Name:_____________ Section:____________ Pre-Lab 7: Solubility and Net Ionic Equations Answer the following questions after reading the background information at the beginning of the lab. This should be completed before coming to lab. 1. Write the balanced equation for dissolving the following solid ionic salts in water: a) NaCl(s) b) Ba(NO3)2(s) c) MgF2(s) 2. Write the total ionic and balanced net ionic equations for the following reactions: a) AgNO3(aq) + NaCl(aq) ----> AgCl(s) + NaNO3(aq) b) BaCl2(aq) + K2CrO4(aq) ----> KCl(aq) + BaCrO4(s) c) KOH(aq) + Fe(NO3)3(aq) ----> Fe(OH)3(s) + KNO3(aq) ~ 80 ~ This page was left blank intentionally! ~ 81 ~ Lab 7: Solubility and Net Ionic Equations Objectives: In this experiment you will mix small quantities of aqueous ionic solutions together and in some cases, observe the formation of precipitates. General procedure: 1. Mix small quantities of different ionic solutions together. 2. Observe the absence or presence of a precipitate and its physical characteristics such as color, amount, etc. 3. Formulate general solubility rules based on experimental observations. 4. Write net ionic equations to describe the precipitation reactions. Safety • Wear safety goggles at all times. • Wear shoes that cover the entire foot. • Never touch, taste or smell chemicals. • Keep your hands away from your face, eyes, nose and mouth. • Always wash your hands before leaving the laboratory. . Table of Ionic Salt Solutions Solution #1 Solution #2 Solution #3 Solution #4 Solution #5 Solution #6 Set I Set II Ba(NO3)2 Na2SO4 BaCl2 Al2(SO4)3 NaI Sr(NO3)2 AgNO3 CaCl2 NaNO3 AgNO3 KCl ~ 82 ~ Part I. Writing Total Ionic and Net Ionic Equations Students will test ionic salt solutions for insoluble products. This is done be systemaically combining solutions Equipment List: Set 1 of the ionic salt solutions 12 well spotting plate Procedure: 1.Clean the Twelve well spotting plate. 2.Spot a row of 5 spots on the spotting plate. 3.Test this row against the other 5 solution in the first set. 4.Look for reactions and make observations in the charts below. Results 5.Choose another solution, and test against the remaining 4 solutions. 6.Continue until all solutions have been tested against each other. Record observations in the chart below: -Look for precipitates, gas bubbles, etc. -Make notes on any colors seen in the precipitates/changes in solution color. Set # I ~ 83 ~ Discussion For each of the solutions that showed a reaction, Record the solutions that were reacted and generate a total and net ionic equation for each reaction. Did A Solutions Reaction Reacted Occur? Write out the Total Ionic Equation and Net Ionic Equation ~ 84 ~ Solutions Did A Reacted Reaction Occur? Write out the Total Ionic Equation and Net Ionic Equation Additional Question #1. Which ion formed the most insoluble products? Additional Question #2. What is the chemical formula for the colored precipitates, and what are their names? ~ 85 ~ Part II. Predicting Reactions Students will test ionic salt solutions for insoluble products. This is done by systematically combining solutions Equipment List: Set 3 of the ionic salt solutions 12 well spotting plate Procedure: 1. Use the solubility laws to predict if 6. Test this row against the other 5 the these reactions should occur. solution in the first set. 2. Record your predictions before 7. Look for reactions and make beginning testing. observations in the charts below. 3. Have the instructor initial the bottom 8. Choose another solution, and test of the page. against the remaining 4 solutions. 4. Clean the Twelve well spotting plate. 9. Continue until all solutions have 5. Spot a row of 5 spots on the spotting been tested against each other. plate. Predictions For each possible reaction indicate wither a reaction will occur or not, and what the reaction product is. Set #2 Solutions Reacted Will a reaction Occur? Write the Net Ionic Equation for each. 1/2 1/3 1/4 1/5 2/3 2/4 ~ 86 ~ 2/5 3/4 3/5 4/5 Results Record observations in the chart below: -Look for precipitates, gas bubbles, etc. -Make notes on any colors seen in the precipitates/changes in solution color. Actual Results Set #2 Solutions Reacted Did a Reaction Occur? Evidence? 1/2 1/3 1/4 1/5 ~ 87 ~ Was this correctly predicted? 2/3 2/4 2/5 3/4 3/5 4/5 ~ 88 ~ Name:_________________ Solubility and Net Ionic Equations Report Sheet Part I. Writing Total Ionic and Net Ionic Equations Answer the following Questions 1. Which solids formed non-white precipitates? Partner:________________ Section:________________ 2. How many reactions had solid products? 3. Write the net ionic equations for the silver containing precipitates Part II. Predicting Reactions Answer the following Questions 1. # of incorrect predictions: 2. What Ion formed the most solid precipitates? 3. What are the net ionic Equations of the products? Additional Questions: 1. Which of the following salts are soluble in water and explain why: a) Na3PO4 b) CaCO3 2. Explain the following observations using solubility: a) A warm can of soda fizzes up when opened b) One pack of sugar will dissolve in 8 oz.of ice coffee at 35◦F, but 3 packets dissolve in a hot cup at 180◦F. ~ 89 ~