Properties of Matter part I presented by Dr. Alan S. Cornell P125, School of Physics, University of the Witwatersrand Wits 2050 Matter as we know it comes in all shapes an sizes. From microscopic life-forms to gigantic man-made structures. While we can classify material objects in all sorts of ways Solids Liquids Gases Metals Non-Metals Steels Cu-Alloys Al-Alloys .. . etc. where Solids are objects of stable shape and volume, Liquids of stable volume, and Gases expand to the container limit. The treatment of liquids and gases will largely be covered in our studies of fluids in these lectures we shall study some of the bulk/generic properties of matter Overview of material to be covered • Equilibrium • Elasticity: - Stress and Strain - Plastic deformation and breaking stress - Young’s, shear and bulk moduli - Hooke’s law • Hydrostatics (more on this later) • Surface tension • Hydrodynamics (which will be with your next lecturer) Equilibrium Equilibrium body is said to be in equilibrium when it has A body is said to be in ero net forces and torques. equilibrium when the net forces and torques body in (about stable anyequilibrium axis) is zero eturns to equilibrium when A body is in a state of sturbed.stable equilibrium if it returns to equilibrium after body in unstable equilibrium it is disturbed oves away from equilibrium A body is in a state of hen disturbed. unstable equilibrium if it moves away from equilibrium after it is disturbed In order to solve equilibrium problems 1. Identify all the forces acting on the body, including their directions and locations 2. Draw a free-body diagram with all the forces indicated on it 3. Write down a vector force equation for each component (eg. in the x-direction, y-direction etc.) with proper signs, that is: ! ! ! ! F= Fx = Fy = Fz = 0 The vector sums must be independently equal to zero 4. Select a rotational axis for torque calculations (more on this in your mechanics courses) 5. Write down the torque equations with proper signs 6. Solve the equations for any unknown quantities Classifying Load But what happens to objects when they are placed under some sort of external forces? Classifying Loadof loads materials can be Firstly, let us classify the types subjected to: • Normal Load (Axial load) : Load is perpendicular to the Normal Load (Axial): Load that is perpendicular to supporting material. - Tension Load : As the ends of material the supporting material, such as: are pulled apart to make the material longer, the load is called a tension - Tension load.Load: where the ends of the material are pulled - Compression : As the ends of material are pushed in apart to make theLoad material longer, to make the material loadends is called - Compression Load:smaller, wherethethe of the material are a compression load. pushed together to make the material shorter. Tension Compression Tungsten 35 # 10 Steel 20 # 1010 100 Copper 11 # 1010 Strain Stress Brass 2) 9.1 # 1010 0 0.002 0.004 0.006 0.008 0.01 (MN/m Aluminum 7.0 # 1010 Classifying Load (cont) Figure 12.15 Stress-versus-strain 400 Glass 6.5–7.8 # 1010 curve for an elastic solid. Elastic5.6 # 1010 Breaking • Shear Load : Tangential load 300 Quartz limit Water — point — 200 Mercury ∆x Elastic behavior 14 # 10 20 # 1 8.4 # 1010 6#1 10 4.2 # 10 14 # 1 Table1012.1 3.5 # 10 6.1 # 1 10 Typical Values for 2.5 # 10 7.0 #El1 2.6–3.2 # 1010 5.0–5.5 # Youn 10 2.6 # 10 2.7 #1 Substance (N/m — 0.21 # 1 — 2.8 # 1 Shear (or Tangential) Load: where forces act in one direction on one side of an object, and in another direction on the other side. For example: pulling apart h –F Cargo Pressure fs A Tungsten 35 F Steel 20 100 Copper 11 Strain Young’s modulus is typically used to characterize str Brass a rod or wire 9.1 0 0.002 0.004 0.006 0.008 0.01 tension or compression. Note that becauseAluminum strain is a dimension 7.0 Figure 12.15 Stress-versus-strain Fixed face units of force per unit area. Typical values are given in Table 12.1. Glass 6.5–7 curve for an elastic solid. (a) (a) that for a fixed applied force, the change in length is proporti Quartz 5.6 length and (b) that the force necessary to produce a given strain Water are in accord w the cross-sectional area. Both of these observations Mercury For∆xrelatively small stresses, the bar will return to its initial lengt removed. TheAelastic limit of a substance is defined as the maxim F F be applied to the substance before it becomes permanently deform turnhto its initial length. It is possible to exceed the elastic limit of a ing a sufficiently large stress, as seen in Figure 12.15. Initially, a Young’s modulus is ty curve is a straight line. As the stress increases, however, the cu tension or compressio straight line. When the stress exceeds the elastic limit, the object –F Fixed face units after of force per isuni torted and does not return to its original shape the stress rem (a) (a) that for a fixed ap (b) is increased material ultimately breaks. compare materials iseven byfurther, howthethey respond Elastic behavior A good Active wayFigure to 12.16 (a) A shear length and (b) that t deformation in which a rectangular to different types of loads. the cross-sectional are Shear Modulus: Elasticity of Shape block is distorted by two forces of magnitude but opposite We willequal need some sorts of measures for how they do this. For relatively small Another type of deformation occurs when an object is subjected to a directions applied to two parallel faces. (b) A book under shear stress. At the Active Figures link removed. The elastic of its faces while the opposite face is held fixed by another force (Fig F If the object be applied to the subs in this case is called a shear stress. is originally a rectan Stress and Strain So to start us off with the elastic properties of solids, where in reality objects will be deformed by the action of external forces (though internal forces resist this deformation). The deformation of solids can be understood in terms of Stress and Strain Stress and Strain, where: Stress: AIn quantity proportional tohave themeasures. force causing order to compare materials, we must the deformation, that is, the load per unit area • Stress : load per unit Area F F ó = σ= A A F : load applied in Newtons where F: load applied in Newtons A : cross sectional area in m! A: the cross-sectional area!in m2in Pa : stress σ: stress in P a A F F 12.4 Elastic Properties of Solids Except for our discussion about springs in earlier chapters, we have assumed that objects remain rigid when external forces act on them. In reality, all objects are deformable. That is, it is possible to change the shape or the size (or both) of an object by applying external forces. As these changes take place, however, internal forces in the object resist the deformation. We shall discuss the deformation of solids in terms of the concepts of stress and strain. Stress is a quantity that is proportional to the force causing a deformation; more specifically, stress is the external force acting on an object per unit cross-sectional area. The result of a stress is strain, which is a measure of the degree of deformation. It is found that, for sufficiently small stresses, strain is proportional to stress; the constant of proportionality depends on the material being deformed and on the nature of the deformation. We call this proportionality constant the elastic modulus. The elastic modulus is therefore defined as the ratio of the stress to the resulting strain: Strain: A measure of the degree of deformation, as measure by the elongation of a material from its original length (cont) ∆L Strain = L0 ss and Strain tion of a n stress (12.5) of the material in m modulus where ∆L = Elastic L− L0!: strain the elongation The modulusunloaded in general relates what is done to a solid object (a force isof ap- the material (m) L0elastic : the (original) length plied) to how that object responds (it deforms to some extent). We consider three types of deformation and define an elastic modulus for each: Note that Strain hasoriginal no dimensions. material to the length 1. Young’s modulus, which measures the resistance of a solid to a change in its length Lo e 2. Shear modulus, which measures the resistance to motion of the planes within a solid parallel to each other Li ∆L 3. Bulk modulus, which measures the resistance of solids or liquids to changes in their volume A Young’s Modulus: Elasticity in Length L Consider a long bar of cross-sectional area A and initial length Li that is clamped at one end, as in Figure 12.14. When an external force is applied perpendicular to the cross section, internal forces in the bar resist distortion (“stretching”), but the bar reaches an equilibrium situation in which its final length Lf is greater than Li and in which the external force is exactly balanced by internal forces. In such a situation, the bar is said to be stressed. We define the tensile stress as the ratio of the magnitude of the external force F to the cross-sectional area A. The tensile strain in this case is defined as the ratio of the change in length !L to the original length Li. We define Young’s modulus by a combination of these two ratios: elongation (m) unloaded(original) length of a material (m) strain (m/m) F Active Figure 12.14 A long bar clamped at one end is stretched by an amount !L under the action of a force F. At the Active Figures link at http://www.pse6.com, you can adjust the values of the applied force and Young’s modulus to observe the change in length of the bar. Uniaxial (Tension or Compression) Forces and Distortions Uniaxial (Tension or Compressive) Forces and Distortions To recap, for a material under a uniaxial force (the definitions be for/ more general loads): F isabove +ve –can Tension Elongation If F is positive the material will be under tension is –ve – Compressive / Shortening (that is,Felongated) If F is negative the material will be under a comUniaxial force F pressive forceStress (that is, Uniaxial = shortened) = cross sectional area A Uniaxial force F Uniaxial Stress = = -2L-2]=[ML-1T-2] [!] =[stress]=[F/A]=[MLT cross − sectional area A −2 −2 −1 −2 [σ] = [stress] = [F/A] = [M LT L ] = [M L -2 -3 Units: Nm = Pascal = Pa or Nm m = Joules Tm-3 ] That is, it has units: N m−2 = Pascal = P a or N.m/m3 = Joules m−3 extension L ! L0 extension ÄL ∆L Longitudin al Strain = = = == Longitudinal Strain original length L0 L0 L0 original length Strain hashas no no units or or dimensions Strain units dimensions Tension testing machines A36 Steel Stress and Strain Diagram Stress-Strain Diagrams As we saw from the movie, a plot of stress vs. strain gives us the behaviour of the material to applied forces, where Stress-Strain these diagrams are different forDiagram different materials. ultimate tensile strength 3 Slope= E ! UTS yield strength !y E = Eε ó =E å σ =E = ó å ε Strain Hardening 2 Stress (F/A) σ Plastic Region Elastic Region 1 E= necking óy å2 ! å1 4 Strain ( Fracture 5 Elastic region slope=Young’s(elastic) modulus yield strength Plastic region ultimate tensile strength strain hardening fracture !) (e/Lo) Before continuing with our definitions let us look at each element in this plot and what it represents in the movie we saw: • Elastic Region (Points 1-2) - The material will return to its original shape after the material is unloaded (like a rubber band) - The stress is linearly proportional to the strain in this region σ σ = E Strain or E = Strain where σ = Stress E is the Elastic modulus (Young’s Modulus) • Yield Strength (Point 2): a point at which permanent deformation occurs. If it is passed, the material will no longer return to its original length. • Plastic Region (Point 2-3) - If the material is loaded beyond the yield strength, the material will not return to its original shape after unloading - It will have some permanent deformation - If the material is unloaded at Point 3, the curve will proceed from Point 3 to Point 4. The slope will be the same as the slope between Point 1 and 2 - The distance between Point 1 and 4 indicates the amount of permanent deformation • Strain Hardening - If the material is loaded again from Point 4, the curve will follow back to Point 3 with the same Elastic Modulus (slope) - The material now has a higher yield strength of Point 4 - Raising the yield strength by permanently straining the material is called Strain Hardening • Tensile Strength (Point 3) - The largest value of stress on the diagram is called the Tensile Strength or the Ultimate Tensile Strength - It is the maximum stress which the material can support y all solid without materials respond to a small breaking d force by• changing length.5) Fracture (Point - If the material is stretched beyond Point 3, the stress esponsedecreases takes three progressive as necking and non-uniform deformation occurs as the force increases, - Fracturing will finally occur at Point 5. Elasticity ic region – ortional deformation ic region – permanent mation re - fracture Poisson’s ratio Poisson’s Ratio Note that longitudinal strain does not occur in isolation, there is Longitudinal Strain does not occur in isolation, also some thinning (or widening) there is also a thinning (widening) of the specimen whichspecimen. is called transverseThis Strain is called of the Transverse Strain !b b - b0 Transverse Strain = b0 = b0 ∆b b − b0 Transverse Strain = = b0 ÄL Lb!0 L Longitudinal Strain = L = 0 L ∆L where Longitudinal Strain = . L0 Strain ( "b / b ) It Transverse is therefore convenient to= define ratio:s Ratio =Const. = the ! = Poisson' 0 0 0 Longitudinal Strain ( "L / L ) 0 Transverse Strain (∆b/b0 ) Poisson s Ratio = =− =ν Longitudinal Strain (∆L/L0 ) ! where ν is a constant. Young’s, shear and bulk moduli As seen earlier in the stress vs. strain plots, there is a region where (the elastic region) where stress is proportional to strain, this constant of proportionality is the Elastic Modulus stress Elastic Modulus ≡ strain There are three types of elastic modulus we shall look at here: 1. Young’s modulus: which is a measure of the elasticity in length 2. Shear modulus: which is a measure of the elasticity in the plane 3. Bulk modulus: which is a measure of the elasticity in volume Tensile deformation again In the case of tensile deformation, like in the movie, in the elastic region, the elastic modulus is called the Young’s !"#$%&"'(")*+,-.%*# modulus, where 9,$)"*0$('0#1$)"#$#-'0)*($5+2 )"#$:+4,.;0$5+24- T ensile Stress F/A F Li Y = = = T ensile Strain ∆L/Li A∆L where some common values are Y = 107 − 108 P a for rubber, and Y = 2 × 1011 P a for steel. ) *&+%'* !"#*++ ( " ) *&+%'* !"#$%& !"#$%& !"#$%&'()"*#+#' ,-").'(!"#$% /01123 /0112304567 ( " '!( ! ( " 0#' ! 21#3"3* 2#$%3" #$%3" " 21#4!3 3* Shear deformation In the same way, when we have deformation caused by a force acting parallel to one face of an object whilst an opposing force acts on another face in the opposite direction 01',*%&'()*+,-.)/ (eg holding it in place), we can define shear stress and strain A"##B1+,*#()*+((#,-.#()*,/-"# as: F Shear stress = $" F %7(.' %&'( A where F is the tangential to the area A φ # ! &.09(0&/.# : 2';( + ,% of the face being sheared ! x & Shear strain = h where x is the horizontal distance that 6 φ %7(.' %&'./0 ! % 7 the sheared face moves and h is the height of the object. The Shear modulus is then defined as: F/A shear stress = S= shear strain x/h S E C T I O N 1 2 . 4 • Elastic Properties of Solids a single subforces occurs f deformation ess is defined the area A of y in more det "P ! "F/A, in is equal to Equation 12.5, ulk modulus, (12.8) number. This ses a decrease 375 Note that that shear modulus or coefficient of rigidity can also be called the torsion modulus or modulus of rigidity and is usually between Y /3 to Y /2 (Y is the Young’s modulus). This is for solid materials only! Bulk modulus: Volume Elasticity Finally, when the stress is a uniform pressure on all sides Bulk modulus of the object, and the resulting deformation is a volume change, we speak of bulk stress and bulk strain. Vi alues in a difsted. The reci- ulus. However, a liquid does ensile force is oor. The fric- F A ∆V Bulk Strain = V olume Strain = V0 ∆p Bulk M odulus = B = − ∆V /V0 Bulk Stress = P ressure = P = F Vi + ∆V Active Figure 12.17 When a solid is under uniform pressure, it undergoes a change in volume but no change in shape. This cube is compressed on all sides by forces nor- Note that the negative sign is inserted to ensure that B is a positive number, as an increase in pressure (∆P ) causes a decrease in volume (negative ∆V ) and vice versa. In some texts the reciprocal of the bulk modulus is given, this quantity is known as the compressibility. Hooke’s law As most of you should know, the work done in moving a particle a distance x for a constant force F is W = Fx But this is only true if F is a constant. In cases where F is a function of x ! xf W = F (x)dx xi One common example of this is for the case of a block moving on a frictionless surface which is connected to a spring. If the spring is either stretched or compressed a small distance from its unstretched (equilibrium) position, the force exerted on the block can be expressed as: S ECTI O N 7.4 • Work Done b F = −kx Fs is negative. x is positive. where x is the position of the block relative to the equilibrium position (x = 0) and k is a positive constant called the force constant or the spring constant. This force law for a spring is known as Hooke’s law, where k is a measure of the stiffness of the spring. In this case, the work done in moving a particle from position xi to xf while attached to a spring with spring constant k is: ! xf ! xf 1 W = F dx = (−kx)dx = k(x2i −x2f ) 2 xi xi As we shall see in the next section, the spring constant k can be related to the modulus for elasticity. x x x=0 (a) Fs = 0 x=0 x x=0 (b) Fs is positive. x is negative. x x x=0 (c) Fs Area = –1 kx 2max 2 kx max x 0 x max Fs = –kx (d) Active Figure 7.10 The force exerted by a spring on a block varies with the block’s position x relative to the equilibrium position x ! 0. (a) When x is positive (stretched spring), the spring force is directed to the left. (b) When x is zero (natural length of the spring), the spring force is zero. (c) When x is negative (compressed spring), the spring force is directed to the right. (d) Graph of Fs versus x for the block–spring At th link at htt you can o motion fo 32$/+,1&#-#%45 Elastic energy ∆* ? @ > > >(% /, 4( ! + (, + (, /, 2 / ! ! + #3& ! 3 ! 4 3 ( In the above)1(2 we stretch a rod which has )*+,-./01-)2'-2 3(2 2 Young’s modulus: F/A F/A H/&(;!"I('!1&(*1()-"&-#/*12(-/&("!'(*1#"&$)&)(-/&(7!-&1-*$%( = Y = &1&"2,(!<(-/&("!'>(H/*)(*)(#$%%&'(*#(,)$0&*-*+1.> ∆!/L x/L "6 is related to "6the spring constant: where the force $ % 5 ! + #3&73 ! 4 ( * 373 ! % 4( 6 YA * YA F (x) = x = kx , k = L L $ 8$1 ! 4( 6 % % The work done in stretching this rod increases the potential energy of the rod. This is called the elastic energy ! x ! x 1 2 1 2 W = F (x)dx = k xdx = kx ⇒ Eelastic = kx 2 2 0 0 That is, the energy stored in the material is also expressible as: 1 Y Ax2 1 " x #2 Estored = = Y (AL) 2 L 2 L 1 = Y (strain)2 V 2 The energy density stored within the material is then: Estored 1 1 (stress)2 2 u≡ = Y (strain) = V 2 2 Y