Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 10 HOMEWORK 10-1 (pp. 303–304) VOCABULARY Define. 1. kinetic-molecular theory ______________________________________________________________ __________________________________________________________________________________ 2. ideal gas __________________________________________________________________________ __________________________________________________________________________________ 3. elastic collision _____________________________________________________________________ __________________________________________________________________________________ Complete the sentence. 4. Kinetic-molecular theory can be used to explain _________________________________________ _________________________________________________________________________________. SKILL BUILDER On a separate sheet of paper, create an outline to list the assumptions that support the kineticmolecular theory of gases. Your outline should have five main points. Each main point should have at least one subtopic. You can use an outline with Roman numerals and numbers, a bulleted list, or some other form. STANDARDIZED TEST PREP Circle the letter of the best answer. 1. The average kinetic energy of gas particles a. stays the same regardless of the temperature. b. increases with a decrease in temperature. c. increases with an increase in temperature. d. does not depend on the mass of the particles. 2. Which statement is true? a. Gas particles bond when they collide. b. Molecules in liquids are farther apart than molecules in gases. c. The kinetic-molecular theory applies only to gases and their properties. d. Argon molecules have lower average speeds than oxygen molecules. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Print Lesson Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 10 HOMEWORK 10-2 (pp. 305–307) VOCABULARY Complete each sentence. 1. Liquids and gases are alike because ____________________________________________________. 2. Diffusion is ______________________________________________________________________. 3. The density of a substance in a gaseous state is much less than its density in liquid or solid state because __________________________________________________________________________. 4. The rate of diffusion of one gas through another depends on _______________________________. 5. The process by which gas particles under pressure pass through a tiny opening is called __________ _________________________________________________________________________________. 6. A real gas is ______________________________________________________________________. SKILL BUILDER Circle the three gases that you would expect to behave most like ideal gases. Kr NH3 H2O O2 SO2 Ne Circle the three gases that you would expect to deviate most from ideal behavior. HCl CO2 Rn Ar N2H4 H2 Assume that the gases in each pair are allowed to mix with each other at the same temperature. Circle the gas that will diffuse more rapidly. 1. Kr NH3 2. H2O N2H4 3. Ne Kr 4. CO2 SO2 5. PCl3 C4H10 STANDARDIZED TEST PREP Circle the letter of the best answer. 1. Which is not true about gases? a. Gases expand to fill their containers. b. Gas particles mix with other gas particles in random patterns. c. Gases are generally less dense than solids. d. Gas particles move rapidly without significant attraction or repulsion between particles. 2. Which of these gases will effuse more quickly than CO? a. Xe b. O2 c. C3H8 d. Ne Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 10 HOMEWORK 10-3 (pp. 308–310) VOCABULARY Answer each question. 1. How is pressure defined? ____________________________________________________________ 2. Write the formula for pressure. _______________________________________________________ 3. What is the SI unit for force? What does that SI unit measure? _______________________________ _________________________________________________________________________________ 4. What does a barometer measure? _____________________________________________________ 5. On what does specific atmospheric pressure depend? ____________________________________ _________________________________________________________________________________ GRAPHIC ORGANIZER Using an additional sheet of paper, make a K-W-L Chart similar to the one below to record your ideas about the physical characteristics of gases. In the K column, write what you already know, both from your prior knowledge and the first section of this chapter. In the W column, write what you want to know about the physical characteristics of gases. Finally, in the L column, record the answers to your questions as you read. You may not be able to answer all of your questions. Continue working on your K-W-L chart as you read the rest of Chapter 10. K What I Know The Physical Characteristics of Gases W What I Want to Know L What I’ve Learned STANDARDIZED TEST PREP Circle the letter of the best answer. 1. What conditions are required so that the average pressure of the atmosphere supports a 760 mm column of mercury? a. altitude of 0 km, 0ºC b. altitude of 0 km, 0ºF c. altitude of 0 km, any temperature d. any altitude, 0ºC 2. If two equal forces are applied to two different areas, which statement is true? a. The force that is applied to a smaller area results in less pressure. b. The pressure on the two areas will be the same, regardless of their size. c. The force that is applied to a larger area results in less pressure. d. The force that is applied to a smaller area results in a lower temperature. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 10 HOMEWORK 10-4 (pp. 311–312) VOCABULARY Select the term in Column B that matches the expression in Column A. Column A Column B 1. pressure formula _____ a. 1 N/m2 2. millimeters of mercury _____ b. mm Hg 3. Pascal _____ c. force/area 4. 1 atmosphere _____ d. 760 mm Hg 5. STP _____ e. 1 atm, 0ºC SKILL BUILDER Fill in the chart by supplying the missing quantities. Use conversion factors to convert data in atmospheres, mm Hg, and kPa. Show four significant figures in your answers. Pressure in atm Pressure in mm Hg Pressure in kPa 0.943 1345.21 79.64 1029.8 0.546 STANDARDIZED TEST PREP Circle the letter of the best answer. 1. The mercury in a barometer falls until a. the pressure exerted by its weight is equal to the pressure exerted by the atmosphere. b. the diameter of the mercury tube is increased. c. the pressure exerted by its weight is less than the pressure exerted by the atmosphere. d. a barometer is placed at an elevation lower than sea level. 2. Each item shows common units of measurement in chemistry. In which item are all of the units shown used to express pressure measurements? a. Pa, kPa, atm, kg b. kPa, torr, km, K c. atm, torr, mm Hg, Pa d. torr, N, mm Hg, kJ Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 10 HOMEWORK 10-5 (pp. 313–315) VOCABULARY Define. 1. gas laws ___________________________________________________________________________ __________________________________________________________________________________ 2. Boyle’s law ________________________________________________________________________ __________________________________________________________________________________ Write two equations that express Boyle’s law. Write three equations that can be used to calculate values when comparing changing conditions for a gas. SKILL BUILDER On a separate sheet of paper, solve the following problems. 1. A gas occupies 14.5 L at a pressure of 0.526 atm. What is the volume when the pressure is increased to 0.780 atm? 2. If a gas occupies 5.40 L at a pressure of 1.25 atm, what will be its volume at a pressure of 3.00 atm? 3. A gas occupies 250 L at 101.325 kPa. What will be the pressure if the gas is compressed to fill a 12.5 L tank? 4. 560.0 mL of a gas is under a pressure of 735.0 torr. What would the volume of the gas be at a pressure of 935.0 torr? 5. A 3.50-L flask is filled with nitrogen at a pressure of 16.0 atm. What size flask would be required to hold this gas at a pressure of 4.00 atm? STANDARDIZED TEST PREP Circle the letter of the best answer. 1. A graph of volume vs. pressure for a gas at constant temperature yields a a. curved line. b. straight line. c. series of random points. d. hyperbola. 2. The equation P1V1 = P2V2 can be used only for systems in which a. the gases involved are noble gases. b. the volumes are measured in mL. c. the temperature is held constant. d. the gases involved are ideal gases. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Print Lesson Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 10 HOMEWORK 10-6 (pp. 316–319) VOCABULARY Define. 1. absolute zero _______________________________________________________________________ __________________________________________________________________________________ 2. Charles’s law ______________________________________________________________________ __________________________________________________________________________________ Answer each question on a separate sheet of paper. 3. Write an equation you can use to convert degrees Celsius to kelvins. 4. Write two equations that express Charles’s law. 5. Why is it important to use kelvins when measuring temperature for gas law calculations? GRAPHIC ORGANIZER Complete the table of volume–temperature data for a gas sample held at constant mass and pressure. Then graph your results. k 3 3 3 3 3 3 3 Volume (L) 1.5 Kelvin Temperature (K) 3.0 4.13 14.8 19.5 24.6 8.20 9.63 44.0 STANDARDIZED TEST PREP Circle the letter of the best answer. 1. A 450.0-mL sample of oxygen is warmed from 45.0°C to 73.5°C. If its pressure remains constant, its volume will be a. 275.5 mL b. 413.0 mL c. 490.3 mL d. 735.0 mL 2. If the Kelvin temperature of a gas is doubled, the volume of the gas will a. be cut in half. b. stay the same. c. double. d. quadruple. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 10 HOMEWORK 10-7 (pp. 319–322) VOCABULARY Define. 1. Gay-Lussac’s law __________________________________________________________________ _________________________________________________________________________________ 2. combined gas law __________________________________________________________________ _________________________________________________________________________________ Answer each question. 3. Write two equations that express Gay-Lussac’s law. _______________________________________ ____________________________________________________________________________________ 4. Write two equations that express the combined gas law. ____________________________________ ____________________________________________________________________________________ SKILL BUILDER On an additional sheet of paper, solve the following problems. 1. At conditions of 640.5 torr and 23.00°C, a gas occupies a volume of 56.40 mL. What will be the volume of the same gas at 782.0 torr and 32.00° C? 2. At a pressure of 740.0 mm Hg and 26.30°C, a certain gas has a volume of 462.0 mL. What will be the volume of this gas at STP? 3. 3.300 L of nitrogen, originally at 28.00°C and 820.0 mm Hg, are heated until a volume of 18.00 L and a pressure of 226.0 mm Hg are reached. What is the new temperature? 4. 78.00 mL of oxygen at STP are heated to 76.00°C. The volume increases to 3.650 L. What is the new pressure? 5. A gas sample occupies 4.250 L at 39.00°C and 1725 mm Hg. At what temperature will the gas occupy 8430 mL at 1.00 atm? STANDARDIZED TEST PREP Circle the letter of the best answer. 1. A graph of pressure vs. temperature for a gas at constant volume yields a. a curved line passing through the origin. b. a hyperbola. c. a straight line passing through the origin. d. either a straight or curved line, depending on the value of k. 2. The action that happens when a balloon is squeezed best illustrates a. Gay-Lussac’s law. b. Boyle’s law. c. Charles’s law. d. the combined gas law. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 10 HOMEWORK 10-8 (pp. 322–325) VOCABULARY Complete each sentence. 1. The partial pressure of a gas is ________________________________________________________ _________________________________________________________________________________. 2. Dalton’s law of partial pressures states that ______________________________________________ _________________________________________________________________________________. 3. Charles’s law represents the relationship between _________________________________________ _________________________________________________________________________________. 4. Boyle’s law shows the relationship between ______________________________________________ _________________________________________________________________________________. 5. Gay-Lussac’s law represents the relationship between ______________________________________ _________________________________________________________________________________. SKILL BUILDER On an additional sheet of paper, solve the following problems. 1. A container holds helium, oxygen, and carbon monoxide gases. Their respective partial pressures are 3.00 atm, 1.50 atm, and 4.00 atm. What is the total pressure inside the container? 2. A container with two gases, hydrogen and argon, is 30.0% hydrogen by volume. Calculate the partial pressures of hydrogen and argon if the total pressure inside the container is 5.00 atm. 3. Hydrogen gas is collected over water at 35°C. If the barometric pressure is 784.0 mm Hg, what is the partial pressure of the hydrogen gas? 4. 275 mL of hydrogen is collected over water at 32°C and 1.4 atm. What is the pressure of the hydrogen at STP? STANDARDIZED TEST PREP Circle the letter of the best answer. 1. In which of these situations does Dalton’s law of partial pressures not apply? a. A gas is collected over water at STP. b. One of the gases involved in the calculations is a noble gas. c. The gases are involved in a chemical reaction. d. Four or more gases are combined in one container. 2. Which statement about gases is not true? a. The relationship between pressure and temperature at constant volume is directly proportional. b. The four measurable quantities needed to fully describe a gas are pressure, volume, temperature, and number of molecules. c. The volume of a gas increases or decreases in direct proportion to the Celsius temperature. d. The relationship between volume and pressure at constant temperature is inversely proportional. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved.