Date of Issue: 02/2015
Page 1 of 2
Phenylmagnesium Bromide, typ. 45 % solution in
Diethyl Ether (typ. 2.8 M)
PRODUCT
Phenylmagnesium Bromide, typ. 45 % solution in Diethyl Ether (typ. 2.8 M)
Product No. 408465
CAS-No. 100-58-3
EINECS-No. 202-867-2
FURTHER
INGREDIENTS
Diethyl Ether
CAS-No. 60-29-7 EINECS-No. 200-467-2
APPLICATION
Grignard-reactions: reagent for the introduction of the phenyl group.
APPEARANCE
yellowish to dark brown liquid
FORMULA
C 6 H 5 BrMg
PHYSICAL
PROPERTIES
Molecular weight:
181.33 g/mol
Density:
1.13 g/ccm (at 20 °C)
Boiling Point:
34.5 °C for Diethyl Ether
Flash Point:
-45 °C for Diethy Ether
Thermal Stability:
crystallisation below around -5 °C
SPECIFICATION
Phenylmagnesium Bromide: 44.0 – 46.0 %
METHOD OF
ANALYSIS
Acidimetric titration of the hydrolyzed product for the determination of assay as total base.
Detailed description available on request.
HANDLING
Phenylmagnesium Bromide should only be handled under inert gas atmosphere. Avoid
contact with eyes, skin and clothes as well as inhalation. Never add water, acids or oxidizing
materials. In case of fire use dry extinguishers based on sodium chloride or limestone
powder, never use water or CO2 . Pay attention to the Safety Data Sheet.
The abov e details hav e been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current state
of our long practical experience. No liabilities or guarantees deriv ing
f rom or in connection with this leaf let can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 40126-72000
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623
Product No. 408465
Date of Issue: 02/2015
Page 2 of 2
STORAGE
Phenylmagnesium Bromide should be stored in tightly closed containers under exclusion of
air and humidity. Under these conditions, stable over practically unlimited periods.
Recommended retest date: six months after date of delivery.
TRANSPORT
REGULATIONS
UN-No.:
2924
Rail/Road (RID/ADR):
Class 3
PG II
Label 3 (8)
Sea (IMDG-Code):
Class 3
PG II
Label 3 (8)
Air (IATA-DGR):
Class 3
PG II
PAX 352
CAO 363
GHS HAZARD
PICTOGRAMS
H&P Phrases: See Safety Data Sheet
SIGNAL WORD
Danger
PACKING
Glass bottles of 100, 250, 500 and 1,000 ml. Steel bottles with volumes of 7.4, 27, 127 and
450 l. For safety reasons these are filled to a maximum of 90 %. Steel drums up to 200 l.
TIME OF DELIVERY
To be agreed upon.
FURTHER RELATED
DOCUMENTS
Brochure ''Organomagnesium Compounds''
Trifold 'C-C Coupling Reactions in Organic Synthesis'
Safety Data Sheet.
The abov e details hav e been compiled to the best of our knowledge
on the basis of thorough tests and with regard to the current state
of our long practical experience. No liabilities or guarantees deriv ing
f rom or in connection with this leaf let can be imputed to us.
Reproduction, in whole or in part, only with our express permission.
® registrated trademark
www.rockwoodlithium.com
Europe:
Rockwood Lithium GmbH
Fax: +49 69 40126-72000
Americas:
Rockwood Lithium Inc.
Fax: +1 704 734-2718
Asia:
Rockwood Lithium Japan K.K.
Fax: +81-3-6434-5623