suPER PuRE NICKEl 1/2 Data sheets // SUPER PURE NICKEL // 7

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Data sheets // SUPER PURE NICKEL // 7
Brand
Name
Material
Code
Super Pure Nickel
Abbreviation
Ni 99.98
1)
Chemical Composition (mass components) in %.
Average values of alloy components
Ni
99.89
Features and Application Notes
Super Pure Nickel is especially characterized by very high temperature
coefficient and low resistivity. Super Pure Nickel is used for resistors
with a strongly temperature-dependent resistance value, also for the
production of spark-plugs. Super Pure Nickel is magnetic up to a
temperature of approx. +360 °C (the Curie point is at approx. +357.5 °C).
The maximum working temperature in air is +700 °C.
Form of Delivery
Super Pure Nickel is supplied in the form of round wires in the
range 0.10 to 3.00 mm Ø in bare and enamelled condition.
Electrical Resistance in Annealed Condition
Temperature coefficient 2) of electrical
resistance between
Electrical resistivity in: µΩ x cm (first line) and Ω/CMF (second line)
Reference Values
+20 °C and +105 °C
10 -6/K
+20 °C
tolerance ±10 %
+100 °C
+200 °C
+300 °C
+400 °C
+500 °C
approx. + 6,600
7
11
17
24
31
36
42
66
102
144
186
211
Physical Characteristics (Reference Values)
Density at +20 °C
Melting point
g/cm³
lb/cub in
°C
8.90
0.32
+1,453
Specific heat
at +20 °C
J/g K
Thermal conductivity 3) at +20 °C
W/m K
Average linear thermal expansion coefficient
between +20 °C and
Thermal EMF
against copper at
+100 °C
+400 °C
+20 °C
10 /K
10 /K
µV/K
-6
-6
-23.00
see special
graphs
Strength Properties at +20 °C in Annealed Condition
Tensile Strength4)
Elongation (L 0 = 100 mm) % at nominal diameter in mm
MPa
psi
0.020 to 0.063
> 0.063 to 0.125
> 0.125 to 0.50
> 0.50 to 1.00
> 1.00
> 400
> 58,000
< 10
≈ 10
≈ 15
≥ 18
≥ 20
1) Super Pure Nickel is not a standardized alloy.
2) These are approximate values; tolerances must separately be agreed upon.
3) As with all pure metals, the thermal conductivity strongly depends on the purity and temperature.
4) This value applies to wires of 2.0 mm diameter. For thinner wires the minimum values will substantially increase, depending on the dimensions.
Issue 29-March-2014
Notes on Treatment // Super Pure Nickel is very soft as
compared with the types of technically pure nickel quoted in
DIN 17740; this must be taken into consideration when it is
processed. As can be seen on page 2 graphs, its physical
properties are heavily temperature-dependent, the latter
being strongly affected if the Curie point is exceeded.
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Data sheets // SUPER PURE NICKEL // 7
Special Remarks on the Behaviour of the Electrical Resistance vs. Temperature // The variation of the resistivity of Super
Pure Nickel vs. temperature in the range between -200 °C and
+1,000 °C is shown in graph 1. As can be seen, the values below the
Curie point are distinctly lower than could be expected on the basic
20
of the behaviour
in the paramagnetic range above the Curie Point.
Accordingly, the temperature coefficient increases from a value of
6,600 ppm/K in the range between 0 °C and +100 °C to values of
about 10,000 ppm / K in the range between 0 °C and +357 °C and
shows a distinct decrease at still higher temperatures. The ratio of
the resistivity values at +1,200 °C and at +20 °C is >7.
50
12
40
Ni: 99.2 %
Ni: 99.98 %
30
Curie Point
8
20
10
4
0
-200 -200
0
0 +200 +200 +400 +400 +600 +600 +800 +800+1,000
temperature
temperature
[°C] [°C]
0.80
800
16
true specific heat
0.60
12
0.40
400
enthalpy
Curie Point
8
0.20
200
4
0.00
-200
-400 -200 0 0
Graph 2: Specific Heat and Enthalpy of Super Pure Nickel
96
20
16
80
Ni: 99.98 %
72
12
64
Curie Point
8
56
Ni: 99.2 %
484
-200
0
+200 +300+400+400 +600
+1000 +200
+500 +800
+600
temperature [°C]
temperature
[°C]
Graph 3: Thermal Conductivity of two Nickel Types of Different Pureness
16
12
Curie Point
8
4
-200
0
+200
+400
+600
+800
temperature [°C]
Graph 4: Thermal Expansion Coefficient of Super Pure Nickel
Issue 29-March-2014
thermal conductivity [W/m·K]
88
thermal expansion coefficient [10-6/K]
20
thermal expansion coefficient [10-6/K]
0
+200+400 +600
+400 +800 +1,000
+600 +1,200
+800
+200
temperature
temperature
[°C] [°C]
1 ppm = 10-6 = 0.0001 %, 1,000 ppm = 1 ∙ 10-3 = 0.1 %.
Graph 1: Resistivity of Nickel vs. Temperature
600
enthalpy [J/g]
16
60
thermal
expansion
coefficient [10-6/K]
true
specific
heat [J/g·K]
thermal
expansion
coefficient [10-6/K]
resistivity
[µ x cm]
20
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