Menu Print Name Date Class CHAPTER 3 TEST Atoms: The Building Blocks of Matter MULTIPLE CHOICE On the line at the left of each statement, write the letter of the choice that best completes the statement or answers the question. 1. The behavior of cathode rays in a glass tube containing gas at low pressure led scientists to conclude that the rays were composed of . a. energy b. positive particles 2. c. negative particles d. neutral particles The basic principles of atomic theory that are still recognized today were first conceived by . a. Avogadro b. Bohr 3. c. Dalton d. Rutherford An example of the law of multiple proportions is the existence of a. FeCl3 and Fe(SO4)3 b. O2 and O3 4. 5. c. CO and CO2 d. FeCl2 and Fe(NO3)2 Atoms of the same element can differ in a. b. c. d. . chemical properties mass number atomic number number of protons and electrons Dalton’s atomic theory helped to explain the law of conservation of mass because it stated that atoms . a. could not combine b. were invisible 6. Milliken’s experiments determined a. b. c. d. 7. c. all had the same mass d. could not be created or destroyed . that the electron carried no charge that the electron carried the smallest possible positive charge the approximate value of the electron’s mass that the electron had no mass In Rutherford’s experiment, a small percentage of the positively charged particles bombarding the metal’s surface . a. b. c. d. 8. . were slightly deflected as they passed through the metal were deflected back toward the source from the metal passed straight through the metal combined with the metal Most of the volume of an atom is made up of the a. nucleus b. nuclides MODERN CHEMISTRY HRW material copyrighted under notice appearing earlier in this work. . c. electron cloud d. protons CHAPTER 3 TEST 9 Menu Print Name Date Class CHAPTER 3 TEST continued FILL IN THE BLANK Write the correct term (or terms) in the space provided. 9. If a particular compound is composed of elements A and B, the ratio of the mass of B to the mass of A will always be the same. This is a statement of the law of . 10. The amount of a substance that contains a number of particles equal to the number of atoms in exactly 12 g of carbon-12 is referred to as a(n) . 11. Since any metal cathode used in a cathode-ray tube produced the same charged particles, it was concluded that all atoms contain . 12. The smallest particle of an element that retains the chemical properties of that element is a(n) . 13. Atoms of one element that have different masses are called . 14. The total number of protons and neutrons in the nucleus of an isotope is called its number. 15. The short-range attractive forces that hold the nuclear particles together are called . 16. The number of protons in the nucleus of an element is called its number. 17. If two or more compounds are composed of elements A and B, the ratio of the masses of B combined with 1 g of A make each compound a ratio of small whole numbers. This is a statement of the law of . 18. Dalton’s atomic theory agreed with the modern atomic theory EXCEPT for the statement that all atoms of the same element have the same . Complete the following table to compare the types of subatomic particles. Particle Mass number 19. Proton 20. Neutron 21. Electron 10 CHAPTER 3 TEST Relative charge Location MODERN CHEMISTRY HRW material copyrighted under notice appearing earlier in this work. Menu Print Name Date Class CHAPTER 3 TEST continued SHORT ANSWER Write the answers to the following questions in the space provided. 22. Give three of the main concepts in Dalton’s atomic theory. 23. What is molar mass? How is it related to atomic mass? 24. Explain why the atomic mass of a particular isotope of an element differs from the average atomic mass of that element. PROBLEMS Write the answers to the questions on the line to the left, and show your work in the space provided. 25. The atomic number of nickel-60 is 28. How many neutrons does this isotope have? 26. Carbon-14 has 8 neutrons. What is the atomic number of carbon-14? MODERN CHEMISTRY HRW material copyrighted under notice appearing earlier in this work. CHAPTER 3 TEST 11 Menu Print Name Date Class CHAPTER 3 TEST continued 27. An atom of silicon-30 contains 14 protons. How many electrons does it have? 28. Oxygen has three naturally occurring isotopes in the following proportions: oxygen-16, 99.762% (15.994 91 amu); oxygen-17, 0.038000% (16.999 13 amu); oxygen-18, 0.20000% (17.999 16 amu). What is the average atomic mass of oxygen? 29. The average atomic mass of chromium is 52.00 amu. What is the mass of 3.00 mol of chromium? 30. How many moles are in a sample of 63.658 g of carbon? (The molar mass of carbon is 12.01 g/mol.) 31. The mass of a sample of nickel (average atomic mass 58.69 amu) is 11.74 g. How many atoms does it contain? 32. The atomic mass of sulfur is 32.06 amu. How many atoms are present in exactly 2 mol sulfur? 12 CHAPTER 3 TEST MODERN CHEMISTRY HRW material copyrighted under notice appearing earlier in this work. Menu 36. 37. 38. 39. 40. Print The graph of two quantities that are inversely proportional is a curve called a hyperbola. 2.20 g/cm3 3% 114 g 8.12 102 L 3.164 g 28. 29. 30. 31. 32. 15.999 amu 156 g 5.300 mol 1.205 1023 atoms 1.204 1024 atoms 4 3 1. 2. 3. 4. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. Atoms: The Building Blocks of Matter, pp. 9–12 c 5. d c 6. c c 7. b b 8. c definite proportions mole electrons atom isotopes mass nuclear forces atomic multiple proportions mass 1; 1; in the nucleus 1; 0; in the nucleus 0; 1; outside the nucleus (in the electron cloud) Answers should include three of the following: All matter is composed of extremely small particles called atoms. All atoms of an element are identical in size, mass, and other properties; atoms of different elements differ in size, mass and other properties. Atoms cannot be subdivided, created, or destroyed. Atoms of different elements combine in simple whole-number ratios to form chemical compounds. In chemical reactions, atoms are combined, separated, or rearranged. The molar mass of a substance is the mass of one mole of the substance. A mole of any substance contains 6.022137 1023 particles, or Avogadro’s number of particles. The atomic mass is the mass of one atom. The atomic mass of a single isotope of an element is its relative mass compared to the mass of carbon-12. The average atomic mass of an element is the weighted average of the masses of all naturally occurring isotopes of an element. 32 6 14 90 CHAPTER TESTS ANSWER KEY 1. 2. 3. 4. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. Arrangement of Electrons in Atoms, pp. 13–16 c 5. c d 6. b d 7. a b 8. a noble gas frequency or wavelength longer hertz wavelength photoelectric effect ground state frequency line-emission 3.00 108 m/s red Heisenburg uncertainty principle inner-shell electrons electromagnetic radiation d a b c the photoelectric effect and the line-emission spectrum of hydrogen A line-emission spectrum is produced when an electron drops from a higher-energy orbit to one with lower energy, emitting a photon whose energy is equal to the difference in energy between the two orbits. 1s22s22p5 1s22s22p63s23p4 1s22s22p63s23p64s2 1s22s22p63s23p63d64s2 [He] 2s22p2 [He] 2s22p6 [Xe] 6s2 [Ar] 4s1 ↑↓ ↑ 37. 1s 2s ↑↓ ↑↓ ↑ 38. 1s 2s 2px ↑ 2py 2pz ↑↓ ↑↓ ↑↓ 39. 1s 2s 2px ↑↓ 2py ↑↓ 2pz MODERN CHEMISTRY HRW material copyrighted under notice appearing earlier in this work.