Safety Data Sheet Sasfroth 10 Version 1.10 Revision Date 19.04.2012 1. Identification of the substance/mixture and of the company/undertaking Trade name Sasfroth 10 Synonyms Sasfroth 10 Product code 3283 Company Sasol Solvents A Division of Sasol Chemical Industries 2 Sturdee Avenue Rosebank 2196 Republic of South Africa Information (Product safety) Telephone: +27 11 280 0000 Fax: +27 11 280 0198 E-mail address msds.info@sasol.com Emergency telephone number Europe, Israel, Africa, Americas Middle East, Arabic African countries Asia Pacific China South Africa Australia +44 (0)1235 239 670 +44 (0)1235 239 671 +65 3158 1074 +86 10 5100 3039 +27 (0)17 610 4444 +61 2 9032 0460 2. Hazards identification Identification of the risks R22 Harmful if swallowed. 3. Composition/information on ingredients Preparation on the base: hexan-1-ol Contents: 25.98 %W/W CAS-No. 111-27-3 Symbol(s) Xn Index-No. 603-059-00-6 R-phrase(s) -R22 EC-No. 203-852-3 1-pentanol Contents: 9.53 %W/W CAS-No. 71-41-0 Symbol(s) Xn Print Date 19.04.2012 Index-No. 603-200-00-1 EC-No. 200-752-1 R-phrase(s) -R10 -R20 -R37 -R66 100000002042 1/7 Safety Data Sheet Sasfroth 10 Version 1.10 Revision Date 19.04.2012 Cyclohexanol Contents: 7.65 %W/W CAS-No. 108-93-0 Symbol(s) Xn Index-No. 603-009-00-3 EC-No. 203-630-6 R-phrase(s) -R20/22 -R37/38 2-methylcyclohexanol, mixed isomers Contents: 1.27 %W/W CAS-No. 583-59-5 Symbol(s) Xn Index-No. 603-010-00-9 R-phrase(s) -R20 EC-No. 209-512-0 For the full text of the R-phrases mentioned in this Section, see Section 16. 4. First aid measures General advice If you feel unwell, seek medical advice (show the label where possible). Inhalation Move to fresh air in case of accidental inhalation of vapours. In case of shortness of breath, give oxygen. If breathing is irregular or stopped, administer artificial respiration. Call a physician immediately. Skin contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Eye contact Rinse immediately with plenty of running water, also under the eyelids, for at least 15 minutes Remove contact lenses. If eye irritation persists, consult a specialist. Ingestion If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. 5. Firefighting measures Suitable extinguishing media Water spray, Dry powder, Foam Specific hazards during firefighting Do not allow run-off from fire fighting to enter drains or water courses. Wear self-contained breathing apparatus and protective suit. Special protective equipment for firefighters Further information Print Date 19.04.2012 Standard procedure for chemical fires. In the event of fire, cool tanks with water spray. 100000002042 2/7 Safety Data Sheet Sasfroth 10 Version 1.10 Revision Date 19.04.2012 6. Accidental release measures Personal precautions Use personal protective equipment. Do not breathe vapours or spray mist. Ensure adequate ventilation. Keep away from sources of ignition - No smoking. Environmental precautions Avoid subsoil penetration. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). The material taken up must be disposed of in accordance with regulations. 7. Handling and storage Handling Safe handling advice Wear personal protective equipment. Avoid contact with skin and eyes. Keep away from sources of ignition - No smoking. No special protective measures against fire required. Advice on protection against fire and explosion Storage Requirements for storage Keep containers tightly closed in a cool, well-ventilated place. areas and containers 8. Exposure controls/personal protection Components with workplace control parameters NATIONAL OCCUPATIONAL EXPOSURE LIMITS Contains no substances with occupational exposure limit values. EUROPEAN OCCUPATIONAL EXPOSURE LIMITS Contains no substances with occupational exposure limit values. Engineering measures Provide sufficient air exchange and/or exhaust in work rooms. Personal protective equipment Respirator with a vapour filter (EN 141) Respiratory protection Hand protection Eye protection Print Date 19.04.2012 Solvent-resistant gloves Safety glasses with side-shields 100000002042 3/7 Safety Data Sheet Sasfroth 10 Version 1.10 Revision Date 19.04.2012 Skin and body protection Protective suit, Safety shoes Hygiene measures Wash hands before breaks and immediately after handling the product. Protective measures Wear suitable protective equipment. 9. Physical and chemical properties Form Liquid State of matter Liquid; at 20 °C; 1,013 hPa Colour Clear, colourless amber Odour Alcohol-like pH 7; Neutral Melting point/range -40 °C Boiling point/boiling range 140 °C Flash point 57 °C; Closed cup Density 0.85 g/cm ; 20 °C Water solubility Partly soluble Partition coefficient: n-octanol/water No data available Solubility in other solvents Medium: Diethylether; Soluble Solubility in other solvents Medium: Methanol; Soluble Solubility in other solvents Medium: acetone-like; Soluble Solubility in other solvents Medium: n-octanol; slightly soluble Viscosity, dynamic 1.32 mPa.s; 20 °C 3 10. Stability and reactivity Materials to avoid Oxidizing agents, Reducing agents Hazardous decomposition products Carbon dioxide (CO2) Carbon monoxide Print Date 19.04.2012 100000002042 4/7 Safety Data Sheet Sasfroth 10 Version 1.10 Revision Date 19.04.2012 11. Toxicological information Acute oral toxicity Hexanol: LD50 rat: 720 mg/kg; literature value n-Pentanol: LD50 rat: 370 mg/kg; literature value Acute inhalation toxicity n-Pentanol: LCLo rat: 14,000 mg/m3; literature value; 6 h Acute dermal toxicity Hexanol: LD50 rabbit: 3,100 mg/kg; literature value n-Pentanol: LDLo rabbit: 4,490 mg/kg; literature value 12. Ecological information Ecotoxicity effects Toxicity to fish Hexanol: LC50 Pimephales promelas: 97.5 mg/l; 96 h; literature value 13. Disposal considerations Product In accordance with local and national regulations. Contaminated packaging Packaging that cannot be cleaned must be disposed of in the same way as the material itself. 14. Transport information ADR RID ADNR IMDG ICAO/IATA Print Date 19.04.2012 UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. (hexanols, pentanols) UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. (hexanols, pentanols) UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. (hexanols, pentanols) UN number: 1987; Class: 3; EmS: F-E, S-D; Packaging group: III; Description of the goods: ALCOHOLS, N.O.S. (hexanols, pentanols) UN number : 1987; Class: 3; Packaging group: III; Description of the goods: Alcohols, n.o.s. (hexanols, pentanols) 100000002042 5/7 Safety Data Sheet Sasfroth 10 Version 1.10 Revision Date 19.04.2012 15. Regulatory information Labelling Regulatory base 1999/45/EC Symbol(s) Xn: Harmful R-phrase(s) R22: Harmful if swallowed. S-phrase(s) S 7/9: Keep container tightly closed and in a well-ventilated place. S16: Keep away from sources of ignition - No smoking. S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S60: This material and its container must be disposed of as hazardous waste. S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Hazardous components which must be listed on the label hexan-1-ol 16. Other information Full text of R-phrases referred to under sections 2 and 3 R10 R20 R20/22 R22 R37 R37/38 R66 Print Date 19.04.2012 Flammable. Harmful by inhalation. Harmful by inhalation and if swallowed. Harmful if swallowed. Irritating to respiratory system. Irritating to respiratory system and skin. Repeated exposure may cause skin dryness or cracking. 100000002042 6/7 Safety Data Sheet Sasfroth 10 Version 1.10 Revision Date 19.04.2012 All reasonable efforts were exercised to compile this SDS in accordance with ISO 11014 and ANSIZ400.1.1993. The SDS provides information regarding the health, safety and environmental hazards, at the date of issue, to facilitate the safe receipt, use and handling of the product in the workplace. Since Sasol and its subsidiaries cannot anticipate or control all conditions under which the product may be handled, used and received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this SDS in the context within which the product will be received, handled or used in the workplace. The user, handler or receiver must ensure that the necessary mitigating measures are in place as regards health and safety. This does not substitute the need or requirement for any relevant risk assessments to be conducted. It further remains the responsibility of the receiver, handler or user to communicate such information to all relevant parties that may be involved in the receipt, use or handling of the product. Although all reasonable efforts were exercised in the compilation of this SDS, Sasol does not expressly warrant the accuracy or assume any liability for the incompleteness of the information contained herein or any advice given. The product is sold and risk passes in accordance with the specific terms and conditions of sale. The MSDS was created by: F. SHAI The MSDS was approved by: M. HUYSER Print Date 19.04.2012 100000002042 7/7