Atomic Structure Atoms. Everything is made of atoms. An atom is the smallest piece of a substance that can exist. 7 million atoms joined together in a straight line would be about 1mm long. All atoms have a nucleus (the big bit in the middle). The nucleus contains protons and neutrons. All atoms have electrons. For any neutral atom, the number of protons is the same as the number of electrons. If an atom loses or gains electrons, it is called an ion. This is a picture of a sodium atom. It has 11 protons, 11 electrons and 12 neutrons. Each proton has an electrical charge of +1. Each electron has a charge of -1. The neutron has no charge (it is neutral). Because an atom has the same number of protons and electrons, the overall charge is zero (it is neutral). The mass of a neutron and a proton are the same. An electron is very much smaller, about 1/2000th the size of a proton, although it has an equal and opposite electrical charge. The electrons, although tiny, take up most of the space of an atom. This means that most of the space of an atom contains hardly any mass, it is empty, with nearly all the mass centered at the nucleus. Summary Particle Relative Mass Relative Charge Proton 1 +1 Neutron 1 0 Electron 1/ 1840 -1 The protons, neutrons and electrons are shown colored to distinguish them from each other. In reality they have no color. Atomic Number. The number of protons in the nucleus is called the atomic number. For sodium (Na), the atomic number is 11. The atomic number tells you what the element is (see Periodic Table). The atomic number of an element never changes. Mass Number. The number of protons plus the number of neutrons is called the mass number. Sodium has 11 protons and 12 neutrons, the mass number is 23. The mass number is the total number of particles in the nucleus. The mass number and the atomic number are written above and below the chemical symbol for the element, as shown. Isotopes. Atoms of the same element may have different numbers of neutrons. These are called isotopes. For example, Chlorine (atomic number 17) may have 18 or 20 neutrons. The mass number will be either 35 or 37. Isotopes of the same element will have the same chemical properties, because the number of protons and electrons will be the same. Practice Time Fill in the table below in your notes. Notice the color coding to help you out. The answers are on the last page of the notes. Name Fluorine‒19 Symbol 19 9 Oxygen-16 16 8 Nitrogen-14 Protons 9 Neutrons 10 Electrons 9 F O 8 7 8 Atomic # 9 Mass # 19 Ions Atoms can gain or lose electrons. This gives the atom a negative or positive charge. When sodium reacts, it will lose its outer electron. The unstable sodium atom loses its outer electron to become a stable sodium ion. The sodium ion still has 11 protons (11 positive charges), but now only 10 electrons (10 negative charges). The sodium ion has an extra positive charge, shown by the + sign. In general, if an atom gains an electron it will become negatively charged (gaining negatively charge electrons causes the atom to become negatively charged). Losing electrons causes the atom to become positively charged (losing a negative charge leaves the atom with a positive charge due to more protons). Practice Time Fill in the table below in your notes. Notice the color coding to help you out. The answers are on the last page of the notes. Name Nitrogen ‒14 ion Symbol 14 7 Oxygen-16 ion 16 8 Sodiumion N O 3- 2- Protons Neutrons Electrons Atomic # Mass # 7 7 10 7 14 8 Charge of ion 3- 10 11 10 11 1+ Answers to Practice Exercises: Name Symbol Fluorine‒19 19 9 Protons 9 Neutrons 10 Electrons 9 Atomic # 9 Mass # 19 8 8 8 8 16 7 7 7 7 14 F Oxygen-16 16 8 O Nitrogen-14 14 N 7 Name Nitrogen ‒14 ion Symbol 14 7 Oxygen-16 ion 16 8 Sodium- 22 ion 22 N 3- 2- O + Na 11 Protons Neutrons Electrons Atomic # Mass # 7 7 10 7 14 Charge of ion 3- 8 8 10 8 16 2- 11 11 10 11 22 1+