Metamorphic Zones and Facies (based primarily on sect. 18.1-18.3, Hefferan & OʼBrien, 2010) Metamorphic Zones metamorphic grade The degree of metamorphic recrystallization can range from almost no change to the protolith to changes that make the protolith unrecognizable, from the growth of new minerals in a shale to complete recrystallization as schist or gneiss. This variation in metamorphic grade is due to variations in the temperature and pressure (burial depth) that the protoliths experienced. Barrovian metamorphic zones and index minerals late 19th century geologist were aware that specific metamorphic minerals formed at or above certain temperatures and pressure they could be used as index minerals for temperature and burial depth Barrows (1912) and Tilley (1925) mapped regional metamorphic rocks in Scotland based on the first appearance of several index materials from lowest to highest grade in pelitic (mud-rock) protoliths chlorite zone lowest grade rocks: chlorite-bearing slate, phyllite, schist minerals: chlorite, sericite (phyllosilicate), muscovite ! quartz, albite (Na plag.) and pyrophyllite (phyllosilicate) biotite zone growth of biotite mica, chlorite mica unstable! rocks: biotite-bearing phyllite and schist minerals: remnant chlorite, muscovite, sericite, quartz, Na-rich plagioclase garnet zone: growth of almandine (red, Fe-garnet) rocks: garnet-mica schist ! minerals: almandine, biotite, muscovite, magnetite, quartz, Na-rich plagioclase staurolite zone: growth of staurolite (nesosilicate related to kyanite & silimanite) ! rocks: staurolite-mica schist, staurolite-garnet-mica schist minerals: staurolite, biotite, muscovite, almandine, quartz, k-spar kyanite zone: growth of kyanite (Al2SiO5), staurolite not stable rocks: kaynite schist, kyanite-mica schist minerals: kyanite, biotite, muscovite, almandine, quartz, cordierite silimanite zone: growth of silimanite (Al2SiO5), kyanite not stable ! ! Barrowsʻ & Tilleyʼs highest temperature zone rocks: silimanite schist, silimanite gneiss, cordierite gneiss minerals: silimanite, biotite, muscovite, almandine, quartz, oligoclase and ! orthoclase feldspars, cordierite (cyclosilicate related to emerald & tourmaline) migmatites: at even higher temperature, partial melting can begin in wet protoliths migmatites are an intermingling of gneissic banding and felsic igneous layers with increasing grade (temp & pressure) low-temperature, hydrous phyllosilicates are replaced by minerals stable at higher temp & pressure a problem with Barrovian metamorphic zones is that they were defined based on single index minerals that form from only one kind of protolith Metamorphic Facies Eskola (1920, 1939), Turner (1958) developed the concept of metamorphic facies based on assemblages of minerals that should form together in a metamorphic rock based on specific protoliths and at particular temperatures & pressures hornfels facies - high temp low pressure metamorphism the product of contact metamorphism most common in the upper crust (< 8-10 km) where the country rocks are relatively “cold” compared to the intruding magma albite-epidote hornfels facies < 450 °C contact metamorphism at < 6 km depth meta Rx of this facies contain albite (Na-plag) and/or epidote (a hydrous sorosilicate) ! regardless of protolith includes other hydrous minerals, e.g., chlorite & actinolite hornblende hornfels facies 450-600 °C contact metamorphism at < 8 km depth meta Rx of this facies contain hornblende and/or another amphibole (all hydrous) ! regardless of protolith pyroxene hornfels facies 600-800 °C contact metamorphism at < 8 km depth ! found in direct contact with high temp, mafic intrusions these Rx contain one or more pyroxenes (hypersthene, diopside, augite, enstatite) ! regardless of prototype biotite is the only hydrous mineral in these high temperature metamorphic rocks sanidinite hornfels facies > 800 °C contact metamorphism at < 8 km depth rare, found around mafic & ultramafic intrusions sanidine is common where protolith was felsic silicate composition hydrous minerals are absent increasing temp & pressure facies greenschist through granulite facies correspond approximately to Barrovian regional metamorphic zones zeoloite facies low pressure-low temperature, ~150-300 °C, < ~15 km depth all but ultramafic protoliths produce zeolites (hydrous framework alumino-silicates) ! zeolites commonly form via hydrothermal metamorphism of volcanic rocks pelitic Rx: altered mudrocks to low-grade slate prehnite-pumpellyite facies ~250-350 °C, < ~20 km depth hydrothermal & burial metamorphism prehnite (hydrous phyllosilicate), pumpellyite (hydrous sorosilicate) rich in other hydrous minerals pelitic Rx: slate to phyllite greenschist facies regional metamorphism at ~350-550 °C, ~10-30 km depth corresponds approximately to the Barrovian chlorite through lower garnet facies key minerals: epidote, chlorite, actinolite (a green amphibole) ! pelitic Rx: slate, phyllite, schist dehydration reactions release volatiles ! water released by breakdown of kaolinite clay ! CO2 liberated by breakdown of dolomite into calcite amphibolite facies regional metamorphism at ~550-750 °C, ~12-40 km depth corresponds approximately to the Barrovian upper garnet through silimanite facies pelitic Rx: schist, gneiss dehydration reactions release volatiles ! water released by breakdown of talc ! CO2 liberated by breakdown of dolomite into diopside (pyroxene) ! both water and CO2 liberated by reaction of tremolite and calcite to form diopside granulite facies regional metamorphism at ~700-900 °C, ~10-50 km depth corresponds approximately to the Barrovian upper garnet through silimanite facies hydrous minerals are absent from upper granulite facies rocks ! quartz & kspar are common in pelitic and quartzofeldspathic rocks ! pelitic Rx: gneiss, granulite dehydration reactions release water ! amphiboles undergo dehydration reactions into pyroxenes ! phyllosilicates (clays & micas) dehydrate to various (e.g., muscovite - kspar) high pressure facies form in environments with much lower temperature to pressure (depth) relationship than for the greenschist - granulite sequence associated with subduction zones (sinking crust remains cool, well down into mantle) and very deep lower crustal and mantle conditions blueschist facies - high pressure low temperature subduction zone metamorphism at ~150-500 °C, but ~13-66 km depth often contains the blue amphibole, glaucophane eclogite facies rocks from the deep lower crust or from the mantle metamorphism at ~400-900 °C, and ~40 km to >80 km depth ! key minerals: garnet & omphacite (pyroxene) very dense rocks very deep eclogite facies rocks contain ultra-high pressure minerals ! that are evidence for the depths the rocks were at before being brought to the ! surface ! ! coesite (high pressure polymorph [crystal form] of SiO2) ! ! diamond (high pressure polymorph of carbon) ! ! majorite (high pressure nesosilicate - garnet) ultra-high pressure minerals are also found in impactites