兴
关61828-25-9兴
关99/16兴
关621-71-6兴
关87/5兴
关61828-12-4兴
关99/16兴
关61868-11-9兴
关99/16兴
关630-05-7兴
关94/2兴
关87/5兴关66/8兴
关1720-11-2兴
关99/16兴
关66214-20-8兴
关99/16兴
关61828-26-0兴
关99/16兴
关61828-13-5兴
关99/16兴
关61868-12-0兴
关99/16兴
关55429-84-0兴
关87/5兴关55/11兴
关55429-83-9兴
关87/5兴关55/11兴
关14167-59-0兴
关94/2兴
关87/5兴
关87/5兴关66/8兴
关66214-27-5兴
Method
A, MG
A
TE
A, EST
EST
CAS registry number
Reference
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
808
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C34H70S
C35H64
C35H64
C35H70
C35H70
C35H70
C35H72
C35H72
C35H72S
C36H60O6
C36H62O4
C36H66
C36H72
C36H72
C36H74
C36H74
C36H74
C36H74S
C36H75N
C37H68
C37H70O6
C37H74
C37H74
C37H76
C37H76
C37H76S
C38H70
C38H74O4
C38H76
C38H76
C38H78
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共486 –750兲
124.8
1-tetratriacontanethiol
共509–780兲
130.7
15-phenylnonacosane
共523–550兲
126.5
nonacosylbenzene
共495–771兲
125.4
nonacosylcyclohexane
共495–771兲
124.4
1-pentatriacontene
共492–761兲
125.5
15-cyclohexylnonacosane
共548 –581兲
129.0
pentatriacontane
共529–764兲
122.4
2-methyltetratriacontane
共491–758兲
126.9
1-pentatriacontanethiol
共514 –787兲
132.2
triisononanyltrimellitate
共334 –372兲
102.2
ditetradecyl phthalate
共416 – 465兲
126.0
triacontylbenzene
共501–778兲
127.0
1-hexatriacontene
共497–768兲
127.4
triacontylcyclohexane
共500–778兲
126.3
hexatriacontane
共452–516兲
157⫾2
共535–571兲
124.4
13-undecylpentacosane
共548 –580兲
132.9
2-methylpentatriacontane
共497–765兲
128.7
1-hexatriacontanethiol
共518 –793兲
134.0
tridodecylamine
共579– 807兲
82.1
hexatriacontylbenzene
共506 –785兲
128.8
1-caprylic-2-lauryl-3-myristic glycerol
共464 –526兲
131.7
hentriacontylcyclohexane
共505–785兲
128.1
1-heptatriacontene
共502–775兲
129.2
heptatriacontane
共471–511兲
155⫾2
共541–778兲
126.4
2-methylhexatriacontane
共502–772兲
130.5
1-heptatriacontanethiol
共523–799兲
135.3
dotriacontylbenzene
共511–791兲
130.4
ditetradecyl sebacate
共431– 483兲
135.5
dotriacontylcyclohexane
共510–792兲
129.8
1-octatriacontene
共507–782兲
131.0
octatriacontane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共501兲
共524兲
EST
共536兲
A, MG
共510兲
共510兲
共507兲
共563兲
A, MG
共544兲
A, EST
共506兲
共529兲
EST
共349兲
ME
共431兲
T
共516兲
共512兲
共515兲
共484兲
共550兲
TE
A, EST
共563兲
A, MG
共512兲
共533兲
EST
共594兲
A
共521兲
共479兲
A, T
共520兲
共517兲
共491兲
共556兲
TE
A, EST
共517兲
共538兲
EST
共526兲
共446兲
共525兲
共522兲
A, T
CAS registry number
Reference
关99/16兴
关66214-28-6兴
关99/16兴
关56247-97-3兴
关87/5兴关55/11兴
关61828-27-1兴
关99/16兴
关61828-14-6兴
关99/16兴
关61868-13-1兴
关99/16兴
关55521-27-2兴
关87/5兴关55/11兴
关630-07-9兴
关87/5兴关66/8兴
关14167-65-8兴
关99/16兴
关66576-86-1兴
关99/16兴
关00/11兴
关2915-60-8兴
关87/5兴关49/9兴
关50715-02-1兴
关99/16兴
关61868-14-2兴
关99/16兴
关61828-15-7兴
关99/16兴
关630-06-8兴
关94/2兴
关87/5兴关66/8兴
关55517-89-0兴
关87/5兴关55/11兴
关66576-73-6兴
关99/16兴
关66577-23-9兴
关99/16兴
关102-87-4兴
关87/5兴
关61828-28-2兴
关99/16兴
关30283-10-4兴
关87/5兴关49/16兴
关61828-16-8兴
关99/16兴
关61868-15-3兴
关99/16兴
关7194-84-5兴
关94/2兴
关87/5兴关66/8兴
关66577-06-8兴
关99/16兴
关66577-07-9兴
关99/16兴
关61828-29-3兴
关99/16兴
关26719-47-1兴
关87/5兴关49/9兴
关61828-17-9兴
关99/16兴
关61868-16-4兴
关99/16兴
关7194-85-6兴
ENTHALPIES OF VAPORIZATION
809
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C38H78
C38H78S
C39H72
C39H72
C39H74O6
C39H78
C39H78
C39H78
C39H80
C39H80
C39H80S
C40H74
C40H80
C40H80
C40H82
C40H82
C40H82S
C41H76
C41H82
C41H82
C41H84
C41H84
C41H84S
C42H78
C42H84
C42H84
C42H86
C42H86
C42H86
C42H86S
C42H87N
Compound
共Temperature range/K兲
共471–511兲
共546 –785兲
2-methylheptatriacontane
共507–779兲
1-octatriacontanethiol
共527– 805兲
17-phenyltritriacontane
共544 –571兲
tritriacontylbenzene
共516 –798兲
glycerol trilaurate
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
160⫾2
128.5
共491兲
共561兲
TE
A, EST
132.2
共522兲
136.7
共542兲
EST
147.1
共557兲
A, MG
132.0
共531兲
221.1
共458 –520兲
137.6
共473兲
1-nontriacontene
共512–788兲
132.5
共527兲
triatriacontylcyclohexane
共515–798兲
131.4
共530兲
17-cyclohexyltritricontane
共570– 602兲
131.9
共585兲
nonatriacontane
共552–791兲
130.3
共567兲
2-methyloctatriacontane
共512–785兲
133.8
共527兲
1-nonatriacontanethiol
共531– 811兲
138.1
共546兲
tetratriacontylbenzene
共520– 804兲
133.8
共535兲
1-tetracontene
共517–794兲
134.0
共532兲
tetratriacontylcyclohexane
共520– 804兲
132.9
共535兲
tetracontane
共557–798兲
132.2
共572兲
2-methylnonatricontane
共517–791兲
135.3
共532兲
1-tetracontanethiol
共535– 817兲
139.6
共550兲
pentatriacontylbenzene
共525– 810兲
135.2
共540兲
1-hentetracontene
共521– 800兲
135.8
共536兲
pentatriacontylcyclohexane
共524 – 810兲
134.5
共539兲
hentetracontane
共562– 804兲
134.1
共577兲
2-methyltetracontane
共521–797兲
137.1
共536兲
1-hentetracontanethiol
共539– 822兲
140.8
共554兲
hexatriacontylbenzene
共529– 815兲
129.0
共544兲
1-dotetracontene
共526 – 806兲
137.1
共541兲
hexatriactonylcyclohexane
共529– 816兲
135.8
共544兲
dotetracontane
共567– 810兲
136.0
共582兲
2-methylhentetracontane
共526 – 803兲
138.5
共541兲
2,2,4,15,17,17-hexamethyl-7,12-bis共3,5,5-trimethylhexyl兲octadecane
共512–575兲
118.3
共527兲
1-dotetracontanethiol
共543– 828兲
142.1
共558兲
tritetradecylamine
TGA
A, T
A, MG
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
A, MG
EST
CAS registry number
Reference
关94/2兴
关87/5兴关66/8兴
关66576-92-9兴
关99/16兴
关66576-93-0兴
关99/16兴
关55517-74-3兴
关87/5兴关55/11兴
关61828-30-6兴
关99/16兴
关538-24-9兴
关02/33兴
关87/5兴关49/16兴
关61868-17-5兴
关99/16兴
关61828-18-0兴
关99/16兴
关55517-75-4兴
关87/5兴关55/11兴
关7194-86-7兴
关87/5兴关66/8兴
关66576-59-8兴
关99/16兴
关66576-60-1兴
关99/16兴
关61828-31-7兴
关99/16兴
关61868-18-6兴
关99/16兴
关61828-19-1兴
关99/16兴
关4181-95-7兴
关87/5兴关66/8兴
关66576-48-5兴
关99/16兴
关66576-49-6兴
关99/16兴
关61828-32-8兴
关99/16兴
关66576-37-2兴
关99/16兴
关61828-20-4兴
关99/16兴
关7194-87-8兴
关87/5兴关66/8兴
关66575-38-3兴
关99/16兴
关66576-39-4兴
关99/16兴
关61828-33-9兴
关99/16兴
关21807-60-3兴
关99/16兴
关61828-21-5兴
关99/16兴
关7098-20-6兴
关87/5兴关66/8兴
关66576-40-7兴
关99/16兴
关55470-97-8兴
关87/5兴关55/11兴
关66576-41-8兴
关99/16兴
关27911-72-4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
810
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C43H80
C43H86
C43H86
C43H88
C43H88
C43H88S
C44H82
C44H88
C44H88
C44H90
C44H90
C44H90S
C45H84
C45H86O6
C45H86O6
C45H86O6
C45H90
C45H90
C45H92
C45H92
C45H92S
C46H86
C46H92
C46H92
C46H94
C46H94
C46H94S
C47H88
C47H90O6
C47H90O6
C47H94
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共609– 848兲
86.6
heptatriacontylbenzene
共533– 821兲
138.3
heptatriacontylcyclohexane
共533– 821兲
137.4
1-tritetracontene
共530– 812兲
138.7
tritetracontane
共572– 820兲
137.7
2-methyldotetracontane
共530– 809兲
140.0
1-tritetracontanethiol
共547– 833兲
143.2
octatriacontylbenzene
共537– 826兲
139.7
octatriacontylcyclohexane
共537– 827兲
138.7
1-tetratetracontene
共534 – 818兲
140.1
tetratetracontane
共577– 821兲
139.3
2-methyltritetracontane
共534 – 815兲
141.5
1-tetratetracontanethiol
共551– 838兲
144.1
nontriacontylbenzene
共541– 832兲
141.0
(dl) 1-lauric-2-myristic-3-plamitic glycerol
共491–551兲
147.8
(dl) 1-myristic-2-capric-3-stearic glycerol
共490–551兲
148.4
glycerol trimyristate
199.1
共488 –551兲
147.8
nonatriacontylcyclohexane
共541– 832兲
140.1
1-pentatetracontene
共538 – 823兲
141.5
pentatetracontane
共582– 827兲
141.0
2-methyltetratetracontane
共538 – 820兲
142.9
1-pentatetracontanethiol
共554 – 843兲
145.6
tetracontylbenzene
共545– 837兲
142.3
1-hexatetracontene
共542– 828兲
142.8
tetracontylcyclohexane
共545– 837兲
141.3
hexatetracontane
共586 – 832兲
142.8
2-methylpentatetracontane
共542– 826兲
144.2
1-hexatetracontanethiol
共557– 847兲
146.7
hentetracontylbenzene
共549– 842兲
143.5
(dl) 1-myristic-2-lauric-3-stearic glycerol
共493–558兲
150.5
(dl) 1-palmitic-2-capric-3-stearic glycerol
共507–559兲
154.8
hentetracontylcyclohexane
共548 – 842兲
142.8
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
Method
共624兲
A
共548兲
共548兲
共545兲
共587兲
A, EST
共545兲
共562兲
EST
共552兲
共552兲
共549兲
共592兲
A, EST
共549兲
共566兲
EST
共556兲
共506兲
A, T
共505兲
A, T
共503兲
TGA
A, T
共556兲
共553兲
共597兲
A, EST
共553兲
共569兲
EST
共560兲
共557兲
共560兲
共601兲
A, EST
共557兲
共572兲
EST
共564兲
CAS registry number
Reference
关87/5兴
关66576-74-7兴
关99/16兴
关66576-75-8兴
关99/16兴
关66576-76-9兴
关99/16兴
关66576-76-9兴
关87/5兴关66/8兴
关66576-77-0兴
关99/16兴
关66576-78-1兴
关99/16兴
关66576-79-2兴
关99/16兴
关66576-80-5兴
关99/16兴
关66576-81-6兴
关99/16兴
关7098-22-8兴
关87/5兴关66/8兴
关66576-82-7兴
关99/16兴
关66576-83-8兴
关99/16兴
关66576-61-2兴
关99/16兴
关60138-25-2兴
关87/5兴关49/16兴
关87/5兴关49/16兴
关555-45-3兴
关02/33兴
关87/5兴关49/16兴
关66576-62-3兴
关99/16兴
关66576-63-4兴
关99/16兴
关7098-23-9兴
关87/5兴关66/8兴
关66576-64-5兴
关99/16兴
关66576-65-6兴
关99/16兴
关66576-67-8兴
关99/16兴
关66576-68-9兴
关99/16兴
关66576-69-0兴
关99/16兴
关7098-24-0兴
关87/5兴关66/8兴
关66564-10-1兴
关99/16兴
关66564-11-2兴
关99/16兴
关66564-12-3兴
关99/16兴
共508兲
A, T
关87/5兴关49/16兴
共522兲
A, T
关87/5兴关49/16兴
关66564-13-4兴
关99/16兴
共563兲
ENTHALPIES OF VAPORIZATION
811
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C47H94
C47H96
C47H96
C47H96S
C48H90
C48H96
C48H96
C48H98
C48H98
C48H98S
C49H92
C49H94O6
C49H98
C49H98
C49H100
C49H100
C49H100S
C50H94
C50H100
C50H100
C50H102
C50H102
C50H102S
C51H96
C51H98O6
C51H98O6
C51H102
C51H102
C51H104
C51H104
C51H104S
C52H98
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
1-heptatetracontene
共546 – 833兲
143.9
heptatetracontane
共591– 837兲
144.2
2-methylhexatetracontane
共546 – 831兲
145.3
1-heptatetracontanethiol
共561– 852兲
147.6
dotetracontylbenzene
共552– 846兲
144.9
dotetracontylcyclohexane
共552– 847兲
143.9
1-octatetracontene
共549– 838兲
145.4
octatetracontane
共595– 843兲
145.9
2-methylheptatetracontane
共550– 836兲
146.5
1-octatetracontanethiol
共564 – 856兲
148.7
tritetracontylbenzene
共556 – 851兲
145.9
(dl) 1-palmitic-2-lauryl-3-stearic glycerol
共506 –567兲
160.0
1-nonatetracontene
共553– 843兲
146.4
tritetracontylcyclohexane
共556 – 852兲
144.9
nonatetracontane
共599– 847兲
147.5
2-methyloctatetracontane
共553– 840兲
147.9
1-nonatetracontanethiol
共567– 861兲
149.7
tetratetracontylbenzene
共559– 856兲
147.1
1-pentacontene
共556 – 848兲
147.8
tetratetracontylcyclohexane
共559– 856兲
146.2
pentacontane
共603– 852兲
149.0
2-methylnonatetracontane
共557– 845兲
148.8
1-pentacontanethiol
共570– 865兲
150.7
pentatetracontylbenzene
共562– 860兲
148.3
1-myristic-2-palmitic-3-stearic glycerol
共508 –572兲
157.9
glycerol tripalmitate
474.3
共506 –572兲
160.8
1-henpentacontene
共560– 852兲
148.6
pentatetracontylcyclohexane
共562– 861兲
147.4
henpentacontane
共607– 857兲
150.6
2-methylpentacontane
共560– 850兲
150.0
1-henpentacontanethiol
共573– 869兲
151.6
hexatetracontylbenzene
Mean temperature
(T m /K)
Method
共561兲
共606兲
A, EST
共561兲
共576兲
EST
共567兲
共567兲
共564兲
共610兲
A, EST
共565兲
共579兲
EST
共571兲
共521兲
A, T
共568兲
共571兲
共614兲
A, EST
共568兲
共582兲
EST
共574兲
共571兲
共574兲
共618兲
A, EST
共572兲
共585兲
EST
共577兲
共523兲
A, T
共521兲
TGA
A, T
共575兲
共577兲
共622兲
A, EST
共575兲
共588兲
EST
CAS registry number
Reference
关66576-01-0兴
关99/16兴
关7098-25-1兴
关87/5兴关66/8兴
关66576-02-1兴
关99/16兴
关66576-03-2兴
关99/16兴
关66576-04-3兴
关99/16兴
关66576-05-4兴
关99/16兴
关66576-06-5兴
关99/16兴
关7098-26-2兴
关87/5兴关66/8兴
关66576-07-6兴
关99/16兴
关66576-08-7兴
关99/16兴
关66576-09-8兴
关99/16兴
关87/5兴关49/16兴
关66576-19-1兴
关99/16兴
关66576-11-2兴
关99/16兴
关7098-27-3兴
关87/5兴关66/8兴
关66576-12-3兴
关99/16兴
关66576-13-4兴
关99/16兴
关66576-14-5兴
关99/16兴
关63911-02-4兴
关99/16兴
关66576-15-6兴
关99/16兴
关6596-40-3兴
关87/5兴关66/8兴
关66576-16-7兴
关99/16兴
关66576-17-8兴
关99/16兴
关66576-18-9兴
关99/16兴
关60138-20-7兴
关87/5兴关49/16兴
关555-44-2兴
关02/33兴
关87/5兴关49/16兴
关66576-19-0兴
关99/16兴
关66576-20-3兴
关99/16兴
关7667-76-7兴
关87/5兴关66/8兴
关66575-81-3兴
关99/16兴
关66575-82-4兴
关99/16兴
关66575-84-6兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
812
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C52H104
C52H104
C52H106
C52H106
C52H106S
C53H100
C53H106
C53H106
C53H108
C53H108
C53H108S
C54H102
C54H108
C54H110
C54H110
C54H110
C54H110S
C55H104
C55H110
C55H110
C55H112
C55H112
C55H112S
C56H106
C56H108
C56H108
C56H114
C56H114
C56H114S
C57H108
C57H108O6
C57H108O6
Compound
共Temperature range/K兲
共566 – 864兲
1-dopentacontene
共563– 857兲
hexatetracontylcyclohexane
共565– 865兲
dopentacontane
共611– 861兲
2-methylhenpentacontane
共563– 854兲
1-dopentacontanethiol
共575– 873兲
heptatetracontylbenzene
共569– 868兲
heptatetracontylcyclohexane
共568 – 869兲
1-tripentacontene
共566 – 861兲
tripentacontane
共615– 866兲
2-methyldopentacontane
共566 – 858兲
1-tripentacontanethiol
共578 – 877兲
octatetracontylbenzene
共572– 873兲
octatetracontylcyclohexane
共571– 873兲
1-tetrapentacontene
共569– 865兲
tetrapentacontane
共618 – 870兲
2-methyltripentacontane
共569– 863兲
1-tetrapentacontanethiol
共581– 881兲
nontetracontylbenzene
共575– 877兲
nonatetracontylcyclohexane
共574 – 877兲
1-pentapentacontene
共572– 869兲
pentapentacontane
共622– 874兲
2-methyltetrapentacontane
共572– 867兲
1-pentapentacontanethiol
共584 – 885兲
pentacontylbenzene
共577– 880兲
1-hexapentacontene
共575– 873兲
pentacontylcyclohexane
共577– 881兲
hexapentacontane
共625– 878兲
2-methylpentapentacontane
共575– 871兲
1-hexapentacontanethiol
共586 – 888兲
henpentacontylbenzene
共580– 884兲
1,3-distearic-2-oleic glycerol
共523–593兲
glycerol tristearate
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
149.1
共581兲
149.8
共578兲
148.5
共580兲
152.0
共626兲
151.2
共578兲
152.6
共590兲
150.1
共584兲
149.6
共583兲
150.9
共581兲
153.4
共630兲
152.3
共581兲
153.7
共593兲
151.1
共587兲
150.6
共586兲
151.9
共584兲
155.0
共633兲
153.4
共584兲
154.4
共596兲
152.1
共590兲
151.6
共589兲
152.9
共587兲
156.3
共637兲
154.3
共587兲
155.0
共599兲
153.2
共592兲
154.5
共588兲
152.4
共592兲
157.8
共640兲
155.9
共588兲
156.0
共601兲
154.1
共595兲
165.8
共538兲
Method
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, T
CAS registry number
Reference
关99/16兴
关66575-85-7兴
关99/16兴
关66575-86-8兴
关99/16兴
关7719-79-1兴
关87/5兴关66/8兴
关66575-87-9兴
关99/16兴
关66575-88-0兴
关99/16兴
关66575-89-1兴
关99/16兴
关66563-49-3兴
关99/16兴
关66577-50-2兴
关99/16兴
关7719-80-4兴
关87/5兴关66/8兴
关66575-90-4兴
关99/16兴
关66575-91-5兴
关99/16兴
关66575-92-6兴
关99/16兴
关66575-93-7兴
关99/16兴
关66575-94-8兴
关99/16兴
关5856-66-6兴
关87/5兴关66/8兴
关66575-95-9兴
关99/16兴
关66575-96-0兴
关99/16兴
关66575-98-2兴
关99/16兴
关66575-99-3兴
关99/16兴
关66576-00-9兴
关99/16兴
关5846-40-2兴
关87/5兴关66/8兴
关66575-60-8兴
关99/16兴
关66575-61-9兴
关99/16兴
关66575-62-0兴
关99/16兴
关66575-63-1兴
关99/16兴
关66575-64-2兴
关99/16兴
关7719-82-6兴
关87/5兴关66/8兴
关66575-65-3兴
关99/16兴
关66575-66-4兴
关99/16兴
关66575-67-5兴
关99/16兴
关2846-04-0兴
关87/5兴关49/16兴
关555-43-1兴
ENTHALPIES OF VAPORIZATION
813
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C57H114
C57H114
C57H116
C57H116
C57H116S
C58H110
C58H116
C58H116
C58H118
C58H118
C58H118S
C59H112
C59H118
C59H118
C59H120
C59H120
C59H120S
C60H114
C60H120
C60H120
C60H122
C60H122
C60H122S
C61H116
C61H122
C61H122
C61H124
C61H124
C61H124S
C62H118
C62H124
Compound
共Temperature range/K兲
共521–588兲
henpentacontylcyclohexane
共580– 885兲
1-heptapentacontene
共578 – 877兲
heptapentacontane
共629– 882兲
2-methylhexapentacontane
共578 – 875兲
1-heptapentacontanethiol
共589– 892兲
dopentacontylbenzene
共583– 888兲
dopentacontylcyclohexane
共582– 888兲
1-octapentacontene
共580– 881兲
octapentacontane
共632– 886兲
2-methylheptapentacontane
共581– 879兲
1-octapentacontanethiol
共591– 895兲
tripentacontylbenzene
共585– 891兲
tripentacontylcyclohexane
共585– 892兲
1-nonapentacontene
共583– 885兲
nonapentacontane
共635– 890兲
2-methyloctapentacontane
共583– 882兲
1-nonapentacontanethiol
共593– 899兲
tetrapentacontylbenzene
共588 – 895兲
1-hexacontene
共586 – 888兲
tetrapentacontylcyclohexane
共587– 895兲
hexacontane
共638 – 893兲
2-methylnonapentacontane
共586 – 886兲
1-hexacontanethiol
共595–902兲
pentapentacontylbenzene
共590– 898兲
1-henhexacontene
共588 – 891兲
pentapentacontylcyclohexane
共590– 899兲
henhexacontane
共642– 897兲
2-methylhexacontane
共588 – 889兲
1-henhexacontanethiol
共597–905兲
hexapentacontylbenzene
共592–902兲
1-dohexacontene
共590– 895兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
220.8
167.5
共536兲
TGA
A, T
153.3
共595兲
154.6
共593兲
158.9
共644兲
155.9
共593兲
156.7
共604兲
155.7
共598兲
154.3
共597兲
155.8
共595兲
160.3
共647兲
156.8
共596兲
157.4
共606兲
155.9
共600兲
155.0
共600兲
156.4
共598兲
161.8
共650兲
157.9
共598兲
158.3
共608兲
156.6
共603兲
157.1
共601兲
156.0
共602兲
163.0
共653兲
158.5
共601兲
159.1
共610兲
157.5
共605兲
158.0
共603兲
156.6
共605兲
163.9
共657兲
159.4
共603兲
159.6
共612兲
158.4
共607兲
158.6
共605兲
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
CAS registry number
Reference
关02/33兴
关87/5兴关49/16兴
关66575-68-6兴
关99/16兴
关66575-69-7兴
关99/16兴
关5856-67-7兴
关87/5兴关66/8兴
关66575-70-0兴
关99/16兴
关66575-75-1兴
关99/16兴
关66575-73-3兴
关99/16兴
关66575-74-4兴
关99/16兴
关66575-75-5兴
关99/16兴
关7667-78-9兴
关87/5兴关66/8兴
关66575-76-6兴
关99/16兴
关66575-77-7兴
关99/16兴
关66575-78-8兴
关99/16兴
关66575-80-2兴
关99/16兴
关66575-79-9兴
关99/16兴
关7667-70-0兴
关87/5兴关66/8兴
关66575-49-3兴
关99/16兴
关66575-50-6兴
关99/16兴
关66575-51-7兴
关99/16兴
关66575-52-8兴
关99/16兴
关66575-53-9兴
关99/16兴
关7667-80-3兴
关87/5兴关66/8兴
关66575-54-0兴
关99/16兴
关66575-55-1兴
关99/16兴
关66563-50-6兴
关99/16兴
关66563-51-7兴
关99/16兴
关66563-52-8兴
关99/16兴
关7667-81-4兴
关87/5兴关66/8兴
关66563-53-9兴
关99/16兴
关66563-54-0兴
关99/16兴
关66563-55-1兴
关99/16兴
关66563-56-2兴
关99/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
814
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C62H126
C62H126
C62H126
C62H122S
C63H120
C63H126
C63H126
C63H128
C63H128
C63H128S
C64H122
C64H128
C64H128
C64H130
C64H130
C64H130S
C65H124
C65H130
C65H130
C65H132
C65H132
C65H132S
C66H126
C66H132
C66H132
C66H134
C66H134
C66H134S
C67H128
C67H134
C67H134
C67H136
Compound
共Temperature range/K兲
hexapentacontylcyclohexane
共592–902兲
dohexacontane
共645–901兲
2-methylhenhexacontane
共590– 892兲
1-dohexacontanethiol
共599–908兲
heptapentacontylbenzene
共595–905兲
heptapentacontylcyclohexane
共594 –905兲
1-trihexacontene
共593– 899兲
trihexacontane
共647–904兲
2-methyldohexacontane
共593– 897兲
1-trihexacontanethiol
共602–911兲
octapentacontylbenzene
共597–908兲
octapentacontylcyclohexane
共596 –908兲
1-tetrahexacontene
共595–902兲
tetrahexacontane
共650–907兲
2-methyltrihexacontane
共595–900兲
1-tetrahexacontanethiol
共604 –914兲
nonapentacontylbenzene
共599–911兲
nonapentacontylcyclohexane
共599–912兲
1-pentahexacontene
共597–905兲
pentahexacontane
共653–910兲
2-methyltetrahexacontane
共597–903兲
1-pentahexacontanethiol
共606 –917兲
hexacontylbenzene
共602–914兲
hexacontylcyclohexane
共601–915兲
1-hexahexacontene
共599–908兲
hexahexacontane
共656 –914兲
2-methylpentahexacontane
共599–906兲
1-hexahexacontanethiol
共607–920兲
henhexacontylbenzene
共603–917兲
henhexacontylcyclohexane
共603–917兲
1-heptahexacontene
共601–911兲
heptahexacontane
共659–937兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
157.5
共607兲
165.2
共660兲
160.1
共605兲
160.1
共614兲
158.9
共610兲
158.2
共609兲
159.8
共608兲
116.7
共662兲
161.3
共608兲
161.1
共617兲
159.5
共612兲
158.8
共611兲
160.5
共610兲
168.3
共665兲
161.9
共610兲
161.6
共619兲
160.1
共614兲
159.9
共614兲
161.1
共612兲
169.0
共668兲
162.5
共612兲
162.1
共621兲
161.2
共617兲
160.5
共616兲
161.7
共614兲
170.0
共671兲
163.1
共614兲
162.8
共622兲
162.1
共618兲
160.9
共618兲
162.3
共616兲
170.9
共674兲
Method
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
CAS registry number
Reference
关66563-57-3兴
关99/16兴
关7719-83-7兴
关87/5兴关66/8兴
关66563-58-4兴
关99/16兴
关66563-59-5兴
关99/16兴
关66563-60-8兴
关99/16兴
关66563-61-9兴
关99/16兴
关66563-62-0兴
关99/16兴
关7719-84-8兴
关87/5兴关66/8兴
关66563-63-1兴
关99/16兴
关66563-64-2兴
关99/16兴
关66563-65-3兴
关99/16兴
关66563-66-4兴
关99/16兴
关66563-36-8兴
关99/16兴
关7719-87-1兴
关87/5兴关66/8兴
关66563-37-9兴
关99/16兴
关66563-38-0兴
关99/16兴
关66563-39-1兴
关99/16兴
关66563-40-4兴
关99/16兴
关66563-41-5兴
关99/16兴
关7719-88-2兴
关87/5兴关66/8兴
关66563-42-6兴
关99/16兴
关66563-43-7兴
关99/16兴
关66563-44-8兴
关99/16兴
关66563-45-9兴
关99/16兴
关66563-46-0兴
关99/16兴
关7719-89-3兴
关87/5兴关66/8兴
关66563-47-1兴
关99/16兴
关66563-48-2兴
关99/16兴
关66563-72-2兴
关99/16兴
关66563-73-3兴
关99/16兴
关66563-74-4兴
关99/16兴
关7719-90-6兴
关87/5兴关66/8兴
ENTHALPIES OF VAPORIZATION
815
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C67H136
C67H136S
C68H130
C68H136
C68H136
C68H138
C68H138
C68H138S
C69H132
C69H138
C69H138
C69H140
C69H140
C69H140S
C70H134
C70H140
C70H140
C70H142
C70H142
C70H142S
C71H136
C71H142
C71H142
C71H144
C71H144
C71H144S
C72H138
C72H144
C72H144
C72H146
C72H146
C72H146S
Compound
共Temperature range/K兲
2-methylhexahexacontane
共601–909兲
1-heptahexacontanethiol
共609–922兲
dohexacontylbenzene
共605–920兲
dohexacontylcyclohexane
共605–920兲
1-octahexacontene
共603–913兲
octahexacontane
共661–920兲
2-methylheptahexacontane
共603–912兲
1-octahexacontanethiol
共611–925兲
trihexacontylbenzene
共607–923兲
1-nonhexacontene
共605–916兲
trihexacontylcyclohexane
共607–923兲
nonahexacontane
共664 –923兲
2-methyloctahexacontane
共605–914兲
1-nonahexacontanethiol
共612–928兲
tetrahexacontylbenzene
共609–925兲
1-heptacontene
共607–919兲
tetrahexacontylcyclohexane
共608 –926兲
heptacontane
共666 –926兲
2-methylnonahexacontane
共607–917兲
1-heptacontanethiol
共614 –930兲
pentahexacontylbenzene
共611–928兲
1-henheptacontene
共609–922兲
pentahexacontylcyclohexane
共610–928兲
henheptacontane
共669–928兲
2-methylheptacontane
共609–920兲
1-henheptacontanethiol
共616 –933兲
hexahexacontylbenzene
共613–931兲
1-doheptacontene
共610–924兲
hexahexacontylcyclohexane
共612–931兲
doheptacontane
共671–931兲
2-methylhenheptacontane
共611–923兲
1-doheptacontanethiol
共617–935兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
163.7
共616兲
163.2
共624兲
162.6
共620兲
161.5
共620兲
162.8
共618兲
172.3
共676兲
164.3
共618兲
163.6
共626兲
163.1
共622兲
163.4
共620兲
162.0
共622兲
173.2
共679兲
164.9
共620兲
164.4
共627兲
163.6
共624兲
163.9
共622兲
162.8
共623兲
174.4
共681兲
165.4
共622兲
164.8
共621兲
164.4
共626兲
164.4
共624兲
163.3
共625兲
175.2
共684兲
165.9
共624兲
165.1
共631兲
164.5
共628兲
165.3
共625兲
163.8
共627兲
176.4
共686兲
166.4
共626兲
165.8
共632兲
Method
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
CAS registry number
Reference
关66563-75-5兴
关99/16兴
关66563-76-6兴
关99/16兴
关66563-75-5兴
关99/16兴
关66563-78-8兴
关99/16兴
关66563-79-9兴
关99/16兴
关7719-91-7兴
关87/5兴关66/8兴
关66563-80-2兴
关99/16兴
关66563-81-3兴
关99/16兴
关66563-82-4兴
关99/16兴
关66563-83-5兴
关99/16兴
关66563-93-7兴
关99/16兴
关7719-92-8兴
关87/5兴关66/8兴
关66563-94-8兴
关99/16兴
关66577-83-1兴
关99/16兴
关66577-84-2兴
关99/16兴
关66577-85-3兴
关99/16兴
关66577-86-4兴
关99/16兴
关7719-93-9兴
关87/5兴关66/8兴
关66577-87-5兴
关99/16兴
关66577-88-6兴
关99/16兴
关66577-89-7兴
关99/16兴
关66577-90-0兴
关99/16兴
关66577-91-1兴
关99/16兴
关7667-82-5兴
关87/5兴关66/8兴
关66577-92-2兴
关99/16兴
关66577-93-3兴
关99/16兴
关66577-94-4兴
关99/16兴
关66577-95-5兴
关99/16兴
关66577-96-6兴
关99/16兴
关7668-83-6兴
关87/5兴关66/8兴
关66577-97-7兴
关99/16兴
关66577-98-8兴
关99/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
816
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C73H140
C73H146
C73H146
C73H148
C73H148
C73H148S
C74H142
C74H148
C74H148
C74H150
C74H150
C74H150S
C75H144
C75H150
C75H150
C75H152
C75H152
C75H152S
C76H146
C76H152
C76H152
C76H154
C76H154
C76H154S
C77H148
C77H154
C77H154
C77H156
C77H156
C77H156S
C78H150
C78H156
Compound
共Temperature range/K兲
heptahexacontylbenzene
共614 –933兲
heptahexacontylcyclohexane
共614 –933兲
1-triheptacontene
共612–927兲
triheptacontane
共674 –934兲
2-methyldoheptacontane
共613–926兲
1-triheptacontanethiol
共619–938兲
octahexacontylbenzene
共616 –936兲
octahexacontylcyclohexane
共615–936兲
1-tetraheptacontene
共614 –930兲
tetraheptacontane
共676 –936兲
2-methyltriheptacontane
共615–928兲
1-tetraheptacontanethiol
共620–940兲
nonahexacontylbenzene
共618 –938兲
nonahexacontylcyclohexane
共617– 632兲
1-pentaheptacontene
共616 –932兲
pentaheptacontane
共678 –939兲
2-methyltetraheptacontane
共616 –931兲
1-pentaheptacontanethiol
共622–942兲
heptacontylbenzene
共619–941兲
heptacontylcyclohexane
共619–941兲
1-hexaheptacontene
共617–935兲
hexaheptacontane
共680–941兲
2-methylpentaheptacontane
共618 –933兲
1-hexaheptacontanethiol
共623–945兲
henheptacontylbenzene
共621–943兲
henheptacontylcyclohexane
共620–943兲
1-heptaheptacontene
共619–937兲
heptaheptacontane
共682–944兲
2-methylhexaheptacontane
共620–936兲
1-heptaheptacontanethiol
共625–947兲
doheptacontylbenzene
共622–945兲
doheptacontylcyclohexane
共622–945兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
165.4
共629兲
164.2
共629兲
165.7
共627兲
177.1
共689兲
166.9
共628兲
166.2
共634兲
165.8
共631兲
165.0
共630兲
166.2
共629兲
178.2
共691兲
167.4
共630兲
166.9
共635兲
166.3
共633兲
165.4
共632兲
166.7
共631兲
179.4
共693兲
168.2
共631兲
167.2
共637兲
167.0
共634兲
165.8
共634兲
167.5
共632兲
180.4
共695兲
168.7
共633兲
169.8
共638兲
167.4
共636兲
166.6
共635兲
167.9
共634兲
181.4
共697兲
169.1
共635兲
168.2
共640兲
167.3
共637兲
166.9
共637兲
Method
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
CAS registry number
Reference
关66577-99-9兴
关99/16兴
关66578-00-5兴
关99/16兴
关66578-01-6兴
关99/16兴
关7667-84-7兴
关87/5兴关66/8兴
关66578-02-7兴
关99/16兴
关66577-64-8兴
关99/16兴
关66577-65-9兴
关99/16兴
关66577-66-0兴
关99/16兴
关66577-67-1兴
关99/16兴
关7667-85-8兴
关87/5兴关66/8兴
关66577-68-2兴
关99/16兴
关66577-69-3兴
关99/16兴
关66577-70-6兴
关99/16兴
关66577-71-7兴
关99/16兴
关66577-72-8兴
关99/16兴
关7667-86-9兴
关87/5兴关66/8兴
关66577-73-9兴
关99/16兴
关66577-74-0兴
关99/16兴
关66577-75-1兴
关99/16兴
关66577-76-2兴
关99/16兴
关66577-77-3兴
关99/16兴
关7667-87-0兴
关87/5兴关66/8兴
关66577-78-4兴
关99/16兴
关66577-79-5兴
关99/16兴
关66577-80-8兴
关99/16兴
关66577-81-9兴
关99/16兴
关66577-82-0兴
关99/16兴
关7719-94-0兴
关87/5兴关66/8兴
关66575-56-2兴
关99/16兴
关66575-57-3兴
关99/16兴
关66327-30-8兴
关99/16兴
关66327-31-9兴
关99/16兴
ENTHALPIES OF VAPORIZATION
817
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C78H156
C78H158
C78H158
C78H158S
C79H152
C79H158
C79H158
C79H160
C79H160
C79H160S
C80H154
C80H160
C80H160
C80H162
C80H162
C80H162S
C81H156
C81H162
C81H162
C81H164
C81H164
C81H164S
C82H158
C82H164
C82H164
C82H166
C82H166
C82H166S
C83H160
C83H166
C83H166
C83H168
Compound
共Temperature range/K兲
1-octaheptacontene
共621–940兲
octaheptacontane
共685–946兲
2-methylheptaheptacontane
共621–939兲
1-octaheptacontanethiol
共626 –949兲
triheptacontylbenzene
共623–947兲
1-nonaheptacontene
共622–942兲
triheptacontylcyclohexane
共623–948兲
nonaheptacontane
共687–949兲
2-methyloctaheptacontane
共622–940兲
1-nonaheptacontanethiol
共628 –952兲
tetraheptacontylbenzene
共625–949兲
1-octacontene
共624 –945兲
tetraheptacontylcyclohexane
共625–950兲
octacontane
共689–951兲
2-methylnonaheptacontane
共624 –943兲
1-octacontanethiol
共629–954兲
pentaheptacontylbenzene
共636 –952兲
1-henoctacontene
共625–946兲
pentaheptacontylcyclohexane
共627–952兲
henoctacontane
共691–953兲
2-methyloctancontane
共625–945兲
1-henoctacontanethiol
共630–955兲
hexaheptacontylbenzene
共628 –954兲
1-dooctacontene
共626 –949兲
hexaheptacontylcyclohexane
共627–954兲
dooctacontane
共693–955兲
2-methylhenoctacontane
共627–947兲
1-dooctacontanethiol
共631–957兲
heptaheptacontylbenzene
共628 –955兲
heptaheptaconylcyclohexane
共629–956兲
1-trioctacontene
共628 –951兲
trioctacontane
共694 –957兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
168.3
共636兲
181.8
共700兲
169.9
共636兲
168.8
共641兲
168.0
共638兲
169.1
共637兲
167.7
共638兲
182.7
共702兲
167.8
共637兲
169.1
共643兲
168.4
共640兲
169.4
共639兲
168.0
共640兲
183.6
共704兲
170.2
共639兲
169.6
共644兲
169.1
共641兲
169.3
共640兲
168.4
共642兲
184.5
共706兲
170.9
共640兲
169.4
共645兲
169.4
共643兲
157.6
共641兲
168.5
共642兲
185.3
共708兲
171.3
共642兲
170.0
共646兲
169.6
共643兲
168.9
共644兲
170.4
共643兲
186.5
共709兲
Method
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
CAS registry number
Reference
关66327-32-0兴
关99/16兴
关7719-85-9兴
关87/5兴关66/8兴
关66327-33-1兴
关99/16兴
关66375-13-1兴
关99/16兴
关66327-34-2兴
关99/16兴
关66327-35-3兴
关99/16兴
关66327-36-4兴
关99/16兴
关7719-86-0兴
关87/5兴关66/8兴
关66327-37-5兴
关99/16兴
关66327-38-6兴
关99/16兴
关66327-39-7兴
关99/16兴
关66327-40-0兴
关99/16兴
关66327-41-1兴
关99/16兴
关7667-88-1兴
关87/5兴关66/8兴
关66327-42-2兴
关99/16兴
关66327-43-3兴
关99/16兴
关66327-44-4兴
关99/16兴
关66327-45-5兴
关99/16兴
关66327-46-6兴
关99/16兴
关7667-89-2兴
关87/5兴关66/8兴
关66327-47-7兴
关99/16兴
关66327-48-8兴
关99/16兴
关66327-49-9兴
关99/16兴
关66327-50-2兴
关99/16兴
关66327-09-1兴
关99/16兴
关7719-95-1兴
关87/5兴关66/8兴
关66327-10-4兴
关99/16兴
关66327-11-5兴
关99/16兴
关66327-12-6兴
关99/16兴
关66327-13-7兴
关99/16兴
关66327-14-8兴
关99/16兴
关7667-90-5兴
关87/5兴关66/8兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
818
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C83H168
C83H168S
C84H162
C84H168
C84H168
C84H170
C84H170
C84H170S
C85H164
C85H170
C85H170
C85H172
C85H172
C85H172S
C86H166
C86H172
C86H172
C86H174
C86H174
C86H174S
C87H168
C87H174
C87H174
C87H176
C87H176
C87H176S
C88H170
C88H176
C88H176
C88H178
C88H178
C88H178S
Compound
共Temperature range/K兲
2-methyldooctacontane
共628 –949兲
1-trioctacontanethiol
共633–959兲
octaheptacontylbenzene
共630–957兲
octaheptacontylcyclohexane
共630–958兲
1-tetraoctacontene
共629–953兲
tetraoctacontane
共696 –960兲
2-methyltrioctacontane
共629–951兲
1-tetraoctacontanethiol
共634 –962兲
nonheptacontylbenzene
共631–960兲
nonheptacontylcyclohexane
共632–960兲
1-pentaoctacontene
共630–955兲
pentaoctacontane
共698 –962兲
2-methyltetraoctacontane
共631–953兲
1-pentaoctacontanethiol
共634 –963兲
octacontylbenzene
共633–962兲
1-hexaoctacontene
共631–957兲
octacontylcyclohexane
共632–962兲
hexaoctacontane
共700–964兲
2-methylpentaoctacontane
共632–956兲
1-hexaoctacontanethiol
共636 –965兲
henoctacontylbenzene
共633–963兲
henoctacontylcyclohexane
共633–964兲
1-heptaoctacontene
共633–959兲
heptaoctacontane
共702–966兲
2-methylhexaoctacontane
共633–957兲
1-heptaoctacontanethiol
共637–967兲
dooctacontylbenzene
共635–965兲
dooctacontylcyclohexane
共635–966兲
1-octaoctacontene
共634 –961兲
octaoctacontane
共703–967兲
2-methylheptaoctacontane
共634 –959兲
1-octacontanethiol
共639–969兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
171.1
共643兲
170.2
共648兲
169.9
共645兲
169.5
共645兲
170.1
共644兲
187.3
共711兲
171.8
共644兲
170.8
共649兲
170.6
共646兲
169.8
共647兲
170.9
共645兲
187.9
共713兲
172.1
共646兲
170.8
共649兲
170.9
共648兲
171.5
共646兲
169.9
共647兲
188.6
共715兲
172.8
共647兲
171.1
共651兲
171.0
共648兲
170.6
共648兲
171.8
共648兲
189.3
共717兲
172.6
共648兲
171.7
共652兲
171.3
共650兲
170.8
共650兲
172.5
共649兲
190.4
共718兲
173.3
共649兲
171.9
共654兲
Method
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
A, EST
EST
CAS registry number
Reference
关66327-15-9兴
关99/16兴
关66327-16-0兴
关99/16兴
关66327-17-1兴
关99/16兴
关66327-18-2兴
关99/16兴
关66327-19-3兴
关99/16兴
关7667-91-6兴
关87/5兴关66/8兴
关66327-20-6兴
关99/16兴
关66327-21-7兴
关99/16兴
关66327-22-8兴
关99/16兴
关66327-23-9兴
关99/16兴
关66327-24-0兴
关99/16兴
关7719-96-2兴
关87/5兴关66/8兴
关66327-25-1兴
关99/16兴
关66327-26-2兴
关99/16兴
关66327-27-3兴
关99/16兴
关66327-28-4兴
关99/16兴
关66327-29-5兴
关99/16兴
关7667-92-7兴
关87/5兴关66/8兴
关66426-88-3兴
关99/16兴
关66326-89-4兴
关99/16兴
关66326-90-7兴
关99/16兴
关66326-91-8兴
关99/16兴
关66326-92-9兴
关99/16兴
关7667-93-8兴
关87/5兴关66/8兴
关66326-93-0兴
关99/16兴
关66326-94-1兴
关99/16兴
关66326-95-2兴
关99/16兴
关66326-96-3兴
关99/16兴
关66326-97-4兴
关99/16兴
关7667-94-9兴
关87/5兴关66/8兴
关66326-98-5兴
关99/16兴
关66326-99-6兴
关99/16兴
ENTHALPIES OF VAPORIZATION
819
TABLE 6. Enthalpies of vaporization of organic compounds, 1880–2002—Continued
Molecular formula
C89H172
C89H178
C89H178
C89H180
C89H180
C89H180S
C90H174
C90H182
C91H184
C92H186
C93H188
C94H190
C95H192
C96H194
C97H196
C98H198
C99H200
C100H202
Compound
共Temperature range/K兲
trioctacontylbenzene
共636 –967兲
1-nonaoctacontene
共635–962兲
trioctacontylcyclohexane
共636 –968兲
nonaoctacontane
共705–969兲
2-methyloctaoctacontane
共636 –962兲
1-nonaoctacontanethiol
共639–970兲
tetraoctacontylbenzene
共637–968兲
nonacontane
共707–971兲
hennonacontane
共708 –973兲
dononacontane
共710–975兲
trinonacontane
共711–977兲
tetranonacontane
共713–978兲
pentanonacontane
共714 –980兲
hexanonacontane
共716 –982兲
heptanonacontane
共717–983兲
octanonacontane
共719–985兲
nonanonacontane
共720–986兲
hectane
共721–988兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
172.0
共651兲
172.3
共650兲
171.5
共651兲
190.9
共720兲
173.6
共651兲
171.9
共654兲
171.7
共652兲
191.6
共722兲
A, EST
192.5
共723兲
A, EST
193.0
共725兲
A, EST
194.1
共726兲
A, EST
194.5
共728兲
A, EST
195.4
共729兲
A, EST
195.8
共731兲
A, EST
196.6
共732兲
A, EST
196.9
共734兲
A, EST
197.8
共735兲
A, EST
198.5
共736兲
A, EST
Method
A, EST
EST
CAS registry number
Reference
关66327-00-2兴
关99/16兴
关66327-01-3兴
关99/16兴
关66327-02-4兴
关99/16兴
关7719-76-8兴
关87/5兴关66/8兴
关66327-03-5兴
关99/16兴
关66327-04-6兴
关99/16兴
关66327-05-7兴
关99/16兴
关7667-51-8兴
关87/5兴关66/8兴
关7719-97-3兴
关87/5兴关66/8兴
关7667-95-0兴
关87/5兴关66/8兴
关7667-96-1兴
关87/5兴关66/8兴
关1574-32-9兴
关87/5兴关66/8兴
关7667-97-2兴
关87/5兴关66/8兴
关7763-13-5兴
关87/5兴关66/8兴
关7670-25-9兴
关87/5兴关66/8兴
关7670-26-0兴
关87/5兴关66/8兴
关7670-27-1兴
关87/5兴关66/8兴
关6703-98-6兴
关87/5兴关66/8兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
820
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002
Molecular formula
Al
C3 H9 Al
C4 H10AlCl
C4 H11Al
Compound
共Temperature range/K兲
trimethylaluminum
共336 – 400兲
diethylaluminum chloride
共278 –318兲
共273– 473兲
diethylaluminum hydride
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
39.8
63.2⫾1.7
41.1
共351兲
50.5
53.9
共293兲
共373兲
Method
BG
57.7⫾2.1
46.9
C6 H15Al
triethylaluminum
73.2⫾2.1
60.2
54.1
C6 H15AlO
C7 H17AlO
C8 H19Al
diethylaluminum ethoxide
共403– 463兲
diethylaluminum propoxide
共398 – 463兲
diisobutylaluminum hydride
BG
48.7⫾0.8
共433兲
51.0⫾0.8
共430兲
42.3⫾2.1
35.6
C9 H21Al
C9 H21AlO3
C12H27Al
C12H27AlO3
C12H27AlO3
C12H27AlO3
C15H12AlF9 O6
C15H21AlO6
AlB3 H12
As
CAsCl2 F3 S
CH3 AsBr2
CH3 AsCl2
CH3 AsF2
C2 AsClF6 S2
C2 H2 AsCl3
C2 H2 AsCl3
C2 H2 AsCl3
C2 H2 AsCl3
tripropylaluminum
42.5⫾1.2
aluminum isopropoxide
共353–399兲
48.1⫾6.3
triisobutylaluminum
共273–322兲
38.3
tributoxyaluminum
共503–533兲
104.1
triisobutoxyaluminum
共500–550兲
139.4
tri-sec-butoxyaluminum
共425– 469兲
81.5
tris共1,1,1-trifluoro-2,4-pentanedionato兲aluminum共III兲
共349– 411兲
58.7⫾0.7
共392– 484兲
69.6⫾0.5
tris共pentane-2,4-dionato兲aluminum共III兲
共430–530兲
78.7⫾0.9
aluminum borohydride
共231–290兲
30.0
dichloro 共trifluoromethylthio兲arsine
共293–373兲
methyl dibromoarsine
共293–333兲
methyl dichloroarsine
共273–313兲
methyl difluorarsine
共244 –350兲
chloro bis共trifluoromethylthio兲arsine
共293–373兲
␤-chlorovinyldichloroarsine
共339–383兲
cis-2-chlorovinyldichloroarsine
共341–382兲
trans-2-chlorovinyldichloroarsine
共323– 423兲
2-chlorovinyldichloroarsine
共293–333兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共376兲
共298兲
共518兲
A, I
共515兲
A, I
共440兲
A, I
共380兲
共438兲
BG
共298兲
T
CAS registry number
Reference
关75-24-1兴
关63/5兴
关63/34兴关82/15兴
关46/13兴
关96-10-6兴
关91/1兴
关91/1兴
关871-27-2兴
关67/33兴关82/15兴
关65/27兴
关65/27兴
关97-93-8兴
关67/33兴关82/15兴
关65/27兴
关65/27兴
关46/13兴
关1586-92-1兴
关74/16兴
关74/16兴
关1191-15-7兴
关67/33兴关82/15兴
关65/27兴
关65/27兴
关102-67-0兴
关67/33兴关82/15兴
关555-31-7兴
关72/18兴
关100-99-2兴
关64/20兴
关3085-30-1兴
关87/5兴关57/26兴
关3453-79-0兴
关87/5兴关57/26兴
关2269-22-9兴
关87/5兴关57/26兴
关14354-59-7兴
关88/18兴
关78/10兴
关13963-57-0兴
关86/11兴
共260兲
关40/13兴
37.1
共333兲
49.9
共313兲
41.0
共293兲
关60/25兴
关676-70-0兴
关48/12兴
关593-89-5兴
关48/12兴
35.5
共297兲
39.6
共333兲
关60/25兴
U88.3
共354兲
关47/3兴
48.5
共356兲
关48/4兴
54.5
共338兲
53.4
共313兲
关50/1兴
关541-25-3兴
关48/12兴
MM
关46/15兴
ENTHALPIES OF VAPORIZATION
821
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C2 H2 AsF6 N
C2 H5 AsCl2
C2 H5 AsF2
C3 AsF9 S
C3 AsF9 Se
C3 H4 AsF6 N
C3 H7 AsCl2
C3 H9 As
C3 H9 AsO3
C4 HAs2 F12N
C4 H6 AsF6 N
C4 H6 AsF6 N
C4 H11As
C4 H12AsN
C5 AsF13Se
C5 H7 AsCl2
C5 H11AsBr2
C5 H15AsN2
C6 H5 AsCl2
C6 H9 As
C6 H12AsN
C6 H15As
C6 H15AsO3
C6 H18AsN3
C8 H12AsNO3
C9 H21As
C9 H21As
C9 H21AsO3
C9 H21AsO3
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
共amino兲 bis共trifluoromethyl兲arsine
共313–358兲
31.8
ethyl dichloroarsine
共293–333兲
44.6
ethyl difluorarsine
共248 –367兲
33.9
bis共trifluoromethyl兲 trifluoromethylthioarsine
共263–312兲
34.0
bis共trifluoromethyl兲 trifluoromethylselenoarsine
共227–295兲
34.8
共methylamino兲 bis共trifluoromethyl兲arsine
共293–355兲
34.9
propyl dichloroarsine
共293–333兲
49.2
trimethyl arsine
共240–280兲
27.7⫾0.2
28.9⫾1.3
trimethyl arsenite
共300–335兲
42.3⫾1.3
iminobis关bis共trifluoromethyl兲arsine兴
共357–398兲
38.9
共ethylamino兲 bis共trifluoromethyl兲arsine
共292–368兲
32.8
共dimethylamino兲 bis共trifluoromethyl兲arsine
共296 –358兲
35.6
diethyl arsine
共281–366兲
35.2
共281–366兲
34.2
共dimethylamino兲 dimethylarsine
共274 –342兲
36.7
heptafluoropropylseleno bis共trifluoromethyl兲arsine
共277–348兲
40.3
bis共2-chlorovinyl兲methylarsine
共293–333兲
55.6
pentyl dibromoarsine
共293–333兲
60.0
bis共dimethylamino兲 methylarsine
共273–333兲
39.2
phenyl dichloroarsine
共313–333兲
58.4
共335–529兲
48.7
trivinylarsine
共295–339兲
35.6
cyano共ethyl兲propylarsine
共293–313兲
54.6
triethylarsine
共273–339兲
38.1⫾1.5
共290–379兲
38.5⫾0.7
43.1⫾4.2
arsenic 共III兲 triethoxide
47.9⫾1.1
共305–340兲
50.6⫾4.2
tris共dimethylamino兲arsine
共288 –359兲
45.8
dimethyl arsanilate
共288 – 433兲
48.8
triisopropylarsine
共346 – 405兲
45.2⫾0.5
tripropylarsine
共314 – 420兲
44.0⫾0.7
arsenic 共III兲 tripropoxide
51.2⫾1.8
arsenic 共III兲 triisopropoxide
80.1⫾0.9
Mean temperature
(T m /K)
Method
共335兲
关59/22兴
关598-14-1兴
关48/12兴
共313兲
共307兲
CAS registry number
Reference
MM
关46/15兴
共287兲
关62/32兴
共261兲
关62/32兴
共324兲
共298兲
关59/22兴
关926-53-4兴
关48/12兴
关593-88-4兴
关01/9兴
关56/24兴关82/15兴
关6596-95-8兴
关53/16兴关70/31兴
共377兲
关59/22兴
共330兲
关59/22兴
共327兲
关59/22兴
关692-42-2兴
关01/5兴
关01/5兴
共313兲
共260兲
共273兲
共298兲
MM
MM
关59/20兴
共312兲
关62/32兴
共313兲
关48/12兴
共313兲
关48/12兴
共323兲
共350兲
关59/20兴
关696-28-6兴
关48/12兴
关47/5兴
共310兲
关57/15兴关84/9兴
共303兲
关48/12兴
关617-75-4兴
关01/9兴
关01/9兴
关63/37兴关82/15兴
共306兲
共334兲
DSC
共298兲
关96/7兴
关53/16兴关70/31兴
关59/20兴
共303兲
关47/5兴
共376兲
DSC
关01/9兴
关5852-57-3兴
关95/5兴关01/9兴
关15606-91-4兴
关96/7兴
DSC
关96/7兴
共367兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
822
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C10H16AsNO3
Compound
共Temperature range/K兲
C12H27AsO3
diethyl arsanilate
共311– 454兲
arsenic 共III兲 tributoxide
C12H27AsO3
arsenic 共III兲 triisobutoxide
C13H10AsN
AsF3
diphenylarsine carbonitrile
共296 –326兲
tripentylarsine
共408 – 466兲
triphenylarsine
共493–563兲
arsenic trifluoride
AsH3
arsine
As2 S2
arsenic 共II兲 sulfide
共663– 838兲
C15H33As
C18H15As
B
CH3 BO
C2 H3 BCl2
C2 H6 B4
C2 H6 O-BF3
C2 H6 ClBO2
C2 H6 S-BH3
C2 H7 B5
C2 H8 BSb
C2 H10BP
C2 H11B2 N
C2 H13B5
C3 BF9 S3
C3 H5 BF2
C3 H7 BF2
C3 H9 BO3
C3 H9 B
共326兲
A
64.0⫾1.8
DSC
75.7⫾1.2
DSC
关87/5兴关47/5兴
关3141-10-4兴
关96/7兴
关96/7兴
关23525-22-6兴
关87/5兴
共432兲
75.7
共508兲
35.8
共293兲
16.7
共210兲
69.6
共750兲
关32/4兴
关603-32-7兴
关87/5兴
关7784-35-2兴
关41/11兴
关7784-42-1兴
关55/19兴
关1303-32-8兴
关68/25兴
19.7
共194兲
关47/5兴
32.7
共295兲
26.6
共207兲
T
31.5
共269兲
T
22.6
共203兲
T
27.7
共260兲
T
关63/26兴
关32038-87-2兴
关60/12兴
关758-99-6兴
关60/12兴
关358-95-2兴
关60/10兴
关3677-80-3兴
关60/10兴
35.1⫾0.8
共298兲
关31/3兴关70/31兴
37.2⫾1.3
carborane-4
共241–287兲
26.2
dimethyl ether—boron trifluoride complex
共311–346兲
53.1
dimethoxychloroborane
34.3⫾1.2
dimethyl sulfide—borane complex
共273–314兲
44.9
2,4-dicarba-closo-heptaborane
共273–323兲
31.6
dimethylstibinoborine
共234 –273兲
32.1
dimethylphosphine borine
共303–383兲
45.1
N-dimethylaminodiborane
共220–267兲
29.3
1-ethylpentaborane 共9兲
共273–383兲
35.0
tris共trifluoromethylthio兲borane
共242–298兲
33.9
allyldifluoroborane
共194 –249兲
28.0
propyldifluoroborane
共195–248兲
29.4
trimethylborate
共304 –340兲
34.2
trimethylborane
20.2⫾0.1
23.9
共298兲
关51/14兴关70/31兴
共272兲
关63/3兴
共328兲
关60/7兴
共298兲
关31/3兴关70/31兴
关13292-87-0兴
关99/16兴
关20693-69-0兴
关76/17兴
dimethylaminodichloroborane
C2 H3 BF2
54.2
CAS registry number
Reference
62.3
C2 H6 BCl2 N
C2 BCl2 F3
Method
共311兲
C2 H5 BCl2 O
C2 BF5
Mean temperature
(T m /K)
84.6
borine carbonyl
共134 –209兲
1-methylpentaborane 共9兲
共241–349兲
perfluorovinyldifluoroborine
共177–238兲
perfluorovinyldichloroborine
共238 –301兲
vinyldifluoroborane
共178 –228兲
vinyldichloroborane
共237–282兲
ethoxydichloroborane
CH11B5
⌬ vapH m
共kJ mol⫺1兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
A
A
共293兲
共288兲
I
共254兲
关59/6兴
共318兲
关53/4兴
共252兲
关55/14兴
共328兲
关63/26兴
关36884-78-3兴
关99/16兴
共270兲
共221兲
T
关60/10兴
共221兲
T
关60/10兴
关121-43-7兴
关67/2兴
共319兲
BG
关61/13兴关61/15兴
关46/13兴
ENTHALPIES OF VAPORIZATION
823
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C3 H9 BS
C3 H9 BS2
C3 H9 BS3
C3 H9 B3 O3
C3 H12BN
C3 H15B5
C4 BClF6
C4 H6 BF
C4 H6 BCl
C5 H10O-BF3
C4 H10O-BF3
C4 H10BClO2
C4 H12BClN2
C4 H11N-C3 H9 B
C4 H12B2 O4
C4 H17B5
C5 H16B10
C5 H16B10O2
C5 H19B5
C6 BF9
C6 H5 BBr2
C6 H5 BCl2
C6 H12BCl3 O3
C6 H13BO2
C6 H15B
C6 H15BO3
C6 H15BS3
C6 H15B3 O3
C6 H16BN
C6 H17B5 Br2 Si2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
dimethyl共methylthio兲borane
共227–304兲
31.6
methylbis共methylthio兲borane
共300–373兲
44.7
tris共methylthio兲borane
共325– 462兲
44.9
共303– 493兲
51.6
共303– 493兲
54.0⫾0.8
methylboric acid anhydride
共273–327兲
37.4
borine trimethylamine
共136 –195兲
19.9
1-isopropylpentaborane 共9兲
共273–398兲
37.2
bis共perfluorovinyl兲chloroborine
共280–322兲
35.6
divinylfluoroborane
共193–273兲
25.8
divinylchloroborane
共275–298兲
33.0
tetrahydopyran—boron trifluoride complex
共323–368兲
60.9
diethyl ether—boron trifluoride complex
共283–353兲
55.1
diethoxychloroborane
38.9⫾0.8
bis共dimethylamino兲chloroborane
41.8⫾2.1
N,N-dimethylethylamine—trimethylborane complex
共303–339兲
58.2
tetramethoxydiboron
共273–348兲
44.0
44.7
1-sec-butylpentaborane 共9兲
共299– 428兲
41.4
isopropenyl-o-carborane
共323– 473兲
36.7
1-acetoxymethyl-o-carborane
56.5
1-methyl-2-sec-butylpentaborane
共301– 423兲
41.0
tris共perfluorovinyl兲borine
共297–335兲
41.1
phenylboron dibromide
共391– 433兲
43.9⫾2.1
phenylboron dichloride
共273–318兲
33.7⫾0.8
tris共2-chloroethyl兲 orthoborate
共390– 448兲
57.7
1-butaneboronic acid, cyclic ethylene ester
40.2
triethylborane
33.6
36.8⫾0.4
triethylborate
共302–382兲
41.0
共302–382兲
38.2
triethylthioborane
61.5⫾2.1
triethylboroxin
共347– 424兲
46.0
共N-ethylamino兲diethylborane
60.7⫾0.8
2,4-bis共bromodimethylsilyl兲-2,4-dicarbo-closo-heptaborane 共7兲
Method
CAS registry number
Reference
共394兲
共398兲
共298兲
关19163-05-4兴
关99/16兴
关19163-08-7兴
关99/16兴
关997-49-9兴
关99/16兴
关67/8兴
关67/8兴
共288兲
关40/4兴
共180兲
关37/6兴
共335兲
关63/26兴
共265兲
共315兲
共301兲
T
关60/12兴
共233兲
T
关60/10兴
共286兲
T
关60/10兴
共345兲
关60/8兴
共318兲
关60/7兴
共298兲
关31/3兴关70/31兴
共298兲
关51/14兴关70/31兴
共321兲
关60/9兴
共310兲
关60/13兴
关72/32兴
共364兲
关63/26兴
共398兲
共569兲
关63/46兴
关19528-60-0兴
关74/31兴
共362兲
关63/26兴
共316兲
T
关60/12兴
共412兲
T
关67/1兴
共296兲
T
关67/1兴
共419兲
关46/9兴
关10173-39-4兴
关70/29兴
关97-94-9兴
关83/1兴
关63/32兴关82/15兴
关150-46-9兴
关67/2兴
关67/2兴
共329兲
共293兲
共317兲
共391兲
关66/27兴关70/31兴
共362兲
EB
关90/19兴
关67/32兴关82/15兴
关66798-29-6兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
824
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C6 H17B5 Cl2 Si2
C6 H18BN
C6 H18BN3
C6 H19B5 Si2
C6 H20B2 N2
C6 H20B10
C6 H20B10
C6 H20B10
C6 H20B10
C7 H15BO2
C7 H15B3 F3 N3
C7 H22B10
C7 H22B10
C8 H17BO2
C8 H18BBr
C8 H18BCl
C8 H19BO2
C8 H20B2 O
C8 H20B2 O4
C8 H24B2 N4
C8 H24B10
C8 H24B10
C8 H23B5 Si2
C9 H11BO2
C9 H15BCl6 O3
C9 H21B
C9 H21B
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共388 – 463兲
53.1
共403兲
2,4-bis共chlorodimethylsilyl兲-2,4-dicarbo-closo-heptaborane 共7兲
共359– 439兲
46.2
共374兲
triethylaminoborane
69.7⫾0.8
tris共triethylamino兲borane
46.9⫾0.8
2,4-bis共dimethylsilyl兲-2,4-dicarba-closo-heptaborane
共373– 453兲
41.3
共388兲
dimethylaminomethyl borane cyclic dimer
共311–357兲
57.8
共314兲
1-butyl-o-carbaborane 共12兲
共433–534兲
77.3⫾3.8
共298兲
共433–534兲
50.6⫾1.3
共571兲
1-isobutyl-o-carbaborane 共12兲
共427–536兲
72.8⫾2.1
共298兲
共427–536兲
49.1⫾0.9
共564兲
1-butyl-m-carbaborane 共12兲
共406 –527兲
67.7⫾0.8
共298兲
共406 –527兲
46.7⫾0.6
共537兲
1-isobutyl-m-carbaborane 共12兲
共400– 488兲
64.1⫾2.8
共298兲
共400– 488兲
44.6⫾1.3
共532兲
1-butaneboronic acid, cyclic trimethylene ester
43.1
共348兲
1,2,3,4,5-pentamethyl-6-共trifluorovinyl兲borazaine
共280–324兲
18.4
共302兲
1-pentyl-o-carbaborane 共12兲
共446 –549兲
84.3⫾6.0
共298兲
共446 –549兲
52.0⫾1.5
共571兲
1-pentyl-m-carbaborane 共12兲
共421–544兲
74.6⫾2.4
共298兲
共421–544兲
48.6⫾0.8
共555兲
1-butaneboronic acid, cyclic tetramethylene ester
76.6
共364兲
dibutylboron bromide
共293–363兲
50.6
共328兲
dibutylboron chloride
共293–363兲
48.2
共328兲
1-butaneboronic acid, diethyl ester
43.3
共346兲
tetraethyldiboroxane
共343– 421兲
42.9
共358兲
tetraethoxydiboron
共273–358兲
52.9
共315兲
tetra共dimethylamino兲diboron
共296 – 408兲
52.7
共352兲
1-hexyl-o-carbaborane 共12兲
共458 –530兲
93.5⫾6.0
共298兲
共458 –530兲
54.1⫾2.1
共601兲
1-hexyl-m-carbaborane 共12兲
共434 –544兲
79.8⫾2.4
共298兲
共434 –544兲
50.7⫾1.0
共572兲
2,4-bis共trimethylsilyl兲-2,4-dicarba-closo-heptaborane
共373– 473兲
45.0
共388兲
benzeneboronic acid, cyclic trimethylene ester
47.3
共426兲
tris共2,2⬘-dichloroisopropyl兲 orthoborate
共488 –513兲
77.0
共465兲
tripropylborane
41.8⫾1.3
共273–393兲
40.0
triisopropylborane
41.8⫾1.3
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
I
I
CAS registry number
Reference
关79/25兴
关28699-83-4兴
关79/25兴
关67/32兴关70/31兴
I
关51/14兴关70/31兴
关59351-11-0兴
关76/17兴
关66/6兴
EB
EB
关79/26兴
关79/26兴
EB
EB
关79/26兴
关79/26兴
EB
EB
关79/26兴
关79/26兴
EB
EB
关79/26兴
关79/26兴
关30169-71-2兴
关70/29兴
关20453-68-3兴
关99/16兴
EB
EB
关79/26兴
关79/26兴
EB
EB
关79/26兴
关79/26兴
关31044-62-9兴
关70/29兴
关5674-70-4兴
关53/11兴
关1730-69-4兴
关53/11兴
关10394-51-1兴
关70/29兴
EB
关90/19兴
关60/13兴
关60/14兴
EB
EB
关79/26兴
关79/26兴
EB
EB
关79/26兴
关79/26兴
关59351-10-9兴
关76/17兴
关4406-77-3兴
关70/29兴
I
关46/9兴
BG
关63/33兴关82/15兴
关46/13兴
关1776-66-5兴
关63/33兴关82/15兴
ENTHALPIES OF VAPORIZATION
825
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C9 H21BO3
C9 H21BO3
C9 H21BS3
C9 H22BNO
C10H13BO2
C10H15BO2
C11H24B10O3
C12H10BBr
C12H10BCl
C12H21B
C12H27B
C12H27BO3
C12H27BO3
C12H27BS3
C15H32B10O5
C15H33BO3
C15H33BS3
C18H12BCl3 O3
C18H12BCl3 O3
C18H15B
C21H12BN3 O3
C21H21BO3
C21H21BO3
C21H21BO6
C21H21BO6
B2 D6
B2 H6
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共273–393兲
40.0
tripropylborate
共340– 453兲
52.3
共355兲
共358 – 452兲
47.6
共452兲
triisopropylborate
共338 – 412兲
42.4
共412兲
tri共propylthio兲borane
共423– 483兲
76.2
共453兲
共423– 483兲
87.0⫾2.1
共298兲
butyl共dimethylamino兲methoxyborane
共369– 427兲
48.1
共384兲
58.2⫾2.5
共298兲
benzeneboronic acid, cyclic tetramethylene ester
57.3
共441兲
benzeneboronic acid, diethyl ester
67.4
共332兲
3-methyl-3-共7-isopropyl-m-carboranoylperoxy兲-1-butyne
共353–368兲
140.6⫾4.4
共360兲
diphenylboron bromide
共436 –516兲
60.2⫾2.5
共476兲
diphenylboron chloride
共363– 485兲
41.4⫾2.1
共424兲
dodecahydro-9-boraphenalene
共304 – 404兲
53.1
共319兲
tributylboron
共293–363兲
54.7
共328兲
tributylborate
共380–504兲
58.1
共395兲
共390– 491兲
55.9
共405兲
triisobutylborate
共372– 472兲
51.7
共483兲
tri共butylthio兲borane
共440–503兲
83.9
共471兲
共440–503兲
95.8⫾2.1
共298兲
2,5-dimethyl-共2-tert-butylperoxy-5-m-carboranoylperoxy兲-3-hexyne
共353–366兲
86.8⫾5.4
共360兲
tripentylborate
共410–505兲
67.7
共425兲
tri共penthylthio兲borane
共446 –503兲
92.3
共474兲
共446 –503兲
104.6⫾2.1
共298兲
tris共4-chlorophenoxy兲borane
共428 – 476兲
30.6⫾0.9
共452兲
tris共3-chlorophenoxy兲borane
共476 –524兲
49.6⫾1.6
共500兲
triphenylborane
共423–568兲
64.3
共438兲
共423–548兲
64.4⫾2.1
共486兲
tris共4-cyanophenoxy兲borane
共448 –506兲
46.2⫾2.0
共477兲
tris共4-methylphenoxy兲borane
共475–525兲
76.1⫾1.7
共500兲
tris共3-methylphenoxy兲borane
共477–523兲
77.1⫾2.2
共500兲
tris共3-methoxyphenoxy兲borane
共440– 496兲
57.8⫾2.4
共468兲
tris共4-methoxyphenoxy兲borane
共448 –500兲
42.4⫾2.7
共474兲
perdeuterodiborane
共118 –179兲
15.3
共164兲
diborane
共118 –179兲
15.3
共164兲
14.2
共180兲
12.6
共210兲
Method
CAS registry number
Reference
BG
关46/13兴
关688-71-1兴
关80/15兴
关67/2兴
关5419-55-6兴
关67/2兴
关998-38-9兴
关67/8兴
关67/8兴
EB
关73/17兴
关73/17兴
关4406-76-2兴
关70/29兴
关31044-59-4兴
关70/29兴
ME
关99/17兴
关5123-17-1兴
关67/1兴
关3677-81-4兴
关67/1兴
关16664-33-8兴
关87/5兴
关122-56-5兴
关53/11兴
关688-74-4兴
关80/15兴
关67/2兴
关13195-76-1兴
关67/2兴
关998-46-9兴
关67/8兴
关67/8兴
T
T
A
ME
关99/17兴
关80/15兴
MM
MM
A
MM
MM
关67/8兴
关67/8兴
关7539-58-2兴
关73/2兴
关42080-72-8兴
关73/2兴
关960-71-4兴
关87/5兴
关67/1兴
关73/2兴
关14643-62-0兴
关73/2兴
MM
关73/2兴
关42080-76-2兴
关73/2兴
关42080-75-1兴
关73/2兴
C
C
关61/29兴
关19287-45-7兴
关61/29兴
关59/19兴
关59/19兴
MM
MM
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
826
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
B3 Br3 H3 N3
B3 Cl3 H3 N3
Be
C2 H6 Be
C10H8 BeF6 O4
C10H14BeO4
C22H38BeO4
BeF2
Bi
CH5 Bi
C2 H7 Bi
C3 H9 Bi
C6 H9 Bi
C6 H15Bi
Compound
共Temperature range/K兲
2,4,6-tribromoborazine
共404 – 415兲
2,4,6-trichloroborazine
共363– 409兲
共360–386兲
BrF5
Br2
Br3 FO3
HBr
Cd
C2 H6 Cd
C4 H10Cd
C6 H14Cd
C8 H18Cd
CdCl2
Mean temperature
(T m /K)
Method
10.5
7.3
共240兲
共270兲
C
C
47.0⫾5.1
共409兲
I
49.6⫾0.2
47.8
共386兲
共373兲
I
dimethyl beryllium
共373– 453兲
88.7
bis共1,1,1-trifluoro-2,4-pentanedionato兲berylium共II兲
共387– 474兲
59.8⫾0.4
bis共2,4-pentanedionato兲berylium共II兲
共382–511兲
65.7⫾1.1
bis共2,2,6,6-tetramethylheptane-3,5-dionato兲berylium
共383–525兲
65.1
beryllium fluoride
共823–1223兲
222.8
共802–1021兲
209.6
共821–1002兲
196.6
共745–968兲
212.9
methylbismuthine
共190–258兲
dimethylbismuthine
共206 –250兲
trimethylbismuthine
共215–380兲
trivinylbismuthine
共293–346兲
triethylbismuthine
共301–343兲
Br
BrF3
⌬ vapH m
共kJ mol⫺1兲
bromine trifluoride
共311– 428兲
bromine pentafluoride
共297–314兲
共213–297兲
bromine
共343–383兲
共297–389兲
perbromyl fluoride
共188 –291兲
hydrogen bromide
dimethyl cadmium
共271–378兲
共270–295兲
diethyl cadmium
共286 –362兲
dipropyl cadmium
共312–373兲
dibutyl cadmium
共336 –376兲
cadmium chloride
共875–1026兲
Cl
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共388兲
共431兲
BG
共447兲
BG
共454兲
BG
共1923兲
共911兲
共911兲
共856兲
TE, ME, GS
GS
CAS registry number
Reference
关59/19兴
关59/19兴
关13703-88-3兴
关66/1兴
关933-18-6兴
关66/1兴
关55/18兴
关506-63-8兴
关52/4兴
关13939-10-1兴
关88/18兴
关10210-64-7兴
关88/18兴
关36915-22-7兴
关88/18兴
关7787-49-7兴
关63/26兴
关58/16兴
关58/17兴
关54/16兴
29.9
共224兲
32.7
共228兲
35.8
36.0⫾1.3
34.8
共298兲
48.5
共308兲
关66172-95-0兴
关61/28兴
关1438-45-4兴
关61/28兴
关593-91-9兴
关61/28兴
关54/18兴关82/15兴
关46/13兴
关65313-35-1兴
关57/15兴关84/9兴
46.0⫾4.2
43.9
共322兲
关63/37兴关82/15兴
关57/15兴
45.9
共326兲
30.6
31.2
共304兲
共255兲
29.8
31.3
共358兲
共312兲
25.3
共250兲
17.6
共206兲
37.1⫾0.1
38.9
37.9⫾0.1
35.4
共324兲
共282兲
46.0⫾0.4
46.0⫾2.1
共324兲
54.2⫾0.4
共342兲
67.7⫾1.2
共356兲
132.6
共950兲
BG
关52/19兴
关7789-30-2兴
关56/21兴
关31/2兴
关7726-95-6兴
关73/36兴
关55/23兴
C
BG
关72/36兴
关10035-10-6兴
关28/6兴
关506-82-1兴
关85/8兴关01/9兴
关56/4兴
关49/22兴关82/15兴
关46/13兴
关592-02-9兴
关85/8兴关01/9兴
关49/21兴关82/15兴
关5905-48-6兴
关85/8兴关01/9兴
关3431-67-2兴
关85/8兴关01/9兴
关10108-64-2兴
关58/28兴
ENTHALPIES OF VAPORIZATION
827
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
ClFO3
ClF3
ClNO
Cl2 O6
HCl
Co
C3 CoNO4
C4 HCoO4
C4 H3 CoO4 Si
C7 H5 CoO2
C8 H2 Co2 O8 Si
Cr
C6 CrO6
C10H10Cr
C15H12CrF9 O6
C15H21CrO6
C16H20Cr
C20H28Cr
C21H30Cr
C24H36Cr
Cu
C6 H12CuN2 S4
C14H28CuN2 S4
C16H20CuF6 O4
C16H20CuF6 O4 (C10H20O5 )
C18H36CuN2 S4
C18H36CuN2 S4
C22H38CuO6
Dy
C33H57DyO6
Er
C33H57ErO6
Eu
C33H57EuO6
Compound
共Temperature range/K兲
perchloryl fluoride
共164 –228兲
chlorine trifluoride
共299–317兲
共226 –303兲
nitrosyl chloride
共203–258兲
dichlorine hexaoxide
共273–318兲
hydrogen chloride
cobalt nitrosyl tricarbonyl
共272–353兲
hydridocobalt tetracarbonyl
共273–295兲
silyl tetracarbonyl cobalt
共263–357兲
共cyclopendienyl兲 cobalt dicarbonyl
共313–369兲
silylene bis共tetracarbonylcobalt兲
共297–335兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
19.2
19.3
共226兲
共226兲
MM
C
关58/5兴
关58/5兴
27.5
28.4
共313兲
共288兲
25.3
共230兲
52.3
共295兲
16.2
共188兲
36.3
共287兲
28.0
37.8
关97/16兴
关51/11兴
关2696-92-6兴
关49/24兴
C
关47/5兴
T
关80/19兴
关14652-62-1兴
关69/36兴
T
关00/19兴
关23591-62-0兴
关69/36兴
BG
关13007-92-6兴
关47/5兴
关1271-24-5兴
关84/32兴
关14592-89-2兴
关78/11兴
关21679-31-2兴
关88/18兴
GS
共310兲
52.1⫾0.7
38.7
chromium hexacarbonyl
共309– 424兲
62.5
chromocene
共452–519兲
49.5⫾1.5
tris共1,1,1-trifluoro-2,4-pentanedionato兲chromium共III兲
共424 – 486兲
76.7⫾0.6
tris共2,4-pentanedionato兲chromium共III兲
共490–536兲
82.2⫾2.0
bis共ethylbenzene兲chromium
75.3⫾8.4
bis共1,2-diethylbenzene兲chromium
75.3⫾8.4
共1,2-diisopropylbenzene兲isopropylbenzenechromium
100.4⫾8.4
bis共1,2-diisopropylbenzene兲chromium
100.4⫾8.4
bis共dimethyldithiocarbamate兲copper
共443– 473兲
147.4
bis共dipropyldithiocarbamate兲copper
共422– 453兲
118.4
bis共pivaloyltrifluoroacetonato兲copper
共381– 443兲
76.5⫾2.0
bis共pivaloyltrifluoroacetonato兲copper 15-crown-5 complex
共368 – 443兲
80.2⫾2.0
bis共dibutyldithiocarbamate兲copper
共423– 468兲
121.8
bis共diisobutyldithiocarbamate兲copper
共425– 445兲
101.8
bis共2,2,6,6-tetramethylheptane-3,5-dionato兲copper共II兲
共468 –519兲
77.8⫾0.8
共316兲
共324兲
共485兲
共455兲
共513兲
关90/18兴
关7647-01-0兴
关28/4兴
关73/32兴关82/15兴
关73/32兴关82/15兴
关73/32兴关82/15兴
关73/32兴关82/15兴
关137-29-1兴
关99/16兴
关14358-07-5兴
关99/16兴
共458兲
共437兲
GS
关93/14兴
GS
关93/14兴
关13927-71-4兴
关99/16兴
关51205-55-1兴
关99/16兴
关14040-05-2兴
关79/20兴
共445兲
共435兲
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲dyprosium共III兲
共456 –500兲
86.2
BG
关15522-69-7兴
关69/28兴
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲erbium共III兲
共454 – 490兲
85.6
BG
关14319-09-6兴
关69/28兴
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲europium共III兲
关15522-71-1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
828
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共466 – 490兲
F
F3 NO
F5 I
HF
Fe
C4 H6 FeO4 Si2
C5 FeO5
C7 H6 FeO3
trifluoroamine oxide
共116 –191兲
iodine pentafluoride
共283–378兲
hydrogen fluoride
共240–290兲
共190–320兲
tetracarbonyl disilyl iron
共329–377兲
iron pentacarbonyl
共254 –304兲
共266 –353兲
共266 –378兲
1,3-butadiene iron tricarbonyl
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
87.4
Method
CAS registry number
Reference
BG
关69/28兴
关13847-65-9兴
关68/30兴
关7783-66-6兴
关71/35兴
关7664-39-3兴
关34/8兴
关24/1兴
16.1
39.3
共330兲
25.2
25.2
共265兲
共255兲
43.8
共353兲
40.1⫾0.5
39.0
38.1⫾0.4
40.2⫾0.8
37.6
共279兲
共309兲
共298兲
T
共281兲
49.0⫾4.2
C10H10Fe
C15H12F9 FeO6
Ga
C3 H9 Ga
ferrocene
共456 –523兲
共451–523兲
共519– 604兲
47.3
49.8
44.7
47.3
tris共1,1,1-trifluoro-2,4-pentanedionato兲iron共III兲
共392– 428兲
87.0⫾1.2
共471兲
共466兲
共561兲
共456兲
A
A
共410兲
C6 H9 Ga
C6 H15Ga
C9 H21Ga
C9 H21Ga
C11H24GaNS2
C11H24GaNS2
C11H24GaNS2
C12H27Ga
C13H28GaNS2
C15H12F9 GaO6
C15H32GaNS2
Gd
C33H57GdO6
Ge
CHCl5 Ge
diethylgallium chloride
共273–333兲
59.9
trivinyl gallium
共298 –373兲
U72.6
关Note: Decomposition noted above 333 K.兴
triethyl gallium
共299–387兲
43.1⫾1.6
38.5⫾0.4
triisopropyl gallium
共298 –373兲
49.0
tripropyl gallium
共316 –385兲
46.6⫾0.5
共298 –373兲
49.2
di-tert-butyl gallium dimethyldithiocarbamate
共374 – 427兲
43⫾1
dibutyl gallium dimethyldithiocarbamate
共385– 424兲
53⫾1
di-sec-butyl gallium dimethyldithiocarbamate
共366 – 425兲
44⫾1
tributyl gallium
共330–378兲
51.6⫾1.3
共426 –507兲
56.2
di-tert-butyl gallium diethyldithiocarbamate
共372– 419兲
48⫾6
tris共1,1,1-trifluoro-2,4-pentanedionato兲gallium共III兲
共401– 459兲
75.6⫾0.5
di-tert-butyl gallium dipropyldithiocarbamate
共365– 424兲
46⫾1
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲gadolinium共III兲
共456 –500兲
90.2
trichloro共dichloromethyl兲germane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共303兲
共335兲
关1115-99-7兴
关01/9兴关01/24兴
关73/31兴关82/15兴
关54614-59-9兴
关62/27兴
关29868-77-7兴
关01/9兴
关62/27兴
共343兲
共335兲
共350兲
共335兲
共354兲
共441兲
关76/23兴关82/15兴
关102-54-5兴
关87/5兴关99/16兴
关87/5兴
关72/34兴
关52/21兴
关14526-22-8兴
关78/11兴
关1445-79-0兴
关58/18兴关82/15兴
关33/14兴关58/20兴
关30914-08-0兴
关91/1兴
关1188-13-2兴
关62/27兴
trimethyl gallium
33.1⫾0.8
32.6
C4 H10ClGa
关26469-80-7兴
关69/38兴
关13463-40-6兴
关74/27兴
关70/25兴
关59/14兴
关59/18兴关82/15兴
关47/5兴
TGA
关99/33兴
TGA
关99/33兴
TGA
关99/33兴
关15677-44-8兴
关01/9兴
关87/5兴
A
TGA
关99/33兴
关15453-83-5兴
关78/10兴
TGA
关99/33兴
BG
关14768-15-1兴
关69/28兴
共430兲
ENTHALPIES OF VAPORIZATION
829
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
CH2 Cl4 Ge
CH3 Cl3 Ge
CH4 Cl2 Ge
CH5 BrGe
CH5 ClGe
CH6 Ge
CH6 GeS
C2 H5 Cl3 Ge
C2 H7 ClGe
C2 H8 Ge
C2 H10Ge2
C2 H10Ge2
C3 H9 ClGe
C3 H9 FGe
C3 H12Ge2
C4 H9 Cl3 Ge
C4 H12Ge
C4 H12GeO
C4 H12GeO4
C5 H11Cl3 Ge
C6 H5 Cl3 Ge
C6 H13Cl3 Ge
C6 H15BrGe
C6 H18Ge2 O
C6 H30ClGeN3
C7 H7 Cl3 Ge
C7 H15Cl3 Ge
C8 H20Ge
Compound
共Temperature range/K兲
共303– 423兲
trichloro共chloromethyl兲germane
共303– 423兲
methyltrichlorogermane
共293–385兲
methyldichlorogermane
共281–346兲
共273–290兲
methylbromogermane
共273–333兲
methyl chlorogermane
共241–263兲
methylgermane
共159–230兲
共164 –197兲
共methylthio兲germane
共223–291兲
trichloro共ethyl兲germane
共293– 415兲
dimethylchlorogermane
共273–288兲
dimethylgermane
共196 –228兲
1,1-dimethyldigermane
共259–295兲
1,2-dimethyldigermane
共258 –295兲
trimethylchlorogermane
共293–363兲
共273–341兲
trimethylfluorogermane
共285–345兲
1,1,2-trimethyldigermane
共268 –294兲
butyltrichlorogermanium
共313– 453兲
共337–377兲
tetramethylgermane
trimethylmethoxygermane
共273–335兲
tetramethoxygermane
共303–385兲
pentyltrichlorogermanium
共323– 473兲
共305– 475兲
phenyltrichlorogermane
共343– 473兲
hexyltrichlorogermanium
共315– 491兲
bromotriethylgermane
共303– 463兲
hexamethyldigermoxane
共291–345兲
tris共diethylamino兲chlorogermane
共363– 493兲
benzyltrichlorogermane
共373– 473兲
heptyltrichlorogermanium
共323–506兲
pentyl共trimethyl兲germane
共303– 423兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
47.9
共318兲
关75/29兴
45.9
共318兲
关75/29兴
37.4
共308兲
关71/12兴
34.5
33.1
共313兲
共281兲
SG
关61/1兴
关61/27兴
33.3
共303兲
SG
关61/1兴
25.8
共252兲
16.6
21.4
共194兲
共181兲
29.8
共257兲
关61/27兴
关1449-65-6兴
关61/1兴
关61/27兴
关16643-16-8兴
关99/16兴
41.9
共308兲
关71/12兴
29.4
共280兲
26.5
共212兲
31.8
共277兲
29.3
共277兲
36.3
34.4
共308兲
共307兲
SG
32.4
共315兲
SG
33.5
共281兲
关61/27兴
关1449-64-5兴
关61/27兴
关23830-51-5兴
关69/39兴
关23830-52-6兴
关69/39兴
关1529-47-1兴
关72/19兴
关61/1兴
关661-37-0兴
关61/1兴
关23830-53-7兴
关69/39兴
49.2
45.8
共328兲
共352兲
28.1⫾0.1
27.6⫾2.1
共285兲
C
32.4
共304兲
SG
40.2⫾0.4
44.0
共344兲
51.9
49.7
共338兲
共320兲
55.4
共358兲
51.1
共329兲
48.3
共318兲
44.1
共318兲
64.4
共378兲
58.8
共388兲
52.3
共338兲
关70/12兴
关6181-21-1兴
关72/13兴
关1190-86-9兴
关72/10兴
44.3
共318兲
关75/30兴
Method
SG
CAS registry number
Reference
关75/30兴
关72/10兴
关865-52-1兴
关70/25兴
关69/27兴关82/15兴
关6163-67-3兴
关61/1兴
关70/32兴关77/23兴
关58/26兴
关25425-26-7兴
关75/30兴
关72/10兴
关1074-29-9兴
关72/13兴
关35460-93-6兴
关72/10兴
关1067-10-3兴
关71/12兴
SG
关61/1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
830
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C8 H20Ge
Compound
共Temperature range/K兲
tetraethylgermane
共253–293兲
共337– 436兲
C8 H20GeO4
C8 H24Ge4 O4
C10H25GeN
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
43.4
45.7⫾0.4
46.1
44.8⫾1.3
共273兲
共298兲
共352兲
Method
GS
C
共328 – 414兲
octomethylcyclotetragermoxane
共333– 473兲
triethyl共diethylamino兲germane
共303– 463兲
tert-butylperoxytriethylgermane
C12H28Ge
tetrapropylgermane
共353– 493兲
43.1⫾0.4
47.9
共371兲
51.4
共403兲
50.9
46.0⫾4.8
共318兲
关70/32兴关77/23兴
关58/26兴
关7749-82-8兴
关72/17兴
关756-66-1兴
关70/12兴
关71/30兴关82/15兴
43.5⫾4.2
C12H28GeO4
C12H30Ge2 Hg
tetrapropoxygermane
共343– 453兲
共369– 465兲
tetraisopropoxygermane
共313– 453兲
共355– 444兲
bis共triethylgermyl兲mercury
共383– 403兲
C12H30Ge2
hexaethyldigermane
C12H30Ge2 O
hexaethyldigermoxane
C16H12Ge
共diethynyl兲diphenylgermane
共305–337兲
tetrabutoxygermane
共394 –519兲
tetraisobutoxygermane
共369– 482兲
tetra-sec-butoxygermane
共365– 475兲
tetra-tert-butoxygermane
共364 – 460兲
bis共triisopropylgermyl兲mercury
共373– 483兲
C16H36GeO4
C16H36GeO4
C16H36GeO4
C16H36GeO4
C18H42Ge2 Hg
C24H20GeO4
tetraphenoxygermane
Ge4 H10
tetragermane
Ge5 H12
pentagermane
GeH6 Si
germylsilane
共190–250兲
germanium tetraiodide
共419– 613兲
GeI4
Hg
C2 H6 Hg
C2 F6 HgS2
C4 H10Hg
dimethyl mercury
共275–367兲
bis共trifluoromethylthio兲mercury
共353– 423兲
diethyl mercury
dipropyl mercury
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
关71/29兴关82/15兴
关994-65-0兴
关87/5兴
关64/28兴关82/15兴
54.7
61.5⫾4.2
共368兲
A
63.3
55.0
共358兲
共417兲
A
关87/5兴
关58/26兴
60.4
54.9
共328兲
共400兲
A
64.8
62.8⫾4.2
共393兲
关87/5兴
关58/26兴
关4149-28-4兴
关72/15兴
关72/31兴关82/15兴
62.8
关63/35兴关82/15兴
58.6⫾4.2
关71/29兴关82/15兴
110.8
共320兲
62.4
共456兲
关87/5兴
关25063-27-8兴
关58/26兴
59.9
共426兲
关58/26兴
59.9
共420兲
关58/26兴
53.8
共412兲
68.7
54.4⫾4.2
共388兲
关58/26兴
关24004-54-4兴
关72/15兴
关72/31兴关82/15兴
A
37.4⫾0.4
关70/32兴关77/23兴
32.8
关59/25兴
34.6
关59/25兴
25.0
共220兲
64.2⫾0.2
共419兲
36.7⫾0.1
34.6⫾0.8
共321兲
49.9
共368兲
44.8⫾1.7
44.9
C6 H14Hg
关597-63-7兴
关92/5兴
关77/7兴
关74/12兴
关64/27兴关82/15兴
tetraethoxygermane
C10H25GeO2
C12H28GeO4
CAS registry number
Reference
关63/27兴
关13450-95-8兴
关99/22兴
关593-74-8兴
关01/9兴
关50/12兴关82/15兴
关99/16兴
关627-44-1兴
关51/12兴关82/15兴
关35/7兴
关628-85-3兴
ENTHALPIES OF VAPORIZATION
831
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
UV
关52/20兴关82/15兴
关1071-39-2兴
关52/20兴关82/15兴
关4149-28-4兴
关72/15兴
关4149-29-5兴
关72/15兴
关24004-54-4兴
关72/15兴
关7774-29-0兴
关02/7兴
BG
关15522-73-3兴
关69/28兴
C
关10034-85-2兴
关29/4兴
55.2⫾1.3
C6 H14Hg
diisopropyl mercury
C12H30Ge2 Hg
bis共triethylgermyl兲mercury
共383– 403兲
bis共triethylsilyl兲mercury
共383– 433兲
bis共triisopropylgermyl兲mercury
共373– 483兲
mercuric iodide
共537– 610兲
53.6⫾1.7
C12H30HgSi2
C18H42Ge2 Hg
HgI2
Ho
C33H57HoO6
I
HI
64.8
共393兲
64.0
共398兲
68.7
共388兲
147.4
共574兲
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲holmium共III兲
共458 –500兲
84.6
hydrogen iodide
19.8
In
C6 H15In
C9 H21In
C9 H21In
C12H27In
C15H12F9 InO6
Li
C4 H9 Li
triethyl indium
共326 –376兲
45.0⫾0.7
tripropyl indium
共400– 483兲
52.0
triisopropyl indium
共318 –366兲
52.3⫾0.7
共394 – 478兲
51.0
tributyl indium
共444 –539兲
58.5
tris共1,1,1-trifluoro-2,4-pentanedionato兲indium共III兲
共398 – 478兲
77.4⫾0.6
共238兲
共351兲
共441兲
共342兲
共336兲
共459兲
A
共438兲
关109-72-8兴
关61/24兴关82/15兴
butyl lithium
107.1⫾2.9
关Note: Authors of 关61/24兴 noted that the experimental data was not
very reproducible, and subject to considerable error.兴
Lu
C33H57LuO6
Mn
C5 H3 MnO5 Si
C10H10Mn
C10O10MnRe
C10O10Mn2
Mo
MoF6
N
BrClFN
BrF2 N
Br2 FN
Br3 N
Cl2 FN
Cl3 N
HNO3
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲lutetium共III兲
共448 – 490兲
83.6
silyl pentacarbonyl manganese
共294 –391兲
bis共cyclopentadienyl兲manganese
共378 – 435兲
manganese rhenium decacarbonyl
共440– 463兲
dimanganese decacarbonyl
共428 – 463兲
molybdenum hexafluoride
共318 –363兲
bromochlorofluoroammonia
共240–310兲
bromodifluoroammonia
共180–250兲
dibromofluoroammonia
共280–350兲
nitrogen tribromide
共380– 450兲
dichlorofluoroammonia
共200–280兲
nitrogen trichloride
共280– 440兲
nitric acid
共273–356兲
关923-34-2兴
关01/9兴关01/24兴
关3015-98-3兴
关99/16兴
关17144-80-8兴
关01/9兴
关99/16兴
关15676-66-1兴
关87/5兴
关15453-87-9兴
关78/10兴
BG
关15497-45-2兴
关69/28兴
39.6
共343兲
T
58.0
共393兲
A
56.5
共451兲
60.7⫾1.3
共446兲
关15770-61-3兴
关69/37兴关67/40兴
关1271-27-8兴
关87/5兴
关14693-30-2兴
关71/14兴
关10170-69-1兴
关71/14兴
27.4
共340兲
关7783-77-9兴
关68/27兴
30.2
共275兲
23.2
共215兲
33.6
共315兲
44.1
共415兲
25.7
共240兲
32.9
共360兲
38.6
共312兲
关96/31兴
关15605-95-5兴
关96/31兴
关145543-67-5兴
关96/31兴
关15162-90-0兴
关96/31兴
关96/31兴
关10025-85-1兴
关96/31兴
关7697-37-2兴
关66/30兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
832
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
NH3
Compound
共Temperature range/K兲
ammonia
共293–392兲
共199–241兲
NO
nitric oxide
N2
nitrogen
共63–126兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
22.7
23.5
23.4
Method
CAS registry number
Reference
共308兲
共239兲
共239兲
C
关7664-41-7兴
关79/24兴
关37/13兴
关37/13兴
13.8
共212兲
C
6.1
5.6
共78兲
共77兲
26.4
共200兲
关29/3兴
关7727-37-9兴
关67/42兴
关33/16兴
关10036-47-2兴
关58/15兴
关302-01-2兴
关49/13兴
关10024-94-2兴
关45/5兴
A
关87/5兴
BG
关15492-47-4兴
关69/28兴
N2 F4
tetrafluorohydrazine
N2 H4
hydrazine
共288 –353兲
nitrous oxide
共182–236兲
44.5
共303兲
16.1
共221兲
pentaethylniobate
共376 – 414兲
107.6
共391兲
N2 O
Nb
C10H25NbO5
Nd
C33H57NdO6
Ni
C3 NiO3 C3 F9 P
C4 NiO4
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲neodymium共III兲
共491–510兲
99.1
tris共trifluoromethyl兲phosphine—nickel tricarbonyl complex
共273–323兲
nickel tetracarbonyl
共277– 412兲
共250–315兲
C6 H12N2 NiS4
C14H28N2 NiS4
C18H36N2 NiS4
C18H36N2 NiS4
C22H44N2 NiS4
O
H2 O2
31.2
共298兲
共448兲
关58/21兴
关13463-39-3兴
关70/35兴
关57/24兴关82/15兴
关55/17兴
关55/17兴
关53/14兴
关47/5兴
关42/9兴关55/17兴
关1903/1兴关55/17兴
关15521-65-0兴
关99/16兴
关14516-30-4兴
关99/16兴
关13927-77-0兴
关99/16兴
关28371-07-5兴
关99/16兴
关55935-69-8兴
关99/16兴
29.8
27.6⫾1.3
28.0
27.2
30.2⫾0.1
29.5
30.1
27.2
共344兲
48.5
共320兲
关7722-84-1兴
关24/2兴
56.3⫾1.3
共535兲
101.7
共420兲
bis共dimethyldithiocarbamate兲nickel
共448 – 478兲
139.9
bis共dipropyldithiocarbamate兲nickel
共433– 462兲
126.1
bis共dibutyldithiocarbamate兲nickel
共438 –562兲
136.6
bis共diisobutyldithiocarbamate兲nickel
共453– 473兲
124.0
bis关bis共3-methylbutyl兲dithiocarbamate兴nickel
共429– 468兲
164.5
hydrogen peroxide
共277–363兲
Os
C10H10Os
osmocene
共506 –563兲
C10O10Os3
triosmium dodecacarbonyl
共497–543兲
P 共see table 6 for organophosphorous compounds兲
Br3 P
tribromophosphine
共298兲
共265兲
共463兲
共448兲
共500兲
共463兲
关1273-81-0兴
关84/11兴
关15696-40-9兴
关74/19兴
关7789-60-8兴
关96/23关63/31兴
关7719-12-2兴
关96/23关63/31兴
48.5
Cl3 P
trichlorophosphine
F2 HOP
F2 N3 OP
hydrophosphoryl difluoride
共220–271兲
hydrothiophosphoryl difluoride
共188 –258兲
difluorophosphoryl azide
F3 N3 P3
trimeric phosphonitrilic fluoride
32.6
F2 HPS
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
36.1
共245兲
T
关67/36兴
29.1
共223兲
T
关67/36兴
36.4
共296兲
关72/23兴
ENTHALPIES OF VAPORIZATION
833
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
F4 N4 P4
tetrameric phosphonitrilic fluoride
F6 NP3
tris共difluorophosphino兲amine
PH3
phosphine
F5 P
Pb
C2 H8 Pb
C3 H10Pb
C4 H12Pb
C5 H9 F5 Pb
C8 H20Pb
phosphorous pentafluoride
共179–189兲
dimethylplumbane
共173–223兲
trimethylplumbane
共193–243兲
tetramethyllead
共298 –308兲
共pentafluoroethyl兲trimethyllead
共295–329兲
tetraethyllead
共311– 456兲
共273–343兲
共351– 423兲
Pr
C33H57O6 Pr
Re
C10O10MnRe
C10O10 Re2
Ru
C5 O5 Ru
C10H10Ru
S
Br2 OS
Br2 S2
Br2 FO2 S
ClF2 NO2 S
ClFOS
ClFO2 S
ClFO5 S2
ClHO3 S
Cl2 OS
Cl2 O2 S
Cl2 O5 S2
Cl2 S
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
ruthenium pentacarbonyl
共243–323兲
ruthenocene
共479–544兲
thionyl bromide
共313– 439兲
disulfur dibromide
共365–503兲
sulfuryl bromide fluoride
共236 –333兲
difluoroamidosulfuryl chloride
共232–290兲
thionyl chloride fluoride
共212–304兲
sulfuryl chloride fluoride
共211–300兲
pyrosulfuryl chloride fluoride
共284 –396兲
chlorosulfonic acid
共324 – 454兲
thionyl chloride
共257–372兲
sulfuryl chloride
共357–365兲
pyrosulfuryl dichloride
共325– 450兲
sulfur chloride
共265–348兲
CAS registry number
Reference
32.1
关58/27兴
37.3
关58/27兴
31.2
关75/38兴
关7803-51-2兴
关39/5兴
关37/15兴
关7647-19-0兴
关37/16兴
14.6⫾0.1
14.6
共186兲
共185兲
17.2
共184兲
25.5
共198兲
关60/26兴
31.1
共218兲
38.1⫾0.4
35.7
共303兲
关60/26兴
关75-74-1兴
关59/17兴关82/15兴
关29/6兴
39.1
共312兲
T
56.6⫾1.0
57.3
56.9⫾2.5
56.3
56.7
共298兲
共326兲
C
QM
共308兲
共387兲
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲praseodymium共III兲
共495–530兲
109.2
manganese rhenium decacarbonyl
共440– 463兲
dirhenium decacarbonyl
共454 – 483兲
Method
BG
56.5
共451兲
68.7
共468兲
42.2
共283兲
53.6⫾1.4
共511兲
43.6
共330兲
53.9
共380兲
32.0
共251兲
31.2
共261兲
27.7
共227兲
29.0
共226兲
40.8
共299兲
45.8
共339兲
32.4
共272兲
34.5
共272兲
44.7
共340兲
43.8
共280兲
关60/11兴
关78-00-2兴
关80/4兴
关47/5兴
关56/22兴关82/15兴
关36/9兴
关35/7兴
关15492-48-5兴
关69/28兴
关14693-30-2兴
关71/14兴
关14285-68-8兴
关71/14兴
关91/16兴
关1287-13-4兴
关84/11兴
关507-16-4兴
关99/16兴
关13172-31-1兴
关99/16兴
关13536-61-3兴
关99/16兴
关71/19兴
关14177-25-4兴
关99/16兴
关13637-84-8兴
关99/16兴
关13637-85-9兴
关99/16兴
关7790-94-5兴
关99/16兴
关7719-09-7兴
关99/16兴
关7791-25-5兴
关99/16兴
关7791-27-7兴
关99/16兴
关10545-99-0兴
关99/16兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
834
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
Cl2 S2
FHO3 S
FNS
F2 HPS
F2 N2 S
F2 OS
F2 O2 S
F2 O4 S
F2 O5 S2
F2 O8 S3
F2 S2
F3 NO3 S
F3 NS
F3 NS
F4 OS
F4 O5 S2
F4 S
F6 O3 S2
F10O2 S2
F10S2
F14O2 S3
F10O2 S2
H2 S
H2 S2
H2 S3
H2 S4
H2 S5
SO2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
disulfur dichloride
共306 – 439兲
41.1
共321兲
fluorosulfonic acid
共343– 459兲
55.7
共358兲
thiazyl fluoride
共270–299兲
21.7
共285兲
hydrothiophosphoryl difluoride
共188 –258兲
29.1
共223兲
dinitrogen sulfur difluoride
共192–281兲
23.9
共207兲
thionyl fluoride
共173–244兲
23.7
共188兲
sulfuryl fluoride
共160–233兲
20.0
共175兲
peroxysulfuryl difluoride
共198 –248兲
25.7
共223兲
pyrosulfuryl difluoride
共240–346兲
31.4
共255兲
trisulfur octoxide difluoride
共296 – 419兲
40.7
共311兲
disulfur difluoride
共153–196兲
14.9
共168兲
N,N-difluorohydroxylamine-O-fluorosulfonate
共206 –272兲
24.6
共239兲
N-fluorosulfur difluoride amide
共213–246兲
24.1
共230兲
nitrogen fluoride sulfide
共184 –268兲
23.1
共199兲
sulfur oxide tetrafluoride
共166 –240兲
21.4
共181兲
disulfur pentoxide tetrafluoride
共246 –353兲
18.0
共261兲
sulfur tetrafluoride
共170–250兲
21.1
共185兲
共160–224兲
24.6
共192兲
pentafluorosulfur fluorosulfane
共228 –273兲
32.2
共250兲
thiosulfuryl decafluoride
共239–344兲
31.8
共242兲
disulfur decafluoride
共226 –322兲
30.1
共241兲
共222–273兲
29.6
共237兲
bis共pentafluorosulfato兲tetrafluoro sulfur (SF5 OSF4 OSF5 )
33.4
共pentafluorosulfato兲tetrafluoro sulfur peroxide (SF5 OSF4 OOSF4 OSF5 )
47.5
hydrogen sulfide
共185–228兲
19.5
共200兲
共228 –363兲
18.6
共243兲
dihydrogen disulfide
共256 –367兲
34.0
共271兲
33.8⫾0.1
共293兲
dihydrogen trisulfide
共328 – 474兲
43.1
共343兲
45.5⫾0.2
共293兲
dihydrogen tetrasulfide
共384 –547兲
52.2
共399兲
56.8⫾0.3
共293兲
dihydrogen pentasulfide
共426 –592兲
61.5
共441兲
68.4⫾0.6
共293兲
sulfur dioxide
共200–263兲
24.9
共263兲
24.9
共263兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
CAS registry number
Reference
关10025-67-9兴
关99/16兴
关7789-21-1兴
关99/16兴
关18820-63-8兴
关99/16兴
T
关67/36兴
关500010-01-5兴
关99/16兴
关7783-42-8兴
关99/16兴
关2699-79-8兴
关99/16兴
关75/40兴
关13036-75-4兴
关99/16兴
关13709-33-6兴
关99/16兴
关16860-99-4兴
关99/16兴
关63/28兴
关69/26兴
关15930-75-3兴
关99/16兴
关13809-54-1兴
关99/16兴
关44982-62-9兴
关99/16兴
关7783-60-0兴
关99/16兴
关55/16兴
关62/36兴
关12395-41-4兴
关99/16兴
关5714-22-7兴
关99/16兴
关62/36兴
关108021-40-5兴
关63/45兴
C
C
C
C
C
关63/45兴
关7783-06-4兴
关99/16兴
关99/16兴
关13465-07-1兴
关99/16兴
关58/14兴
关13845-23-3兴
关99/16兴
关58/14兴
关13465-25-5兴
关99/16兴
关58/14兴
关13465-24-4兴
关99/16兴
关58/14兴
关7446-09-5兴
关38/11兴
关38/11兴
ENTHALPIES OF VAPORIZATION
835
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
SO3
Sb
CH5 Sb
C2 H7 Sb
C2 H8 BSb
C3 Cl2 F9 Sb
C3 F9 Sb
C3 H9 Sb
C4 H12Sb2
C6 H9 Sb
C6 H15Sb
C18H15Sb
Sc
C15H12F9 O6 Sc
Compound
共Temperature range/K兲
sulfur trioxide
共290–318兲
共290–318兲
共353– 473兲
46.7
45.5⫾0.8
32.4
共290兲
共298兲
共368兲
tris共1,1,1-trifluoro-2,4-pentanedionato兲scandium共III兲
共397– 457兲
82.2⫾0.8
trifluoromethylselenyl bromide
CClF3 Se
trifluoromethylselenyl chloride
COSe
carbon oxyselenide
共221–252兲
共156 –251兲
CSe2
Mean temperature
(T m /K)
methylstibine
共223–273兲
27.4
dimethylstibine
共241–273兲
30.8
dimethylstibinoborine
共234 –273兲
32.1
tris共trifluoromethyl兲antimony dichloride
共243–323兲
38.8
tris共trifluoromethyl兲stibine
共215–343兲
34.7
trimethylstibine
28.9⫾1.3
31.2
tetramethylbistibine
共325–358兲
46.9
trivinylstibine
共293–363兲
38.7
triethylstibine
共193–333兲
39.9⫾1.3
43.5⫾4.2
41.8
triphenylantimony
共503–553兲
83.3
Se
CBrF3 Se
CSSe
⌬ vapH m
共kJ mol⫺1兲
carbon selenide sulfide
共226 –359兲
共273–357兲
carbon diselenide
共230–290兲
共290–337兲
CHF3 Se
共273–323兲
trifluoromethaneselenol
CH3 FO3 Se
fluoroselenic acid, methyl ester
C2 BrF5 Se
C2 ClF5 Se
C2 F3 NOSe
C2 F3 NSSe
C2 F3 NSSe
CAS registry number
Reference
关7446-11-9兴
关85/14兴
关85/14兴
关63/43兴
共257兲
关23362-09-6兴
关59/6兴
关23362-10-9兴
关59/6兴
共254兲
关59/6兴
共283兲
关57/28兴
共279兲
关57/28兴
关594-10-5兴
关55/15兴关82/15兴
关46/13兴
共248兲
BG
共341兲
共308兲
共306兲
BG
共518兲
共427兲
A
关59/6兴
关5613-68-3兴
关57/15兴关84/9兴
关617-85-6兴
关01/9兴
关63/37兴关82/15兴
关46/13兴
关603-36-1兴
关87/5兴
关14634-68-5兴
关78/11兴
30.9
关80/22兴
27.6
关80/22兴
关1603-84-5兴
关99/16兴
关47/5兴
关37/12兴
关5951-19-9兴
关99/16兴
关14/1兴关84/9兴
关506-80-9兴
关99/16兴
关99/16兴
关66/26兴关82/15兴
关47/2兴关84/9兴
关55446-31-6兴
关80/22兴
关17697-13-1兴
关67/41兴
22.1
21.7
22.1
共236兲
共236兲
共211兲
35.5
33.6
共241兲
共288兲
39.1
35.9
37.2⫾0.8
39.0
共245兲
共305兲
共288兲
22.5
CH3 F3 SeSi
Method
46.9
silyl trifluoromethyl selenide
共213–277兲
28.0
共pentafluoroethane兲 selenyl bromide
共242–293兲
34.5
共pentafluoroethane兲 selenyl chloride
共215–289兲
30.3
trifluoromethyl selenium isocyanate
共233–284兲
29.5
trifluoromethyl selenium thiocyanate
共233–383兲
25.9
trifluoromethane sulphenyl selenocyanate
共263–313兲
33.3
共245兲
共258兲
关62/31兴
关6123-59-7兴
关99/16兴
关6123-50-8兴
关99/16兴
关20334-48-9兴
关68/18兴
关21438-06-2兴
关68/18兴
共288兲
关63/42兴
共267兲
共252兲
共259兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
836
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C2 F3 NSe
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
CF6 Se
CF6 Se2
C2 H3 F3 Se
C2 H6 Se
C2 H6 Se2
C3 AsF9 Se
C3 BrF7 Se
C3 ClF7 Se
C3 F5 NSe
C3 H2 F6 Se2
C3 H3 F5 Se
C3 H3 F7 SeSi
C3 H4 F5 NSe
C3 H5 FOSe
C3 H5 F3 Se
C3 H6 F3 NSe
C4 F10Se
C4 F10Se2
C4 HF10NSe2
C4 H3 F7 Se
C4 H4 Se
C4 H5 F5 Se
C4 H6 F5 NSe
C4 H6 Se
C4 H8 OSe
C4 H10Se
Method
trifluoromethyl selenocyanate
37.9
37.6
C2 F3 NSe2
Mean temperature
(T m /K)
共233–273兲
trifluoromethyl selenium selenocyanate
共223–268兲
26.6
bis共trifluoromethyl兲selenide
24.4
bis共difluoromethyl兲 diselenide
33.1
methyl共trifluoromethyl兲selenide
共209–294兲
27.7
dimethyl selenide
共280–318兲
30.3⫾0.1
共278 –313兲
31.9
dimethyl diselenide
共288 –313兲
74.9
42.0⫾1.0
bis共trifluoromethyl兲 trifluoromethylselenoarsine
共227–295兲
34.8
共heptafluoro-1-propane兲 selenyl bromide
共251–298兲
35.0
共heptafluoro-1-propane兲 selenyl chloride
共223–289兲
33.4
pentafluoroethyl selenocyanate
共254 –293兲
32.0
bis关共trifluoromethyl兲seleno兴methane
共273–359兲
35.4
methyl pentafluoroethyl selenide
共234 –286兲
31.9
共heptafluoropropyl兲selenyl silane
共233–393兲
33.1
共pentafluoroethyl兲seleno methylamine
共243–318兲
33.8
fluoroselenoacetic acid, Se-methyl ester
共273–333兲
46.3
ethyl共trifluoromethyl兲selenide
共223–254兲
31.6
N,N-dimethyl共trifluoromethyl兲selenenamide
共231–321兲
28.1
bis共pentafluoroethyl兲selenide
共232–295兲
31.6
bis共pentafluoroethyl兲 diselenide
共272–318兲
40.0
bis关共pentafluoroethyl兲seleno兴amine
共270–322兲
38.3
methyl共heptafluoropropyl兲 selenide
共232–324兲
30.8
selenophene
共234 –300兲
40.8
38.1⫾0.7
共234 –387兲
34.0
ethyl共pentafluoroethyl兲 selenide
共241–311兲
34.8
1,1,2,2,2-pentafluoro-N,N-dimethylethane selenamide
共256 –320兲
34.8
divinyl selenide
42.0⫾1.0
1,4-oxaselenane
共352– 429兲
46.6
diethyl selenide
共243–381兲
39.7
38.9⫾1.0
38.9⫾4.2
共298 –308兲
36.8
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共253兲
共245兲
共251兲
共295兲
共295兲
I
共300兲
共298兲
I
C
共261兲
共256兲
共273兲
共315兲
共260兲
共263兲
共280兲
共303兲
共238兲
共276兲
共263兲
共295兲
共296兲
共278兲
C
共276兲
共288兲
共298兲
C
共367兲
共258兲
共298兲
共303兲
关1717-4903兴
关80/22兴
关68/18兴
关20563-91-1兴
关68/18兴
关371-79-9兴
关80/22兴
关372-65-6兴
关80/22兴
关1544-45-2兴
关99/16兴关63/41兴
关593-79-3兴
关99/16兴关97/30兴
关94/9兴
关7101-31-7兴
关94/9兴
关89/12兴
关62/32兴
关662-44-2兴
关99/16兴关63/41兴
关662-46-4兴
关99/16兴关63/41兴
关20334-51-4兴
关68/18兴
关691-25-8兴
关99/16兴关63/41兴
关6123-56-4兴
关99/16兴
关1647-59-2兴
关99/16兴关62/31兴
关6123-53-1兴
关99/16兴
关367-52-2兴
关99/16兴
关690-25-5兴
关99/16兴关63/41兴
共274兲
共272兲
共298兲
共249兲
CAS registry number
Reference
C
关63/41兴
关6123-61-1兴
关99/16兴
关6123-49-5兴
关99/16兴
关6123-55-3兴
关99/16兴
关662-45-3兴
关99/16兴关63/41兴
关288-05-1兴
关99/16兴
关89/12兴
关47/5兴
关6123-57-5兴
关99/16兴
关6123-52-0兴
关99/16兴
关57796-75-5兴
关89/12兴
关5368-46-7兴
关99/16兴
关627-53-2兴
关99/16兴
关89/12兴
关36/5兴关82/15兴
关29/6兴
ENTHALPIES OF VAPORIZATION
837
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C4 H10Se2
C5 AsF13Se
C5 H3 F10NSe2
C5 H5 F7 Se
C5 H6 F7 NSe
C6 F14Se
C6 F14Se2
C6 H6 Se
C6 H14Se
C7 H8 Se
C8 H18Se
C10H22Se
C12H10Se
Cl2 OSe
D2 Se
F2 OSe
F4 Se
F6 O2 Se
Si
CH2 Cl4 OSi
CH3 Cl3 Si
CH4 Cl2 Si
CH4 Cl2 Si
CH5 ClSi
CH5 BrSi
CH6 OSi
CH8 Si2
C2 H3 Cl3 Si
C2 H3 Cl5 Si
C2 H4 Cl6 Si2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
共298兲
C
关628-39-7兴
关89/12兴
diethyl diselenide
47.1⫾0.9
heptafluoropropylseleno bis共trifluoromethyl兲arsine
共277–348兲
40.3
N,N-bis关共pentafluoroethyl兲seleno兴methylamine
共282–324兲
38.3
ethyl共heptafluoropropyl兲 selenide
共243–333兲
36.0
N,N-dimethyl共heptafluoropropyl兲selenenamide
共228 –321兲
30.8
bis共heptafluoropropyl兲 selenide
共228 –343兲
34.5
bis共heptafluoropropyl兲 diselenide
共260–348兲
37.7
benzene selenol
共331– 458兲
45.4
diisopropyl selenide
43.1⫾1.0
methyl phenyl selenide
共273–291兲
52.5
dibutyl selenide
47.3⫾1.0
dipentyl selenide
51.9⫾1.0
diphenyl selenide
共379–575兲
63.4
共378 –575兲
61.9
63.6⫾2.5
selenium oxychloride
共352– 476兲
59.1
共353– 453兲
46.9
hydrogen selenide—d2
共202–256兲
22.2
seleninyl difluoride
共316 – 420兲
52.1
46.9⫾0.8
selenium tetrafluoride
共297–398兲
46.4
trans bis共fluoroxy兲 tetrafluoroselenium
共241–286兲
26.5
chloromethoxytrichlorosilane
共273–323兲
methyltrichlorosilane
共328 –358兲
共287–337兲
共dichloromethyl兲silane
共283–319兲
methyldichlorosilane
共275–314兲
共chloromethyl兲silane
共246 –297兲
methylbromosilane
共283–295兲
methoxysilane
共184 –216兲
methyldisilane
共190–273兲
trichlorovinylsilane
共291–356兲
1,2-dichloroethyltrichlorosilane
共375– 453兲
bis共trichlorosilyl兲ethane
共312兲
关62/32兴
关6123-54-2兴
关99/16兴
关755-44-2兴
关99/16兴关63/41兴
共303兲
共288兲
共274兲
共312兲
关63/41兴
关755-81-7兴
关99/16兴关63/41兴
关755-51-1兴
关99/16兴关63/41兴
关645-96-5兴
关99/16兴
关37773-02-7兴
关89/12兴
关4346-64-9兴
关99/16兴
关14835-66-6兴
关89/12兴
关14835-67-7兴
关89/12兴
关1132-39-4兴
关99/16兴
关87/5兴
关73/33兴关82/15兴
关7791-23-3兴
关99/16兴
关71/24兴
关13536-95-3兴
关99/16兴
关7783-43-9兴
关99/16兴
关79/27兴
关13465-66-2兴
关99/16兴
共263兲
关70/13兴
9.3
共288兲
30.7
31.2
31.0⫾2.1
共343兲
共302兲
关58/3兴
关75-79-6兴
关67/26兴
关54/1兴
关69/30兴关82/15兴
32.5
共301兲
28.3
共290兲
27.5
共271兲
关57/27兴
28.5
共289兲
25.8
共201兲
26.8
共231兲
T
34.2
共306兲
I
45.7
共390兲
I
关58/24兴
关2171-96-2兴
关61/5兴
关13498-43-6兴
关66/16兴
关75-94-5兴
关54/1兴
关684-00-4兴
关54/1兴
共286兲
共304兲
共395兲
共298兲
C
共282兲
共298兲
C
共298兲
C
共394兲
共393兲
A
共367兲
共403兲
共217兲
共331兲
共298兲
C
I
I
关57/27兴
关75-54-7兴
关54/1兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
838
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C2 H4 Si
C2 H5 Cl3 Si
C2 H5 F3 OSi
C2 H6 Cl2 Si
C2 H6 Cl2 Si
C2 H6 Cl4 Si2
C2 H6 F3 NSi
C2 H10Si2
C2 H11NSi2
C3 H4 Cl3 NSi
C3 H5 Cl3 Si
C3 H6 Cl4 Si
C3 H6 Cl4 Si
C3 H8 Cl2 OSi
C3 H9 BrSi
C3 H9 ClSi
C3 H10OSi
C3 H11NSi
C3 H13NSi2
C3 H15NSi3
C4 H8 Cl6 SSi2
C4 H8 Cl2 Si
C4 H9 F6 NSi2
C4 H10Cl2 Si
C4 H10F3 NSi
C4 H10F3 NSi
C4 H10Si
C4 H12Si
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
共364 – 432兲
48.6
silylacetylene
共215–251兲
22.0
trichloroethylsilane
共303–363兲
35.1
共301–368兲
35.9
ethoxytrifluorosilane
共206 –248兲
26.8
dichlorodimethylsilane
共301–345兲
31.5
dichloroethylsilane
共279–346兲
31.5
共301–345兲
31.6
1,1,2,2-tetrachloro-1,2-dimethyldisilane
共300–375兲
42.4
1,1,1-trifluoro-N,N-dimethylaminosilane
共225–288兲
28.5
1,2-dimethyldisilane
共227–273兲
25.4
N,N-dimethyldisilanylamine
共207–273兲
35.4
trichloro-␤-cyanoethylsilane
共343– 443兲
53.5
allyltrichlorosilane
共319–388兲
40.1
␥-chloropropyltrichlorosilane
共313– 443兲
49.7
共360– 452兲
46.4
␤-chloropropyltrichlorosilane
共313– 443兲
46.9
dichloroethoxymethylsilane
共239–373兲
38.0
bromotrimethylsilane
32.6⫾2.1
chlorotrimethylsilane
共274 –325兲
30.8
共276 –329兲
30.2
30.1⫾1.7
trimethylsilanol
共291–357兲
46.8
45.6⫾1.7
共291–358兲
44.2
N,N-dimethyl共methylsilyl兲amine
共273–317兲
28.2
N-methyldi共methylsilyl兲amine
共303–351兲
32.2
tri共methylsilyl兲amine
共323–378兲
33.7
2,5-bis共trichlorosilyl兲thiophene
共374 –519兲
55.6
dichloroethylvinylsilane
共318 –395兲
38.1
1,1,1-trifluoro-N-共1-methylpropyl兲-N-共trifluorosilyl兲silanamine
共193–233兲
25.8
dichlorodiethylsilane
共321– 401兲
39.2
共N,N-diethylamino兲trifluorosilane
共208 –274兲
27.4
共N-tert-butylamino兲trifluorosilane
共208 –250兲
33.6
1-methylsilacyclobutane
25.1
diethylsilane
30.0⫾0.4
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共379兲
Method
CAS registry number
Reference
I
关54/1兴
I
关63/39兴
关115-21-9兴
关70/37兴
关54/1兴
共233兲
共318兲
共316兲
共227兲
共316兲
I
共294兲
共316兲
I
关49/26兴
关75-78-5兴
关54/1兴
关1789-58-8兴
关54/1兴
关54/4兴
共337兲
关67/23兴
共273兲
关61/4兴
关870-26-8兴
关62/6兴
共258兲
共240兲
T
共358兲
共333兲
I
共328兲
共375兲
I
关63/30兴
关78/12兴
关107-37-9兴
关54/1兴
关2550-06-3兴
关72/14兴
关54/1兴
共328兲
关72/14兴
共254兲
关47/5兴
关2857-97-8兴
关67/34兴关82/15兴
关75-77-4兴
关64/8兴
关54/1兴
关67/34兴关82/15兴
关1066-40-6兴
关87/5兴
关69/30兴关82/15兴
关53/15兴
共289兲
共291兲
共306兲
A
共324兲
I
共296兲
关58/24兴
共327兲
关58/24兴
共350兲
关58/24兴
共388兲
关81/24兴
关10138-21-3兴
关54/1兴
关28245-41-2兴
关73/30兴
关1719-53-5兴
关54/1兴
关28245-37-6兴
关74/34兴
关28245-40-1兴
关73/34兴
关765-33-3兴
关91/4兴
关542-91-6兴
关72/30兴关82/15兴
共333兲
I
共213兲
共336兲
I
共241兲
共229兲
共298兲
C
ENTHALPIES OF VAPORIZATION
839
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C4 H12Cl2 OSi2
C4 H12O3 Si
C4 H12O4 Si
C4 H12Si
C4 H13NSi
C4 H14N2 Si
C4 H16N2 Si2
C5 H6 Cl2 SSi2
C5 H9 F6 NOSSi
C5 H10F3 NSi
C5 H12Si
C5 H12Si
C5 H12Si
C5 H14OSi
C5 H14O3 SSi
C5 H14Si
C5 H15NSi
C5 H20O5 Si5
C6 H4 Cl4 Si
C6 H4 Cl4 Si
C6 H5 Cl3 Si
C6 H5 F3 Si
C6 H8 Cl4 SSi2
C6 H9 F6 NSi
C6 H10Cl2 Si
Compound
共Temperature range/K兲
1,3-dichlorotetramethyldisiloxane
共303– 403兲
methyltrimethoxysilane
tetramethoxysilane
共364 –393兲
共309–394兲
tetramethylsilane
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
40.3
共318兲
34.3⫾0.6
34.3⫾0.3
共298兲
共298兲
C
EB
38.0
41.4⫾0.7
41.4⫾0.2
41.0
共379兲
共298兲
共298兲
共324兲
EB
C
EB
26.0⫾0.6
26.2⫾0.4
24.2⫾0.1
共298兲
C
共299兲
C
37.4⫾0.8
36.0⫾2.1
共298兲
C
Method
N,1,1,1-tetramethylsilanamine
bis共dimethylamino兲silane
共288 –344兲
32.4
共316兲
N,N,N⬘,N⬘-tetramethyldisilanylamine
共311–354兲
39.3
共332兲
2-共methyldichlorosilyl兲thiophene
共341– 467兲
46.4
共356兲
S,S-bis共trifluoromethyl兲-N-共trimethylsilyl兲sulfoximine
33.5
共378兲
1-共trifluorosilyl兲piperidine
共250–282兲
33.9
共266兲
1,2-dimethylsilacyclobutane
33.1
共298兲
1,1-dimethylsilacyclobutane
32.1
共356兲
33.0⫾0.8
共298兲
34.7⫾2.1
vinyltrimethylsilane
33.1⫾0.6
共298兲
ethoxytrimethylsilane
38.4⫾0.6
共298兲
38.4⫾0.3
共298兲
共223–349兲
35.1
共238兲
trimethoxy关共methylthio兲methyl兴silane
40.2⫾0.6
共298兲
methyldiethylsilane
34.6⫾0.7
共298兲
pentamethylsilanamine
33.6⫾0.8
共298兲
31.8⫾1.7
共313–357兲
31.7
共335兲
1,3,5,7,9-pentamethylcyclopentasiloxane
47.0⫾0.9
共298兲
共2-chlorophenyl兲trichlorosilane
共406 – 472兲
52.1
共439兲
共3-chlorophenyl兲trichlorosilane
共398 – 463兲
50.7
共430兲
phenyl trichlorosilane
共333– 453兲
51.1
共348兲
共375– 470兲
47.9
共390兲
trifluorophenylsilane
共242–371兲
40.1
共257兲
2,5-bis共methyldichlorosilyl兲thiophene
共405–522兲
55.7
共420兲
1,1,1-trimethyl-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-silanamine
30.5
共358兲
diallydichlorosilane
共254 –390兲
47.9
共269兲
CAS registry number
Reference
关2401-73-2兴
关71/11兴
关1185-55-3兴
关88/15兴
关85/13兴
关681-84-5兴
关89/5兴
关88/15兴
关85/13兴
关80/15兴
关75-76-3兴
关88/15兴
关72/30兴关82/15兴
关41/5兴
关16513-17-0兴
关91/6兴
关67/34兴关82/15兴
T
关64/29兴
T
关63/30兴
I
关81/24兴
关34556-30-4兴
关72/25兴
关33552-49-7兴
关73/34兴
C
I
C
C
EB
C
C
C
C
EB
EB
I
I
关91/4兴
关2295-12-7兴
关75/31兴
关74/22兴
关72/30兴关82/15兴
关754-05-2兴
关88/15兴
关1825-62-3兴
关88/15兴
关85/13兴
关47/5兴
关57557-66-1兴
关89/11兴
关760-32-7兴
关88/15兴
关2083-91-2兴
关91/6兴
关67/34兴关82/15兴
关58/24兴
关6166-86-5兴
关91/5兴
关2003-90-9兴
关74/22兴
关2003-89-6兴
关74/22兴
关98-13-5兴
关70/37兴
关54/1兴
关368-47-8兴
关47/5兴
关81/24兴
关17599-55-2兴
关72/24兴
关47/5兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
840
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C6 H11NSi2
C6 H12Si2
C6 H12Si
C6 H14Si
C6 H14Si
C6 H14Si
C6 H15ClSi
C6 H15FO3 Si
C6 H15NOSi2
C6 H16OSi
C6 H16OSi
C6 H16OSi
C6 H16O2 Si
C6 H16O3 SSi
C6 H16O3 SSi
C6 H16Si
C6 H16Si
C6 H16Si2
C6 H17B5 Br2 Si2
C6 H17B5 Cl2 Si2
C6 H18Cl2 O2 Si3
C6 H18OSi2
C6 H18O3 Si3
C6 H18Si2
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
N-phenyldisilazane
共298 –356兲
34.9
1,1,3,3-tetramethyl-1,3-disilacyclobutane
39.5
1-methyl-1-vinylsilacyclobutane
33.1
1,1,2-trimethylsilacyclobutane
36.0
1,1-dimethylsilacyclopentane
37.7⫾2.1
1,1,3-trimethylsilacyclobutane
35.5
chlorotriethylsilane
共268 – 419兲
42.9
triethoxyfluorosilane
共291–373兲
40.3
pentamethyldisilanyl isocyanate
共320–377兲
44.2
propoxytrimethylsilane
34.3⫾0.6
34.3⫾0.3
isopropoxytrimethylsilane
31.8⫾0.6
31.8⫾0.4
triethylsilanol
共298 – 413兲
50.6
diethoxydimethylsilane
43.1⫾0.7
43.1⫾0.3
共254 –386兲
43.3
trimethoxy关2-共methylthio兲ethyl兴silane
45.2⫾0.7
关共ethylthio兲methyl兴trimethoxysilane
41.4⫾0.6
dimethyldiethylsilane
38.9⫾0.6
triethylsilane
37.4⫾0.6
共303–373兲
33.5
36.4⫾1.3
1,1,3,3-tetramethyl-1,3-disilacyclobutane
36.7⫾1.1
41.0⫾2.1
2,4-bis共bromodimethylsilyl兲-2,4-dicarbo-closo-heptaborane 共7兲
共388 – 463兲
53.1
2,4-bis共chlorodimethylsilyl兲-2,4-dicarbo-closo-heptaborane 共7兲
共359– 439兲
46.2
1,5-dichlorohexamethyltrisiloxane
共299– 457兲
49.8
hexamethyldisiloxane
共300–383兲
36.9
共293–361兲
33.1
37.2⫾1.7
共309– 411兲
36.0
34.6⫾0.1
33.1⫾0.1
31.3⫾0.1
37.2⫾1.7
hexamethylcyclotrisiloxane
共342– 419兲
40.8
共353– 403兲
39.7
共339– 407兲
39.0
共343–388兲
39.7
hexamethyldisilane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
共327兲
Method
CAS registry number
Reference
T
关69/33兴
关1627-98-1兴
关75/31兴
共298兲
C
共298兲
C
关91/4兴
关30681-90-4兴
关91/4兴
共391兲
共298兲
C
关72/30兴关82/15兴
关2295-13-8兴
关91/4兴
关994-30-9兴
关47/5兴
I
关49/26兴
共419兲
共332兲
共348兲
共298兲
共298兲
C
C
共298兲
共298兲
C
EB
共355兲
I
共298兲
共298兲
共269兲
C
EB
共298兲
C
共298兲
C
共298兲
C
共298兲
C
EB, I
共298兲
I
共403兲
I
共374兲
I
共314兲
共315兲
共327兲
EB
共324兲
共332兲
共351兲
共373兲
EB
C
C
C
共357兲
共368兲
共373兲
共365兲
EB
关63/40兴
关1825-63-4兴
关88/15兴
关85/13兴
关1825-64-5兴
关88/15兴
关85/13兴
关597-52-4兴
关53/15兴
关78-62-6兴
关88/15兴
关85/13兴
关47/5兴
关66785-19-1兴
关89/11兴
关53696-79-0兴
关89/11兴
关756-81-0兴
关88/15兴
关617-86-7兴
关88/15兴
关75/34兴
关72/30兴关82/15兴
关1627-98-1兴
关74/23兴
关72/30兴关82/15兴
关66798-29-6兴
关79/25兴
关28699-83-4兴
关79/25兴
关47/5兴
关107-46-0兴
关86/4兴
关71/15兴
关64/26兴关82/15兴
关61/15兴
关61/15兴
关61/15兴
关61/15兴
关47/5兴
关541-05-9兴
关86/4兴
关74/18兴
关71/15兴
关53/20兴
关1450-14-2兴
ENTHALPIES OF VAPORIZATION
841
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
Compound
共Temperature range/K兲
共305–387兲
C6 H19B5 Si2
C6 H19NSi2
C6 H19N3 Si
C6 H21N3 Si3
C7 H8 Cl2 Si
C7 H8 Cl2 Si
C7 H8 Cl2 Si
C7 H8 F2 Si
C7 H9 F8 NOSSi
C7 H9 F9 N2 OSSi
C7 H16O3 SSi
C7 H17ClSi
C7 H18OSi
C7 H18O3 SSi
C7 H18O3 SSi
C7 H18O3 Si
C7 H18SSi
C7 H18Si
C7 H18Si
C7 H18Si
C7 H19NSi
C7 H20Si2
C7 H21NSi2
C8 H10Cl2 OSi
C8 H10Cl2 Si
C8 H11ClSi
C8 H11FSi
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
36.3
共320兲
EB
37.4⫾0.4
共288 –310兲
37.2
共294 –334兲
36.8
2,4-bis共dimethylsilyl兲-2,4-dicarba-closo-heptaborane
共373– 453兲
41.3
共388兲
I
hexamethyldisilazane
42.2⫾0.9
共298兲
C
共294 –395兲
36.0
共344兲
41.4⫾2.1
tris共dimethylamino兲silane
共309–387兲
41.1
共348兲
T
hexamethylcyclotrisilazane
共342– 456兲
45.6
共399兲
benzyl dichlorosilane
共318 – 467兲
58.5
共333兲
phenyldichloromethylsilane
共309– 479兲
51.2
共323兲
dichloro-4-tolylsilane
共319– 469兲
58.0
共334兲
difluoromethylphenylsilane
共303– 413兲
44.6
共318兲
2,2,3,3,4,4,5,5-octafluoro-1,1,2,3,4,5-hexahydro-1-关共trifluoromethyl兲-silyl兴imino兴thiophene-1-oxide
31.4
共383兲
1,1,1-trifluoro-N-关2,2,2-trifluoro-1-共trifluoromethyl兲ethylidene兴-N⬘-共trimethylsilyl兲methanesulfonimidamide
39.3
共429兲
I
trimethoxy关共2-propenylthio兲methyl兴silane
38.6⫾0.5
共298兲
C
共1-chloroethyl兲diethylmethylsilane
共353– 445兲
41.8
共400兲
butyl trimethylsilyl ether
共344 –397兲
38.5
共359兲
EB
trimethoxy关3-共methylthio兲propyl兴silane
43.5⫾0.6
共298兲
C
关2-共ethylthio兲ethyl兴trimethoxysilane
41.4⫾0.7
共298兲
C
triethoxymethylsilane
45.1⫾0.7
共298兲
C
45.1⫾0.4
共298兲
EB
共272– 416兲
45.2
共287兲
共n-butylthio兲trimethylsilane
40.6⫾2.1
methyltriethylsilane
40.5⫾0.6
共298兲
C
methyldipropylsilane
35.9⫾0.7
共298兲
C
methyldiisopropylsilane
32.4⫾0.8
共298兲
C
N,N-diethyl-1,1,1-trimethylsilanamine
37.9⫾0.8
共298兲
C
methylene-bis共trimethylsilane兲
共323– 407兲
40.3⫾0.3
QM
共323– 407兲
40.3⫾0.3
共365兲
N,1,1,1-tetramethyl-N-共trimethylsilyl兲silanamine
38.1⫾0.8
共298兲
C
38.9⫾2.1
dichloroethoxyphenylsilane
共325– 496兲
56.3
共340兲
dichloroethylphenylsilane
共316 –503兲
51.3
共331兲
chlorodimethylphenylsilane
共302– 467兲
52.2
共317兲
共303– 466兲
49.7
共318兲
fluorodimethylphenylsilane
CAS registry number
Reference
关86/12兴
关72/30兴关82/15兴
关59/26兴关86/12兴
关41/12兴关86/12兴
关59351-11-0兴
关76/17兴
关999-97-3兴
关91/6兴
关72/19兴
关66/22兴关82/15兴
关64/29兴
关1009-93-4兴
关72/19兴
关18173-99-4兴
关47/5兴关99/16兴
关149-74-6兴
关47/5兴关99/16兴
关13272-80-5兴
关47/5兴关99/16兴
关328-57-4兴
关99/16兴
关77589-40-3兴
关81/16兴
关62609-67-0兴
关77/19兴关99/16兴
关57877-58-4兴
关89/11兴
关18817-17-9兴
关99/16兴
关1825-65-6兴
关69/13兴关84/9兴
关94358-36-8兴
关89/11兴
关40532-52-3兴
关89/11兴
关2031-67-6兴
关88/15兴
关85/13兴
关47/5兴
关67/34兴关82/15兴
关757-21-1兴
关88/15兴
关999-03-1兴
关88/15兴
关18442-00-7兴
关88/15兴
关996-50-9兴
关91/6兴
关2117-28-4兴
关76/25兴
关75/25兴关75/31兴
关920-68-3兴
关91/6兴
关67/34兴关82/15兴
关18236-80-1兴
关99/16兴
关1125-27-5兴
关99/16兴
关768-33-2兴
关99/16兴
关47/5兴
关454-57-9兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
842
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C8 H12Si
C8 H12Si
C8 H16Cl4 O4 Si
C8 H18F3 NOSi2
C8 H18O3 Si
C8 H20Cl2 OSi2
C8 H20O3 SSi
C8 H20O3 SSi
C8 H20O3 SSi
C8 H20O3 SSi
C8 H20O3 Si
C8 H20O4 Si
C8 H20Si
C8 H20Si
C8 H20Si
C8 H20Si
C8 H21NO3 Si
C8 H23B5 Si2
C8 H24Si3
C8 H24Cl2 O3 Si4
C8 H24N4 Si
C8 H24O2 Si3
C8 H24O4 Si4
Compound
共Temperature range/K兲
共303– 423兲
tetravinylsilane
dimethylphenylsilane
共298 – 432兲
tetrakis共2-chloroethoxy兲silane
共447–500兲
CF3 C关OSi共CH) 3 ]⫽NSi共CH3 ) 3
共316 –350兲
vinyltriethoxysilane
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
49.6
共318兲
42.7⫾0.7
共298兲
45.3
共293兲
81.1
共473兲
41.8
共333兲
50.2⫾0.8
50.2⫾0.4
共334 – 421兲
46.2
1,3-dichloro-1,1,3,3-tetraethyldisiloxane
共343– 463兲
53.6
关3-共ethylthio兲propyl兴trimethoxysilane
41.8⫾0.6
关共butylthio兲methyl兴trimethoxysilane
41.6⫾0.6
trimethoxy关关共2-methylpropyl兲thio兴methyl兴silane
38.7⫾0.6
关关共1,1-dimethylethyl兲thio兴methyl兴trimethoxysilane
50.6⫾0.7
ethyltriethoxysilane
共338 – 426兲
47.0
tetraethoxysilane
共323– 442兲
53.9
共323– 442兲
52.3
共404 – 437兲
40.9
48.5⫾0.3
共313– 440兲
50.0
共273–344兲
U33.9
共289– 441兲
49.5
dimethyldipropylsilane
40.2⫾0.6
tetraethylsilane
39.0⫾0.7
39.7⫾2.1
共272– 426兲
43.3
ethyldipropylsilane
37.9⫾0.6
ethyldiisopropylsilane
38.1⫾0.7
␥-aminopropyltriethoxysilane
共363– 492兲
55.8
2,4-bis共trimethylsilyl兲-2,4-dicarba-closo-heptaborane
共373– 473兲
45.0
octamethyltrisilane
46.0⫾0.8
1,7-dichloro-1,1,3,3,5,5,7,7-octamethyltetrasiloxane
共326 – 495兲
53.8
tetrakis共dimethylamino兲silane
共361– 415兲
40.0
octamethyltrisiloxane
共346 – 446兲
43.2
39.7⫾2.1
共345– 417兲
40.2
octamethylcyclotetrasiloxane
57.0⫾0.8
共361– 469兲
47.6
共334 – 423兲
44.1
共303– 428兲
56.1
共303– 428兲
48.5
共303– 428兲
45.6
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Method
C
CAS registry number
Reference
关99/16兴
关1112-55-6兴
关88/15兴
关766-77-8兴
关47/5兴
关18290-84-1兴
关99/16兴关46/9兴
共298兲
C
共298兲
C
关70/27兴
关78-08-0兴
关88/15兴
关85/13兴
关54/1兴
关18825-03-1兴
关71/11兴关99/16兴
关57557-74-1兴
关89/11兴
关57557-68-3兴
关89/11兴
关57557-69-4兴
关89/11兴
关57557-70-7兴
关89/11兴
关78-07-9兴
关54/1兴
关78-10-4兴
关95/10兴
关95/10兴
关89/5兴
关85/13兴
关80/15兴
关73/16兴
关47/5兴
关995-89-1兴
关88/15兴
关631-36-7兴
关88/15兴
关72/30兴关82/15兴
关47/5兴
关998-14-1兴
关88/15兴
关17591-40-1兴
关88/15兴
I
关76/24兴
关59351-10-9兴
关76/17兴
共298兲
共298兲
共349兲
C
EB
I
共358兲
共298兲
C
共298兲
C
共298兲
C
共298兲
C
共353兲
I
共298兲
共298兲
共419兲
共298兲
共328兲
SG
SG
EB
EB
共304兲
共298兲
C
共298兲
C
共287兲
共388兲
共388兲
关72/30兴关82/15兴
关2474-02-4兴
关99/16兴
共341兲
共388兲
T
共361兲
EB
共381兲
共298兲
共376兲
共378兲
共298兲
共373兲
共398兲
C
EB
I
I
I
关64/29兴
关107-51-7兴
关86/4兴
关72/30兴关82/15兴
关71/16兴
关556-67-2兴
关91/5兴
关86/4兴
关71/15兴
关54/13兴
关54/13兴
关54/13兴
ENTHALPIES OF VAPORIZATION
843
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C8 H28N4 Si4
C9 H14OSi
C9 H20OSi
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
octamethylcyclotetrasilazane
共388 –513兲
phenoxytrimethylsilane
52.3
共450兲
56.9⫾0.8
共298兲
C
45.1
共379兲
EB
42.3⫾0.6
共298兲
C
40.0⫾0.7
共298兲
C
39.1⫾0.7
共298兲
C
共298兲
C
共298兲
C
共298兲
C
C9 H22O3 SSi
cyclohexyl trimethylsilyl ether
共364 – 441兲
triethoxy关共ethylthio兲methyl兴silane
C9 H22Si
propyltriethylsilane
C9 H22Si
tripropylsilane
C9 H22Si
methyldibutylsilane
C9 H23NSi
C9 H23NSi
C9 H24Si2
C9 H27NSi3
C10H11NSi4
C10H16OSi
C10H16OSi
C10H16OSi
C10H16OSi
C10H16OSi
C10H16O3 SSi
C10H20O2 Si
C10H24O2 Si
C10H24O3 SSi
C10H24Si
C10H24Si
C10H24Si
C10H24Si
C10H25NO2 Si3
C10H25NSi
C10H25NSi
C10H28O4 Si3
C10H30O3 Si4
C10H30O3 Si4
36.2⫾0.7
1,1,1-triethyl-N-共1-methylethyl兲silanamine
38.6⫾0.8
1,1,1-triethyl-N-propylsilanamine
41.5⫾0.8
1,3-propanediyl-bis共trimethylsilane兲
共338 – 443兲
43.1⫾0.5
共338 – 443兲
43.1⫾0.5
tris共trimethylsilyl兲amine
54.4⫾8.4
1,1,3,3-tetramethyl-1,3-bis共trimethylsilyl兲disilazane
共378 – 435兲
58.0
共2-methoxyphenyl兲trimethylsilane
59.4⫾0.8
共3-methoxyphenyl兲trimethylsilane
56.1⫾0.8
共4-methoxyphenyl兲trimethylsilane
56.9⫾0.8
m-tolyl trimethylsilyl ether
共371–398兲
49.7
p-tolyl trimethylsilyl ether
共374 – 402兲
49.8
trimethoxy关共phenylthio兲methyl兴silane
56.4⫾0.7
diallyl共diethoxy兲silane
共342– 459兲
48.3
dipropyldiethoxysilane
46.5⫾0.7
46.4⫾0.3
triethoxy关2-共ethylthio兲ethyl兴silane
46.9⫾0.7
diethyldipropylsilane
41.5⫾0.7
methyltripropylsilane
42.6⫾0.6
ethyldibutylsilane
39.9⫾0.7
ethyldiisobutylsilane
39.8⫾0.7
1,1,1,3,5,5,5-heptamethyl-3-共2-cyanoethyl兲trisiloxane
共367–511兲
59.5
pentaethylsilanamine
42.2⫾1.0
N-共1,1-dimethylethyl兲-1,1,1-triethylsilanamine
40.3⫾0.9
1,5-diethoxy-1,1,3,3,5,5-hexamethyltrisiloxane
共314 – 470兲
56.2
methyl tris共trimethylsiloxy兲silane
共362– 476兲
49.5
decamethyl tetrasiloxane
共366 – 479兲
50.3
Method
QM
共390兲
CAS registry number
Reference
关1020-84-4兴
关72/19兴
关1529-17-5兴
关88/15兴
关13871-89-1兴
关69/13兴
关53696-83-6兴
关89/11兴
关994-44-5兴
关88/15兴
关998-29-8兴
关88/15兴
关999-35-9兴
关88/15兴
关5277-20-3兴
关91/6兴
关17887-11-5兴
关91/6兴
关2295-05-8兴
关76/25兴
关75/25兴关75/31兴
关67/34兴关82/15兴
共393兲
A
关87/5兴
关704-43-8兴
关88/15兴
关17876-90-3兴
关88/15兴
关877-68-9兴
关88/15兴
关17902-31-7兴
关69/13兴
关17902-32-8兴
关69/13兴
关57557-71-8兴
关89/11兴
关13081-67-9兴
关87/5兴
关2031-63-2兴
关88/15兴
关85/13兴
关57557-72-9兴
关89/11兴
关994-59-2兴
关88/15兴
关995-24-4兴
关88/15兴
关998-61-8兴
关88/15兴
关17591-42-3兴
关88/15兴
共298兲
C
共298兲
C
共298兲
C
共384兲
EB
共388兲
EB
共298兲
C
共357兲
A
共298兲
共298兲
C
EB
共298兲
C
共298兲
C
共298兲
C
共298兲
C
共298兲
C
共382兲
A
共298兲
C
共298兲
C
共329兲
A
关87/5兴
关6022-10-2兴
关91/6兴
关17940-20-4兴
关91/6兴
关17928-13-1兴
关87/5兴
共377兲
EB
关86/4兴
共381兲
EB
关86/4兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
844
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C10H30O5 Si5
Compound
共Temperature range/K兲
共343– 454兲
decamethyl cyclopentasiloxane
共383– 496兲
共364 – 472兲
C10H30Si4
C10H31NSi4
C11H18O3 SSi
C11H20OSi
C11H20OSi2
C11H20O3 Si3
C11H24O3 Si
C11H26Si
C11H26Si
C11H26Si
C11H27NSi
C11H28O4 Si4
C11H28O4 Si4
C12H9 Cl3 Si
C12H9 Cl3 Si
C12H10Cl2 Si
C12H10F2 Si
C12H13NSi
C12H20Cl8 O4 Si
C12H20O3 Si
C12H28O4 Si
C12H28O4 Si
C12H28Si
C12H28Si
C12H28Si
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
CAS registry number
Reference
48.2
共358兲
A
关87/5兴关71/16兴
59.0⫾1.0
52.1
49.0
48.1⫾2.1
共298兲
共398兲
共379兲
C
EB
A
关91/5兴
关86/4兴
关87/5兴关71/15兴
关72/30兴关82/15兴
decamethyltetrasilane
52.3⫾1.7
bis共pentamethyldisilanyl兲amine
共376 – 435兲
57.8
共405兲
关Note: Molecular formula given in paper is not consistent with chemical name.兴
trimethoxy关关共phenylmethyl兲thio兴methyl兴silane
56.1⫾0.7
共298兲
triallylethoxy silane
共349– 473兲
48.4
共364兲
pentamethylphenyl disiloxane
共347– 474兲
53.3
共362兲
共347– 474兲
44.4
共410兲
1,1,3,3,5-pentamethyl-5-phenylcyclotrisiloxane
共396 –503兲
48.0
共450兲
vinyltripropoxysilane
52.3⫾0.9
共298兲
52.3⫾0.4
共298兲
ethyltripropylsilane
41.0⫾0.7
共298兲
methyldipentylsilane
40.3⫾0.7
共298兲
methyldi共2,2-dimethylpropyl兲silane
38.1⫾0.1
共298兲
1,1,1-triethyl-N-共1-methylbutyl兲silanamine
46.9⫾1.0
共298兲
8,8,10,10,12,12-hexamethyl-7,9,11,13-tetrasiloxa-6,8,10,12-tetrasilaspiro关5,7兴tridecane
共393–504兲
47.6
共408兲
共393–504兲
48.8
共449兲
hexamethyl共silacyclohexyl兲cyclotetrasiloxane
共403–504兲
48.89
共453兲
2-共trichlorosilyl兲biphenyl
共461–552兲
67.1
共476兲
4-共trichlorosilyl兲biphenyl
共479–573兲
75.7
共494兲
dichlorodiphenylsilane
共465–555兲
62.5
共480兲
69.5⫾4.2
difluorodiphenylsilane
共392–516兲
50.7
共407兲
共N,N-diphenylamino兲silane
共425– 495兲
50.4
共460兲
tris共2,2⬘-dichloroisopropyl兲 orthosilicate
共517–532兲
U172.7共524兲
triethoxyphenylsilane
58.3⫾0.9
共298兲
共344 –506兲
61.8
共359兲
tetrapropoxysilane
49.8⫾0.8
共298兲
共307–563兲
66.9
共322兲
49.8⫾0.4
共298兲
tetraisopropoxysilane
共327– 438兲
52.7
共342兲
tetrapropylsilane
42.2⫾0.7
共298兲
tributylsilane
42.9⫾0.7
共298兲
triisobutylsilane
40.0⫾0.7
共298兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
关72/30兴关82/15兴
关63/40兴
C
A
A
关53696-80-3兴
关89/11兴
关17962-20-8兴
关87/5兴
关14920-92-4兴
关87/5兴
关74/32兴
关74/17兴
C
EB
C
C
C
C
A
关88/15兴
关85/13兴
关994-63-8兴
关88/15兴
关1001-48-5兴
关88/15兴
关88/15兴
关133943-80-3兴
关91/6兴
关35331-58-9兴
关87/5兴
关74/17兴
A
关74/21兴
关18030-62-1兴
关87/5兴
关18030-61-0兴
关87/5兴
关80-10-4兴
关87/5兴关54/1兴
关66/23兴关82/15兴
关312-40-3兴
关87/5兴
T
关69/34兴
A
A
A, I
C
C
A
EB
C
C
C
关46/9兴
关780-69-8兴
关88/15兴
关47/5兴
关682-01-9兴
关88/15兴
关87/5兴
关85/13兴
关1992-48-9兴
关80/15兴
关994-66-1兴
关88/15兴
关998-41-4兴
关88/15兴
关6485-81-0兴
关88/15兴
ENTHALPIES OF VAPORIZATION
845
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C12H28Si
C12H28Si
C12H30HgSi2
C12H30O3 Si3
C12H31N3 Si
C12H36O4 Si5
C12H36O6 Si6
C12H48O4 Si5
C13H14Si
C13H26O2 Si3
C13H26O4 Si4
C13H30O3 SSi
C13H30Si
C13H30Si
C14H16O2 Si
C14H16Si
C14H32Si
C14H32Si
C14H32Si
C14H33NSi
C14H33NSi
C14H33NSi
C14H42O5 Si6
C14H42O7 Si7
C15H34Si
C15H34Si
C15H34Si
C15H34Si
C16H20O2 Si
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
41.2⫾0.7
共298兲
C
共298兲
C
ethyldipentylsilane
ethyldiisopentylsilane
42.6⫾0.7
bis共triethylsilyl兲mercury
共383– 433兲
64.0
hexaethyl cyclotrisiloxane
共385–524兲
57.9
共434 –516兲
58.7
N,N,N⬘,N⬘,N⬙,N⬙-hexamethylsilanetriamine
58.4⫾1.0
dodecamethyl pentasiloxane
共395–515兲
55.4
共389– 498兲
50.3
53.1⫾2.1
dodecamethyl cyclohexasiloxane
共411–531兲
56.1
共340–509兲
62.6
tetrakis共trimethylsiloxy兲silane
共398 – 494兲
52.3
methyldiphenylsilane
64.6⫾0.8
1,1,1,3,5,5,5-heptamethyl-3-phenyl trisiloxane
共357– 492兲
61.5
2,4,4,6,6,8,8-heptamethyl-2-phenylcyclotetrasiloxane
共397–514兲
65.6
关3-共butylthio兲propyl兴triethoxysilane
47.1⫾0.6
decyltrimethylsilane
共340–513兲
57.8
methyldihexylsilane
42.6⫾0.7
diphenoxydimethylsilane
64.4⫾0.9
ethyldiphenylsilane
66.1⫾0.8
triethyloctylsilane
共347–535兲
56.1
ethyldihexylsilane
44.8⫾0.7
dipropyldibutylsilane
44.0⫾0.8
N,N-dibutyl-1,1,1-triethylsilanamine
56.3⫾1.0
1,1,1-triethyl-N,N-bis共1-methylpropyl兲silanamine
51.4⫾0.9
1,1,1-triethyl-N-octylsilanamine
59.1⫾1.0
tetradecamethyl hexasiloxane
共449–545兲
56.9
共397–522兲
56.6
tetradecamethyl cycloheptasiloxane
共359–537兲
58.6
共431–548兲
60.6
propyltributylsilane
45.0⫾0.8
tripentylsilane
48.1⫾0.8
triisopentylsilane
43.8⫾0.7
dodecyltrimethylsilane
共364 –546兲
62.0
bis共2-methylphenoxy兲dimethylsilane
63.6⫾0.8
共398兲
共400兲
共449兲
A
A
共298兲
C
共410兲
共404兲
EB
A
共426兲
共355兲
EB
A
共413兲
EB
共298兲
C
共372兲
A
共412兲
A
共298兲
C
共355兲
共298兲
C
共298兲
C
共298兲
C
共361兲
共298兲
C
共298兲
C
共298兲
C
共298兲
C
共298兲
C
共464兲
共412兲
EB
A
共374兲
共446兲
A
EB
共298兲
C
共298兲
C
共298兲
C
共379兲
共298兲
C
CAS registry number
Reference
关17591-43-4兴
关88/15兴
关18159-61-0兴
关88/15兴
关72/15兴
关2031-79-0兴
关87/5兴
关87/5兴关54/1兴
关15730-66-2兴
关91/6兴
关141-63-9兴
关86/4兴
关87/5兴关71/16兴
关72/30兴关82/15兴
关540-97-6兴
关86/4兴
关87/5兴关71/15兴
关86/4兴
关776-76-1兴
关88/15兴
关546-44-1兴
关87/5兴
关10448-09-6兴
关87/5兴
关57557-75-2兴
关89/11兴
关47/5兴
关1001-46-3兴
关88/15兴
关6843-66-9兴
关88/15兴
关7535-07-1兴
关88/15兴
关10175-53-8兴
关47/5兴
关17591-45-6兴
关88/15兴
关88/15兴
关17995-32-3兴
关91/6兴
关133943-79-0兴
关91/6兴
关133943-81-4兴
关91/6兴
关107-52-8兴
关86/4兴
关87/5兴关71/16兴
关107-50-6兴
关87/5兴
关86/4兴
关994-78-5兴
关88/15兴
关6485-78-5兴
关88/15兴
关17922-08-6兴
关88/15兴
关17908-09-7兴
关47/5兴
关17964-48-6兴
关88/15兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
846
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C16H20O2 Si
C16H20O2 Si
C16H20O2 Si
C16H22O3 Si3
C16H22O3 Si3
C16H22O3 Si3
C16H32O4 Si4
C16H32O4 Si4
C16H36O4 Si
C16H40O4 Si4
C16H46O7 Si6
C16H48O6 Si7
C16H48O8 Si8
C17H26O4 Si4
C17H32O2 Si
C17H38Si
C18H28O4 Si4
C18H40Si
C18H40Si
C18H54O7 Si8
C18H54O9 Si9
C19H18O3 Si
C20H20OSi
C20H24ClOSi2
C20H32O4 Si4
C20H44O4 Si
C20H58O9 Si8
C20H60O8 Si9
C20H60O10Si10
C21H22Si
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
61.5⫾0.8
共298兲
C
bis共3-methylphenoxy兲dimethylsilane
bis共4-methylphenoxy兲dimethylsilane
65.3⫾0.9
共298兲
diethoxydiphenylsilane
共385–569兲
71.5
共399兲
1,1,3,3-tetramethyl-5,5-diphenylcyclotrisiloxane
共439–523兲
66.9
共481兲
cis 1,1,3,5-tetramethyl-3,5-diphenylcyclotrisiloxane
共423–541兲
66.0
共532兲
trans 1,1,3,5-tetramethyl-3,5-diphenylcyclotrisiloxane
共397–535兲
66.4
共466兲
6,12,18,24-tetraoxa-5,7,13,19-tetrasilatetraspiro关4,1,4,1,4,1,4,1兴-tetracosane
共452–583兲
67.6
共467兲
tetra共silacyclopentyl兲cyclotetrasiloxane
共452–583兲
69.5
共517兲
tetrabutoxysilane
52.0⫾1.0
共298兲
共333– 479兲
79.6
共348兲
octaethyl cyclotetrasiloxane
共420–574兲
69.2
共435兲
1,11-diethoxy-1,1,3,3,5,7,7,9,9,11,11-dodecamethylhexasiloxane
共376 –547兲
66.9
共391兲
hexadecamethylheptasiloxane
共443– 468兲
63.8
共459兲
共443–551兲
60.8
共458兲
hexadecamethyl cyclooctasiloxane
共378 –563兲
66.6
共391兲
共454 –576兲
64.5
共469兲
hexamethyl共silaacenaphthenyl兲cyclotetrasiloxane
共466 –548兲
68.6
共507兲
3-methyl-3-关2-cyclohexylpropylperoxy兴-1-trimethylsilyl-1-butyne
共307–318兲
74.2⫾2.0
tetradecyltrimethylsilane
共393–573兲
70.9
共408兲
2,2,4,4,6,8-hexamethyl-6,8-diphenylcyclotetrasiloxane
共459–576兲
70.5
共474兲
trihexylsilane
51.0⫾0.7
共298兲
ethyldioctylsilane
47.3⫾0.7
共298兲
octadecamethyl octasiloxane
共378 –563兲
67.7
共393兲
共464 –586兲
68.4
共479兲
octadecamethyl cyclononasiloxane
共463–584兲
67.9
共478兲
共473–578兲
68.0
共488兲
methyltriphenoxysilane
71.5⫾0.9
共298兲
ethoxytriphenylsilane
共440– 617兲
89.7
共455兲
1,3-dimethyl-1,1,3-triphenyl-3-chlorodisiloxane
共468 – 626兲
69
共547兲
tetrasilacyclopentylcyclotetrasiloxane
共452–583兲
69.5
共518兲
tetrakis共1-ethylpropoxy兲silane
共371– 427兲
89.2
共386兲
1,15-diethoxy-1,1,3,3,5,5,7,7,9,9,1,1,13,13,15,15-hexadecamethyl-octasiloxane
共406 –585兲
79.7
共421兲
eicosamethylnonasiloxane
共417–581兲
85.9
共432兲
eicosamethylcyclodecasiloxane
共480– 603兲
71.3
共495兲
tribenzylsilane
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
C
A
C
A
A
A
EB
A
A
EB
CAS registry number
Reference
关17964-47-5兴
关88/15兴
关17964-49-7兴
关88/15兴
关2553-19-7兴
关47/5兴
关1693-51-2兴
关74/17兴
关31751-60-7兴
关72/19兴
关31751-59-4兴
关72/19兴
关177-49-1兴
关87/5兴
关74/21兴
关4766-57-8兴
关88/15兴
关87/5兴
关1451-99-6兴
关87/5兴
关18143-15-2兴
关87/5兴
关541-01-5兴
关86/4兴
关87/5兴关71/16兴
关556-68-3兴
关87/5兴
关86/4兴
关74/21兴
ME
A
C
C
A
EB
A
EB
C
关99/23兴
关47/5兴
关18604-02-9兴
关87/5兴
关2929-52-4兴
关88/15兴
关51502-64-8兴
关88/15兴
关556-69-4兴
关87/5兴
关86/4兴
关556-71-8兴
关87/5兴
关86/4兴
关3439-97-2兴
关88/15兴
关1516-80-9兴
关47/5兴
关74/17兴
关74/21兴
A
关87/5兴
A
关87/5兴
关2652-13-3兴
关87/5兴
关18772-36-6兴
关87/5兴
关1747-92-8兴
A
A
ENTHALPIES OF VAPORIZATION
847
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C21H24OSi2
C21H24O3 Si3
C21H24O3 Si3
C21H46Si
C21H46Si
C22H24O3 Si
C22H24O3 Si
C22H24O3 Si
C22H40O4 Si
C22H48Si
C22H66O11Si11
C23H30O3 Si3
C24H22N2 Si
C24H52O4 Si
C24H52Si
C24H72O12Si12
C26H26OSi2
C27H30O2 Si
C27H58Si
C28H28O4 Si
C28H28O4 Si
C28H28O4 Si
C28H32O2 Si
C28H32O2 Si3
C28H32O2 Si3
C28H32O2 Si3
C29H34O2 Si
C30H40F30O3 Si4
C30H64Si
C33H34O2 Si3
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
Method
共460– 637兲
81.9
共475兲
1,1,3-trimethyl-1,3,3-triphenyl disiloxane
共494 – 624兲
80.0
共509兲
共495– 624兲
64.4
共560兲
trans trimethyltriphenylcyclotrisiloxane
共483–586兲
76.1
共534兲
cis trimethyltriphenylcyclotrisiloxane
共473–551兲
80.6
共512兲
triheptylsilane
57.4⫾0.8
共298兲
methyldidecylsilane
57.4⫾0.8
共298兲
methyltris共2-methylphenoxy兲silane
68.2⫾0.9
共298兲
methyltris共3-methylphenoxy兲silane
66.9⫾0.8
共298兲
methyltris共4-methylphenoxy兲silane
70.3⫾0.9
共298兲
dimethyldi-关3-methyl-3-tert-amylperoxy-1-butynyl兴silane
共318 –338兲
92.0⫾1.6
ethyldidecylsilane
58.7⫾0.8
共298兲
docosamethyl cycloundecasiloxane
共496 – 620兲
74.5
共511兲
1,1,1,3,5-pentamethyl-3,5,5-triphenyltrisiloxane
共521– 678兲
69.8
共536兲
N,N,N⬘N⬘-tetraphenyl silane diamine
共410– 473兲
59.1
共425兲
共410– 473兲
57.3
共441兲
tetrahexyloxysilane
共454 –573兲
87.0
共469兲
trioctylsilane
59.8⫾0.8
共298兲
tetracosamethyl cyclododecasiloxane
共508 – 636兲
76.6
共523兲
1,3-dimethyl-1,1,3,3-tetraphenyldisiloxane
共518 – 616兲
93.3
共533兲
共518 – 685兲
64.4
共602兲
3-methyl-3-tert-butylperoxy-1-triphenylsilyl-1-butyne
共378 –398兲
115.9⫾3.2
trinonylsilane
61.8⫾0.8
共298兲
tetrakis共2-methylphenoxy兲silane
76.2⫾1.0
共298兲
tetrakis共3-methylphenoxy兲silane
73.6⫾0.9
共298兲
tetrakis共4-methylphenoxy兲silane
97.1⫾1.0
共298兲
3-methyl-3-tert-amylperoxy-1-triphenylsilyl-1-butyne
共378 –393兲
120.3⫾5.8
1,1,1,3-tetramethyl-3,5,5,5-tetraphenyltrisiloxane
共549– 678兲
82.6
共564兲
1,1,3,5-tetramethyl-1,3,5,5-tetraphenyltrisiloxane
共566 – 666兲
90.9
共581兲
1,3,3,5-tetramethyl-1,1,5,5-tetraphenyltrisiloxane
共544 – 686兲
88.3
共559兲
3-methyl-3-tert-hexylperoxy-1-triphenylsilyl-1-butyne
共383–398兲
126.3⫾3.0
1,1,1,3,5,5,5-hepta共␥-trifluoropropyl兲-3-tris共␥-trifluoropropyl兲siloxytrisiloxane
共502– 652兲
64.3
共671兲
tris共decyl兲silane
65.3⫾0.8
共298兲
1,1,3-trimethyl-1,3,5,5,5-pentaphenyltrisiloxane
共603–711兲
91.3
共618兲
A
A
CAS registry number
Reference
关87/5兴
关14920-93-5兴
关87/5兴
关74/17兴
关72/16兴
C
C
C
C
C
ME
C
A
A
A
T
A
C
A
A
ME
C
C
C
C
关72/16兴
关18753-02-1兴
关88/15兴
关51502-65-9兴
关88/15兴
关55893-94-2兴
关88/15兴
关55893-95-3兴
关88/15兴
关55893-96-4兴
关88/15兴
关99/23兴
关51502-66-0兴
关88/15兴
关18766-38-6兴
关87/5兴
67102-99-2兴
关87/5兴
关22519-45-5兴
关87/5兴
关69/34兴
关7425-86-7兴
关87/5兴
关18765-09-8兴
关88/15兴
关18919-94-3兴
关87/5兴
关807-28-3兴
关87/5兴
关74/17兴
关99/23兴
关51502-67-1兴
关88/15兴
关16714-40-2兴
关88/15兴
关16714-54-8兴
关88/15兴
关16714-41-3兴
关88/15兴
A
关99/23兴
关67103-00-8兴
关87/5兴
关67142-05-6兴
关87/5兴
关3982-82-9兴
关87/5兴
ME
关99/23兴
C
关74/34兴
关18765-73-6兴
关88/15兴
关67103-01-9兴
关87/5兴
ME
A
A
A
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
848
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C33H34O2 Si3
C33H34O4 Si4
AsH9 Si3
Br3 HSi
Cl2 H2 Si
Cl3 HSi
Cl4 Si
FH3 Si
FH5 Si2
F2 H2 Si
F2 H4 NPSi
F3 ISi
F3 HSi
H5 ISi2
H7 NSi2
H9 PSi3
H9 SbSi3
H10Si4
H10OSi4
Compound
共Temperature range/K兲
1,3,5-trimethyl-1,1,3,5,5-pentaphenyltrisiloxane
共575– 625兲
87.3
1,3,5-trimethyl-1,3,5,7,7-pentaphenylcyclotetrasiloxane
共523– 676兲
86.9
trisilylarsine
共258 –287兲
41.0
tribromosilane
共273–393兲
34.8
dichlorosilane
共290–350兲
22.2⫾0.7
trichlorosilane
共303–325兲
24.9
共275–305兲
27.2
silicon tetrachloride
共298 –313兲
29.9
共273–326兲
30.4
共275–330兲
30.2
共273–333兲
30.1
fluorosilane
共145–167兲
18.5
disilanyl fluoride
共178 –227兲
26.3
difluorosilane
共151–167兲
19.9
silylaminodifluorophosphine
共200–273兲
34.3
trifluoroiodosilane
共139–227兲
21.3
trifluorosilane
共156 –168兲
20.1
disilanyl iodide
共274 –363兲
33.9
disilazane
共177–250兲
23.4
trisilylphosphine
共243–284兲
36.4
trisilylstibine
32.0
tetrasilane
共273–369兲
35.6
bis共disilanyl兲 ether
共273–363兲
36.4
Sn
C3 H9 BrSn
trimethyltin bromide
C3 H9 ISn
trimethyltin iodide
C4 H9 F3 Sn
共trifluoromethyl兲trimethyltin
共276 –323兲
tetramethyltin
共273–350兲
共313–393兲
C4 H12Sn
共273–308兲
共308 –355兲
C5 H9 F5 Sn
C5 H12Sn
⌬ vapH m
共kJ mol⫺1兲
共298 –308兲
共pentafluoroethyl兲trimethyltin
共295–329兲
trimethylvinyltin
Method
CAS registry number
Reference
共590兲
A
关3390-61-2兴
关87/5兴
共600兲
关74/17兴
共272兲
关62/34兴
关7789-57-3兴
关34/4兴
关4109-96-0兴
关86/14兴
关10025-78-2兴
关67/24兴
关54/1兴
关10026-04-7兴
关73/29兴
关64/8兴
关54/1兴
关36/4兴
关13537-33-2兴
关44/9兴
共333兲
共314兲
共290兲
共305兲
共288兲
共290兲
共303兲
I
I
共156兲
共202兲
共159兲
关63/30兴
关13824-36-7兴
关44/9兴
共236兲
关72/39兴
共183兲
共162兲
关73/35兴
关13465-71-9兴
关44/9兴
共318兲
关60/6兴
共213兲
T
SG
共263兲
关69/35兴
关62/35兴
关63/44兴
T
共318兲
关46/14兴
关60/6兴
47.3⫾4.2
关57/22兴关82/15兴
48.1⫾4.2
关57/22兴关82/15兴
37.5
共300兲
32.6⫾0.2
31.3
31.1⫾0.1
32.8⫾0.1
33.1⫾1.3
30.5
33.4
31.6
33.1
31.6
共311兲
35.6
37.2⫾2.1
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
Mean temperature
(T m /K)
共298兲
共298兲
T
GC
C
共298兲
共290兲
共331兲
共298兲
共303兲
I
I
I
共312兲
T
关60/11兴
关594-27-4兴
关01/9兴
关92/21兴
关80/4兴
关70/1兴
关63/36兴关82/15兴
关36/1兴
关30/2兴
关30/2兴
关30/2兴
关29/6兴
关60/11兴
关59/16兴关82/15兴
ENTHALPIES OF VAPORIZATION
849
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C5 H14Sn
Compound
共Temperature range/K兲
C6 H16Sn
C6 H18Sn2
hexamethyldistannane
C7 H18OSn
triethylmethoxystannane
共312– 435兲
共312– 435兲
tert-butyltrimethyltin
C7 H18Sn
Mean temperature
(T m /K)
Method
ethyl trimethyltin
共243–381兲
共273–336兲
共336 –384兲
trimethylpropyltin
共261– 405兲
共286 –328兲
共328 – 405兲
trimethylisopropyltin
C6 H16Sn
⌬ vapH m
共kJ mol⫺1兲
37.7⫾1.7
38.4
37.0
34.9
共258兲
共304兲
共360兲
I
I
43.8
41.4
38.0
共276兲
共307兲
共366兲
I
I
C8 H15F5 Sn
C8 H20Sn
tetravinyltin
共313–393兲
共pentafluoroethyl兲triethyltin
共303–343兲
tetraethyltin
共293– 455兲
共313–393兲
C9 H14Sn
phenyltrimethyltin
C10H16Sn
benzyltrimethyltin
C10H24O2 Sn
triethyltin tert-butylperoxide
C10H25NSn
共N,N-diethylamino兲triethyltin
C12H27BrSn
tributyltin bromide
C12H20Sn
tetraallyltin
共333–393兲
tetrapropyl tin
共343– 457兲
共333–393兲
共361– 470兲
关66/24兴关82/15兴
50.2⫾4.2
MM
MM
关57/22兴关82/15兴
关1067-21-6兴
关01/5兴
关01/5兴
GC
关66/24兴关82/15兴
关1112-55-6兴
关92/21兴
49.9
48.7
共273兲
共298兲
40.5
39.2
共323兲
56.5⫾4.2
关60/11兴
关597-64-8兴
关01/9兴
关92/21兴
关80/4兴
关63/36兴关82/15兴
关934-56-5兴
关59/16兴关82/15兴
关4314-94-7兴
关59/16兴关82/15兴
46.6⫾0.6
42.4
50.6⫾0.2
51.0⫾2.1
共374兲
48.8⫾2.1
关71/29兴关82/15兴
50.2⫾4.2
关71/30兴关82/15兴
83.7⫾12.6
关59/16兴关82/15兴
关7393-43-3兴
关92/21兴
关2176-98-9兴
关01/9兴
关92/21兴
关87/5兴
关80/4兴
关63/36兴关82/15兴
关35/7兴
关2949-42-0兴
关01/9兴
关92/21兴
关66/24兴关82/15兴
共298兲
T
GC
C
52.3⫾4.2
C12H28Sn
C12H28Sn
tetraisopropyl tin
共342– 441兲
共333–393兲
C15H26OSn
bis共triethyltin兲oxide
C15H26O2 Sn
triethyltin dimethylphenylperoxide
C12H36Sn2
hexaethyldistannane
C16H36Sn
tetrabutyl tin
共389– 462兲
C16H36Sn
SnI4
tetraisobutyl tin
共391– 451兲
stannic iodide
共418 –523兲
关3531-44-0兴
关63/36兴关82/15兴
关47/5兴
关30/2兴
关30/2兴
关3531-45-1兴
关47/5兴
关30/2兴
关30/2兴
40.6⫾2.1
54.0⫾4.2
C8 H12Sn
CAS registry number
Reference
52.0
GC
55.0⫾0.7
60.8
52.5
65.4⫾2.5
66.9⫾2.1
60.7
共400兲
GC
共376兲
共298兲
48.0⫾0.7
56.4
64.9⫾4.2
共392兲
A
C
GC
52.3⫾2.1
关71/29兴关82/15兴
56.5⫾2.1
关71/29兴关82/15兴
62.8⫾4.2
关66/25兴关82/15兴
关1461-25-2兴
关01/9兴
关63/36兴关82/15兴
关3531-43-9兴
关01/9兴
关7790-47-8兴
关36/7兴
67.8⫾0.5
82.8⫾2.1
共425兲
53.6⫾1.1
共421兲
57.2
共423兲
Sm
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
850
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C33H57O6 Sm
Ta
C10H25O5 Ta
Tb
C33H57O6 Tb
Te
C2 H6 Te
C4 H6 Te
C4 H10Te
C6 H14Te
C6 H14Te
C6 H14Te2
C8 H18Te
C8 H18Te
C8 H18Te
C8 H18Te2
C10H22Te
C10H22Te
TeCl4
Ti
C8 H24N4 Ti
C12H28O4 Ti
C12H28O4 Ti
C16H36O4 Ti
C16H36O4 Ti
C16H36O4 Ti
C16H36O4 Ti
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
Mean temperature
(T m /K)
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲samarium共III兲
共468 –500兲
93.0
pentaethyltantalate
共388 – 424兲
72.6
共403兲
A
关87/5兴
BG
关15492-51-0兴
关69/28兴
dipropyl telluride
共298 – 434兲
diisopropyl telluride
共298 –399兲
dipropyl ditelluride
dibutyl telluride
共303– 423兲
diisobutyl telluride
共303– 410兲
di-sec-butyl telluride
共303–372兲
dibutyl ditelluride
dipentyl telluride
共343– 403兲
diisopentyl telluride
共343– 403兲
tellurium tetrachloride
共506 – 660兲
titanium tetradimethylamide
共353– 418兲
tetraisopropyl titanate
共336 – 459兲
tetrapropyl titanate
共411– 479兲
tetrabutoxy titanium
共462–564兲
共443– 493兲
tetraisobutoxy titanium
共436 –529兲
tetra-sec-butoxy titanium
共378 – 414兲
共370– 476兲
tetra-tert-butoxy titanium
共386 – 486兲
共322–388兲
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
关593-80-6兴
关99/16兴
关97/30兴关96/29兴
关96/30兴
关96/30兴
关89/12兴
关88/1兴
关63000-06-6兴
关89/12兴
关88/1兴
关627-54-3兴
关99/16兴
关96/29兴
关89/12兴
关64501-17-3兴
关96/29兴
关89/12兴
34.4
35.6⫾0.1
36.9
36.1⫾1.0
37.4⫾0.7
36.0⫾2.1
共313兲
共323兲
共282兲
共298兲
共298兲
BG
BG
C
44.8⫾0.8
38.1⫾2.1
共298兲
C
41.8
41.6⫾0.2
41.6⫾0.8
共310兲
共344兲
共298兲
C
45.5⫾0.3
46.5⫾0.7
共366兲
共298兲
C
40.4⫾0.1
共349兲
52.7⫾1.0
共298兲
C
53.4⫾0.1
51.0⫾1.0
共358兲
共298兲
C
47.6⫾0.1
共356兲
关96/29兴
49.6⫾0.9
共338兲
57.3⫾1.0
共298兲
关96/29兴
关77129-69-2兴
关89/12兴
59.5⫾0.8
共373兲
关96/29兴
51.9⫾0.7
共373兲
关96/29兴
77.0
共583兲
53.8⫾3.0
共383兲
62.3
共351兲
A
关87/5兴
111.9
共426兲
A
关87/5兴
89.7
85.0⫾3.1
共477兲
共458兲
A
A
关87/5兴
关87/5兴关78/13兴
77.4
共451兲
A
关87/5兴
76.8
67.1
共393兲
共385兲
A
A
关87/5兴
关87/5兴
55.9
62.6
66.1⫾3.3
共401兲
共337兲
共298兲
A
SG
SG
关87/5兴
关58/13兴关84/9兴
关58/13兴关66/20兴
divinyl telluride
diethyl telluride
共295– 411兲
共273– 415兲
CAS registry number
Reference
关15492-50-9兴
关69/28兴
BG
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲terbium共III兲
共454 –500兲
87.0
dimethyl telluride
共298 –367兲
共273–372兲
共267–369兲
共267–369兲
Method
C
GS
关96/29兴
关79971-42-9兴
关89/12兴
关38788-38-4兴
关96/29兴
关89/12兴
关30/7兴
关3275-24-9兴
关84/33兴关01/23兴
ENTHALPIES OF VAPORIZATION
851
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C16H36O4 Ti
C16H40N4 Ti
C20H44O4 Ti
C20H44O4 Ti
C20H44O4 Ti
C20H44O4 Ti
C20H44O4 Ti
C24H52O4 Ti
C24H52O4 Ti
C24H52O4 Ti
Cl4 Ti
I4 Ti
Tl
C3 H9 Tl
C6 H15Tl
Tm
C33H57O6 Tm
U
UF6
V
C12H17O4 V
C12H17O4 V
C12H17O4 V
C12H17O4 V
W
WF6
Xe
XeF2
XeF4
Yb
C33H57O6 Yb
Zn
C2 H6 Zn
Compound
共Temperature range/K兲
⌬ vapH m
共kJ mol⫺1兲
titanium 共IV兲 tetrabutylate
共323– 418兲
47.6⫾0.7
titanium 共IV兲 tetrakis共diethylamide兲
共423– 463兲
94.6⫾4.0
tetrakis共1,1-dimethylpropoxy兲titanium
共397– 430兲
67.8
共361– 423兲
71.0
77.4⫾3.8
tetrakis共1-ethylpropoxy兲titanium
共385– 445兲
103.6
tetrakis共3-methylbutoxy兲titanium
共407– 493兲
119.7
tetrapentoxytitanium
共484 –558兲
103.4
tetra-tert-pentoxytitanium
共361– 423兲
71.1
tetrakis共1,1-dimethylbutoxy兲titanium
共414 – 454兲
94.6
tetrakis共1-methyl-ethylpropoxy兲titanium
共412– 460兲
86.2
tetrahexyloxy titanium
共520–581兲
94.8
titanium 共IV兲 tetrachloride
共250– 423兲
37.5
共363– 415兲
37.9
共313–357兲
39.8
titanium 共IV兲 tetraiodide
共433– 643兲
58.5
trimethylthallium
共311–360兲
共328 –349兲
triethylthallium
共282– 465兲
Mean temperature
(T m /K)
vanadic acid,
共395– 435兲
vanadic acid,
共383– 418兲
vanadic acid,
共378 – 413兲
vanadic acid,
共348 –385兲
关02/39兴
共443兲
关01/23兴
共412兲
共376兲
共298兲
A
SG
SG
关87/5兴
关58/13兴关84/9兴
关58/13兴关66/20兴
共400兲
A
关87/5兴
共422兲
A
关87/5兴
共499兲
A
关87/5兴
共376兲
A
关87/5兴
共429兲
A
关87/5兴
共427兲
A
关87/5兴
共535兲
A
共265兲
共378兲
共335兲
I
关87/5兴
关7550-45-0兴
关66/29兴
关59/29兴
关53/19兴
关7720-83-4兴
关47/15兴
共538兲
40.6
37.9
共335兲
共338兲
41.9
共297兲
BG
共352兲
90.2
共410兲
A
82.2
共398兲
A
82.4
共393兲
A
714
共363兲
A
25.8
共316兲
53.5
共568兲
60.0
共568兲
tri-sec-butyl ester
tri-tert-butyl ester
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲ytterbium共III兲
共444 – 494兲
82.8
30.4⫾0.1
29.5⫾0.4
关3003-15-4兴
关65/1兴
关46/6兴
关687-82-1兴
关47/5兴
关15631-58-0兴
关69/28兴
关7783-81-5兴
关53/18兴
29.5
triisobutyl ester
xenon difluoride
共553– 663兲
xenon tetrafluoride
共553– 663兲
dimethyl zinc
共273–313兲
I, MM
I
tributyl ester
tungsten hexafluoride
共290–343兲
CAS registry number
Reference
共370兲
tris共2,2,6,6-tetramethylheptane-3,5-dionato兲thulium共III兲
共446 – 490兲
84.1
uranium hexafluoride
共337–389兲
Method
关1801-76-9兴
关87/5兴
关19120-62-8兴
关87/5兴
关17838-66-3兴
关87/5兴
关1686-24-4兴
关87/5兴
关7783-82-6兴
关68/27兴
关13709-36-9兴
关83/15兴
关13709-61-0兴
关83/15兴
BG
关15492-52-1兴
关69/28兴
关97/30兴
关49/21兴关82/15兴
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
852
J. S. CHICKOS AND W. E. ACREE, JR.
TABLE 7. Enthalpies of vaporization of select organo-metallic and inorganic compounds, 1880–2002—Continued
Molecular formula
C4 H10Zn
Compound
共Temperature range/K兲
共248 –318兲
diethyl zinc
共250–391兲
C6 H14Zn
C8 H18Zn
C8 H18Zn
diisopropyl zinc
共303–345兲
共310–338兲
dibutyl zinc
共305–379兲
C10H22Zn
di-sec-butyl zinc
共287–372兲
diisobutyl zinc
共288 –372兲
di-tert-butyl zinc
共300–322兲
dipentyl zinc
C12H26Zn
dihexyl zinc
C14H30Zn
diheptyl zinc
Cl2 Zn
zinc chloride
共695– 826兲
C8 H18Zn
C8 H18Zn
Mean temperature
(T m /K)
Method
29.9
共283兲
BG
37.9
40.2⫾2.1
39.9
40.2
共298兲
共265兲
BG
dipropyl zinc
共313–370兲
C6 H14Zn
⌬ vapH m
共kJ mol⫺1兲
43⫾2
42.1⫾0.4
45.6⫾2.5
39.5
40.3
共341兲
BG
41.8⫾0.5
47.4
共324兲
共324兲
50.7⫾0.3
54.4⫾3.3
45.3
42.9
共342兲
40.9⫾0.2
共330兲
44.6⫾0.2
共330兲
49.3⫾0.8
共311兲
BG
56.2
62.3
C20H44O4 Zr
C20H44O4 Zr
C24H52O4 Zr
C24H52O4 Zr
134.5
tetra-tert-butoxy zirconium
共374 –587兲
56.6
tetrakis共1,1-dimethylpropoxy兲zirconium
共392– 426兲
68.0
tetra-tert-pentoxyzirconium
共361– 435兲
74.1
tetrakis共1,1-dimethylbutoxy兲zirconium
共406 – 449兲
93.3
tetrakis共1-methyl-1-ethylpropoxy兲zirconium
共423– 460兲
91.4
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
关46/13兴
关557-20-0兴
关83/1兴
关49/21兴关82/15兴
关47/5兴
关46/13兴
关628-91-1兴
关02/43兴
关84/34兴
关49/21兴关82/15兴
关49/25兴
关46/13兴
关625-81-0兴
关84/34兴
关46/4兴
关1119-90-0兴
关84/13兴
关49/21兴关82/15兴
关49/25兴
关46/13兴
关7446-94-8兴
关84/13兴
关84/13兴
关7446-94-8兴
关84/13兴
关14402-93-8兴
关49/25兴
关13822-55-4兴
关49/25兴
关14402-95-0兴
关49/25兴
关7646-85-7兴
关58/28兴
48.6
Zr
C16H36O4 Zr
CAS registry number
Reference
共760兲
共389兲
A
关87/5兴
共407兲
A
关87/5兴
共361兲
A
关87/5兴
共421兲
A
关87/5兴
共438兲
A
关87/5兴
ENTHALPIES OF VAPORIZATION
853
TABLE 8. References to Tables 6 and 7
1882
82/1 F. Kraft, Ber. 15, 1687 共1882兲.
1883
83/1 G. W. A. Kahlbaum, Ber. 16, 2476 –2484 共1883兲.
1886
86/1 A. Richardson, J. Chem. Soc. 共London兲 49, 761–776 共1886兲.
1894
94/1 G. W. A. Kahlbaum, Z. Phys. Chem. 13, 14 –55 共1894兲.
1898
98/1 G. W. A. Kahlbaum, Z. Phys. Chem. 26, 577 共1898兲.
98/2 W. Louguinine, Ann. Chim. 共Paris兲 7, 334 –377 共1898兲.
1901
01/1 M. De Forgrand, Comp. Rend. 132, 688 共1901兲.
1903
03/1 J. Dewar and H. O. Jones, Proc. Roy. Soc. London 71A, 427
共1903兲.
1904
04/1 A. Jaquerod and E. Wassmer, Ber. 3, 2531–2535 共1904兲.
1906
06/1 A. Rex, Z. Physik. Chem. 55, 355–370 共1906兲.
1910
10/1 E. C. Bingham, Am. Chem. J. 43, 287–309 共1910兲.
1912
12/1 W. Herz and W. Rathmann, Chem.-Ztg. 36, 1417–1418 共1912兲.
1914
14/1 A. Stock and E. Willfroth, Ber. 47, 144 –154 共1914兲.
1915
15/1 J. M. Crafts, J. Chim. Phys. Phys.-Chim. Biol. 13, 105–161 共1915兲.
1919
19/1 E. Moles and T. Batuecas, J. Chim. Phys. Phys.-Chim. Biol. 17,
537–588 共1919兲.
1921
21/1 A. Stock, F. Henning, and E. Kuss, Ber. 54, 1119–1129 共1931兲.
21/2 O. Maas and C. H. Wright, J. Am. Chem. Soc. 43, 1098 –1111
共1921兲.
21/3 O. Maas and C. H. Wright, J. Am. Chem. Soc. 43, 1098 –1111
共1921兲.
1922
22/1 O. A. Nelson and C. E. Senseman, Ind. Eng. Chem. 14, 58 – 62
共1922兲.
22/2 R. S. Taylor and L. B. Smith, J. Am. Chem. Soc. 44, 2450–2463
共1922兲.
1923
23/1 F. S. Mortimer and R. V. Murphy, Ind. Eng. Chem. 15, 1140–1142
共1923兲.
23/2 C. E. Senseman and O. A. Nelson, Ind. Eng. Chem. 15, 382–383
共1923兲.
1924
24/1 J. Simons, J. Am. Chem. Soc. 46, 2179–2183 共1924兲.
24/2 O. Maas and P. G. Hiebert, J. Am. Chem. Soc. 46, 2693–2700
共1924兲.
1925
25/1 J. H. Perry, J. Am. Chem. Soc. 47, 2629–2632 共1925兲.
1926
26/1 H. Sinozaki, R. Hara, and S. Mitsukuri, Bull Chem. Soc. Jpn. 1,
59– 61 共1926兲.
26/2 A. G. Loomis and J. E. Walters, J. Am. Chem. Soc. 48, 2051–2055
共1926兲.
26/3 F. Straus, Ber. 59, 1664 –1681 共1926兲.
26/4 W. V. Evans and M. B. Aylesworth, Ind. Eng. Chem. 18, 24 –27
共1926兲.
26/5 C. A. Taylor and W. H. Rinkenbach, J. Chem. Soc. 48, 1305–1309
共1926兲.
26/6 G. W. C. Yates, Philos. Mag. 817– 826 共1926兲.
26/7 W. A. Felsing and S. A. Durban, J. Am. Chem. Soc. 48, 2885–2893
共1926兲.
26/8 J. H. Perry and F. Porter, J. Am. Chem. Soc. 48, 299–302 共1926兲.
26/9 H. Sinozaki, R. Hara, and S. Mitsukuri, Bull. Chem. Soc. Jpn. 1,
59– 61 共1926兲.
1927
27/1 W. H. Rinkenbach, Ind. Eng. Chem. 19, 474 – 476 共1927兲.
27/2 J. H. Perry, J. Phys. Chem. 31, 1737–1741 共1927兲.
27/3 N. N. Nagornov, Ann. Inst. Anal. Phys. Chem. 共Leningrad兲 3,
562–583 共1927兲; Chem. Zentr. II, 2668 共1927兲; Chem. Abstracts 22,
4298 共1928兲.
27/4 O. E. May, J. F. T. Berliner, and D. F. J. Lynch, J. Am. Chem. Soc.
49, 1012–1016 共1927兲.
27/5 S. Klosky, L. P. L. Woo, and R. J. Flanigan, J. Am. Chem. Soc. 49,
1280–1281 共1927兲.
1928
28/1 O. A. Nelson, Ind. Eng. Chem. 20, 1382–1384 共1928兲.
28/2 O. A. Nelson, Ind. Eng. Chem. 20, 1380–1382 共1928兲.
28/3 M. Roland, Bull. Soc. Chim. Belg. 37, 117–140 共1928兲.
28/4 W. F. Giauque and R. Wiebe, J. Am. Chem. Soc. 50, 101–122
共1928兲.
28/5 G. S. Parks and B. Barton, J. Am. Chem. Soc. 50, 24 –27 共1928兲.
28/6 W. F. Giauque and R. Wiebe, J. Am. Chem. Soc. 50, 2193–2202
共1928兲.
1929
29/1 J. N. Pearce and P. E. Peters, J. Phys. Chem. 33, 873– 878 共1929兲.
29/2 C. P. Smyth and E. W. Engel, J. Am. Chem. Soc. 51, 2646 –2660
共1929兲.
29/3 H. L. Johnston and W. F. Giauque, J. Am. Chem. Soc. 51, 3194 –
3215 共1929兲.
29/4 W. F. Giauque and R. Wiebe, J. Am. Chem. Soc. 51, 1441–1449
共1929兲.
29/5 C. F. Haggerty and J. F. Weiler, J. Am. Chem. Soc. 51, 1623–1626
共1929兲.
29/6 Y. Tanaka and Y. Nagai, Proc. Imp. Acad. 共Japan兲 5, 78 –79 共1929兲;
Chem. Abstracts 23, 2622 共1929兲.
1930
30/1 O. A. Nelson, Ind. Eng. Chem. 22, 971–972 共1930兲.
30/2 R. H. Bullard and A. C. Haussman, J. Phys. Chem. 34, 743–747
共1930兲.
30/3 M. A. Zmaczynski, J. Chim. Phys. 27, 503–517 共1930兲.
30/4 G. B. Cunningham, Power 72, 374 –377 共1930兲.
30/5 R. Livingston and G. B. Heisig, J. Am. Chem. Soc. 52, 2409–2410
共1930兲.
30/6 H. A. Schuette and R. W. Thomas, J. Am. Chem. Soc. 52, 2028 –
2030 共1930兲.
30/7 J. H. Simons, J. Am. Chem. Soc. 52, 3488 –3493 共1930兲.
30/8 A. S. Coolidge, J. Am. Chem. Soc. 52, 1874 –1887 共1930兲.
1931
31/1 H. A. Scheulte and M. A. Cowley, J. Am. Chem. Soc. 53, 3485–
3489 共1931兲.
31/2 O. Ruff and W. Menzel, Z. Anorg. Allgem. Chem. 202, 49– 61
共1931兲.
31/3 E. Wiberg and W. Sütterlin, Z. Anorg. Allgem. Chem. 202, 1–21
共1931兲.
1932
32/1 W. E. Vaughan, J. Am. Chem. Soc. 54, 3863–3876 共1932兲.
32/2 L. M. Ellis, Jr. and E. E. Reid, J. Am. Chem. Soc. 54, 1674 –1687
共1932兲.
32/3 J. O. Clayton and W. F. Giauque, J. Am. Chem. Soc. 54, 2610–2626
共1932兲.
32/4 W. J. Jones, W. J. C. Dyke, G. Davies, D. C. Griffiths, and J. H. E.
Webb, J. Chem. Soc. 2285–2293 共1932兲.
1933
33/1 W. Menzel and F. Mohry, Z. Anorg. Allgem. Chem. 210, 257–263
共1933兲.
33/2 G. B. Heisig and O. D. Murd, J. Am. Chem. Soc. 55, 3485–3487
共1933兲.
33/3 H. S. Booth, P. E. Burchfield, E. M. Bixly, and J. B. MacKelvey, J.
Am. Chem. Soc. 53, 2231–2235 共1933兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
854
J. S. CHICKOS AND W. E. ACREE, JR.
33/4 F. Hovorka and F. E. Geiger, J. Am. Chem. Soc. 55, 4759– 4761
共1933兲.
33/5 O. A. Nelson and H. D. Young, J. Am. Chem. Soc. 55, 2429–2431
共1933兲.
33/6 M. A. Cowley and H. A. Schuelte, J. Am. Chem. Soc. 55, 387–391
共1933兲.
33/7 A. Taylor and E. T. Layng, J. Chem. Phys. 1, 798 – 808 共1933兲.
33/8 H. S. Booth, P. E. Burchfield, E. M. Bixly, and J. B. MacKelvey, J.
Am. Chem. Soc. 53, 2231–2235 共1933兲.
33/9 F. Hovorka, H. P. Lankelma, and C. K. Naujoks, J. Am. Chem. Soc.
53, 4820– 4822 共1933兲.
33/10 H. Tannelberger, Ber. 66B, 484 – 486 共1933兲; Chem. Abstracts 27,
3374 共1933兲.
33/11 G. B. Heisig, J. Am. Chem. Soc. 55, 2304 –2311 共1933兲.
33/12 E. G. V. Barrett and L. J. Burrage, J. Phys. Chem. 37, 1029–1035
共1933兲.
33/13 F. T. Miles and A. W. C. Menzies, J. Phys. Chem. 37, 435– 430
共1933兲.
33/14 C. A. Kraus and F. E. Toonder, Proc. Natl. Acad. Sci. 共USA兲 19,
292–298 共1933兲; Chem. Abstracts 27, 2646 共1933兲.
33/15 M. T. Toral and E. Moles, Anales Soc. Espan. Fis. Quim. 31,
735–745 共1933兲; Chem. Abstracts 28, 954 共1934兲.
33/16 W. F. Giauque and J. O. Clayton, J. Am. Chem. Soc. 55, 4875–
4889 共1933兲.
1934
34/1 W. Mehl, Z. Physik. Chem. A164, 312–313 共1934兲.
34/2 W. Hieber and A. Woerner, Z. Elektrochem. 40, 252–256 共1934兲.
34/3 N. E. Rigler, W. A. Felsing, and H. R. Henze, J. Am. Chem. Soc.
56, 1499 共1934兲.
34/4 W. C. Schumb and F. A. Bickford, J. Am. Chem. Soc. 56, 852– 858
共1934兲.
34/5 G. N. Lewis and P. W. Schultz, J. Am. Chem. Soc. 56, 1002 共1934兲.
34/6 J. W. Goodeve, Trans. Faraday Soc. 30, 501–504 共1934兲. 关Vapor
pressure data are presented graphically in paper as log P versus 1/T.]
34/7 S. Oguri, S. Anjo and Y. Kuwabara, Bull. Waseda Appl. Chem. Soc.
22, 1– 4 共1934兲; Chem. Abstracts 28, 4298 共1934兲.
34/8 A. N. Campbell and A. J. R. Campbell, Trans. Faraday Soc. 30,
1109–1114 共1934兲.
1935
35/1 R. Spence and W. Wild, J. Chem. Soc. 138, 506 –509 共1935兲.
35/2 H. W. Thompson and J. W. Linnett, Trans. Faraday Soc. 31,
1743–1747 共1935兲.
35/3 H. Bauer and K. Burschkies, Ber. 68, 1238 –1243 共1935兲.
35/4 H. Schierholtz and M. L. Staples, J. Am. Chem. Soc. 57, 2709–
2711 共1935兲.
35/5 V. A. Kireev and A. A. Popov, J. Gen. Chem. 共U.S.S.R.兲 5, 1399–
1401 共1935兲; Chem. Abstracts 30, 2441 共1936兲.
35/6 J. A. V. Butler, C. N. Ramchandani, and D. W. Thompson, J. Chem.
Soc. 280–285 共1935兲.
35/7 W. J. Jones, D. P. Evans, T. Gulwell, and D. C. Griffiths, J. Chem.
Soc. 39– 47 共1935兲.
1936
36/1 H. W. Thompson and J. W. Linnett, Trans. Faraday Soc. 32,
681– 685 共1936兲.
36/2 M. Ewert, Bull. Soc. Chim. Belg. 45, 493–515 共1936兲.
36/3 H. E. Bent, G. R. Cuthbertson, M. Dorfman, and R. E. Leary, J.
Am. Chem. Soc. 58, 165–170 共1936兲.
36/4 K. Kearby, J. Am. Chem. Soc. 58, 374 –375 共1936兲.
36/5 H. Merten and H. Schlüter, Chem. Ber. 69B, 1364 –1366 共1936兲.
36/6 F. Hovorka, R. A. Schaefer, and D. Dreisback, J. Am. Chem. Soc.
58, 2264 共1936兲.
36/7 G. R. Negishi, J. Am. Chem. Soc. 58, 2293–2296 共1936兲.
36/8 J. G. Aston and G. H. Messerly, J. Am. Chem. Soc. 58, 2354 –2361
共1936兲.
36/9 E. J. Buckler and R. G. W. Norrish, J. Chem. Soc. 1567–1569
共1936兲.
1937
37/1 A. Klemenc and G. Wagner, Ber. 70B, 1880–1882 共1937兲; Chem.
Abstracts 31, 8412 共1937兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
37/2 J. D. Kemp and W. F. Giauque, J. Am. Chem. Soc. 59, 79– 84
共1937兲.
37/3 H. W. Thompson and F. S. Dainton, Trans. Faraday Soc. 33,
1546 –1555 共1937兲.
37/4 A. Guyer, W. Schutze, and M. Weidenmann, Helv. Chim. Acta 20,
936 –949 共1937兲.
37/5 C. J. Egan and J. D. Kemp, J. Am. Chem. Soc. 59, 1264 –1268
共1937兲.
37/6 A. B. Burg and W. I. Schlesinger, J. Am. Chem. Soc. 59, 780–787
共1937兲.
37/7 V. G. Moor, E. K. Kanep, and I. E. Dobkin, Trans. Exptl. Research
Lab. Khemgas, Materials on Cracking and Chemical Treatment of
Cracking Products U.S.S.R. 3, 320–328 共1937兲; Chem. Abstracts 31,
6072 共1937兲.
37/8 A. V. Grosse and V. N. Ipatieff, J. Org. Chem. 2, 447– 458 共1937兲.
37/9 J. C. Rintelen, Jr., J. H. Saylor, and P. M. Gross, J. Am. Chem. Soc.
59, 1129–1130 共1937兲.
37/10 J. G. Aston, C. W. Siller, and G. H. Messerly, J. Am. Chem. Soc.
59, 1743–1751 共1937兲.
37/11 G. S. Gardner and J. E. Brewer, Ind. Eng. Chem. 29, 179–181
共1937兲.
37/12 R. H. Purcell and F. D. Zahoorbux, J. Chem. Soc. 1029–1035
共1937兲.
37/13 R. Overstreet and W. F. Giauque, J. Am. Chem. Soc. 59, 254 –259
共1937兲.
37/14 R. K. Witt and J. D. Kemp, J. Am. Chem. Soc. 59, 273–276
共1937兲.
37/15 C. C. Stephenson and W. F. Giauque, J. Chem. Phys. 5, 149–158
共1937兲.
37/16 R. Linke and W. Rohrmann, Z. Physik. Chem. B35, 256 –260
共1937兲.
1938
38/1 J. D. Brandner, Ind. Eng. Chem. 30, 681– 684 共1938兲.
38/2 M. Linhard, Z. Anorg. Allgem. Chem. 236, 200–208 共1938兲.
38/3 C. G. Egan and J. D. Kemp, J. Am. Chem. Soc. 60, 2097–2101
共1938兲.
38/4 L. Reidel, Z. Ges. Kalte-Ind. 45, 221 共1938兲.
38/5 G. Scatchard and C. L. Raymond, J. Am. Chem. Soc. 60, 1278 –
1287 共1938兲 关Erratum 60, 3099 共1938兲兴.
38/6 D. Radalescu and M. Alexa, Bull. Chem. Soc. Romania 20A,
89–113 共1938兲.
38/7 K. Kuchinskaya, Sbornik Trudov. Opytnogo Zavoda im. Akad. S. V.
Lebedeva 27–30 共1938兲; Chem. Abstracts 34, 3147 共1940兲.
38/8 A. R. Ubbelohde, Trans. Faraday Soc. 34, 283–292 共1938兲.
38/9 E. Levin and I. Shtern, Zh. Prikl. Khim. 共Moscow兲 11, 426 – 441
共1938兲.
38/10 F. Hovorka, H. P. Lankelma, and S. C. Stanford, J. Am. Chem.
Soc. 60, 820– 827 共1938兲.
38/11 W. F. Giauque and C. C. Stephenson, J. Am. Chem. Soc. 60,
1389–1394 共1938兲.
38/12 E. Eftring, Dissertation, University of Lund, 1938; as quoted in
关56/25兴.
1939
39/1 J. G. Aston, M. L. Eidinoff, and W. S. Forster, J. Am. Chem. Soc.
61, 1539–1543 共1939兲.
39/2 T. M. Powell and W. F. Giauque, J. Am. Chem. Soc. 61, 2366 –2370
共1939兲.
39/3 F. H. Verhoek and A. L. Marshall, J. Am. Chem. Soc. 61, 2736 –
2742 共1939兲.
39/4 K. B. Goldblum, R. W. Martin, and R. B. Young, Ind. Eng. Chem.
39, 1474 –1476 共1947兲.
39/5 A. Frank and K. Clusius, Z. Phys. Chem. 42B, 395– 421 共1939兲.
39/6 W. Patnode and W. J. Scheiber, J. Am. Chem. Soc. 61, 3449–3451
共1939兲.
39/7 L. Reidel, Bull. Intern. Inst. Refrig. 20, 1–10 共1939兲.
1940
40/1 A. F. Benning and R. C. McHarness, Ind. Eng. Chem. 32, 497– 499
共1940兲.
ENTHALPIES OF VAPORIZATION
40/2 G. H. Messerly and J. C. Aston, J. Am. Chem. Soc. 62, 886 – 890
共1940兲.
40/3 A. B. Lamb and E. E. Roper, J. Am. Chem. Soc. 62, 806 – 814
共1940兲.
40/4 A. B. Burg, J. Am. Chem. Soc. 62, 2228 –2234 共1940兲.
40/5 J. M. Stuckey and J. H. Saylor, J. Am. Chem. Soc. 62, 2922–2955
共1940兲.
40/6 K. S. Pitzer, J. Am. Chem. Soc. 62, 1224 –1227 共1940兲.
40/7 F. Hovorka, H. P. Lankelma, and W. R. Smith, J. Am. Chem. Soc.
62, 2372–2374 共1940兲.
40/8 F. Hovorka, H. P. Lankelma, and A. E. Axelrod, J. Am. Chem. Soc.
62, 187–189 共1940兲.
40/9 F. Hovorka, H. P. Lankelma, and I. Schneider, J. Am. Chem. Soc.
62, 1096 –1098 共1940兲.
40/10 J. G. Aston and G. H. Messerly, J. Am. Chem. Soc. 62, 1917–
1923 共1940兲.
40/11 J. G. Aston, R. M. Kennedy, and S. C. Schumann, J. Am. Chem.
Soc. 62, 2059 共1940兲; 62, 2063 共1940兲.
40/12 A. A. Zil’berman-Granovskaya and E. A. Shugam, J. Phys. Chem.
共USSR兲 14, 759–767 共1940兲.
40/13 H. I. Schlesinger, R. T. Sanderson, and A. B. Burg, J. Am. Chem.
Soc. 62, 3421–3425 共1940兲.
40/14 E. R. Smith, J. Res. National Bureau Stand. 24, 229–234 共1940兲.
40/15 G. H. Messerly and R. M. Kennedy, J. Am. Chem. Soc. 62,
2988 –2991 共1940兲.
1941
41/1 A. F. Belyaev, Acta Physicochem. U.S.S.R. 14, 523 共1941兲.
41/2 D. M. Youst, C. S. Garner, D. W. Osborne, T. R. Rubin, and H.
Russell, Jr., J. Am. Chem. Soc. 63, 2267–2272 共1941兲.
41/3 R. M. Kennedy, M. Sagenkahn, and J. G. Aston, J. Am. Chem. Soc.
63, 2267–2272 共1941兲.
41/4 D. W. Osborne, C. S. Garner, R. N. Doecher, and D. M. Yost, J.
Am. Chem. Soc. 63, 3496 –3499 共1941兲.
41/5 J. G. Aston, R. M. Kennedy, and G. H. Messerly, J. Am. Chem.
Soc. 63, 2243–2348 共1941兲.
41/6 M. W. Lister, J. Am. Chem. Soc. 63, 143–149 共1941兲.
41/7 V. A. Kireev and I. P. Sitnikov, J. Appl. Chem. 共USSR兲 14,
483– 485 共1941兲; Chem. Abstracts 36, 2189 共1942兲.
41/8 C. B. Heisig, J. Am. Chem. Soc. 63, 1698 –1699 共1941兲.
41/9 E. R. Smith, J. Res. National Bureau Stand. 26, 129–134 共1941兲.
41/10 J. W. Stout and L. H. Fisher, J. Chem. Phys. 9, 163–168 共1941兲.
41/11 H. Russell, Jr., R. E. Rundle, and D. M. Yost, J. Am. Chem. Soc.
63, 2825–2828 共1941兲.
41/12 L. O. Brockway and N. R. Davidson, J. Am. Chem. Soc. 63, 3287
共1941兲.
41/13 L. Riedel, Z. Ges Kalte-Ind. 48, 9–13 共1941兲.
1942
42/1 H. Russell, Jr., D. W. Osborne, and D. M. Yost, J. Am. Chem. Soc.
64, 165–169 共1942兲.
42/2 D. W. Osborne, R. W. Doescher, and D. M. Yost, J. Am. Chem.
Soc. 64, 169–172 共1942兲.
42/3 P. E. Burchfield, J. Am. Chem. Soc. 64, 2501 共1942兲.
42/4 G. E. Williams and E. C. Gilbert, J. Am. Chem. Soc. 64, 2776 –
2777 共1942兲.
42/5 S. C. Schumann, J. G. Aston, and M. Sagenkahn, J. Am. Chem.
Soc. 64, 1039–1043 共1942兲 关Erratum 64, 30690 共1942兲兴.
42/6 J. A. Beattie, H. G. Ingersoll, and W. H. Stockmayer, J. Am. Chem.
Soc. 64, 546 –548 共1942兲.
42/7 S. W. Benson and G. B. Kistiakowsky, J. Am. Chem. Soc. 64,
80– 86 共1942兲.
42/8 S. W. Benson, Ind. Eng. Chem., Anal. Ed. 13, 189–191 共1942兲.
42/9 B. Suginuma and K. Satozaki, Rikagaku Kenkyusho Iho 41, 432
共1942兲.
1943
43/1 K. S. Pitzer and D. W. Scott, J. Am. Chem. Soc. 65, 803– 811
共1943兲.
43/2 D. R. Stevens, Ind. Eng. Chem. 35, 655– 660 共1943兲.
43/3 J. F. Lemons and W. A. Felsing, J. Am. Chem. Soc. 65, 46 – 48
共1943兲.
855
43/4 J. G. Aston, H. L. Finke, and S. C. Schumann, J. Am. Chem. Soc.
65, 341–346 共1943兲.
43/5 J. G. Aston, G. J. Szasz, and H. L. Finke, J. Am. Chem. Soc. 65,
1135–1139 共1943兲.
43/6 W. P. Hall and E. E. Reid, J. Am. Chem. Soc. 65, 1466 –1468
共1943兲.
43/7 J. S. N. Cramer, Rec. Trav. Chem. 62, 606 – 610 共1943兲; Chem.
Zentr. II, 2234 共1943兲; Chem. Abstracts 38, 6148 共1944兲.
43/8 G. Holst and L. Melander, Svensk. Kem. Tid. 55, 131–135 共1943兲;
Chem. Abstracts 40, 2706 共1946兲.
1944
44/1 H. J. McDonald, J. Phys. Chem. 48, 47–50 共1944兲.
44/2 T. R. Rubin, B. D. Levedahl, and D. M. Yost, J. Am. Chem. Soc.
66, 279–282 共1944兲.
44/3 H. Russell, Jr., D. R. V. Golding, and D. M. Yost, J. Am. Chem.
Soc. 66, 16 –20 共1944兲.
44/4 G. Milazzo, Gazz. Chim. Ital. 74, 49–57 共1944兲.
44/5 I. I. Ioffe and E. S. Yamp’olskaya, Zh. Prikl. Khim. 17, 527–528
共1944兲; Chem. Abstracts 39, 3986 共1945兲.
44/6 J. G. Aston, M. L. Sagenkahn, G. J. Szasz, G. W. Moessen, and H.
F. Zuhr, J. Am. Chem. Soc. 66, 1171–1177 共1944兲.
44/7 P. M. Althouse and H. O. Triebold, Ind. Eng. Chem., Anal. Ed. 16,
605– 606 共1944兲.
44/8 R. B. Scott, W. J. Ferbuson, and F. G. Brickwedde, J. Res. National
Bureau Stand. 33, 1–20 共1944兲.
44/9 H. J. Emeleus and A. G. Maddock, J. Chem. Soc. 293–296 共1944兲.
1945
45/1 E. S. Swift, Jr. and H. P. Hochanadel, J. Am. Chem. Soc. 67,
880– 881 共1945兲.
45/2 C. B. Willingham, W. J. Taylor, J. M. Pignocco, and F. D. Rossini,
J. Res. National Bureau Stand. 35, 219–224 共1945兲.
45/3 L. Guttman and K. S. Pitzer, J. Am. Chem. Soc. 67, 324 –327
共1945兲.
45/4 R. C. Wackher, C. B. Linn, and A. V. Grosse, Ind. Eng. Chem. 37,
464 – 468 共1945兲.
45/5 H. J. Hoge, J. Res. National Bureau Stand. 34, 281–293 共1945兲.
45/6 H. S. Davis and O. F. Wiedeman, Ind. Eng. Chem. 37, 482– 485
共1945兲.
45/7 E. J. Prosen and F. D. Rossini, J. Res. National Bureau Stand. 34,
59– 63 共1945兲.
45/8 F. S. Fawcett and H. E. Rasmussen, J. Am. Chem. Soc. 67,
1705–1709 共1945兲.
1946
46/1 R. A. Ruehrkein and T. M. Powell, J. Am. Chem. Soc. 68, 1063–
1066 共1946兲.
46/2 J. E. Kilpatrick and K. S. Pitzer, J. Am. Chem. Soc. 68, 1066 –1072
共1946兲.
46/3 F. H. Field and J. H. Saylor, J. Am. Chem. Soc. 68, 2649–2650
共1946兲.
46/4 G. W. Thompson, Chem. Rev. 38, 1–39 共1946兲.
46/5 C. R. Patrick and G. S. Prosser, Trans. Faraday Soc. 60, 700–704
共1946兲.
46/6 H. Gilman and R. G. Jones, J. Am. Chem. Soc. 68, 517–520
共1946兲.
46/7 J. G. Aston, H. L. Finke, A. B. Bestul, E. L. Pace, and G. J. Szasz,
J. Am. Chem. Soc. 68, 52–57 共1946兲.
46/8 R. B. Scott and R. G. Brickwedde, J. Res. National Bureau Stand.
35, 501–512 共1946兲.
46/9 W. J. Jones, L. H. Thomas, E. H. Pritchard, and S. T. Bowden, J.
Chem. Soc. 824 – 827 共1946兲.
46/10 K. S. Pitzer, L. Guttman, and E. F. Westrum, Jr., J. Am. Chem.
Soc. 68, 2209–2212 共1946兲.
46/11 R. Spitzer and K. S. Pitzer, J. Am. Chem. Soc. 68, 2537–2538
共1946兲.
46/12 J. W. Knowlton, N. C. Schieltz, and D. MacMillan, J. Am. Chem.
Soc. 68, 208 –210 共1946兲.
46/13 C. H. Bamford, D. L. Levi, and D. M. Newitt, J. Chem. Soc.
468 – 471 共1946兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
856
J. S. CHICKOS AND W. E. ACREE, JR.
46/14 H. J. Emeleus and A. G. Maddock, J. Chem. Soc. 1131–1134
共1946兲.
46/15 L. H. Long, H. J. Emeleus, and H. V. A. Briscoe, J. Chem. Soc.
1123–1126 共1946兲
46/16 D. A. Crooks and F. M. Feetham, J. Chem. Soc. 899–901 共1946兲.
46/17 L. S. Dzung, Brown Boveri Rev. 33, 158 –163 共1946兲.
1947
47/1 J. Beersmans and J. C. Jungers, Bull. Soc. Chim. Belg. 56, 238 –250
共1947兲.
47/2 D. J. G. Ives, R. W. Pittman, and W. Wardlaw, J. Chem. Soc.
1080–1083 共1947兲.
47/3 C. Gould, G. Holzman, and C. Niemann, Anal. Chem. 19, 204 –206
共1947兲.
47/4 J. A. A. Ketalaar, P. F. Van Velden, and J. S. Zalm, Rec. Trav. Chim.
66, 721–732 共1947兲.
47/5 D. R. Stull, Ind. Eng. Chem. 39, 517–540 共1947兲.
47/6 E. W. Balson, K. G. Denbigh, and N. K. Adam, Trans. Faraday Soc.
43, 42– 48 共1947兲.
47/7 N. S. Osborne and D. C. Ginnings, J. Res. National Bureau Stand.
39, 453– 477 共1947兲.
47/8 F. H. Stross, C. M. Gable, and G. C. Rounds, J. Am. Chem. Soc.
69, 1629–1630 共1947兲.
47/9 F. H. Stross, J. M. Monger, and H. De V. Finch, J. Am. Chem. Soc.
69, 1627–1628 共1947兲.
47/10 G. Waddington, S. S. Todd, and H. M. Huffman, J. Am. Chem.
Soc. 69, 22–30 共1947兲.
47/11 W. M. Jones and W. F. Giauque, J. Am. Chem. Soc. 69, 983–987
共1947兲.
47/12 G. Waddington and D. R. Douslin, J. Am. Chem. Soc. 69,
2275–2279 共1947兲.
47/13 J. G. Aston and G. J. Szasz, J. Am. Chem. Soc. 69, 3108 –3114
共1947兲.
47/14 R. D. Fowler, J. M. Hamilton, Jr., J. S. Kasper, C. E. Weber, W. B.
Burford III, and H. C. Anderson, Ind. Eng. Chem. 39, 375–378 共1947兲.
47/15 J. M. Blocher, Jr. and I. E. Campbell, J. Am. Chem. Soc. 69,
2100–2101 共1947兲.
1948
48/1 K. B. Kellogg and G. H. Cady, J. Am. Chem. Soc. 70, 3986 –3990
共1948兲.
48/2 W. F. Giauque and W. M. Jones, J. Am. Chem. Soc. 70, 120–124
共1948兲.
48/3 E. L. Pace and J. G. Aston, J. Chem. Soc. 566 –570 共1948兲.
48/4 G. H. Whiting, J. Chem. Soc. 1209–1210 共1948兲.
48/5 J. F. Ganeff and J. C. Jungers, Bull. Soc. Chim. Belg. 57, 82– 87
共1948兲.
48/6 J. Gordon and W. F. Giauque, J. Am. Chem. Soc. 70, 1506 –1510
共1948兲.
48/7 A. A. Banks, H. J. Emeleus, R. N. Haszeldine, and V. Kerrigan, J.
Chem. Soc. 2188 –2190 共1948兲.
48/8 C. E. Bonhorst and P. M. Athouse, Ind. Eng. Chem. 40, 2379–2384
共1948兲.
48/9 C. E. Redemann, S. W. Chaikin, and R. B. Fearing, J. Am. Chem.
Soc. 70, 631– 634 共1948兲.
48/10 P. A. Small, K. W. Small, and P. Cowley, Trans. Faraday Soc. 44,
810– 816 共1948兲.
48/11 H. E. Bent and R. J. Francel, J. Am. Chem. Soc. 70, 634 – 637
共1948兲.
48/12 C. E. Redemann, S. W. Chaiken, R. B. Fearing, and D. Benedict,
J. Am. Chem. Soc. 70, 637– 639 共1948兲.
48/13 C. E. Redemann, S. W. Chaikin, and R. B. Fearing, J. Am. Chem.
Soc. 70, 1648 –1650 共1948兲.
48/14 C. E. Redemann, S. W. Chaikin, R. B. Fearing, G. J. Rotariu, J.
Savit, and D. Van Hoesen, J. Am. Chem. Soc. 70, 3604 –3606 共1948兲.
48/15 A. Michels and T. Wassenaar, Physica 共Amsterdam兲 14, 104 –110
共1948兲.
48/16 O. Glemser and V. Haüser, Z. Naturforsch. 3B, 159–163 共1948兲.
48/17 H. J. Emeleus and J. F. Wood, J. Chem. Soc. 2183–2188 共1948兲.
1949
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
49/1 R. R. Dreisbach and S. A. Shrader, Ind. Eng. Chem. 41, 2879–2880
共1949兲; R. R. Dreisbach and R. A. Martin, Ind. Eng. Chem. 41, 2875–
2878 共1949兲.
49/2 E. Nicolini and P. Laffitte, Comptes Rend. 229, 757–759 共1949兲;
229, 935–936 共1949兲.
49/3 W. Kuhn and P. Massini, Helv. Chim. Acta 32, 1530–1542 共1949兲.
49/4 W. F. Giauque and J. Gordon, J. Am. Chem. Soc. 71, 2176 –2181
共1949兲.
49/5 C. B. Kretschmer and R. Wiebe, J. Am. Chem. Soc. 71, 1793–1797
共1949兲.
49/6 A. F. Forziati, W. R. Norris, and F. D. Rossini, J. Res. National
Bureau Stand. 43, 555–563 共1949兲.
49/7 G. Waddinton, J. W. Knowlton, D. W. Scott, S. D. Oliver, S. S.
Todd, W. N. Hubbard, J. C. Smith, and H. M. Huffman, J. Am. Chem.
Soc. 71, 797– 808 共1949兲.
49/8 G. Waddington, J. C. Smith, D. W. Scott, and H. M. Huffman, J.
Am. Chem. Soc. 71, 3902–3906 共1949兲.
49/9 E. S. Perry and W. H. Weber, J. Am. Chem. Soc. 71, 3726 –3730
共1949兲.
49/10 T. Higuchi, N. Endow, and J. E. Willard, J. Am. Chem. Soc. 71,
365–366 共1949兲.
49/11 G. W. Sears and E. R. Hopke, J. Am. Chem. Soc. 71, 2575–2576
共1949兲.
49/12 D. W. Scott, G. Waddington, J. C. Smith, and H. M. Huffman, J.
Am. Chem. Soc. 71, 2767–2773 共1949兲.
49/13 D. W. Scott, G. D. Oliver, M. E. Gross, W. N. Hubbard, and H. M.
Huffman, J. Am. Chem. Soc. 71, 2293–2297 共1949兲.
49/14 G. S. Parks and G. E. Moore, J. Chem. Phys. 17, 1151–1153
共1949兲.
49/15 J. Birks and R. S. Bradley, Proc. Roy. Soc. 共London兲 A198,
226 –239 共1949兲.
49/16 E. S. Perry, W. H. Weber, and B. F. Baubert, J. Am. Chem. Soc.
71, 3720–3726 共1949兲.
49/17 R. S. Bradley and A. D. Shellard, Trans. Faraday Soc. 45,
501–507 共1949兲.
49/18 F. R. Buck, K. F. Coles, G. T. Kennedy, and F. Morton, J. Chem.
Soc. 2377–2383 共1949兲.
49/19 J. C. Nicholson, J. Chem. Soc. 1553–1555 共1949兲.
49/20 N. L. Yarym-Agaev, N. N. Fedos’ev, and K. G. Skorikov, Zh. Fiz.
Khim. 11, 1257–1265 共1949兲.
49/21 A. S. Carson, K. Hartley, and H. A. Skinner, Trans. Faraday Soc.
45, 1159–1167 共1949兲.
49/22 A. S. Carson, K. Hartley, and H. A. Skinner, Proc Royal Soc.
共London兲 A195, 500–512 共1949兲.
49/23 D. W. Scott, M. E. Gross, G. D. Oliver, and H. M. Huffman, J.
Am. Chem. Soc. 71, 1634 –1636 共1949兲.
49/24 J. R. Partington and A. L. Wynes, J. Phys. Chem. 53, 500–503
共1949兲.
49/25 L. F. Hatch, G. Sutherland, and W. J. Ross, J. Org. Chem. 14,
1130–1136 共1949兲; vapor pressure data presented graphically as log P
versus 1/T in paper.
49/26 H. J. Emeleus and H. G. Heal, J. Chem. Soc. 1696 –1699 共1949兲.
49/27 J. Thompson and H. J. Emeleus, J. Chem. Soc. 3080 共1949兲.
49/28 L. O. Winstrom and L. Kulp, Ind. Eng. Chem. 41, 2584 –2586
共1949兲.
1950
50/1 J. B. Matthews, J. F. Sumner, and E. A. Moellyn-Hughes, Trans.
Faraday Soc. 46, 797– 803 共1950兲.
50/2 R. M. Noyes, W. A. Noyes, and H. Steinmetz, J. Am. Chem. Soc.
72, 33–34 共1950兲.
50/3 A. Michels and T. Wassennar, Physica 共Amsterdam兲 16, 221–224
共1950兲.
50/4 K. F. Coles and F. Popper, Ind. Eng. Chem. 42, 1434 –1438 共1950兲.
50/5 D. W. Scott, H. L. Finke, M. E. Gross, G. B. Guthrie, and H. M.
Huffman, J. Am. Chem. Soc. 72, 2424 –2430 共1950兲.
50/6 A. F. Forziati, D. L. Camin, and F. D. Rossini, J. Res. Natl. Bur.
Standards 45, 406 – 410 共1950兲.
ENTHALPIES OF VAPORIZATION
50/7 D. W. Scott, H. L. Finke, W. N. Hubbard, J. P. McCullough, M. E.
Gross, K. D. Williamson, G. Waddington, and H. M. Huffman, J. Am.
Chem. Soc. 72, 4664 – 4666 共1950兲.
50/8 D. W. Scott and G. Waddington, J. Am. Chem. Soc. 72, 4310– 4311
共1950兲.
50/9 H. O. Day and W. A. Felsing, J. Am. Chem. Soc. 72, 1698 –1699
共1950兲.
50/10 J. G. Aston, S. V. R. Mastrangelo, and G. W. Moessen, J. Am.
Chem. Soc. 72, 5287–5291 共1950兲.
50/11 A. Z. Conner, P. J. Elving, J. Benischeck, P. E. Tobias, and S.
Steingiser, Ind. Eng. Chem. 42, 106 –110 共1950兲.
50/12 K. Hartley, H. O. Pritchard, and H. A. Skinner, Trans. Faraday
Soc. 46, 1019–1025 共1950兲.
1951
51/1 J. G. Aston, H. L. Fink, G. J. Janz, and K. E. Russell, J. Am. Chem.
Soc. 73, 1939–1943 共1951兲.
51/2 J. P. McCullough, W. B. Person, and R. Spitzer, J. Am. Chem. Soc.
73, 4069– 4071 共1951兲.
51/3 D. G. Flom, N. Alpert, and P. J. Elving, Ind. Eng. Chem. 43,
1178 –1181 共1951兲.
51/4 D. W. Scott, H. L. Finke, J. P. McCullough, M. E. Gross, K. D.
Williamson, G. Waddington, and H. M. Huffman, J. Am. Chem. Soc. 73,
261–265 共1951兲.
51/5 D. Bryce-Smith and K. E. Howlett, J. Chem. Soc. 1141–1142
共1951兲.
51/6 G. D. Oliver and J. W. Grisard, J. Am. Chem. Soc. 73, 1688 –1690
共1951兲.
51/7 G. M. Barrow and A. L. McClellan, J. Am. Chem. Soc. 73,
573–575 共1951兲.
51/8 T. F. Smith and R. F. Bonner, Ind. Eng. Chem. 43, 1169–1173
共1951兲.
51/9 J. C. Potter and J. H. Saylor, J. Am. Chem. Soc. 73, 90–91 共1951兲.
51/10 A. C. Egerton, W. Emte, and G. J. Minkoff, Diss. Faraday Soc.
278 –282 共1951兲.
51/11 J. W. Grisard, H. A. Bernhardt, and G. D. Oliver, J. Am. Chem.
Soc. 73, 5725–5727 共1951兲.
51/12 K. Hartley, H. O. Pritchard, and H. A. Skinner, Trans. Faraday
Soc. 47, 254 –263 共1951兲.
51/13 W. H. Johnson, M. V. Kilday, and E. J. Prosen, J. Res. Nat. Bur.
Stand. 65A, 215–219 共1961兲.
51/14 A. B. Burg and C. L. Randolph, J. Am. Chem. Soc. 73, 953–957
共1951兲.
51/15 J. G. Aston, G. J. Janz, and K. E. Russell, J. Am. Chem. Soc. 73,
1943–1945 共1951兲.
1952
52/1 V. E. Stiles and G. H. Cady, J. Am. Chem. Soc. 74, 3771–3773
共1952兲.
52/2 L. C. Leitch and A. T. Morse, Can. J. Chem. 30, 924 –932 共1952兲.
52/3 G. B. Guthrie, D. W. Scott, Jr., and G. Waddington, J. Am. Chem.
Soc. 74, 2795–2800 共1952兲.
52/4 G. E. Coates, F. Glocling, and N. D. Huck, J. Chem. Soc. 4496 –
4501 共1952兲.
52/5 W. S. Jones and W. S. Tamplin, 共glycols兲 American Chemical
Society’s Series of Chemistry monographs 共1952兲.
52/6 J. P. McCullough, D. W. Scott, H. L. Finke, M. E. Gross, K. D.
Williamson, R. E. Pennington, G. Waddington, and H. M. Huffman, J.
Am. Chem. Soc. 74, 2801–2804 共1952兲.
52/7 G. H. Whipple, Ind. Eng. Chem. 44, 1664 –1667 共1952兲.
52/8 H. L. Finke, D. W. Scott, M. E. Gross, G. Waddington, and H. M.
Huffman, J. Am. Chem. Soc. 74, 2804 –2806 共1952兲.
52/9 P. T. White, D. G. Bernard-Smith, and F. A. Fidler, Ind. Eng. Chem.
44, 1430–1438 共1952兲.
52/10 W. N. Hubbard, H. L. Finke, D. W. Scott, J. P. McCullough, C.
Katz, M. E. Gross, J. F. Messerly, R. E. Pennington, and G. Waddington,
J. Am. Chem. Soc. 74, 6025– 6030 共1952兲.
52/11 D. W. Scott, H. L. Finke, W. N. Hubbard, J. P. MuCullough, G. D.
Oliver, M. E. Gross, C. Katz, K. D. Williamson, G. Waddington, and H.
M. Huffman, J. Am. Chem. Soc. 74, 4656 – 4662 共1952兲.
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52/12 D. W. Scott, H. L. Finke, J. P. McCullough, M. E. Gross, R. E.
Pennington, and G. Waddington, J. Am. Chem. Soc. 74, 2478 –2848
共1952兲.
52/13 T. A. Scott, Jr., D. MacMillan, and E. H. Melvin, Ind. Eng. Chem.
44, 172–175 共1952兲.
52/14 E. T. G. Fuge, S. T. Bowden, and W. J. Jones, J. Phys. Chem. 56,
1013–1016 共1952兲.
52/15 G. Edwards, Trans. Faraday Soc. 48, 513–515 共1952兲.
52/16 J. H. Simons and J. W. Hausteller, J. Chem. Phys. 20, 1516 –1519
共1952兲.
52/17 G. B. Guthrie, D. W. Scott, W. N. Hubbard, C. Katz, J. P.
McCullough, M. E. Gross, K. D. Williamson, and G. Waddington, J. Am.
Chem. Soc. 74, 4662– 4669 共1952兲.
52/18 I. Brown, Austr. J. Sci. Research 5, 530–540 共1952兲.
52/19 G. D. Oliver and J. W. Grisard, J. Am. Chem. Soc. 74, 2705–2707
共1952兲.
52/20 C. T. Mortimer, H. O. Pritchard, and H. A. Skinner, Trans. Faraday
Soc. 48, 220–228 共1952兲.
52/21 L. Kaplan, W. L. Kester, and J. J. Katz, J. Am. Chem. Soc. 75,
5531–5532 共1952兲.
52/22 G. A. R. Brandt, H. J. Emeleus, and R. N. Haszeldine, J. Chem.
Soc. 2198 –2205 共1952兲.
1953
53/1 J. A. Barker, I. Brown, and F. Smith, Disc. Faraday Soc. 15,
142–150 共1953兲.
53/2 G. T. Furukawa, R. E. McCoskey, and M. L. Reilly, J. Res. Natl.
Bur. Standards 51, 69–72 共1953兲.
53/3 J. G. Aston, J. L. Wood, and T. P. Zolki, J. Am. Chem. Soc. 75,
6202– 6204 共1953兲.
53/4 E. F. G. Herington and J. F. Martin, Trans. Faraday Soc. 49,
154 –162 共1953兲.
53/5 V. V. Serpinskii, S. A. Voitkevich, and N. Yu. Lyuboshits, Zh. Fiz.
Khim. 27, 1032–1038 共1953兲; Chem. Abstracts 49, 3594e 共1955兲.
53/6 S. Kardon and J. H. Saylor, J. Am. Chem. Soc. 75, 1997 共1953兲.
53/7 J. P. McCullough, D. W. Scott, H. L. Finke, W. N. Hubbard, M. E.
Gross, C. Katz, R. E. Pennington, J. F. Messerly, and G. Waddington, J.
Am. Chem. Soc. 75, 1818 –1824 共1953兲.
53/8 D. W. Scott, H. L. Finke, W. N. Hubbard, J. P. McCullough, C.
Katz, M. E. Gross, J. F. Messerly, R. E. Pennington, and G. Waddington,
J. Am. Chem. Soc. 75, 2795–2800 共1953兲.
53/9 H. Stage, E. Müller, and P. Faldix, Erdöle und Kohle 6, 375–380
共1953兲. 关Enthalpies of vaporization were calculated by fitting published
vapor pressure data, taken from various sources to the Antoine equation.
Some of the references are to unpublished data measured by chemical
companies.兴
53/10 R. T. Davis, Jr. and R. W. Schiessler, J. Phys. Chem. 57, 966 –968
共1953兲.
53/11 H. A. Skinner and T. F. S. Tees, J. Chem. Soc. 3378 –3383 共1953兲.
53/12 G. W. Rathjens and W. D. Gwinn, J. Am. Chem. Soc. 75, 5629–
5633 共1953兲.
53/13 H. E. Clements, K. V. Wise, and S. E. Johnson, J. Am. Chem. Soc.
75, 1593–5395 共1953兲.
53/14 K. A. Walsh, U. S. Atom. Energy Comm. Report LA-1649, 1953,
Chem. Abstracts 55, 19391c 共1961兲.
53/15 W. T. Grubb and R. C. Osthoff, J. Am. Chem. Soc. 75, 2230–2232
共1953兲.
53/16 T. Charnley, C. T. Mortimer, and H. A. Skinner, J. Chem. Soc.
1181–1184 共1953兲.
53/17 A. Michels, T. Wassenaar, P. Louwerse, R. J. Lunbeck, and G. W.
Wolkers, Physica 19, 287–289 共1953兲.
53/18 G. D. Oliver, H. T. Milton, and J. W. Grisard, J. Am. Chem. Soc.
75, 2827–2829 共1953兲.
53/19 H. Schaefer and F. Zeppernick, Z. Anorg. Allgem. Chem. 272,
274 –278 共1953兲.
53/20 R. C. Osthoff, W. T. Grubb, and C. A. Burkhard, J. Am. Chem.
Soc. 75, 2227–2229 共1953兲.
1954
54/1 A. C. Jenkins and G. F. Chambers, Ind. Eng. Chem. 46, 2367–2369
共1954兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
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54/2 J. P. McCullough, D. W. Scott, R. E. Pennington, I. A. Hossenlopp,
and G. Waddington, J. Am. Chem. Soc. 76, 4791– 4796 共1954兲.
54/3 A. E. Potter, Jr. and H. L. Ritter, J. Phys. Chem. 58, 1040–1042
共1954兲.
54/4 M. Davies and D. G. Jenkin, J. Chem. Soc. 2374 –2377 共1954兲.
54/5 G. T. Furukawa, R. E. McCoskey, and M. L. Reilly, J. Research
Natl. Bureau Standards 52, 11–16 共1954兲.
54/6 T. I. Bowell and G. L. Jones, Jr., J. Phys. Chem. 58, 666 – 667
共1954兲.
54/7 D. L. Camin, A. F. Forziati, and F. D. Rossini, J. Phys. Chem. 58,
440– 442 共1954兲.
54/8 G. R. Nicholson, M. Szarc, and J. W. Taylor, J. Chem. Soc.
2767–2769 共1954兲.
54/9 V. V. Serpinskii, S. A. Voitkevich, and N. Yu. Lyuboshits, Zh. Fiz.
Khim. 28, 1969–1974 共1954兲; Chem. Abstracts 50, 4573i 共1956兲.
54/10 V. V. Serpinskii, S. A. Voitkevich, and N. Yu. Lyuboshits, Zh. Fiz.
Khim. 28, 810– 813 共1954兲; Chem. Abstracts 49, 6677c 共1955兲.
54/11 W. H. Hubbard and G. Waddington, Rec. Trav. Chim. 910–913
共1954兲.
54/12 M. Bukala, J. Majewski, and W. Rodzinski, Przemysl Chem. 10,
6 –11 共1954兲.
54/13 R. C. Osthoff and W. T. Grubb, J. Am. Chem. Soc. 76, 399– 401
共1954兲.
54/14 G. Lord and A. A. Wolf, J. Chem. Soc. 2546 –2551 共1954兲.
54/15 V. Fried, J. Pick, E. Hala, and O. Vilim, Chem. Listy 48, 774 –775
共1954兲.
54/16 K. A. Sense, M. J. Snyder, and J. W. Clegg, J. Phys. Chem. 58,
223–224 共1954兲.
54/17 K. V. Wise, J. Am. Chem. Soc. 76, 3094 –3095 共1954兲.
54/18 L. H. Long and J. F. Sackman, Trans. Faraday Soc. 50, 1177–1182
共1954兲.
1955
55/1 J. G. Aston, P. E. Wills, and T. P. Zolki, J. Am. Chem. Soc. 77,
3939–3941 共1955兲.
55/2 J. J. Jasper and G. B. Miller, J. Phys. Chem. 59, 441– 442 共1955兲.
55/3 G. A. N. Cummings and E. McLaughlin, J. Chem. Soc. 1391–1392
共1955兲.
55/4 O. R. Foz Gazulla, J. Morcilio, A. Perez-Masia, and A. Mendes,
Anales Real Soc. Espan. Fis. Quim. 共Madrid兲 50B, 23–34 共1955兲.
55/5 G. H. Kosolapoff, J. Chem. Soc. 2964 –2965 共1955兲.
55/6 J. G. Aston, T. P. Zolki, and J. L. Wood, J. Am. Chem. Soc. 77,
281–284 共1955兲.
55/7 D. L. Camin and F. D. Rossini, J. Phys. Chem. 59, 1173–1179
共1955兲.
55/8 V. V. Serpinskii, S. A. Voitkevich, and N. Yu. Lyuboshits, Zh. Fiz.
Khim. 29, 653– 657 共1955兲; Chem. Abstracts 50, 16231e 共1956兲.
55/9 E. Von Terres, F. Gebert, H. Hulsemann, H. Petereit, H. Toepsch,
and W. Ruppert, Brennst.-Chem. 36, 272–274 共1955兲.
55/10 O. Ya. Tsypikina, J. Appl. Chem. 共U.S.S.R.兲 28, 167–172 共1955兲;
Chem. Abstracts 49, 9967h 共1955兲.
55/11 R. W. Schiessler and F. C. Whitmore, Ind. Eng. Chem. 47,
1660–1665 共1955兲; data are deposited as supplementary material,
Document No. 4597.
55/12 J. P. McCullough, H. L. Finke, J. F. Messerly, R. E. Pennington, I.
A. Hossenlopp, and G. Waddington, J. Am. Chem. Soc. 77, 6119– 6125
共1955兲.
55/13 D. W. Scott, H. L. Finke, J. P. McCullough, M. E. Gross, J. F.
Messerly, R. E. Pennington, and G. Waddington, J. Am. Chem. Soc. 77,
4993– 4998 共1955兲.
55/14 G. T. Furukawa, R. E. McCoskey, M. L. Reilly, and A. W.
Herman, J. Res. Natl. Bur. Standards 55, 201–207 共1955兲.
55/15 L. H. Long and J. F. Sackman, Trans. Faraday Soc. 51, 1062–1064
共1955兲.
55/16 F. Brown and P. L. Robinson, J. Chem. Soc. 3147–3151 共1955兲.
55/17 J. E. Spice, L. A. K. Staveley, and G. A. Harrow, J. Chem. Soc.
100–104 共1955兲.
55/18 C. A. Brown and A. W. Laubengayer, J. Am. Chem. Soc. 77,
3699–3700 共1955兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
55/19 R. H. Sherman and W. F. Giauque, J. Am. Chem. Soc. 77,
2154 –2160 共1955兲.
55/20 W. H. Mears, R. F. Stahl, S. R. Orfeo, R. C. Shair, L. F. Kells, W.
Thompson, and H. McCann, Ind. Eng. Chem. 47, 1449–1454 共1955兲.
55/21 A. T. Morse, P. B. Ayscough, and L. C. Leitch, Can. J. Chem. 33,
453– 457 共1955兲.
55/22 R. Dreyer, W. Martin, and U. von Weber, J. Prakt. Chem. 273,
324 –328 共1955兲.
55/23 J. Fischer and J. Bingle, J. Am. Chem. Soc. 77, 6511– 6512
共1955兲.
1956
56/1 D. Ambrose, Trans. Faraday Soc. 52, 772–781 共1956兲.
56/2 J. C. M. Li and K. S. Pitzer, J. Am. Chem. Soc. 78, 1077–1080
共1956兲.
56/3 P. Gray, M. W. T. Pratt, and M. J. Larkin, J. Chem. Soc. 210–212
共1956兲.
56/4 J. C. M. Li, J. Am. Chem. Soc. 78, 1081–1083 共1956兲.
56/5 G. Milazzo, Ann. Chim. 共Rome兲 46, 1105–1111 共1956兲; Chem.
Abstracts 51, 7791c 共1957兲.
56/6 J. Pick, V. Fried, E. Hala, and O. Vilim, Collect. Czech. Chem.
Commun. 21, 260–261 共1956兲.
56/7 R. E. Pennington, D. W. Scott, H. L. Finke, J. P. McCullough, J. F.
Messerly, I. A. Hossenlopp, and G. Waddington, J. Am. Chem. Soc. 78,
3266 –3272 共1956兲.
56/8 A. Von Brockhaus and E. Jenckel, Macromol. Chem. 18Õ19,
262–293 共1956兲.
56/9 D. L. Camin and F. D. Rossini, J. Phys. Chem. 60, 1446 –1451
共1956兲.
56/10 E. J. Barber and G. H. Cady, J. Phys. Chem. 60, 504 –505 共1956兲.
56/11 F. Fromm and M. C. Loeffler, J. Phys. Chem. 60, 252–253 共1956兲.
56/12 R. H. Capps and W. M. Jackson, J. Phys. Chem. 60, 811– 812
共1956兲.
56/13 D. W. Scott, J. P. McCullough, W. N. Hubbard, J. F. Messerly, I.
A. Hossenlopp, F. R. Frow, and G. Waddington, J. Am. Chem. Soc. 78,
5463–5468 共1956兲.
56/14 D. N. Glew and L. W. Reeves, J. Phys. Chem. 60, 615 共1956兲.
56/15 E. M. Toops, Jr., J. Phys. Chem. 60, 304 –306 共1956兲.
56/16 Manufacturing Chemists Association Research Project 1956, Tables
23-9-2共2.0111兲-k and 23-9-2共2.0112兲-k; Tables 23-10-2共2.0111兲-k and
23-10-2共2.0112兲-k; Tables 23-11-2共2.0111兲-k and 23-11-2共2.0112兲-k. The
authors suspect that the tabulated Antoine Constants for the various
compounds were generated in the manner discussed in Ref. 关61/13兴.
56/17 Manufacturing Chemists Association Research Project 1956, Tables
23-18-2共1.01111兲-k and 23-18-2共1.01112兲-k. The authors suspect that the
tabulated Antoine Constants for the various compounds were generated in
the manner discussed in Ref. 关61/13兴.
56/18 D. Garvin and C. Schubert, J. Phys. Chem. 60, 807– 808 共1956兲.
56/19 D. W. Scott, J. P. McCullough, W. D. Good, J. F. Messerly, R. E.
Pennington, T. C. Kincheloe, I. A. Hossenlopp, D. R. Douslin, and G.
Waddington, J. Am. Chem. Soc. 78, 5457–5463 共1956兲.
56/20 H. L. Finke, D. W. Scott, M. E. Gross, J. F. Messerly, and G.
Waddington, J. Am. Chem. Soc. 78, 5469–5476 共1956兲.
56/21 M. T. Rogers and J. L. Speirs, J. Phys. Chem. 60, 1462–1463
共1956兲.
56/22 W. D. Good, D. W. Scott, and G. Waddington, J. Phys. Chem. 60,
1090–1095 共1956兲.
56/23 E. Neale, L. T. D. Williams, and V. T. Moores, J. Chem. Soc.
422– 427 共1956兲.
56/24 L. H. Long and J. F. Sackman, Trans. Faraday Soc. 52, 1201–1206
共1956兲.
56/25 F. W. Kirkbride, J. Appl. Chem. 6, 11–21 共1956兲.
56/26 D. Brennan and A. R. Ubbelohde, J. Chem. Soc. 3011–3016
共1956兲.
1957
57/1 F. Call, J. Sci. Food Agric. 8, 81– 85 共1957兲.
57/2 P. Gray and M. W. T. Pratt, J. Chem. Soc. 2163–2168 共1957兲.
57/3 I. Brown and F. Smith, Aust. J. Chem. 10, 423– 428 共1957兲.
57/4 T. C. Bissot, R. W. Parry, and D. H. Campbell, J. Am. Chem. Soc.
79, 796 – 800 共1957兲.
ENTHALPIES OF VAPORIZATION
57/5 W. K. Hall and L. Alexander, J. Phys. Chem. 61, 240–242 共1957兲.
57/6 J. Dykyj, M. Seprakova, and J. Paulech, Chem. Zvesti 11, 461– 466
共1957兲.
57/7 D. W. Scott, H. L. Finke, J. P. McCullough, J. F. Messerly, R. E.
Pennington, I. A. Hossenlopp, and G. Waddington, J. Am. Chem. Soc.
79, 1062–1068 共1957兲.
57/8 A. Dobry and R. Keller, J. Phys. Chem. 61, 1448 –1449 共1957兲.
57/9 V. V. Serpinskii, S. A. Voitkevich, and N. Yu. Lyuboshits, Zh. Fiz.
Khim. 31, 1278 –1284 共1957兲; Chem. Abstracts 52, 3270f 共1958兲.
57/10 J. P. McCullough, W. N. Hubbard, F. R. Frow, I. A. Hossenlopp,
and G. Waddington, J. Am. Chem. Soc. 79, 561–566 共1957兲.
57/11 J. P. McCullough, D. R. Douslin, J. F. Messerly, I. A. Hossenlopp,
T. C. Kincheloe, and G. Waddington, J. Am. Chem. Soc. 79, 4289– 4295
共1957兲.
57/12 F. Glaser and H. Ruland, Chemie Ing. Tech. 29, 772 共1957兲.
57/13 B. C. Easton, M. K. Hargreaves, and R. K. S. Mitchell, J. Appl.
Chem. 共London兲 7, 198 –204 共1957兲.
57/14 J. S. Rowlinson and R. I. Thacker, Trans. Faraday Soc. 53, 1– 8
共1957兲.
57/15 L. Maier, O. Seyforth, F. C. A. Stone, and E. Rochov, J. Am.
Chem. Soc. 79, 5884 –5889 共1957兲.
57/16 A. Rose, J. A. Acciari, R. C. Johnson, and W. W. Sanders, Ind.
Eng. Chem. 49, 104 –109 共1957兲.
57/17 W. S. Barnhart, R. J. Seffl, R. F. Wade, F. W. West, and J. L.
Zollinger, J. Chem. Eng. Data 2, 80– 83 共1957兲.
57/18 E. F. Neilson and D. White, J. Am. Chem. Soc. 79, 5618 –5621
共1957兲.
57/19 J. W. Frazer and R. H. Sanborn, U. S. Atomic Energy Commission,
Report UCRL-4978, 1957; Chem. Abstracts 52, 8936a 共1958兲.
57/20 J. Aylett, J. Chem. Soc. 4152– 4154 共1957兲.
57/21 K. D. Williamson and R. H. Harrison, J. Chem. Phys. 26, 1409–
1411 共1957兲.
57/22 J. B. Pedley, H. A. Skinner, and C. L. Chernick, Trans. Faraday
Soc. 53, 1612–1617 共1957兲.
57/23 L. H. Long and J. F. Sackman, Trans. Faraday Soc. 53, 1606 –1611
共1957兲.
57/24 A. K. Fischer, F. A. Cotton, and J. Wilkinson, J. Am. Chem. Soc.
79, 2044 –2046 共1957兲.
57/25 S. D. Beskov, L. I. Kochetkova, and R. M. Golubeva, Uchenye
Zapiski Moskov. Gosudarst. Pedagog. Inst. Im. V. I. Lenina 99, 147–149
共1957兲; Chem. Abstracts 53, 20993d 共1959兲.
57/26 R. C. Wilhoit, J. Phys. Chem. 61, 114 –116 共1957兲.
57/27 H. D. Kaesz and F. G. A. Stone, J. Chem. Soc. 1433–1435 共1957兲.
57/28 J. W. Dale, H. J. Emeleus, R. N. Haszeldine, and J. H. Moss, J.
Chem. Soc. 3708 –3713 共1957兲.
1958
58/1 L. Molard, Mem. Poudres 40, 13 共1958兲; as quoted in 关77/6兴.
58/2 A. Rose, B. T. Paphronis, and E. T. Williams, J. Chem. Eng. Data 3,
216 –219 共1958兲.
58/3 R. E. Frost and E. G. Rochow, J. Inorg. Nucl. Chem. 52, 201–206
共1958兲; Chem. Abstracts 52, 6999c 共1958兲.
58/4 J. A. Brown and W. H. Mears, J. Phys. Chem. 62, 960–962 共1958兲.
58/5 J. K. Koehler and W. F. Giauque, J. Am. Chem. Soc. 80, 2659–
2662 共1958兲.
58/6 D. W. Scott, J. P. McCullough, J. F. Messerly, R. E. Pennington, I.
A. Hossenlopp, H. L. Finke, and G. Waddington, J. Am. Chem. Soc. 80,
55–59 共1958兲.
58/7 J. P. McCullough, H. L. Finke, D. W. Scott, R. E. Pennington, M.
E. Gross, J. F. Messerly, and G. Waddington, J. Am. Chem. Soc. 80,
4786 – 4793 共1958兲.
58/8 W. N. Hubbard, D. R. Douslin, J. P. McCullough, D. W. Scott, S. S.
Todd, J. F. Messerly, I. A. Hossenlopp, A. George, and G. Waddington, J.
Am. Chem. Soc. 80, 3547–3554 共1958兲.
58/9 V. V. Serpinskii, S. A. Voitkevich, and N. Yu. Lyuboshits, Trudy
Vsesoyuz. Nauch.- Issledovatel. Inst. Sintet. I. Natural. Dushistykh
Veshchestv 4, 125–130 共1958兲.
58/10 W. Mahler and A. B. Burg, J. Am. Chem. Soc. 80, 6161– 6167
共1958兲.
859
58/11 A. B. Burg and F. J. Slota, Jr., J. Am. Chem. Soc. 80, 1107–1109
共1958兲.
58/12 R. D. Dunlap, C. J. Murphy, Jr., and R. C. Bedford, J. Am. Chem.
Soc. 80, 83– 85 共1958兲.
58/13 D. C. Bradley and J. D. Swanwick, J. Chem. Soc. 3207–3214
共1958兲.
58/14 F. Feher and G. Hitzemann, Z. Anorg. Allgem. Chem. 294, 50– 62
共1958兲.
58/15 C. B. Colburn and A. Kennedy, J. Am. Chem. Soc. 80, 5004
共1958兲.
58/16 K. A. Sense and R. W. Stone, J. Phys. Chem. 62, 453– 457 共1958兲.
58/17 A. V. Novoselova, K. N. Semenenko, and O. Ya. Turova, Vestnik
Moskov. Univ. Ser. Mekh., Astron. Fiz. Khim. 13, 139–147 共1958兲.
58/18 L. H. Long and J. F. Sackman, Trans. Faraday Soc. 54, 1797–1803
共1958兲.
58/19 P. Gray and M. W. T. Pratt, J. Chem. Soc. 3403–3412 共1958兲.
58/20 P. A. Fowell and C. T. Mortimer, J. Chem. Soc. 3734 –3736
共1958兲.
58/21 H. J. Emeleus and J. D. Smith, J. Chem. Soc. 527–528 共1958兲.
58/22 R. C. Cass, S. E. Fletcher, C. T. Mortimer, P. G. Quincey, and H.
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58/23 R. C. Cass, S. E. Fletcher, C. T. Mortimer, H. D. Springall, and T.
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58/24 E. A. V. Ebsworth and H. J. Emeleus, J. Chem. Soc. 2150–2156
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58/25 R. C. Cass, S. E. Fletcher, C. T. Mortimer, P. G. Quincey, and H.
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58/27 C. P. Haber and R. K. Uenishi, Chem. Eng. Data Ser. 3, 323–324
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1959
59/1 R. A. McDonald, S. A. Shrader, and D. R. Stull, J. Chem. Eng. Data
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59/4 J. P. McCullough, D. R. Douslin, W. N. Hubbard, S. S. Todd, J. F.
Messerly, I. A. Hossenlopp, F. R. Frow, J. P. Dawson, and G.
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59/6 A. B. Burg and L. R. Grant, J. Am. Chem. Soc. 81, 1–5 共1959兲.
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59/8 J. P. McCullough, R. E. Pennington, J. C. Smith, I. A. Hossenlopp,
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59/9 M. Usanovich and A. I. Dembitskii, Zh. Obshch. Khim. 29,
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59/10 D. L. Hildenbrand, G. C. Sinke, R. A. McDonald, and W. R.
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59/11 I. Brown and F. Smith, Aust. J. Chem. 12, 407– 412 共1959兲.
59/12 W. D. Good, D. R. Douslin, D. W. Scott, A. George, J. L. Lacina,
J. P. Dawson, and G. Waddington, J. Phys. Chem. 63, 1133–1138 共1959兲.
59/13 M. Usanovich and A. I. Dembitskii, Zh. Obshch. Khim. 29,
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59/14 A. J. Leadbetter and J. E. Spice, Can. J. Chem. 37, 1923–1929
共1959兲.
59/15 E. Terres, L. Brinkmann, D. Fischer, D. Hüllstrung, W. Loz, and
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59/16 J. B. Pedley and H. A. Skinner, Trans. Faraday Soc. 55, 544 –547
共1959兲.
59/17 W. D. Good, D. W. Scott, J. L. Lacina, and J. P. McCullough, J.
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59/20 K. Mödritzer, Chem. Ber. 92, 2637–2640 共1959兲; Chem. Abstracts
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59/21 H. J. Emeleus and J. D. Smith, J. Chem. Soc. 375–381 共1959兲.
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59/24 P. A. Folwell and C. T. Mortimer, J. Chem. Soc. 2913–2918
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59/25 E. Amberger, Angew. Chem. 71, 372–373 共1959兲; Chem. Abstracts
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59/26 H. Suga and S. Seki, Bull. Chem. Soc. Jpn. 32, 1088 共1959兲.
59/27 P. Chaiyavech and M. Van Winkle, J. Chem. Eng. Data 4, 53–57
共1959兲.
59/28 L. C. Yen and T. M. Reed III, J. Chem. Eng. Data 4, 102–107
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1960
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共1960兲.
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60/7 D. E. McLaughlin and M. Tamres, J. Am. Chem. Soc. 82, 5618 –
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60/8 D. E. McLaughlin, M. J. Tamres, and S. Searless, Jr., J. Am. Chem.
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60/10 F. E. Brinckman and F. G. A. Stone, J. Am. Chem. Soc. 82,
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60/12 S. L. Stafford and F. G. A. Stone, J. Am. Chem. Soc. 82, 6238 –
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60/13 R. J. Brotherton, A. L. McCloskey, J. L. Boone, and H. M.
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60/14 R. J. Brotherton, A. L. McCloskey, L. L. Petterson, and H.
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60/21 R. A. McKay and B. H. Sage, J. Chem. Eng. Data 5, 21–24
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60/22 F. M. Trent, F. D. Miller, and G. H. Brown, J. Chem. Eng. Data 5,
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60/23 A. P. Claydon, P. A. Fowell, and C. T. Mortimer, J. Chem. Soc.
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60/24 H. J. Emeleus and S. N. Nabi, J. Chem. Soc. 1103–1108 共1960兲.
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60/26 E. Amberger, Angew. Chem. 72, 494 共1960兲; Chem. Abstracts 55,
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1961
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61/14 A. B. Burg and J. E. Griffiths, J. Am. Chem. Soc. 83, 4333– 4335
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61/16 H. M. Huffman, M. E. Gross, D. W. Scott, and J. P. McCullough,
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61/17 J. K. Nickerson, K. A. Kobe, and J. J. McKetta, J. Phys. Chem.
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61/18 J. F. Mathews and J. J. McKetta, J. Phys. Chem. 65, 758 –762
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61/23 I. M. Schiopu, O. Bot, and V. Onu, Bul. Inst. Politeh. Iasi. 7,
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61/25 W. D. Good, J. L. Lacina, and J. P. McCullough, J. Phys. Chem.
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61/26 H. Zimmerman and H. Greisenfelder, Z. Electrochem. 65, 368 –371
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61/27 E. Amberger and H. Boeters, Angew. Chem. 73, 114 共1961兲;
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61/28 E. Amberger, Chem. Ber. 94, 1447–1452 共1961兲; Chem. Abstracts
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61/29 J. F. Ditter, J. C. Perrine, and I. Shapiro, J. Chem. Eng. Data 6,
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61/30 A. Labbauf, J. B. Greenshields, and F. D. Rossini, J. Chem. Eng.
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1962
62/1 R. H. Valentini, G. E. Brodale, and W. R. Giauque, J. Phys. Chem.
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62/2 G. Waddington, J. C. Smith, K. D. Williamson, and D. W. Scott, J.
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62/4 A. Kreglewski, Bull. Acad. Pol. Sci., Ser. Sci. Chem. 10, 629– 633
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62/32 H. J. Emeleus, K. H. Packer, and N. Welcman, J. Chem. Soc.
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62/33 A. J. Downs, J. Chem. Soc. 4361– 4366 共1962兲.
62/34 E. Amberger and H. Boeters, Angew. Chem. 74, 293 共1962兲;
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62/35 E. Amberger and H. Boeters, Angew. Chem. 74, 32–33 共1962兲;
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62/36 B. Cohen and A. G. MacDiarmid, Inorg. Chem. 1, 754 –756
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1963
63/1 R. H. Boyd, J. Chem. Phys. 38, 2529–2535 共1963兲.
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63/25 V. V. Sokolov, L. P. Zhilina, and K. P. Mischenko, Zh. Prikl Khim.
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63/37 W. F. Lautsch, A. Tröber, W. Zimmer, L. Mehner, W. Linck, H. M.
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63/44 E. Amberger and H. Boeters, Z. Naturforsch. 18B, 157 共1963兲;
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1964
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64/21 L. A. Serafimov, V. S. Timofeev, M. P. Strukova, and S. V. L’vov,
Russ. J. Phys. Chem. 38, 1018 –1019 共1964兲.
64/22 C. T. Ratcliffe and J. M. Shreeve, Inorg. Chem. 3, 631– 633
共1964兲.
64/23 N. S. Berman, C. W. Larkam, and J. J. McKetta, J. Chem. Eng.
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64/24 V. Kliment, V. Fried, and J. Pick, Collect. Czech. Chem. Commun.
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64/26 W. D. Good, J. L. Lacina, B. L. De Prater, and J. P. McCullough,
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64/27 J. L. Bills and F. A. Cotton, J. Phys. Chem. 68, 806 – 810 共1964兲.
64/28 A. E. Pope and H. A. Skinner, Trans. Faraday Soc. 60, 1404 –1407
共1964兲.
64/29 B. J. Aylett and L. K. Peterson, J. Chem. Soc. 3429–3436 共1964兲.
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1965
65/1 S. J. Price and M. G. Jacko, Can. J. Chem. 43, 3481–3482 共1965兲.
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65/5 L. A. McDougall and J. E. Kilpatrick, J. Chem. Phys. 42, 2311–
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65/7 R. R. Collerson, J. F. Counsell, R. Handley, J. F. Martin, and C. H.
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65/10 N. V. Lutugina, V. N. Kolbina, and L. I. Reshetova, Zh. Prikl.
Khim. 38, 1541–1546 共1965兲.
65/11 P. A. Naro, J. Chem. Eng. Data 10, 86 共1965兲.
65/12 I. Wadso, Acta Chem. Scand. 19, 1079–1087 共1965兲.
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65/14 H. L. Finke, I. A. Hossenlopp, and W. T. Berg, J. Phys. Chem. 69,
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65/15 M. Davies and B. Kybett, Trans. Faraday Soc. 61, 1608 –1617
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65/16 J. F. Counsell, J. L. Hales, and J. F. Martin, Trans. Faraday Soc.
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65/17 J. Linek, V. Fried, and J. Pick, Collect. Czech. Chem. Commun.
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65/20 L. A. Nisel’son and I. I. Lapivus, Russ. J. Phys. Chem. 39, 80– 83
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65/21 I. G. Gakh and E. P. Babin, Russ. J. Phys. Chem. 39, 924 共1965兲.
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65/23 G. W. Fraser and J. M. Shreeve, Inorg. Chem. 4, 1497–1498
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65/24 H. Kilian and H. J. Bittrich, Z. Phys. Chem. 230, 383 共1965兲.
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65/27 Yu. Kh. Shaulov, G. O. Schmyreva, and V. S. Tubyanskaya, Zh.
Fiz. Khim. 39, 105–109 共1965兲.
65/28 H. S. Hull, A. F. Reid, and A. G. Turnbull, Austr. J. Chem. 18,
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65/29 B. J. Aylett and L. K. Peterson, J. Chem. Soc. 4043– 4048 共1965兲.
1966
66/1 A. W. Laubengayer and C. W. J. Scaife, J. Chem. Eng. Data 11,
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66/4 W. H. Mears, E. Rosenthal, and J. V. Sinka, J. Chem. Eng. Data 11,
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66/5 A. N. Osborn and D. R. Douslin, J. Chem. Eng. Data 11, 502–509
共1966兲.
66/6 N. E. Miller, M. D. Murphy, and D. L. Reznicek, Inorg. Chem. 5,
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66/8 A. P. Kudchadker and B. J. Zwolinski, J. Chem. Eng. Data 11,
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66/9 H. L. Morris, M. Tamres, and S. Searles, Inorg. Chem. 5, 2156 –
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66/10 W. D. Good and B. L. DePrater, J. Phys. Chem. 70, 3606 –3609
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66/11 F. D. Evans and P. F. Tiley, J. Chem. Soc. B 134 –136 共1966兲.
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66/13 M. F. Zimmer, R. A. Robb, and G. A. Carpenter, J. Chem. Eng.
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ENTHALPIES OF VAPORIZATION
66/14 V. A. Branzhan, S. V. Semenenko, and O. G. Kirillova, Zh. Prikl.
Khim. 39, 1399–1403 共1966兲; Chem. Abstracts 65, 9820f 共1966兲.
66/15 D. D. DesMarteau and G. H. Cady, Inorg. Chem. 5, 169–171
共1966兲.
66/16 M. Abedini and A. G. MacDiarmid, Inorg. Chem. 5, 2040–2042
共1966兲.
66/17 J. J. Delfino and J. M. Shreeve, Inorg. Chem. 5, 308 –309 共1966兲.
66/18 B. L. Earl, B. K. Hill, and J. M. Shreeve, Inorg. Chem. 5,
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66/19 B. Börjesson, Y. Nakase, and S. Sunner, Acta Chem. Scand. 20,
803– 810 共1966兲.
66/20 D. C. Bradley and M. J. Hillyer, Trans. Faraday Soc. 62, 2374 –
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66/21 R. C. Dobbie, J. Chem. Soc. A 1555–1556 共1966兲.
66/22 A. E. Beezer and C. T. Mortimer, J. Chem. Soc. A 514 –516
共1966兲.
66/23 M. A. Ring, H. E. O’Neal, A. H. Kadhim, and F. Jappe, J.
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66/24 D. J. Coleman and H. A. Skinner, Trans. Faraday Soc. 62,
1721–1755 共1966兲.
66/25 V. I. Tel’noi and I. B. Rabinovich, Russ. Zh. Fiz Khim. 40,
1556 –1563 共1966兲.
66/26 G. Gattow and M. Dräger, Z. Anorg. Allg. Chem. 343, 232–243
共1966兲.
66/27 A. Finch, P. J. Gardner, and E. J. Pearn, Trans. Faraday Soc. 62,
1072–1081 共1966兲.
66/28 A. A. Zalykin and Yu. A. Strepikheev, J. Appl. Chem. USSR 39,
2448 共1966兲.
66/29 G. P. Luchinskii, Zh. Fiz. Khim. 40, 593–598 共1966兲.
66/30 I. Holeci, Chem. Prumysl 16, 267–270 共1966兲.
66/31 D. H. Brown, G. W. Fraser, and D. W. A. Sharp, J. Chem. Soc. A
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66/32 R. C. Dobbie and H. J. Emeleus, J. Chem. Soc. A 933–936 共1966兲.
66/33 H. J. Emeleus and T. Onak, J. Chem. Soc. A 1291–1292 共1966兲.
66/34 J. L. Carson, R. C. Stewart, and A. G. Williamson, J. Chem. Eng.
Data 11, 231–233 共1966兲.
66/35 M. Mansson and S. Sunner, Acta Chem. Scand. 20, 845– 848
共1966兲.
1967
67/1 A. Finch, P. J. Gardner, E. J. Pearn, and G. B. Watts, Trans. Faraday
Soc. 63, 1880–1888 共1967兲.
67/2 P. M. Christopher and A. Shilman, J. Chem. Eng. Data 12, 333–335
共1967兲.
67/3 J. Murto and A. Kivinen, Suomen Kemistil. B 40, 258 –264 共1967兲.
67/4 A. C. Meeks and I. J. Goldfarb, J. Chem. Eng. Data 12, 196 共1967兲.
67/5 E. L. Pace and A. C. Plaush, J. Chem. Phys. 47, 38 – 43 共1967兲.
67/6 K. H. Goebel, J. Schaffenger, and G. Opel, Chem. Tech. 19,
307–308 共1967兲.
67/7 R. L. Shak, J. Chem. Eng. Data 12, 474 – 480 共1967兲.
67/8 A. Finch, P. J. Gardner, and G. B. Watts, Trans. Faraday Soc. 63,
1603–1607 共1967兲.
67/9 A. C. Plaush and E. L. Pace, J. Chem. Phys. 47, 44 – 48 共1967兲.
67/10 H. C. Van Ness, C. A. Soczek, G. L. Peloquin, and R. L. Machado,
J. Chem. Eng. Data 12, 217–223 共1967兲.
67/11 M. Haccuria and M. P. Mathieu, Ind. Chim. Belg. 32, 165–167
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67/12 H. A. Berman and E. D. West, J. Chem. Eng. Data 12, 197–199
共1966兲.
67/13 W. A. Van Hook, J. Chem. Phys. 46, 1907–1918 共1967兲.
67/14 A. B. Kletshii and L. E. Petric, Zh. Fiz. Khim. 41, 1183–1184
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67/15 G. A. Crowder, Z. H. Taylor, T. M. Reed, and J. A. Young, J.
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67/16 E. F. Westrum and A. Ribner, J. Phys. Chem. 71, 1216 –1224
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67/17 I. I. Konstantinov, E. Z. Zhuravlev, and Z. G. Teplova, Zh. Prikl.
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67/18 N. V. Ermakov and V. P. Skripov, Zh. Fiz. Khim. 41, 77– 81
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863
67/19 D. W. Scott, W. T. Berg, I. A. Hossenlopp, W. N. Hubbard, J. F.
Messerly, S. S. Todd, D. R. Douslin, J. P. McCullough, and G.
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67/20 A. Ribner and E. F. Westrum, Jr., J. Phys. Chem. 71, 1208 –1215
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67/21 A. J. B. Cruickshank and A. J. B. Cutler, J. Chem. Eng. Data 12,
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67/22 M. M. Omar, J. Chem. Soc. C 2038 –2040 共1967兲.
67/23 D. Reedy and G. Urry, Inorg. Chem. 6, 2117–2118 共1967兲.
67/24 L. L. Lapidus, L. A. Nisel’son, and A. A. Karateeva, Russ. J. Phys.
Chem. 41, 241–243 共1967兲.
67/25 E. A. Miroshnichenko, Yu. A. Lebedev, S. A. Shevelev, V. I.
Gulevskaya, A. A. Fainzil’berg, and A. Ya. Apin, Russ. J. Phys. Chem.
41, 783–785 共1967兲.
67/26 Yu. V. Golubkov, I. I. Lapidus, and L. A. Nisel’son, Russ. J. Phys.
Chem. 41, 1122–1123 共1967兲.
67/27 T. M. Lesteva, S. K. Ogorodnikov, and A. I. Morozova, Zh. Prikl.
Khim. 共Leningrad兲 40, 891– 894 共1967兲.
67/28 M. Lustig, Inorg. Chem. 6, 1064 –1065 共1967兲.
67/29 M. L. Anderson and R. N. Hammer, J. Chem. Eng. Data 12,
442– 447 共1967兲.
67/30 V. Fried, P. Gallant, and G. B. Schneier, J. Chem. Eng. Data 12,
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67/31 O. Glemser, U. Biermann, and M. Fild, Chem. Ber. 100, 1082–
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67/32 N. K. Smith and W. D. Good, J. Chem. Eng. Data 12, 570–572
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67/33 S. Pawlenko, Chem. Ber. 100, 3591–3598 共1967兲.
67/34 J. C. Baldwin, M. F. Lappert, J. B. Pedley, and J. A. Treverton, J.
Chem. Soc. A 1980–1984 共1967兲.
67/35 S. M. Danov and Yu. D. Golubev, Tr. Khim. Khim. Tekhnol.
52–55 共1967兲; Chem. Abstracts 68, 95253a 共1968兲.
67/36 T. L. Charlton and R. G. Cavell, Inorg. Chem. 6, 2204 –2208
共1967兲.
67/37 K. Pihlaja and J. Heikkila, Acta Chem. Scand. 21, 2430–2434
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67/38 M. Hirata and S. Suda, Kagaku Kogaku 31, 339–342 共1967兲.
67/39 J. L. Hales, E. B. Lees, and D. Ruxton, J. Trans. Faraday Soc. 63,
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67/40 B. J. Aylett and J. M. Campbell, Inorg. Nucl. Chem. Letters 3,
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67/41 V. R. Paetzold, R. Kurze, and G. Engelhardt, Z. Anorg. Allgem.
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67/42 M. P. Edejer and G. Thodos, J. Chem. Eng. Data 12, 206 –209
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1968
68/1 I. Wadso, Acta Chem. Scand. 22, 2438 –2444 共1968兲.
68/2 E. L. Cherkasskaya, A. M. Tur, Z. F. Petrenkova, and V. I.
Lyubomilov, Zh. Prikl. Khim. 41, 2553–2554 共1968兲.
68/3 F. Gopal and S. A. Rizvi, J. Indian Chem. Soc. 45, 13–16 共1968兲.
68/4 A. G. Osborn and D. R. Douslin, J. Chem. Eng. Data 13, 534 –537
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68/5 P. F. Malbrunot, P. A. Meunier, G. M. Scatena, W. H. Mears, K. P.
Murphy, and J. V. Sinka, J. Chem. Eng. Data 13, 16 –21 共1968兲.
68/6 W. J. Gaw and F. L. Swinton, Trans. Faraday Soc. 64, 637– 647
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68/7 E. Z. Zhuravlev and I. I. Konstantinov, Zh. Prikl. Khim. 41,
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68/8 J. O. Hill and I. Wadso, Acta Chem. Scand. 22, 1590–1594 共1968兲.
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68/10 D. Ambrose, J. Chem. Soc. 1381–1383 共1968兲.
68/11 L. Fowler, W. N. Trump, and C. E. Vogler, J. Chem. Eng. Data 13,
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68/12 E. E. Baroody, G. A. Carpenter, R. A. Robb, and M. F. Zimmer, J.
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68/13 I. I. Lapidus and L. A. Nisel’son, Russ. J. Phys. Chem. 42,
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68/14 Yu. Ya. Maksimov, Russ. J. Phys. Chem. 42, 1550–1552 共1968兲.
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68/15 C. Ratcliffe and J. M. Shreeve, J. Am. Chem. Soc. 90, 5403–5408
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68/16 R. V. Kachalova and M. S. Nemcov, Zh. Prikl. Khim. 共Leningrad兲
41, 2315–2319 共1968兲.
68/17 R. D. Place and S. M. Williamson, J. Am. Chem. Soc. 90,
2550–3556 共1968兲.
68/18 N. Welcman and M. Wulf, Israel J. Chem. 6, 37– 41 共1968兲.
68/19 M. Mansson, Y. Nakase, and S. Sunner, Acta Chem. Scand. 22,
171–174 共1968兲.
68/20 D. P. Baccanari, J. A. Novinski, Y.-C. Pan, M. M. Yevitz, and H.
A. Swain, Jr., Trans. Faraday Soc. 64, 1201–1205 共1968兲.
68/21 O. Glemser and S. P. von Halasz, Z. Naturforsch. 23B, 743–745
共1968兲.
68/22 O. Glemser, S. P. von Halasz, and U. Biermann, Z. Naturforsch.
23B, 1381–1382 共1968兲.
68/23 W. J. Gaw and F. L. Swinton, Trans. Faraday. Soc. 64, 2023–2034
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68/24 V. V. Kushchenko and K. Mishchenko, P. Zh. Prikl. Khim. 41,
646 – 648 共1968兲; Chem. Abstracts 68, 117314a 共1968兲.
68/25 B. M. Kuadzhe, G. P. Ustyugov, and A. A. Kudryavtsev, Tr. Mosk.
Khim. Tekhnol. Inst. 58, 27–28 共1968兲; Chem. Abstracts 71, 6728
共1969兲.
68/26 R. J. L. Andon, J. F. Counsell, J. L. Hales, E. B. Lees, and J. F.
Martin, J. Chem. Soc. 2357–2361 共1968兲.
68/27 L. A. Nisel’son, R. K. Nikolaev, T. D. Sokolova, V. I. Stolyarov,
and Yu. M. Korolev, Izv. Sib. Otd. Akad. Nauk. SSSR, Ser. Khim. Nauk
109–114 共1968兲; Chem. Abstracts 69, 69834s 共1969兲.
68/28 G. Geiseler and J. Hoffmann, Z. Phys. Chem. 共Frankfurt am Main兲
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68/29 M. Cihova, J. Vojtko, and M. Hrusovsky, Zb. Pr. Chemickotechnol.
Fak. SVST 共Slov. Vys. SK. Tech.兲 135–138 共1968兲; Chem. Abstracts 72,
136676u 共1970兲.
68/30 W. B. Fox, J. S. MacKenzie, E. R. McCarthy, J. R. Holmes, R. F.
Stahl, and R. Juurik, Inorg. Chem. 7, 2064 –2067 共1968兲.
68/31 A. S. Khorevskaya and S. Sh. Byk, Zh. Prikl. Khim. 共Leningrad兲
41, 2566 –2568 共1968兲; Chem. Abstracts 70, 61317a 共1969兲.
1969
69/1 Zh. V. Davydova, I. A. Makolkin, and P. S. Bataev, Zh. Obshch.
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69/2 I. Wadso, Acta Chem. Scand. 23, 2061–2064 共1969兲.
69/3 J. A. Devore and H. E. O’Neal, J. Phys. Chem. 73, 2644 –2648
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69/4 M. A. Soulie, P. Goursot, A. Peneloux, and J. Metzger, J. Chim.
Phys. Physicochim. Biol. 66, 603– 606 共1969兲.
69/5 R. H. Kemme and S. I. Kreps, J. Chem. Eng. Data 14, 98 –102
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69/6 J. H. Smith and E. L. Pace, J. Phys. Chem. 73, 4232– 4236 共1969兲.
69/7 B. G. Rueben, J. Chem. Eng. Data 14, 235–236 共1969兲.
69/8 T. M. Lesteva, A. I. Morozova, V. I. Morozova, S. K. Ogorodnikov,
and T. M. Tyvina, Zh. Prikl. Khim. 42, 533–538 共1969兲.
69/9 T. J. V. Findlay, J. Chem. Eng. Data 14, 229–231 共1969兲.
69/10 G. C. Calero, M. M. Valle, and C. G. Losa, Rev. Acad. Cienc. Fis.
Quim. Nat. Zaragoza 24, 137–158 共1969兲.
69/11 A. L. Woodman and A. Adicoff, J. Chem. Eng. Data 14, 479– 480
共1969兲.
69/12 A. G. Osborn and D. R. Douslin, J. Chem. Eng. Data 14, 208 –209
共1969兲.
69/13 R. J. Sheehan and S. H. Langer, J. Chem. Eng. Data 14, 248 –250
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69/14 J. Konicek, M. Prochazka, V. Krestanova, and M. Smisek, Collect.
Czech. Chem. Commun. 34, 2249–2257 共1969兲.
69/15 J. Cidlinsky and J. Polak, Collect. Czech. Chem. Commun. 34,
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69/16 F. Franks and B. Watson, Trans. Faraday Soc. 65, 2339–2349
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69/17 N. G. Krokhin, Russ. J. Phys. Chem. 43, 1342–1343 共1969兲.
69/18 M. Mansson, J. Chem. Thermodyn. 1, 141–151 共1969兲.
69/19 I. Brown, W. Fock, and F. Smith, J. Chem. Thermodyn. 1,
273–291 共1969兲.
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Zh. Fiz. Khim. 43, 733–736 共1969兲; Chem. Abstracts 71, 6729g 共1969兲.
69/21 J. Vojtko, M. Cihova, and M. Hrusovsky, Zb. Pr. Chem.-Tech. Fak.
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69/22 O. Glemser and S. P. Von Halasz, Inorg. Nucl. Chem. Lett. 5,
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69/23 R. Lamantine and R. Perrin, Bull. Soc. Chim. France 443– 445
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69/24 H. Mackle, D. V. McNally, and W. V. Steele, Trans. Faraday Soc.
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69/25 S. Meszaros, Period. Poltech. Chem. Eng. 共Budapest兲 13, 79– 88
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69/26 O. Glemser, R. Mews, and H. W. Roesky, J. Chem. Soc., Chem.
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69/27 Y. K. Shaulov, A. K. Federov, and V. G. Genchel, Zh. Fiz Khim.
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69/28 J. E. Sicre, J. T. Dubois, K. J. Eisentraut, and R. E. Sievers, J. Am.
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69/29 M. A. Soulie, P. Goursot, A. Peneloux, and J. Metzger, J. Chim.
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69/30 M. Ya. Agarunov and S. N. Hajiev, Dokl. Akad. Nauk. SSSR 185,
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69/31 T. Melia and R. Merrifield, J. Appl. Chem. 共London兲 19, 79– 82
共1969兲.
69/32 J. Mason, J. Chem. Soc. A 1587–1592 共1969兲.
69/33 B. J. Aylett and M. J. Hakim, J. Chem. Soc. A 800– 803 共1969兲.
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69/35 B. J. Aylett and M. J. Hakim, J. Chem. Soc. A 639– 642 共1969兲.
69/36 B. J. Aylett and J. M. Campbell, J. Chem. Soc. A 1910–1916
共1969兲.
69/37 B. J. Aylett and J. M. Campbell, J. Chem. Soc. A 1916 –1920
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69/38 B. J. Aylett, J. M. Campbell, and A. Walton, J. Chem. Soc. A
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1970
70/1 A. J. Valerga, Dissertation Abstracts 31, 3316-B 共1970–1971兲.
70/2 D. Ambrose and C. H. S. Sprake, J. Chem. Thermodyn. 2, 631– 645
共1970兲.
70/3 J. Polak, S. Murakami, V. T. Lam, and G. C. Benson, J. Chem. Eng.
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70/4 D. Ambrose, J. F. Counsell, and A. J. Davenport, J. Chem.
Thermodyn. 2, 283–294 共1970兲.
70/5 E. D. Smith and W. L. Thornsberry, J. Chem. Eng. Data 15,
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70/6 R. M. Varushchenko, N. A. Belikova, S. M. Skuratov, and A. F.
Plate, Zh. Fiz. Khim. 44, 3022–3025 共1970兲.
70/7 D. N. Andreevskii and M. M. Brazhnikov, Vestn. Beloruss. Univ. 2,
14 –18 共1970兲; Chem. Abstracts 76, 158651s 共1972兲.
70/8 J. Konicek and I. Wadso, Acta Chem. Scand. 24, 2612–2616
共1970兲.
70/9 R. J. Irving and I. Wadso, Acta Chem. Scand. 24, 589–593 共1970兲.
70/10 G. A. Carpenter, M. F. Zimmer, E. E. Baroody, and R. A. Robb, J.
Chem. Eng. Data 15, 150–153 共1970兲.
70/11 W. D. Good and R. T. Moore, J. Chem. Eng. Data 15, 150–153
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70/12 A. K. Goncharov, M. Kh. Karapet’yants, and G. M. Kol’yakova,
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70/13 J. E. Smith and G. H. Cady, Inorg. Chem. 9, 1293–1294 共1970兲.
70/14 J. Dykyj and A. Vanko, Petrochemica 10, 3–22 共1970兲.
70/15 L. M. Zaborowski and J. M. Shreeve, J. Am. Chem. Soc. 92,
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70/16 J. Dykyj, Petrochemica 10, 51–59 共1970兲; 123–146 共1970兲; 10,
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70/17 K. Kusano and I. Wadso, Acta Chem. Scand. 24, 2037–2042
共1970兲.
70/18 P. Sellers, J. Chem. Thermodyn. 2, 211–219 共1970兲.
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70/19 D. Harrop, A. J. Head, and G. B. Lewis, J. Chem. Thermodyn. 2,
203–210 共1970兲.
70/20 J. F. Counsell, J. O. Fenwick, and E. B. Lees, J. Chem.
Thermodyn. 2, 367–372 共1970兲.
70/21 M. Prochazka, V. Krestanova, J. Konicek, and M. Smisek, Collect.
Czech. Chem. Commun. 35, 727–732 共1970兲.
70/22 E. Koizumi and S. Ouchi, Nippon Kagaku Zasshi 91, 501–503
共1970兲.
70/23 D. W. Scott, J. Chem. Thermodyn. 2, 833– 837 共1970兲.
70/24 O. Eisen and A. Orav, Eesti Tead. Akad. Toim., Keem. Geol. 19,
202–205 共1970兲.
70/25 A. J. Valerja and J. E. Kilpatrick, J. Chem. Phys. 52, 4545– 4549
共1970兲.
70/26 A. B. Burg and D.-K. Kang, J. Am. Chem. Soc. 92, 1901–1908
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70/27 S. P. Von Halasz and O. Glemser, Chem. Ber. 103, 553–560
共1970兲.
70/28 J. Vojtko, M. Cihova, and M. Hrusovsky, Chem. Zvesti 24,
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70/29 A. Finch, P. J. Gardner, P. McNamara, and G. R. Wellum, J. Chem.
Soc. A 3339–3345 共1970兲.
70/30 S.-J. Chang, D. McNally, S. Sharry-Tehrany, M. J. Hickey, and R.
H. Boyd, J. Am. Chem. Soc. 92, 3109–3118 共1970兲.
70/31 J. D. Cox and G. Pilcher, Thermochemistry of Organic and
Organometallic Compounds 共Academic, London, 1970兲.
70/32 Y. K. Shaulov, A. K. Federov, G. Y. Zueva, G. V. Borisyuk, and V.
G. Genchen, Russ. J. Phys. Chem. 44, 1181–1182 共1970兲; Zh. Fiz. Khim.
44, 2081–2083; Chem. Abstracts 74, 7230m 共1971兲.
70/33 M. G. Barlow, R. N. Haszeldine, and R. Hubbard, J. Chem. Soc. C
1232–1237 共1970兲.
70/34 F. I. Mullayanov, G. V. Galagan, M. F. Buz’ko, Yu. V. Churkin,
and A. A. Shiryaeva, Tr. Nauch-Issled. Inst. Neftekhim. Proizvod. 95–97
共1970兲; Chem. Abstracts 74, 91930v 共1971兲.
70/35 A. K. Baev, Obshch. Prikl. Khim. 146 –160 共1970兲; Chem.
Abstracts 74, 91934z 共1971兲.
70/36 V. D. Moisev and N. D. Antonova, Zh. Fiz. Khim. 44, 2912–2913
共1970兲; Chem. Abstracts 69, 80487e 共1971兲.
70/37 V. B. Sokolov, M. Kh. Karapet’yants, and A. K. Goncharov, Tr.
Mosk. Khim.-Tekhnol. Inst. 67, 37–39 共1970兲; Chem. Abstracts 75,
122149z 共1971兲.
70/38 P. Sellers, Acta Chem. Scand. 24, 2453–2458 共1970兲.
1971
71/1 J. K. Choi and M. J. Joncich, J. Chem. Eng. Data 16, 87–90 共1971兲.
71/2 H. K. Hall, Jr. and J. H. Baldt, J. Am. Chem. Soc. 93, 140–145
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71/3 C. Eon, C. Pommier, and G. Guiochon, J. Chem. Eng. Data 16,
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71/4 E. F. Meyer, T. A. Renner, and K. S. Stec, J. Phys. Chem. 76,
642– 648 共1971兲.
71/5 K. Kusano and I. Wadso, Acta Chem. Scand. 25, 219–224 共1971兲.
71/6 Yu. N. Matyushin, V. I. Pepekin, S. P. Golova, T. I. Godovikova,
and L. I. Khmelnitskii, Bull Acad. Sci. USSR, Div. Chem. Sci. 162–164
共1971兲.
71/7 E. Morawetz, Chem. Scripta 1, 103–111 共1971兲.
71/8 P. Sellers, Acta Chem. Scand. 25, 2189–2193 共1971兲.
71/9 K. Kusano and I. Wadso, Bull. Chem. Soc. Jpn. 44, 1705–1707
共1971兲.
71/10 N. D. Lebedeva, Yu. A. Katin, and G. Ya. Akhmedova, Russ. J.
Phys. Chem. 45, 1192–1193 共1971兲.
71/11 V. B. Sokolov, M. Kh. Karapet’yants, N. D. Rumyantseva, and V.
A. Drozdov, Russ. J. Phys. Chem. 45, 1332–1333 共1971兲.
71/12 A. K. Goncharov, M. Kh. Karapet’yants, and T. K. Gar, Russ. J.
Phys. Chem. 45, 104 –105 共1971兲.
71/13 N. D. Lebedeva, Yu. A. Katin, and G. Ya. Akhmedova, Russ. J.
Phys. Chem. 45, 771–772 共1971兲.
71/14 A. K. Baev, V. V. Dem’yanchuk, G. Girzoev, G. I. Novikov, and N.
E. Kolobova, Russ. J. Phys. Chem. 45, 777–778 共1971兲.
71/15 V. E. Ditsent, I. I. Skorokhodov, N. A. Terent’eva, and M. N.
Zolotareva, Russ. J. Phys. Chem. 45, 901–902 共1971兲.
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71/16 I. I. Skorokhodov, V. E. Ditsent, N. A. Teret’eva, and M. N.
Zolotarev, Russ. J. Phys. Chem. 45, 902 共1971兲.
71/17 F. Swindell, L. M. Zaborowski, and J. M. Shreeve, Inorg. Chem.
10, 1635–1638 共1971兲.
71/18 R. A. De Marco and J. M. Shreeve, Inorg. Chem. 10, 911–913
共1971兲.
71/19 L. M. Zaborowski and J. M. Shreeve, Inorg. Chem. 10, 407– 409
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71/20 D. T. Sauer and J. M. Shreeve, Inorg. Chem. 10, 358 –362 共1971兲.
71/21 J. Dykyj, Petrochemia 11, 27– 45 共1971兲.
71/22 Z. I. Geller, V. D. Simonov, M. V. Lyubarskii, E. A. Brakhfogel, L.
M. Meizler, and I. A. Paramonov, Izv. Uyssh. Ucheb. Zaved., Nept. Gaz
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71/23 I. Mita, I. Imai, and I. Kambe, Thermochimica Acta 2, 337–344
共1971兲.
71/24 L. A. Nisel’son, K. V. Tret’yakova, E. P. Paremuzov, and E. N.
Torbina, Izv. Akad. Nauk SSSR, Neorg. Mater. 7, 792–794 共1971兲;
Chem. Abstracts 75, 67746q 共1971兲.
71/25 B. Ringner, S. Sunner, and H. Watanabe, Acta Chem. Scand. 25,
141–146 共1971兲.
71/26 K. Pihlaja and M.-L. Tuomi, Acta Chem. Scand. 25, 465– 469
共1971兲.
71/27 J. Polak and G. C. Benson, J. Chem. Thermodyn. 3, 235–242
共1971兲.
71/28 R. C. Wihoit and B. J. Zwolinski, Handbook of Vapor Pressures
and Heats of Vaporization of Hydrocarbons and Related Compounds, API
44-TRC 共Publications in Science and Engineering, College Station, TX,
1971兲.
71/29 I. B. Rabinovich, E. G. Kiparisov, and Y. A. Aleksandrov, Dokl.
Akad. Nauk. SSSR 200, 1116 –1118 共1971兲.
71/30 G. M. Kol’yakova, I. B. Rabinovich, and N. S. Vyazankin, Dokl.
Akad. Nauk. SSSR 200, 111–113 共1971兲.
71/31 P. Sellers, Acta Chem. Scand. 25, 2099–2102 共1971兲.
71/32 I. E. Nakhutin, N. M. Smirnova, V. I. Krivenko, and G. A.
Loshakov, Zh. Obshch. Khim. 41, 940–943 共1971兲; Chem. Abstracts 75,
122154x 共1971兲.
71/33 S. A. Voitkevich, M. M. Shchedrina, N. P. Solov’eva, and T. A.
Rudol’fi, Maslo-Zhir. Prom. 37, 27–30 共1971兲.
71/34 D. T. Sauer and J. M. Shreeve, J. Fluorine Chem. 1, 1–11 共1971兲.
71/35 D. W. Osborne, F. Schreiner, and H. Selig, J. Chem. Phys. 54,
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71/36 W. D. Good and R. T. Moore, J. Chem. Thermodyn. 3, 701–705
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71/37 F. E. Rodgers, J. Phys. Chem. 75, 1734 –1737 共1971兲.
1972
72/1 M. Colomina, J. L. Laynez, R. Perez-Ossorio, and C. Turrion, J.
Chem. Thermodyn. 4, 499–506 共1972兲.
72/2 E. L. Pace and P. E. Hodge, J. Chem. Thermodyn. 4, 441– 447
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72/3 M. Mansson, J. Chem. Thermodyn. 4, 865– 871 共1972兲.
72/4 J. F. Counsell and D. A. Lee, J. Chem. Thermodyn. 4, 915–917
共1972兲.
72/5 R. Prydz and R. D. Goodwin, J. Chem. Thermodyn. 4, 123–127
共1972兲.
72/6 T. Boublik and K. Aim, Collect. Czech. Chem. Commun. 37, 3513
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72/7 R. M. Varuschenko and A. I. Druzhinina, Zh. Fiz. Khim. 46, 1313
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72/8 G. Jakli and W. A. Van Hook, J. Chem. Thermodyn. 4, 857– 864
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72/9 D. Ambrose, C. H. S. Sprake, and R. Townsend, J. Chem.
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72/10 A. K. Goncharov and M. Kh. Karapet’yants, Zh. Fiz. Khim. 46,
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72/11 W. D. Good, J. Chem. Eng. Data 17, 158 –162 共1972兲.
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72/13 V. B. Sokolov, M. Kh. Karapet’yants, S. P. Kolesnikov, B. L.
Perl’mutter, and O. M. Nefedov, Tr. Mosk. Khim.-Tekhnol. Inst. 71, 6 –7
共1972兲; Chem. Abstracts 80, 100456y 共1974兲.
72/14 V. B. Sokolov, G. P. Bragin, and M. Kh. Karapet’yants, Tr. Mosk.
Khim.-Tekhnol. Inst. 71, 8 –9 共1972兲; Chem. Abstracts 80, 100457z
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72/15 G. P. Brajin, M. Kh. Karapet’yants, A. K. Goncharov, and G. M.
Kol’yakova, Tr. Mosk. Khim.-Tekhnol. Inst. 71, 10–12 共1972兲; Chem.
Abstracts 80, 100458a 共1974兲.
72/16 V. E. Ditsent, I. I. Skorokhodov, N. A. Terent’eva, and M. N.
Zolotareva, Russ. J. Phys. Chem. 46, 317–318 共1972兲; Zh. Fiz. Khim.
46, 544 共1972兲; Chem. Abstracts 77, 9812p 共1972兲.
72/17 E. A. Volchkova, D. D. Smol’yaminova, V. G. Genchel, I. L.
Lopatkina, and Yu. Kh. Shaulova, Russ. J. Phys. Chem. 46, 1053–1054
共1972兲.
72/18 R. H. T. Bleyerveld and W. Fieggen, Recl. Trav. Chim. Pays-Bas
91, 477– 482 共1972兲; Chem. Abstracts 76, 145167p 共1972兲.
72/19 V. E. Ditsent, I. I. Skorokhodov, N. A. Terent’eva, and M. N.
Zolotareva, Russ. J. Phys. Chem. 46, 1088 共1972兲; Zh. Fiz. Khim. 46,
1887–1888 共1972兲; Chem. Abstracts 77, 106168r 共1972兲; 77, 106166p
共1972兲.
72/20 J. Dykyj, Petrochemia 12, 13–31 共1972兲; 12, 34 – 63 共1972兲.
72/21 R. F. Swindell and J. M. Shreeve, J. Am. Chem. Soc. 94, 5713–
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72/22 S. G. Metcalf and J. M. Shreeve, Inorg. Chem. 11, 1631–1634
共1972兲.
72/23 S. R. O’Neill and J. M. Shreeve, Inorg. Chem. 11, 1629–1631
共1972兲.
72/24 R. F. Swindell, D. P. Babb, T. J. Ouellette, and J. M. Shreeve,
Inorg. Chem. 11, 242–245 共1972兲.
72/25 D. T. Sauer and J. M. Shreeve, Inorg. Chem. 11, 238 –242 共1972兲.
72/26 Ya. A. Strepikheev, O. P. Novikova, and A. L. Chimishkyan, Khim.
Prom. 共Moscow兲 48, 230–231 共1972兲; Chem. Abstracts 69, 145717t
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72/27 G. Geiseler and J. Sawitowsky, Z. Phys. Chem. 共Leipzig兲 250,
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72/28 E. Morawetz, J. Chem. Thermodyn. 4, 455– 460 共1972兲.
72/29 E. Morawetz, J. Chem. Thermodyn. 4, 139–144 共1972兲.
72/30 J. B. Pedley and B. S. Iseard, CATCH Tables, Silicon Compounds
共University of Sussex Press, Brighton, 1972兲.
72/31 G. M. Kol’yakova, I. B. Rabinovich, E. N. Gladyshev, and N. S.
Vyazankin, Dokl. Akad. Nauk. SSSR 204, 356 –358 共1972兲.
72/32 A. Finch, P. J. Gardner, and A. F. Webb, J. Chem. Thermodyn. 4,
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72/33 R. Sabbah, R. Chastel, and M. Laffitte, Thermochimica Acta 5,
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72/34 L. A. Nisel’son, T. D. Sokolova, and R. K. Nikolaev, Vestn. Mosk.
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72/35 M. Nishimura, M. Hakayama, and T. Yano, J. Chem. Eng. Jpn. 5,
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72/36 G. K. Johnson, P. A. G. O’Hare, and E. H. Appelman, Inorg.
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72/37 V. A. Granzhan and E. A. Salganikov, Tr. Nauch.-Issled. Proekt.
Inst. Azotn. Prom. Prod. Org. Sin. 85– 87 共1972兲; Chem. Abstracts 79,
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72/38 K. Nakanishi and O. Toyama, Bull. Chem. Soc. Jpn. 45, 3210–
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72/39 D. E. J. Arnold, E. A. V. Ebsworth, H. F. Jessep, and D. W. H.
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72/40 R. A. De Marco and J. M. Shreve, J. Fluorine Chem. 1, 269–276
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72/41 J. Laynez and I. Wadso, Acta Chem. Scand. 26, 3148 –3152
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72/42 M. Mansson, Acta Chem. Scand. 26, 1707–1708 共1972兲.
72/43 F. E. Rogers, J. Phys. Chem. 75, 1734 –1737 共1971兲.
1973
73/1 H. K. Hall, Jr., C. D. Smith, and J. H. Bald, J. Am. Chem. Soc. 95,
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73/2 J. W. Wilson and J. T. F. Fenurck, J. Chem. Thermodyn. 5, 341–345
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73/4 G. R. De Mare, T. Lehman, and M. Termonia, J. Chem. Thermodyn.
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73/5 D. H. Rochester and J. R. Symonds, J. Chem. Soc., Faraday Trans.
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73/6 J. Konicek, Acta Chem. Scand. 27, 1496 –1502 共1973兲.
73/7 D. Ambrose, C. H. S. Sprake, and R. Townsend, J. Chem. Soc.,
Faraday Trans. 1 69, 839– 841 共1975兲.
73/8 H.-J. Rauh, W. Geyer, H. Schmidt, and G. Z. Geiseler, Phys. Chem.
共Leipzig兲 253, 43– 48 共1973兲.
73/9 F. A. Gothard, D. C. Mentianu, D. G. Breban, and C. I. Cristea, J.
Chem. Eng. Data 18, 381–384 共1973兲.
73/10 E. A. Dietz and D. R. Martin, J. Inorg. Nucl. Chem. 35, 3681–
3684 共1973兲.
73/11 G. F. Carruth and R. Kobayashi, J. Chem. Eng. Data 18, 115–126
共1973兲.
73/12 E. F. Meyer and R. D. Hotz, J. Chem. Eng. Data 18, 359–362
共1973兲.
73/13 V. Svoboda, F. Vesely, R. Holub, and J. Pick, Collect. Czech.
Chem. Commun. 38, 3539–3543 共1973兲.
73/14 J. Linek and I. Wichterle, Collect. Czech. Chem. Commun. 38,
1846 –1852 共1973兲.
73/15 I. N. Fel’dman, V. V. Savko, U. I. Mamai, and M. F. Finkel’shtein,
Russ. J. Phys. Chem. 47, 1531 共1973兲.
73/16 N. N. D’yachkova, E. N. Vigdorovich, and L. A. Ivanyutin, Russ.
J. Phys. Chem. 47, 258 –259 共1973兲.
73/17 G. L. Gal’chenko, E. P. Brykina, R. M. Varushchenko, L. S.
Vasil’ev, and B. N. Mikhailov, Russ. J. Phys. Chem. 47, 914 共1973兲.
73/18 J. Kkykj and M. Repas, Petrochemia 13, 179–198 共1973兲.
73/19 C. J. Schack, D. Pilipovich, and J. F. Hon, Inorg. Chem. 12,
897–900 共1973兲.
73/20 A. Majid and J. M. Shreeve, J. Org. Chem. 38, 4028 – 4031 共1973兲.
73/21 G. H. Sprenger, K. J. Wright, and J. M. Shreeve, Inorg. Chem. 12,
2890–2893 共1973兲.
73/22 R. A. De Marco and J. M. Shreeve, Inorg. Chem. 12, 1896 –1899
共1973兲.
73/23 K. J. Wright and J. M. Shreeve, Inorg. Chem. 12, 77– 80 共1973兲.
73/24 C. S.-C. Wang and J. M. Shreeve, Inorg. Chem. 12, 81– 83 共1973兲.
73/25 V. I. Pepekin, Yu. A. Lebedev, and A. Ya. Apin, Dokl. Phys. Chem.
208, 35–37 共1973兲.
73/26 R. C. Wilhoit and B. J. Zwolinski, J. Phys. Chem. Ref. Data
共Suppl. 1兲 2, 1-1–1-420 共1973兲. 关Note: The authors report Antoine
constants for numerous alcohols that were calculated from vapor pressure
data taken from the published literature. For several of the alcohols, the
authors had only a very limited number of experimental data points that
were pooled from several sources.兴
73/27 W. Waradzin and P. Skubla, Chem. Prum. 23, 556 –557 共1973兲;
Chem. Abstracts 80, 112780n 共1974兲.
73/28 P. D. Dawson, Jr., I. M. Silberberg, and J. J. McKetta, J. Chem.
Eng. Data 18, 7–15 共1973兲.
73/29 D. V. S. Jain and O. P. Yadav, Indian J. Chem. 11, 28 –30 共1973兲.
73/30 H.-D. Beckhaus and C. Rüchardt, Tetrahedron Lett. 1971–1974
共1973兲.
73/31 G. M. Kol’yakova, I. B. Rabinovich, and E. N. Zorina, Dokl.
Akad. Nauk. SSSR 209, 616 – 617 共1973兲.
73/32 V. I. Tel’noi, I. B. Rabinovich, and V. A. Umilin, Dokl. Akad.
Nauk. SSSR 209, 127–129 共1973兲.
73/33 D. S. Barnes and C. T. Mortimer, J. Chem. Thermodyn. 5,
371–377 共1973兲.
73/34 B. J. Aylett, I. A. Ellis, and C. J. Porritt, J. Chem. Soc., Dalton
Trans. 83– 87 共1973兲.
73/35 B. J. Aylett, I. A. Ellis, and J. R. Richmond, J. Chem. Soc., Dalton
Trans. 981–987 共1973兲.
73/36 A. Blair and H. Ihle, J. Inorg. Nucl. Chem. 35, 3795–3803 共1973兲.
73/37 P. A. Bernstein and D. D. Desmarteau, J. Fluorine Chem. 2,
315–321 共1973兲.
73/38 T. Abe and J. M. Shreeve, J. Fluorine Chem. 3, 17–26 共1973/
1974兲.
ENTHALPIES OF VAPORIZATION
1974
74/1 R. A. Murogova, G. L. Tudorovskaya, V. V. Laufer, V. D. Koxlova,
and L. A. Seraphimov, Zh. Prikl. Khim. 47, 2024 –2027 共1974兲.
74/2 S. Sunner and C. A. Wulff, J. Chem. Thermodyn. 6, 287–292
共1974兲.
74/3 W. D. Good, R. T. Moore, A. G. Osborn, and D. R. Douslin, J.
Chem. Thermodyn. 6, 303–310 共1974兲.
74/4 T. M. Letcher and F. Marsicano, J. Chem. Thermodyn. 6, 509–514
共1974兲.
74/5 R. M. Varushchenko and L. L. Bulgakova, Tr. Khim. Khim. Teknol.
1, 69–74 共1974兲.
74/6 D. Ambrose, C. H. S. Sprake, and R. Townsend, J. Chem.
Thermodyn. 6, 693–700 共1974兲.
74/7 L. F. Myasinkova, V. A. Schmelev, I. L. Vaisman, V. I. Bushinskii,
and D. A. Novokhatka, Zh. Prikl. Khim. 共Leningrad兲 47, 2604 –2606
共1974兲.
74/8 D. Ambrose and C. H. S. Sprake, J. Chem. Thermodyn. 6, 453– 456
共1974兲.
74/9 H. F. Gibbard and J. L. Creek, J. Chem. Eng. Data 19, 308 –310
共1974兲.
74/10 J. Dojcansky and J. Heinrich, Chem. Zvesti 28, 157–159 共1974兲;
Chem. Abstracts 82, 64723p 共1975兲.
74/11 A. G. Osborn and D. R. Douslin, J. Chem. Eng. Data 19, 114 –117
共1974兲.
74/12 P. H. Mogul, M. C. Hochberg, R. Michiel, G. K. Nestel, B. L.
Wamsley, and S. D. Coren, J. Chem. Eng. Data 19, 4 – 6 共1974兲.
74/13 D. Ambrose and J. H. Ellender, J. Chem. Thermodyn. 6, 909–914
共1974兲.
74/14 K. Kusano and Y. Saito, Preprints 10th Conference Chemical
Thermodyn. Thermal Analysis, Japan 1974, p. 155; as quoted in 关85/6兴.
74/15 V. N. Kiva, S. I. Nadutkina, L. V. Ivanova, and V. S. Bogdanov,
Russ. J. Phys. Chem. 48, 297 共1974兲.
74/16 G. O. Shmyreva, R. M. Golosova, G. B. Sakharovskaya, A. F.
Popov, N. N. Korneev, and A. A. Smolyaninova, Russ. J. Phys. Chem.
48, 447 共1974兲.
74/17 V. E. Ditsent, I. I. Skorokhodov, N. A. Terent’eva, and M. N.
Zolotareva, Russ. J. Phys. Chem. 48, 447 共1974兲; Zh. Fiz. Khim. 48,
2152–2153 共1974兲; Chem. Abstracts 81, 158939v 共1974兲.
74/18 G. P. Bragin and M. Kh. Karapet’yants, Russ. J. Phys. Chem. 48,
612 共1974兲.
74/19 I. L. Gaidym, A. K. Vaev, V. G. Syrkin, A. A. Uel’skii, and A. E.
Medvedeva, Russ. J. Phys. Chem. 48, 1111 共1974兲; Chem. Abstracts 69,
160019p 共1974兲.
74/20 R. M. Varushchenko, A. I. Druzhimina, O. Ya. Kovner, E. M.
Mil’vitskaya, A. A. Bobyleva, N. A. Belikova, and G. L. Gal’chenko,
Russ. J. Phys. Chem. 48, 1121 共1974兲.
74/21 V. E. Ditsent, I. I. Skorokhodov, N. A. Terent’eva, M. N.
Zolotareva, and M. B. Lotarev, Russ. J. Phys. Chem. 48, 1279 共1974兲;
Zh. Fiz. Khim. 48, 2152 共1974兲; Chem. Abstracts 81, 158938u 共1974兲.
74/22 N. A. Bessareb and Yu. M. Martynov, Russ. J. Phys. Chem. 48,
1547–1548 共1974兲.
74/23 G. O. Shmyreva, V. G. Shlyakova, R. M. Golosova, G. G.
Filippov, E. A. Volnina, E. N. Burdasov, and L. E. Gusel’nikov, Russ. J.
Phys. Chem. 48, 1699–1700 共1974兲.
74/24 K. E. Peterman and J. M. Shreeve, Inorg. Chem. 13, 2705–2709
共1974兲.
74/25 A. Majid and J. M. Shreeve, Inorg. Chem. 13, 2710–2714 共1974兲.
74/26 L. V. Mozhginskay and L. E. Kolysko, Zh. Fiz. Khim. 48,
1506 –1507 共1974兲.
74/27 A. G. Gilbert and K. G. P. Sulzmann, J. Electrochem. Soc. 121,
832– 834 共1974兲.
74/28 R. Sabbah, R. Chastel, and M. Laffitte, Thermochimica Acta 10,
353–358 共1974兲.
74/29 L. Malaspina, G. Bardi, and R. Gigli, J. Chem. Thermodyn. 6,
1053–1064 共1974兲.
74/30 P. Beak, D. S. Mueller, and J. Lee, J. Am. Chem. Soc. 96,
3867–3874 共1974兲.
867
74/31 V. E. Ditsent, I. I. Skorokhodov, N. A. Terent’eva, M. N.
Zolotareva, B. N. Parfenov, and O. I. Minosyan, Zh. Fiz. Khim. 48, 2151
共1974兲; Chem. Abstracts 81, 158937t 共1974兲.
74/32 P. S. Engel, J. L. Wood, J. A. Sweet, and J. L. Margrave, J. Am.
Chem. Soc. 96, 2381–2387 共1974兲.
74/33 M. P. Kozina, L. V. Bychikhina, G. L. Gal’chenko, A. N.
Kalinichenko, A. A. Bobyleva, N. A. Belikova, and A. F. Plate, Zh. Fiz.
Khim. 48, 2075–2077 共1974兲; Chem. Abstracts 81, 159978u 共1974兲.
74/34 V. E. Ditsent, I. I. Skorokhodov, N. A. Terent’eva, M. N.
Zolotareva, N. E. Rodzecich, and O. I. Minosyan, Zh. Fiz. Khim. 48,
2153 共1974兲; Chem. Abstracts 81, 158940p 共1974兲.
74/35 C.-F. Shieh and N. W. Gregory, J. Chem. Eng. Data 19, 11–14
共1974兲.
74/36 Y. Sassa, R. Konishi, and T. Katayama, J. Chem. Eng. Data 19,
44 – 48 共1974兲.
74/37 M. Mansson, Acta Chem. Scand. 28B, 905–908 共1974兲.
74/38 G. H. Spenger and J. M. Shreeve, J. Fluorine Chem. 4, 201–205
共1974兲.
1975
75/1 S. Cabani, G. Conti, V. Mollica, and L. Lepori, J. Chem. Soc.,
Faraday Trans. 1 71, 1943–1945 共1975兲.
75/2 R. J. Irving and M. A. V. Riebeiro da Silva, J. Chem. Soc., Dalton
Trans. 798 – 800 共1975兲.
75/3 J. O. Fenwick, D. Harrop, and A. J. Head, J. Chem. Thermodyn. 7,
943–954 共1975兲.
75/4 J. F. Messerly, H. L. Finke, A. G. Osborn, and D. R. Douslin, J.
Chem. Thermodyn. 7, 1029–1046 共1975兲.
75/5 D. Ambrose, J. E. Connett, J. H. S. Green, J. L. Hales, A. J. Head,
and J. F. Martin, J. Chem. Thermodyn. 7, 1143–1157 共1975兲.
75/6 G. Stridh and S. Sunner, J. Chem. Thermodyn. 7, 161–168 共1975兲.
75/7 W. D. Good, J. F. Messerly, A. G. Osborn, and D. R. Douslin, J.
Chem. Thermodyn. 7, 285–291 共1975兲.
75/8 D. Ambrose, J. H. Ellender, E. B. Lees, C. H. S. Sprake, and R.
Townsend, J. Chem. Thermodyn. 7, 453– 472 共1975兲.
75/9 S. Bergstrom and G. Olofsson, J. Solution Chem. 4, 535–555
共1975兲.
75/10 H. Iwasaki and K. Date, Koatsu Gasu 12, 374 –380 共1975兲.
75/11 A. G. Osborn and D. R. Douslin, J. Chem. Eng. Data 20, 229–231
共1975兲.
75/12 K. Kusano and Y. Saito, Preprints 33rd Annical Meeting Chemical
Society Japan, 1975, pp. 1, 123; as quoted in 关85/6兴.
75/13 H. K. Frensdorff and R. K. Adams, J. Chem. Eng. Data 20, 13–15
共1975兲.
75/14 D. J. Subach and B. J. Zwolinski, J. Chem. Eng. Data 20, 232–234
共1975兲.
75/15 V. V. Pisarev, A. M. Rozhnov, R. M. Varushchenko, and A. G.
Sarkisov, Russ. J. Phys. Chem. 49, 1450–1451 共1975兲.
75/16 V. V. Pisarev, H. M. Rozhnov, R. M. Varushchenko, and A. G.
Sarkisov, Russ. J. Phys. Chem. 49, 1605 共1975兲.
75/17 J. Arro, L. Melder, and H. Tamvelius, Trudy Tallinskogo Instit.
Toimetict, 390, 37– 43 共1975兲.
75/18 V. I. Pepekin, Yu. N. Matyushin, A. D. Nikolaeva, A. P. Kirsanov,
L. V. Platonova, and Yu. A. Lebedev, Izv. Akad. Nauk SSSR, Ser. Khim.
1870–1871 共1975兲.
75/19 K. E. Peterman and J. M. Shreeve, Inorg. Chem. 14, 1223–1228
共1975兲.
75/20 K. E. Peterman and J. M. Shreeve, Inorg. Chem. 14, 1106 –1110
共1975兲.
75/21 R. L. Kirchmeier, U. I. Lasouris, and J. M. Shreeve, Inorg. Chem.
14, 592–596 共1975兲.
75/22 N. S. Walker and D. D. DesMarteau, J. Fluorine Chem. 5,
135–139 共1975兲.
75/23 M. M. Brazhnikov, D. N. Andreevskii, A. I. Sachek, and A. D.
Peshchenko, Zh. Prikl. Khim. 共Leningrad兲 48, 2181–2185 共1975兲.
75/24 H. Kundel, U. Lille, and N. Kaidas, Tr. Tallin. Politekh. Inst. 390,
107–115 共1975兲.
75/25 Z. A. Guseinov, A. A. Kuliev, K. A. Karasharli, and O. I.
Dzhafarov, Azerb. Khim. Zh. 72–74 共1975兲; Chem. Abstracts 84, 65359c
共1976兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
868
J. S. CHICKOS AND W. E. ACREE, JR.
75/26 A. Hoepfner, N. Parekh, Ch. Hoerner, and A. Abdel-Hamid, Ber.
Bunsenges Phys. Chem. 79, 216 –222 共1975兲.
75/27 D. Ambrose, J. W. Ellender, C. H. S. Sprake, and R. I. Townsend,
J. Chem. Soc., Faraday Trans. 71, 35– 41 共1975兲.
75/28 Kh. I. Geidarov, O. I. Dzhafarov, and K. A. Karasharli, Russ. J.
Phys. Chem. 49, 197–198 共1975兲.
75/29 V. B. Sokolov, M. Kh. Karapet’yants, T. N. Sergeeva, S. P.
Kolesnikov, and B. L. Perl’mutter, Izv. Vyssh. Uchebn. Zaved., Khim.
Khim. Teknol. 18, 1319–1321 共1975兲; Chem. Abstracts 84, 22433e
共1976兲.
75/30 V. B. Sokolov, M. Kh. Karapet’yants, T. N. Sergeeva, S. P.
Kolesnikov, and B. L. Perl’mutter, Izv. Vyssh. Uchebn. Zaved., Khim.
Khim. Teknol. 18, 1234 –1237 共1975兲; Chem. Abstracts 84, 9167b
共1976兲.
75/31 Z. A. Guseinov, K. A. Karasharli, O. I. Dzharfarov, G. G.
Nurullaev, N. S. Nametkin, L. E. Gusel’nikov, F. A. Volinina, E. N.
Burdasov, and V. N. Vdovin, Dokl. Akad. Nauk 共SSSR兲 222, 1369–1372
共1975兲.
75/32 Ch. Hoerner, A. Hoepfner, and B. Schmeiser, Ber. Bunsenges Phys.
Chem. 79, 222–225 共1975兲.
75/33 F. Rivenq, Bull. Soc. Chim. France 共Pt. 1兲 2433–2434 共1975兲.
75/34 G. P. Bragin and M. Kh. Karapet’yants, Tr. Khim. Khim. Tekhnol.
78 –79 共1975兲; Chem. Abstracts 85, 83381d 共1976兲.
75/35 K. W. Chun, J. C. Drummond, W. H. Smith, and R. R. Davison, J.
Chem. Eng. Data 20, 58 – 61 共1975兲.
75/36 M. E. Anthoney, A. S. Carson, and P. G. Laye, 4th Conference
International Thermodynamics Chim., 关C.R.兴, Vol. 1, pp. 99–103; Chem.
Abstracts 84, 163961n 共1976兲.
75/37 J. F. Masi and R. B. Scott, J. Res. National Bureau Stand., Sect. A
79A, 619– 628 共1975兲.
75/38 D. E. J. Arnold and D. W. H. Rankin, J. Chem. Soc., Dalton Trans.
889– 894 共1975兲.
75/39 R. Vilcu, S. Perisanu, and I. Ciocazanu, 4th Conference
International Thermodynamics, Chim. 关C.R.兴 Vol. 1, pp. 105–112.
75/40 M. Gambaruto, J. E. Sicre, and H. J. Schumacher, J. Fluorine
Chem. 5, 175–179 共1975兲.
75/41 R. A. De Marco, T. A. Kovacina, and W. B. Fox, J. Fluorine
Chem. 6, 93–104 共1975兲.
75/42 K. E. Peterman and J. M. Shreeve, J. Fluorine Chem. 6, 83–92
共1975兲.
75/43 R. A. De Marco, T. A. Kovacina, and W. B. Fox, J. Fluorine
Chem. 5, 221–230 共1975兲.
1976
76/1 G. Stridh, J. Chem. Thermodyn. 8, 193–194 共1976兲.
76/2 D. Ambrose, J. H. Ellender, C. H. S. Sprake, and R. Townsend, J.
Chem. Thermodyn. 8, 165–178 共1976兲.
76/3 P. S. Engel, R. A. Melaugh, M. Mansson, J. W. Timberlake, A. W.
Garner, and F. D. Rossini, J. Chem. Thermodyn. 8, 607– 621 共1976兲.
76/4 R. A. Melaugh, M. Mansson, and F. D. Rossini, J. Chem.
Thermodyn. 8, 623– 626 共1976兲.
76/5 G. Stridh, J. Chem. Thermodyn. 8, 895– 899 共1976兲.
76/6 G. Stridh, J. Chem. Thermodyn. 8, 901–906 共1976兲.
76/7 V. P. Kolesov, G. M. Slavutskaya, and L. N. Dityat’eva, J. Chem.
Thermodyn. 8, 907–914 共1976兲.
76/8 J. E. Connett, J. F. Counsell, and D. A. Lee, J. Chem. Thermodyn.
8, 1199–1203 共1976兲.
76/9 M. E. Anthoney, A. S. Carson, and P. G. Laye, J. Chem. Soc.,
Perkin Trans. 2 1032–1036 共1976兲.
76/10 E. F. Meyer and C. A. Hotz, J. Chem. Eng. Data 21, 274 –279
共1976兲.
76/11 S. J. Ascroft, J. Chem. Eng. Data 21, 397–398 共1976兲.
76/12 K. V. Rao and C. Chiranjivi, J. Chem. Eng. Data 21, 393–394
共1976兲.
76/13 H. C. Hon, R. P. Singh, and A. P. Kudchadker, J. Chem. Eng. Data
21, 430– 431 共1976兲.
76/14 J. Cihlar, V. Hynek, V. Svoboda, and R. Holub, Collect. Czech.
Chem. Commun. 41, 1– 6 共1976兲.
76/15 M. M. Ammar, L. L. Bulgakova, and R. M. Varushchenko, Russ. J.
Phys. Chem. 50, 1466 –1467 共1976兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
76/16 G. K. Borisov and S. G. Chugunova, Russ. J. Phys. Chem. 50,
1791 共1976兲.
76/17 G. O. Shmyreva, V. G. Shlyakova, R. M. Golosova, A. B.
Petrunin, D. B. Bekker, and A. F. Zhigach, Russ. J. Phys. Chem. 50, 478
共1976兲.
76/18 C. A. Burton and J. M. Shreeve, J. Am. Chem. Soc. 98, 6545–
6547 共1976兲.
76/19 K. Steele, B. E. Poling, and D. B. Manley, J. Chem. Eng. Data 21,
399– 403 共1976兲.
76/20 M. M. Brazhnikov, A. D. Peshchenko, and O. V. Ral’ko, Zh. Prikl.
Khim. 共Leningrad兲 49, 1041–1044 共1976兲.
76/21 V. P. Kuznetsova, E. A. Miroshnichenko, A. N. Zelenetskii, G. V.
Rakova, Yu. A. Lebedev, and N. S. Enikolopyan, Dokl. Phys. Chem. 226,
147–150 共1976兲.
76/22 E. G. Kiparisova, L. Ya. Tsvetkova, and B. V. Lebedev, Russ. J.
Phys. Chem. 50, 638 共1976兲.
76/23 D. L. S. Brown, J. A. Connor, M. L. Leung, M. I. Paz-Andrade,
and H. A. Skinner, J. Organomet. Chem. 110, 79– 89 共1976兲.
76/24 V. E. Ditsent, I. I. Skorokhodov, N. A. Terent’eva, M. N.
Zolotareva, Z. V. Belyakova, and Z. V. Belikova, Zh. Fiz. Khim. 50,
1905–1906 共1976兲; Chem. Abstracts 85, 166806x 共1976兲.
76/25 Z. A. Guseimov, A. A. Kuliev, K. A. Karasharli, and O. I.
Dzhafarov, Azerb. Khim. Zh. 72–74 共1975兲; Chem. Abstracts 84, 65359c
共1976兲.
76/26 D. Ambrose and C. H. S. Sprake, J. Chem. Thermodyn. 8,
601– 602 共1976兲.
76/27 W. S. Hamilton, P. Thompson, and S. Pustejovsky, J. Chem. Eng.
Data 21, 428 – 429 共1976兲.
76/28 E. R. Falardeau and D. D. Desmarteau, J. Fluorine Chem. 7,
185–195 共1976兲.
76/29 I. Stahl, R. Mews, and O. Glemser, J. Fluorine Chem. 7, 55– 64
共1976兲.
76/30 E. R. Falardeau and D. D. Desmarteau, J. Fluorine Chem. 7,
409– 414 共1976兲.
76/31 M. J. Hopkinson and D. D. Desmarteau, J. Fluorine Chem. 7,
501–510 共1976兲.
1977
77/1 M. Mansson, P. Sellers, G. Stridh, and S. Sunner, J. Chem.
Thermodyn. 9, 91–97 共1976兲.
77/2 P. Sellers, J. Chem. Thermodyn. 9, 139–142 共1977兲.
77/3 A. S. Carson, P. G. Laye, and M. Yurkeli, J. Chem. Thermodyn. 9,
827– 829 共1977兲.
77/4 W. V. Steele and I. Watt, J. Chem. Thermodyn. 9, 843– 849 共1977兲.
77/5 G. Stridh, S. Sunner, and Ch. Svenson, J. Chem. Thermodyn. 9,
1005–1010 共1977兲.
77/6 P. A. Pella, J. Chem. Thermodyn. 9, 301–305 共1977兲.
77/7 L. A. Peacock and R. Fuchs, J. Am. Chem. Soc. 99, 5524 –5525
共1977兲.
77/8 V. Svoboda, V. Majer, F. Vesely, and J. Pick, Collect. Czech. Chem.
Commun. 42, 1755–1760 共1977兲.
77/9 N. I. Boldenkov and Yu. Ya Maksimov, Zh. Fiz. Khim. 51, 1502–
1504 共1977兲.
77/10 E. F. Meyer and T. H. Gens, J. Chem. Eng. Data 22, 30–31
共1977兲.
77/11 H. K. Cammenga, F. W. Schulze, and W. Theuerl, J. Chem. Eng.
Data 22, 131–134 共1977兲.
77/12 V. Svoboda, F. Vesely, R. Holub, and J. Pick, Collect. Czech.
Chem. Commun. 42, 943–951 共1977兲.
77/13 R. M. Varushchenko, M. M. Ammar, and L. L. Bulgakova, Russ. J.
Phys. Chem. 51, 167–168 共1977兲.
77/14 V. V. Pisarev, A. M. Rozhnov, and A. G. Sarkisov, Russ. J. Phys.
Chem. 51, 323–324 共1977兲.
77/15 T. Kitazume and J. M. Shreeve, J. Am. Chem. Soc. 99, 3690–3695
共1977兲.
77/16 T. Kitazume and J. M. Shreeve, J. Am. Chem. Soc. 99, 4194 – 4196
共1977兲.
77/17 C. A. Burton and J. M. Shreeve, Inorg. Chem. 16, 1039–1042
共1977兲.
ENTHALPIES OF VAPORIZATION
77/18 C. A. Burton and J. M. Shreeve, Inorg. Chem. 16, 1408 –1411
共1977兲.
77/19 T. Kitazume and J. M. Shreeve, Inorg. Chem. 16, 1818 –1819
共1977兲.
77/20 R. M. Varushchenko, M. M. Ammar, and L. L. Bulgakova, Zh. Fiz.
Khim. 51, 278 –279 共1977兲.
77/21 E. Z. Zhuravlev, T. L. Melent’eva, P. V. Mulyanov, A. I.
Kormushechkina, T. M. Bogdanova, and I. I. Konstantinov, Zh. Prikl
Khim. 共Leningrad兲 50, 2032–2035 共1977兲.
77/22 H. L. Finke, J. F. Messerly, S. H. Lee, A. G. Osborn, and D. R.
Douslin, J. Chem. Thermodyn. 9, 937–956 共1977兲.
77/23 J. B. Pedley and J. Rylance, N. P. L. Computer Analyzed
Thermochemical Data: Organic and Organometallic Compounds 共School
of Molecular Sciences, University of Sussex Press, Brighton, UK, 1977兲.
77/24 B. C. Kim and D. H. Kim, Hwahak Kwa Hwahak Kongop 20,
232–234 共1977兲; Chem. Abstracts 88, 95565s 共1978兲.
77/25 N. D. Lebedeva, V. L. Ryadnenko, N. N. Kiseleva, and L. F.
Nazarova, Vses. Konf. Kalorim. 关Rasshir. Tezisy Dokl.兴 7th 1, 91–95
共1977兲; Chem. Abstracts 92, 75617q 共1980兲.
77/26 M. V. Lyubarskii and R. I. Smolyanets, Vses. Konf. Kalorim.
关Rasshir. Tezisy Dokl.兴 7th 1, 119–121 共1977兲; Chem. Abstracts 92,
75619s 共1980兲.
77/27 V. A. Aleshina, M. P. Kozina, and G. L. Gal’chenko, Vses. Konf.
Kalorim. 关Rasshir. Tezisy Dokl.兴 7th 1, 85–91 共1977兲; Chem. Abstracts
92, 94582r 共1980兲.
77/28 L. N. Dityat’eva and V. P. Kolesov, Vses. Konf. Kalorim. 关Rasshir.
Tezisy Dokl.兴 7th 1, 95–97 共1977兲; Chem. Abstracts 92, 58009a 共1980兲.
77/29 T. F. Vasil’eva and V. I. Kotov, Vses. Konf. Kalorim. 关Rasshir.
Tezisy Dokl.兴 7th 1, 102–106 共1977兲; Chem. Abstracts 92, 58010u
共1980兲.
77/30 J. J. Rao and D. S. Viuswanath, J. Chem. Eng. Data 22, 36 –38
共1977兲.
77/31 T. R. Das, C. O. Reed, Jr., and P. T. Eubank, J. Chem. Eng. Data
22, 3–9 共1977兲.
77/32 T. R. Das, C. O. Reed, Jr., and P. T. Eubank, J. Chem. Eng. Data
22, 9–15 共1977兲.
77/33 T. R. Das, C. O. Reed, Jr., and P. T. Eubank, J. Chem. Eng. Data
22, 16 –21 共1977兲.
77/34 N. Novakova and J. Novak, J. Chromatogr. 135, 13–24 共1977兲.
1978
78/1 W. V. Steele, J. Chem. Thermodyn. 10, 919–927 共1978兲.
78/2 R. B. Cundall, T. F. Palmer, and C. E. C. Wood, J. Chem. Soc.,
Faraday Trans. 1 74, 1339–1345 共1978兲.
78/3 P. S. Engel, R. L. Mongomery, M. Mansson, R. A. Leckonby, H. L.
Foyt, and F. D. Rossini, J. Chem. Thermodyn. 10, 205–211 共1978兲.
78/4 D. G. McCormick and W. S. Hamilton, J. Chem. Thermodyn. 10,
275–278 共1978兲.
78/5 B. V. Lebedev, L. Ya. Tsvetkova, and I. B. Rabinovich, J. Chem.
Thermodyn. 10, 809– 815 共1978兲.
78/6 D. Indritz, J. Stone, and F. Williams, J. Chem. Eng. Data 23, 6 –7
共1978兲.
78/7 R. L. Montgomery, F. D. Rossini, and M. Mansson, J. Chem. Eng.
Data 23, 125–129 共1978兲.
78/8 A. H. N. Mousa, J. Chem. Eng. Data 23, 133–134 共1978兲.
78/9 W. S. Hamilton, S. Benton, J. French, D. McCormick, S.
Pustejovsky, and P. Thomspon, J. Chem. Eng. Data 23, 201–203 共1978兲.
78/10 I. K. Igumenov, Yu. V. Chumanchenko, and S. V. Zemskov, Russ.
J. Phys. Chem. 52, 1531–1532 共1978兲.
78/11 Yu. V. Chumachenko, I. K. Igumenov, and S. V. Zemskov, Russ. J.
Phys. Chem. 52, 1393–1394 共1978兲.
78/12 G. O. Shmyreva, V. G. Shlyakova, and R. M. Golosova, Russ. J.
Phys. Chem. 52, 135–136 共1978兲.
78/13 T. D. Grabik, S. G. Konstantinov, G. P. Dudchik, and O. G.
Polyachenok, Russ. J. Phys. Chem. 52, 894 – 895 共1978兲.
78/14 T. Kitazume and J. M. Shreeve, Inorg. Chem. 17, 2173–2176
共1978兲.
78/15 R. P. Corbally, M. J. Perkins, A. S. Carson, P. G. Laye, and W. V.
Steele, J. Chem. Soc., Chem. Commun. 778 –779 共1978兲.
78/16 R. Fuch and L. A. Peacock, Can J. Chem. 56, 2493–2498 共1978兲.
869
78/17 B. V. Lebedev, L. Ya. Tsvetkova, I. B. Rabinovich, E. Sh.
Finkel’shtein, and B. S. Strel’chick, Termodin. Org. Soedin. 7, 3–7
共1978兲; Chem. Abstracts 92, 83507u 共1980兲.
78/18 M. A. V. Ribeiro da Silva and R. G. Irving, Rev. Port. Quim. 20,
36 – 46 共1978兲; Chem. Abstracts 90, 211054s 共1979兲.
78/19 V. P. Kolesov and L. N. Dityat’eva, Termodin. Org. Soedin. 7,
44 – 47 共1978兲; Chem. Abstracts 92, 75657c 共1980兲.
78/20 S. D. Cave, A. Chainese, and A. Prantera, J. Chem. Eng. Data 23,
279–281 共1978兲.
78/21 S. Sundaram and D. S. Viswanath, J. Chem. Eng. Data 23, 63– 64
共1978兲.
78/22 I. Stahl, R. Mews, and O. Glemser, J. Fluorine Chem. 11, 455– 465
共1978兲.
78/23 R. A. De Marco and W. B. Fox, J. Fluorine Chem. 12, 137–151
共1978兲.
1979
79/1 S. Sunner, Ch. Svensson, and A. S. Zelepuga, J. Chem. Thermodyn.
11, 491– 495 共1979兲.
79/2 S. Sunner and Ch. Svensson, J. Chem. Soc., Faraday Trans. 1 75,
2359–2365 共1979兲.
79/3 T. M. Letcher, S. W. Orchard, and M. Albers, J. Chem. Thermodyn.
11, 173–175 共1979兲.
79/4 C. G. De Kruif and H. A. Oonk, J. Chem. Thermodyn. 11, 287–290
共1979兲.
79/5 S. H. Lee-Bechtold, I. A. Hossenlop, D. W. Scott, A. G. Osborn,
and W. D. J. Good, Chem. Thermodyn. 11, 469– 482 共1979兲.
79/6 Ch. Sevensson, J. Chem. Thermodyn. 11, 593–596 共1979兲.
79/7 P. P. S. Saluja, L. A. Peacock, and R. Fuchs, J. Am. Chem. Soc.
101, 1958 –1962 共1979兲.
79/8 L. Petros, V. Majer, J. Koubek, V. Svoboda, and J. Pick, Collect.
Czech. Chem. Commun. 44, 3533–3540 共1979兲.
79/9 V. Majer, V. Svoboda, J. Koubek, and J. Pick, Collect. Czech.
Chem. Commun. 44, 3521–3528 共1979兲.
79/10 M. Balish and V. Fried, J. Chem. Eng. Data 24, 91–92 共1979兲.
79/11 A. B. Macknick and J. M. Prausnitz, J. Chem. Eng. Data 24,
175–178 共1979兲.
79/12 A. P. Kudchadker, S. A. Kudchadker, R. P. Shukla, and P. R.
Patnaik, J. Phys. Chem. Ref. Data 8, 499–513 共1979兲.
79/13 V. Majer, V. Svoboda, S. Hala, and J. Pick, Collect. Czech. Chem.
Commun. 44, 637– 651 共1979兲.
79/14 G. Berthon, V. Angot, V. Beden, and O. Enea, J. Chem.
Thermodyn. 11, 539–546 共1979兲.
79/15 V. S. Markovnik, A. I. Sachek, A. D. Peshchenko, O. V. Shvaro, D.
N. Andreevskii, and N. M. Olizarevich, Termodin. Org. Soedin. 107–110
共1979兲.
79/16 L. H. Thomas, R. Meatyard, H. Smith, and G. H. Davies, J. Chem.
Eng. Data 24, 159–161 共1979兲.
79/17 R. Fuchs and L. A. Peacock, Can. J. Chem. 57, 2302–2304 共1979兲.
79/18 S. I. Sukhova, O. N. Vlasov, and L. V. Li, Nov. Khim. Sredstva
Azsch Rast. 51–52 共1979兲; Chem. Abstracts 92, 83359x 共1980兲.
79/19 W. F. Spencer, T. D. Shoup, M. M. Cliath, W. J. Farmer, and R.
Haque, J. Agric. Food Chem. 27, 273–278 共1979兲.
79/20 I. K. Igumenov, Yu. V. Chumachenko, and S. V. Zemskov, Khim.
Termodin. Termokhim. 65– 66 共1979兲; Chem. Abstracts 91, 217803c
共1979兲.
79/21 V. I. Bludilina, A. K. Baev, V. K. Matveev, I. L. Gaidym, and E. I.
Shcherbina, Zh. Fiz. Khim. 53, 1052–1053 共1979兲; Chem. Abstracts 91,
9585f 共1979兲.
79/22 D. Das, S. R. Dhawadkar, and M. S. Chandraekharaiah,
Thermochimica Acta 30, 371–376 共1979兲.
79/23 P. J. Maher and B. D. Smith, J. Chem. Eng. Data 24, 16 –22
共1979兲.
79/24 M. Zander and W. Thomas, J. Chem. Eng. Data 24, 1–2 共1979兲.
79/25 R. M. Golosova, G. O. Shmyreva, V. G. Shlyakova, A. B.
Petrunin, D. B. Bekker, and A. F. Zhigach, Zh. Fiz. Khim. 53, 766 –767
共1979兲.
79/26 P. Shul’tse, R. M. Varushchenko, G. L. Gal’chenko, T. V. Klimova,
and V. I. Stanko, J. Gen. Chem. USSR 50, 1482–1488 共1979兲; Zh.
Obshch. Khim. 50, 1818 –1825 共1979兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
870
J. S. CHICKOS AND W. E. ACREE, JR.
79/27 J. Carre, P. Claudy, J. M. Letoffe, M. Kollmannsberger, and J.
Bousquet, J. Fluorine Chem. 14, 139–152 共1979兲.
79/28 A. Sekiya and D. D. Desmarteau, J. Fluorine Chem. 14, 289–297
共1979兲.
1980
80/1 V. Majer, L. Svab, and V. Svoboda, J. Chem. Thermodyn. 12,
843– 847 共1980兲.
80/2 R. H. Davies, A. Finch, and P. G. Gardner, J. Chem. Thermodyn.
12, 291–296 共1980兲.
80/3 V. Majer, Z. Wanger, V. Svoboda, and V. Cadek, J. Chem.
Thermodyn. 12, 387–391 共1980兲.
80/4 M. H. Abraham and R. J. Irving, J. Chem. Thermodyn. 12, 539–544
共1980兲.
80/5 R. Fuchs and L. A. Peacock, Can. J. Chem. 58, 2796 –2799 共1980兲.
80/6 C. Van de Rostyne and J. M. Prausnitz, J. Chem. Eng. Data 25, 1–3
共1980兲.
80/7 M. Urbani, R. Gigli, and V. Picente, J. Chem. Eng. Data 25, 97–100
共1980兲.
80/8 E. F. Meyer, M. J. Awe, and R. E. Wagner, J. Chem. Eng. Data 25,
371–374 共1980兲.
80/9 V. Mayer, V. Svoboda, A. Posta, and J. Pick, Collect. Czech. Chem.
Commun. 45, 3063–3069 共1980兲.
80/10 T. Abe and J. M. Shreeve, Inorg. Chem. 19, 3063–3067 共1980兲.
80/11 A. G. Osborn and D. W. Scott, J. Chem. Thermodyn. 12, 429– 438
共1980兲.
80/12 N. K. Smith, R. C. Stewart, Jr., A. G. Osborn, and D. W. Scott, J.
Chem. Thermodyn. 12, 919–926 共1980兲.
80/13 V. Svoboda, V. Uchtyilova, V. Majer, and J. Pick, Collect. Czech.
Chem. Commun. 45, 3233–3240 共1980兲.
80/14 J. A. Jonsson, L. Mathiasson, and A.-M. Olsson, Acta Chem.
Scand. 34A, 147–150 共1980兲.
80/15 L. H. Thomas, H. Smith, and G. H. Davis, J. Chem. Tech.
Biotechnol. 30, 476 – 480 共1980兲.
80/16 H.-D. Beckhaus, G. Kratt, K. Lay, J. Greiselmann, C. Rüchardt, B.
Kitschke, and H. J. Lindner, Chem. Ber. 113, 3441–3455 共1980兲.
80/17 P. Nasir, S. C. Hwang, and R. Kobayashi, J. Chem. Eng. Data 25,
298 –301 共1980兲.
80/18 R. Francesconi, C. Castellari, A. Arcelli, and F. Comelli, Can. J.
Chem. Eng. 58, 113–115 共1980兲.
80/19 J. A. Roth and M. Orchin, J. Organometal. Chem. 187, 103–105
共1980兲.
80/20 N. D. Lebedeva, L. F. Nazarov, and Yu. A. Katin, Zh. Prikl. Khim.
共Leningrad兲 53, 1394 –1395 共1980兲.
80/21 A. Aihara, Denki Tsushin. Daigaku Gakuho 31, 65– 68 共1980兲;
Chem. Abstracts 94, 174045z 共1981兲.
80/22 W. Gombler and H.-U. Weiler, J. Fluorine Chem. 15, 279–288
共1980兲.
80/23 C. R. Patrick and F. Tomes, J. Fluorine Chem. 15, 267–278
共1980兲.
80/24 V. S. Pityugin, T. L. Kislitsyna, R. F. Shakirov, L. N.
Sharif’yanova, and E. N. Maslennikov, Khim. Prom-st., Ser.: Khlornaya
Prom-st. 11–14 共1980兲.
80/25 L. N. Sharif’yanova, F. M. Sadykova, and S. G. Akhmerova,
Khim. Prom-st., Ser.: Khlornaya Prom-st. 16 –18 共1980兲.
1981
81/1 S. A. Wieczorek and P. Kobayashi, J. Chem. Eng. Data 26, 8 –11,
共1981兲; 26, 11–13 共1981兲.
81/2 D. R. Edwards and J. M. Prausnitz, J. Chem. Eng. Data 26,
121–124 共1981兲.
81/3 K. G. De Kruif, J. M. Herman, and P. J. Van den Berg, J. Chem.
Eng. Data 26, 359–362 共1981兲.
81/4 V. Tekac, V. Majer, V. Svoboda, and V. Hynek, J. Chem.
Thermodyn. 13, 659– 662 共1981兲.
81/5 T. S. Papina, P. A. Erastov, and V. P. Kolevsov, J. Chem.
Thermodyn. 13, 683– 689 共1981兲.
81/6 C. G. De Kruif, T. Kuipers, J. C. van Miltenburg, R. C. F. Schaake,
and G. Stevens, J. Chem. Thermodyn. 13, 1081–1086 共1981兲.
81/7 K. Bystrom, J. Chem. Thermodyn. 13, 139–145 共1981兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
81/8 I. A. Hossenlopp and D. W. Scott, J. Chem. Thermodyn. 13,
405– 414 共1981兲.
81/9 I. A. Hossenlopp and D. W. Scott, J. Chem. Thermodyn. 13,
415– 421 共1981兲.
81/10 I. A. Hossenlopp and D. W. Scott, J. Chem. Thermodyn. 13,
423– 428 共1981兲.
81/11 D. Ambrose, J. H. Ellender, H. A. Gundry, D. A. Lee, and R.
Townsend, J. Chem. Thermodyn. 13, 795– 802 共1981兲.
81/12 M. Shimizu, Y. Saito, and K. Kusano, Preprints 17th Conference
on Chemical Thermodynic Thermal Analysis, Japan 1981, p. 50; as
quoted in 关85/6兴.
81/13 V. Majer, V. Svoboda, A. Posta, and J. Pick, Collect. Czech. Chem.
Commun. 46, 817– 822 共1981兲.
81/14 V. Svoboda, V. Charvatova, V. Majer, and J. Pick, Collect. Czech.
Chem. Commun. 46, 2983–2988 共1981兲.
81/15 T. Abe and J. M. Shreeve, Inorg. Chem. 20, 2894 –2899 共1981兲.
81/16 T. Abe and J. M. Shreeve, Inorg. Chem. 20, 2432–2434 共1981兲.
81/17 D. Ambrose and D. J. Hall, J. Chem. Thermodyn. 13, 61– 66
共1981兲.
81/18 G. N. D’yakova, G. L. Korichev, A. D. Korkhova, T. F. Vasil’eva,
and I. A. Vasil’ev, Zh. Prikl. Khim. 共Leningrad兲 54, 1644 –1646 共1981兲.
81/19 J. S. Chickos, A. S. Hyman, L. H. Ladon, and J. F. Liebman, J.
Org. Chem. 46, 4294 – 4296 共1981兲.
81/20 S. N. Guseinova, V. V. Kas’yanov, and Yu. V. Politanskii, Khim.
Prom-st. Ser., Khlornaya Prom-st. 28 –30 共1981兲; Chem. Abstracts 95,
225804b 共1981兲.
81/21 G. M. Wilson, R. H. Johnston, S.-C. Hwang, and C. Tsonopoulos,
Ind. Eng. Chem., Process Des. Dev. 20, 94 –104 共1981兲.
81/22 D. Ferro, V. Piacente, and M. Pelino, Rev. Roum. Chim. 26, 9–15
共1981兲.
81/23 R. M. Varushchenko, L. L. Bulgakova, P. S. Minzabekyants, and
K. N. Makarov, Russ. J. Phys. Chem. 55, 1480–1482 共1981兲.
81/24 V. E. Ditsent, I. I. Skorokhodov, M. N. Zolotareva, V. I. Savuskina,
and B. N. Tabenko, Zh. Prikl. Khim. 共Leningrad兲 54, 1617–1619 共1981兲.
1982
82/1 B. T. Grayson and L. A. Fosbraey, Pestic. Sci. 13, 269–278 共1982兲.
82/2 F. L. Rook, J. Chem. Eng. Data 27, 72–73 共1982兲.
82/3 C. Castellari, R. Francesconi, and F. Comelli, J. Chem. Eng. Data
27, 156 –158 共1982兲.
82/4 G. C. De Kruif, R. C. F. Schaake, J. C. Van Meltenburg, K. Van der
Klauw, and J. G. Blok, J. Chem. Thermodyn. 14, 791–798 共1982兲.
82/5 R. Fuchs, J. H. Hallman, and M. O. Perlman, Can. J. Chem. 60,
1832–1835 共1982兲.
82/6 R. Fuchs, L. A. Peacock, and W. K. Stephenson, Can. J. Chem. 60,
1953–1958 共1982兲.
82/7 B. Gutsche and H. Knapp, Fluid Phase Equilib. 8, 285–300 共1982兲.
82/8 G. S. Hong, R. Wakslak, H. Finston, and V. Fried, J. Chem. Eng.
Data 27, 146 –148 共1982兲.
82/9 K. Bystrom and M. J. Mansson, J. Chem. Soc., Perkin Trans. II
565–569 共1982兲.
82/10 V. Svoboda, V. Charvatova, V. Majer, and V. Hynek, Collect.
Czech. Chem. Commun. 47, 543–549 共1982兲.
82/11 C. Invernizzi, Termotecnica 4, 78 – 85 共1982兲.
82/12 R. M. Varushchenko, S. S. Puchkov, and A. I. Druzinina, Zh. Fiz.
Khim. 56, 2934 –2937 共1982兲.
82/13 A. I. Sachek, A. D. Peshenenko, V. S. Markovnik, O. V. Ral’ko, D.
N. Andreevskii, and A. A. Leont’eva, Termodin. Org. Soedin. 94 –98
共1982兲.
82/14 P. Reche and M.-F. Grenier-Loustalot, J. Chromatogr. 238,
317–334 共1982兲.
82/15 G. Pilcher and H. A. Skinner, in The Chemistry of the
Metal-Carbon Bond, edited by F. R. Hartley and S. Patai 共Wiley, New
York, 1982兲, Chap. 2.
82/16 B. E. Gammon, J. E. Callanan, I. A. Hossenlopp, A. G. Osborn,
and W. D. Good, Proc. Symp. Thermophys. Prop. 8, 402– 408 共1982兲.
82/17 D. J. Wren and A. C. Vikis, J. Chem. Thermodyn. 14, 435– 437
共1982兲.
82/18 J. Furukawa, M. Sakiyama, S. Seki, Y. Saito, and K. Kusano, Bull.
Chem. Soc. Jpn. 55, 3329–3330 共1982兲.
ENTHALPIES OF VAPORIZATION
82/19 R. A. De Marco and W. B. Fox, J. Org. Chem. 47, 3772–3773
共1982兲.
1983
83/1 J. E. House, Jr., Thermochimica Acta 71, 215–218 共1983兲.
83/2 V. Machat, thesis, Utzcht, Prague, 1983.
83/3 V. Uchytilova, V. Majer, V. Svoboda, and V. Hynek, J. Chem.
Thermodyn. 15, 853– 858 共1983兲.
83/4 A. Sivaraman and R. Kobayashi, J. Chem. Thermodyn. 15, 1127–
1135 共1983兲.
83/5 X.-W. An and M. Mansson, J. Chem. Thermodyn. 15, 287–293
共1983兲.
83/6 R. Fuchs and J. H. Hallman, Can. J. Chem. 61, 503–505 共1983兲.
83/7 J. H. Hallman, W. K. Stepenson, and R. Fuchs, Can. J. Chem. 61,
20-44 –2047 共1983兲.
83/8 C. Tsonopoulos and G. M. W. Wilson, AIChE J. 29, 990–999
共1983兲.
83/9 D. Ferro, V. Piacente, and P. Scardala, Thermochimica Acta 68,
329–339 共1983兲.
83/10 A.-M. Olsson, J. A. Jonsson, B. Thelin, and T. Liljefors, J. Chem.
Ecol. 9, 375–385 共1983兲.
83/11 Yu. Ya. Van-Chin-Syan, N. S. Kachurina, G. A. Petrovskaya, and S.
K. Chuchmarev, Russ. J. Phys. Chem. 57, 1751–1752 共1983兲.
83/12 G. Natarajan and D. S. Viswanath, Rev. Sci. Instrum. 54, 1175–
1179 共1983兲.
83/13 A. Tamir, C. Dragoescu, A. Apelblat, and J. Wisniak, Fluid Phase
Equilib. 10, 9– 42 共1983兲.
83/14 T. Schmeling and R. Strey, Ber. Bunsenges. Phys. Chem. 87,
871– 874 共1983兲.
83/15 J. E. House, Jr., J. Fluorine Chem. 22, 299–303 共1983兲.
83/16 R. M. Clay, S. Corr, G. Keenan, and W. V. Steele, J. Am. Chem.
Soc. 105, 2070–2071 共1983兲.
83/17 A. Sivaraman, R. J. Martin, and R. Kobayashi, Fluid Phase
Equilib. 12, 175–188 共1983兲.
1984
84/1 E. Surova, Chem. Zvesti 38, 83–99 共1984兲.
84/2 V. Majer, V. Uchytilova, V. Svoboda, and A. Posta, J. Chem.
Thermodyn. 16, 761–766 共1984兲.
84/3 S. C. Mraw and C. F. Keweshan, J. Chem. Thermodyn. 16,
873– 883 共1984兲.
84/4 V. Majer, V. Svoboda, and M. Lencka, J. Chem. Thermodyn. 16,
1019–1024 共1984兲.
84/5 V. Majer, V. Svoboda, and V. Hynek, J. Chem. Thermodyn. 16,
1059–1066 共1984兲.
84/6 P. Starzewski, I. Wadso, and W. Zielenkiewicz, J. Chem.
Thermodyn. 16, 331–334 共1984兲.
84/7 V. Uchytilova, V. Majer, V. Svoboda, and I. Hemer, J. Chem.
Thermodyn. 16, 475– 479 共1984兲.
84/8 V. Majer, V. Svoboda, J. Pechacek, and S. Hala, J. Chem.
Thermodyn. 16, 567–572 共1984兲.
84/9 T. Boublik, V. Fried, and E. Hala, The Vapor Pressures of Pure
Substances: Selected Values of the Temperature Dependence of the Vapor
Pressures of Some Pure Substances in the Normal and Low Pressure
Region, 2nd revised edition 共Elsevier, Amsterdan, The Netherlands,
1984兲. The vaporization enthalpies were calculated from the vapor
pressures obtained from the Antoine constants reported in this
compendium. In cases where the Antoine constant C⫽0, the Antoine
Equation (log10 P⫽A⫺B/(C⫹T)) reduces to the integrated form of the
Clausius Clapeyron equation directly. This was the case for many
vaporization enthalpies. In those cases where C⫽0, the vaporization
enthalpy was calculated as ⌬H V ⫽2.303RB 关 T/(T⫹C) 兴 2 .
84/10 A. I. Sachek, V. S. Markovnik, A. D. Peshchenko, A. V. Shvaro,
and D. N. Andreevskii, Khim. Prom.-St. 共Moscow兲 337–340 共1984兲.
84/11 A. K. Baev and A. A. Barkatin, Russ. J. Phys. 58, 195–198 共1984兲.
84/12 H.-D. Beckhaus, C. Rüchardt, and M. Smisek, Thermochimica
Acta 79, 149–159 共1984兲.
84/13 A. Sokolovskii and A. K. Baev, Russ. J. Phys. Chem. 58, 195–198
共1984兲.
84/14 G. G. Nurullaev, S. A. Mekhtiev, K. A. Karasharli, N. F. Musaeva,
and M. S. Salakhov, Azerb. Khim. Zh. 132–135 共1984兲.
871
84/15 M.-A. Michou-Saucet, J. Jose, C. Michou-Saucet, and J. C. Merlin,
Thermochimica Acta 75, 85–106 共1984兲.
84/16 A. H. N. Mousa, J. Fluorine Chem. 25, 165–168 共1984兲.
84/17 M. P. Kozina, L. P. Timofeeva, G. L. Gal’chenko, E. S. Balenkova,
and M. D. Ordubadi, Vestn. Mosk. Univ., Ser. 2: Khim. 25, 364 –368
共1984兲; Chem. Abstracts 101, 190955q 共1984兲.
84/18 A. E. Shcherbina, L. M. Kaporovskii, and E. A. Shcherbina, Zh.
Prikl. Khim. 共Leningrad兲 57, 1910–1912 共1984兲; Chem. Abstracts 101,
177895a 共1984兲.
84/19 C. Castellari, R. Francesconi, and F. Comelli, J. Chem. Eng. Data
29, 90–93 共1984兲.
84/20 C. Castellari, R. Francesconi, and F. Comelli, J. Chem. Eng. Data
29, 126 –128 共1984兲.
84/21 S. Putcha, R. V. Ivanturi, and R. Machiraju, J. Chem. Eng. Data
29, 135–136 共1984兲.
84/22 S. R. Bosco and A. G. Turner, J. Chem. Eng. Data 29, 242–243
共1984兲.
84/23 C. Castellari, R. Francesconi, F. Comelli, and S. Ottani, J. Chem.
Eng. Data 29, 283–284 共1984兲.
84/24 H. Katayama and Y. Harada, J. Chem. Eng. Data 29, 373–375
共1984兲.
84/25 A. Sivaraman and R. Kobayashi, J. Chem. Eng. Data 29, 375–379
共1984兲.
84/26 I. Cervenkova and T. Boublik, J. Chem. Eng. Data 29, 425– 427
共1984兲.
84/27 J. T. Sipowska and S. A. Wieczorek, J. Chem. Thermodyn. 16,
693– 699 共1984兲.
84/28 N. D. Lebedeva, N. M. Gutner, Yu. A. Katin, N. M. Kozlova, N.
N. Kiseleva, E. F. Makhina, and S. L. Dobychin, J. Appl. Chem. 共USSR兲
57, 2118 –2122 共1984兲.
84/29 P. T. Eubank, L. E. Cediel, J. C. Holste, and K. R. Hall, J. Chem.
Eng. Data 29, 389–393 共1984兲.
84/30 R. Eng and S. I. Sandler, J. Chem. Eng. Data 29, 156 –161 共1984兲.
84/31 D. M. Hull and B. C.-Y. Lu, J. Chem. Eng. Data 29, 417– 419
共1984兲.
84/32 A. K. Baev, A. A. Barkatin, and L. M. Dyagileva, Vestsi Akad.
Navuk BSSR, Ser. Khim. 60– 62 共1984兲.
84/33 A. K. Baev, V. E. Mikhailov, and A. A. Baev, Vestsi Akad. Navuk
BSSR, Ser. Khim. Navuk 75–77 共1984兲.
84/34 A. E. Sokolovskii and A. K. Baev, Vestsi Akad. Navuk BSSR, Ser.
Khim. Navuk 115–117 共1984兲.
1985
85/1 V. Majer, V. Svoboda, and M. Lencka, J. Chem. Thermodyn. 17,
365–370 共1985兲.
85/2 K. Kusano, Thermochimica Acta 88, 109–120 共1985兲.
85/3 V. Majer, V. Svoboda, V. Uchytilova, and M. Finke, Fluid Phase
Equilibr. 20, 111–118 共1985兲.
85/4 A. Raviprasad and K. V. Rao, J. Chem. Thermodyn. 17, 117–121
共1985兲.
85/5 S. A. Wieczorek and J. T. Sipowska, J. Chem. Thermodyn. 17,
255–261 共1985兲.
85/6 V. Majer and V. Svoboda, Enthalpies of Vaporization of Organic
Compounds: A Critical Review and Data Compilation 共Blackwell
Scientific, Oxford, U.K., 1985兲.
85/7 G. Barone, G. Castronuovo, G. Della Gatta, V. Elia, and A. Iannone,
Fluid Phase Equilib. 21, 157–164 共1985兲.
85/8 A. E. Sokolovski and A. K. Baev, Vestsi Akad. G. Emii Navuk
BSSR, Ser. Khim. Navuk 112–114 共1985兲.
85/9 A. G. R. Scholz and E. Brunner, J. Chem. Eng. Data 30, 72–74
共1985兲.
85/10 G. Natarajan and D. S. Viswanath, J. Chem. Eng. Data 30,
137–140 共1985兲.
85/11 V. Piacente, P. Scardala, D. Ferro, and R. Gigli, J. Chem. Eng.
Data 30, 372–376 共1985兲.
85/12 K. D. Reddy, M. V. P. Rao, and M. Ramakrishna, J. Chem. Eng.
Data 30, 394 –397 共1985兲.
85/13 V. A. Klyuchnikov, T. F. Danilova, M. G. Voronkov, and V. M.
D’yakov, Dokl. Phys. Chem. 281, 373–377 共1985兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
872
J. S. CHICKOS AND W. E. ACREE, JR.
85/14 S. N. Kondrat’ev and B. V. Strizhov, Zh. Fiz. Khim. 59, 2933–
2938 共1985兲.
85/15 A. H. N. Mousa, J. Fluorine Chem. 30, 29–35 共1985兲.
85/16 E. H. Appelman, M. H. Mendelsohn, and H. Kim. J. Am. Chem.
Soc. 107, 6515– 6518 共1985兲.
85/17 C. J. Wormald and T. K. Yerlett, J. Chem. Thermodyn. 17,
1171–1186 共1985兲.
1986
86/1 E. F. Meyer and J. J. Meyer, J. Chem. Eng. Data 31, 273–274
共1986兲.
86/2 B. Wisniewska, M. Lencka, and M. Rogalski, J. Chem. Thermodyn.
18, 703–708 共1986兲.
86/3 P. J. Achorn, W. G. Haseltine, and J. K. Miller, J. Chem. Eng. Data
31, 385–387 共1986兲.
86/4 O. L. Flaningan, J. Chem. Eng. Data 31, 266 –277 共1986兲.
86/5 R. M. Varushchenko, Zh. Fiz. Khim. 60, 291–294 共1986兲.
86/6 N. Allemand, J. Jose, and J. C. Merlin, Thermochimica Acta 105,
79–90 共1986兲.
86/7 V. S. Tsvetkov, A. G. Nazmutdinov, K. G. Sharonov, and A. M.
Rozhnov, Termodin. Org. Soedin. 71–73 共1986兲.
86/8 Yu. G. Dmitriev, N. S. Kachurina, C. H. Wang, and V. V.
Kouchukei, Vestn. L’vov. Politekh. Inst. 201, 29–30 共1986兲.
86/9 M.-A. Michou-Saucet, J. Jose, and C. Michou-Saucet,
Thermochimica Acta 102, 271–279 共1986兲.
86/10 V. Baliah and K. Gnanasekaran, Indian J. Chem. 25A, 673– 674
共1986兲.
86/11 Ya. Kh. Grinberg, V. B. Lazarev, A. Yu. Zavernyaev, V. A.
Shreider, and S. D. Chepik, Zh. Fiz. Khim. 60, 1386 –1389 共1986兲;
Chem. Abstracts 105, 86041k 共1986兲.
86/12 S. Takagi, M. Ishikawa, M. Kumada, T. Kimura, and R. Fujishiro,
Thermochimica Acta 109, 55– 61 共1986兲.
86/13 H.-I. Paul, J. Krug, and H. Knapp, Thermochimica Acta 108, 9–27
共1986兲.
86/14 V. M. Vorotyntsev, V. V. Balabanov, and D. A. Shamrakov, Zh. Fiz.
Khim. 60, 234 –235 共1986兲; Chem. Abstracts 104, 96047k 共1986兲.
86/16 C. M. White, J. Chem. Eng. Data 31, 198 –203 共1986兲.
86/17 T. K. Yerlett and C. J. Wormald, J. Chem. Thermodyn. 18,
719–726 共1986兲.
86/18 T. K. Yerlett and C. J. Wormald, J. Chem. Thermodyn. 18,
371–379 共1986兲.
1987
87/1 X.-W. An, H.-P. Zhu, and R.-H. Hu, Thermochimica Acta 121,
473– 477 共1987兲.
87/2 P. Kneisi and J. W. Zondio, J. Chem. Eng. Data 21, 11–13 共1987兲.
87/3 P. L. Mills, R. L. Fenton, and F. G. Schaefer, J. Chem. Eng. Data
32, 251–265 共1987兲.
87/4 R. Fuchs, E. J. Chambers, and W. K. Stepenson, Can. J. Chem. 65,
2624 –2627 共1987兲.
87/5 R. M. Stephenson and S. Malanowski, Handbook of the
Thermodynamics of Organic Compounds 共Elsevier: New York, 1987兲.
The data in this listing were obtained directly from this compendium
which does not contain literature references. The vaporization enthalpies
were calculated from the vapor pressures obtained from the Antoine
constants reported in this compendium. Vapor pressures were calculated
over a 30 K temperature range closest to 298 K and the temperature
dependence was reformulated in terms of the integrated form of the
Clausius Clapeyron equation.
87/6 D. Ambrose and N. B. Ghiassee, J. Chem. Thermodyn. 19, 911–913
共1987兲.
87/7 D. Ambrose and N. B. Ghiassee, J. Chem. Thermodyn. 19, 903–909
共1987兲.
87/8 Z. Atik, Y. Saito, and K. Kusano, J. Chem. Thermodyn. 19, 99–102
共1987兲.
87/9 D. Ambrose and N. B. Ghiassee, J. Chem. Thermodyn. 19, 505–519
共1987兲.
87/10 P. L. Mills and R. L. Fenton, J. Chem. Eng. Data 32, 266 –273
共1987兲.
87/11 R. M. Varushchenko, O. L. Loseva, and A. I. Druzhinina, Zh. Fiz.
Khim. 61, 31–35 共1987兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
87/12 R. M. Varushchenko, O. L. Loseva, and A. I. Druzhinina, Zh. Fiz.
Khim. 61, 638 – 642 共1987兲.
87/13 H. Yan, J. Gu, X. An, and R.-H. Hu, Huaxue Xuebao 45, 1184 –
1187 共1987兲.
87/14 Yu. Ya. Van-Chin-Syan and N. S. Kachurina, Russ. J. Phys. Chem.
61, 622– 624 共1987兲.
87/15 F. Garcia-Sanchez and A. Trejo, J. Chem. Thermodyn. 19,
359–361 共1987兲.
87/16 T. Treszczanowicz and B. C.-Y. Lu, J. Chem. Thermodyn. 19,
391–394 共1987兲.
87/17 E. C. Azandegbe, Analusis 15, 370–373 共1987兲.
87/18 H. Al-Najjar and D. Al-Sammerrai, J. Chem. Tech. Biotechnol. 37,
145–152 共1987兲.
87/19 O. An, R. Hu, H. Wang, M. Wu, and Y. Zou, Acta Physico-Chim.
Sinica 3, 668 – 671 共1987兲.
1988
88/1 V. I. Tel’noi, V. N. Larina, E. N. Karataev, and E. N. Deryagina, Zh.
Fiz. Khim. 62, 3108 –3109 共1988兲.
88/2 H. Katayama, J. Chem. Eng. Data 33, 75–77 共1988兲.
88/3 C. F. Askonas and T. E. Daubert, J. Chem. Eng. Data 33, 225–229
共1988兲.
88/4 A. K. Baglay, L. L. Gurarly, and G. G. Kuleshov, J. Chem. Eng.
Data 33, 512–518 共1988兲.
88/5 D. Ambrose and N. B. Ghiassee, J. Chem. Thermodyn. 20, 765–766
共1988兲.
88/6 D. Ambrose, N. B. Ghiassee, and R. Tuckerman, J. Chem.
Thermodyn. 20, 767–768 共1988兲.
88/7 I. A. Hossenlopp and D. G. Archer, J. Chem. Thermodyn. 20,
1061–1068 共1988兲.
88/8 D. Ambrose and N. B. Ghiassee, J. Chem. Thermodyn. 20, 1231–
1232 共1988兲.
88/9 T. M. Letcher, J. Sewry, and S. W. Orchard, J. Chem. Thermodyn.
20, 1231–1232 共1988兲.
88/10 M. Bastos, S. O. Nilsson, M. D. M. C. Ribeiro da Silva, M. A. V.
Ribeiro da Silva, and I. Wadso, J. Chem. Thermodyn. 20, 1353–1359
共1988兲.
88/11 R. M. Varushchenko, O. L. Loseva, A. I. Druzhinina, and E. F.
Zorina, Zh. Fiz. Khim. 62, 1776 –1780 共1988兲.
88/12 K. Sasse, J. Jose, and J.-C. Merlin, Fluid Phase Equilib. 42,
287–304 共1988兲.
88/13 R. H. Shay, B. N. Diel, D. M. Schubert, and A. D. Norman, Inorg.
Chem. 27, 2378 –2382 共1988兲.
88/14 P. Knauth and R. Sabbah, Bull. Soc. Chem. Fr. 834 – 836 共1988兲.
88/15 M. G. Voronkov, V. P. Baryshok, V. A. Klyuchnikov, T. F.
Danilova, V. I. Pepekin, A. N. Korchagina, and Yu. I. Khudobin, J.
Organomet. Chem. 345, 27–38 共1988兲.
88/16 J. F. Messerly, H. L. Finke, W. D. Good, and B. Gammon, J.
Chem. Thermodyn. 20, 485–501 共1988兲.
88/17 H. Katayama, Bull. Chem. Soc. Jpn. 61, 3326 –3328 共1988兲.
88/18 V. B. Lazarev, Ya. Kh. Grinberg, Z. P. Ozerova, and G. A.
Sharpataya, J. Thermal Anal. 33, 797–799 共1988兲.
88/19 J.-Q. Dong, R.-S. Lin, and W.-H. Yen, Can. J. Chem. 66, 783–790
共1988兲.
88/20 D. R. Davies, M. B. Ewing, J. A. Hugill, and M. L. McGlashan,
Can. J. Chem. 66, 760–762 共1988兲.
1989
89/1 R. D. Chirico, A. Nguyen, W. V. Steele, M. M. Strube, and C. J.
Tsonopoulos, Chem. Eng. Data 34, 149–156 共1989兲.
89/2 B. Varughese and J. T. Sommerfeld, J. Chem. Eng. Data 34, 25–26
共1989兲.
89/3 H. S. Wu and S. I. Sandler, J. Chem. Eng. Data 34, 209–213
共1989兲.
89/4 R. D. Chirico, S. E. Knipmeyer, A. Nguyen, and W. V. Steele, J.
Chem. Thermodyn. 21, 1307–1331 共1989兲.
89/5 M. Kato and M. Tanaka, J. Chem. Eng. Data 34, 206 –209 共1989兲.
89/6 E. Cepeda, C. Gonzalez, and J. M. Resa, J. Chem. Eng. Data 34,
270–273 共1989兲.
89/7 S. J. Park and J. Gmehling, J. Chem. Eng. Data 34, 399– 401
共1989兲.
ENTHALPIES OF VAPORIZATION
89/8 K. Wang, X.-G. Ying, M.-S. Xia, J.-Z. Xia, and Y. Hu, J. Chem.
Eng. Data 34, 126 –130 共1989兲.
89/9 A. Sakoguichi, Y. Iwai, and J. Takenaka, Kagaku Kogaku
Ronbunshu 15, 166 共1989兲.
89/10 X. An and H. Hu, Wuli Huaxue Xuebao 5, 565–571 共1989兲;
Chem. Abstracts 112, 118206f 共1990兲.
89/11 M. G. Voronkov, M. S. Sorokin, V. A. Klyuchnikov, G. N. Shvetz,
and V. I. Pepekin, J. Organomet. Chem. 359, 301–313 共1989兲.
89/12 M. G. Voronkov, V. A. Klyuchnikov, S. N. Kolabin, G. N. Shvets,
P. I. Varushin, E. N. Deryagina, N. A. Korchevin, and S. I. Tsvetnitskaya,
Dokl. Phys. Chem. 307, 650– 653 共1989兲.
89/13 R. M. Varushchenko and L. L. Pashchenko, Russ. J. Phys. Chem.
63, 964 –967 共1989兲.
89/14 K. Sasse, J. N’Guimbi, J. Jose, and J. C. Merlin, Thermochimica
Acta 146, 53– 61 共1989兲.
89/15 M. D. Vine and C. J. Wormald, J. Chem. Thermodyn. 21, 1151–
1157 共1989兲.
89/16 E. C. Azandegbe, Analusis 17, 285–289 共1989兲.
1990
90/1 M. L. P. Leitao, G. Pilcher, Y. Meng-Yan, J. M. Brown, and A. D.
Conn, J. Chem. Thermodyn. 22, 885– 891 共1990兲.
90/2 D. A. Hinckley, T. F. Bidleman, W. T. Foreman, and J. R. Tuschall,
J. Chem. Eng. Data 35, 232–237 共1990兲.
90/3 N. O. Smith, J. Chem. Eng. Data 35, 387–389 共1990兲.
90/4 H.-D. Beckhaus, B. Dogan, J. Pakusch, S. Verevkin, and C.
Rüchardt, Chem. Ber. 123, 2153–2159 共1990兲.
90/5 T. N. Nesterova, A. G. Nazmutdinov, V. S. Tsvetkov, A. M.
Rozhnov, and I. Yu. Roshchupkina, J. Chem. Thermodyn. 22, 365–377
共1990兲.
90/6 M. Lenka, J. Chem. Thermodyn. 22, 473– 480 共1990兲.
90/7 D. Ambrose, M. B. Ewing, N. B. Ghiassee, and J. C. S. Ochoa, J.
Chem. Thermodyn. 22, 589– 605 共1990兲.
90/8 M. Sohda, M. Okazaki, Y. Iwai, Y. Arai, A. Sakoguchi, R. Ueoka,
and Y. Kato, J. Chem. Thermodyn. 22, 607– 608 共1990兲.
90/9 N. V. K. Dutt, A. P. Kahol, P. J. Reddy, and K. S. Raghunandanan,
J. Chem. Eng. Data 35, 114 –117 共1990兲.
90/10 J. Ortego, P. Susial, and C. de Alfonso, J. Chem. Eng. Data 35,
216 –218 共1990兲.
90/11 X. An, J. He, and R.-H. Hu, Thermochimica Acta 169, 331–337
共1990兲.
90/12 R. H. Davies, A. Finch, and K. Salem, Thermochimica Acta 170,
213–216 共1990兲.
90/13 T. Pompili and V. Piacente, Thermochimica Acta 170, 289–291
共1990兲.
90/14 V. Piacente and P. Scardala, Thermochimica Acta 159, 193–200
共1990兲.
90/15 A. M. Rozhnov, V. I. Barkov, K. G. Sharonov, and V. S. Tsvetkov,
J. Chem. Thermodyn. 22, 327–333 共1990兲.
90/16 G. Barone, G. Della Gatta, D. Ferro, and V. Piacente, J. Chem.
Soc. Faraday Trans. 86, 75–79 共1990兲.
90/17 B. Dogan, H.-D. Beckhaus, J. Schaetzer, S. Hellmann, and C.
Rüchardt, Chem. Ber. 123, 137–144 共1990兲.
90/18 M. I. Lopez and J. E. Sicre, J. Phys. Chem. 94, 3860–3863 共1990兲.
90/19 A. Sprozynski and J. Gregorowicz, Main Group Met. Chem. 13,
1– 6 共1990兲.
1991
91/1 N. I. Buchan, R. M. Potemski, and T. F. Kuech, J. Chem. Eng. Data
36, 372–374 共1991兲.
91/2 P. Basarova and V. Svoboda, Fluid Phase Equilib. 68, 13–34 共1992兲.
91/3 H. S. Wu, K. A. Pividal, and S. I. Sandler, J. Chem. Eng. Data 36,
418 – 421 共1991兲.
91/4 M. G. Voronkov, V. A. Klyuchnikov, E. V. Sokolova, T. F. Danilova,
G. N. Shvets, A. N. Korchagina, L. E. Gussel’nikov, and V. V. Volkova,
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1993
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1994
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1995
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1996
96/1 M. A. V. Ribeiro da Silva, M. D. M. C. Ribeiro da Silva, M. F. B.
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96/20 S. P. Verevkin, S. Züffle, H.-D. Beckhaus, and C. Rüchardt,
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1997
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97/5 S. P. Verevkin, Thermochimica Acta 307, 17–25 共1997兲.
97/6 W. V. Steele, R. D. Chirico, S. E. Knipmeyer, and A. Nguyen, J.
Chem. Eng. Data 42, 1008 –1020 共1997兲.
97/7 W. V. Steele, R. D. Chiricio, S. E. Knipmeyer, A. Nguyen, and N.
K. Smith, J. Chem. Eng. Data 42, 1037–1052 共1997兲.
97/8 W. V. Steele, R. D. Chirico, S. E. Knipmeyer, and A. Nguyen, J.
Chem. Eng. Data 42, 1021–1036 共1997兲.
97/9 S. P. Verekin, J. Mogenthaler, and C. Rüchardt, J. Chem.
Thermodyn. 29, 1175–1183 共1997兲.
97/10 F. W. Welle, S. P. Verevkin, H.-D. Beckhaus, and C. Rüchardt,
Liebigs Ann./Recueil 155–163 共1997兲.
97/11 P. Hernández and J. Ortega, J. Chem. Eng. Data 42, 1090–1100
共1997兲.
97/12 L. M. G. Minier and R. Behrens, Jr., Propellants, Explos. Pyrotech.
22, 23–33 共1997兲.
97/13 B. Koutek, M. Hoskovec, P. Vrkocova, and L. Feltl, J. Chromatogr.
A 759, 93–109 共1997兲.
97/14 F. Schaffer, S. P. Verevkin, H.-J. Rieger, H.-D. Beckhaus, and C.
Rüchardt, Liebigs Ann./Recueil 1333–1344 共1997兲.
97/15 H. Artigas, C. Lafuente, P. Cea, F. M. Royo, and J. S. Urieta, J.
Chem. Eng. Data 42, 132–136 共1997兲.
97/16 T. Sako, S. Horiguchi, H. Ichimaru, and S. Nakagawa, J. Chem.
Eng. Data 42, 169–717 共1997兲.
97/17 J. S. Chickos and J. A. Wilson, J. Chem. Eng. Data 42, 190–197
共1997兲.
97/18 W. V. Steele, R. D. Chirico, A. B. Cowell, S. E. Knipmeyer, and
A. Nguyen, J. Chem. Eng. Data 42, 1053–1066 共1997兲.
97/19 J. C. G. Calado, E. J. M. Filipe, and J. N. C. Lopes, J. Chem.
Thermodyn. 29, 1435–1438 共1997兲.
97/20 A. V. Blokhin, G. J. Kabo, A. A. Kozyro, L. S. Ivashkevich, A. P.
Krasulin, V. V. Diky, and Yu. V. Maksimuk, Thermochimica Acta 292,
19–29 共1997兲.
97/21 S. P. Verevkin, J. Chem. Thermodyn. 29, 891– 899 共1997兲.
97/22 D. R. Defibaugh, E. Carrillo-Nava, J. J. Hurly, M. R. Moldover, J.
W. Schmidt, and L. A. Weber, J. Chem. Eng. Data 42, 488 – 496 共1997兲.
97/23 Yu. V. Maksimuk, G. J. Kabo, A. A. Kozyro, V. V. Simirsky, A. P.
Krasulin, and V. M. Sevruk, J. Chem. Thermodyn. 29, 687– 699 共1997兲.
97/24 M. Hallquist, I. Wangberg, and E. Ljungstrom, Environ. Sci.
Technol. 31, 3166 –3172 共1997兲.
97/25 H. A. Duarte-Garza, C.-A. Hwang, S. A. Kellerman, R. C. Miller,
K. R. Hall, J. C. Holste, K. N. Marsh, and G. E. Gammon, J. Chem.
Eng. Data 42, 497–501 共1997兲.
97/26 B. L. Korsounskii and T. A. Apina, Int. Annu. Conf. ICT 46.1–
46.7 共1997兲; Chem. Abstracts 127, 163997k 共1997兲.
97/27 L.-T. Lim and M. A. Tung, J. Food Sci. 62, 1061–1066 共1997兲.
97/28 H. B. Krop, M. J. M. Velzen, J. R. Parsons, and H. A. J. Govers, J.
Am. Oil Chem. Soc. 74, 309–315 共1997兲.
97/29 S. P. Verevkin, M. Nölke, H.-D. Beckhaus, and C. Rüchardt, J.
Org. Chem. 62, 4683– 4686 共1997兲.
97/30 A. K. Baev, Russ. J. Inorg. Chem. 42, 587–596 共1997兲.
1998
98/1 S. P. Verevkin, H.-D. Beckhaus, U. Schüle, and C. Rüchardt, Struct.
Chem. 9, 1–7 共1998兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
876
J. S. CHICKOS AND W. E. ACREE, JR.
98/2 S. P. Verevkin and F. M. Welle, Struct. Chem. 9, 215–221 共1998兲.
98/3 R. Gudino, L. A. Torres, R. L. Santillan, and N. Farfan, J. Chem.
Thermodyn. 30, 671– 679 共1998兲.
98/4 S. P. Verevkin, Thermochimica Acta 310, 229–235 共1998兲.
98/5 M. A. George, K. M. Young, E. A. Robertson III, S. E. Beck, and
G. Voloshin, J. Chem. Eng. Data 43, 60– 64 共1998兲.
98/6 Y. V. Maksimuk, G. J. Kabo, V. V. Simirsky, A. A. Kozyro, and V.
M. Sevruk, J. Chem. Eng. Data 43, 293–398 共1998兲.
98/7 M. A. Abdi and A. Meisen, J. Chem. Eng. Data 43, 133–137
共1998兲.
98/8 V. Rohac, V. Ruzicka, K. Ruzicka, and K. Aim, J. Chem. Eng. Data
43, 770–775 共1998兲.
98/9 A. Aucejo, S. Loras, R. Munoz, P. Reich, and H. Segura, J. Chem.
Eng. Data 43, 973–977 共1998兲.
98/10 S. P. Verevkin, Thermochimica Acta 316, 131–136 共1998兲.
98/11 J. S. Chickos, D. Hesse, S. Hosseini, G. Nichols, and P. Webb,
Thermochimica Acta 313, 101–110 共1998兲.
98/12 S. P. Verevkin, Struct. Chem. 9, 113–119 共1998兲.
98/13 S. P. Verevkin, J. Chem. Thermodyn. 30, 1069–1079 共1998兲.
98/14 K. M. Morgan and D. A. Kopp, J. Chem. Soc., Perkin Trans. 2
2759–2763 共1998兲.
98/15 J. D. Olson, Fluid Phase Equilib. 150Õ151, 713–720 共1998兲.
98/16 V. Svoboda, V. Hynek, and B. Koutek, J. Chem. Thermodyn. 30,
1411–1417 共1998兲.
98/17 V. P. Kolesov, S. M. Pimenova, V. A. Lukyanova, T. S.
Kuznetsova, and M. P. Kozina, J. Chem. Thermodyn. 30, 1455–1464
共1998兲.
98/18 M. B. Ewing and J. C. Sanchez Ochoa, J. Chem. Thermodyn. 30,
189–198 共1998兲.
98/19 S. P. Verevkin, J. Chem. Thermodyn. 30, 1029–1040 共1998兲.
98/20 K. G. Drouillard, G. T. Tomy, D. C. G. Muir, and K. J. Friesen,
Environ. Toxicol. Chem. 17, 1252–1260 共1998兲.
98/21 S. P. Verevkin, W.-H. Peng, H.-D. Beckhaus, and C. Rüchardt, Eur.
J. Org. Chem. 2323–2332 共1998兲.
98/22 S. P. Verevkin, M. Kümmerlin, H.-D. Beckhaus, C. Galli, and C.
Rüchardt, Eur. J. Org. Chem. 579–584 共1998兲.
98/23 X. Zhang, H. Mo, K. Yang, and F. An, Huanjing Huaxue 17,
50–54 共1998兲; Chem. Abstracts 128, 318311d 共1998兲 共value is referred to
as a vaporization enthalpy兲.
98/24 W. Blanke, G. Klingenberg, and F. Weber, Int. J. Thermophys. 19,
653– 662 共1998兲.
98/25 L. D. Stockton, T. L. Ng, N. Maung, I. B. Poole, J. O. Williams,
A. C. Wright, D. F. Foster, and D. J. Cole-Hamilton, J. Cryst. Growth
183, 95–98 共1998兲.
1999
99/1 M. A. V. Ribeiro da Silva, M. D. M. C. Ribeiro da Silva, M. A. R.
Matos, P. Jimenez, M. V. Roux, J. Elguero, R. Claramunt, P. Cabildo, and
A. Sanchez-Migallon, J. Chem. Thermodyn. 31, 129–138 共1999兲.
99/2 S. P. Verevkin, Thermochimica Acta 332, 27–32 共1999兲.
99/3 S. P. Verevkin, J. Chem. Eng. Data 44, 1245–1251 共1999兲.
99/4 S. P. Verevkin and A. Heintz, J. Chem. Eng. Data 44, 1240–1244
共1999兲.
99/5 O. Mo, M. Yanez, M. V. Roux, P. Jimenez, J. Z. Davalos, M. A. V.
Ribeiro da Silva, M. D. M. C. Ribeiro da Silva, M. A. R. Matos, L. M.
P. F. Amaral, A. Sanchez-Migallon, P. Cabildo, R. Claramunt, J. Elguero,
and J. F. Liebman, J. Phys. Chem. 103, 9336 –9344 共1999兲.
99/6 F. S. Costa, M. E. Eusebio, J. S. Redinha, and M. L. P. Leitao, J.
Chem. Thermodyn. 31, 895–903 共1999兲.
99/7 M. A. V. Ribeiro da Silva, M. A. R. Matos, V. M. F. Morais, and M.
S. Miranda, J. Org. Chem. 64, 8816 – 8820 共1999兲.
99/8 S. P. Verevkin, J. Chem. Eng. Data 44, 175–179 共1999兲.
99/9 Y. D. Lei, F. Wania, and W. Y. Shiu, J. Chem. Eng. Data 44,
577–582 共1999兲.
99/10 J. B. Monton, J. de la Torre, M. C. Burguet, R. Munoz, and S.
Loras, J. Chem. Eng. Data 44, 1158 –1162 共1999兲.
99/11 J. N’Guimbi, C. Berro, I. Mokbel, E. Rauzy, and J. Jose, Fluid
Phase Equilib. 162, 143–158 共1999兲.
J. Phys. Chem. Ref. Data, Vol. 32, No. 2, 2003
99/12 D. E. G. Jones, H. T. Feng, R. A. Austen, and R. C. Fouchard, J.
Therm. Anal. Calorim. 55, 9–19 共1999兲; Chem. Abstracts 132, 182729u
共2000兲.
99/13 Y. D. Lei, F. Wania, W. Y. Shiu, and D. G. B. Boocock, J. Chem.
Eng. Data 44, 200–202 共1999兲.
99/14 R. Garriga, A. C. Andres, P. Perez, and M. Gracia, J. Chem. Eng.
Data 44, 296 –302 共1999兲.
99/15 G. N. Escobedo-Alvarado and S. I. Sandler, J. Chem. Eng. Data
44, 319–322 共1999兲.
99/16 J. Dykyj, J. Svoboda, R. C. Wilhoit, M. L. Frenkel, and K. R.
Hall, Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine
Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and
Hydrogen Containing Organic Compounds 共Springer, Berlin, 1999兲. The
vaporization enthalpies were calculated from the vapor pressures obtained
from the Antoine constants reported in this compendium. In cases where
the Antoine constant C⫽0, the Antoine Equation (log10 P⫽A⫺B/(C
⫹T)) reduces to the integrated form of the Clausius Clapeyron equation
directly. This was the case for many vaporization enthalpies. In those
cases where this condition was not met the vaporization enthalpy was
calculated as ⌬H V ⫽2.303RB 关 T/(T⫹C) 兴 2 .
99/17 V. N. Dibrivnyl, Z. E. Pistun, Yu. Ya. Van-Chin-Syan, A. P.
Yuvchenko, and T. D. Zvereva, Russ. J. Phys. Chem. 73, 2043–2045
共1999兲.
99/18 S. P. Verevkin, J. Chem. Thermodyn. 31, 559–585 共1999兲.
99/19 S. P. Verevkin, J. Chem. Thermodyn. 31, 1397–1416 共1999兲.
99/20 V. Rohac, V. Ruzicka, K. Ruzicka, M. Polednicek, K. Aim, J. Jose,
and M. Zabransky, Fluid Phase Equilibra 157, 121–142 共1999兲.
99/21 S. P. Verevkin, Thermochimica Acta 326, 17–25 共1999兲.
99/22 V. A. Titov, L. N. Zelenina, and T. P. Chusova, Russ. J. Phys.
Chem. 73, 835– 837 共1999兲.
99/23 V. N. Dibrivnyl, G. V. Lusiv, Yu. Ya. Van-Chin-Syan, A. P.
Yuvchenko, and E. A. Dikusar, Russ. J. Phys. Chem. 73, 2040–3042
共1999兲.
99/24 R. D. Chirico, S. E. Knipmeyer, A. Nguyen, and W. V. Steele, J.
Chem. Thermodyn. 31, 339–378 共1999兲.
99/25 V. Rohac, J. E. Musgrove, K. Ruzicka, V. Ruzicka, M. Zabransky,
and K. Aim. J. Chem. Thermodyn. 31, 971–986 共1999兲.
99/26 F. Weber, PTB-Mitteilungen 109, 469– 471 共1999兲.
99/27 M. A. E. Diaz, T. Guetachew, P. Landy, J. Jose, and A. Voilley,
Fluid Phase Equilib. 109, 469– 471 共1999兲.
99/28 S. Loras, A. Aucejo, and R. Munoz, Fluid Phase Equilib. 156,
185–195 共1999兲.
99/29 J. S. Lim, J.-Y. Park, B.-G. Lee, Y.-W. Lee, and J.-D. Kim, J.
Chem. Eng. Data 44, 1226 –1230 共1999兲.
99/30 A. Aucejo, S. Loras, R. Munoz, and L. M. Ordonez, Fluid Phase
Equilib. 156, 173–178 共1999兲.
99/31 A. Keys, S. G. Bott, and A. R. Barron, Chem. Mater. 11, 3578 –
3587 共1999兲.
99/32 D. Fatu, J. Thermal. Anal. Calor. 56, 739–747 共1999兲.
99/33 M. I. Zaretskii, E. M. Chartov, L. A. Pushkina, and V. V. Elkin,
Russ. J. Appl. Chem. 72, 1702–1705 共1999兲.
2000
00/1 M. A. V. Ribeiro da Silva, M. D. M. C. Ribeiro da Silva, M. A. R.
Matos, P. Jimenez, M. V. Roux, M. A. Martin-Luengo, J. Elguero, R.
Claramut, and P. Cabildo, J. Chem. Thermodyn. 32, 237–245 共2000兲.
00/2 S. P. Verevkin, J. Chem. Thermodyn. 32, 207–216 共2000兲.
00/3 M. A. V. Ribeiro da Silva, M. A. R. Matos, C. A. Rio, V. M. F.
Morais, J. Wang, G. Nichols, and J. S. Chickos, J. Phys. Chem. A 104,
1774 –1778 共2000兲.
00/4 I. Mokbel, K. Ruzicka, V. Majer, V. Ruzicka, M. Ribeiro, J. Jose,
and M. Zabransky, Fluid Phase Equilib. 169, 191–207 共2000兲.
00/5 S. P. Verevkin and C. Schick, J. Chem. Eng. Data 45, 946 –952
共2000兲.
00/6 S. P. Verevkin, J. Chem. Eng. Data 45, 953–960 共2000兲.
00/7 S. P. Verevkin, D. Wandschneder, and A. Heintz, J. Chem. Eng.
Data 45, 618 – 625 共2000兲.
00/8 J. M. Resa, C. Gonzalez, S. Ortiz de Landaluce, and J. Lanz, J.
Chem. Eng. Data 45, 867– 871 共2000兲.
ENTHALPIES OF VAPORIZATION
00/9 G. Nichols, J. Orf, S. M. Reiter, J. S. Chickos, and G. W. Gokel,
Thermochimica Acta 346, 15–28 共2000兲.
00/10 P. V. Ova, B. Koultek, and M. Hoskovec, in Practice Oriented
Results on Use and Production of Neem Ingredients and Pheromones VI;
edited by H. Kleeberg and C. P. W. Zebitz 共Druck and Graphic, Giessen,
2000兲, pp. 211–218.
00/11 Y.-H. Liang and P.-S. Ma, Shiyou Huagong 29, 939–941 共2000兲.
00/12 S. Rodriguez, H. Artigas, C. Lafuente, A. M. Mainar, and F. M.
Royo, Thermochimica Acta 362, 153–160 共2000兲.
00/13 R. Reich, M. Cartes, H. Segura, and J. Wisniak, Phys. Chem. Liq.
38, 217–232 共2000兲.
00/14 S. P. Verevkin, J. Chem. Thermodyn. 32, 247–259 共2000兲.
00/15 S. P. Verevkin and A. Heintz, J. Chem. Thermodyn. 32, 1169–1182
共2000兲.
00/16 V. Rohac, M. Censky, D. Zala, V. Ruzicka, K. Ruzicka, K. Sporka,
and K. Aim, J. Chem. Eng. Data 45, 1205–1210 共2000兲.
00/17 M. Palczewska-Tulinska and A. M. Szafranski, J. Chem. Eng. Data
45, 988 –990 共2000兲.
00/18 E. Bourret-Courchesne, Q. Ye, D. W. Peters, J. Arnold, M. Ahmed,
S. J. C. Irvine, R. Kanjolia, L. M. Smith, and S. A. Rushworth, J. Cryst.
Growth 217, 47–54 共2000兲.
00/19 B. Sztaray and T. Baer, J. Am. Chem. Soc. 122, 9219–9226
共2000兲.
00/20 C. J. Wormald and D. P. Fennell, Int. J. Thermophys. 21, 767–779
共2000兲.
00/21 A. I. Druzhinina, R. M. Varushchenko, V. S. Sarisova, and A. A.
Pimerzin, Zh. Fiz. Khim. 74, 404 – 411 共2000兲.
00/22 S. V. Melkhanova, S. M. Pimenova, V. P. Kolesov, A. A. Pimerzin,
and V. S. Sarkisova, J. Chem. Thermodyn. 32, 1311–1317 共2000兲.
00/23 S. Bobbo, R. Camporese, and R. Stryjek, J. Chem. Thermodyn. 32,
1647–1656 共2000兲.
00/24 C. J. Wormald and M. D. Vine, J. Chem. Thermodyn. 32, 329–339
共2000兲.
00/25 C. J. Wormald and M. D. Vine, J. Chem. Thermodyn. 32, 659– 669
共2000兲.
00/26 C. J. Wormald and G. F. James, J. Chem. Eng. Data 45, 348 –352
共2000兲.
2001
01/1 S. Puri, J. S. Chickos, and W. J. Welsh, Anal. Chem. 73, 1480–1484
共2001兲.
01/2 A. Wong, Y. D. Lei, M. Alaee, and F. Wania, J. Chem. Eng. Data
46, 239–242 共2001兲.
01/3 D. Kilikov, S. P. Verevkin, and A. Heintz, Fluid Phase Equilib. 192,
187–206 共2001兲.
01/4 R. M. Varushchenko, L. L. Paschenko, A. I. Druzhinina, A. V.
Abramenkov, and A. A. Pimersin, J. Chem. Thermodyn. 33, 733–744
共2001兲.
01/5 A. K. Baev, Russ. J. Appl. Chem. 74, 162–163 共2001兲.
01/6 S. Bernatova and I. Wichterle, Fluid Phase Equilib. 189, 111–118
共2001兲.
01/7 D. Kulikov, S. P. Verevkin, and A. Heintz, J. Chem. Eng. Data 46,
1593–1600 共2001兲.
01/8 J. G. Blok, A. C. G. van Genderen, P. R. van der Linde, and H. A.
G. Oonk, J. Chem. Thermodyn. 33, 1097–1106 共2001兲.
01/9 A. K. Baev, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 44,
3–13 共2001兲.
01/10 N. Bureau, J. Jose, I. Mokbel, and J.-C. de Hemptinne, J. Chem.
Thermodyn. 33, 1485–1498 共2001兲.
01/11 S. A. Tittlemier and G. T. Tomy, Environ. Toxicol. Chem. 20,
146 –148 共2001兲.
01/12 H. Segura, E. Lam, R. Reich, and J. Wisniak, Phys. Chem. Liq. 39,
43–54 共2001兲.
01/13 L. Zhu, H. Li, C. Wang, and S. Han, J. Chem. Eng. Data 46,
1231–1234 共2001兲.
01/14 P. Uusi-Kyyny, J.-P. Pokki, J. Aittaman, and S. Liukkonen, J.
Chem. Eng. Data 46, 1244 –1248 共2001兲.
01/15 L. A. L. Munoz and M. A. Krahenbuhl, J. Chem. Eng. Data 46,
120–124 共2001兲.
877
01/16 S. P. Verevkin and A. Heintz, J. Chem. Eng. Data 46, 984 –990
共2001兲.
01/17 K. Chylinski, Z. Fras, and S. K. Malanowski, J. Chem. Eng. Data
46, 29–33 共2001兲.
01/18 S. P. Verevkin and A. Heintz, J. Chem. Eng. Data 46, 41– 46
共2001兲.
01/19 S. Horstmann, H. Gardeler, K. Fischer, F. Köster, and J. Gmehling,
J. Chem. Eng. Data 46, 337–345 共2001兲.
01/20 K. Chatterjee, D. Dollimore, and K. Alexander, Instrum. Sci.
Technol. 29, 133–144 共2001兲; Chem. Abstracts 135, 16629t 共2001兲
共reported values are referred to as enthalpies of vaporization兲.
01/21 J. O. Lalah, K.-W. Schramm, D. Lenoir, B. Henkelmann, N.
Hertkorn, G. Matuschek, A. Kettrup, and K. Günther, Chem. Eur. J. 7,
4790– 4795 共2001兲.
01/22 I. Kul, D. D. DesMarteau, and A. L. Beyerlein, Fluid Phase
Equilib. 185, 241–253 共2001兲.
01/23 A. K. Baev and V. E. Mikhailov, Russ. J. Appl. Chem. 74,
1435–1438 共2001兲.
01/24 A. K. Baev and I. N. Chernyak, Russ. J. Inorg. Chem. 46,
310–316; 共2001兲 Zh. Neorg. Khim. 46, 361–367 共2001兲; enthalpies of
vaporization are presented graphically in paper for binary mixtures.
2002
02/1 R. M. Varushchenko and A. I. Druzhinina, Fluid Phase Equilib. 199,
109–119 共2002兲.
02/2 D. Deng, H. Li, and S. Han, J. Chem. Thermodyn. 34, 1431–1437
共2002兲.
02/3 T. V. Sorokina, D. Dollimore, and K. S. Alexander, Thermochimica
Acta 392Õ393, 315–321 共2002兲.
02/4 A. Valtz, C. Coquelet, A. Baba-Ahmed, and D. Richon, Fluid Phase
Equilib. 202, 29– 47 共2002兲.
02/5 J.-P. Pokki, P. Uusi-Kyyny, J. Aittamaa, and S. Liukkonen, J. Chem.
Eng. Data 47, 371–375 共2002兲.
02/6 S. Bobbo, L. Fedele, M. Scattolini, and R. Camporese, J. Chem.
Eng. Data 47, 179–182 共2002兲.
02/7 C.-H. Su, S. Zhu, N. Ramachandran, and A. Burger, J. Cryst.
Growth 235, 313–319 共2002兲.
02/8 H. Segura, J. Wisniak, G. Galindo, and R. Reich, Phys. Chem. Liq.
40, 67– 81 共2002兲.
02/9 B. E. Swiatek and S. K. Malanowski, J. Chem. Eng. Data 47,
478 – 481 共2002兲.
02/10 R. M. Varuschenko, L. L. Pashchenko, A. I. Druzhinina, A. Yu.
Churkina, I. I. Vorob’ev, and S. N. Kravhun, Russ. J. Phys. Chem. 76,
546 –551 共2002兲.
02/11 R. M. Varuschenko, C. A. Aitkeeva, A. I. Druzhinina, Y. A.
Myshenseva, and L. L. Pashchenko, Russ. J. Phys. Chem. 76, 724 –728
共2002兲.
02/12 I. M. Marrucho, N. S. Oliveira, and R. Dohrn, J. Chem. Eng. Data
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